Abstract: The present invention relates to an inhibitor package that allows for low temperature cure in thermal solventless paper release products while at the same time maintaining reasonable bulk and thin film bath lives.

Abstract: The invention provides a method of making thermoplastic resin-coated paper which comprises coating a paper sheet with a liquid thermoplastic resin, passing the thermoplastic resin-coated paper sheet through a nip of a pressure roll and a thermally conductive medium to form a resin-medium interface, heating the interface to a temperature of from 35.degree. C. to 350.degree. C. for a nip time period of from 0.002 to 10 seconds and a pressure of from 17,500 to 1,750,000 Pa-m, cooling the interface to a temperature of -73.degree. to 32.degree. C. for a cooling time period of from 0.001 to 100 seconds, and separating the thermoplastic resin-coated paper from the medium.

Abstract: A latex useful as a binder for paper, nonwovens, and textiles is prepared by copolymerizing in aqueous emulsion using a redox initiator at 5.degree. C. a mixture of 35 to 60% weight of a conjugated diene monomer and from about 30 to 65% by weight of a vinyl aryl monomer. Additional improvements can be obtained by incorporating in the mixture a small percentage by weight of copolymerizable monomers such as acrylic acid, methacrylic acid, itaconic acid and/or a functional type monomer having an activatable methyl, ethyl, propyl or butyl ester group and a vinyl group.

Abstract: Packaging materials are produced by a process which comprises coating substrates suitable for packaging with an aqueous solution or emulsion which contains a copolymer A) composed ofa) from 10 to 100% by weight of an ethylenically unsaturated C.sub.3 -C.sub.5 -carboxylic acid or C.sub.3 -C.sub.5 -di-carboxylic acid or anhydrides or half-esters of the dicarboxylic acids,b) from 0 to 50% by weight of an ethylenically unsaturated compound having at least one sulfo or sulfonate group andc) from 0 to 70% by weight of further monomers,and a polyester B) and, if required, then applying further top coats.

Abstract: Binders for powder coatings comprising A) a solid unsaturated polyester and B) a polyurethane comprising (meth)acryloyl groups. These polyester-containing mixtures are distinguished by an improved blocking stability compared with polyurethane alone.

Abstract: A multi-ply structure which includes a release coating sandwiched between two plies of the structure and present in an amount of about 5 to about 25 g/sq yd., one of the plies of the structure being flexible and in contact with the release coating and removable therefrom by the application of a force of between about 90 to about 600 g/in., as determined by the Keil test procedure, including a composition for forming the release coating and comprising an aqueous coating composition which includes a solids portion and which is effective in forming a coating having release properties, the solids portion of the composition comprising a major amount of resin binder and a minor amount of filler, the filler comprising a major amount of clay and a minor amount of magnesium or calcium hydroxide, and including also a continuous process for forming such multi-ply structure, including particularly a structure comprising a poly(vinyl chloride) ply strippable from a support ply.

Abstract: Provided are aqueous dispersion consisting essentially of high-molecular weight polymer prepared by aqueous suspension polymerizing a blend of monomers, said blend consisting essentially of: (i) a plasticizing amount by weight of a monomer selected from the group consisting of plasticizing alkyl acrylate monomers and mixtures thereof, (ii) a hardening amount by weight of a monomer selected from the group consisting of hardening alkyl acrylate monomers and mixtures thereof, and (iii) a crosslinking amount by weight of a monomer selected from the group consisting of di-ethylenically unsaturated monomers and mixtures thereof, in an aqueous suspension comprising a polymer component consisting essentially of a low-molecular weight, water-soluble, acrylic polymer having carboxylate functionality.

Abstract: A novel aqueous polymeric formulation is disclosed. Also disclosed are methods of making the polymeric formulation, and of using the polymeric formulation to produce a crosslinked polymeric surface coating on a substrate. One embodiment of the novel polymeric formulation comprises an aqueous carrier; at least one polymeric ingredient; a non-polymeric polyfunctional amine; and base. The one polymeric ingredient has both acid-functional and acetoacetoxy-type functional pendant moieties. The non-polymeric polyfunctional amine has at least two amine-functional moieties. The amount of base contained within the formulation is effective for inhibiting gellation, which would otherwise occur as a result of crosslinking between the acetoacetoxy-type functional and amine-functional moieties. Another embodiment of the novel polymeric formulation comprises at least two polymeric ingredients, one of which has acetoacetoxy-type functional pendant moieties and the other of which has acid-functional pendant moieties.

