Abstract: In an improved method of curing a topcoat coating composition, at least a portion of the curing catalyst for the topcoat is contained in the basecoat composition. After applying the topcoat, the curing catalyst in the basecoat migrates to the topcoat, where it contributes to the curing the topcoat. Improved intercoat adhesion is obtained. In addition, the disclosed method enables the use of one package silane coating systems.

Abstract: A washout resistant roof mastic is disclosed in which an emulsion is applied and contacted with a second material that causes the emulsion to flocculate and set quickly. The emulsion can be applied for example through an applicator that simultaneously applies the emulsion and the flocculant.

Abstract: A method for stabilizing shelf life conductivity of conductive coatings such as polypyrrole or nickel sulfide on a substrate such as fiberglass, by incorporating in such conductive coating a polyphenol or a polysiloxane. The polyphenol is derived from a phenolic material in the form of a phenol-formaldehyde monomer or an oligomer of phenolformaldehyde, and the polysiloxane is derived from a siloxane. Upon heating, the phenolic material cures to a polyphenol and the siloxane is converted to a polysiloxane, forming the stabilizing material on the conductive polypyrrole or nickel sulfide coated substrate. The phenolic material is preferably incorporated directly into the solution formulation for preparing the conductive nickel sulfide or polypyrrole on the substrate, and the polyphenol stabilizer is formed together with the conductive coating on the substrate by heating.

Abstract: A method and apparatus for generating lubricant at the head/disk interface throughtout the life of a disk drive utilizing friction at the slider/disk interface to activate the polymerization of a monomer at the catalytic surface on the slider and/or the disk surface. The monomer is supplied to the catalytic surface through the vapor state from a reservoir.

Abstract: (Meth)acrylic ester formulations employing peroxy initiators have accelerated cure rates when the substrates to which they are applied, or the compositions themselves, include nitrite, borate, silicate or carbonate salts. The compositions should be free of acids having a PKa of 6 or less unless the composition also includes a transition metal compound.

Abstract: Disclosed is a process for passivating a metal surface in a metal/polyimide structure, such as a polyimide layer on a semiconductor substrate containing a pattern of metallization. The process invovles the formation of an intermediate layer of a silsesquioxane polymer between the polyimide layer and the substrate. The silsesquioxane layer passivates the metal, to inhibit interaction between the metal surface and the polyimide precursor material used in forming the polyimide, to provide a moisture-resistant and oxidation-resistant interface.

Abstract: A process for producing a monomolecular built-up film of monomolecular layers of a silane surfactant is described. In the process, the silane surfactant is chemically adsorbed on a hydrophilic surface of a substrate and is subjected to irradiation of a high energy beam or plasma treatment in an active gas atmosphere to activate the monomolecular layer. This activated layer is further adsorbed with the silane surfactant to form a built-up film. The beam irradiation or plasma treatment may be effected in a desired pattern. The beam irradiation or plasma treatment and the further adsorption are repeated until the desired number of the monomolecular layers is obtained.

Abstract: In the pursuit of the forming of light composite materials which may be substituted for metal without loss of strength, composites have been manufactured from silicon carbide fibers in a titanium matrix. Titanium diffuses into the given boundaries of the silicon carbide and degrades it. Yttria has been sandwiched between the titanium and silicon carbide, to provide a reaction skin of yttria which reduces the extent of diffusion. The present invention oxidizes the silicon carbide prior to applying the yttrium and thus further improves the resistance to diffusion.

Abstract: A method of permanently modifying the surface of a substrate material so as to develop a microscopically smooth, biocompatible surface thereon comprises covalently grafting at least a first biocompatible material, preferably having pendant terminal carboxylic acid or amine groups, to the surface of the substrate material by radio frequency plasma-induced grafting. In addition, a method of permanently modifying the surface of the substrate material comprises cross-linking a second biocompatible material to the first biocompatible material grafted to the substrate material using a cross-linking agent. Further, a prosthesis used in mammals, including an intraocular lens, comprises a polymer core and at least a first biocompatible material, preferably having pendant terminal carboxylic acid or amine groups, covalently grafted to the polymer core by radio frequency plasma induction.

