Addition Of Fugitive Material Patents (Class 419/36)
  • Patent number: 5399438
    Abstract: Disclosed is a stainless steel member with a high corrosion resistance suitable for a structural member used in highly corrosive environments, such as an edge seal plate of a molten carbonate fuel cell. This stainless steel member includes a base material consisting of stainless steel containing chromium, and a corrosion-protective layer formed on the surface of the base material. In this corrosion-protective layer, a granular heterophase containing chromium is precipitated in an ordered alloy consisting of aluminum and the constituent elements of the base material.
    Type: Grant
    Filed: September 14, 1993
    Date of Patent: March 21, 1995
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Hiroshi Tateishi, Kiyoshi Imai, Hideyuki Ohzu, Kazuaki Nakagawa, Yoshihiro Akasaka
  • Patent number: 5397531
    Abstract: Metal injection-molded green bodies (2) are formed from a granulated feedstock comprising metal powder and a binder comprising:a) 15-25 volume % paraffin waxb) 20-30 volume % microcrystalline waxc) 45-60 volume % polyethylene.The paraffin wax has two melting regions around 45.degree. C. and 63.degree. C. and the microcrystalline wax exhibits four melting regions in the range 62.degree. C. and 144.degree. C. By raising the temperature of the oven in a controlled manner, first the paraffin wax and then the microcrystalline wax melts and is vapourised and entrained in a flow of carrier gas which flows over supporting trays (5), as indicated by the horizontal arrows (a). The requirement for wicking powder is eliminated by the staged removal of the wax and the polyethylene can subsequently be removed at a higher temperature by thermal depolymerisation in the same apparatus.
    Type: Grant
    Filed: June 2, 1993
    Date of Patent: March 14, 1995
    Assignee: Advanced Materials Technologies Pte Limited
    Inventors: D. Dunstan H. Peiris, Jian G. Zhang
  • Patent number: 5393486
    Abstract: A method of making an orthodontic appliance such as a bracket includes the step of forming a preform of molding material while a portion of the molding material is in contact with a textured portion of a web. The web is subsequently degraded by a thermal or solvent degrading process to leave a witness impression on the underside of the preform. The web optionally serves as a conveyor to move the preform from one processing area to another, and optionally has the appearance of a woven material such that the resulting appliance resembles a mesh base appliance having undercut regions.
    Type: Grant
    Filed: December 9, 1993
    Date of Patent: February 28, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Robert P. Eckert, Evangelos G. Georgakis
  • Patent number: 5384088
    Abstract: Wire, bulk, film, etc. of a superconductive material is manufactured from a powdery precursor. The superconductive material has a superconductive crystal of 1223 phase and/or 1234 phase as a main component, and the powdery precursor comprises at least 1212 phase as a main component.
    Type: Grant
    Filed: October 23, 1992
    Date of Patent: January 24, 1995
    Assignees: Hitachi Cable, Ltd., Hitachi Ltd.
    Inventors: Junichi Sato, Masahiro Seido, Akira Nomoto, Tomoichi Kamo, Katsuzo Aihara
  • Patent number: 5380476
    Abstract: A debinding method for use in a process for producing a sintered object, by effecting a debinding pre-treatment by heating the injection-molded object in an atmosphere of reduced pressure at a temperature at which the vapor pressure of the component of the organic binder having the highest vapor pressure does not exceed the pressure of the atmosphere, thereby removing the organic binder in the amount of at least about 18 wt %; and effecting a further debinding heat treatment in which the injection-molded object is heated to and maintained at a temperature higher than the temperature in the debinding pre-treatment.
    Type: Grant
    Filed: September 16, 1991
    Date of Patent: January 10, 1995
    Assignee: Kawasaki Steel Corporation
    Inventors: Masakazu Matsushita, Yoshisato Kiyota, Hiroshi Ohtsubo, Junichi Ohta
  • Patent number: 5380179
    Abstract: The improved binder system for use in the injection molding of sinterable powders such as metal powders, ceramic powders and cermet powders comprises a (co)polymer that has a molecular weight in excess of 2000 and which contains at least one epoxy group in the molecule. Preferably, the binder system comprises said (co)polymer, a (co)polymer other than said (co)polymer, and an organic compound having a molecular weight up to 2000. Using a binder system comprising (a) 3-80 wt % of a (co)polymer that has a molecular weight in excess of 2000 and which has at least one epoxy group in the molecule, (b) up to 70 wt % of a (co)polymer other than component (a), and (c) 20-80 wt % of an organic compound having a molecular weight of not more than 2000, there is provided a composition for the injection molding of sinterable powders. The compound has excellent moldability and strength properties.
    Type: Grant
    Filed: March 16, 1993
    Date of Patent: January 10, 1995
    Assignee: Kawasaki Steel Corporation
    Inventors: Kimihiro Nishimura, Kenji Yoshino
  • Patent number: 5376328
    Abstract: There is disclosed a precious metal article which is formed of a solid-phase sintered product of a precious metal powder. For manufacturing the precious metal article, a moldable mixture which contains a precious metal powder and a binder removable by sintering is shaped into a prescribed molded object, and the molded object is then subjected to sintering. The moldable mixture is produced by preparing a precious metal powder, preparing a jellylike cellulose binder by blending a cellulose with water and leaving for a prescribed period of time, and blending the precious metal powder and the jellylike cellulose binder together. The most preferable moldable mixture contains 50 to 90% by weight of precious metal powder, 0.8 to 8% by weight of water-soluble cellulose binder, 0.08 to 3% by weight of a surface-active agent. 0.1 to 3% by weight of oil, balance water and unavoidable impurities.
