Abstract: An expandable aqueous coating composition includes a polymeric binder including latex particles wherein the latex particles include a copolymer having a glass transition temperature of about -20.degree. C. to about +60.degree. C. and a weight average molecular weight of about 20,000 to about 500,000 and including expandable particles having a liquid blowing agent contained within a thermoplastic shell.

Abstract: This invention relates to a blend of at least two emulsion polymers. In particular, the emulsion polymer blend comprises from 95 to 40 percent by weight of at least one first latex and from 5 to 60 percent by weight of at least one second latex, wherein the first latex is multi-stage comprising from 95 to 50 percent by weight of at least one soft stage polymer having a Tg less than 50.degree. C. and from 5 to 50 percent by weight of at least one hard stage polymer having a Tg from about 20.degree. C. to about 160.degree. C., and wherein the second latex is not an ambient temperature film-forming polymer. The emulsion polymer blend of this invention can be used to formulate a variety of aqueous coating compositions, such as for example, paints, mastics, caulks, sealants, varnishes, floor polishes, and the like. The emulsion polymer blend of this invention is also useful for formulating an aqueous coating composition which is coalescent-free.

Abstract: Heat sealable paper can be prepared by applying to a surface-sized paper web a coating of a dispersion comprising a microcrystalline wax and a copolymer of ethylene and acrylic acid or methacrylic acid. The coating can be applied by means of a size press between dryer sections in a paper machine. The coating neither adheres to nor leaves a residue on the heated drums in the dryer section following the size press.

Abstract: A corrugated paperboard strength enhancing process includes at least one resin application station located within the confines of the corrugator at a position where it is operable to apply a preselected amount of a strength enhancing resin to at least one side of the medium after it has been fluted. At least one liner is adhered to the set of opposed flute tips. Thereafter the combined board with the resin compound on selected transverse portions of the fluted medium is allowed to cure, under selected temperature and moisture conditions and without the application of pressure that would crush the fluted medium. A suitable resin for the intended purpose is an isocyanate compound.

Abstract: An aqueous correction fluid is provided which includes a latex binder, an opacifying pigment, a protective colloid, a nonionic surfactant, an anionic dispersant, and water. Preferably, the polymer binder is provided in the form of an aqueous emulsion. The correction fluid has improved freeze-thaw stability.

Abstract: A process for applying a barrier layer of ethylene/vinyl alcohol copolymer (EVOH) to a substrate, such as a plastic film, by coating the substrate with a solution of EVOH in a solvent of tetrahydrofuran and water, followed by removing the solvent. Multilayer structures having an EVOH barrier layer coated on a plastic substrate from solution in aqueous tetrahydrofuran solvent have excellent oxygen barrier properties.

Abstract: There is disclosed a laminate comprising (a) a layer of a styrenic polymer having a higher degree of syndiotactic configuration and a crystallinity of at least 25%, preferably 35%, (b) a layer of paper and optionally (c) an adhesive layer and (d) a barrier layer. The above laminate is excellent in heat resistance, hydrolytic resistance, tearability, dead foldability and gloss and can find a wide range of effective application.

Abstract: A matte printing paper, excepting bank note and security document paper, especially for offset or intaglio printing, is coated with a composition containing calcium carbonate as a coating pigment, a binding agent for absorption of printing ink and 10 to 65% by weight, based on its total solids content, of ungelatinized starch granules, except rice starch granules.

Abstract: The new vinyl polymer dispersions are obtainable by free radical polymerisation of olefinically unsaturated monomers in the presence of a cationic polyamidoamine which has been rendered hydrophobic, and can be used as sizing agents for paper which are distinguished, in particular, by their shear, electrolyte, heat and storage stability.

