Abstract: Provided is a process for manufacturing a Fluid Catalytic Cracking catalyst additive composition with a novel binder. The steps involve mixing an alumina source with water to make a slurry; adding to the alumina slurry an amount of P2O5 source; the slurry is then stirred and reacted under controlled temperature and time conditions to form an aluminum phosphate binder; adding to the aluminum phosphate binder a zeolite, an amount of silica binder and an amount of clay; and spray-drying the slurry to form catalyst additive particles. The catalyst additive composition comprises a about 35 wt % to about 65 wt % zeolite; about 0 wt % to about 10 wt % silica; about 15 wt % to about 50 wt % clay and an aluminum phosphate binder comprising about 2.5 wt % to 5 wt % amorphous or pseudo-boehmite alumina and about 7 wt % to 15 wt % phosphoric acid.

Abstract: Described is a method for the culture of microalgae, comprising: providing a consortium of at least two living species of microalgae; culturing under illumination the consortium in a controllable bioreactor and under non-sterile aqueous culture conditions; and controlling the culture conditions for affecting at least one of the following output: (i) flocculation and/or settling of said consortium of microalgae; and (ii) adhesion of the microalgae to surfaces of the bioreactor; wherein said culture conditions are controlled to promote (i) and/or to minimize (ii), without adversely affecting growth of the consortium of microalgae. It is also possible to control the culture conditions for affecting iii) the protein, carbohydrate, and/or fat content of the said microalgae consortium. A system for carrying out the method is also described.

Abstract: Dermal delivery compositions are provided. Aspects of the dermal delivery compositions include the presence of active agent-calcium phosphate particle complexes, where these complexes include uniform, rigid, spherical nanoporous calcium phosphate particles associated with one or more active agents. Also provided are methods of using the compositions in active agent delivery applications.

Abstract: Calcium peroxyphosphate compounds and dental compositions comprising these compounds that combine both whitening/stain removal of teeth with remineralization are disclosed. The calcium peroxyphosphate compounds are capable of releasing, in an aqueous environment, whitening and remineralization effective amounts of calcium ion, phosphate ion, and active oxygen. Preferred compounds are calcium peroxymonophosphate or calcium diperoxymonophosphate compounds. These compounds may be used in humans and other animals, including other mammals.

Abstract: Colorless dental compositions for restoring the enamel layer of a tooth are disclosed. The colorless enamel compositions are combined with pigmented dentin compositions to provide a true color match and natural esthetics. Methods that utilize the compositions in placement/build-up techniques in direct restorations are also disclosed.

Abstract: A method for preparing nanoscale hydroxyapatite particles by combining an amount of a calcium ion source, which includes calcium acetate, and an amount of a phosphate ion source, wherein the amounts are sufficient to produce nanoscale hydroxyapatite particles and the amounts are combined under ambient conditions to produce the hydroxyapatite particles. Nanoscale hydroxyapatite particles are also presented.

Abstract: The invention generally relates to methods of selectively removing lithium from various liquids, methods of producing high purity lithium carbonate, methods of producing high purity lithium hydroxide, and methods of regenerating resin.

Abstract: Delayed reaction modified disodium dihydrogen diphosphate (SAPP), the preparation thereof and the use thereof as a leavening acid for the production of baked goods. The process for the preparation of the modified disodium dihydrogen diphosphate (SAPP), includes adding an aqueous solution containing at least one of sodium hydroxide and sodium carbonate to an aqueous phosphoric acid solution containing at least one compound of magnesium, calcium, potassium, aluminium the total amount of magnesium plus calcium plus potassium plus aluminium being at least 300 ppm, to obtain an aqueous solution product and dewatering the aqueous solution product at a temperature in the range of from 190 to 250° C. to obtain a modified disodium dihydrogen diphosphate product having an orthophosphate content, measured as P2O5, of <5.0 wt. %.

Abstract: Brushite (DCPD, dicalcium phosphate dihydrate, CaHPO4-2HH2O) and octacaicium phosphate (OCP, Ca8(HPO4)2(PO4)4-5H2O) granules in the millimetre size range were prepared by using calcium carbonate granules of marble-origin as the starting material. The method of the invention comprised of soaking the marble granules in aqueous solutions containing phosphate and/or calcium ions at temperatures between 20° and 75° C. The load-bearing DCPD and OCP granules of this invention are useful in maxillofacial and orthopedic void/bone defect filiing and grafting applications.