    Type: Grant
    Filed: April 22, 1994
    Date of Patent: December 27, 1994
    Assignee: Mitsubishi Materials Corporation
    Inventors: Koji Hoshino, Masaki Morikawa, Tohru Kohno, Koshiro Ueda, Masaki Miyakawa
  • Patent number: 5374391
    Abstract: A method of producing a molded ceramic article comprises the first step mixing powdery raw materials and a liquid additive, thereby obtaining a mixed raw material, the second step press-molding the mixed raw material obtained in the first step in a hydrostatically applied condition of pressure, thereby removing an excess of the liquid additive to obtain a preform, and the third step calcining the preform obtained in the second step to obtain a molded ceramic article. The molded ceramic article comprises, as a principal component, copper and, as essential components, Cr and Ni within composition ranges of 0.1.ltoreq. Cr< 2 wt. % and 0.1.ltoreq. Ni< 10 wt. % and further at least one additive component selected from the group consisting of the following composition ratios: the following composition ratios: O<Fe< 5 wt. %, O.ltoreq.Co< 5 wt. %, O.ltoreq.Al< 10 wt. %, O.ltoreq.Ti< 20 wt. %, O.ltoreq.Mo< 3 wt. %, O.ltoreq.Si< 3 wt. %, O.ltoreq.V< 3 wt. %, O.ltoreq.Mg< 1 wt. % and O.
    Type: Grant
    Filed: June 9, 1993
    Date of Patent: December 20, 1994
    Assignee: Honda Giken Kogyo Kabushiki Kaisha
    Inventors: Mitsuo Kuwabara, Kiyoshi Ikegami, Teruaki Yoshida, Koji Takahashi, Tamotsu Harada, Takeshi Komiyama, Fumio Hirai, Masamichi Hayashi
  • Patent number: 5370837
    Abstract: A high temperature heat-treating jig characterized by forming a tungsten layer or a tungsten alloy layer on the surface of a heat-resistant base to avoid discoloration and color shading during the heat treatment at a high temperature.
    Type: Grant
    Filed: January 12, 1994
    Date of Patent: December 6, 1994
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Masanori Kibata, Noboru Kitamori, Shigeki Kajima, Kazunori Yokosu, Mituo Kawai, Hideo Ishihara, Noriaki Yagi
  • Patent number: 5366688
    Abstract: A heat sink composed of metal particles dispersed in a binder or a sintered structure in which the binder is removed; and the method of forming a heat sink by molding the heat sink from a thermoplastic or epoxy material which has been filled with metal particles.
    Type: Grant
    Filed: March 10, 1994
    Date of Patent: November 22, 1994
    Assignee: Iowa State University Research Foundation, Inc.
    Inventors: Robert L. Terpstra, Barbara K. Lograsso, Iver E. Anderson, Jeffrey A. Moore
  • Patent number: 5366679
    Abstract: A process for thermal debinding and sintering of a workpiece made by molding a mixture of a binder and a powder, the process entailing the steps of injection molding a workpiece entailing at least 30% vol. of binder, the binder containing from about 70% to about 90% wt. of at least one wax and from about 10% to 30% wt. of high molecular weight polymer, introducing the molded workpiece in an enclosure at ambient temperature, injecting an atmosphere of at least 95% vol. hydrogen and less than 5% vol. water vapor, heating the enclosure and/or the workpiece until reaching a temperature between about 150.degree. C. to about 200.degree. C., maintaining the temperature during a period of time sufficient to substantially decompose all the waxes in the binder, then heating again the enclosure and/or the workpiece to reach a temperature of about 700.degree. C.
    Type: Grant
    Filed: May 27, 1992
    Date of Patent: November 22, 1994
    Assignee: L'Air Liquide, Societe Anonyme pour l'Etude et l'Exploitation des Procedes Georges Claude
    Inventor: Eric Streicher
  • Patent number: 5362332
    Abstract: A magnet base, having a flux density equal to that of an Fe-50%Co alloy and an input current response equal to that of an Fe--Si alloy, is used as a component of the magnetic circuit employed for a printing head of a wire dot printer, the magnetic circuit further having by-pass and armature components. The material of the magnetic base is an Fe-50% Co alloy and the base has an end face which is perpendicular to the magnetic circuit of the printing head. A layer, of a material selected from the class consisting of metals and metal alloys which function to increase the specific resistance of a magnet bases of an Fe-50% Co alloy, is formed on the end face of the magnet base and reduces eddy current loss therein, particularly at high frequency energization of the magnetic circuit, further serving to increase the input current response.
