Boron Or Compound Thereof Patents (Class 423/276)
  • Patent number: 11617998
    Abstract: A metal boride aerogel includes a three-dimensional aerogel structure comprising metal boride particles having an average diameter of less than one micron. A method is disclosed for forming a metal boride aerogel including dispersing boron nanoparticles in a solution of a metal salt, forming a boron-loaded metal oxide precursor gel using the dispersed boron nanoparticles in the solution of the metal salt, drying the boron-loaded metal oxide precursor gel to form a boron-loaded metal oxide precursor aerogel, and heating the boron-loaded metal oxide precursor aerogel to form a metal boride aerogel. The metal boride aerogel is essentially free of metal oxide.
    Type: Grant
    Filed: March 5, 2020
    Date of Patent: April 4, 2023
    Assignee: Lawrence Livermore National Security, LLC
    Inventors: Marcus A. Worsley, Theodore F. Baumann, Joshua Kuntz
  • Patent number: 11332369
    Abstract: A composition (or an aggregate) comprising an epitaxial h-BN/BNNT structure that comprises a hexagonal boron nitride structure that is epitaxial with respect to a boron nitride nanotube structure. Also, a composition (or an aggregate) that comprises independent boron nitride nanotubes, in which a total mass percentage of independent hexagonal boron nitride and residual boron in the composition is not more than 35%. Also, a composition (or an aggregate) in which not more than 1% of independent boron nitride nanotubes and boron nitride nanotube structures have a dixie cup or bamboo defect. Also, a composition in which at least 50% of independent boron nitride nanotubes and boron nitride nanotube structures are single-wall. Also, a method of making a composition that comprises epitaxial h-BN/BNNT structures.
    Type: Grant
    Filed: March 22, 2018
    Date of Patent: May 17, 2022
    Assignee: BNNano, Inc.
    Inventors: Jason Edward Taylor, Mark Edmond, Steven Michael Wilcenski
  • Patent number: 11296354
    Abstract: A process and system for creating a lithium ion anolyte from lithium alloys. Metal and lithium alloys are processed to remove the metal with lithium from the alloy remaining. A lithium ion anolyte formed may be used in a process to form lithium metal. Alternatively, a process and system for recovering lithium from sources such as lithium alloys and lithium metal oxides and other feedstock such as recycled batteries into a thin lithium metal film via electrodeposition in an organic electrolyte contacting both anode (holder for lithium source) and cathode (substrate for lithium deposition) in a single-compartment electrolysis cell.
    Type: Grant
    Filed: September 28, 2018
    Date of Patent: April 5, 2022
    Assignee: UChicago Argonne, LLC
    Inventors: Patricia Anne Ignacio de Leon, John N. Hryn, Li Tang, Edward F. Barry, Daniel Yoav Arenas
  • Patent number: 11108087
    Abstract: Compounds (salts) for use as electrolytes, e.g. in batteries such as Li ion, Na ion and Mg ion batteries are provided. The negative ions (anions) of the compounds are complex molecules containing superhalogens, and thus exhibit improved safety, and yet have electron affinities that are equal to or greater than those of halogens. In addition, the binding energy between Li+ and the anions is relatively small so ions can move easily from one electrode to the other in solutions in which the compounds are dissolved. A further advantage is that the affinity of the electrolyte for water is also relatively low so that batteries in which the electrolytes are used have longer lives than those of the prior art.
    Type: Grant
    Filed: February 7, 2017
    Date of Patent: August 31, 2021
    Assignee: VIRGINIA COMMONWEALTH UNIVERSITY
    Inventor: Purusottam Jena
  • Patent number: 10315926
    Abstract: Embodiments relate to methods, systems And apparatus tor generating lithium from brine. The brine is heated in a first vessel to greater than 260° C. and CO2 gas is injected mixing with the brine such that the CO2/P is greater than 18 g/atm. The brine is held at greater than 18 g/atm for longer than 20 minutes so that any impurities precipitate as solids leaving only lithium ions and chlorine ions. The brine is moved to a second vessel screening out solid precipitates leaving a brine containing only chlorine and lithium. CO2 gas is injected and mixed with the brine at 260° C. so that the CO2/P is greater than 200 g/atm. The brine is held at greater than 200 g/atm for longer than 20 minutes suppressing the chlorine as dissolved ions while lithium precipitates out as lithium carbonate. The lithium carbonate precipitate is removed from the brine solution.
    Type: Grant
    Filed: October 10, 2017
    Date of Patent: June 11, 2019
    Assignee: U.S. Department of Energy
    Inventors: Jinichiro Nakano, Anna Nakano, James P. Bennett
  • Patent number: 9926204
    Abstract: The presently disclosed and/or claimed inventive concept(s) relates generally to hexagonal osmium boride, OsB2, and methods of producing the same. In one non-limiting embodiment, hexagonal OsB2 is produced by mechanochemical synthesis of osmium and boron in a high energy ball mill.
    Type: Grant
    Filed: January 16, 2014
    Date of Patent: March 27, 2018
    Assignee: University of Central Florida Research Foundation, Inc.
