Including Subsequent Reshaping (e.g., Stretching, Etc.) Patents (Class 264/173.15)
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Publication number: 20020160169Abstract: A thermoplastic multi-layer film for forming hermetic seals on packages comprising layer A comprising polyethylene, layer B comprising polypropylene, layer C comprising a copolymer, and an adhesion promoting coating applied to layer C.Type: ApplicationFiled: February 20, 2002Publication date: October 31, 2002Inventor: Michael J. Bader
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Publication number: 20020155308Abstract: The present invention is directed to a biaxially oriented multi-layer film which comprises: (a) a core layer comprising a syndiotactic propylene homopolymer; and (b) at least one additional layer adjacent to the core layer comprising a polymer which is an ethylene or a propylene homopolymer, ethylene copolymer or terpolymer containing comonomers of propylene and/or butene-1. Optionally, there can be a skin layer applied to the exposed surface of the outer layer. The skin layer and/or the at least one additional layer is a polyolefin selected from the group consisting of isotactic polypropylene, polyethylene, ethylene-propylene random copolymer, ethylene-propylene block copolymer or ethylene-propylene -butene-1 terpolymer.Type: ApplicationFiled: December 21, 2001Publication date: October 24, 2002Inventors: Michael T. Heffelfinger, Jay K. Keung, Robert G. Peet
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Publication number: 20020155307Abstract: The present invention is a non-porous, breathable membrane of at least polyamide-4,6, with an elongation at rupture of about 250 to about 500% in the longitudinal direction and about 200 to about 500% in the transverse direction. The membrane has a higher heat resistance than a non-porous, breathable membrane made from polyether ester and, if it also contains an antioxidant, passes the oven/watertightness test. If the membrane is produced from a mixture of polyamide-4,6 and about 10 to about 30% by weight polyether amide, the membrane exhibits a surprisingly increased water-vapor permeability. The membrane is usable in the manufacture of thermally protective clothing.Type: ApplicationFiled: April 3, 2002Publication date: October 24, 2002Applicant: SYMPATEX TECHNOLOGIES GMBHInventors: Bertram R. Bohringer, Henricus Joannes Maria Van De Ven, Jozef Christiaan Wilhelmus Spijkers
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Publication number: 20020155267Abstract: A thermoplastic multi-layer film for forming hermetic seals on packages comprising layer B comprising polypropylene and a softening additive; and layer C comprising a copolymer.Type: ApplicationFiled: February 22, 2001Publication date: October 24, 2002Inventor: Michael John Bader
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Publication number: 20020150751Abstract: Biaxially oriented, coextruded polyester films with a base layer at least 90% by weight of which is composed of a thermoplastic polyester, preferably polyethylene terephthalate (PET), and with at least one sealable outer layer and a second nonsealable outer layer and, if desired, with other intermediate layers, and comprising at least one UV absorber, preferably hydroxybenzotriazoles and triazines, have high UV resistance, do not embrittle when exposed to high temperatures, have a surface without undesirable haze and are suitable for numerous indoor and outdoor applications. The outer layers comprise antiblocking agents, such as silica with an average particle diameter preferably below 50 nm and/or above 2 &mgr;m, and the sealable outer layer is preferably composed of a copolyester which has been built up from ethylene terephthalate units and ethylene isophthalate units.Type: ApplicationFiled: February 8, 2001Publication date: October 17, 2002Inventors: Ursula Murschall, Ulrich Kern, Guenther Crass, Andreas Stopp, Herbert Peiffer
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Patent number: 6461555Abstract: Film-forming means are coextruded to form all plastic multilayer liners and facestocks for pressure-sensitive labels, tapes, decals, signs, bumper stickers, and other products formed from sheet and roll stock. Fill means in a charge for the liner coextrusion affects stiffness and dimensional stability of the liner and/or affects the roughness of a liner face or faces. The film materials of the layers of the constructions are selected according to the cost/benefit characteristics of candidate materials considering the functional or operational requirements of the layer in question.Type: GrantFiled: March 3, 2000Date of Patent: October 8, 2002Assignee: Avery Dennison CorporationInventor: Melvin S. Freedman