Abstract: A paper comprised of a supporting substrate with a coating comprised of a desizing component and a hydrophilic polymer, and more specifically in an embodiment the paper is comprised of a paper comprised of a supporting substrate treated with desizing agents selected from the group consisting of (1) hydrophilic poly(dialkylsiloxanes); (2) poly(alkylene glycol); (3) poly(propylene oxide)-poly(ethylene oxide) copolymers; (4) fatty ester modified compounds of phosphate, sorbitan, glycerol, poly(ethylene glycol), sulfosuccinic acid, sulfonic acid and alkyl amine; (5) poly(oxyalkylene) modified compounds of sorbitan esters, fatty amines, alkanol amides, castor oil, fatty acids and fatty alcohols; (6) quaternary alkosulfate compounds; (7) fatty imidazolines; and mixtures thereof.

Abstract: A porous fibrous sheet material for use in the manufacture of food casings and the like is pressed prior to bonding and is bonded with about 10% by weight or less of a non-viscose bonding agent. The pressed and bonded material can be used to form casings having characteristics of thinness and elasticity similar to the thinness and elasticity of viscose-bonded casings, without the environmental problems associated therewith. The non-viscose bonding agent will result in significantly less shrinkage in the base web than results from viscose bonding.

Abstract: A coating for paper comprising water, pigments, binder and poly(ethylene oxide). The binder comprising about 1 to 30 percent by weight of the dry weight of the pigments and the poly(ethylene oxide) comprising about 0.001 to 10 percent by weight of the dry weight of the pigments. The coating has a very low Brookfield viscosity. The poly(ethylene oxide) coating provides superior gloss and smoothness relative to conventional paper coatings and may be applied to the paper in higher coat weights. A process for using the poly(ethylene oxide) coating to make improved paper is also disclosed.

Abstract: Fluorochemical compositions comprising fluorinated compounds, wherein the fluorinated compound comprises fluorochemical oligomeric portion bonded through --O--, --S--, --NH--, or CO.sub.2 -- to a moiety comprising a group derived from an amino resin. Also disclosed are fluorochemical compositions in the form of fluorochemical liquid dispersions and methods for preparing substrates treated with such compositions. Substrates so treated exhibit particularly durable and abrasion-resistant oil and water repellent properties.

Abstract: The present invention provides a method of producing a cast coated paper including the steps of providing a pigment coating layer for casting on a base paper, plasticizing the coating layer by means of a rewet liquid, and drying the coating layer by pressing the coating layer against a heated metal drum having a highly polished surface such that the dried coating layer has a high gloss. The rewet liquid is an aqueous dispersion having a complex resin. The complex resin includes a copolymer resin and a colloidal silica, the copolymer resin being obtained by copolymerizing a styrene monomer and an unsaturated carboxylic ester monomer, and the colloidal silica having a mean particle diameter ranging from 0.005 .mu.m to 0.01 .mu.m.

Abstract: Disclosed is a receiver sheet which comprises a substrate and a coating which comprises a pigment and a binder comprising polyvinyl alcohol and an additional binder component selected from the group consisting of styrene-butadiene latices, cationic polyamines, cationic polyacrylamides, cationic polyethyleneimines, styrene-vinyl pyrrolidone copolymers, styrene-maleic anhydride copolymers, polyvinyl pyrrolidone, vinyl pyrrolidone-vinyl acetate copolymers, and mixtures thereof. When the receiver sheet is a coated paper, the paper substrate has a Hercules sizing degree of at least about 50 seconds and a basis weight of less than about 90 grams per square meter. When the receiver sheet is a transparency, the substrate is substantially transparent. The receiver sheet is particularly suitable for printing with aqueous based inks, such as those employed in ink jet printing systems.

Abstract: Process for coating papers and other articles in which the said papers and other articles are treated at pH 4 to 5 with a cross-linked anionic polymer, insoluble in water, and use for obtaining papers or other similar articles intended to be flexographically printed.

Abstract: Archival materials including paper manuscripts are preserved by a thin protective polymer film applied to the surface of the item by plasma polymerization of an organic monomer gas in a high frequency glow discharge. The polymer film protects the item against humidity and prevents widening of stroke lines due to ink spreading on the document. Microorganism growth is stopped by pretreatment of the document in a monoatomic gas plasma.