    Inventors: Nina Orlovskaya, Zhilin Xie, Richard G. Blair
  • Patent number: 9796595
    Abstract: This disclosure relates to porous boron nitride and a method for preparing the same. The porous boron nitride of the present invention may be obtained by mixing a boron source with a nitrogen source, heating the mixture to form a compound, and then, extracting elements other than boron and nitrogen. The porous boron nitride of the present invention comprises both micropores and mesopoers, and it has a large specific surface area, and thus, may be usefully used in various fields.
    Type: Grant
    Filed: July 24, 2013
    Date of Patent: October 24, 2017
    Assignees: Hanwha Chemical Corporation, SNU R&DB Foundation
    Inventors: Shin Hoo Kang, Ji Soon Ihm, Dong Ok Kim, Jin-Hong Kim
  • Patent number: 9701542
    Abstract: The presently disclosed and/or claimed inventive concept(s) relates generally to hexagonal osmium boride, OsB2, and methods of producing the same. In one non-limiting embodiment, hexagonal OsB2 is produced by mechanochemical synthesis of osmium and boron in a high energy ball mill.
    Type: Grant
    Filed: February 7, 2014
    Date of Patent: July 11, 2017
    Assignee: University of Central Florida Research Foundation, Inc.
    Inventors: Nina Orlovskaya, Zhilin Xie, Richard G. Blair
  • Patent number: 9458180
    Abstract: The invention discloses a method for preparation of cyano compounds of the 13th group of the periodic table with 1, 2, 3 or 4 cyano residues, represented by formula (I): [Catn+][Z1F4-m(CN)m)?]n by a reaction of [(Z1F4)?] with trimethylsilylcyanide in the presence of a Lewis acid and in the presence of the cation Catn+; Cat2+ is a cation, Z1 is B, Al, Ga, In or Tl, m is 1, 2, 3 or 4 and n is 1, 2, 3 or 4.
    Type: Grant
    Filed: September 23, 2014
    Date of Patent: October 4, 2016
    Assignee: Lonza Ltd.
    Inventors: Katharina Sievert, Axel Schulz, Jorg Harloff, Stefan Ellinger, Christoph Taeschler, Cornelia Zur Taeschler
  • Patent number: 9227913
    Abstract: A method for preventing the crystallization of boric acid present in an aqueous phase, or for suppressing this crystallization when crystallization has already been initiated, including the addition of at least one compound comprising at least two hydroxyl functions, the compound being selected from alcohols, aminoalcohols, carboxylic acids, and hydroxy acids.
    Type: Grant
    Filed: May 27, 2013
    Date of Patent: January 5, 2016
    Assignee: Commissariat a L'Energie Atomique et aux Energies Alternatives
    Inventors: Laurence Longuet, Laurence Autissier, Alix Briere
  • Patent number: 9169128
    Abstract: Nanowire synthesis and one dimensional nanowire synthesis of titanates and cobaltates. Exemplary titanates and cobaltates that are fabricated and discussed include, without limitation, strontium titanate (SrTiO3), barium titanate (BaTiO3), lead titanate (PbTiO3), calcium cobaltate (Ca3Co4O9) and sodium cobaltate (NaCo2O4).
    Type: Grant
    Filed: February 21, 2012
    Date of Patent: October 27, 2015
    Assignee: PURDUE RESEARCH FOUNDATION
    Inventors: Yue Wu, Gautam G. Yadav, Genqiang Zhang
  • Publication number: 20150126355
    Abstract: Feed material comprising uniform solution precursor droplets is processed in a uniform melt state using microwave generated plasma. The plasma torch employed is capable of generating laminar gas flows and providing a uniform temperature profile within the plasma. Plasma exhaust products are quenched at high rates to yield amorphous products. Products of this process include spherical, highly porous and amorphous oxide ceramic particles such as magnesia-yttria (MgO—Y2O3). The present invention can also be used to produce amorphous non oxide ceramic particles comprised of Boron, Carbon, and Nitrogen which can be subsequently consolidated into super hard materials.
    Type: Application
    Filed: January 15, 2015
    Publication date: May 7, 2015
    Applicant: AMASTAN TECHNOLOGIES LLC
    Inventors: Kamal Hadidi, Makhlouf Redjdal
  • Patent number: 8951496
    Abstract: Feed material comprising uniform solution precursor droplets is processed in a uniform melt state using microwave generated plasma. The plasma torch employed is capable of generating laminar gas flows and providing a uniform temperature profile within the plasma. Plasma exhaust products are quenched at high rates to yield amorphous products. Products of this process include spherical, highly porous and amorphous oxide ceramic particles such as magnesia-yttria (MgO—Y2O3). The present invention can also be used to produce amorphous non oxide ceramic particles comprised of Boron, Carbon, and Nitrogen which can be subsequently consolidated into super hard materials.