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Patent number: 6458469Abstract: An oriented multilayer film comprises: (a) a base layer containing a thermoplastic polymer; (b) at least one tie layer; and (c) at least one outer layer containing a metallocene catalyzed polyethylene chosen for its performance as an adhesion layer and having improved processability. The multilayer films are useful for various end uses including printing, metallization, adhesive lamination, and cold sealing.Type: GrantFiled: July 8, 1999Date of Patent: October 1, 2002Assignee: ExxonMobil Chemical CompanyInventors: John P. DeLisio, Lyle J. Harley, Jay K. Keung, Robert G. Peet
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Publication number: 20020125607Abstract: An elongated composite tube made up of an inner tube 42 and an outer tube 44 (see FIG. 3) with a plurality of elongated helical ribs disposed between the inner tube and the outer tube in a supporting relationship to both. A slinky like toy made from the composite tube is also disclosed, as is a method of making both.Type: ApplicationFiled: May 7, 2002Publication date: September 12, 2002Inventor: F. John Herrington
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Publication number: 20020122932Abstract: The application discloses a transparent, biaxially oriented polyester film having a base layer at least 80% by weight of which is composed of a thermoplastic polyester, and having at least one outer layer, wherein the outer layer is composed of a polymer or a mixture of polymers which comprises at least 40% by weight of ethylene 2,6-naphthalate units and up to 60% by weight of ethylene terephthalate units and/or units from cycloaliphatic or aromatic diols and/or dicarboxylic acids, with the proviso that the Tg2 value of the polyester film is above the Tg2 value of the base layer but below the Tg2 value of the outer layer, where the base layer comprises particles and the Ra value of at least one surface is between 1 and 1000. The film has low gas transmission. It is particularly suitable for packaging uses, specifically for packaging foodstuffs and other consumable items, or as magnetic tape film and as capacitor film.Type: ApplicationFiled: March 24, 1999Publication date: September 5, 2002Inventors: HERBERT PEIFFER, CYNTHIA BENNETT, GOTTFRIED HILKERT
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Publication number: 20020122952Abstract: An oriented multilayer film comprises:Type: ApplicationFiled: July 8, 1999Publication date: September 5, 2002Inventors: JOHN P. DELISIO, LYLE J. HARLEY, JAY K. KEUNG, ROBERT G. PEET
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Publication number: 20020102399Abstract: The application discloses a transparent, biaxially oriented polyester film having a base layer at least 80% by weight of which is composed of a thermoplastic polyester, and having at least one outer layer, wherein the outer layer is composed of a polymer or a mixture of polymers which comprises at least 40% by weight of ethylene 2,6-naphthalate units and up to 60% by weight of ethylene terephthalate units and/or units from aliphatic, cycloaliphatic, or aromatic diols and/or dicarboxylic acids, with the proviso that the base layer has a diethylene glycol content in the range from 0.9 to 3.0% by weight.Type: ApplicationFiled: March 24, 1999Publication date: August 1, 2002Inventors: HERBERT PEIFFER, CYNTHIA BENNETT, GOTTFRIED HILKERT
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Patent number: 6423401Abstract: The invention relates to a biaxially oriented, sealable polyester film with at least a base layer (B), with a sealable outer layer (A) and with another, nonsealable outer layer (C), where the sealable outer layer (A) has a minimum sealing temperature of not more than 110° C. and a seal seam strength of at least 1.3 N/15 mm of film width, and the topographies of the two outer layers (A) and (C) have particular characterizing features. The film of the invention is particularly suitable for use in flexible packaging and specifically in particular for use on high-speed packaging machinery.Type: GrantFiled: March 27, 2001Date of Patent: July 23, 2002Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Richard Lee Davis, Gottfried Hilkert
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Patent number: 6420019Abstract: The invention relates to a coextruded, transparent, biaxially oriented polyester film having at least three layers, with at least one base layer B, at least 80% by weight of which is composed of a thermoplastic polyester, where an outer layer has been applied to each surface of this base layer, and where at least one outer layer comprises particles, wherein the gloss of both surfaces of the film is above 170 the haze of the film is below 2.4% the planar orientation &Dgr;p of the film is below 0.162. the coefficient of friction (COF) is below 0.6. The invention further relates to the use of a film of this type, and also its production.Type: GrantFiled: June 26, 2001Date of Patent: July 16, 2002Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Gottfried Hilkert
