Abstract: New soluble preceramic polymers formed by reacting B.sub.10 H.sub.14-n R.sub.n, (where R is a lower alkyl group having from 1 to about 8 carbon atoms, a substituted or unsubstituted cycloalkyl group having from 3 to about 8 carbon atoms, a substituted or unsubstituted lower alkenyl group having from 2 to about 8 carbon atoms, or a substituted or unsubstituted lower aryl group having from 6 to about 10 carbon atoms, and n is a number from zero to about six) with a diamine in an organic solvent are disclosed. Preferably the diamine has the formulaR.sup.1 R.sup.2 N-R.sup.3 -NR.sup.4 R.sup.5where R.sup.1, R.sup.2, R.sup.4 and R.sup.5 are H, a lower alkyl group having from 1 to about 8 carbon atoms, a substituted or unsubstituted cycloalkyl group having from 3 to about 8 carbon atoms, a substituted or unsubstituted lower alkenyl group having from 2 to about 8 carbon atoms, a substituted or unsubstituted lower aryl group having from 6 to about 10 carbon atoms, or a di- or triorganosilyl. R.sup.

Abstract: A process for producing cubic boron nitride comprises heating at an elevated temperature and under high pressure a source of boron and a source of nitrogen in the presence of a fluoronitride or a source of fluoronitride.

Abstract: The present invention is a novel crystalline lead aluminum borate composition characterized by a unique x-ray diffraction pattern.

Abstract: The present invention is directed to a method of reducing fouling and corrosion in furnaces during the thermal cracking of hydrocarbons. The method generally comprises adding to the hydrocarbon an effective amount of boron or boron compounds. The preferred boron materials are the oxides, borates, borate esters, peroxyborates, boranes, organoboranes, borazine and salts of boron oxides. The oxides, borates or salts thereof, are preferable in non-mono-alcohol solvents.

Abstract: The present invention relates to a method of preparing B-trichloroborazine, B.sub.3 N.sub.3 Cl.sub.3 H.sub.3. Generally, the method includes the combination of gaseous boron trichloride in an anhydrous aprotic organic solvent followed by addition of excess gaseous ammonia at ambient temperature or below. The reaction mixture is heated to between about 100.degree. to 140.degree. C. followed by cooling, removal of the solid ammonium chloride at ambient temperature, distillation of the solvent under vacuum if necessary at a temperature of up to about 112.degree. C., and recovery of the B-trichloroborazine. Solvents include, toluene, benzene, xylene, chlorinated hydrocarbons, chlorinated aromatic compounds, or mixtures thereof. Toluene is a preferred solvent. The process provides a convenient synthesis of a material which often decomposes on standing. B-trichloroborazine is useful in a number of chemical reactions, and particularly in the formation of high temperature inorganic polymers and polymer precursors.

Abstract: New magnetic hydride Nd.sub.2 Fe.sub.14 BH.sub.x (0<x<5) and family corresponding to other rare earths and yttrium. Possible substitution of Fe by Co. Preparation from Nd.sub.2 Fe.sub.14 B by hydrogenation (ambient temperature; pH.sub.2 >20 bar), which can be reversed to give powdered Nd.sub.2 Fe.sub.14 B. Remarkable magnetic properties.

Abstract: Boron compounds such as alkali metal or alkaline earth metal borates capable of forming hydrates or higher hydrates may be formed into shaped bodies by forming into a paste with water and allowing the water to be bound to form a solid shaped body. The bodies are useful as inserts into preformed cavities in structures, e.g. of wood, liable to insect, fungal or other infestation by virtue of the slow dissolution of the insert and the toxicity to such organisms of the boron compounds.

Abstract: A method of removing boron from gases which comprises passing the gas stream in contact with solid sodium bicarbonate.

Abstract: Disclosed is potassium perborate-hydrate of the formula KBO.sub.3.nH.sub.2 O where n is 0 to 1 and a process for its preparation by the reaction of H.sub.2 O.sub.2 with potassium metaborate in the presence of an excess of potassium ions.

Abstract: A novel method for synthesizing pentafluorotellurium hypofluorite by effecting a reaction between B(OTeF.sub.5).sub.3 and elemental fluorine.

Abstract: A boron nitride type compound of the formula: LiMBN.sub.2 where M is calcium or barium and other similar compounds are provided. These compounds are prepared by heating a mixture of (i) finely divided Li.sub.3 N or metallic lithium, (ii) finely divided alkaline earth metal nitride selected from Ca.sub.3 N.sub.2, Mg.sub.3 N.sub.2, Sr.sub.3 N.sub.2, Ba.sub.3 N.sub.2 and Be.sub.3 N.sub.2, and/or an alkaline earth metal selected from Ca, Mg, Sr, Ba and Be, and (iii) hexagonal boron nitride at 800.degree. to 1,300.degree. C. in an inert gas or ammonia atmosphere thereby to react the ingredients (i), (ii) and (iii) with each other in a molten state, and then, cooling the reaction product to be solidified. The above-mentioned compounds are useful as a catalyst for use in the production of cubic boron nitride from hexagonal boron nitride.

Abstract: Tungsten is recovered from alkaline brines by: (1) initial loading of metal values on an 8-hydroxyquinoline-resorcinol-formaldehyde resin, (2) selective desorption of boron, arsenic and sulfur from the resin by means of an NH.sub.4 Cl--NH.sub.4 OH solution having a pH of about 7.5 to 9.5, and (3) desorption of tungsten from the resin by means of water or an alkaline solution.