Abstract: This invention discloses a process for preparing a latex which is particularly beneficial for utilization in manufacturing high performance masking tape, which comprises the seqential steps of (1) terpolymerizing a vinyl aromatic monomer, an alkyl acrylate monomer, and an alkyl propenoic acid monomer in an aqueous polymerization medium by free radical polymerization to produce a seed polymer latex; (2) neutralizing the seed polymer latex to a pH of about 6 to about 9 by the addition of an alkali; (3) adding additional vinyl aromatic monomer and alkyl acrylate monomer to the neutralized seed polymer latex; and (4) allowing the additional vinyl aromatic monomer and alkyl acrylate monomer to polymerize in a second polymerization step to a solids content of about 30% to about 50% to produce the latex which is particularly beneficial for utilization in manufacturing high performance masking tape.

Abstract: A toner recording medium including a substrate, such as paper, containing a coating composition of particulate silica and a polyvinyl alcohol in a coating weight of less than 2.0 g/m.sup.2 per side of the substrate. The composition is preferably about 50 to less than 90 parts by dry weight of particulate silica and about 10 to 50 parts by dry weight binder. A process is also disclosed for coating a substrate, such as paper, to produce a toner recording medium.

Abstract: A process is disclosed for strengthening and sizing paper which comprises the step of applying a composition comprising (a) an isocyanate and (b) an isocyanate-reactive component comprising at least one polyol having an ethylene oxide content of at least 1%, wherein said composition does not contain water to the paper by means of an electrostatic spraying device having a linear orifice.

Abstract: A novel aqueous polymeric formulation is disclosed. Also disclosed are methods of making the polymeric formulation, and of using the polymeric formulation to produce a crosslinked polymeric surface coating on a substrate. One embodiment of the novel polymeric formulation comprises an aqueous carrier; at least one polymeric-ingredient; a non-polymeric polyfunctional amine; and base. The one polymeric ingredient has both acid-functional and acetoacetoxy-type functional pendant moieties. The non-polymeric polyfunctional amine has at least two amine-functional moieties. The amount of base contained within the formulation is effective for inhibiting gellation, which would otherwise occur as a result of crosslinking between the acetoacetoxy-type functional and amine-functional moieties. Another embodiment of the novel polymeric formulation comprises at least two polymeric ingredients, one of which has acetoacetoxy-type functional pendant moieties and the other of which has acid-functional pendant moieties.

Abstract: An improved latex composition is provided that has been found to exhibit a superior ability to form a substantially uniform polymeric film when applied to a substrate. The composition is capable of being handled and applied to a substrate in the absence of excessive foaming. The aqueous composition includes as essential components specified concentrations of a specifically-defined normally liquid predominantly hydrophobic nonionic alcohol ethoxylate surfactant, and a solely hydrophobic defoaming agent (e.g., a hydrocarbon-based mineral oil). It is possible for the composition to be applied even to a hydrophobic substrate (e.g., a polyester film substrate). Compositions of the present invention, following application to a substrate and the volatilization of the water component, form a substantially uniform polymeric film that can serve as a coating or adhesive.

Abstract: This invention provides a process for surface sizing paper or paperboard involving applying a surface sizing composition containing a mixture of starch and a surfactantless stable vinyl polymer microemulsion, followed by drying. The vinyl polymer microemulsion is prepared by emulsion polymerization of a styrene or styrene containing organic group with a C.sub.2 -C.sub.8 acrylic or methacrylic ester utilizing as the sole emulsifying agent a low molecular weight alkali soluble, acid containing copolymer.

Abstract: Hot melt polymer/fatty acid compositions are described that render fibrous products such as paper, paperboard and corrugated paper containers water-resistant at room temperature, but enable such articles to be repulped and recycled when the coated articles are repulped in a heated nearly neutral to alkaline pH aqueous medium.

