Abstract: Improved techniques are provided for forming a very thin polycrystalline layer of a semiconductor material on a glass substrate. The film material may be formed from a slurry of a semiconductor powder and a liquid carrier, and the slurry economically applied at room temperature by spraying techniques. Once dried, the film is compressed by the application of a substantial mechanical force. The compressed film is regrown in a heated atmosphere, forming a polycrystalline film comprised of large mean diameter crystals, with many crystals having a mean diameter in excess of the film thickness. A high quality cadmium sulfide polycrystalline film suitable for forming a photovoltaic cells may be inexpensively manufactured according to these techniques.

Abstract: In the method, the radio frequency (RF) antenna is made by providing a clean coil made of copper tubing or other metal conductor, which is coated with a tacky organic binder, and then with a powdered glass frit, as by sprinkling the frit uniformly over the binder. The coil is then heated internally in an inert gas atmosphere, preferably by passing an electrical heating current along the coil. Initially, the coil is internally heated to about 200.degree. C. to boil off the water from the binder, and then to about 750.degree. C.-850.degree. C. to melt the glass frit, while also burning off the organic binder. The melted frit forms a molten glass coating on the metal coil, which is then cooled to solidify the glass, so that the metal coil is covered with a thin continuous homogeneous impervious glass coating of substantially uniform thickness.

Abstract: What is disclosed is an improvement in a method for treating the reaction residue from the preparation of organochlorosilanes or chlorosilanes from the reaction of metallic silicon with a chlorinated hydrocarbon or hydrogen chloride, said method comprising combining the reaction residue with water and granulating the mixture of the reaction residue and water, the improvement comprising (A) coating the resulting granules from the granulating of the mixture of the reaction residue and water with an inert inorganic powder.

Abstract: A process for preparing a ceramic substrate for metallization wherein a surface of the ceramic substrate is contacted with a composition containing one or more alkali metal compounds, preferably in the form of solid pellets. The pellets are melted on the ceramic surface. As the pellets melt, advancing waves of the molten composition spread across and wet the ceramic surface. The molten alkali metal composition is kept in contact with the ceramic surface for a time period sufficient to etch the surface and thus prepare it for adherent deposition of metal. The moving waves of melting composition supply fresh alkali metal compounds at the ceramic surface. After adhesion promotion, the ceramic surface is treated with compounds that promote adsorption of catalyst for metal deposition before being plated with metal. Uniform surface coverage with catalyst and metal and an improved adherent bond of metal to the ceramic surface are obtained.

Abstract: A filler material for filling an outlet aperture of a casting ladle or similar container, comprising a particulate core principally composed of quartz and a coating layer which covers a surface of the core, the coating layer having a multiplicity of fine particles principally made of at least one material selected from materials of feldspar group can be surely taken off from the outlet aperture of a casting ladle or other similar container to allow substantially complete opening of the aperture when the slide gate is opened.

Abstract: A method of producing an exhaust valve for a diesel engine comprising the steps of cutting a part of a valve or valve seat body, depositing or spraying onto the cut part a mixture of grains of ceramics and metals, and varying the proportion of grains of ceramics and metals during the deposition or spraying so that the deposited or sprayed layer will vary in content of metal and ceramics with the proportion of ceramics increasing with the increase in height from the valve or seat body of the coated layer, and then subjecting the coating to pressure of 3 to 7 Kg/mm.sup.2 and concurrently heating the coating to 700.degree. to 800.degree. C., thereby to produce a contact surface which forms the contact point between the valve and valve seat which has better adhesion, is close to the body, and has better corrosion resistance, anti-invasion properties, and good thermal shock resistance.

Abstract: The present invention concerns processes for making composite materials.The process is characterized essentially by the fact that it consists in making a fibrous preform 1, in pre-treating this fibrous preform by a fluorine containing flux 3 and in wetting the said pre-treated preform by a light alloy.Utilization for the making of composite pieces with a fibrous armature such as carbon wet by a light aluminum-based alloy.