    Type: Grant
    Filed: December 4, 2012
    Date of Patent: February 10, 2015
    Assignee: Amastan Technologies LLC
    Inventors: Kamal Hadidi, Makhlouf Redjdal
  • Publication number: 20150023858
    Abstract: In some embodiments, the present disclosure pertains to methods of forming a reinforcing material by: (1) depositing a first material onto a catalyst surface; and (2) forming a second material on the catalyst surface, where the second material is derived from and associated with the first material. In some embodiments, the first material includes, without limitation, carbon nanotubes, graphene nanoribbons, boron nitride nanotubes, chalcogenide nanotubes, carbon onions, and combinations thereof. In some embodiments, the formed second material includes, without limitation, graphene, hexagonal boron nitride, chalcogenides, and combinations thereof. In additional embodiments, the methods of the present disclosure also include a step of separating the formed reinforcing material from the catalyst surface, and transferring the separated reinforcing material onto a substrate without the use of polymers.
    Type: Application
    Filed: July 18, 2014
    Publication date: January 22, 2015
    Applicant: William Marsh Rice University
    Inventors: James M. Tour, Zheng Yan, Zhiwei Peng, Robert H. Hauge, Yilun Li
  • Publication number: 20140377662
    Abstract: Disclosed are compositions containing a formula of LixTiyV1Bz wherein x, y, and z are real numbers greater than zero. In certain embodiments, x is not greater than 7, and y is not greater than 6, or a combination thereof. The composition may be a microporous aerogel, a mesoporous aerogel, a crystalline structure, or a combination thereof. In certain embodiments, the composition may be an aerogel, and a surface of the aerogel comprises microcrystals, nanocrystals or a combination thereof. The compositions have very low densities. Also disclosed are methods to produce the composition and use of the composition in energy storage devices.
    Type: Application
    Filed: June 19, 2014
    Publication date: December 25, 2014
    Inventor: Nilanjan DEB
  • Patent number: 8900538
    Abstract: A method of making a semiconductor device, includes providing a graphene sheet, creating a plurality of nanoholes in the graphene sheet to form a graphene nanomesh, the graphene nanomesh including a plurality of carbon atoms which are formed adjacent to the plurality of nanoholes, passivating a dangling bond on the plurality of carbon atoms by bonding a passivating element to the plurality of carbon atoms, and doping the passivated graphene nanomesh by bonding a dopant to the passivating element.
    Type: Grant
    Filed: July 31, 2011
    Date of Patent: December 2, 2014
    Assignees: International Business Machines Corporation, Egypt Nanotechnology Center
    Inventors: Ahmed Abou-Kandil, Ahmed Maarouf, Glenn J. Martyna, Hisham Mohamed, Dennis M. Newns
  • Publication number: 20140251500
    Abstract: New magnetic materials containing cerium, iron, and small additions of a third element are disclosed. These materials comprise compounds Ce(Fe12?xMx) where x=1-4, having the ThMn12 tetragonal crystal structure (space group I4/mmm, #139). Compounds with M=B, Al, Si, P, S, Sc, Co, Ni, Zn, Ga, Ge, Zr, Nb, Hf, Ta, and W are identified theoretically, and one class of compounds based on M=Si has been synthesized. The Si cognates are characterized by large magnetic moments (4?Ms greater than 1.27 Tesla) and high Curie temperatures (264?Tc?305° C.). The Ce(Fe12?xMx) compound may contain one or more of Ti, V, Cr, and Mo in combination with an M element. Further enhancement in Tc is obtained by nitriding the Ce compounds through heat treatment in N2 gas while retaining the ThMn12 tetragonal crystal structure; for example CeFe10Si2N1.29 has Tc=426° C.
    Type: Application
    Filed: March 6, 2013
    Publication date: September 11, 2014
    Applicant: GM GLOBAL TECHNOLOGY OPERATIONS LLC
    Inventors: CHEN ZHOU, FREDERICK E. PINKERTON, JAN F. HERBST
  • Publication number: 20140227152
    Abstract: Process for removing metal compounds or metalloid compounds M present in the gas phase from a gas G comprising these, wherein the gas G comprising the volatile metal compound or metalloid compound M is brought into contact with a solid donor D and the resulting reaction product is separated off.
    Type: Application
    Filed: February 5, 2014
    Publication date: August 14, 2014
    Applicant: BASF SE
    Inventors: Michael Krayer, Günther Huber, Jesus Enrique Zerpa Unda, Jasmina Kessel
  • Patent number: 8795614
    Abstract: The present invention relates to a method of economical extraction of magnesium, boron and calcium, while minimizing the loss of lithium, from a lithium bearing solution. More specifically, the present invention provides a method for economical extraction of magnesium, boron, and calcium, while minimizing the loss of lithium, from a lithium bearing solution comprising the steps of: (a) adding an alkali in the lithium bearing solution to precipitate magnesium hydroxide; (b) absorbing boron ions on the surface of the magnesium hydroxide by adjusting the pH to about 8.5 to about 10.5; and (c) simultaneously extracting magnesium and boron by filtering the magnesium hydroxide absorbed with the boron ions from the lithium bearing solution.