Abstract: An ionized gas plasma is established in an electrical field in contact with a non-vapor volume monomer (liquid and/or solid). The plasma causes polymerization of the monomers which are of the phosphazene or carborane type.

Abstract: An isotope separation apparatus comprises a plurality of independent developing units, each comprising 2 to 20 adsorbent-packed columns forming a continuous developing circuit or passageway, and the developing units are connected to at least one common main pipe for supplying an isotope mixture solution, a regenerating agent solution, or an eluent solution. Also, in a further embodiment the developing units are connected to common liquid-discharge main pipes.The separation or concentration of isotopes such as uranium isotopes, nitrogen isotopes, boron isotopes, etc., is performed by continuously developing the isotope mixture solution passed through the individual adsorbent-packed columns successively in each developing units.

Abstract: This invention relates to a novel hard material which may be used as an abrasive and a method of making the material. The material consists essentially of B.sub.x C.sub.y N.sub.z, wherein x, y and z can have any value greater than 1, in tetrahedral form. The preferred material is BCN. The material is made by subjecting an appropriate source of boron, nitrogen and carbon to conditions of temperature and pressure sufficient to produce the material. The preferred method is to subject boron carbonitride in hexagonal or amorphous form in the presence of an appropriate solvent for the substance such as an aluminium/iron alloy to a pressure exceeding 50 kilobars and simultaneously a temperature exceeding 1300.degree. C.

Abstract: Sulfur tetrachloride derivatives are prepared by reacting suitable sulfur-containing compounds in hydrogen fluoride with a gas containing molecular chlorine in the presence of one or more acidic halides. Such derivatives can be used to remove water from its solutions in hydrogen fluoride.

Abstract: The compound NF.sub.4 MF.sub.6 where M is a Group V metalloid is reacted with a fluoride of sodium to yield tetrafluorammonium bifluoride in solution with hydrogen fluoride and a precipitate of the formula NaMF.sub.6. The preferred metaloid is antimony. The formed tetrafluorammonium bifluoride may be converted to NF.sub.4 BF.sub.4 by reaction with BF.sub.3.

Abstract: Dry calcium fluoborate suitable for use in the manufacture of boron trifluoride is produced by reacting, in an aqueous medium, calcium fluoride, hydrofluoric acid and boric acid followed by removing water from the calcium fluoborate reaction product by purging the reaction product with a dry inert gas such as nitrogen, at a temperature between about 140.degree. to 160.degree. C.

Abstract: SbF.sub.5 is heated in the presence of an excess of NF.sub.3 and F.sub.2 to 250.degree. C until conversion of the SbF.sub.5 to NF.sub.4 SbF.sub.6 is complete. The NF.sub.4 SbF.sub.6 may be used itself or may be combined, in 0-15 mol % excess, with CsBF.sub.4 in anhydrous HF to produce NF.sub.4 BF.sub.4.

Abstract: Process for the preparation of a concentrated tetrafluoroboric acid from boron/oxygen compounds and hydrogen fluoride by reacting a solid boron/oxygen compound with a hydrogen fluoride-containing gas.

Abstract: Boron or uranium isotopes can be chemically separated and enriched with high speed and with high separating efficiency by using weakly basic anion exchange fibers having a diameter of not more than 100 .mu., an aspect ratio of at least 5 and an exchange capacity of at least 2 meq/g-dry fiber, which are packed in a column at a specific volume of 2.0 - 20.0 ml/g-dry fiber.

Abstract: A process for removing boron contaminant from magnesium halide-containing brine wherein the brine is contacted with active magnesia to precipitate boron-containing magnesium hydrate and to remove at least 50%, and up to at least 95%, by weight of the total boron content of the untreated brine, without reduction of the magnesium halide content of said brine. The active magnesia is employed in an amount of from about 0.1% to about 10% by weight, preferably from about 2% to about 6% by weight, of the untreated brine, which may be heated e.g., from about 140.degree. F to the boiling point thereof, prior to contact with said active magnesia. Subsequently, the treated brine can be used, by reacting it with dolime, to form magnesium hydroxide which, in turn, can be calcined to produce MgO, each of which is a high-purity-low-boron product, i.e., less than 150 ppm boron on an oxide basis, and preferably less than 75 ppm. In addition, the MgO will contain less than 1.

Abstract: A flexible electromagnetic shield is provided. The shield comprises interlaced filaments of at least one glassy metal alloy. The glassy alloy has a maximum permeability of at least about 50,000 and a coercivity of less than about 0.08 Oe.

Abstract: A method for maintaining a desired boric acid concentration in an aqueous stream by mixing a selected quantity of the aqueous stream with an aqueous solution containing an alkali metal hydroxide in an amount stoichiometrically equal to the amount of boric acid which would be present in the selected quantity of the aqueous stream at the desired boric acid concentration and thereafter determining the pH of the solution and adjusting the boric acid concentration in the aqueous stream in response to the pH determination.

Abstract: A method of simultaneously obtaining separate enriched fractions of heavier and lighter isotopes from mixtures thereof with the use of an ion exchange resin column by passing a ligand body containing this isotope mixture through the column. The isotopes, as they are passed through the column, are present in the forms of ligand-containing coordination compounds having different valence states and are followed by an eluant and form a band which travels through the column, the front and rear portions of which are respectively enriched in one of the isotopes and depleted in the other.

Abstract: Minute amounts of boron present in naturally occurring brines found in oceans, inland seas, salt lakes and the like are removed by treating the brine with an oxide of aluminum.