Abstract: The present invention provides a water-resistant surface coating formulation comprising a reaction product obtained by subjecting an acrylamide polymer to a crosslinking reaction with 0.1 to 20 parts by mole, per 100 parts by mole of amido groups in the acrylamide polymer, of a glyoxalmonoureine; a method for improving the water resistance of paper by using the formulation; and coated paper so obtained. As a result of improved water resistance of the coating formulation, this invention makes it possible to conduct coating work stably.

Abstract: A composite integral sheet of wrap material which includes a first layer of absorbent material containing fibers bearing foraminous hydrophobic water-vapor-permeable pellicles, a second layer of printable material and an impermeable pigmented polymer layer interposed between the first and second layers. Additionally, the absorbent layer will include highly absorbent material formed by in-situ crosslinking of a partially pre-neutralized polyacrylic acid. The composite wrap material has a plurality of air pockets formed between at least one of the first or second layers and the polymer layer, by discontinuously bonding the first or second layers to the polymer material. A method of making the composite integral sheet.

Abstract: The invention is directed to a composition of matter useful as a paper impregnant, to the method of its use, and to the products produced by the method. Poly (diphenylmethane diisocyanate) or PMDI has been used in the past as a paper impregnant with or without propylene carbonate as a diluent. These products have generally required pressing under high pressures and at elevated temperatures. It has now been found that triacetin and/or triethyl citrate in usages up to about 20% of PMDI give superior performance in impregnated products. The modified PMDI will cure at essentially ambient conditions in times as short as 1-2 days to insoluble polyureas with low residual amounts of isocyanates and reaction byproducts such as 4,4'-diaminodiphenylmethane. The treated papers can be used in applications of which skins for sandwich panels and high strength corrugated board would be exemplary.

Abstract: The invention provides photographic paper having increased image stability. The invention is generally accomplished by forming a paper sheet, drying said paper in a first stage to below about 10 percent water, then applying a polyvinyl alcohol solution to both sides of said paper sheet, drying said paper in a second stage to below about 5 percent water, and then applying further polyvinyl alcohol solution to said paper and drying in a third stage. The paper then may be coated to form a silver halide photosensitive color paper. The paper contains between about 4 and about 6 weight percent of polyvinyl alcohol that is concentrated near the surface of said paper. Further, the paper has a oxygen leak rate of less than about 25 cc/m.sup.2 /day and an oxygen GTR rate of less than about 1 cc/m.sup.2 /day.

Abstract: The invention is directed to a stable phenolic dispersion of hydrophilic phenolic resin polymer using polyvinyl alcohol as protective colloid. Incorporation of a small proportion of an etherified bisphenol-A resin into an aqueous solution of a phenolic resin and a protective colloid (e.g., polyvinyl alcohol) forms a stable dispersion with low volatile organics content.

Abstract: A coating agent with a viscosity of 100-1000 mPa.s, measured by rotational viscometry at 70.degree. C. and a shear rate of 235 s.sup.-1, containing45-85 wt % of one or more polyesters, that have a branched structure and are essentially free from aromatic structural units, with a number-average molecular weight (M.sub.n) of 350-3000 and a polydispersity of less than 3.5,10-40 wt % of one or more cross-linkers based on aminoplastic resins and/or blocked di- and/or polyisocyanates,0-20 wt % of one or more reactive diluents, and 0-10 wt % of one or more organic solvents.They are particularly suitable as hot-sprayable clear coats for multicoat lacquer finishes.

Abstract: A process for producing coated paper comprises applying an aqueous coating solution onto coating base paper and drying the coating base paper, wherein a steam provided for drying or gas composed mainly of a steam is brought into direct contact with paper sheet, heated for regeneration, and then circulation for re-use, in which owing to the improvements in the heat efficiency and drying rate in the drying step, not only the productivity is improved, but also a high-quality coated paper is stably produced with a good efficiency.

Abstract: The present invention relates to a process for forming a laminate and the laminate using silicone release coating compositions comprising (A) a mixture of (i) a dimethylsiloxane-methylvinylsiloxane-methylphenylsiloxane copolymer and (ii) a dimethylsiloxane-methylvinylsiloxane copolymer, (B) an organohydrogenpolysiloxane, (C) a platinum catalyst, and (D) an organic solvent. The silicone release coating compositions of the present invention provide small release resistance values both at low and high peeling velocities and do not impair the residual adhesion of tacky substances that have come into contact with the coating.