Abstract: A metal brazing sleeve includes a ceramic flux band formed on the sleeve adjacent an annular recess typically disposed near an open end of the sleeve for receiving a conventional braze preform, by adhering a powder flux to the sleeve by a tacky adhesive and then melting the powder flux in place, by internal heating of the tube. The ceramic flux band is hard and adherent, and resistant to abrasion effects during insertion of the sleeve into a tube, and provides a shadow effect for protecting an optional cemented powder flux band which may be formed on the braze ring.

Abstract: A method of producing a thin film comprising a conductive metal silicide and the products produced therefrom are disclosed. The method is much less complex than methods employed in the prior art for producing conductive thin films and the method reduces substrate damage by maintaining processing temperatures at about 1,000.degree. C. or less. The process employs a stable suspension comprising ultrafine powders in a solvent. This suspension is deposited on a surface of a substrate and is subsequently heated to form a thin conductive film. The thin conductive film comprises polycrystalline metal silicide, preferably a refractory metal silicide, and may also contain silicon. Composites comprising the thin conductive films and a substrate are also disclosed. The process and products are particularly suited for use in VLSI and VVLSI production.

Abstract: A track recording support for recording devices is suggested with a support (10) made of paper or plastic on which a metallic coating (12) is mounted by means of evaporation and being able to be burned off by means of recording electrodes, in particular an aluminum coating. A lubricant in a finely dispersed form is added to contrast coating (11) for reducing of scratching and grinding traces on the surface of metal coating (12) which reaches metal coating (12) and the freely exposed surface thereof by means of diffusion. Preferably, the lubricant is fed to the contrast substance in a powdery form before the processing of the same. On the one hand, it acts in a physical point of view by a reduction of the slide friction on the surface and, on the other hand, in a chemical point of view in that it substantially prevents the build up of combustion residues from the contrast layer on the recording electrodes.

Abstract: An inorganic composition adapted for use in bonding a high temperature resistant polymeric material to an aluminum base substrate is provided. The composition is obtained by reacting a first inorganic compound containing chromium and oxygen with a second inorganic compound containing at least one element selected from the group consisting essentially of calcium, barium and strontium to form a reaction product containing chromium, oxygen and at least one element selected from the group essentially consisting of calcium, barium and strontium. A method of bonding a high temperature resistant polymeric material to an aluminum base substrate using the above composition is also provided.

Abstract: A ceramic shaped body having an improved mechanical strength which is useful for a structural material, such as engine parts, is produced by coating a slip which is substantially the same in the chemical composition as the ceramic shaped body and is very small in the difference of the thermal expansion coefficient at 800.degree. C. from the shaped body, on the surface of the shaped body, drying the coated shaped body, subjecting the thus treated shaped body to a hydrostatic press and firing such a shaped body.

Abstract: An electrically conductive substrate is coated with a material containing an unsintered powder of a metal active for electrochemical proton reduction and colloidal silica and the said material is heated on the substrate successively in an oxidizing atmosphere and then in a reducing atmosphere.The electrode may be employed as a cathode for electrolytic production of hydrogen in an alkaline medium.

Abstract: A coil comprising a carbon filament winding with fused particulate insulative coating therearound and method of producing such carbon filament coil.

Abstract: A process for metallizing the surface of a ceramic is provided. The surface of a ceramic is coated with a mixture of SiO.sub.2 and at least one copper compound selected from the group consisting of copper carbonate, copper sulfate, copper sulfide, copper oxide, and copper chloride. Thereafter, the film is heated at 900.degree. to 1300.degree. C. in an oxidizing atmosphere to form a baked layer on the surface of the ceramic. The ceramic having the baked layer formed thereon is subjected to a reduction treatment to form a copper-metallized layer on the surface of the ceramic.

Abstract: A method of manufacturing a thin layer detector for integrating solid state dosimeters, in particular for thermoluminescence dosimeters (TLD's), from thermoluminescent powder material, comprising the simultaneous application of high pressure and elevated temperature to the powder layer at selected values (working point) sufficient to cause physico-chemical bonding of the layer with a suitably prepared substrate by plastic flow of the powder grains.