    Type: Grant
    Filed: January 8, 2013
    Date of Patent: August 5, 2014
    Assignee: Research Institute of Industrial Science & Technology
    Inventors: Uong Chon, Gi Chun Han, Ki Hong Kim, Chang Ho Song, Ki Young Kim
  • Patent number: 8778289
    Abstract: The present invention relates to a method of extracting lithium from a lithium bearing solution. More specifically, the present invention provides a method of economical extraction of lithium from a lithium bearing solution by adding a phosphorous supplying material to the solution to precipitate lithium phosphate from the dissolved lithium.
    Type: Grant
    Filed: January 8, 2013
    Date of Patent: July 15, 2014
    Assignee: Research Institute of Industrial Science & Technology
    Inventors: Uong Chon, Oh Joon Kwon, Ki Hong Kim, Chang Ho Song, Gi Chun Han, Ki Young Kim
  • Publication number: 20140155249
    Abstract: Feed material comprising uniform solution precursor droplets is processed in a uniform melt state using microwave generated plasma. The plasma torch employed is capable of generating laminar gas flows and providing a uniform temperature profile within the plasma. Plasma exhaust products are quenched at high rates to yield amorphous products. Products of this process include spherical, highly porous and amorphous oxide ceramic particles such as magnesia-yttria (MgO—Y2O3). The present invention can also be used to produce amorphous non oxide ceramic particles comprised of Boron, Carbon, and Nitrogen which can be subsequently consolidated into super hard materials.
    Type: Application
    Filed: December 4, 2012
    Publication date: June 5, 2014
    Inventors: Kamal HADIDI, Makhlouf REDJDAL
  • Publication number: 20140147753
    Abstract: A lithium ionic conductor (solid electrolyte) contains lithium (Li), phosphorus (P), boron (B) and sulfur (S) as constituent elements and has a crystal structure that boron (B) is substituted for part of phosphorus (P) in the ? structure of Li3PS4.
    Type: Application
    Filed: February 3, 2014
    Publication date: May 29, 2014
    Applicant: FUJITSU LIMITED
    Inventors: Kenji HOMMA, Tamotsu YAMAMOTO, Tsutomu TANAKA
  • Patent number: 8734748
    Abstract: A method of purifying a nanomaterial and the resultant purified nanomaterial in which a salt, such as ferric chloride, at or near its liquid phase temperature, is used to penetrate and wet the internal surfaces of a nanomaterial to dissolve impurities that may be present, for example, from processes used in the manufacture of the nanomaterial.
    Type: Grant
    Filed: September 28, 2010
    Date of Patent: May 27, 2014
    Assignee: The United States of America as Represented by the Administrator of National Aeronautics and Space Administration
    Inventors: Ching-Cheh Hung, Janet Hurst
  • Patent number: 8709368
    Abstract: The invention provides a preparation process of transition metal boride, comprising the following steps: A) aluminum is put in a reactor, inert gas is fed into the reactor after evacuation, the reactor is heated up to 700 to 800° C. and then added with dry potassium fluoborate or sodium fluoborate, monomer boron and cryolite are generated by rapid stirring and reaction for 4 to 6 hours, and the molten liquid at the upper layer is sucked out and the monomer boron is obtained by means of separation; and B) the obtained monomer boron is added with transition metal for reaction at the temperature from 1800 to 2200° C. in order to generate corresponding transition metal boride.
    Type: Grant
    Filed: December 9, 2012
    Date of Patent: April 29, 2014
    Assignee: Shenzhen Sunxing Light Alloys Materials Co., Ltd.
    Inventors: Xuemin Chen, Jun Yang, Zhihong Li, Weiping Wu
  • Patent number: 8697024
    Abstract: A precursor formulation of a silicon carbide material that includes a ceramic material and a boron-11 compound. The ceramic material may include silicon and carbon and, optionally, oxygen, nitrogen, titanium, zirconium, aluminum, or mixtures thereof. The boron-11 compound may be a boron-11 isotope of boron oxide, boron hydride, boron hydroxide, boron carbide, boron nitride, boron trichloride, boron trifluoride, boron metal, or mixtures thereof. A material for use in a nuclear reactor component is also disclosed, as are such components, as well as a method of producing the material.
    Type: Grant
    Filed: December 18, 2009
    Date of Patent: April 15, 2014
    Assignee: COI Ceramics, Inc.
    Inventors: Timothy E. Easler, Andrew Szweda, Eric Stein
  • Patent number: 8641996
    Abstract: A cyclic preparation method including the following steps: a) boric acid or boric anhydride is added with hydrofluoric acid and then with potassium sulfate for reaction to generate potassium fluoborate; titanium-iron concentrate is added with hydrofluoric acid and then with potassium sulfate for reaction to generate potassium fluotitanate; B) the potassium fluoborate is mixed with the potassium fluotitanate, and the mixture reacts with aluminum to generate titanium boride and potassium cryolite; C) the potassium cryolite is sucked out and then fed into a rotary reaction kettle together with concentrated sulfuric acid, hydrogen fluoride gas as well as potassium sulfate and potassium aluminum sulfate are generated by reaction in the rotary reaction kettle, and the hydrogen fluoride gas is collected and then dissolved in water to obtain hydrofluoric acid aqueous solution; and D) the obtained hydrofluoric acid aqueous solution and potassium sulfate aqueous solution are recycled.
