Abstract: In the formation of a metal or metal compound coating on a face of a heated glass substrate during its displacement in a downstream direction through a coating station at which the said face is contacted with at least one downwardly inclined stream of droplets comprising a substance or substances from which said coating is formed, there is a problem in achieving coatings of homogeneous structure and in providing uniform coverage of the substrate. To help reduce these problems each droplet stream delivered by spray guns 9 is inclined downwardly towards the substrate 4 in the upstream or downstream 6 direction, and one or more counter-currents of gas is or are caused to flow adjacent the substrate path from ducts 15, 16 and towards the front of each droplet stream, (the front being where the droplets have the longest trajectories), and suction force is exerted in exhaust ducting 13, 14 whose entrance is located for drawing gases away from the front of the droplet streams at a higher level.

Abstract: In the formation of a metal or metal compound coating on a face of a heated glass substrate during its forward displacement along a tunnel by contacting the substrate at a coating station in the tunnel with at least one stream of droplets comprising one or more substances from which said coating is formed, and simultaneously exerting suction forces in exhaust ducting to draw environmental gases away from that station, the coating may sometimes be spoiled by side reactions or by the spurious deposition of substances from the atmosphere within the tunnel. To help reduce this spoiling, the exhaust ducting comprises at least one exhaust duct (12) whose entrance is located in said tunnel (1) forwardly or rearwardly of the coating station and which forms or is associated with a barrier wall (16) located so as to prevent gases from passing over said duct, towards and into contact with the droplet stream(s) (9, 10).

Abstract: An electrochromic display cell comprises two opposing glass substrates, transparent electrodes formed on the glass substrates, electrochromic layers formed on the transparent electrodes, and a liquid electrolyte disposed in the cell. The electrochromic layer is formed in the following manner. A metal compound such as tungsten chloride (WCl.sub.6) is dissolved in an organic solvent such as an alcohol to obtain an organic solution including hydroxide (W(OH).sub.6). The organic solution is painted on the transparent electrode and, then calcined to obtain the electrochromic layer including tungsten oxide (WO.sub.3).

Abstract: A method is disclosed for depositing a coating from a turbulent gaseous stream of a powder coating reactant delivered to a substrate surface through a slot-shaped nozzle.

Abstract: A surface coating composition comprising:(A) 100 parts by weight of a partially hydrolyzed condensation product of alkyltrialkoxysilane having the general formulaR.sup.1 Si(OR.sup.2).sub.3in which R.sup.1 represents an aliphatic hydrocarbon group of C.sub.1 -C.sub.4 or an aromatic hydrocarbon group, and R.sup.2 represents an aliphatic hydrocarbon group of C.sub.1 -C.sub.4 ;(B) 10-100 parts by weight of an organic carboxylic acid of C.sub.1 -C.sub.5 ; and(C) 0.01-1.0 part by weight of an anionic surface active agent containing a fluorocarbon chain.

Abstract: In the formation of a metal or metal compound coating on a face of a heated glass substrate during its forward displacement through a coating station by contacting the substrate with at least one stream of droplets comprising a substance or substances from which said coating is formed there is a problem in achieving coatings of high uniform quality.In order to help meet this problem, the droplet stream(s) 23 from spray gun(s) 20 is or are inclined downwardly and forwardly (6) or downwardly and rearwardly towards the substrate 4 and at least one jet of gas is discharged (from nozzle 22) into the environment above the substrate so that it travels in the same (forward or rearward) direction above the substrate 4 and impinges against such droplet stream(s) 23.

Abstract: A method and apparatus are disclosed for producing a film on a substrate surface from a cloud of dust-sized particles of a coating reactant.

Abstract: An improvement in a method of coating a glass plate surface with a heat-reflecting titanium oxide film, which may optionally comprise other metal oxide(s), by spraying a solution of a thermally decomposable organic titanium compound in an organic solvent onto a sufficiently heated glass plate. As the improvement, the absolute humidity of the spraying atmosphere is maintained below about 0.008 kg H.sub.2 O/kg dry gas, whereby the resultant oxide film is practically free from tiny, opaque spots which are liable to appear in the product of conventional methods and exhibits improved resistance to chemical attacks.