Abstract: A coating agent comprising a particulate PVA having an average particle diameter of 0.01 to 1 .mu.m has excellent applicability through blade coaters or roll coaters.

Abstract: A hot melt process for producing a release coating. The process involves first forming a mixture of a release agent and a thermoplastic polymer in the absence of a solvent. The release agent is not completely compatible with the thermoplastic polymer. The mixture has a softening temperature ranging from about 120.degree. to about 350.degree. F. The mixture is heated to a temperature at or above its softening temperature and then coated onto at least a portion of a substrate. The coated substrate is cooled for a time and at a temperature sufficient to cause the mixture to solidify.

Abstract: A one-part, substantially formaldehyde-free, self-curing interpolymer comprising repeating units derived from a) about 4 to about 30 percent by weight of at least one functional monomer selected from olefinically unsaturated monomer containing a nucleophile group; b) about 4 to about 40 percent by weight of an olefinically unsaturated dicarboxylic acid; c) about 1 to about 60 percent by weight of (meth)acrylonitrile; d) about 0 to about 80 percent by weight of at least one monomer selected from the group consisting of (meth)acrylic acid ester of an alcohol containing 1 to 30 carbon atoms; and e) about 0 to about 80 percent by weight of at least one monomer selected from the group consisting of styrene, vinyl acetate, and vinyl halides, wherein at least one of monomers d) and e) are present in an amount of from about 0.1 percent by weight, for use as a fiber binder, such as for coating non-woven glass mats, or as a saturant for fiber substrates such as paper.

Abstract: The present invention relates to an inhibitor package that allows for low temperature cure in thermal solventless paper release products while at the same time maintaining reasonable bulk and thin film bath lives.

Abstract: The invention relates to a new process for the preparation of cellulose-containing material provided with a dry-strength and wet-strength finish and/or sized, characterized in that the cellulose-containing material is treated with a water-dispersible polyisocyanate mixture (I), which contains tertiary amino and/or ammonium groups, optionally polyether units and optionally hydrophobic groups.

Abstract: Paper coating formulations comprising sulfated oleic acid as a lubricant additive thereto are disclosed and are characterized by improved healing properties which permit coating at higher solids levels over formulations containing prior art lubricants when applied to the paper with a blade coater.

Abstract: A thermostable substrate for flexible circuit boards having excellent flame-resistance, handling, and storage qualities may be produced by treating a substrate of a nonwoven fabric or paper with a flame-resistant, halogen-free polymeric composition. The polymeric composition comprises an aqueous mixture of a copolymerizate of acrylic acid esters and styrene, and an aminoplastic or phenoplastic precondensate to which a mixture of fine-particle red phosphorus and fine-particle ammonium polyphosphate is also added.

Abstract: A method for treating paper which comprises applying to the surface of the paper an aqueous medium containing a sizing composition consisting essentially of 75 to 99.9 wt % polyvinyl alcohol which is at least 95 mole % hydrolyzed and 0.1 to 25 wt % ketene dimer represented by the formula: ##STR1## wherein R and R.sup.1 are the same or different hydrocarbyl groups having 8-30 carbon atoms.

Abstract: A generally flat tray is adapted for supporting a pizza or other food item on an upper surface thereof. The tray is preferably comprised of corrugated paperboard with its upper surface having a parchment-like coating and including a plurality of linear, elongated slots arranged in a spaced manner to permit juices and liquids exuded by the pizza to flow into and be trapped within the inner corrugated portion of the tray for maintaining the pizza crust dry and crisp. Facing edges of each slot are beveled downwardly to facilitate flow of the juices and liquids into the tray's inner portion where the juices and liquids are entrapped. The parchment-like coating on the tray's upper surface draws the juices and liquids from the pizza crust and redirects heat emanating from the pizza upward back into the pizza to maintain the pizza at an elevated temperature. The tray may be used for storing and serving pizza and may be integrated in the bottom of a closed container for transport and extended storage of the pizza.

Abstract: This invention relates to a method of coating a substrate by applying thereon an aqueous coating composition containing an alkali-swellable complex hydrophobe associative thickener. When a blade coater is utilized to apply said composition, lower blade pressures are obtained allowing increased line speeds to be used without scratching the substrate.