Abstract: A corrosion-resistant protective coating on an aluminum substrate capable of withstanding corrosion attack by process halogen gases and plasmas is disclosed. The protective coating is formed by contacting an aluminum oxide layer on an aluminum substrate with one or more fluorine-containing gases at an elevated temperature. In a preferred embodiment, a high purity corrosion-resistant protective coating on an aluminum substrate capable of withstanding corrosion attack may be formed by first forming a high purity aluminum oxide layer on the aluminum substrate and then contacting the aluminum oxide layer with one or more high purity fluorine-containing gases at an elevated temperature to form the high purity corrosion resistant protective coating theron.

Abstract: A thermal transfer record sheet comprising a substrate sheet and a dye receptive layer and a non-tacky layer in this order on at least one surface of the substrate sheet; the dye receptive layer being composed of a crosslinking reaction product of a composition comprising (A-1) a saturated polyester containing units derived from 2,2-bis(4-hydroxyphenyl)propane in the main chain of the polyester and having a glass transition temperature of at least 60.degree. C. and (A-2) a polyisocyanate compound, and the non-tacky layer (B-1) comprising a water-insoluble or sparingly water-soluble fluorine-containing surface-active agent and (B-2) having a thickness of 50 to 200 angstrom.

Abstract: A two-part system and method for increasing the reflex-reflectivity of a substrate is disclosed wherein a first aerosol dispensing means containing a first coating composition capable of forming a base coating on a substrate and a second aerosol dispensing means containing a second coating composition capable of imparting reflex-reflectivity to the base coating is employed. The first coating composition comprises a binder resin and a solvent in which the binder resin is dissolved and the second coating composition contains transparent microspheres having a particle size from about 45 to about 90 microns and a carrier in which the transparent microspheres are dispersible. The substrate is coated first with the first coating composition via aerosol means to form a base coating which is subsequently coated with the second coating to impart reflex-reflectivity to the base coating.

Abstract: A method for preparing an aluminum surface for adhesive bonding which conts essentially of the steps of:(a) preparing an aqueous solution of an epoxy-functional silane;(b) degreasing a selected area of the surface;(c) wet abrading the selected area using the aqueous epoxy silane solution;(d) removing any residue from the selected area;(e) allowing the surface to air dry;(f) wiping an alcoholic solution of an amino-functional silane onto the selected area; and(g) allowing the surface to air dry.

Abstract: A method of forming a coating on a web. A coating mixture includes a continuous phase of a first material and a second material contained in microcapsules. The first material and the second material interact to form the coating. The coating mixture is applied to a face of the web. The web is passed between a back-up member and a doctor blade so that the doctor blade levels the coating mixture on the web and crushes the microcapsules to cause mixing of the materials on the web to form the coating on the web.

Abstract: Benzocyclobutene-functionalized organosilanes, and a method of increasing adhesion between a polymer and an inorganic surface by using benzocyclobutene-functionalized organosilanes as adhesion aids.

Abstract: A responsive film containing a responsible group occuring a chemical reaction by energy beam is formed on an insulated substrate, and energy beam is irradiated in a pattern, and part of the responsive group is selectively deactivated or activated, and only the remaining portion of the responsive group of the responsive film is coupled with a chemical substance containing metal in a later process, and an ultrafine pattern of metal film is formed.

Abstract: A method of making a permeation-resistant silicone elastomer-containing laminate useful for making fluid-containing implants such as mammary prostheses and gastric balloons. The method is accomplished by (a) applying a layer of an unvulcanized heat-curable silicone elastomer composition to a cured silicone elastomer substrate, (b) applying a layer of a solvent dispersion of a permeation-resistant elastomer and a solvent on the layer of unvulcanized silicone elastomer composition to form a three-layered laminate, and (c) exposing the three-layered laminate to heat until the unvulcanized silicone elastomer composition is vulcanized.