Abstract: Iron(III) orthophosphate of the general formula FePO4×nH2O (n?2.5), prepared by a process in which iron(II)-, iron(III)- or mixed iron(II, III) compounds selected from among hydroxides, oxides, oxidehydroxides, oxide hydrates, carbonates and hydroxidecarbonates are reacted with phosphoric acid having a concentration in the range from 5% to 50%, any iron(II) present after the reaction is converted into iron(III) by addition of an oxidant and solid iron(III) orthophosphate is separated off from the reaction mixture.

Abstract: Methods for the synthesis of tricalcium phosphates are presented, as well as a series of specific reaction parameters that can be adjusted to tailor, in specific ways, properties in the tricalcium phosphate precursor precipitate. Particulate tricalcium phosphate compositions having an average crystal size of about 250 nm or less are provided. Compositions of the invention can be used as prosthetic implants and coatings for prosthetic implants.

Abstract: The present invention provides a method of crystallizing Yb:C-FAP [Yb3+:Ca5(PO4)3F], by dissolving the Yb:C-FAP in an acidic solution, following by neutralizing the solution. The present invention also provides a method of forming crystalline Yb:C-FAP by dissolving the component ingredients in an acidic solution, followed by forming a supersaturated solution.

Abstract: Bone graft compositions for repairing bone defects, which are characterized by a chemical composition of cementitious, non-cementitious, highly-resorbable and poorly-resorbable particulate substances, and further characterized by a specific particle size distribution that includes two or more different ranges of particle size, are disclosed. Further disclosed are articles of manufacturing and unit dosage forms containing the bone graft compositions, methods of repairing bone defects utilizing the bone graft compositions, and processes of preparing the same. Also provided are applicators for applying flowable mixtures formed by mixing a dry composition and a liquid carrier, which are particularly useful for preparing and applying bone graft compositions, as well as methods of using same.

Abstract: A method for preparing nanoscale hydroxyapatite particles by combining an amount of a calcium ion source, which includes calcium acetate, and an amount of a phosphate ion source, wherein the amounts are sufficient to produce nanoscale hydroxyapatite particles and the amounts are combined under ambient conditions to produce the hydroxyapatite particles. Nanoscale hydroxyapatite particles are also presented.

Abstract: This study reports in vitro and in vivo properties of fluorapatite (FA)-forming calcium phosphate cements (CPCs). Experimental cements contained from (0 to 3.1) mass % of F, corresponding to presence of FA at levels of approximately (0 to 87) mass %. The crystallinity of the apatitic cement product increased greatly with the FA content. When implanted subcutaneously in rats, the in vivo resorption rate decreased significantly with increasing FA content. The cement with the highest FA content was not resorbed in soft tissue, making it biocompatible and bioinert CPC. These bioinert CPCs are candidates for use in useful applications where slow or no resorption of the implant is required to achieve the desired clinical outcome.

Abstract: Methods for preparing a tricalcium phosphate coarse particle composition are provided. Aspects of the methods include converting an initial tricalcium phosphate particulate composition to hydroxyapatite, sintering the resultant hydroxyapatite to produce a second tricalcium phosphate composition and then mechanically manipulating the second tricalcium phosphate composition to produce a tricalcium phosphate coarse particle composition. The subject methods and compositions produced thereby find use in a variety of applications.

Abstract: A process for preparing a vanadium, phosphorus, and oxygen comprising catalyst precursor for preparing maleic anhydride by heterogeneously catalyzed gas-phase oxidation of a hydrocarbon having at least four carbon atoms, which comprises (a) reacting vanadium pentoxide with 102% to 110% strength phosphoric acid in the presence of isobutanol and optionally of a primary or secondary, noncyclic or cyclic, unbranched or branched, saturated alcohol having 3 to 6 carbon atoms in a temperature range from 80 to 160° C.; (b) isolating the precipitate formed; (c) (i) drying the isolated precipitate down to a residual isobutanol content of less than 5% by weight; (ii) then passing a gas which in addition to one or more inert gases comprises 0.1% to 9% by volume of oxygen through the dried precipitate, directly or after isolation, in the temperature range from 130° C. to 200° C.

Abstract: A material for cement which comprises a calcium salt powder with an inositol phosphate and/or a salt thereof as adsorbed on the surface thereof, the powder having a specific surface area of 60-120 m2/g. A method of producing a material for cement comprises the step of mixing a calcium ion-containing solution adjusted to alkalinity with a phosphate ion-containing solution to produce a precipitate, the step of maturing the precipitate-containing system while maintaining the alkalinity to obtain a calcium salt powder, the step of recovering the calcium salt powder and drying the same, and the step of immersing the dried calcium salt powder in a solution containing an inositol phosphate and/or a salt thereof to cause the inositol phosphate and/or salt thereof to be adsorbed on the surface of the calcium salt powder.