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Publication number: 20020090498Abstract: The invention relates to a transparent, biaxially oriented polyester film with a base layer B, at least 80% by weight of which is composed of a thermoplastic polyester, and with at least one outer layer A. The outer layer A is composed of a copolymer or a mixture of polymers/copolymers which contains ethylene 2,6-naphthalate units in a range of from 90 to 98% by weight and up to 10% by weight of ethylene terephthalate units, and/or units derived from cycloaliphatic or aromatic diols and/or dicarboxylic acids. Its thickness is more than 0.7 &mgr;m and makes up less than 25% by weight of the total film and the Tg2 value of the polyester film is above the Tg2 value of the base layer, but below the Tg2 value of the polyester for the outer layer. The transparent film has low permeability to atmospheric oxygen and exhibits very good adhesion between the individual layers. It is particularly suitable for packaging purposes, specifically for packaging foods or other consumable items.Type: ApplicationFiled: July 20, 2001Publication date: July 11, 2002Inventors: Herbert Peiffer, Gottfried Hilkert, Richard Lee Davis
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Patent number: 6410124Abstract: A multi-layer film includes a base layer comprising a polyolefin and at least one additional layer comprising a metallocene-catalyzed syndiotactic polypropylene, wherein the base layer and the at least one additional layer comprising a metallocene-catalyzed syndiotactic polypropylene are not suitable for use as a heat sealable film. The multi-layer films of the present invention have improved metallizable surfaces and the metallized films exhibit excellent gas (e.g., oxygen and water vapor) barrier properties, as well as good pick off, optical properties (optical density, haze, and gloss), and coefficient of friction (COF).Type: GrantFiled: March 30, 1999Date of Patent: June 25, 2002Assignee: ExxonMobil Oil CorporationInventor: Robert G. Peet
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Publication number: 20020071945Abstract: The invention relates to a biaxially oriented polyester film having at least one matt side and composed of at least one base layer (B) made from a thermoplastic polyester and of, applied to this base layer (B), at least one matt outer layer (A) which comprises at least 70% by weight of thermoplastic polyester. The outer layer (A) has a characteristic matt surface and characteristic optical properties and has good suitability for use as a packaging film or for industrial application. The invention further relates to the use and to a process for its production.Type: ApplicationFiled: September 10, 2001Publication date: June 13, 2002Inventors: Herbert Peiffer, Stefan Bartsch, Martin Mueller-Roosen
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Publication number: 20020068159Abstract: The invention relates to a matt, biaxially oriented polyester film having at least one matt base layer (B) which comprises at least 70% by weight of thermoplastic polyester, and also a pigment system with narrow grain size distribution. The invention further relates to the use of the film and to a process for its production. The film of the invention has characteristic matt surfaces and has good suitability for use as a packaging film or for industrial applications.Type: ApplicationFiled: September 10, 2001Publication date: June 6, 2002Inventors: Herbert Peiffer, Guenther Crass, Gottfried Hilkert
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Publication number: 20020068158Abstract: The invention relates to a biaxially oriented polyester film having at least one matt side and composed of at least one base layer (B) and of, applied to this base layer, at least one matt outer layer (A) which comprises at least 70% by weight of thermoplastic polyester and also to a pigment system with narrow grain size distribution. The invention further relates to the use of the film and to a process for its production. The film of the invention with the outer layer (A) has a characteristic matt surface and characteristic optical properties and has good suitability for use as a packaging film or for industrial applications.Type: ApplicationFiled: September 10, 2001Publication date: June 6, 2002Inventors: Herbert Peiffer, Stefan Bartsch
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Publication number: 20020064646Abstract: A multilayer polymeric film comprises:Type: ApplicationFiled: May 27, 1999Publication date: May 30, 2002Inventors: GEORGE CRETEKOS, ROBERT A. MIGLIORINI