    Type: Grant
    Filed: December 9, 2012
    Date of Patent: February 4, 2014
    Assignee: Shenzhen Sunxing Light Alloys Materials Co., Ltd.
    Inventors: Xuemin Chen, Yueming Yu, Qingdong Ye, Jun Yang, Zhi Zhou
  • Publication number: 20130330932
    Abstract: Hardmask films having high hardness and low stress are provided. In some embodiments a film has a stress of between about ?600 MPa and 600 MPa and hardness of at least about 12 GPa. In some embodiments, a hardmask film is prepared by depositing multiple sub-layers of doped or undoped silicon carbide using multiple densifying plasma post-treatments in a PECVD process chamber. In some embodiments, a hardmask film includes a high-hardness boron-containing film selected from the group consisting of SixByCz, SixByNz, SixByCzNw, BxCy, and BxNy. In some embodiments, a hardmask film includes a germanium-rich GeNx material comprising at least about 60 atomic % of germanium. These hardmasks can be used in a number of back-end and front-end processing schemes in integrated circuit fabrication.
    Type: Application
    Filed: August 15, 2013
    Publication date: December 12, 2013
    Applicant: Novellus Systems, Inc.
    Inventors: Vishwanathan Rangarajan, George Andrew Antonelli, Ananda Banerji, Bart Van Schravendijk
  • Publication number: 20130306927
    Abstract: A method of forming a metal chalcogenide material. The method comprises introducing a metal precursor and a chalcogenide precursor into a chamber, and reacting the metal precursor and the chalcogenide precursor to form a metal chalcogenide material on a substrate. The metal precursor is a carboxylate of an alkali metal, an alkaline earth metal, a transition metal, a post-transition metal, or a metalloid. The chalcogenide precursor is a hydride, alkyl, or aryl precursor of sulfur, selenium, or tellurium or a silylhydride, silylalkyl, or silylaryl precursor of sulfur, selenium, or tellurium. Methods of forming a memory cell including the metal chalcogenide material are also disclosed, as are memory cells including the metal chalcogenide material.
    Type: Application
    Filed: May 21, 2012
    Publication date: November 21, 2013
    Applicant: MICRON TECHNOLOGY, INC.
    Inventors: Eugene P. Marsh, Stefan Uhlenbrock
  • Patent number: 8574526
    Abstract: A cyclic preparation method for producing titanium boride from intermediate feedstock sodium-based titanium-boron-fluorine salt mixture and producing sodium cryolite as byproduct, which comprises the steps: a) boric acid or boric anhydride is added with hydrofluoric acid and then with sodium carbonate solution for concentration and crystallization to generate sodium fluoborate; titanium-iron concentrate is added with hydrofluoric acid and then with sodium carbonate and sodium hydroxide to obtain sodium fluotitanate; B) the sodium fluoborate is mixed with the sodium fluotitanate, and the mixture reacts with aluminum to generate titanium boride and sodium cryolite; C) the sodium cryolite is sucked out and then fed into a rotary reaction kettle together with concentrated sulfuric acid, hydrogen fluoride gas as well as sodium sulfate and sodium aluminum sulfate are generated by reaction in the rotary reaction kettle, and the hydrogen fluoride gas is collected and then dissolved in water to obtain hydrofluoric aci
    Type: Grant
    Filed: December 8, 2012
    Date of Patent: November 5, 2013
    Assignee: Shenzhen Sunxing Light Alloys Materials Co., Ltd.
    Inventors: Xuemin Chen, Yueming Yu, Qingdong Ye, Jun Yang, Zhi Zhou
  • Patent number: 8558166
    Abstract: A method for determining boron isotopic composition by PTIMS (Positive Thermal Ionization Mass Spectrometry)-static double collection realizes simultaneous static collection of m/e309 peak and m/e308 peak by double Faraday cups through adjusting the two parameters Focus Quad and Dispersion Quad in Zoom Optics, and completes high-accuracy determination of boron isotopic composition. The method includes (1) determining Focus Quad and Dispersion Quad parameters in the Zoom Optics of the ion source; (2) determining the two parallel cups in the Faraday collector and their parameters; (3) determining the collection mass number of the center cup of the Faraday collector.
    Type: Grant
    Filed: January 27, 2011
    Date of Patent: October 15, 2013
    Assignee: Nanjing University
    Inventors: Shaoyong Jiang, Haizhen Wei
  • Patent number: 8557208
    Abstract: One embodiment of the present disclosure provides a method of making a ceramic material that contains boron and a metal. A metal source, an oxidizer, a boron source, and a fuel source are combined. These reactants are then heated at, or to, a temperature sufficient to initiate a combustion reaction. The combustion reaction produces a ceramic material that includes boron and the metal. The present disclosure also provides materials formed by the disclosed method, as well as methods and systems using such materials.