Abstract: A method for making a nonwoven filter which comprises impregnating a nonwoven filter substrate with a curable binder composition, the binder composition consisting essentially of(a) 10 to 100 wt% fully hydrolyzed PVOH which has a DPn of 100 to 2300; and(b) 0 to 90 wt% aqueous polymer emulsion, on a solids basis.The preferred aqueous polymer emulsion is an ethylene-vinyl chloride (EVCl) copolymer emulsion or a vinyl acetate/-N-methylolacrylamide (VAc/NMA) copolymer emulsion, or both.

Abstract: Process for coating papers and other articles in which the said papers and other articles are treated at pH 4 to 5 with a cross-linked anionic polymer, insoluble in water, and use for obtaining papers or other similar articles intended to be flexographically printed.

Abstract: A laminate suitable for use as wrapping or packaging materials for foods and industrial materials is disclosed, which is produced by laminating a thermoplastic resin composition which comprises (1) 10 to 95 % by weight of an ethylene copolymer composed mainly of units derived from ethylene and units derived from an unsaturated carboxylic acid anhydride and (2) 70 to 5 % by weight of a flexible resin having an MFR (190.degree. C.) of 0.1 to 1,000 g/10 min, to one or more kinds of substrates selected from thermoplastic resins, metals, papers, and fabrics. A process for efficiently producing the laminate is also disclosed.

Abstract: V-groovable gravure printable paper having the machinability of vinyl and the printability of paper, and a process for manufacturing such a product. A smooth, saturated only paper is subjected to heavy calendering during processing in order to provide adequate smoothness as required by printers. The paper is saturated with an acrylic/PVC blend designed to give good "miter-fold" strength, good smoothness and adequate adhesive anchorage. The saturant also allows the ink types used on vinyl films to adhere to the paper, and exhibits good stain resistance.

Abstract: A method of forming a sheet of material with indicia thereon comprises applying indicia to the sheet by an electrostatic copying process in which a toner powder is deposited on the sheet and is heated to cause it to fuse. The sheet of material comprises a flexible support layer that is provided with a porous coating of a latent curable material, preferably in particulate and/or filamentary form and especially one based on an epoxy material.It has been found that the indicia are more indelible than those formed on other surfaces by the same process even though the fused toner is not absorbed by the curable material.

Abstract: Coating process for papers and cardboards, in which cross-linked polymers insoluble in water, containing in molar proportions in the polymerized state:50 to 99.995% acrylic acid at least 70% of which is in the form of ammonium acrylate,0.005 to 0.5% bisacrylamidoacetic acid which has about the same neutralization ratio as acrylic acid and,the complement to 100% with acrylamide, are used as coating agent, and use in paper coating.

Abstract: This invention relates to a process of coating a finish film and one endless edge which comprising applying to said film and edge a heat curable coating composition containing an organic solvent, a lacquer additive and (a) from about 40 to about 85 parts by weight of an acetal and hydroxy functional resin; (b) from about 3 to about 20 parts by weight of an aminoplast resin; and (c) from about 0 to about 40 parts by weight of a polyester resin; and curing the wet film at a temperature between about 120 degrees C., to about 200 degrees C.

Abstract: The present invention provides a release agent formed by reacting an organopolysiloxane compound having at least one hydrogen atom with a hydrocarbon compound having at least one double bond which reacts with said hydrogen atom and a manufacturing method thereof.The release agent of this invention, which makes substantially no migration into any pressure sensitive adhesive layer, is well adaptable to whichever process, extrusion laminating process or coating process.

Abstract: A novel topical medicinal composition is described which comprises a copolymer which has both pendant fluorochemical groups and pendant polysiloxane grafts.

Abstract: Coated paper for labels, specially adapted to the conditions of utilization in breweries, is fabricated by applying to one side of the fibrous label paper medium a hydrophilic coating slip having a fast reaction to water so as to accelerate the absorption of water and by applying to the other surface a coating of a composition containing a binder comprising a mixture of cross-linkable and soft latex. Strict electronic control of the moisture rate of the paper during the manufacturing process provides for a remarkable dimensional stability and an excellent inherent flatness in a relatively large moisture range.