Abstract: This invention relates to the use of low temperature plasma technology for significantly improved corrosion protection of steel. The plasma process involves pretreating of the steel surfaces by oxygen plasma and thin film deposition by polymerization of certain precursors on the steel. The process utilizes DC power, substrates as the cathode, magentron anodes, and system pressures of 0.01-0.5 torr. After the thin film plasma deposition it is also preferably to put a primer coating over the thin film.

Abstract: An inking roller or ink metering roller comprised of a base roller, a substantially continuous hard and wear-resistant microporous ceramic coated layer bonded to the base roller and an interdiffused and immobilized oleophilic and hydrophobic essentially organic polymeric based material affixed to the surfaces and interstices of the microporous layer. The material may be a titanate coupling agent or a silane coupling agent.

Abstract: This invention relates to a method of joining two or more surfaces together by applying to at least one of the surfaces a water-based adhesive or an adhesive which liberates water during curing, and generating salt during the course of the joining operation, which salt will bind water that is present during the joining as water of crystallization.

Abstract: An aqueous system for treating a film or coating containing water-dispersible polymeric material having water solubilizing sulfonate groups in its molecular structure, the system being effective for insolubilizing the sulfonate groups and enhancing the water resistance of the film, and having dispersed therein per 100 grams of water, from about 0.002 to about 0.5 gram-ion equivalents of a multivalent cation, and from about 0.1 to about 25.0 grams of water-dispersible polyurethane material, and preferably having a No. 2 Zahn cup viscosity of from about 15 to about 50 seconds.

Abstract: The invention relates to a crosslinking process for self-crosslinking copolymers essentially based on (meth)acrylic monomers and is characterized in that, on or before the deposition of a layer containing at least one crosslinking catalyst, a second layer containing at least one self-crosslinking copolymer in suspension or in solution in an aqueous medium or in an organic solvent is applied, and in that these two layers are subjected to a heat treatment such that crosslinking of the layer containing the copolymer is initiated.The invention is used in the production of molded, impregnated, coated and printed articles, adhesives, binders, finishes, paints and varnishes.

Abstract: A process for improving the bonding of hotmelt materials which post crosslink in the presence of moisture, to water vapor impermeable substrates by applying an activator material, which release bound water at the hotmelt application temperature, to at least one of the water vapor impermeable substrates.

Abstract: A method for forming a metal oxide film on a substrate is provided comprising the steps of depositing a continuous metal layer having an exposed surface onto a substrate, forming a metal oxide layer on the exposed surface, contacting the oxide layer with an effective amount of a fluxing agent, providing a protective polymeric layer on the oxide layer and forming discrete metal microspheres by melting the metal layer. A metal polymer composite comprising a continuous metal oxide layer which may be transparent is thus provided.

Abstract: The invention relates to a method for the production of shaped plastic parts which are provided with an antistatic adhesive thermoplastic coating; according to the method, the adhesive thermoplastic coating is coated with a solution which contains a binder and a suitable oxidant for the oxidative polymerization of 5- or 6-membered heterocyclic compounds which have nitrogen or sulphur as heteroatoms, and the coating thus obtained is treated with a solution of the 5- or 6-membered heterocyclic compound.

Abstract: An electrically conductive surface layer is produced on moldings consisting of plastics which are soluble or swellable in organic solvents, the conductivity of the said layer being based on a system, incorporated therein, oforganic electron acceptors (I) on the one hand andorganic electron donors (II), iodides (III) or a mixture of (II) and (III) as electron donors, on the other hand,by a process in which the moldings are treated with organic solutions of these components.The products have a surface resistance of from 10.sup.8 to 10.sup.2 ohm and have the advantage that the remaining properties of the moldings are virtually unaffected by the agents (I) to (III).