    Type: Grant
    Filed: May 26, 2009
    Date of Patent: October 15, 2013
    Assignee: Board of Regents of the Nevada System of Higher Education, on behalf of the University of Nevada, Reno
    Inventors: Olivia A. Graeve, Raghunath Kanakala, Gabriel Rojas-George
  • Publication number: 20130266499
    Abstract: Provided are: a novel bonds useful as a highly-functional material; and a novel production method for a polycrystalline sintered product of a bonds, of which the energy cost is low, which does not require a sintering promoter, which enables the product to be worked into complicated forms and which enables a development to a polynary boride. Provided are a boride having a composition Na—Si—B, and a polycrystalline reaction-sintered product thereof. A mixed compact of boron and an element, M (M means Si and/or C) is heated along with metal sodium to give a polycrystalline reaction-sintered product.
    Type: Application
    Filed: August 17, 2011
    Publication date: October 10, 2013
    Inventors: Haruhiko Morito, Hisanori Yamane
  • Publication number: 20130256608
    Abstract: The present invention provides a metal material comprising an alloy that is represented by the compositional formula Mn3-xM1xSiyAlzM2a, wherein M1 is at least one element selected from the group consisting of Ti, V, Cr, We, Co, Ni, and Cu; M2 is at least one element selected from the group consisting of B, P, Ga, Ge, Sn, and Bi, where 0?x?3.0, 3.5?y?4.5, 2.5?z?3.5, and 0?a?1, the alloy having a negative Seebeck coefficient and an electrical resistivity of 1 m?·cm or less at a temperature of 25° C. or higher. The metal material of the present invention is a novel material that has good thermoelectric conversion capability in the intermediate temperature region and excellent durability, and that is useful as an n-type thermoelectric conversion material.
    Type: Application
    Filed: December 1, 2011
    Publication date: October 3, 2013
    Applicants: NATIONAL INSTITUTE OF ADVANCED INDUSTRIAL SCIENCE AND TECHNOLOGY, TES NEWENERGY CO.
    Inventors: Ryoji Funahashi, Hideaki Tanaka, Tomonari Takeuchi, Tetsuo Nomura
  • Patent number: 8501138
    Abstract: A production method of high purity silver tetrafluoroborate, capable of producing silver tetrafluoroborate (AgBF4) at purity higher than the conventional, without using an organic solvent. The production method of the present invention is characterized in that the method comprises the step of: reacting silver fluoride with boron trifluoride in the presence of anhydrous hydrofluoric acid. Boron trifluoride is delivered into a solution obtained by dissolving or suspending silver fluoride in an anhydrous hydrofluoric acid solution.
    Type: Grant
    Filed: June 9, 2006
    Date of Patent: August 6, 2013
    Assignee: Stella Chemifa Coporation
    Inventors: Hirohisa Kikuyama, Masayuki Miyashita, Masahide Waki, Tomohiko Satonaga, Kazuhiko Shogami
  • Patent number: 8501136
    Abstract: A method for preparing single-crystalline, rare-earth metal hexaboride nanowires by a chemical vapor deposition process is described. Also described are the nanowires themselves, the electron emitting properties of the nanowires, and the use of the nanowires in electron emitting devices, particularly as point electron sources.
    Type: Grant
    Filed: February 6, 2007
    Date of Patent: August 6, 2013
    Assignee: The University of North Carolina at Chapel Hill
    Inventors: Lu-Chang Qin, Han Zhang, Qi Zhang, Jie Tang
  • Patent number: 8465780
    Abstract: The specification discloses a borate microemulsion product. In one embodiment, the borate microemulsion includes from about 24 to about 32 weight percent emulsified sodium pentaborate; and from about 24 to about 32 weight percent particulate boric acid suspended therein. The microemulsion has a density of about 9.5 to about 10.5 pounds per gallon at about room temperature. In certain embodiments, the microemulsion has a viscosity of about 1200 to about 1520 at a temperature of from about 66° F. to about 70° F. In certain other embodiments, microemulsion has a viscosity of about 1000 to about 3000 at a temperature of from about 70° F. to about 75° F.
    Type: Grant
    Filed: February 19, 2010
    Date of Patent: June 18, 2013
    Assignee: Nisus Corporation
    Inventor: Jeffrey Douglas Lloyd
  • Patent number: 8449854
    Abstract: According to some embodiments, a method of preparing a superhard material involves using mixtures of boron with carbon nitride of C3N4 stoichiometry as precursors. The C3N4 may be nanospherical. The result of chemical interaction of these components is the formation of new ternary compound B—C—N compound with a cubic structure. According to some embodiments, the composition is BCxN, where x is about 0.5. According to some embodiments, the composition is BCxN, where x is about 0.2. According to some embodiments, the compound has a unit cell parameter a=3.645±0.005 ?. According to some embodiments, the unit cell parameter a is about 3.655 ?. Synthesis is carried out under the conditions of thermodynamic stability of diamond at pressures higher that 6.0 GPa and temperatures above 1000° C. The starting components are taken according to the following ratio: boron—20-60 wt. %, C3N4—40-80 wt. %.