Abstract: A method of forming a cured thermoset composition by applying radio signals having a frequency of about 1 to 100 MHz to a composition comprising a major portion of thermoset and a receptor, said receptor having a dissipation factor of about 0.1 or greater and a dielectric constant of at least 0.1 or greater, said receptor selected from the group consisting of alkali or alkaline earth metal sulfate salts, aluminum trihydrate, quaternary ammonium salts, phosphonate compounds, phosphate compounds, polystyrene sulfonate sodium salts or mixtures thereof, said method comprising the steps of:(a) applying said composition to a substrate;(b) applying radio signals to the composition deposited on the substrate; and(c) dissipating the radio signals received by the receptor as thermal energy in an amount effective to cure the composition to a thermoset bond.

Abstract: A thermosetting resin composition comprising(A) 60 to 95% by weight of a prepolymer or precopolymer selected from the group consisting of (A-1), (A-2) and (A-3) below,(A-1) a prepolymer of diallyl phthalate,(A-2) a precopolymer of diallyl terephthalate derived from diallyl terephthalate of the following formula (1) ##STR1## and an aromatic benzyl hydrocarbon having at least one hydrogen atom at the benzyl position and represented by the following formula (2) ##STR2## wherein each of R.sup.1 and R.sup.2 represents a member selected from the class consisting of a hydrogen atom and lower alkyl groups, and n is an integer of 1 to 3, and(A-3) a mixture of (A-1) and (A-2), and(B) 40 to 5% by weight of a polyacrylate or polymethacrylate of dipentaerythritol having at least 4 acryloyl or methacryloyl groups in the molecule and represented by the following formula ##STR3## wherein each R.sup.3 represents a hydrogen atom, --COCH.dbd.CH.sub.2 or ##STR4## and at least four R.sup.3 groups represent --COCH.dbd.CH.sub.

Abstract: Barrier coatings are disclosed to reduce the migration of contaminants from paperboard into food products packaged in containers prepared from the paperboard. The barrier coatings operate to either absorb the contaminants or provide a tortuous path to their migration from the paperboard particularly at the high temperatures reached during the cooking of the food products in microwave ovens.

Abstract: A method for forming a hydrothermally aggregated kaolin clay pigment, comprising: preparing an aqueous slurry of a particulate kaolin clay, sodium silicate, and finely divided calcium carbonate, having a total solids concentration of from about 10 to 20% by weight; the non-aqueous components including 60 to 80 parts per hundred by weight of said kaolin and from 10 to 20 pph by weight each of said sodium silicate and said calcium carbonate; and hydrothermally treating said slurry in a closed system to form aggregates of adherent kaolin platelets.

Abstract: Copolymers having the general formula: ##STR1## are useful as compatibility, dispersion and grinding agents for aqueous pigmentary suspensions formulated from a mixture of mineral pigments, at least one of which is hydrated calcium sulfate. These suspensions are useful in papermaking.

Abstract: A process is disclosed for the preparation of styrene/acrylic type polymers which are useful in the sizing of paper. The process comprises polymerizing the monomers in an alcohol/water mixture at reflux temperature in the presence of a free-radical generating catalyst. The catalyst is added portion-wise over the course of the reaction and the resultant polymer is neutralized while substantially simultaneously separating the alcohol/water mixture and adding water to recover a product of less than 25% polymer solids.

Abstract: A paper coating composition which comprises:(I) a pigment,(II) an aqueous binder, and(II) a resinous ingredient comprising (A) a water-soluble resin which is prepared by cross-linking (a) a condensation product of (al) an alkylenediamine or a polyalkylenepolyamine and (a2) an urea compound with (b) a cross-linking compound. This composition imparts excellent ink receptivity, excellent water resistance, and in particular, excellent anti-blister property to paper.