Abstract: A shatter-resistant mirror article and method for making same is disclosed wherein the back side of the mirror article is spray coated with two successive layers of a rubber adhesive composition with subsequent heat treatment steps wherein the mirror and layers are dried from the back side of the mirror outwardly to eliminate moisture and mirror defects and enhance adherence and shatter resistance.

Abstract: Pyrolytic deposition of a durable, uniform, electrically nonconductive solar energy reflecting spinel-type film from an aqueous solution of a water soluble cobalt salt and a water soluble tin compound is disclosed.

Abstract: This invention relates to making continuous ribbons of clear, flexible interlayer material into a maximum number of interlayers having a coating of graded intensity along a longitudinal edge portion thereof for use in curved laminated safety glass windshields. The method avoids rubbing or differentially stretching the flexible interlayer material during processing, which includes cutting a continuous ribbon of clear, flexible interlayer material into successive interfitting flexible sheets of trapezoidal shape, applying a shade band, preferably by electrostatic spraying, to a predetermined portion of each sheet and laminating the sheet so treated to one or more rigid transparent sheets of glass or a recognized plastic substitute for glass.

Abstract: A mixture of carboxylate and diketonate coating reactants is disclosed to form a metal oxide film with essentially the same reflectance and transmittance properties as a metal oxide film formed from diketonate coating reactants alone, while providing improvement in the control of defects in the film.

Abstract: This invention provides a composition for coating plastics articles comprising (A) a hydrolyzed product of an organoalkoxysilane represented by the formulaR.sup.1.sub.n Si(OR.sup.2).sub.4-n (I)wherein R.sup.1 is a saturated or unsaturated hydrocarbon residue having 1 to 4 carbon atoms, R.sup.2 is a saturated hydrocarbon residue having 1 to 4 carbon atoms, and n is 0, 1 or 2, (B) an epoxy resin having an epoxy equivalent of about 120 to about 700, and (C) a bicyclic amidine represented by the formula ##STR1## wherein m is 3 or 5, or a salt thereof; a method of coating plastics articles with use of the composition; and plastics articles having a cured coating of the composition.

Abstract: Glass mirrors having improved weathering properties are prepared by an improvement in the process for making the mirrors. The glass surface after it has been cleaned but before it is silvered, is contacted with a solution of lanthanide rare earths in addition to a sensitization solution of tin or palladium. The addition of the rare earths produces a mirror which has increased resistance to delamination of the silver from the glass surface in the presence of water.

Abstract: Disclosed is a process of making a glass article containing a thin surface film antireflective coating made by providing a dispersion containing at least one metalloorganic compound in solution, depositing a thin coating of such dispersion on the glass substrate, heating the film to drive off the solvent and to decompose the organic components, thus forming a glass film from the remaining inorganic oxide components, further heating the glass film layer to cause phase separation thereof, and thereafter etching and leaching such film to dissolve out preferentially one of the phases of the phase-separated glass, leaving a skeletonized surface film having a graded refractive index; and products resulting from such process.

Abstract: Commercially available alkali halide crystals are passivated in a plasma environment and coated by a plasma polymerization process to form moisture resistant alkali halide cyrstals. Prolonged exposure to high humidity did not cause observable damage to the surface of the crystal.

Abstract: Electroconductive tin oxide coatings are deposited by an airless method of spraying a liquid composition of a thermally decomposable tin compound onto a hot glass surface in order to prevent overspray of the liquid coating composition onto the opposite glass surface.

Abstract: The addition of 2-ethyl-1-hexanol to an organometallic titanium compound dissolved in a diluent and optionally containing a lower aliphatic alcohol spreading modifier, produces a solution that can be sprayed onto a substrate and cured to form an antireflection titanium oxide coating having a refractive index of from about 2.0 to 2.2.