Abstract: The invention generally relates to methods of selectively removing lithium from various liquids, methods of producing high purity lithium carbonate, methods of producing high purity lithium hydroxide, and methods of regenerating resin.

Abstract: A method is provided for making inexpensive synthetic inorganic resins that are stable, mix easily with water and may be conveniently diluted to form an easy-to-use paste for commercial applications. The method uses environmentally friendly techniques to provide improved efficiencies in the commercial production of these resins. The resins are produced by the partial reaction of phosphoric acid with sparsely-soluble oxides, or sparsely-soluble oxide minerals, that are added to the phosphoric acid under controlled conditions. In certain specific embodiments, methods are provided for modifying synthetic inorganic resins so as to produce rapid-setting phosphate cements and ceramics having high flexural strength. Unique synthetic inorganic resin formulations are also disclosed.

Abstract: The invention generally relates to methods of selectively removing lithium from various liquids, methods of producing high purity lithium carbonate, methods of producing high purity lithium hydroxide, and methods of regenerating resin.

Abstract: The invention concerns a process for preparing an additive for polymers, the additive itself and the use of the additive for improving the surface properties of polymers.

Abstract: The present invention provides a crystalline layered zirconium phosphate, which is an ion exchanger particle excellent in heat resistance and chemical resistance, and utilizable as an impurity ion trapping agent for electronic materials, a raw material for antibacterials, a deodorant, a discoloration inhibitor, a rust preventive and the like, and which is also excellent in various processabilities. As a result of exhaustive studies to solve the problems, the present inventor has found a novel layered zirconium phosphate represented by the general formula (1) shown below: Zr1-xHfxHa(PO4)b.nH2O??(1) wherein a and b are positive numbers satisfying 3b?a=4; b is a number satisfying 2<b?2.3; x is a positive number satisfying 0?x<1; and n is a positive number satisfying 0?n?2, and thus has achieved the present invention.

Abstract: Methods for the synthesis of tricalcium phosphates are presented, as well as a series of specific reaction parameters that can be adjusted to tailor, in specific ways, properties in the tricalcium phosphate precursor precipitate. Particulate tricalcium phosphate compositions having an average crystal size of about 250 nm or less are provided. Compositions of the invention can be used as prosthetic implants and coatings for prosthetic implants.

Abstract: A solid free-flowing particulate fertilizer composition is provided, as well as a method of manufacturing same. The composition has low tendency to caking, is easy for storage and manipulation, dissolves rapidly and completely in water, and can be used directly as a fertilizer or serves in the preparation of concentrated aqueous fertilizer compositions comprising otherwise scarcely soluble nutrients.

Abstract: Disclosed and described are multi-component inorganic phosphate formulations of acidic phosphate components and basic oxide/hydroxide components. Also disclosed are high solids, atomizable compositions of same, suitable for spray coating.

Abstract: Solid acid/surface-hydrogen-containing secondary component electrolyte composites, methods of synthesizing such materials, electrochemical device incorporating such materials, and uses of such materials in fuel cells, membrane reactors and hydrogen separations are provided. The stable electrolyte composite material comprises a solid acid component capable of undergoing rotational disorder of oxyanion groups and capable of extended operation at a wide temperature range and a secondary compound with surface hydrogen atoms, which when intimately mixed, results in a composite material with improved conductivity, mechanical and thermal properties, when compared to pure solid acid compound.

Abstract: Zirconium phosphate particles are synthesized by providing a solution of zirconium oxychloride in an aqueous solvent, adding at least one oxygen-containing additive to the solution, the oxygen-containing additive being selected to form a complex with zirconium ions in the solution of zirconium oxychloride and thereby reduce hydration of the zirconium ions, and combining this solution with phosphoric acid or a phosphoric acid salt to obtain zirconium phosphate particles by sol gel precipitation.

Abstract: Disclosed herein are methods directed toward the synthesis of ordered structures of hydroxyapatite and hydroxyapatite derivatives. More specifically, disclosed herein is a method of preparing ordered hydroxyapatite nanorod structures including the steps of suspending calcium and phosphate in a solvent, adjusting the pH to above 5, and heating to a temperature sufficient to support formation of the ordered hydroxyapatite nanorod structures. In some cases, the methods may include ethylenediamine tetraacetic acid or ethylenediamine tetraacetic acid derivatives. Also disclosed are methods that additionally involve a step of coating hydroxyapatite nanorods with a protein or an amphiphile such as a surfactant or polymer.