Abstract: A process for improving the bath life and/or cure time of curable compositions. The process comprises first mixing an inhibitor with a catalyst, then adding that mixture to an organosilicon compound, and then adding the resulting mixture to an organohydrogensilicon compound. The process can optionally comprise a bath life extender compound. This process produces curable coating compositions which have a long bath life at room temperature and/or a rapid cure time at elevated temperatures such that they are useful in fast-paced coating operations, such as adhesive release coating operations wherein the cured coating is further coated with an adhesive immediately after being cured.

Abstract: A method of enhancement of a type impression printed by impact from an ink bearing fabric ribbon which involves applying thermographic powder to the type impression, applying heat to the type impression and thermogaphic powder at a temperature (usually about 100.degree.-150.degree. C./212.degree.-302.degree. F.) and for a time (usually a few seconds) sufficient to melt the thermographic powder, and allowing the melted thermographic powder to cool and adhere to the type impression. Ribbons which may be used in this process include cloth, nylon and similar fabric ribbons but exclude such non-fabric ribbons as film ribbons. Further, the ribbon must be ink bearing and cannot be a ribbon of the type commonly referred to as a "carbon ribbon". The powder may also contain a material capable of imparting an opaque, metallic or pigmented appearance to the enhanced type impression.

Abstract: A high quality coated paper for printing having excellent smoothness, gloss and printability is provided by using a coating composition mainly composed of a pigment and a latex of heterogeneous polymer particles consisting of a hard polymer domain having a glass transition temperature of 80.degree. to 220.degree. C. and a soft polymer domain having a glass transition temperature of 25.degree. to 95.degree. C. in combination with a high temperature calender finishing.

Abstract: A process for producing a resin is disclosed, comprising reacting (a) a polyalkylenepolyamine, (b) an alicyclic dibasic carboxylic acid and/or a reaction product having a free carboxyl group that is obtained by reacting an alicyclic dibasic carboxylic acid with a glycol, (c) a urea, and (d) an aldehyde and/or an alkylating agent. The resulting resin is useful as a wet strength agent to provide a paper coating composition having improved printability and printing effects.

Abstract: A curable organosilicon composition comprises a component having silicon-bonded hydrogen atoms, a component having silicon-bonded radicals reactive therewith, a curing catalyst, a catalyst-inhibitor and a bath life extender. The use of certain compounds, which are ineffective as a bath life extender in the absence of a catalyst inhibitor, effectively extend the room temperature bath life of a silicone coating composition containing a catalyst inhibitor. Being a substantial non-inhibitor for the catalyst the bath life extender component does not effect the cure time and/or cure temperature of the composition.This discovery has permitted the preparation of curable coating compositions which have a long bath life at room temperature and a rapid cure time at elevated temperatures which does not drift to longer intervals as the coating compositions ages over a typical production run.

Abstract: A silicone release coating emulsion includes a reactive crosslinkable silicone, a catalyst and a high molecular weight, water soluble or water dispersible polymeric thickening agent such as polyethylene oxide. The polymeric thickening agent has a molecular weight greater than about 100,000 g/mole Mw. The silicone release emulsion is applied as a coating to a substrate, and particularly paper, and cured to form a release coating for pressure sensitive adhesives. The silicone emulsion exhibits improved holdout of the silicone from the substrate.

Abstract: Disclosed is a method for making a paper support for photographic paper by a Fourdrinier paper machine of the twin-wire type provided with a lower wire on which a wet web is formed and an endless upper wire facing said lower wire with the wet web between them wherein the upper wire comes in contact with the wet web after the latter has travelled a distance of 5 to 12 m from the point where the paper stock had been fed to the lower wire which is preferably shaked in a horizontal direction and the rate of drainage through the upper wire to the sum of drainages through the lower wire and the upper wire is adjusted to 15 to 50% to give a smooth surface on which a photographic emulsion layer is to be formed.