    Type: Grant
    Filed: October 7, 1993
    Date of Patent: November 8, 1994
    Assignee: Fujitsu Limited
    Inventors: Yutaka Shimizu, Yoshihiko Seyama
  • Patent number: 5354536
    Abstract: A silicon carbide material is made following a procedure including hot pressing to provide a finished product having a microstructure with an optimal grain size of less than 7 micrometers. The material exhibits a dominant failure mode of intergranular fracture requiring significant energy for crack propagation. The method of manufacturing is cost-effective by allowing the use of "dirty" raw materials since the process causes impurities to segregate at multi-grain boundary junctions to form isolated pockets of impurities which do not affect the structural integrity of the material. End uses include use as protective projectile-resistant armor.
    Type: Grant
    Filed: September 3, 1993
    Date of Patent: October 11, 1994
    Assignee: Cercom Inc.
    Inventor: Andre Ezis
  • Patent number: 5350558
    Abstract: There is disclosed a process for preparing a resin composition for powder molding, comprising 50 to 97 wt % of a metal or alloy powder and 50 to 3 wt % of a thermoplastic resin having heat resistance and crystallinity, which process comprises dissolving the thermoplastic resin having heat resistance crystallinity in a solvent and at the same time, dispersing therein at least one metal or alloy powder selected from iron, brass, nickel silver, stainless steel and aluminum, having an average particle diameter of not more than 500 .mu.m to thereby prepare a mixture. In addition, there is disclosed a process for producing a powder molded product which comprises cold compressing molding the above resin composition and then heating the molding at a temperature not less than the melting point of the thermoplastic resin. This powder molded product has excellent dimensional stability against heat, chemical resistance, and mechanical strength.
    Type: Grant
    Filed: August 4, 1993
    Date of Patent: September 27, 1994
    Assignee: Idemitsu Kosan Co., Ltd.
    Inventors: Hiroshi Kawato, Tatsuya Tomioka
  • Patent number: 5342563
    Abstract: The invention relates to (1) a method of preparing sintered shapes, comprising the steps of forming a green body from a mixture comprising (A) a major amount of at least one inorganic powder with (B) at least one reaction product of a alkanolamine with a hydrocarbyl-substituted carboxylic acylating agent provided that when the hydrocarbyl group of the acylating agent contains less than 40 carbon atoms then the carboxylic acylating agent is a polycarboxylic acylating agent; and (2) sintering the body. Sintered shapes made from the methods of the present invention have relatively high fired densities and small uniform grain sizes; and low porosity. The reaction products of the present invention help disperse the inorganic powder. These reaction products also improve deagglomeration of the inorganic powder and help prevent reagglomeration of the powder.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: August 30, 1994
    Assignee: The Lubrizol Corporation
    Inventors: Robert E. Quinn, W. Miachel Burk
  • Patent number: 5342573
    Abstract: A method of producing a tungsten heavy alloy product according to a powder metallurgical procedure utilizing the injection molding technique which enables production of tungsten heavy alloy products having high dimensional accuracy and complex configuration and yet having high physical strength and toughness in high productivity and at low cost. A powder mixture of tungsten powder and nickel powder, iron powder or copper powder is mixed with an organic binder and they are kneaded together. The kneaded mixture is injection molded into a predetermined shape, and thereafter the binder is removed from the molded product. Subsequently, the molded product is sintered in a temperature range of from the melting point of the bond phase of nickel, iron or copper to +50.degree. C. relative to the melting point.
    Type: Grant
    Filed: August 20, 1992
    Date of Patent: August 30, 1994
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventors: Yoshinari Amano, Masahiro Omati, Junzo Matsumura
  • Patent number: 5340532
    Abstract: A method for manufacturing a sintered body by a) forming a slurry comprising a powder mixture, a dispersant providing steric stabilization for the powders and an organic solvent with a possible addition of one or more soluble polymers; b) transferring the slurry into a mold; and c) changing the temperature sufficient to cause gelation of the sterically stabilized suspension to form a green body. The method also includes d) removing the green body from the mold; e) transferring the green body to a chamber where the gelation temperature can be maintained and the pressure decreased to facilitate removal of the solvent to form a dried body; f) heating the body for a time sufficient to substantially remove the dispersant from the body and; g) sintering the body. The sintered body can be an insert for metal cutting tools.
    Type: Grant
    Filed: April 23, 1993
    Date of Patent: August 23, 1994
    Assignee: Sandvik AB
    Inventor: Lennart Bergstrom
  • Patent number: 5338506
    Abstract: A process for making a non magnetic Ni-WC cemented carbide composition and articles made from the same. The process comprises:(a) dewaxing a green Ni-WC cemented carbide substrate in the presence of hydrogen gas at a pressure less than about 1000 torr and at a sufficient flow rate and a sufficient time to affect the saturation magnetization and magnetic permeability of the Ni-WC cemented carbide substrate;(b) pumping out the hydrogen gas and introducing argon at a pressure in the range of about 1 torr to 1000 torr;(c) increasing the temperature up to the sintering temperature to facilitate sintering of the Ni-WC cemented carbide substrate; and;(d) cooling the furnace to room temperature.The articles made according to this invention are useful as wear parts for electronic instruments and as punches form aluminum beverage cans.
    Type: Grant
    Filed: December 21, 1992
    Date of Patent: August 16, 1994
    Assignee: Valenite Inc.
