Abstract: Thin multilayer signature control films having a large differential between the indices of refraction of adjoining layers are characterized by the use as the low index layer or layers of a material having a high coefficient of extinction and a very low index of refraction. The enhanced differential between the indices of refraction results in signature control materials which, in one embodiment, may be comprised of just a substrate and a coating and, in another embodiment, may be a supported or unsupported multilayer film comprised of as few as three layers that have performance characteristics equal to or exceeding prior art films comprised of 15-30 layers. Both continuous films and pigmented liquid coating compositions for signature control are provided. Improved pigments for liquid coating compositions are comprised of appropriately coated microspheres and microballoons.

Abstract: A coating film having a refractive index of from 1.28 to 1.38 and a contact angle of water of from 90.degree. to 115.degree., adhered on a substrate surface, and prepared by reacting a particular tetraalkylsilicate, a particular fluorine-containing silicon compound, a particular hydroxy-containing compound, and oxalic acid in a particular range of ratios and in the absence of water, and under further specified reaction conditions.

Abstract: A method and an equipment in which a comparatively thick film such as the barrier rib of a plasma display panel is formed by one time of coating process. According to the nozzle coating equipment (10), a coating line (21A) is formed in such a way that, while a coating solution is being discharged from the tip of a nozzle (20) which is provided at the lower end of a liquid vessel (18) filled with the coating solution, the liquid vessel (18) carrying the nozzle (20) is driven in an X-direction relatively to a glass plate (16). Subsequently, the liquid vessel (18) is shifted in a Y-direction to the amount of a pitch P which is smaller than the width of each coating line, whereupon the next coating line (21B) is formed. Thus, a coated surface (22) is formed on the glass plate (16) in such a manner that the adjacent coating lines overlap each other in the widthwise direction thereof in succession.

Abstract: Electrically conductive and infrared-reflecting tin oxide layers with a reduced optical irisation intensity on glass, glass ceramic and enamel are produced in that initially a solution of boron, silicon, tin and optionally phosphorus compounds in water and/or organic solvents is applied and converted pyrolytically into a layer of oxides of these elements, the refractive index of which lies between that of the substrate to be coated and that of the tin oxide layer and on this layer, a tin oxide layer is applied pyrolytically in a known manner.

Abstract: A method of producing a cathode-ray tube (CRT) of anti-static-processed type and further a cathode-ray tube which screens a leakage electric field (VLF band width). The method including the steps of forming a high-refractive transparent conductive layer, a low-refractive smooth transparent layer, and a low-refractive rough transparent layer on a faceplate of the CRT. This triple coat layer serving to reduce the weight of the CRT, minimize the deterioration of the resolution and contrast of images displayed, diminish the reflection of external light, and provide sufficient film strength for practical use.

Abstract: A method of manufacturing a metal oxide coated glass which is a glass substrate bearing a pyrolytically formed coating composed of at least two metal oxides and which has a corrosion resistance at least equal to 5 as determined by Applicants' defined transmission test, the method including contacting a hot glass substrate with a coating precursor material composed of a tin-containing material and a titanium-containing material in the presence of oxygen to form a metal oxide coating composed of at least two metal oxides including tin oxide and titanium oxide on the hot glass substrate by pyrolyzing the coating precursor material as it contacts the hot glass substrate, wherein the titanium-containing material comprises a titanium chelate which is a reaction product of octyleneglycol titanate and acetylacetone.

Abstract: To produce functional vitrous, preferably colored or colloid-dyed layers, a composition produced by hydrolysis and polycondensation of(A) at least on hydrolyzable silane of general formula (I)SiX.sub.4 (I)wherein the radicals X are the same or different and represent hydrolyzable groups or hydroxy groups, or an oligomer derived therefrom, and(B) at least one organosilane of general formula (II)R.sup.1.sub.a R.sup.2.sub.b SiX.sub.(4-a-b) (II)wherein R.sup.1 is a non-hydrolyzable radical, R.sup.

Abstract: Liquid methyltin halide compositions and their use as intermediates in chemical synthesis and as precursors for forming tin oxide coatings on substrates are disclosed.