Abstract: A pressure-sensitive adhesive tape comprising a plurality of superimposed layers, at least one outer layer being a pressure-sensitive adhesive layer, contiguous layer defining an interface therebetween, each of said layers comprising a photopolymerized matrix of polymeric chains; said polymeric chains extending from the matrix of one of said layers through said interface into the matrix of a contiguous layer; said polymeric chains comprising polymerized monomers having migrated from the matrix of each contiguous layer prior to polymerization, whereby said layers cannot be delaminated.

Abstract: A process of making pressure-sensitive adhesive tape comprising a plurality of concurrently coated superimposed layers, at least one outer layer being a pressure-sensitive adhesive layer, contiguous layers defining an interface therebetween, each of the layers comprising a photopolymerized matrix of polymeric chains; the polymeric chains extending from the matrix of one of the layers through the interface into the matrix of a contiguous layer; the polymeric chains comprising photopolymerized monomers having migrated from the matrix of each contiguous layer prior to photopolymerization, whereby the layers cannot be delaminated.

Abstract: A method for the preparation of silicate glasses of controlled index of refraction involves the thermal and/or plasma processing of organo-silicon polymers. Compositions so treated evidence a suppressed index of refraction which may subsequently be increased by sintering to yield a material uniquely suited for use in fiber optic devices.

Abstract: Described is a method for imparting a photochromic response to a synthetic plastic article, e.g., an optical lens such as a sunglass lens prepared from an allyl diglycol carbonate monomer. The method described comprises depositing a thin uniform substantially dry film of a photochromic-bearing polymeric resin onto at least one planar surface of the synthetic plastic material, heating the plastic article and resin film substantially uniformly at temperatures near to but below the melting temperature of the photochromic substance for a time sufficient to transfer a photochromic amount of the photochromic material into the subsurface region of the plastic article, and thereafter removing the photochromic-lean resin film from the planar surface(s) of the plastic article.

Abstract: A novel combined hot melt and other fluid preferably slot nozzle-roller coater assembly and technique enabling elimination of streaks and other aberrations caused by undissolved particles or dust and the like in the fluid, and adapted for multi-fluid mixing, if desired.

Abstract: The disclosed charge transfer signal processor includes a vacuum housing having an input face and an output face, a 2-D electromagnetic input means cooperative with said input face for providing a 2-D input electronic charge signal within the vacuum housing, transfer means for imaging the 2-D input electronic charge signal in a region of the vacuum housing proximate the vacuum housing output face, and charge feedthrough means coupled to the vacuum housing output face for transferring the imaged 2-D electronic charge signal externally to the vacuum housing. In one embodiment, the charge transfer signal processor is operable as Gen-1 charge transfer amplifier. In another embodiment, a microchannel plate assembly is disposed in the vacuum housing intermediate the input and output faces, and the charge transfer signal processor is operable as a high-gain charge transfer signal amplifier.

Abstract: Semipermeable composite membranes suitable for separating organic compounds of low moelcular weight from aqueous, inorganic salts containing solutions are provided. These membranes are obtained by coating one side of a membrane support with an aqueous solution containing dissolved therein an organic, film-forming, hydrophilic polymer, and a cross-linking agent (1) and optionally ionic monomeric compounds to form at least one polymer layer, contacting the still wet polymer layer(s) interfacially with an organic solution of a cross-linking agent (2), containing at least two functional groups, drying the resultant product for a time sufficient to form the composite membrane comprising the membrane support and an asymmetrical coacting consisting of polymer layer(s) and a thin semipermeable cross-linked film, containing ionic groups resting on the top of said layer and being integrally attached thereto.