    Inventors: John W. Friederichs, Prakash K. Mirchandani, Paul J. Krudy
  • Patent number: 5336465
    Abstract: A slurry compound prepared by a sintering powdery material and a binder is press-molded to obtain a contour for the final product applicable to a bone-implant such as hip prosthesis. The molded body is given a programmed movement of rotation and/or swinging to impart a centrifugal force to the sintering particles which direct toward the inner wall of the mold cavity. The final product obtained after sintering has a hollow interior having no communication to the outside. Imparting conditions of rotating/swinging movement may be changed or programmed in order to achieve a desired structure or constitution of the final product. By way of example, larger particles concentrate near the inner wall of the mold to provide a rough, porous surface of the body, whereas it has a dense core consisting mainly of sintered fine particles. A hip prosthesis having a ceramic-rich femoral head and a metal-rich stem may also be produced by so programming the movement imparting conditions.
    Type: Grant
    Filed: December 3, 1992
    Date of Patent: August 9, 1994
    Assignees: Janome Sewing Machine Co., Ltd., Terumo Corporation
    Inventors: Noboru Matsunaga, Kazuyoshi Azeyanagi, Ichirou Sogaishi, Takeo Katakura, Yoshihisa Ueda, Takaaki Ohsawa
  • Patent number: 5332543
    Abstract: The disclosure relates to a binder, and the method of formulating the said binder, which is suitable for shaping parts from metallic and/or ceramic particles by injection molding. The binder comprises materials that are mainly thermoplastics, each of which having a percentage that is determined by its thermogravimetric analysis (TGA) profile and a weight loss versus temperature profile that is designed for the binder to allow highest binder removal rate from a green body by progressive heating. The removal of this binder from the green body is performed within a much shorter period of time than those published in the prior art. An example binder comprises 40-70% HDPE, 18-30% Paraffin wax, 10-25% microcrystalline wax and 2-5% stearic acid. Another binder comprises 35-65% PP, 23-35% paraffin wax, 10-25% microcrystaline wax and 2-5% stearic acid.
    Type: Grant
    Filed: August 26, 1992
    Date of Patent: July 26, 1994
    Assignee: Advanced Materials Technologies Pte Ltd
    Inventors: Jian G. Zhang, Dunstan H. Peiris, Jun W. Zhao, Sow W. Loh
  • Patent number: 5332537
    Abstract: An improved binder is mixed with powder to form feedstock for molding. The binder includes a first component which is soluble in water and a second component which is insoluble in water. The two binder components are miscible with each other in a liquid state. The two binder components form a uniform heterogeneous mixture when mixed in a liquid state. The binder is mixed with a suitable powder to form the feedstock. The feedstock is molded to form a compact. Polymer units of the binder are cross linked after the compact has been formed. The cross linking of the polymer units of a component of the binder is accomplished by exposing the compact to ultraviolet radiation or by the use of a catalyst. The compact is partially debound by exposing the compact to water, that is, to a water based solvent. Thereafter, the compact is further debound to remove the component which is insoluble in water. The powder is then sintered to form an article.
    Type: Grant
    Filed: December 17, 1992
    Date of Patent: July 26, 1994
    Assignee: PCC Airfoils, Inc.
    Inventors: Karl F. Hens, Donald M. Kupp, Ricky A. Alexander, Karl-Heinz Schofalvi
  • Patent number: 5330700
    Abstract: A porous electrode for pacemakers is comprised of a plurality of platinum globules sintered together to form a porous mass of semi-hemispherical shape at the end of a platinum electrode stem. The globules, which are themselves made by sintering together spherically-shaped particles of approximately one micron diameter, provide the globules with an irregular outer surface of high total surface area. The globules have diameters within a critical range of 40-200 microns. The large total surface area of the globules improves the sensing function of an electrode configuration of given size and surface area, while the globule diameters of 40-200 microns have been found to beneficially accommodate tissue ingrowth within the electrode. In a preferred method of making the electrode, the platinum globules, which are formed by sintering together platinum particles of much smaller size, are mixed with organic solvent and organic binder to form a paste.
    Type: Grant
    Filed: September 18, 1991
    Date of Patent: July 19, 1994
    Assignee: Siemens Pacesetter, Inc.
    Inventors: Thomas M. Soukup, Paul E. Kreyenhagen
  • Patent number: 5328657
    Abstract: The present method relates to molding metal particles by forming a flowable mixture. The metal particles are mixed with a polyorganic acid which chemically reacts with the metal particles. The flowable mixture is transferred to a mold before the chemical reaction between the metal particles and the polyorganic acid proceeds so far as to substantially increase the viscosity of the flowable mixture. A green preform is created by applying pressure to the mixture in a mold. The green preform is heated to a first temperature to vaporize substantially all of the non-organic components of the reacted polyorganic acid from the preform. The preform is then heated to a second temperature greater than the first temperature to sinter the metal particles.