Abstract: The present invention discloses a method of reducing marking of a heat softened glass sheet which results when portions of the sheet are contacted by glass sheet handling equipment. The portions of the sheet susceptible to marking are sprayed with an inert material having a melting point and decomposition temperature of at least 1200.degree. F. to form a layer that protects the sheet portion against marking from the equipment. In one particular embodiment of the invention, the lower major surface of a glass sheet is sprayed with an aqueous solution of sodium sulfate to form a layer of sodium sulfate along the glass surface which protect against marking of the glass by conveyor rolls.

Abstract: Very thin films of liquid anti-reflection materials are applied to optical substrates to increase effectively visual clarity and visual acuity by reducing reflection light losses, reducing internal reflections and increasing light transmission. The primary properties of the materials which are useful as anti-reflection films are characterized as non-volatile, optically clear liquids having a refractive index less than the refractive index of the optical substrate to which they are applied. Low cost, effective anti-reflection coatings are thus applied to optical substrates, such as eyeglasses, using a single liquid layer of the anti-reflective material.

Abstract: A process for producing a plastic lens is disclosed, which comprises the steps of: providing a primer layer comprising a polyurethane on the surface of a plastic lens substrate; subsequently providing a hard coat layer comprising a silicone resin on the surface of the primer layer; and then providing a single-layer or multi-layer anti-reflection coating on the surface of the hard coat layer by depositing an inorganic material, wherein the polyurethane used for providing the primer layer is a thermosetting polyurethane.

Abstract: A process for producing thin films includes a step of dissolving one or two or more thin film materials into solutions or dispersions that are sprayed respective spray nozzles provided for each component onto a substrate in a high vacuum vessel. The components are deposited on the substrate and then are heated.

Abstract: A planar optical waveguide comprises a substrate 1, a waveguide core layer 2, at least one planar optical element, wherein said planar optical element comprises at least one optically functional interface 3 which is adjacent to a cavity 4, and an overclad layer 5. The cavity enhances the optical characteristics of the planar optical element because of the substantial difference in the refractive index of the cavity as compared to the refractive index of said waveguide core layer.

Abstract: A method for manufacturing a color filter which comprises arranging colorants on a substrate by using inks capable of curing by the application of energy, said method comprising (1) a step of imparting, to the substrate, the inks capable of curing by the application of energy to form colored portions, (2) a step of applying the energy to the substrate to partially cure the colored portions, (3) a step of forming an energy-curable resin layer on the partially cured colored portions, and (4) a step of curing the partially cured colored portions and the resin layer by the application of the energy.

Abstract: An infrared-ray cutoff material having a structure in which tin-doped indium oxide powder (ITO) powder is dispersed in an inorganic or organic matrix. The material can be in the form of a coating on a substrate available by applying a composition comprising ITO powder, a binder (an organic resin and/or a metal alkoxide) and a solvent (an organic solvent, water and/or alcohol) onto the substrate and drying the same. It may also be in the form of a film, a sheet, a fiber or other shape available by forming a composition made by dispersing ITO powder in an organic polymer. The ITO powder should preferably have an x-value of from 0.220 to 0.295 and a y-value of from 0.235 to 0.352 on the xy chromaticity scale, a lattice constant of from 10.110 to 10.160 .ANG., and a minimum cutoff wavelength of up to 1,000 nm. The infrared-ray cutoff material of the present invention is transparent within the visible region and can totally cut off infrared rays of wavelengths ranging from relatively shorter ones.

Abstract: An anti-reflection film is produced on the panel surface of a cathode-ray tube by:(A) preparing a solution for forming an anti-reflection film, which contains water and a metal alkoxide having the formula,M(OR).sub.nwherein M is a metal selected from the group consisting of Si, Ti, Al, Zr, Sn, In, Sb and Zn; R is an alkyl group having 1-10 carbon atoms; n is an integer of from 1 to 8; and when n is not 1, the alkyl groups represented by R may be the same or different,(B) coating the solution for forming an anti-reflection film on the outermost surface of the panel of a cathode-ray tube, and(C) applying an ultraviolet light to the solution for forming an anti-reflection film coated on said surface to cure the solution to form a transparent film with fine roughness.