Abstract: A coating composition for the pyrolytic deposition of metal oxide films is disclosed comprising an organometallic coating reactant, a high boiling point organic compound which modifies the rate of film formation and decreases the particle size of the metal oxide, and, preferably, a nonflammable halocarbon-containing solvent.

Abstract: A method of applying a metallic oxide coating to a moving ribbon of glass is disclosed for four thicknesses of glass, namely, 7/32; 3/16; 5/32 and 1/8 inch. In each of these methods, first and second spray zones are established at opposite edges of the moving ribbon. The spray zones are moved in a simultaneous manner at the same speed from one edge to the other edge whereby the spray zones pass each other at the center line of the moving ribbon. When each of the spray zones reach the opposite edge of the moving ribbon, their direction of travel is reversed so that they once again pass one another at the center line of the moving ribbon. The first and second spray zones are spaced a slight distance from one another in the direction of movement of the moving ribbon. The moving spray zones are cycled back and forth in the aforedescribed manner continuously as the ribbon of material is moved thereunder so that a coating is applied to the moving ribbon.

Abstract: A mirror construction and method wherein shatter resistant optical quality first surface mirrors may be inexpensively fabricated. A styrene sheet is press polished and the polished surface is coated with a reflective layer. The press polished, reflectively coated styrene sheet may be subjected to further processing steps in order to produce a highly rigid and flat mirror. A surface of the styrene sheet is scored along a straight line to a depth that does not penetrate the front mirrored surface, but rather leaves a relatively thin region along the scored line having a minimal extent in the plane of the sheet. The styrene sheet is then folded, bringing portions on either side of the scored line towards each other and partially splitting the thin region. A membrane remains along the scored line to form a semi-flexing hinge. The ability of the membrane to withstand cracking can be improved somewhat by carrying out the folding step at a temperature generally greater than approximately 20.degree. C.

Abstract: An improved selective absorber on a glass substrate having high solar absorption and low infrared emission. The Selective Absorber on a glass substrate includes an electrically conducting layer of silver metal having a thickness on the order of 0.1 microns, and an absorbing layer of either black nickel or, alternatively, a layer of oxidized iron over a layer of nickel or bright nickel. The method of this invention defines the process of producing the Selective Absorber on a glass substrate by thoroughly cleaning the glass, chemically depositing a thin layer of silver metal over the clean glass surface, then electroplating an absorbing layer over the silver layer. The absorbing layer may be electroplated black nickel or, alternatively, an electroplated layer of nickel or bright nickel, such as cobalt-nickel, and an electroplated cover layer of iron. The glass substate and composite layers are heat treated to thermally cured to improve its optical and properties.

Abstract: Forming a colored shade band on an elongated area of a flexible sheet of interlayer material comprising applying a dye composition by electrostatic spraying against a portion of a surface of a flexible sheet of non-conductive interlayer material such as polyurethane or plasticized polyvinyl butyral. A novel grounded shielding structure of electroconductive material comprises a primary shield located in close proximity to the upper surface of a workpiece to be partially coated. A preferred embodiment comprises primary and secondary shields with an optional manifold between the shields to ensure superior control of a pattern of graded intensity along the transverse dimension of an elongated area to be coated. One or both shields may be heated to avoid the deposit of spray particles that cause optical defects. The workpiece so coated is useful as an interlayer in shaded, bent laminated safety glass windshields.

Abstract: Method of producing photomasks of X-ray amorphous iron oxide (Fe.sub.2 O.sub.3) by spraying a transparent substrate at a temperature between 180.degree. and 250.degree. C. with a solution of an hydrolysable iron salt in a polar organic solution or, in accordance with a variant of this method, at a temperature between 180.degree. and 750.degree. C. with a solution of a hydrolysable iron salt which also contains a salt of a metal having a greater ion diameter. If temperatures above approximately 230.degree. C. are used, the solvent may in the latter case also consist of water only.