Abstract: Calcium peroxyphosphate compounds and dental compositions comprising these compounds that combine both whitening/stain removal of teeth with remineralization are disclosed. The calcium peroxyphosphate compounds are capable of releasing, in an aqueous environment, whitening and remineralization effective amounts of calcium ion, phosphate ion, and active oxygen. Preferred compounds are calcium peroxymonophosphate or calcium diperoxymonophosphate compounds. These compounds may be used in humans and other animals, including other mammals.

Abstract: The present invention provides fertilizer compositions comprising calcium and magnesium phosphates together with alkali metal double phosphates, and process for their preparation. The solid composition is freely flowing and well soluble.

Abstract: Zirconium phosphate particles are synthesized by providing a solution of zirconium oxychloride in an aqueous solvent, adding at least one oxygen-containing additive to the solution, the oxygen-containing additive being selected to form a complex with zirconium ions in the solution of zirconium oxychloride and thereby reduce hydration of the zirconium ions, and combining this solution with phosphoric acid or a phosphoric acid salt to obtain zirconium phosphate particles by sol gel precipitation.

Abstract: A process for the production of nanofine metal phosphates including the steps of: preparing a solution containing metal cations, phosphate anions and organic carboxylic acid, and finely spraying the solution in a reactor at a temperature above 100 degrees C. wherein the temperature is selected to vaporize the organic acid, and water if present, to obtain nanofine metal phosphate particles.

Abstract: A method for fabricating a substitute component for bone, including the processes of: provision of a chemical spray including at least three of calcium chloride, hydrogen phosphate, hydrogen carbonate and water to form a combined solution; reaction and precipitation of the combined solution onto a substrate; allowing the precipitated particles to form a porous structure on the substrate; applying substantially isostatic pressure to the porous structure to form a compressed structure; and (optional) providing one or more through-holes in the compressed structure to promote osteoinduction.

Abstract: Among the various aspects of the present invention is a process for making calcium phosphate bodies comprising amorphous calcium phosphate, hydroxyapatite or calcium triphosphate, the bodies themselves and the use of such bodies in any of a variety of applications.

Abstract: A calcium oxide-silica composite biomaterial either in amorphous state or crystalline state having an average pore size, as determined by the BET method, in the range of from 0.8 to 4 nm, wherein the calcium oxide-silica content of the biomaterial is at least 80 wt %, the balance being optionally one or more other materials and wherein the molar ratio of calcium oxide to silica is at least 0.1.

Abstract: A process for producing monobasic potassium phosphate is provided wherein a reaction mixture of phosphoric acid is combined with potassium hydroxide. The resulting product is cooled to allow crystallization of the product. The product is homogenized and spray dried, resulting in a pure free flowing powder of monobasic potassium phosphate (MKP).

Abstract: Zirconium phosphate particles are synthesized by providing a solution of zirconium oxychloride in an aqueous solvent, adding at least one oxygen-containing additive to the solution, the oxygen-containing additive being selected to form a complex with zirconium ions in the solution of zirconium oxychloride and thereby reduce hydration of the zirconium ions, and combining this solution with phosphoric acid or a phosphoric acid salt to obtain zirconium phosphate particles by sol gel precipitation.

Abstract: Zirconium phosphate particles are synthesized by providing a solution of zirconium oxychloride in an aqueous solvent, adding at least one oxygen-containing additive to the solution, the oxygen-containing additive being selected to form a complex with zirconium ions in the solution of zirconium oxychloride and thereby reduce hydration of the zirconium ions, and combining this solution with phosphoric acid or a phosphoric acid salt to obtain zirconium phosphate particles by sol gel precipitation.

Abstract: The present invention relates to a solid phosphoric acid catalyst and a process for conversion of hydrocarbons using a solid phosphoric acid catalyst. The solid phosphoric acid catalyst comprises silicon orthophosphate, and has a silicon orthophosphate to silicon pyrophosphate ratio of at least about 5:1. The total pore volume of the solid phosphoric acid catalyst is at least about 0.17 cm3 per gram of catalyst, of which at least about 0.15 cm3 per gram is contributed by pores with diameter of at least about 10,000 ?.