    Type: Grant
    Filed: February 26, 1992
    Date of Patent: July 12, 1994
    Assignee: Drexel University
    Inventors: Ihab L. Kamel, Alan Lawley, Myung-Ho Kim
  • Patent number: 5314658
    Abstract: Tungsten and molybdenum powders are advantageously conditioned for metal injection molding by fluid energy milling the powder prior to batching. A preferred method of conditioning, jet milling, has been found to beneficially effect the particle characteristics to render the metal powder more suitable for injection molding.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: May 24, 1994
    Assignee: AMAX, Inc.
    Inventors: David N. Meendering, Deepak Malhotra, Linda K. Baltich
  • Patent number: 5312580
    Abstract: Porous metal components for high temperature fuel cells which are made by integrating the heretofore employed, separate tape casting and pack cementation processes. Particles of a base metal and a master alloy are suspended in a liquid medium in which a binding agent and a halide activator are dispersed. The suspension is cast into the shape wanted in the component, typically by tape casting; and the cast structure is heated to remove the liquid medium, leaving a flexible, green cast structure commonly referred to as a tape. The green tape is so heated as to: (a) burn out the binder in the tape; (b) form an alloy of the base metal and an alloying metal in the master alloy; and (c) sinter the alloy particles into a porous, coherent metal structure.
    Type: Grant
    Filed: May 12, 1992
    Date of Patent: May 17, 1994
    Inventors: Diane S. Erickson, Estela T. Ong
  • Patent number: 5308556
    Abstract: A method of forming an extrusion die fabricated from sinterable ceramic or metal powders, for use in forming honeycomb monolith structures including machining of the die in the green state or after partial densification. Alternatively, all or part of the machining can be performed after full densification or sintering.
    Type: Grant
    Filed: February 23, 1993
    Date of Patent: May 3, 1994
    Assignee: Corning Incorporated
    Inventor: Rodney D. Bagley
  • Patent number: 5308576
    Abstract: A method for making metal injection molded medical devices is disclosed. The method comprises melt blending, inject ion molding, and sintering a granulated hardenable metal feedstock.
    Type: Grant
    Filed: October 18, 1991
    Date of Patent: May 3, 1994
    Assignee: United States Surgical Corporation
    Inventors: David T. Green, Henry Bolanos
  • Patent number: 5284615
    Abstract: The present invention presents a method of processing ferrous powder materials to produce small component parts exhibiting excellent soft magnetic properties, in particular, residual magnetic flux density. The processing steps involve, in part, mixing with a binder, dewaxing or presintering at a temperature higher than in the conventional dewaxing process, followed by final sintering and a further conversion sintering, at a temperature lower than in the conventional sintering process, to produce parts having density values of over 96% theoretical density and excellent soft magnetic properties. The invented method is suitable for producing small component parts having sufficient strength and excellent soft magnetic properties to make them suitable for miniaturized electrical and electronic equipment.
    Type: Grant
    Filed: July 15, 1992
    Date of Patent: February 8, 1994
    Assignee: Mitsubishi Materials Corporation
    Inventors: Koshiro Ueda, Mutsumi Moribayashi, Tohru Kohno
  • Patent number: 5283031
    Abstract: A process for producing a precision metal part of a sintered body by powder molding comprises using a metal powder of which the oxygen content and the hydrogen reduction loss are controlled to 0.5-6 wt. % and 1-7 wt. %, respectively. The sintered body has a high density near the theoretical density and is excellent in dimensional accuracy. The molding is facilitated, and the process is simple.
    Type: Grant
    Filed: July 23, 1991
    Date of Patent: February 1, 1994
    Assignee: Citizen Watch Co., Ltd.
    Inventors: Naoto Ogasawara, Kenji Kurimura, Ken-ichi Yoshioka, Shigeru Saito, Takao Kasai, Masami Hoshi, Seiichi Nakamura
  • Patent number: 5279785
    Abstract: A sintered or bonded permanent magnet formed from a material consisting mainly of iron, particularly a Nd-Fe-B alloy, and having a high corrosion resistance has a surface coated with a resin obtained by the polycondensation of tannic acid, phenols and aldehydes. A bonded magnet is also made from a powder of any such material composed of particles coated with any such resin.
    Type: Grant
    Filed: July 30, 1992
    Date of Patent: January 18, 1994
    Assignee: Kanegafuchi Kagaku Kogyo Kabushiki Kaisha
    Inventors: Fumihito Mohri, Takuji Nomura, Shougo Miki
  • Patent number: 5273708
    Abstract: In making a dual alloy gas turbine rotor, a plurality of superalloy components are formed to include an airfoil having a directionally solidified columnar grain structure or a single crystal grain structure. A boron-bearing melting point depressant material is applied to the inner surface and a side surface of the components. The components are arranged side-by-side in an annular array with the first side surface of one component juxtaposed to the second side surface of an adjacent component and with the inner surfaces defining a spray-receiving surface. The airfoils extend in a radial axis or direction of the array while the spray-receiving surface extends in a circumferential direction of the article. A sealing member is positioned adjacent an axial end of the array of the components to close off that end and form a spray-receiving cavity. Boron-bearing melting point depressant material is provided between the sealing member and the end of the array.