Abstract: The present invention relates to a process for the use of a novel emulsion composition in the printing industry. The composition when applied to printed substrates provides outstanding lubrication, antistatic and antismudge properties, as well as minimizes the occurrence of tears in the substrate. Additionally, the compositions of the present invention aid in the folding operation.The compositions of the present invention are emulsions. These emulsions are applied to the substrate surface after the ink is applied. The emulsion breaks causing the deposition of a uniform coating of composition of the current invention.The mixed emulsion composition contains one or more dimethylpolysiloxanes, mineral oil, a nonionic emulsification agent and water.

Abstract: Polyurethanes and polyesters are described which are the reaction products of an aromatic, aliphatic or cycloaliphatic diisocyanate, or of a diacid or diacid derivative respectively, with a diol containing a pendent UV-absorbing moiety, optionally also with one or more other diols or diamines. These UV-absorbing polycondensates can be applied to the surfaces of substrates by exhaustion methods or by spraying and act to protect polymers and dyes from degradation by UV radiation. They are therefore useful, either alone or in combination with other coating materials, for the treatment of wood, paper, textiles, leather or other surfaces which are exposed to degrading radiation.

Abstract: A process for preparing a biodegradable water-resistant film. The process includes the steps of dispersing zein in an aqueous solution comprising acetone in an amount of from 65 to 75% by volume to form a zein dispersion, forming the resulting zein dispersion into a film, and drying the film in an atmosphere having a relative humidity of 85% or less at an initial temperature of 55.degree. C. or less. The present invention also relates to a method for imparting water resistance to an article with poor water resistance by coating the article with the zein dispersion prepared as above, and drying the coated zein dispersion under the above conditions. The film or coating film according of the present invention neither dissolves upon contact with water, nor becomes weak due to water absorption or swelling on contact with water.

Abstract: A method for the production of a photographic coating support material includes a vacuum drying of the synthetic resin and the master batches as well as a storing and transport these products in a closed system with cleaned and dried air.

Abstract: Fluorochemical compositions comprising fluorinated compounds, wherein the fluorinated compound comprises fluorochemical oligomeric portion, an organic moiety, and a group that can impart soft hand, stain release, water repellency, or a durable property when the compound is applied to a fibrous substrate, wherein the fluorochemical oligomeric portion is bonded to the organic moiety through an isocyanate-derived linking group. Also disclosed are fluorochemical compositions in the form of fluorochemical liquid dispersions and methods for preparing substrates treated with such compositions. Substrates so treated exhibit particularly durable and abrasion-resistant oil and water repellent properties. Intermediates in the preparation of the fluorochemical compositions are also disclosed. Some of the intermediates are useful as emulsifiers in fluorochemical liquid dispersions.

Abstract: A latex comprises a colloidal suspension in water of essentially non-crystalline particles of a polymer or copolymer or .beta.-hydroxyalkanoates, for example .beta.-hydroxybutyrate and .beta.-hydroxyvalerate; the latex may be employed to produce self-supporting filfms or papers which are biodegradable and also readily recyclable.

Abstract: An improved process is provided for treating a porous web (especially fabric) to produce a novel silicone polymer internally coated web. In the process, a starting curable liquid silicone polymer is coated under pressure upon one surface of the web, and the web is then subjected to localized shear forces sufficient to move the silicone polymer composition into interior portions of the web and to distribute the silicone polymer composition generally uniformly therwithin in such planar region. Excess silicone polymer composition is wiped away from a web surface. Thereafter, the resulting web is heated or irradiated to cure the silicone polymer. Preferably a web is preliminarily impregnated with a fluorochemical. Webs procuded by this process are breathable, waterproof or highly water repellent, and flexible.

Abstract: An aqueous water repellent composition comprising the reaction product of one or more of a carboxylic acid or anhydride containing from 3 to 22 carbon atoms and a polyfunctional aromatic or aliphatic amine or substituted amine containing from 2 to 25 carbon atoms and a water soluble metal complex crosslinking agent containing one or more metals selected from Groups Ia, IIa, IIla, IVa and the first and second rows of transition metals from the Periodic Table of Elements. The composition may contain wax and is dispersed in water to form a water repellent system.