Abstract: A molybdenum article is disclosed in which the substrate thereof has adherently bonded thereto a thermally self-healing plasma-sprayed coating consisting essentially of a composite of molybdenum and a refractory oxide material capable of reacting with molybdenum oxide under oxidizing conditions to form a substantially thermally stable refractory compound of molybdenum. The plasma-sprayed coating is formed of a plurality of interbonded plasma-sprayed layers of a composite of molybdenum/refractory oxide material produced from a particulate mixture thereof. The coating comprises a first layer of molybdenum plasma-sprayed bonded to the substrate of said molybdenum element and a second layer of plasma-sprayed mixture of particulate molybdenum/refractory oxide consisting essentially of predominantly molybdenum bonded to the first layer.

Abstract: This invention is directed to a process of forming composites comprising reinforcing fibers dispersed in a thermoplastic polymer matrix, said process comprising the steps of coating a reinforcing fiber with a curable resin and an initiator for the curing of the resin and for the polymerization of monomer of said polymer; curing said resin to form cured resin coated fiber; coating said resin coated fiber with monomer of said polymer; polymerizing the monomer coating to form a polymer/resin coated fiber; and aligning the polymer/resin coated fiber and molding same into a desired reinforced thermoplastic composite.

Abstract: A novel composite membrane and methods of making the membrane are described. The discriminating layer of the membrane is prepared by reaction of a reactive cationic compound group with a compound bearing a nucleophilic moiety. At least one of the reactants bears an average of two or more reactive groups. The reaction product contains covalent bonds formed via charge eliminating reactions.In a preferred embodiment of the invention, the nucleophilic group is anionic and a coacervate is formed initially on a microporous substrate. The resulting membrane may be useful for reverse osmosis, gas or ultrafiltration separations.

Abstract: A vehicle polishing method includes a first polishing step of moving a portal or gate-type travel frame travellable forwardly and backwardly in one of opposite travelling direction over a stationary vehicle to polish the body surface of the vehicle by rotary brush means mounted on the travel frame during such movement while applying a foamy primary treating agent containing an anionic surfactant onto the body surface by a primary treating agent applicator mounted on the travel frame, and a second polishing and rinsing step of moving the travel frame in the other travelling direction and polishing the body surface by the rotary brush means while applying an aqueous wax containing a cationic surfactant onto the body surface by an aqueous wax applicator, and ejecting fresh water onto the body surface by a rinsing unit mounted on the travel frame to wash away the excessive wax from the body surface.

Abstract: A process for producing a photoelectric conversion film comprising heat-treating a coating (A) of a photoconductive material composed chiefly of at least one of CdSe, CdS, CdTe, CdS.sub.x Se.sub.1-x and CdS.sub.x Te.sub.1-x wherein x is a real number of less than 1, opposite from a coating (B) in proximity thereto, the coating (B) being made of a material composed chiefly of CdS and a Cd halide.

Abstract: A method and kit for glare control and improvement of image transmission through a reflective-transmissive surface comprising surface irregularities to control glare. A dispersion of particles is applied to the surface and allowed to dry. Then an inert fluid coating is applied to the surface to enhance clarity. A liquid dispersion comprising a flattening agent is applied to the surface and allowed to dry so that the particles and flattening agent form a transparent glare-reducing coating. An inert fluid coating is applied to sufficient thickness to remove some, but not all, of the surface irregularities created by the glare reducing coating. A method of formulating the liquid dispersion is also disclosed.

Abstract: A process for producing a temperature and moisture sensitive element, which comprises a step of forming a first coating layer by applying a composition comprising a polymerized organo-silicon compound and an inorganic material onto a substrate, a step of forming a second coating layer apart from the first coating layer by applying the same composition as defined above onto the substrate, a step of heat-treating the first coating layer to form a moisture sensitive section, and a step of treating the second coating layer to form a temperature sensitive section by a treatment different from the heat treatment of the first coating layer.