    Type: Grant
    Filed: June 23, 1992
    Date of Patent: December 28, 1993
    Assignee: Howmet Corporation
    Inventor: William R. Freeman
  • Patent number: 5271891
    Abstract: A polymeric coating material is provided for coating powdered materials and, more particularly, for coating powdered metals formed into parts and sintered, such as to form magnetic cores. The thermoplastic material is polyphenylene oxide which, when properly applied to metal particles to form a magnetic core, is characterized by being sufficiently volatile so as to prevent the formation of contaminants or voids within the sintered article which would be detrimental to the physical properties of the sintered article. Moreover, polyphenylene oxide provides sufficient lubrication and adhesion between adjacent metal particles during an initial compaction process so as to sustain the desired shape of the molded article and maximize metal particle density without the use of additional lubricants, thereby preventing the formation of additional contaminants and/or voids within the resultant sintered article from these lubricants.
    Type: Grant
    Filed: July 20, 1992
    Date of Patent: December 21, 1993
    Assignee: General Motors Corporation
    Inventors: David E. Gay, Robert W. Ward
  • Patent number: 5268233
    Abstract: The invention relates to a method of preparing sintered shapes, comprising the steps of forming a green body from a mixture comprising (A) a major amount of at least one inorganic powder with (B) at least one reaction product of an amine other than an alkanolamine with a hydrocarbyl-substituted carboxylic acylating agent or alkylalkyleneglycolacetic acylating agent; provided the reaction product is other than an alkylene oxide treated fatty monocarboxylic amide and provided that when the hydrocarbyl-substituted carboxylic acylating agent is a nonaromatic acylating agent, then the hydrocarbyl group is other than hydrocarbyl groups having an average of about 55 to about 110 carbon atoms; and sintering the body. Sintered shapes made from the methods of the present invention have relatively high fired densities and small uniform grain sizes; and low porosity. The reaction products of the present invention help disperse the inorganic powder.
    Type: Grant
    Filed: November 22, 1991
    Date of Patent: December 7, 1993
    Assignee: The Lubrizol Corporation
    Inventors: Fred E. Heller, William Higgins, Robert E. Quinn
  • Patent number: 5262122
    Abstract: The disclosure relates to a method of binder removal from a green body before sintering or the like wherein the green body is initially heated to a temperature above the melting or flow point of the binder to liquify the binder and, at the elevated temperature, a small portion of the green body is brought into intimate contact with a non-supporting porous body of lower capillarity potential for the liquid binder. The liquid is drawn from all parts of the green body to the region of contact between the porous body and the green body and enters the body of lower capillarity potential preferentially, removing liquid from the green body through the surface of the green body only at said region of contact. The draining is continued with or without further increase in temperature until the green body is opened or becomes permeable.
    Type: Grant
    Filed: December 10, 1991
    Date of Patent: November 16, 1993
    Assignee: Witec Cayman Patents, Ltd.
    Inventor: Raymond E. Wiech, Jr.
  • Patent number: 5258155
    Abstract: Provided is an injection-molding method for forming into given finished parts by injection-molding raw materials of a metal or ceramic powder feed, in which steps of coating a release agent to the mold, degreasing and freeze solidification are dispensed with. In this method, a metal or ceramic powder feed is kneaded with an agar sol comprising water, which may have or have not been treated magnetically, agar powders having a gel strength of 2000 g/cm.sup.2 at an least 2% concentration and sodium borate to form a clay form of sol-state plastic material, and this material is then put in a heat-retaining hopper of injection-molding equipment in which it is injection-molded. Alternatively, this clay form of plastic material is cooled for gelation and pelletization (to obtain finely granulated gels). The pellets are put in a hopper of injection-molding equipment in which it is formed while heated and melted.
    Type: Grant
    Filed: May 14, 1992
    Date of Patent: November 2, 1993
    Assignee: Shimizu Shokuhin Kaisha, Ltd.
    Inventors: Masakatsu Sekido, Hironori Nakayama, Michio Nukaya, Yoshihisa Noro
  • Patent number: 5250254
    Abstract: A compound for producing sintered parts in an injection molding process and the molding process used to form the parts. The compound contains materials that allow the parts to be formed at lower temperatures and higher production rates when compared to more conventional processes.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: October 5, 1993
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Masakazu Achikita, Akihito Ohtsuka
  • Patent number: 5242654
    Abstract: A process for producing strip products which comprises forming an aqueous slurry of a suspension of metallic particles in a film forming cellulose derivative, depositing a quantity of the slurry onto a support surface, drying the slurry to form a self supporting flat product, removing the dried product from the support surface and roll compacting the same to produce a green strip. The green strip is supported on a moving surface as it travels to and enters a heater in which it is heated in an oxidising atmosphere to a temperature at which substantially all traces of the cellulose derivative are removed. The heated strip is fed while still on the moving support surface to and through a sinter furnace to form a coherent strip of the required composition.
    Type: Grant
    Filed: January 27, 1992
    Date of Patent: September 7, 1993
    Assignee: Mixalloy Limited
    Inventors: Robert F. Ward, Nigel J. Brooks
  • Patent number: 5232659
    Abstract: A powdered aluminum composition is mixed with lithium dispersed in an inert, non-water absorbent, liquid medium to produce a substantially homogenous admixture that is heated to melt the lithium and vaporize the liquid medium to thereby obtain a decovered powdered alloy comprising aluminum and lithium. The liquid medium has major and minor liquid constituents, wherein the major liquid constituent has a boiling point below the melting point of lithium and the minor liquid constituent has a boiling point above the melting point of lithium but below the melting point of the alloy being produced.