Abstract: A color filter in accordance with the present invention comprises an activated film layer (2) arranged on a transparent substrate (1), said activated film layer (2) having a color pattern formed thereon by permeating a dye thereinto, and a thin metal film pattern (3) formed on a portion, of said activated film layer (2), which requires the formation of a black mask. Accordingly, the color filter integrated into various display devices such as a liquid crystal display is capable of displaying an image having a high contrast. Further, a method for forming a color filter in accordance with the present invention comprises the steps of forming an activated film layer (2) on a transparent substrate (1); permeating a dye into said activated film layer (2) to form a color pattern; and performing an electroless plating to form said thin metal film pattern (3) which functions as a black mask.

Abstract: Retroreflective sheet material is produced by forming sheet material with closely spaced retroreflective formations on one face and depositing on this face silver and copper atoms having high kinetic energy to provide a reflective metallic deposit comprising a base layer of metallic silver and an overlying layer of metallic copper. An organic protective coating is thereafter applied over the reflective metallic deposit. Light rays passing through the front face of the body enter the retroreflective formations, impinge upon the interface provided by the silver base layer and are retroreflected therefrom. As a result, the sheet material exhibits a bright white appearance in daylight as well as a bright white coloration at night when an incandescent beam impinges thereon.

Abstract: A method of applying a clear glass primer material and then a black glass primer material onto the marginal edge (40) of a vehicular window glass (42), such as a windshield and/or rear window of an automobile, in which a dispenser (38) is employed to discharge a clear primer material in discrete streams or drops and in which a black primer material is conformally coated onto the clear primer material by another dispenser (36). The clear and black primer materials are able to be applied to the window glass in a single pass operation.

Abstract: An apparatus and method for conformally coating an associated generally planar substrate such as vehicle window glass with a coating material includes first (12), second (22), and third (32) coating guns. The first (12) and second (22) coating guns are aimed at opposite sides (42; 44) of the planar substrate and can simultaneously spray a coating thereon. The third coating gun (32) is aimed toward a third side (46), or edge, of the associated substrate. Therefore, the apparatus can simultaneously spray a coating material on target areas on opposite sides and an included edge of a planar substrate such as a vehicle windshield. The third coating gun has an axis which makes an angle .alpha. with a plane containing the substrate to be sprayed. The first and second guns are offset from each other a distance "X", so that overspray from one gun will not foul or coat the other gun.

Abstract: The present invention is directed to a cathode ray tube having a surface with reduced reflectivity and electrical resistivity and to a method for providing such reduced reflectivity and electrical resistivity. In the method of the invention, a solution of a soluble metallic cation moiety and a silane in an organic solvent is provided. The solution is applied to the surface of a cathode ray tube to provide a coating of the silane and the metallic moiety of the metallic compound on the surface. Thereafter, the cathode ray tube is cured at an elevated temperature for a period of time sufficient to convert the metallic cation moiety to a metal oxide in situ and to provide a metallic oxide in a matrix of siloxane.

Abstract: A structure which is effective as an electrical insulator or as a transmitter-receiver of electromagnetic energy is prepared by providing a suitable substrate and covering the substrate with an adhering layer of a low dielectric, high temperature, linear aromatic polyimide.

Abstract: A process for manufacturing a substrate (12) used in a device (10) for containing a liquid crystal fluid (30) between two spaced electrodes. A plurality of spacers (35) is distributed on a first surface of a substrate by coating the first surface with an admixture of spacers dispersed in a liquid (36). The admixture is agitated during the applications step in order to maintain a uniform dispersion of the spacers in the liquid. The liquid is then evaporated from the substrate surface, leaving a plurality of spacers distributed on the substrate. Preferably, an ester alcohol dispersant is employed in the admixture in order to facilitate dispersion of the spacers in the liquid. Ultrasonics are preferred as the means of agitating the admixture during application. Ultrasonic energy can also be applied to the substrate during application of the admixture to the substrate. Ultrasonic energy can also be applied to the admixture at the point of application (44) of the admixture onto the substrate.