    Type: Grant
    Filed: January 29, 2008
    Date of Patent: May 28, 2013
    Assignee: William Marsh Rice University
    Inventors: Valery N. Khabashesku, Vladimir P. Filonenko, Valeri A. Davydov
  • Publication number: 20130118645
    Abstract: The present invention provides a metallic glass having a chemical composition represented by any one of the following formulae (1) to (3): FemPtnSixByPz (wherein, 20<m?60 at %, 20<n?55 at %, 11?x<19 at %, 0?y<8 at %, and 0<z<8 at %)??(1); Fe55Pt25(SixByPz)20 (wherein, 11?x<19 at %, 0?y<8 at %, and 0<z<8 at %)??(2); and (Fe0.55Pt0.25Si0.16B0.02P0.02)100-xMx (wherein, 0<X?6 at %; and M represents an element or a combination of any two or more of the elements selected from Zr, Nb, Ta, Hf, Ti, Mo, W, V, Cr, Mn, Al, Y, Ag, and rare earth elements.)??(3). The present invention provides a magnetic recording medium 1 comprising: a substrate 11; and a metallic glassy layer 12 that is arranged on the substrate 11 and has a plurality of convex portions 12A and concave portions 12B. The metallic glassy layer 12 has a chemical composition represented by any one of the above formulae (1) to (3).
    Type: Application
    Filed: December 27, 2012
    Publication date: May 16, 2013
    Applicant: JAPAN SCIENCE AND TECHNOLOGY AGENCY
    Inventors: Akihiro MAKINO, Akihisa INOUE, Wei ZHANG, Hisamichi KIMURA
  • Publication number: 20130028823
    Abstract: A method of making a semiconductor device, includes providing a graphene sheet, creating a plurality of nanoholes in the graphene sheet to form a graphene nanomesh, the graphene nanomesh including a plurality of carbon atoms which are formed adjacent to the plurality of nanoholes, passivating a dangling bond on the plurality of carbon atoms by bonding a passivating element to the plurality of carbon atoms, and doping the passivated graphene nanomesh by bonding a dopant to the passivating element.
    Type: Application
    Filed: July 31, 2011
    Publication date: January 31, 2013
    Applicants: Egypt Nanotechnology Center, International Business Machines Corporation
    Inventors: Ahmed Abou-Kandil, Ahmed Maarouf, Glenn J. Martyna, Hisham Mohamed, Dennis M. Newns
  • Patent number: 8303922
    Abstract: A new method is disclosed for the exfoliation of hexagonal boron nitride into mono- and few-layered nanosheets (or nanoplatelets, nanomesh, nanoribbons). The method does not necessarily require high temperature or vacuum, but uses commercially available h-BN powders (or those derived from these materials, bulk crystals) and only requires wet chemical processing. The method is facile, cost efficient, and scalable. The resultant exfoliated h-BN is dispersible in an organic solvent or water thus amenable for solution processing for unique microelectronic or composite applications.
    Type: Grant
    Filed: August 24, 2009
    Date of Patent: November 6, 2012
    Assignee: The United States of America as represeted by the Administrator of the National Aeronautics and Space Administration
    Inventors: Yi Lin, John W. Connell
  • Publication number: 20120263941
    Abstract: A coated article is described. The coated article includes a substrate, and a hydrophobic film formed on the substrate. The hydrophobic film is a non-crystalline boron-carbon-nitrogen layer formed by magnetron sputtering. A method for making the coated article is also described.
    Type: Application
    Filed: July 7, 2011
    Publication date: October 18, 2012
    Applicants: HON HAI PRECISION INDUSTRY CO., LTD., HONG FU JIN PRECISION INDUSTRY (ShenZhen) CO., LTD
    Inventors: HSIN-PEI CHANG, WEN-RONG CHEN, HUANN-WU CHIANG, CHENG-SHI CHEN, CONG LI
  • Patent number: 8278289
    Abstract: The present invention relates to the field of skin disorders, particularly to the prevention and/or treatment of benignant or malignant changes of the epidermis visible in form of e.g. nevus. A pharmaceutical, dermatological and/or cosmetic composition is disclosed comprising as active constituent the boroxine compound. The present invention further provides the respective uses of the boroxine compound in medicine, particularly in the field of skin disorders, and in dermatological and/or cosmetic applications.
    Type: Grant
    Filed: March 21, 2006
    Date of Patent: October 2, 2012
    Inventor: Borivoj Galic
  • Publication number: 20120238021
    Abstract: Methods for synthesizing macroscale 3D heteroatom-doped carbon nanotube materials (such as boron doped carbon nanotube materials) and compositions thereof. Macroscopic quantities of three-dimensionally networked heteroatom-doped carbon nanotube materials are directly grown using an aerosol-assisted chemical vapor deposition method. The porous heteroatom-doped carbon nanotube material is created by doping of heteroatoms (such as boron) in the nanotube lattice during growth, which influences the creation of elbow joints and branching of nanotubes leading to the three dimensional super-structure. The super-hydrophobic heteroatom-doped carbon nanotube sponge is strongly oleophilic and an soak up large quantities of organic solvents and oil. The trapped oil can be burnt off and the heteroatom-doped carbon nanotube material can be used repeatedly as an oil removal scaffold.