Abstract: A method for coating metal with a dissimilar metal which comprises heating a parent metal at a temperature at which substitution of a halide metal for said parent metal occurs or a higher temperature while directly contacting the powdered halide metal with the surface of said parent metal to effect the substitution reaction of said halide metal, then cooling the resulting product, and removing the residue from said product.

Abstract: An oxygen concentration cell having a high peeling resistance of the electrode and an excellent response property can be obtained by a method wherein electrode-adhering particles, which consist essentially of a specifically limited amount of stabilized or partially stabilized zirconia granulated particles having a spherical shape and a particle size of not smaller than 44 .mu.m and a specifically limited amount of stabilized or partially stabilized zirconia fine particles having a particle size of not larger than 10 .mu.m as a sintering aid, are applied and adhered to the surface of a matrix consisting of stabilized or partially stabilized zirconia, the resulting assembly is sintered to form monolithically a large number of convex portions on the matrix surface, an electrode is adhered to the matrix surface having the convex portions monolithically formed thereon, and further a heat-resistant ceramic protecting film is adhered to the electrode film.

Abstract: A wear resistant coating on ceramic or metallic substrates is provided by coating the substrate with a titanium based alloy and then converting the titanium to titanium carbide, titanium nitride, titanium carboxynitride or titanium boride.

Abstract: A method of forming a clinically unbreakable composite structure between a noble based metal and a ceramic comprising depositing a thin layer of a bonding material including finely divided particles of a noble metal halide alone or in combination with particles of a noble metal; sintering the layer at a predetermined temperature between 1775.degree. F. and 1975.degree. F. and firing a ceramic over the sintered coating.

Abstract: A method for forming an anticorrosive coating on the surface of a metal substrate, which comprises, in one embodiment, (1) coating the surface of the metal substrate with an anticorrosive metal capable of forming an alloy with the substrate metal and/or a hydride of the anticorrosive metal; (2) heating the coated surface, and then; (3) heating the coated surface in a vacuum or in an atmosphere substantially inert to the metal coating and the metal substrate by irradiating the coated surface with electron beams, laser beams or a plasma arc to sinter the coated metal and form an alloy layer in the interface between the metal substrate and the metal coating and, in another embodiment, subsequent to Step (2) and prior Step (3) above, coating the coated surface with a solution of a thermally decomposable platinum-group metal compound and then heating the resulting coated surface at about 40.degree. C. to about 600.degree. C.

Abstract: A method of placing a metal oxide film on a surface of a heated glass substrate (16) is disclosed. The glass substrate is one which is being moved in a selected direction from a glass manufacturing process (20) and is one which would have a temperature in a range from 700.degree.-1200.degree. F. (370.degree.-650.degree. C.). The method is accomplished by spraying a heat decomposable, organic based metal salt onto the glass ribbon. The spray powder is delivered by means of a gaseous stream to a location spaced above the moving substrate. The spray powder is then accelerated from the location spaced above the moving glass substrate. The acceleration is accomplished by entraining the spray powder in a high velocity stream of air. The accelerated spray powder is directed downwardly toward the moving glass substrate and longitudinally along the selected direction of movement of the glass substrate.

Abstract: Ethylene/vinyl acetate copolymer film containing 35 to 50 percent copolymerized vinyl acetate by weight is irradiated with 0.5 to 16 megarads of high energy radiation, contacted with an alcoholic solution of a titanate or silane coupling agent, and subsequently contacted with an alcoholic finely divided mineral particulate slurry. The resulting film is elastomeric, heat sealable, transparent upon relaxation after being stretched and free of surface tack.

Abstract: Iron-containing refractory balls, in a retorting process for oil shale, permit effective magnetic separation of the balls from the spent shale. These ceramic balls can be made by a process such as admixing powdered alumina and water to form an extrudable mixture, extruding to form cylinders, reshaping cylinders into balls, overcoating with iron particles, further overcoating with alumina, and firing.