Abstract: Glazing article comprises a substrate bearing a substantially transparent coating comprising an optically functional layer and a thinner anti-iridescence layer undercoat mediate the optically functional layer and the substrate. The anti-iridescence layer eliminates or substantially reduces iridescence and, in addition, is readily designed to make the overall coating colorless or to provide a substantially uniform, muted color. The anti-iridescence layer comprises a high refractive index zone on the substrate, having a refractive index higher than that of the substrate. Multiple gradient step zones are stacked on the high refractive index zone, including a low refractive index zone. A second gradient step zone having a refractive index higher than that of the first gradient step zone is positioned on the low refractive index zone, such that the low refractive index zone is directly sandwiched between the two higher refractive index zones.

Abstract: In accordance with the present invention, there are provided coating liquids for forming conductive coatings, which comprise (i) a zirconium oxysalt, (ii) a conductive substance and, if necessary, (iii) at least one member selected from non-sedimentary silica dispersion and silicon alkoxide or its derivative. The coating liquids, when coated on substrates, form thereon transparent conductive coatings which are excellent in transparency, scratch resistance, permanence properties and adhesion to the substrates and, moreover, excellent in antistatic effect. In particular, when the coating liquids for forming conductive coatings mentioned above are coated by the spray method on appropriate substrates followed by drying and/or heating, there are obtained face plates for display devices, which have excellent regular reflection reducing effect (non-glare) and antistatic effect.

Abstract: This invention is directed to a process for forming coatings comprising light metal fluorides on a substrate. More particularly, the coating comprising light metal fluorides is preferably made using sol-gel techniques and may comprise a concentration gradient of the light metal fluorides across the thickness of the coating to provide it with unique anti-reflective properties.

Abstract: There is disclosed a method of producing a transparent zinc oxide film having an even thickness especially useful as a ultraviolet rays cut off. The method comprises applying a solution of an organic zinc compound selected from the group consisting of a zinc salt of a fatty acid of 3-7 carbons and a chelate compound of a diketone of 5-8 carbons in an organic solution on a substrate, and then baking the resultant coating at temperatures of 300.degree.-600.degree. C. It is preferred that the solution of an organic zinc compound further contains at least one organometallic compound of a metal selected from the group consisting of aluminum, indium, tin and titanium.

Abstract: For coating the glass edge of two wall elements (2, 3) forming interspace (5) for heat insulating structural and/or light element (1), metallic adhesive layer (4) is produced with the use of a physical (PVD) or chemical (CVD) deposition of the coating material from a gas or vapor phase on one side of each wall element (2, 3). On this adhesive layer (4) barrier layer (6) protecting the latter is deposited and the barrier layer is provided with subsequent solder layer (7). These solder layers (7) are bonded with sheet (8) that edges structural and/or light element (1) on the edge in a gastight manner.

Abstract: A pyrolitic deposition process, for pyrolitic deposition of organo-cupric powder to form copper oxide film, is improved. A substrate is heated, and organocupric powder is sprayed at the substrate, using oxygen gas as the carrier gas. Up to one-third greater deposition rate results, as compared to the process using compressed air as the carrier gas.

Abstract: A reactive precursor, for depositing a magnesium fluoride film on glass by a spray pyrolysis or chemical vapor deposition process, comprises magnesium acetylacetonate, trifluoroacetic acid, and optionally a solvent.

Abstract: Process for the storage of information in an organic recording layer which, as the result of local treatment of its surface with an organic solvent in accordance with the shape of the information to be marked can alter its absorption spectrum and/or its photoconductivity in such a way that information is produced and stored respectively at the treated areas of this layer. The information thus stored can be read off visually, by means of a micro-reader or by means of an incorporated electrode system.

Abstract: Chromium acetyl acetonate is added to a zinc acetate-containing reactant mixture, to improve the chemical durability of a zinc oxide layer deposited on a glass substrate by the spray pyrolysis process.