Abstract: Potentially explosive mixtures which can form as a result of accidental contact between a concentrated aqueous solution of ammoniacal silver salt and a concentrated solution of a strong alkali are inhibited in an improved multi-part system for electroless deposition of silver on an activated surface by simultaneous admixture of the diluted parts thereupon. Accordingly, an improved method for inhibiting formation of explosive conditions and compounds in a mixture formed by contacting concentrated aqueous ammoniacal silver salt and a concentrated solution of alkali is provided, whereby an effective amount of an explosion inhibitor is provided either in combination with the ammoniacal silver salt, in which case sufficient extraneous ammonium ions are provided to stabilize the explosion inhibitor, or in the strong alkali, or a portion of the explosion inhibitor is provided in each of said ammoniacal silver salt and strong alkali.

Abstract: The surface of a transparent refractory material such as glass or a vitreous ceramic is coated with a semi-reflective film of tin oxide by projecting finely divided particles of a pyrolytically decomposable organotin compound against the surface of the substrate material that has been heated to a temperature of between about 400.degree. and 650.degree. C. The finely divided organotin compound has a particle size of not greater than about 20 microns and is suspended in an anhydrous carrier gas to which carrier gas has been added a gaseous fluoride compound. In an advantageous embodiment of the process the pyrolytically decomposable organotin compound is dibutyl tin oxide, the carrier gas is dry air and the added fluoride compound is dry hydrogen fluoride.

Abstract: A non-glare, abrasion resistant coating can be produced by spraying a polymerizable composition onto a surface. The composition comprises an epoxy prepolymer of an epoxy-terminated silane and an oxirane comonomer in solution. The composition may be conveniently applied from an aerosol can.

Abstract: A glass plate coated with a metal oxide film comprising aluminum oxide and at least one of commonly used metal oxides such as the respective oxides of Cr, Co, Ni, Fe, Zn, Sn, Cu, Mn and Ti, wherein aluminum oxide is used to suppress the lowering of the reflectivity by a heat treatment of the oxide-coated glass. The oxide film is formed by coating the glass with a solution of thermally decomposable compounds exemplified by acetyl acetonates of the respective metals in an organic solvent and heating the coated solution.

Abstract: A continuous flow process is disclosed in which optical fibre is made by a method involving the chemical vapor deposition of material upon the bore of a tube. The tube is fabricated from an annular crucible around a vertical gas feed and is lowered through a hot zone where it is softened and drawn into fibre. The gas deposits one or more layers on the inside of the tube prior to drawing so as to provide the drawn fibre with optical waveguide properties.

Abstract: High efficiency deposition of silver onto substrates is obtained by utilizing admixed compositions comprising reducible silver ions, complexing agent, reducing agent in the presence of a promoter which is a soluble compound of germanium, tin or lead.

Abstract: A method of forming a colored shade band having a relatively wide portion of essentially uniform intensity and a relatively narrow boundary portion of graded intensity by spraying a dye composition along a longitudinally extending edge portion of a non-electroconductive substrate such as a glass sheet or a sheet of plastic. In one embodiment of this invention, the substrate is sprayed to form the graded band and then laminated to a layer of plastic interlayer material to produce a laminated window having a shade band having a desired transverse pattern of graded intensity along a longitudinally extending edge portion thereof.

Abstract: A method and apparatus are provided for silvering glass at higher than normal deposition efficiencies by premixing a silver solution, a caustic solution and a reducing solution and immediately spraying the mixture onto a glass to be coated through a large orifice spray nozzle. The spray nozzle is one which provides an orifice large enough to pass the total volume of mixtures required for silvering through a single opening with a defined spray pattern, preferably in the form of a conical spray.

Abstract: A metal oxide coating is formed on a vitreous or non-vitreous substrate by applying a solution containing at least one metal compound to the substrate and then heating the coated substrate to convert the compound in situ to leave a coating of metal acetyl acetonate or a mixture of metal acetyl acetonates in a solvent including an aprotonic solvent, a substituted or unsubstituted monocarboxylic acid solvent, an amine or diamine solvent, or a mixture of two or more solvents selected from these groups.