Abstract: The invention is a process for the manufacture of substantially pore-free shaped articles from polycrystalline material, such as tungsten carbide, silicon nitride, titanium boride or silicon carbide, in which encased articles preformed from pulverulent materials and having open pores are isostatically hot-pressed in a vacuum-sealed casing of vitreous or ceramic-like material in a high-pressure autoclave using an inert gas as pressure-transfer medium. Before the application of the casing material, a first layer comprising material that can be decomposed or melted, such as an organic wax or a resin-like product, or of a compressible heat-resistant material such as inorganic fibers or felts, is applied to the preformed articles. Then, the encased articles are thermally treated until the glass or ceramic layer is fused or sintered gas-tight. The articles pretreated in this manner are then isostatically hot-pressed.

Abstract: A ceramic throw-away tip which comprises a hot-pressed sinter of Si.sub.3 N.sub.4 on the surface of which is a thin coating of at least one of Al.sub.2 O.sub.3 and AlON.

Abstract: A method is provided for improving the corrosion resistance of superalloy substrates, such as gas turbine blades, by initially coating the superalloy with an intermediate bonding alloy, followed by plasma spraying the resulting treated surface with cerium oxide or a sprayable blend of cerium oxide and zirconium oxide. The resulting metal oxide-super alloy composite has been found to be resistant to vanadium and sulfur dioxide corrosion.

Abstract: A novel process for fastening ceramic material such as alumina or the like to metallic material such as an electrical conductor. The process is characterized by the fact that a solder wettable, oxidation-resistant barrier is used, on metal particles printed onto the ceramic. In some advantageous processes, the carbide layer allows metallizing processes to be carried out in non-hydrogen atmospheres. The process requires no expensive noble metal; and it utilizes a barrier material which is sufficiently stable to tolerate conductive film formation at high temperatures. Nickel-carbide coated nickel is a particularly favorable material for use in the invention because it is conductive, in the ohmic sense, and is readily wetted by common solders.Also disclosed are novel articles and compositions useful in practice of the process of the invention, and novel articles produced by the process of the invention.

Abstract: Method for hard-facing substrates is disclosed using a hard facing material consisting essentially of at least one vanadium carbide. In a particular embodiment of the invention tungsten is present in the hard facing material in solid solution with vanadium carbide.

Abstract: A stratification mass for the production of top surfacing layers particularly through dipping, painting, filling or spraying on a carrier (especially for friction/slide layers of bearing laminates having metallic base members) of a matrix foundation substance of fluoride-held polymers which has admixed metal or metal-alloy particles and/or additive material with friction and/or slide-improving characteristics. The applied layer material is subjected to heat to melt the same, and the layer is then cooled and pressed. The synthetic substance of the matrix can contain a primer, such as chromium oxide.

Abstract: A process of and apparatus for coating an article with a layer of metal incorporating particles. The article is placed in a barrel together with the particles and the barrel is placed in a plating bath and rotated therein. The barrel has an opening covered by a cover which is pervious to the solution but impervious to the particles. The article is thus flowed over by solution within the barrel which can have a high concentration of particles but there are no particles in the part of the bath outside the barrel. The process may be electroless or electrolytic. In the latter case, the anode is preferably outside the barrel.

Abstract: A composition is provided for marking hot metal objects, which may be moving e.g. steel bar emerging from a rolling mill. The composition is in powder form and comprises a major weight proportion of refractory pigment and a fusible adhesion agent therefor. For marking, the composition may be applied in a carrier gas, optionally through a stencil, to the surface of the object and allowed to adhere there. Clear, durable markings are obtainable.

Abstract: A method of providing a substrate with a layer of a tertiary compound comprising silicon, silicon carbide and a transition series metal. In accordance with the method, a substrate having at least a surface layer thereon of a transition series metal is coated with silicon carbide particles having an average particle diameter in the range of up to about two microns. The coated substrate is then heated in an inert atmosphere to a temperature between 1000.degree. and 1300.degree. C. for sufficient time to allow diffusion to occur between the silicon carbide and the transition series metal layer, thereby forming the tertiary compound. Substrates coated with the tertiary compound are particularly suitable for preparation of alkali metal/polysulfide batteries wherein the substrate may be exposed to corrosive attack by molten polysulfide salts.