Abstract: Provided is an ink jet paper comprised of a substrate coated with a composition comprised of a latex film which has not been fully coalesced. The coating on the ink jet recording sheet is obtained by coating a composition comprised of a hydrophobic polymer latex onto the sheet, and then drying at a temperature below the film forming temperature of the polymer latex. As a result, the latex does not coalesce or form a smooth, continuous film.

Abstract: Recyclable containers such as corrugated or folding boxes are made from a coated paper or kraft grade sheet including a plastic coating thereon. Aqueous acrylic resin containing compositions can be applied in excess on the paper or kraft grade sheet and the unwanted coating metered and removed by directing a jet of air at the coating. After solidification of the coating, the coated paper or kraft sheets can be incorporated as components of corrugated or folding boxes. Recovery of the unwanted coating permits recycling of the coating component. Corrugated and folding boxes including the components can be recycled by conventional repulping processes. A process of manufacture of the coated sheets is also disclosed.

Abstract: Progress for preparing a catalyst for hydrosilylation reactions which comprises reacting (A) a rhodium complex Rh(R.sub.2 S).sub.3 X.sub.3, in which R represents alkyl and other specified hydrocarbon groups and X represents Cl or Br with (B) an organohydrogen polysiloxane in the presence of (C) an organosiloxane having silicon-bonded vinyl or allyl groups. The ratio of silicon-bonded hydrogen atoms provided by (B) to each Rh atom provided by (B) is in the range from 0.5:1 to 6.0:1.The invention also includes the use of the catalyst for reacting .tbd.SiH with .tbd.Si Alkenyl especially in compositions for the treatment of substrates such as paper and plastics.

Abstract: A reversible thermosensitive recording material composed of a support, and a reversible thermosensitive recording layer formed on the support, containing a matrix resin and an organic low-molecular-weight material, the organic low-molecular-weight material being dispersed in the form of discrete domains in the matrix resin, thereby constituting a phase-separation structure, with the periodic distance of the phase-separation structure of the reversible thermosensitive recording layer being 1.3 .mu.m or less. This reversible thermosensitive recording material can be produced by applying a coating liquid containing the organic low-molecular-weight material and the matrix resin which are dissolved in a solvent to the support to form the reversible thermosensitive recording layer on the support; and drying the applied coating liquid under such conditions controlled so as to obtain a 1.3 .mu.

Abstract: The release film-forming organopolysiloxane composition in accordance with the present invention is characterized by its ability to cure rapidly at relatively low temperatures not exceeding 100.degree. C. to yield a cured film that is strongly adherent for the surface of various types of substrates (e.g., synthetic films, paper, polyethylene-laminated paper, etc.) and that also exhibits excellent release properties for tacky substances.

Abstract: Disclosed is a method and an apparatus for efficiently and economically producing printed matter having a high degree of gloss, rub-resistance, water-resistance and resistance to contamination. In this method and apparatus, a web-fed printed matter or a web-fed printing paper is coated with a coating agent for roll press working and subjected to hot roll press working while in the state of a web.

Abstract: This invention relates to an improved process of surface sizing of paper and paperboard. The process consists of:a) Preparing an aqueous surface sizing compound by combining and mixing an aqueous solution of at least one water soluble or dispersible polymer or interpolymer, a solution or dispersion of auxiliary materials, and an aqueous solution of a metal salt, selected from the group of metals consisting of zirconium, hafnium or titanium, to the polymer solution;b) Adjusting the pH of the aqueous sizing compound from about 5 to about 10.

Abstract: Water soluble cellulose acetoacetates prepared by contacting a cellulose material with diketene, an alkyl acetoacetate, 2,2,6-trimethyl-4H-1,3-dioxin-4-one or a mixture thereof in a solvent system comprising lithium chloride plus a carboxamide. Compositions containing the cellulose acetoacetates and, optionally, a crosslinking agent are useful for coatings applications.

Abstract: The invention relates to a method of reducing the water vapor permeability of a sheet of paper, which comprises the step of coating the paper sheet with a film of 5-30 g/sq.m. of a coating medium consisting of a rosin sizing dispersion containing additives improving the film-forming properties of the coating medium, which additives include surfactants and waxes. It also deals with a paper so produced.