Abstract: The invention relates to the application of a releasing agent to a surface of a glass plate which is to be subsequently bent in a heated state together with another glass plate thereon. The glass plate is held in a standing posture, and hot air is blown perpendicularly against a surface of the glass plate, and simultaneously an aqueous solution of a releasing agent is sprayed from a plurality of spray nozzles into a space in front of the glass plate surface such that the sprayed solution mixes with the hot air before arriving at the glass plate surface. In an embodiment the spray nozzles are directed parallel to the glass plate or obliquely so as to make a small acute angle with the glass plate and arranged such that the hot air forces droplets of the sprayed solution to move toward the glass plate surface together with the hot air. In another embodiment the spray nozzles are directed perpendicularly toward the glass plate and arranged such that the sprayed solution soon mixes with the hot air.

Abstract: Cobaltous acetyl acetonate is added to a zinc acetate-containing reactant mixture, to accelerate the growth rate of a zinc oxide layer deposited on a glass substrate by the spray pyrolysis process.

Abstract: A method of treating a painted vehicle or glass to form a film which protects the surface and can be easily cleaned. A treatment solution including a surfactant mixed with water is rubbed into sections of the surface being protected until a tacky residue forms on the surface. The tacky residue is then rubbed into the surface until the surface is wiped free of any streaks.

Abstract: A method of forming a film of metal fluoride in which there is combined a metallo-organic compound solvent solution and an organic fluoride to form a casting liquid. The casting liquid is then coated by a method such as dip coating or spin coating to form a coating on a substrate. The coated substrate is then heated to decompose the metallo-organic compound and organic fluoride resulting in recovery of a metal fluoride coated substrate. The metal fluorides formed may be fluorides of lithium, sodium, potassium, magnesium, calcium, strontium, or barium, lanthanum, yttrium, or the oxifluoride of europium, erbium and other rare earths.

Abstract: This invention relates to a method for forming a transparent conductive metal oxide film having good characteristic properties. The method comprises feeding an atomized or gasified starting material onto a substrate to form a metal oxide film on the substrate, wherein the substrate is heated to form a first metal oxide film having a good degree of orientation of crystals and a second film formation step wherein a second metal oxide film is formed on the first metal oxide film under higher substrate temperature conditions than those in the first film formation step to form a second metal oxide film having a degree of orientation of crystals in conformity with that of the first metal oxide film.

Abstract: A polyurethane film of excellent optical quality is prepared by applying to a substrate, by reactive casting or reactive spraying, a reaction mixture of an isocyanate component and a polyol component containing at least one long difunctional polyol having a molecular weight between 500 to 10,000, containing at least partial ethylene oxide segments, with the percentage by weight of ethylene oxide segments relative to the total weight of the polyurethane being greater than 20%, at least one short diol as chain extender, with the ratio of free NCO groups of the isocyanate component to free OH groups of the polyol component being between 1.5 and 2; and contacting a surface of said applied material intended to face toward the outside of the safety glass with a surface treatment compound of an acrylic derivative or isocyanate having a functionality greater than 2.

Abstract: An antistatic, glare-reducing coating, as for the surface of the viewing surface of a CRT is prepared by (a) warming a glass support surface above room temperature, (b) coating a surface of the warm support with an aqueous solution containing a lithium-stabilized silica sol and an inorganic metallic compound, and drying the deposited coating, (c) heating the glass support surface and the coating to a temperature of about 65.degree. C. for about 30 seconds, and (d) washing and then drying the coating.

Abstract: A liquid preparation for the production of electrically conductive and infrared-reflecting, fluorine-doped tin oxide layers on glass or glass-ceramic surfaces is disclosed. The preparation has a content of tin-IV-chlorides, which optionally comprise organic groups. The preparation contains also tin-II-fluoride as the sole doping agent. A preferred preparation comprises30 to 89% by weight of tin-IV chloride, optionally having organic groups,1 to 5% by weight of tin-II fluoride,10 to 55% by weight of a polar organic solvent and0 to 10% by weight of water.The inventive preparation is procedurally simple to handle and contains no chemically aggressive or toxic compounds. The components of the preparation are easily accessible, cognate and inexpensive chemicals, yet permit high-grade surface layers to be produced on glass or glass-ceramic. A method for forming the layers is also disclosed.