Abstract: Solid constant release composition wherein (a) the solution of soluble core substance within the core space remains saturated during dissolution and (b) the shape and (c) the surface of the coating and (d) the diffusion path for the soluble core substance through the porous coating remains constant while the composition is in a liquid medium, which composition is very useful in media in which constant release during substantially the whole release period is desired, for example, for medical, chemical and fermentation purposes.

Abstract: There is provided a process, and the product resulting therefrom, for coating a refractory block or substrate with a small particle size form of at least one platinum group metal whereby a fused layer of such metal is formed on the refractory and is directly and strongly adhered on a surface thereof. This technique can likewise be employed in such a manner that the layer is a bonding agent for purposes of bonding a separate sheet of a platinum group metal to the refractory which structure can then be employed as a glass contacting member in apparatus for handling molten glass.

Abstract: Method for hard-facing metal substrates is disclosed using a hard facing material consisting essentially of combined vanadium, tungsten and carbon and from about 5 to about 40% by weight of chromium carbide with up to 15% by weight in the aggregate of cobalt, iron, molybdenum and nickel.

Abstract: The surface of a metallic substrate is coated with wear-resistant material by depositing on the surface a layer of a mixture of a coating powder including a metallic carbide with powdery silicon and heating said layer by exposure to a source of high density energy to bring about simultaneous evaporation of said silicon and fusion of said coating powder with bonding to said substrate. A coating of high surface porosity can be obtained.The substrate may be a piston ring for heavy-duty internal combustion engines.

Abstract: Electrochemical cell components such as interelectrode separators, retaining screens and current collectors are contacted with lithium tetrachloroaluminate prior to contact with molten electrolytic salt to improve electrolyte wetting. The LiAlCl.sub.4 can be applied in powdered, molten or solution form but, since this material has a lower melting point than the electrolytic salt used in high-temperature cells, the powdered LiAlCl.sub.4 forms a molten flux prior to contact by the molten electrolyte when both materials are initially provided in solid form. Components of materials such as boron nitride and other materials which are difficult to wet with molten salts are advantageously treated by this process.

Abstract: Wear and corrosion resistant coatings are obtained using the plasma or d-gun techniques and applying a coating material consisting of carbides and nickel-containing base alloy having 6-18 wt.% boron.

Abstract: The invention comprises spectrally selective surfaces having a good performance at relatively low cost, and designed to be used mainly, but not exclusively, in solar thermal energy collectors. Suitable substances in powder form are attached by simple and effective means to a suitable surface. This is accomplished by the use of new classes of binders, or alternatively, by novel, purely mechanical means, without the use of a binder. The binders described herein feature a high transparency for the infrared radiation emitted by the hot underlying surface, coupled with good adhesive properties towards both the powder and the surface to be coated. The method of effecting the adhesion of a powder layer to the underlying surface without the use of a binder consists of bringing the powder layer into intimate contact with the surface, for example by pressing or rolling the powder layer onto or into the surface, especially with simultaneous mechanical deformation of the object whose surface is being coated.

Abstract: A vitreous enamel composition comprising 1 part by weight of a vitreous enamel solid component composed of (1) 90- 99.9 wt. % of glass powder consisting of 30 to 70 wt. % of SiO.sub.2, 1- 65 wt. % of PbO, and 1-- 15 wt. % of R.sub.2 O in which R is K, Na or Li, and (2) 0.1-- 10 wt. % of palladium powder, and 1- 20 parts by weight of an organic vehicle.

Abstract: This invention is concerned with improving the properties of refractory supports used in the manufacture of ceramic articles such as setters, batts, saggars, cranks, stilts, thimbles, saddles and spurs, and resides in the provision on an article-supporting surface of such supports of a coating comprising comminuted plasma dissociated zircon. Also provided is a method of coating refractory supports and a coating composition comprising a dispersion of comminuted plasma dissociated zircon in a carrier liquid.