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Patent number: 6395147Abstract: The present invention relates to the improvement of metal bonding strength in polypropylene films through the addition of ethylene in a mini-random ethylene-propylene copolymer in an amount of no more than about 1 weight percent, more preferably no more than about 0.7 weight percent, and most preferably between about 0.3 weight percent and about 0.5 weight percent, or even amounts between about 0.05 weight percent and about 0.2 weight percent. The invention allows the improvement of metal bond strength in metallizable films. The invention encompasses both the resulting films with enhanced metal bond strength and the process for producing such films.Type: GrantFiled: September 22, 1999Date of Patent: May 28, 2002Assignee: Fina Technology, Inc.Inventors: William R. Wheat, Aiko Hanyu
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Patent number: 6379605Abstract: Disclosed is a process for producing a three layers co-extrusion biaxially oriented polypropylene (hereinafter as BOPP) synthetic paper and transparent film for in-mold label. More particularly, the invention relates to a process for producing a three layers biaxially oriented PP synthetic paper by means of three layers co-extrusion wherein three different PP resin compositions are separately extruded by one primary and two secondary extruders first, and then are co-flowed by a same T-die to form a three layers coating sheet.Type: GrantFiled: October 22, 1999Date of Patent: April 30, 2002Assignee: Nan Ya Plastics CorporationInventor: Allen Fong-Chin Lin
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Publication number: 20020041057Abstract: An embossed, cast polyolefin film or an embossed, oriented polyolefin film comprises: (a) a core layer comprising a propylene polymer; (b) an embossed outer layer on one side of the core layer, the embossed outer layer comprising an olefin polymer capable of being embossed; and (c) an additional outer layer on a side of the core layer opposite to the embossed outer layer, the additional outer layer comprising an olefin polymer. The embossed film can then be metallized to produce a shiny, metallic film having a prismatic or holographic appearance.Type: ApplicationFiled: December 5, 2001Publication date: April 11, 2002Inventors: Robert Andrew Migliorini, Christopher Nothnagle, Salvatore James Pellingra
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Patent number: 6368543Abstract: Disclosed is an improvement of a process for producing a three layers co-extrusion biaxially polypropylene(BOPP) synthetic paper of thickness 25˜250 &mgr;m which is menufactured by using three single screw extruders By means of an improvement of a process for producing a three layers co-extrusion biaxially polypropylene(hereinafter as BOPP) synthetic paper of thickness 25˜250 &mgr;m. More particularly, the invention relates to a process for producing a three layers BOPP synthetic paper by means of three layers co-extrusion wherein two different PP resin compositions are separately extruded by one primary single screw extruder with venting device and two secondary single screw extruders with venting device first, and then are co-flowed by a same T-die to form a three layers coating sheet, and through cooling, biaxial orientation, corona treatment and winding to form a three layers co-extrusion synthetic paper of thickness 25˜250 &mgr;m.Type: GrantFiled: September 13, 1999Date of Patent: April 9, 2002Assignee: Nan Ya Plastics CorporationInventor: Allen Fong-Chin Lin
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Publication number: 20020039646Abstract: A metalized or ceramic-coated biaxially oriented polyester film is disclosed, with a base layer B which comprises at least 80% by weight of thermoplastic polyester, and with at least one outer layer A. The outer layer A is composed of a copolymer or of a mixture of polymers/copolymers which contains from 90 to 98% by weight of ethylene 2,6-naphthalate units and up to 10% by weight of ethylene terephthalate units, and/or units derived from cycloaliphatic or aromatic diols and/or dicarboxylic acids. The thickness of the outer layer A is more than 0.7 &mgr;m and this makes up less than 25% by weight relative to the entire film. The Tg2 value of the polyester film is above the Tg2 value of the base layer, but below the Tg2 value of the outer layer. The film has low permeability to atmospheric oxygen and exhibits very good adhesion between the individual layers. It is particularly suitable for packaging purposes, specifically for packaging foods or other consumable items.Type: ApplicationFiled: August 6, 2001Publication date: April 4, 2002Inventors: Herbert Peiffer, Gottfried Hilkert, Richard Lee Davis