Abstract: Method for making flat gaskets with a soft material layer on a sheet or plate-like support, comprising the following method steps:applying a soft material mass comprising fillers and a binder as soft material layer onto the support,if need be, compacting and/or drying the coated support,impregnating this flat material with impregnating agents containing polysiloxanes which may be cross-linked by means of catalysts,and, if need be, subsequently after-treating the impregnated sheet or plate by processes such as, for example, curing.

Abstract: A process for improving adhesion between photographic layers of a photographic element comprising a support having provided thereon at least(1) a first photographic layer comprising a high molecular weight compound having a functional group capable of reacting with an isocyanate group and(2) a second photographic layer comprising a high molecular weight compound having a functional group capable of reacting with an isocyanate group which compound is different from the high molecular weight compound of said first layer,which process comprises coating from 2 to 20 ml/m.sup.2 of a solution containing a polyisocyanate compound having at least two isocyanate groups on the first photographic layer, drying said solution, and then coating the second photographic layer.

Abstract: A process for chemically bonding a lubricant to a magnetic disk by applying a functionalized polymeric lubricant to the disk, heating it until a significant portion bonds to the disk via the functional terminal group, and then reacting the unbonded residue with a chemical moiety, the residue then forming a mobile lubricant highly resistant to spin-off due to the presence of the bonded lubricant.

Abstract: A thermal transfer recording medium comprising a support, an interlayer provided on said support and a coloring agent layer provided on said interlayer. The interlayer contains a cross-linking agent and the coloring agent layer contains a coloring agent and a reactive polymer. The transfer recording medium can be used repeatedly to provide printed copies of excellent quality.

Abstract: A process for sealing an oxidized aluminium or aluminium alloy surface comprising sealing the surface in the presence of a sealing agent to hinder the formation of a smut layer, the agent being the reaction product of one or more sulphonated aromatic compounds with an aldehyde and/or dimethylolurea or a mixture of formaldehyde and urea. A novel composition comprising the reaction product above and a cobalt or nickel salt may also be used as the above mentioned sealing agent.

Abstract: A polyurethane elastomer and a metal are strongly adhered by using (1) a composition containing a polyepoxy compound and a polyamine compound and (2) a composition containing an isocyanate compound having a concentration of isocyanate group of 15-50% by weight. An adhered composite article thus obtained has excellent water resistance and heat resistance.

Abstract: A sufficiently thick gliding layer is produced on the recording surface of a record carrier of the type comprising an aluminum layer applied over a lacquer layer coated on a support layer. The back surface of the support layer is also coated with a lacquer layer. A fatty acid or a mixture of fatty acids is admixed with one of the two lacquer layers and a metal-diketone or a metal-keto-ester is admixed with the other lacquer layer in approximately in a stoichiometric ratio to the fatty acid. Following the coating of the material with aluminum in a vacuum, the record carrier material is wound into a roll, and stored.

Abstract: A bonded composite laminate is provided comprising a textile layer and a plastic film which contains polyurethane urea coating which laminate is suitable for lining and repair of pipelines and canalizations.

Abstract: Integral silicone molded products comprising a unitary structure of a substrate with different phases is made by coating a substrate with a mixture of an alkenyl containing polyorganosiloxane, a polyorganohydrogensiloxane, and an addition-reaction catalyst where at least one component is applied to the substrate and then additional components are applied and diffuse to result in a coating with a polyorganosiloxane phase whose degree of crosslinking is low and a polyorganosiloxane phase whose degree of crosslinking is high and the phase having the low degree of crosslinking is next to the substrate. Such molded products are coated hybrid IC transistors, solar battery modules, and optical fibers.

Abstract: A method for treating non-woven fabrics or fibers used in the manufacture of automobile tires and accessories, and the products produced by such method. In order to improve the adhesion qualities of fabrics used in the manufacture of pneumatic tires, particularly chafer strip and bead wrap constructions, to thereby reduce or eliminate the splitting and deterioration tendency of such products under high stress conditions, by impregnating the non-woven fabric with at least an equal amount of elastomer by fabric weight.