Abstract: The invention discloses novel silanol waxes and applications thereof. Compounds of the invention by virtue of their silanol fatty ester group are waxy lubricious solids which provide outstanding lubrication and hydrophobicity when applied to surfaces like fiber, hair, skin or paper. The compounds of the present invention are prepared by reacting a silanol compound with a fatty carboxylic and or polycarboxylic acid, ester or anhydride.

Abstract: A process for strengthening the cellulose in materials which have been treated with an alkaline organometallic compound selected from a metal alkyl, metal alkoxide or alkyl metal alkoxide to deacidify the cellulose and which cellulosic material is wet with treatment solvent, by treating the undried cellulosic material with a polar monomer and then drying the cellulose material and polymerizing the monomer by subjecting the treated cellulose to vacuum and heat.

Abstract: Rapidly immobilizing paper coating compositions may be prepared by formulating an aqueous coating composition comprising a cationic starch, pigment and sufficient base to obtain a pH above the pK of the starch derivative so that the starch is no longer cationic; coating the paper substrate; and lowering the pH of the coating such that the starch becomes cationic.

Abstract: A process of curing and cross-linking methylhydrosiloxanes by contacting and forming a mixture of an allyl amide with at least one methylhydrosiloxane in the presence of a Group VIII metal catalyst, and heating the mixture of the allyl amide, the methylhydrosiloxane, and the Group VIII metal catalyst, in the presence of ambient moisture until the methylhydrosiloxane becomes cured and cross-linked.

Abstract: Natural or synthetic fibers (or fabrics, knits, papers, or webs made of such fibers) are improved in at least abrasion resistance, dye receptivity and/or other properties by bringing together on said fibers (or product made thereof) a liquid dispersion of a dispersible normally-solid polymer having pendent acid groups, such as carboxylic groups, and a reagent which reacts with the carboxylic group to render the polymer non-dispersible. The reagent may be one which supplies metal cations having a valence of at least 2 or it may be a primary amine, secondary amine or tertiary amine, or salts of the amine, a polyamine or salt thereof, or a quaternary ammonium salt. The reagent may precede the polymer onto the substrate, or may follow the application of the polymer onto the substrate.

Abstract: A method and apparatus for producing a paper product having a surface with enhanced gloss. The method includes the following steps: Applying a continuous layer of an impressionable coating material to a paper product; contacting the layer of coating material with a polymer release film having a smooth and glossy surface substantially free of defects, the surface having non-adhering and release characteristics; and solidifying the coating material during contact with the release film. Using this technique, a smooth and glossy surface of the release film is substantially imparted to a surface of the layer of solidified coating material. In the case of clay-coated substrates, the coating is solidified by heating, whereas in the case of polyethylene-coated substrates, the coating is solidified by cooling. The end product is a coated substrate in which the coating has a glossy surface to which the texture of a film has been imparted.

Abstract: This invention pertains to the use of silicone fine and micro emulsions in the web printing process. The use of the fine and micro emulsions provide improved antistatic and antimarring properties to the paper. They also have improved wetting onto the applicator roll and are dilution stable.

Abstract: Cast-coated papers having high surface gloss, smoothness and high surface strength are produced by applying an aqueous pigment coating onto the surface of a base paper, drying the applied pigment coating to form a cast-coated layer, rewetting the pigment coating layer with a rewetting solution, pressing the rewetted pigment coating layer into contact with a heated, highly polished drum to impart a high gloss surface, the rewetting solution containing a dispersant and/or a release agent as its main components and having its pH adjusted to be between 2 and 4 by incorporation of at least one carboxylic acid selected from the group consisting of formic acid, acetic acid, tartatic acid, citric acid, lactic acid, succinic acid, malic acid and benzoic acid.

Abstract: A wear and gouge resistant decorative laminate is made by consolidating, under heat and pressure, a suitable backing over which lays a decor layer covered by an overlay sheet, the overlay sheet being provided on its upper surface with an ultra-thin abrasion resistant layer consistent with the disclosure of Scher et al. U.S. Pat. No. 4,255,480 and optionally O'Dell et al. U.S. Pat. No. 4,499,137.