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Patent number: 6364988Abstract: Disclosed is a process for producing a 3-layer co-extruded biaxially polypropylene (hereinafter as BOPP) synthetic paper of thickness 25-250 &mgr;m. More particularly, the invention relates to a process for producing a 3-layer biaxially-oriented PP synthetic paper by means of 3-layer co-extrusion wherein two different PP resin compositions are separately extruded by one primary and two secondary extruders first, and then are co-flowed by a same T-die to form a three layers coating sheet, and through cooling, biaxial orientation, corona treatment and winding to form a 3-layer co-extrusion synthetic paper of thickness 25-250 &mgr;m.Type: GrantFiled: September 13, 1999Date of Patent: April 2, 2002Assignee: Nan Ya Plastics CorporationInventor: Allen Fong-Chin Lin
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Publication number: 20020037418Abstract: A transparent, biaxially oriented polyester film is disclosed, with a base layer B which comprises at least 80% by weight of thermoplastic polyester, and with at least one intermediate layer Z, and with at least one outer layer A. The outer layer A is composed of a polymer or of a mixture of polymers which contains at least 85% by weight of ethylene 2,6-naphthalate units and up to 15% by weight of ethylene terephthalate units, and/or up to 15% by weight of units derived from cycloaliphatic or aromatic diols and/or dicarboxylic acids, and the intermediate layer Z is composed of a mixture of polymers which contains at least 3% by weight of ethylene 2,6-naphthalate units and up to 97% by weight of ethylene terephthalate units, and/or up to 97% by weight of units derived from cycloaliphatic or aromatic diols and/or dicarboxylic acids. The Tg2 value of the polyester film is above the Tg2 value of the base layer B, but below the Tg2 value of the outer layer A.Type: ApplicationFiled: August 6, 2001Publication date: March 28, 2002Inventors: Herbert Peiffer, Gottfried Hilkert
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Publication number: 20020037386Abstract: A three-layer microwaveable, plastic wrap having a core layer between a cling layer and a release layer is disclosed, along with a method for making the plastic wrap. The cling layer comprises a base resin and an effective amount of a tackifier to provide sufficient cling to different surfaces such as, for example, glass, plastic, ceramic, stainless steel laminated cardboard, and aluminum. The release layer includes an effective amount of an anti-blocking agent to facilitate dispensing of the wrap from a dispensing roll.Type: ApplicationFiled: July 31, 2001Publication date: March 28, 2002Inventor: Douglas D. Bonke
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Patent number: 6355336Abstract: The present invention relates to a multi-layer packaging film comprising an intermediate layer having at least one outer layer on both surfaces of the intermediate layer, and having the thickness of not more than 40 &mgr;m, said outer layer comprising a polyolefin resin, said intermediate layer comprising a polytetramethylene terephthalate resin obtained by copolymerizing polytetramethylene oxide glycol having a number-average molecular weight of 300 to 5,000 and having an intrinsic viscosity of 0.7 to 2.0, a melting point of 200 to 228° C. and a crystallization temperature of not higher than 180° C., and the thickness of said intermediate layer being 20 to 80% of the thickness of the multi-layer film.Type: GrantFiled: December 10, 1999Date of Patent: March 12, 2002Assignee: Mitsubishi, Engineering-Plastics CorporationInventors: Nobukatsu Wakabayashi, Ken Honma
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Publication number: 20020015835Abstract: The application discloses a sealable biaxially oriented polyester film having a base layer B at least 80% by weight of which is composed of a thermoplastic polyester, and having two outer layers A and C, wherein the outer layer A is composed of a polymer or of a mixture of polymers which comprises at least 40% by weight of ethylene 2,6-naphthalate units and up to 60% by weight of ethylene terephthalate units and/or units from cycloaliphatic or aromatic diols and/or dicarboxylic acids, and the opposite outer layer C is sealable and has a sealing initialization temperature of from about 100 to 200° C. The film has low atmospheric oxygen transmission. It is particularly suitable for packaging applications, specifically for packaging foods and other consumable items.Type: ApplicationFiled: March 24, 1999Publication date: February 7, 2002Inventors: HERBERT PEIFFER, CYNTHIA BENNETT, GOTTFRIED HILKERT
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Patent number: 6340530Abstract: Book covers and a substantially transparent, coextruded matte, bilayer nylon film which is contact transparent to a paper stock to form a soft book cover having high scratch, abrasion and mar resistance, a soft feel and good moisture curl properties. A substantially transparent, coextruded film which has a first nylon layer attached adjacent to a second nylon layer, the first nylon layer has from about 20 weight percent to about 70 weight percent of a refractory filler based on the weight of the first nylon layer.Type: GrantFiled: April 28, 2000Date of Patent: January 22, 2002Assignee: Honeywell International Inc.Inventors: Simon J. Porter, Jeffrey D. Moulton, Lance R. Altizer