Abstract: A method is provided for producing adherent metal coatings on metal substrates, such as ferrous metal substrates, e.g. steel, cast iron and other metal substrates said material comprising a plurality of ingredients physically combined in intimate contact with each other, each of said plurality of ingredients comprising by weight about 3% to 15% aluminum, about 2% to 15% of a refractory metal silicide and the balance essentially a metal selected from the group consisting of nickel-base, cobalt-base, iron-base and copper-base metals.

Abstract: A method of coating a Al.sub.2 O.sub.3 ceramic surface with a biologically active glass comprising contacting a glass and ceramic having different thermal coefficients of expansion at a temperature sufficient to bond the glass to the ceramic surface by ion diffusion, cooling the coated substrate to a temperature sufficient to produce thermo-mechanical stress induced interconnected micro-cracks in the glass coating and overcoating said micro-cracked glass coating with at least one additional coating of biologically active glass. The invention includes a product of manufacture comprising a compacted Al.sub.2 O.sub.3 ceramic surface coated with at least two layers of biologically active glass characterized in that the first layer of glass has interconnected thermo-mechanical stress induced micro-cracks therein.

Abstract: A process for producing a thick film circuit with terminal elements on an inorganic substrate. A paste of silver powder, copper oxide powder and organic bonding agent is silk screen printed on an inorganic substrate, dried and sintered. Then over preselected locations along individual conductor paths terminal elements are hard soldered. The conductor paths are strongly adhered to the inorganic substrate and the terminal elements are likewise strongly adhered to the individual conductor paths.

Abstract: A boiler tube coating and method are disclosed in which industrial steel tubes or pipes, for example, steel boiler tubes and/or integrated panels of steel boiler tubes, are provided with a fused overlay of a corrosion and erosion resistant coating comprised of a refractory hard component, e.g. tungsten carbide, dispersed through a corrosion resistant matrix alloy.

Abstract: The disclosure relates to a method for diffusing a coating of manganese powder and titanium powder into a ceramic to improve its voltage hold off withstanding capability. The powder coated ceramic is fired for from about 30 to about 90 minutes within about one atmosphere of wet hydrogen at a temperature within the range of from about 1450.degree. to about 1520.degree. C to cause the mixture to penetrate into the ceramic to a depth on the order of a millimeter.

Abstract: A method for producing a tubular multi-layered porous barrier comprising the step of depositing fine powder onto at least one of the inner and outer surfaces of a sintered tubular porous support member in a layer of uniform thickness to form a fine powder layer and pressurizing said powder layer against said support member to form a porous barrier layer on the support member.

Abstract: Powdered binder metal and hard metal granules are deposited in measured quantities on the cutting edge of a metal blade. When these materials both have a magnetic component, an electromagnet with an elongated air gap is used to pick up quantities determined by the amount of exciting current and to deposit them on the surface to be coated. A high-frequency heating current flows through the object being coated and also through a nearby inductor in series. This produces a short heating cycle in which the binder metal is melted, this being done in a protective gas atmosphere and without the presence of a flux. The object to be coated is held in a clamping device provided with a cavity around the surfaces to be coated, which include adjacent side surfaces as well as the edge of the blade, and the clamping plates also operate as heat sinks. The method and apparatus can also be used for sintering on a coating, but that requires a longer heating cycle.

Abstract: Abradable seal composite structure having a porous, abradable ceramic surface layer which is resistant to high temperature oxidation and a metallic bottom layer capable of being bonded to a metallic substrate, with at least two intermediate layers consisting of ceramic/metal mixtures. The intermediate layer next to the ceramic layer has the highest ceramic content, with the remaining intermediate layers having progressively lower ceramic content and correspondingly higher metallic contents. The composite is made by laying up the layers in wet paste form and then drying them, after which the composite can be heated to bond it to the metallic substrate.