    Type: Grant
    Filed: June 29, 1992
    Date of Patent: August 3, 1993
    Inventor: Sanford W. Brown
  • Patent number: 5194203
    Abstract: A method of mixing a powder material and a binder in a predetermined ratio and kneading the mixture so that substantially whole surface of the powder particles are covered by the binder, molding the kneaded mixture into the shapes of desired products, then removing the binder from the moldings without causing expansion or cracks in the moldings before sintering. The binder comprises one or more organic binding substances soluble to an alcohol or to an mixed solvent of an alcohol and benzene or one or more ketones and one or more organic binding substances insoluble to the alcohol or to the mixed solvent. The moldings are put in contact with the alcohol or the mixed solvent to extract the organic binding substances soluble to the alcohol or to the mixed solvent from the moldings. The organic binding substances insoluble to the alcohol or to the mixed solvent are then removed by heat-decomposition.
    Type: Grant
    Filed: December 31, 1991
    Date of Patent: March 16, 1993
    Assignee: Mitsui Mining & Smelting Co., Ltd.
    Inventors: Yoshimitsu Kankawa, Yasunari Kaneko, Norio Kasahara
  • Patent number: 5192372
    Abstract: Isotropic permanent magnet formed of a sintered body having a mean crystal grain size of 1-160 microns and a major phase of tetragonal system comprising, in atomic percent, 10-25% of R wherein R represents at least one of rare-earth elements including Y, 3-23% of B and the balance being Fe. As additional elements M, Al, Ti, V, Cr, Mn, Zr, Hf, Nb, Ta, Mo, Ge, Sb, Sn, Bi, Ni or W may be incorporated.The magnets can be produced through a powder metallurgical process resulting in high magnetic properties, e.g., up to 7 MGOe or higher energy product.
    Type: Grant
    Filed: June 18, 1991
    Date of Patent: March 9, 1993
    Assignee: Sumitomo Special Metals Co., Ltd.
    Inventors: Setsuo Fujimura, Masato Sagawa, Yutaka Matsuura
  • Patent number: 5190709
    Abstract: A process for reaction injection molding of ceramic articles is disclosed. The process comprises (a) injecting a fluid, non-dilatant mixture comprising a ceramic powder, a metal powder or mixtures thereof, and a curable ceramic precursor that is a liquid below its curing temperature, into a heated mold, (b) curing the ceramic precursor to produce a hardened molded article, (c) heating the hardened molded article under a suitable atmosphere to a temperature sufficient to convert the ceramic precursor to a ceramic, and (d) sintering the ceramic to the desired density.
    Type: Grant
    Filed: June 26, 1992
    Date of Patent: March 2, 1993
    Assignee: Hercules Incorporated
    Inventor: Alexander Lukacs, III
  • Patent number: 5188793
    Abstract: A dewaxing method of a metal and/or ceramic molded body which comprises immersing the metal and/or ceramic molded body formed through a plastic molding in a boiling solvent to extract the dispersion medium contained in the molded body with said solvent. According to the method of the invention, the dewaxing time can be shortened from about 150 hours to the sum of about 54 hours for the solvent extraction and about 11 hous for dewaxing under heating. The dewaxed molded body is a sound body containing no crack nor expansion.
    Type: Grant
    Filed: August 8, 1990
    Date of Patent: February 23, 1993
    Assignee: NKK Corporation
    Inventor: Hiroaki Nishio
  • Patent number: 5174951
    Abstract: A method of producing a porous metal, which comprises forming a mixture of a metal powder and a fibrous substance and subjecting the mixture to sintering treatment to obtain a porous metal; a catalyst carrier obtained by laminating a dried sheet wherein a metal powder is supported in a fibrous substance with a dried sheet obtained by corrugating a dried sheet similar to the first-mentioned sheet to form an assembly of a number of cells having both ends opened and subjecting the assembly to sintering treatment; and a filter element obtained by laminating a dried sheet wherein a metal powder is supported in a fibrous substance with a dried sheet obtained by corrugating a dried sheet similar to the first-mentioned sheet to form an assembly of a number of cells whose one end is opened and whose other end is closed and subjecting the assembly to sintering treatment.
    Type: Grant
    Filed: December 21, 1990
    Date of Patent: December 29, 1992
    Assignee: Asahi Tec Corporation
    Inventors: Kiyoshi Nakai, Tokuhiko Ikki
  • Patent number: 5167913
    Abstract: A method of forming an adherent layer of metallurgy on a ceramic substrate which includes the steps of obtaining a ceramic material containing a polymeric binder and copper metallurgy patterns within the ceramic body. In one embodiment of the invention, the ceramic body also contains MgO.Thereafter, a surface layer of metallurgy is formed on the surface of the ceramic body. In one embodiment, the surface layer is nickel and in another embodiment, the surface layer is copper or gold.Then, the ceramic body undergoes a sintering cycle which includes the steps of pyrolysis, binder burnoff and, lastly, densification and, in some cases, crystallization. During densification and crystallization, there is a predetermined steam atmosphere which meets the following requirements: a partial pressure of oxygen less than that necessary to satisfy the equilibrium equation 4Cu+O.sub.2 =2Cu.sub.2 O; and a partial pressure of oxygen less than or equal to that necessary to satisfy the equilibrium equation 2Ni+O.sub.