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Publication number: 20020006520Abstract: A biaxially oriented polyolefin film having more than one layer and made from a base layer and from at least one outer layer. The base layer include a fatty amide and the outer layer include at least 80% by weight of a linear olefin polymer. The film is suitable, for example, for producing a film laminate by melt extrusion of a polyethylene layer.Type: ApplicationFiled: May 21, 1999Publication date: January 17, 2002Inventors: WOLFGANG RASP, DETLEF KLAUS BUSCH
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Patent number: 6332940Abstract: This invention relates to a process for producing an invisible and writable biaxially oriented polypropylene (BOPP) raw processing film of thickness between 20 to 60 &mgr;m. More particularly, this invention relates to a process for producing a three-layers biaxially oriented PP synthetic raw processing film by means of three-layers co-extrusion, wherein two different PP resin compositions are separately extruded by one primary and two secondary extruders first, and then are co-flowed by a same T-die through cooling molding to form a three layers coating sheet, and through biaxial orientation, corona treatment and winding to form three layers co-extrusion synthetic film of thickness 20-60 &mgr;m. The three layers structure of said three layers co-extrusion synthetic film can be made in the form of invisible and writable layer/intermediate resin layer/backing adhesive resin layer, which can be used in industrial application and stationery application after winding finishing.Type: GrantFiled: September 13, 1999Date of Patent: December 25, 2001Assignee: Nan Ya Plastics CorporationInventor: Allen Fong-Chin Lin
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Patent number: 6322894Abstract: The present invention relates to a matte surface film comprising: (a) a base layer comprising high density polyethylene (HDPE); and (b) a matte surface layer comprising a blend of two or more incompatible polyolefins. In preferred embodiments, the matte surface layer comprises (i) a propylene homopolymer or propylene interpolymer and (ii) an ethylene homopolymer or ethylene interpolymer. The film possesses easy and improved cuttability and may be used for packaging and label applications.Type: GrantFiled: May 7, 1999Date of Patent: November 27, 2001Assignee: ExxonMobil Oil CorporationInventors: Lyle J. Harley, Pang-Chia Lu
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Patent number: 6316067Abstract: A packaged article, especially a respiring foodstuff such as cheese which generates or releases gas during storage, and a permeable multilayer biaxially oriented film suitable for allowing escape of such gas while minimizing transfer of oxygen across the film which has a thin layer of a blend of EVOH and nylon. In a preferred embodiment the low cost film having a high permeability to CO2 and low O2 permeability is used to package cheese.Type: GrantFiled: February 3, 1994Date of Patent: November 13, 2001Assignee: Curwood, Inc.Inventors: David Nicholas Edwards, Stephen James Vicik
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Patent number: 6312823Abstract: A compostable multilayer film includes a core layer having a first surface and a second surface, a first blocking reducing layer covering the first surface of the core layer, and a second blocking reducing layer covering the second surface of the core layer. The core layer comprises a lactic acid residue-containing polymer having a glass transition temperature (Tg) below 20° C. At least one of the first and second blocking reducing layers comprise a semicrystalline aliphatic polyester. The core layer may be peroxide modified polylactide polymer which exhibits bridging between polylactide polymer chains.Type: GrantFiled: September 29, 1998Date of Patent: November 6, 2001Assignee: Cargrill, IncorporatedInventors: Ali Zakareya El-Afandi, Patrick Richard Gruber, Jeffrey John Kolstad, James Lunt, Christopher M. Ryan, James Zakareya Nangeroni, Nancy Uzelac Buehler, Mark Hartmann, Jed Richard Randall, Andrea Lee Brosch