Abstract: A method for preparing an electroless gold plating bath comprising a gold salt and a complexing agent is improved by adding the gold salt as a concentrated solution to a concentrated solution of the complexing agent either maintained at or subsequently heated to above ambient temperature in order to eliminate the step of aging the plating bath. The plating efficiency of an electroless gold plating bath comprising a gold salt and an alkali carbonate complexing agent and the quality of the resulting gold film are improved by buffering the bath with an alkali metal bicarbonate thus maintaining a pH between about 8.5 to about 9.5.

Abstract: Uniform gold films having an intense pure gold color and superior abrasion and adhesion properties are prepared by first depositing a gold film on a nonmetallic substrate by a known method, preferably electroless deposition, then depositing a silver film over the gold by electroless deposition.

Abstract: This invention relates to a method of aligning the core of a thin optical fiber with a light emitting optical device. Prior to alignment a thin, continuous high index of refraction layer is formed on a stripped end segment of the optical fiber. The layer is formed by applying a solution of a volatile solvent and high index of refraction polymer to the stripped segment and evaporating the solvent before beading of the polymer solution occurs. The core of the fiber can then be aligned with the light emitting optical device by observing light exit the optical fiber.

Abstract: A surface of an article is coated by moving the article downstream through a linear curtain spray rinse applicator and thereafter through a linear curtain spray coating applicator. The rinse applicator and coating applicator are positioned relative to one another such that the rinsing spray and coating spray intersect at the surface of the article. The rinsing medium is applied as a spray having upstream frontal forces lying in a plane generally parallel to the surface of the article to provide the surface with a uniform thickness of rinsing medium film. The coating medium is applied to the surface of the article having downstream frontal forces lying in a plane generally parallel with the surface of the article to prevent the rinsing medium mixed with the coating medium from moving upstream into the coating spray. In this manner, the surface of the article is more uniformly coated.

Abstract: An optical element is provided having a durable abrasion-resistant, antifog coating applied to at least one surface thereof by coating an optical element comprised of an inorganic or organic transparent base with a transparent abrasion-resistant antifog coating consisting of a lightly cross-linked polyvinyl alcohol, the desired degree of cross-linking being obtained by utilizing a combination of zirconium nitrate and formaldehyde as cross-linking agents.

Abstract: This disclosure depicts a non-settling process for forming on an inner viewing surface of a color cathode ray tube faceplate, a coating of an aqueous slurry composed of an organic binder and a suspension of particulate phosphor material of distributed particle size, which coating exhibits an extraordinarily suppressed radial streaking, a high degree of coating weight uniformity, and a predictable particle size distribution.

Abstract: A method is disclosed for forming a water-based inorganic coating capable of controlling thermal radiation which method comprises applying a layer of a semiconductor pigment upon a highly reflective substrate having a metallic layer and overcoating the pigment layer with a layer of an alkali metal silicate, and heat curing the silicate layer at above ambient temperature, where the two-layer laminate so obtained exhibits high absorbance of visible spectral radiation and low emissivity of thermal radiation.

Abstract: Cyanuric halide is successively reacted with two moles of carboxy substituted aromatic amine and one mole of quaternizing agent such as pyridine and dissolved, e.g., in dilute ammonium hydroxide. At certain concentrations as the solution evaporates, it becomes nematic. The solution is evaporated on an oriented substrate so that the residue is anisotropic and is finally frozen in a resinous form which shows birefringence. The substrate and coating is valuable as a fractional wave plate.

Abstract: Gold films are deposited on non-metallic substrates very rapidly at ambient temperatures by sensitizing and activating a surface of a non-metallic substrate to be coated and subsequently contacting the activated surface with a solution containing a gold salt which is reduced to a metallic gold film in the presence of divalent mercury, cadmium or lead ions.