Abstract: A liquid preparation for the production of electrically conductive and infrared-reflecting, fluorine-doped tin oxide layers on glass or glass-ceramic surfaces is disclosed. The preparation has a content of tin-IV-chlorides, which optionally comprise organic groups. The preparation is produced by dissolving27.5% to 89.5% by weight of tin-IV chlorides, with or without organic groups0.5 to 5.0% by weight of tin-II fluorosilicate in the form of a 30 to 50% by weight aqueous solution10 to 67.5% by weight of a polar organic solventand optionally filtering off the precipitated silicic acid.The inventive preparations are procedurally easy to handle. Their active components are easily accessible and inexpensive chemicals. They permit surface layers with a particularly low surface resistance to be produced on glass or glass-ceramic substrate surfaces.

Abstract: Transition metal nitrates such as nickel nitrate are dissolved in monoalcohols having from 1 to 5 carbon atoms. The coatings are applied to a substrate material and fired to convert the coating to an electrochromically active state.

Abstract: The invention relates to the production of transparent electric conductors.According to the invention, a doped tin oxide layer formed by CVD is heat-treated to improve its conductivity.

Abstract: A method for selecting preferred coating reactants by thermal analysis of decomposition is disclosed along with a preferred coating reactant comprising dibutyltin difluoride in polymolecular form.

Abstract: A method for producing a sheet or film of a transparent synthetic resin, which comprises discharging onto a continuous substrate moving in one direction a synthetic resin material for the transparent synthetic resin from a discharge die having a linear outlet extending perpendicular to the moving direction of the substrate, casting and curing or solidifying the resin material on the substrate to form a sheet or film of the transparent synthetic resin, wherein the discharge die is continuously or intermittently reciprocated in a direction substantially perpendicular to the moving direction of the substrate.

Abstract: The invention relates to coating a heated substrate, particularly glass, by a process according to which a distribution nozzle ending in a slot, sprays a gas stream mixed with a pulverulent or powder product, which decomposes in heat, onto a heated substrate for contact therewith to form a thin coating layer thereupon. The coating zone in the vicinity of the main stream of gas-entrained powder coming from the nozzle is cooled to prevent premature decomposition and to directly remove pulverulent products not immediately deposited upon the substrate. Also, a device for carrying out the novel process is disclosed herein. The invention makes it possible to produce a coated glass substrate which is essentially free of the problem of coating fogging.

Abstract: An anti-fogging and anti-wetting composition for coating at least one surface of an optically clear substrate, in particular, an automobile windshield, and comprising an isoparaffinic hydrocarbon solvent, an alkane selected from the group consisting of isobutane, N-butane, and propane, a hydrocarbon wax, and water. A process for treating the surface of an optically clear substrate with an anti-fogging and anti-wetting composition, which is applied from a pressurized container in aerosol form, to provide a transparent layer of wax on the surface of the substrate.

Abstract: A process for the preparation of continuous polycrystalline diamond films which comprises applying to a substrate diamond powder in an amount of from about one particle per ten square microns to about 10 particles per square micron with an average particle diameter of from about 0.1 to about 0.4 micron; heating the resulting powdered substrate subsequent to incorporation in a processing apparatus; introducing a mixture of gases into the chamber, which gases provide a supply of carbon and hydrogen; and decomposing the gas mixture.

Abstract: In order to prevent an evil caused by flying insects, an insect attraction protectant containing a light shielding agent which absorbs the light ranging from 200 to 500 nm in wave length is used to coat a transparent portion of a window glass and the like.Further, the above insect attraction protectant comprises a transparent synthetic resin such as an acrylic resin, or the like.The light shielding agent comprises an ultraviolet ray absorbent, a mixture of the ultraviolet ray absorbent and a dye, or a dye only.

Abstract: The present invention provides layered polymeric devices to control the sial and spectral distribution of energy in optical beams, particularly high-intensity laser beams. These devices include improved versions of prior art thin-film (vacuum-deposited) interference filters, rugate structure anti-reflection coatings, Q-switches, pulse shapers, modulators, optical bistable devices and the like.