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Patent number: 6312825Abstract: A multi layer film having enhanced barrier properties with respect to oxygen and water vapor transmission as well as an excellent surface for film laminating, printing and coating processes is provided. The multi layer film includes a polyolefin core layer having a wax therein, a first surface layer including a polyolefin copolymer or terpolymer layer, and a second surface layer including a polar layer having ester functionality. Multi layer films according to the present invention are particularly useful as packaging films for food products, and are particularly well suited for subsequent laminating, printing or coating operations.Type: GrantFiled: September 21, 1998Date of Patent: November 6, 2001Assignee: ExxonMobil Oil CorporationInventors: Tien-Kuei Su, Shaw-Chang Chu, Jay K. Keung
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Patent number: 6299984Abstract: A highly oriented, heat-shrinkable, multi-layer film comprising a layer a) comprising a polyamide and an outer heat-sealing layer b) comprising a polyolefin, which film has been oriented at a stretching ratio ≧ about 3.0:1 in the machine direction and at a stretching ratio ≧ about 6.0:1 in the transverse direction, characterized in that the polyamide of layer a) is a crystalline or partially crystalline co-polyamide with a Tg≦100° C.Type: GrantFiled: September 7, 1999Date of Patent: October 9, 2001Assignee: Cryovac, Inc.Inventor: Roberto Forloni
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Patent number: 6291041Abstract: A multi-layer heat resistant film laminate with good optical properties, extended shelflife, and memory characteristics and its method of manufacture, the laminate having the generalized structure of (outside) A/B/C/D/C/B/E (inside), where A is an outer moisture barrier layer, B is an intermediate adhesive layer, C is a polyamide layer D is an oxygen barrier layer, and E is a sealant layer.Type: GrantFiled: May 10, 1999Date of Patent: September 18, 2001Assignee: Curwood, Inc.Inventors: Scott Howells, Gregory Robert Pockat
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Patent number: 6280833Abstract: The invention relates to a biaxially oriented polypropylene film which has very good optical properties and good processing performance and which, after it has been metallized or has been coated with oxidic materials, has a high oxygen barrier value, and whose structure has at least one base layer B and at least one layer A applied to this base layer, where this layer A has a specified number of elevations of specified height and specified diameter. The invention further relates to the use of the film and to a process for its production.Type: GrantFiled: July 30, 1999Date of Patent: August 28, 2001Assignee: Mitsubishi Polyester Film GmbHInventors: Herbert Peiffer, Gottfried Hilkert
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Patent number: 6268026Abstract: Multilayer laminates including films, sheets, preforms, containers and other articles having at least one wholly aromatic, amorphous, stretchable liquid crystalline polymer layer with at least one non-liquid crystalline thermoplastic polyester layer are provided as well as methods for producing and stretching the multilayer articles. The laminates are suitable for thermoforming and stretch blow molding applications and may be stretched to at least 100 percent elongation at temperatures below 200° C. and at high total draw ratios without fractures or tears. Containers suitable for food or beverage products may be produced from the laminates.Type: GrantFiled: October 20, 1997Date of Patent: July 31, 2001Assignee: Hoechst Celanese CorporationInventors: Randy D. Jester, Arnold E. Wolf, Robert M. Kimmel, Dominick Cangiano, John A. Penoyer
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Publication number: 20010008694Abstract: The present invention provides highly oriented multilayer films. They are produced by coextruding or laminating films having at least one layer of a fluoropolymer, at least one layer of a polyolefin homopolymer or copolymer and an intermediate adhesive layer of a polyolefin having at least one functional moiety of an unsaturated carboxylic acid or anhydride thereof. With this structure the polyolefin layer allows the fluoropolymer layer to be stretched up to ten times its original length. Such a high orientation ratio for the fluoropolymer film increases the mechanical strength, toughness, and water vapor barrier properties of the film while using a thinner gauge fluoropolymer film. Coextrusion processing can be done at higher temperatures, i.e. in the range of from at about 280° C. to about 400° C. These temperatures allow films to be produced in the absence of polymer degradation and film melt fracture.Type: ApplicationFiled: January 21, 2001Publication date: July 19, 2001Applicant: AlliedSignal Inc.Inventors: Mingliang Lawrence Tsai, Yash Pal Khanna, Joseph Edgar Mackey