Abstract: An electrically conductive and optically transparent coating comprising a very thin, noble metal oxide film applied to a nonconductive, transparent substrate, said noble metal selected from the group consisting of ruthenium, rhodium, osmium and iridium. These coatings are useful as resistance heaters for windows, as optically transparent electrodes for electro-optic and electro-chemical applications, for radio frequency shieldings and a wide variety of other applications.

Abstract: Cadmium stannate has been found to be useful as a window for solar heat absorbing systems in which advantage is taken of the unique optical properties of cadmium stannate. When cadmium stannate is in an electrically conductive state, having a conductivity of greater than 10.sup.3 ohm.sup..sup.-1 cm.sup..sup.-1, it becomes transparent to solar radiation and reflective of thermal infrared radiation. This enables the cadmium stannate to function as a window which allows passage of solar radiation through it and incident onto a black body, and at the same time serve as a reflector of thermal infrared radiation emitted from said body. This results in more efficient solar heat transfer to the solar heat collector provided with such a window.

Abstract: A metallic oxide coating is formed on a substrate which may be vitreous, partially vitreous or nonvitreous by applying to the substrate a solution of one or more metallic salts selected from the group of the acetates, halides and nitrates in an aprotic solvent having a dielectric constant greater than 15 and a dipolar moment greater then 3D. The substrate and applied solution are then subjected to heat to convert in situ the metallic salt to form a coating comprising at least one metallic oxide.

Abstract: High efficiency deposition of silver on the surface of a substrate is obtained by providing a solution containing reducible dissolved silver in the presence of an alkali metal hydroxide and ammonia, all of which are applied to the substrate in the presence of an aqueous solution of a moderating reducer containing a polyhydric alcohol of the formula CH.sub.2 OH(CHOH).sub.n CH.sub.2 OH, where n is an integer from 1 to 6. Preferably the polyhydric alcohol is sorbitol, and in a preferred embodiment a moderator is the form of a thio glycerol is present.

Abstract: A striped dichroic filter having a substrate with a surface. A first set of spaced parallel stripes capable of reflecting at least one color are carried by the surface. A second set of spaced parallel stripes capable of reflecting at least one different color different from said one color reflected by the first set of stripes is also carried by the surface. The first and second sets of stripes are disposed so that they are substantially parallel to each other and so that they are in abutting relationship with substantially no space or overlap between adjacent stripes. Third and additional sets of stripes for reflecting other colors may be provided.In the method for making the striped dichroic filter, a dual lift-off is used which utilizes both metal and resist lift-off techniques that are mutually exclusive.

Abstract: Multiple layer films of silver-silver oxide and metal oxide are produced on transparent substrates for purposes of solar energy control and production of architectural colors. Solar control properties and the transmitted and reflected colors of the article can be altered by varying the thicknesses of the films and/or the selection of metal oxide overcoat.The article produced can be used in a viewing closure and as a component in a solar energy collection system.

Abstract: A light-transmitting, thermal-radiation reflecting filter which comprises a transparent support coated with indium oxide which is doped with more than 7 atomic percent of tin, calculated with respect to the number of indium atoms, has a free-electron density between 10.sup.21 and 3 times 10.sup.21 per cm.sup.3 and a plasma wavelength of less than 1.2.mu.m. The filter can be manufactured so as to have a stress-free support by heating a support, which is coated in known manner with tin-doped indium oxide, at a temperature between 300.degree.C and the softening temperature of the support material in a gas having an oxygen partial pressure of less than 10.sup..sup.-7 atmosphere.

Abstract: A glare-reducing coating, as for a viewing surface of a cathode-ray tube, is prepared by (a) warming the surface of a support to about 30.degree. to 100.degree.C, (b) coating the warm surface with an aqueous solution containing a lithium stabilized silica sol, (c) drying the coating, (d) baking the dry coating at about 150.degree. to 450.degree.C, and then (e) subsequent to said heating step (d), washing the dry coating with hot water. The coating may contain carbon particles or carbon particles and a color-correcting dye.