    Type: Application
    Filed: March 19, 2012
    Publication date: September 20, 2012
    Applicant: William Marsh Rice University
    Inventors: Daniel Paul Hashim, Pulickel M. Ajayan, Mauricio Terrones
  • Patent number: 8268280
    Abstract: The present invention relates to a method for production of calcium compounds having very low content of phosphorus and boron from an impure calcium chloride, solution containing phosphorus and boron, which method comprises the following steps: a) addition of a FeCl3-solution to the calcium chloride solution, b) adjusting the pH of the solution by addition of a base to between 3 and 9.5 for precipitation of iron hydroxide, iron phosphate and boron compounds, c) removal of the solid precipitate from the solution in step b) obtaining a purified calcium chloride solution, d) precipitation of a calcium compound from the solution from step c), and e) separation of the calcium compound from the solution in step d).
    Type: Grant
    Filed: January 7, 2009
    Date of Patent: September 18, 2012
    Assignee: Elkem Solar AS
    Inventors: Torfinn Buseth, Einar Andersen
  • Patent number: 8226922
    Abstract: A diamond sintered body conventionally used in a cutting tool or the like includes an iron group metal element as a sintering aid, and therefore has a problem in heat resistance. A diamond sintered body not including the iron group metal, on the other hand, does not have sufficient mechanical strength to be used as a tool material, and also does not have conductivity, which makes electrical discharge machining impossible, and thus processing thereof is difficult. A diamond polycrystalline body having high heat resistance and mechanical strength and having conductivity enabling electrical discharge machining is obtained by using only an amorphous or fine graphite-type carbon material as a starting material, adding boron thereto and concurrently performing conversion into diamond and sintering in an ultra-high pressure and temperature condition.
    Type: Grant
    Filed: December 3, 2004
    Date of Patent: July 24, 2012
    Assignee: Sumitomo Electric Industries, Ltd.
    Inventor: Hitoshi Sumiya
  • Publication number: 20120171487
    Abstract: Nanotube filaments comprising carbon, boron and nitrogen of the general formula BxCyNz, having high-aspect ratio and high-crystallinity produced by a pressurized vapor/condenser method and a process of production. The process comprises thermally exciting a boron-containing target in a chamber containing a carbon source and nitrogen at a pressure which is elevated above atmospheric pressure.
    Type: Application
    Filed: September 22, 2011
    Publication date: July 5, 2012
    Inventors: Kevin Jordan, R. Roy Whitney, Michael W. Smith, Jae-Woo Kim, Cheol Park
  • Publication number: 20120160478
    Abstract: A well tool can include a flow path, and a flow blocking device which selectively prevents flow through the flow path. The device can include an anhydrous boron compound. A method of constructing a downhole well tool can include forming a structure of a solid mass comprising an anhydrous boron compound, and incorporating the structure into the well tool.
    Type: Application
    Filed: February 27, 2012
    Publication date: June 28, 2012
    Applicant: HALLIBURTON ENERGY SERVICES, INC.
    Inventors: Bradley L. TODD, Thomas D. WELTON, Luke W. HOLDERMAN, Ivan SULEIMAN
  • Patent number: 8197786
    Abstract: Porous carbon materials and methods of manufacturing the same are provided. One method includes forming a carbon-metal oxide composite by heating a coordination polymer to form a carbon-metal oxide composite, and then removing the metal oxide from the carbon-metal oxide composite. The porous carbon material has an average pore diameter ranging from about 10 nm to about 100 nm, and a d002 ranging from about 3.35 to 3.50 ?.
    Type: Grant
    Filed: September 7, 2007
    Date of Patent: June 12, 2012
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Dong-min Im, Jeong-hee Lee, Yong-nam Ham, Chan-ho Pak
  • Publication number: 20120141745
    Abstract: A chiral liquid crystal precursor composition which comprises at least one salt that changes a position of the selective reflection band exhibited by the composition in a cured state compared to the position of a selective reflection band exhibited by a composition in the cured state that does not contain the at least one salt. This abstract is neither intended to define the invention disclosed in this specification nor intended to limit the scope of the invention in any way.
    Type: Application
    Filed: December 7, 2011
    Publication date: June 7, 2012
    Applicant: SICPA HOLDING SA
    Inventors: Andrea CALLEGARI, Tristan JAUZEIN
  • Patent number: 8182778
    Abstract: The invention relates to boron carbide and to a method for making the same, as well as to a super-abrasive material and a machine device including said boron carbide. The boron carbide of the invention has the following formula BC5 and has a diamond-type cubic structure with a mesh parameter a=3.635±0.006 &angst. The boron carbide of the invention can particularly be used in the field of machining.
    Type: Grant
    Filed: April 9, 2008
    Date of Patent: May 22, 2012
    Assignees: Centre National de la Recherche Scientifique, Universite Pierre et Marie Curie (Paris 6), European Synchrotron Radiation Facility
    Inventors: Yann Le Godec, Mohamed Mezouar, Denis Andrault, Vladimir Solozhenko, Oleksandr Kurakevych