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Publication number: 20010008687Abstract: Conformable multilayer films having alternating layers of a stiff polymeric material and a flexible polymeric material are described.Type: ApplicationFiled: February 7, 2001Publication date: July 19, 2001Applicant: 3M Innovative Properties CompanyInventors: Richard A. Kollaja, David D. Nguyen, Ronald S. Steelman, Buren R. Ree, Steven D. Solomonson, Philip D. Radovanovic
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Publication number: 20010003021Abstract: A clear, multilayer polymeric film that is desirable for thermoforming applications. The film in its various embodiments include two inner layers of nylon and/or a core layer of ethylene vinyl alcohol or ethylene vinyl alcohol copolymer sandwiched between the two inner nylon layers. The film also has an outer layer of a heat sealable polymer and may also have an outer layer of nylon. The film is coextruded, blown into a tubular shape, oriented, and cooled by the method of tubular water quenching. The film has various improved physical properties over the prior art, including properties of “memory”, clarity, gloss and low haze.Type: ApplicationFiled: October 4, 1999Publication date: June 7, 2001Applicant: MARY E. SHEPARD, et alInventors: MARY E. SHEPARD, SCOTT W. MIDDLETON, ROBERT J. BLEMBERG, JERRY F. JESSE
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Patent number: 6238607Abstract: A method of producing highly oriented multilayer films comprising laminating films having at least one layer of a fluoropolymer, at least one layer of a polyolefin homopolymer or copolymer and an intermediate adhesive layer of a polyolefin having at least one functional moiety of an unsaturated carboxylic acid or anhydride thereof. With this structure the polyolefin layer allows the fluoropolymer layer to be stretched up to ten times its original length. Such a high orientation ratio for the fluoropolymer film increases the mechanical strength, toughness, and water vapor barrier properties of the film while using a thinner gauge fluoropolymer film.Type: GrantFiled: December 18, 1998Date of Patent: May 29, 2001Assignee: AlliedSignal Inc.Inventors: Mingliang Lawrence Tsai, Yash Pal Khanna, Joseph Edgar Mackey
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Patent number: 6187236Abstract: Process for the preparation of a polyethylene multilayer film starting from linear low density polyethylene (LLDPE) by cast-extrusion, wherein the multilayer material coming out from a spreading head is collected on a first roller cooled with water maintained between 10° and 25° C. and the film coming out from the first cooling roller is sent to a second roller cooled with water maintained at a temperature lower than that of the first roller and the second roller has a peripheral velocity or speed of rotation 10-40% higher than that of the first roller. Multilayer film having a yield point and an ultimate elongation comprised within certain limits.Type: GrantFiled: November 27, 1996Date of Patent: February 13, 2001Assignee: Pentacast S.r.l.Inventor: Giuseppe Brambilla
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Patent number: 6174470Abstract: A method for forming an automotive instrument panel having a concealed door comprising a series of steps. A plastic parison is extruded to form the substrate layer of the instrument panel. The parison has first and second walls. The parison is placed within a mold and the first wall is contacted with the second wall to form a hinge. The area of contact forms a bond between the first and second walls. A different portion of the first and second walls are contacted to form an opening path. The opening path intersects the hinge. The opening path usually has a thickness much less than the thickness of the first and second walls to form an easily fracturable area. The door swings on the hinge to open. A elongated section of material on the second wall, enables the second wall to wrap along the hinge when the door is opened.Type: GrantFiled: December 4, 1998Date of Patent: January 16, 2001Assignee: Ford Global Technologies, Inc.Inventors: Bradley Richard Plymale, Christopher Alan Myers, Gerald Arthur Heath, Jeffrey Hampton Helms, Lisandro Trevino, Sorin Stancu
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Patent number: 6168826Abstract: Methods of preparing biaxially oriented polyethylene films with improved optics and sealability properties are provided. The methods include stretching in the machine direction a multi-layer base sheet having a core layer with a first and a second side, at least one skin layer and outer surfaces; then coating at least one of the outer surfaces with a resin selected from the group consisting of low density polyethylene, very low density polyethylene, linear low density polyethylene and blends thereof, and finally, stretching the base sheet in a direction transverse to the machine direction.Type: GrantFiled: December 23, 1998Date of Patent: January 2, 2001Assignee: Mobil Oil CorporationInventors: Tien-Kuei Su, Robert V. Poirer