Abstract: This invention is based on the preparation of new solid acid triphosphates with compositions of the general formula M(IV)(HPO4)(H2PO4)2, where M(IV) is a tetravalent metal or a mixture of tetravalent metals. These compounds are insoluble in water the greater part of most organic solvents. They show a high non-water assisted protonic conductivity (about 0.01-0.04 S/cm at 100° C. and a relative humidity lower than 1%). These compounds can be used as proton conduction separators in electrochemical devices, to operate at low relative humidity values, as for example in different fuel cells, protonic pumps for electrochemical hydrogenation and dehydrogenation of organic compounds, or for hydrogen production from hydrogenated organic compounds by electro-reforming, or also for removing hydrogen from equilibrium reactions. These compounds can also be used in electrochemical sensors, in super capacitors and as acid catalysts in non-aqueous or anhydrous gaseous phases.

Abstract: Methods of making porous calcium phosphate bone replacement materials are discussed.

Abstract: Phosphate rock is reacted with phosphoric acid to produce monobasic calcium phosphate. Monobasic calcium phosphate is reacted with ammonium carbonate to produce ammonium phosphate. Dibasic calcium phosphate is also produced as a by-product when monobasic calcium phosphate reacting with ammonium carbonate. The dibasic calcium phosphate is reacted with sulfuric acid to produce phosphoric acid. The phosphoric acid is used to react with phosphate rock. Ammonium sulfate or ammonium hydroxide may be used instead of ammonium carbonate. Phosphate other than ammonium phosphate can be produced if calcium phosphate is reacted with x-y to produce x-phosphate, where x is lithium, sodium, ammonium or potassium and y is carbonate, bicarbonate hydroxide or sulfate.

Abstract: Compounds of formula (I): and uses of such compounds are described.

Abstract: A new and useful method of simultaneously producing and granulating anhydrous dicalcium phosphate is provided. Such a method entails the reaction of concentrated phosphoric acid with a powdered material of lime and/or calcium carbonate in substantially equal stoichiometric amounts, with subsequent, mixing, drying, milling, and sieving to provide the correct target particle size range for the resultant granulated materials. Such specifically produced granulated anhydrous dicalcium phosphate materials exhibit very high available calcium levels, excellent flow characteristics, and very high capability for compression into tablets. Products including such particularly produced granulated anhydrous dicalcium phosphate materials are also encompassed within this invention.

Abstract: Improved solid acid electrolyte materials, methods of synthesizing such materials, and electrochemical devices incorporating such materials are provided. The stable electrolyte material comprises a solid acid in a eulytine structure capable of undergoing rotational disorder of oxyanion groups and capable of extended operation at elevated temperatures, that is, solid acids having hydrogen bonded anion groups; a superprotonic disordered phase; and capable of operating at temperatures of ˜100° C. and higher.

Abstract: A mechanism and technological process for synthesizing nano-sized crystalline hydroxyapatite.

Abstract: The rod-shaped apatite crystals of the formula Ca5(PO4)3(OH)xFy have the following features a) the length-to-breadth ratio of the crystals is at least ?5 and b) x+y=1, where if x or y?0 the total amount of the crystals is present as a mixture of individual hydroxyapatite crystals and fluoroapatite crystals and/or as mixed crystals, such that, based on the total amount of the crystals, (1?x)·100% of the hydroxide ions present if y=0 are replaced by fluoride ions. The invention furthermore describes dispersions which contain such rod-shaped apatite crystals, and a process for the preparation of the dispersions or of the apatite crystals.

Abstract: A method of manufacturing a powder, by which it is possible to adjust the strength of the obtained powder is provided. The manufacturing method of a powder involves a step of preparing a slurry containing agglomerated particles of a synthetic material which is produced by reacting a first material and a second material under agitation, and a step of drying the slurry to obtain a powder of the synthetic material. The method has a feature that the particle size of the agglomerated particles is adjusted by, in the step of preparing a slurry, controlling agitation power for agitating the slurry. In the step of preparing a slurry, it is preferable that the slurry is initially agitated at a first agitation power, and at the time when the viscosity of the slurry approaches its maximum value, or at the time when the pH value of the slurry reaches the vicinity of the isoelectric point of the synthetic material, the agitation power is lowered from the first agitation power to a second agitation power.

Abstract: Methods for synthesis of nanocrystalline apatites are presented, as well as a series of specific reaction parameters that can be adjusted to tailor, in specific ways, properties in the recovered product. Particulate apatite compositions having average crystal size of less than 150 nm are provided. Products also can have a surface area of at least 40 m2/g and can be of high density. Hydroxy apatite material is investigated in particular detail. Compositions of the invention can be used as prosthetic implants and coatings for prosthetic implants.