    Type: Grant
    Filed: December 23, 1991
    Date of Patent: December 1, 1992
    Assignee: International Business Machines Corporation
    Inventors: John Acocella, Philip L. Flaitz, Raj N. Master, Chandrasekhar Narayan, Sarah H. Knickerbocker, Paul H. Palmateer, Sampath Purushothaman, Srinivasa S. N. Reddy
  • Patent number: 5154881
    Abstract: Methods of making sintered parts from a metal powder composition that contains an amide lubricant are provided. The composition comprises an iron-based powder and a lubricant that is the reaction product of a monocarboxylic acid, a dicarboxylic acid, and a diamine. The composition is compacted in a die, preferably at an elevated temperature of up to about 370.degree. C., at conventional compaction pressures, and then sintered according to standard powder-metallurgical techniques.
    Type: Grant
    Filed: February 14, 1992
    Date of Patent: October 13, 1992
    Assignee: Hoeganaes Corporation
    Inventors: Howard G. Rutz, Sidney Luk
  • Patent number: 5147601
    Abstract: A composition comprising a powder of iron and nickel and a binder (e.g. wax) is injection molded. The powder contains 0.5 to 10% by weight of nickel and has an average particle diameter not exceeding 45 microns. The binder is removed from the molded product. The molded product is sintered, and the sintered product is cooled to room temperature slowly at a rate of 2.degree. C. to 50.degree. C. per minute. The sintered product is of an iron-nickel alloy, has a high density and a high level of soft ferromagnetic properties, and may be complicated in shape.
    Type: Grant
    Filed: March 30, 1992
    Date of Patent: September 15, 1992
    Assignee: Sumitomo Metal Mining Co., Ltd.
    Inventors: Akihito Ohtsuka, Yoshio Kijima
  • Patent number: 5143692
    Abstract: A method of making a substructure for a dental restoration which comprises a substructure of a dental metal and a fired on coating of a dental ceramics, which method comprises applying a powder-form mixture of a dental metal powder and a thermoplastic polymeric material having a melting point above 50.degree. C., in the shape of the dental restoration to be made, to a porous refractory model, by means of a heated instrument, heating the assembly so obtained to a temperature at which the thermoplastic polymeric material liquefies and is sucked from the coating into the model, followed by raising the temperature of the assembly to a temperature at which the thermoplastic polymeric material disappears, and raising the temperature further to a sintering temperature at which the dental metal powder is sintered into a solid metal mass. The substructure so formed can be provided with a fired on coating of dental ceramics.
    Type: Grant
    Filed: July 2, 1991
    Date of Patent: September 1, 1992
    Assignee: Elephant Edelmetaal B.V.
    Inventor: Joseph M. van der Zel
  • Patent number: 5135712
    Abstract: A process for producing an injection-molded sintered product by powder metallurgy includes injection molding a kneaded product including a magnetic powder and a binder, releasing the molded product from the metal mold, and sintering the molding after debindering, wherein the molding is taken out from the metal mold using an electromagnet which exerts an adsorptive force to the molding. The process simplifies the release of the injection-molded products from metal molds and the transfer of the molding to the debindering process. The process is suitable for mass production, gives high yield, and has a wide applicability to products regardless of their shape.
    Type: Grant
    Filed: August 7, 1990
    Date of Patent: August 4, 1992
    Assignee: Sumitomo Metal Mining Company Limited
    Inventors: Yoshio Kijima, Kazuo Iijima, Masahiro Yokoo
  • Patent number: 5132080
    Abstract: A process for producing porous articles from metal powders. A slurry including metal powders is deposited on a horizontally moving surface. The slurry/moving surface combination is passed through an evaporating zone, a calender zone and a sintering zone to form the desired article. The article is then separated from the moving surface.
    Type: Grant
    Filed: November 28, 1944
    Date of Patent: July 21, 1992
    Assignee: Inco Limited
    Inventor: Leonard B. Pfeil
  • Patent number: 5130206
    Abstract: Extra loss is introduced in coupled cavity and klystron RF circuits by applying a surface coating to selected parts of circuit elements used in the circuits. The coating is applied in the form of a slurry, which is then sintered. The slurry comprises a mixture of an iron-base powder (such as a stainless steel) and a dielectric glass ceramic, suspended in a binder dissolved in a solvent. Circuits with the loss coating are easier to match than by other prior art techniques. The loss coating of the invention reduces the fabrication cost of coupled-cavity traveling wave tubes, while improving the performance by minimizing the gain ripple. Higher average power operation is possible, due to elimination of loss buttons previously employed in the prior art.
    Type: Grant
    Filed: July 29, 1991
    Date of Patent: July 14, 1992
    Assignee: Hughes Aircraft Company
    Inventors: Sunder S. Rajan, Ivo Tammaru, Steve L. Bosma, John W. Eldridge