Multicolor Or Mosaic (e.g., Color T.v. Tube, Etc.) Patents (Class 427/68)
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Patent number: 5690992Abstract: A cathode ray tube in which a glass-enamel layer having particles with a secondary electron emission coefficient smaller than 1, for example Cr.sub.2 O.sub.3 particles, is provided in the neck.The percentage of particles exceeds approximately 30% and the surface resistance ranges between 10.sup.10 and 10.sup.14 .OMEGA./.quadrature.. The high-voltage behaviour of such a layer is satisfactory. The convergence drift is relatively small. In addition, a description is given of a method of providing such a glass-enamel layer.Type: GrantFiled: April 1, 1996Date of Patent: November 25, 1997Assignee: U.S. Philips CorporationInventor: Leonardus Th. M. Van Hout
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Patent number: 5677071Abstract: The present invention is to improve color purity and brightness of a color Braun tube by constructing a fluorescent film for a red fluorescent material as a laminated structure. The present invention relates to a structure of a fluorescent film for a color Braun tube wherein the fluorescent film of the red fluorescent material comprises fluorescent material layers having a laminate structure made of two different compositions of Y.sub.2 O.sub.2 S: Eu and Y.sub.2 O.sub.3 :Eu.Type: GrantFiled: April 16, 1996Date of Patent: October 14, 1997Assignee: LG Electronics, Inc.Inventor: Seoug Wan Kang
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Patent number: 5674553Abstract: A full color three electrode surface discharge type plasma display device that has fine image elements and is large and has a bright display. The three primary color luminescent areas are arranged in the extending direction of the display electrode pairs in a successive manner and an image element is composed by the three unit luminescent areas defined by these three luminescent areas and address electrodes intersecting these three luminescent areas. Further, phosphors are coated not only on a substrate but also on the side walls of the barriers and on address electrodes. The manufacturing processes and operation methods of the above constructions are also disclosed.Type: GrantFiled: June 2, 1995Date of Patent: October 7, 1997Assignee: Fujitsu LimitedInventors: Tsutae Shinoda, Noriyuki Awaji, Shinji Kanagu, Tatsutoshi Kanae, Masayuki Wakitani, Toshiyuki Nanto, Mamaru Miyahara
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Patent number: 5667655Abstract: A method for use in the construction of a color display screen using deposition of a plurality of electroluminescent materials onto a substrate bearing said screen. The method comprises the forming operations a), b), and c) in any sequence: a) forming on the substrate a first pattern of deposition sites covered with a first material selectively strippable by a first agent; b) forming on the substrate a second pattern of deposition sites covered with a second material strippable by a second agent but not significantly attacked by said first agent; and c) forming on the substrate a matrix surrounding the first and second patterns of deposition sites. The method includes thereafter performing a first stripping of the first material with the first agent to reveal first deposition sites within the matrix and performing a first depositing of a first electroluminescent material within the first revealed deposition sites.Type: GrantFiled: April 15, 1996Date of Patent: September 16, 1997Assignee: Zenith Electronics CorporationInventors: Philomena C. Libman, Felix E. Tello
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Patent number: 5660875Abstract: In a method of coating a curved panel in a cathode ray tube, by placing on the inner surface of a panel having a curved surface a screen frame of a boat-shaped configuration across the bottom of which a screen printing screen is stretched; and by moving a squeegee pushed against the surface of the screen so that ink coated on the surface of the screen passes through the screen and prints on the inner surface of the panel, a fluorescent screen having a good and even film is fabricated on the inner surface of the cathode ray tube panel having a curved face, by a screen printing. In the method, electro-conductive terminals for electro-deposition are not required, steps are reduced, production costs are reduced, and production quality is stabilized.Type: GrantFiled: March 22, 1995Date of Patent: August 26, 1997Assignee: Sony CorporationInventors: Tsuneo Muchi, Yoji Kono, Kano Shimizu
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Patent number: 5660876Abstract: A cathode ray tube which comprises a front panel coated with a nonglare film having a multi-layered structure. The multi-layered structure comprises at least a visible light absorbing layer containing a black dye, and an antistatic layer containing an inorganic metal compound as a conductive agent.Type: GrantFiled: June 6, 1995Date of Patent: August 26, 1997Assignee: Sony CorporationInventors: Kunio Kojima, Takashi Setsuda, Takumi Takamura, Kouichi Kaneko, Hideo Kusama
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Patent number: 5655941Abstract: A high luminescence display, and methods for making such a display, are described. A faceplate for a display device having a glass face is provided, having phosphor elements on the glass face. There are reflective elements, on the glass face and adjacent to the phosphor elements, with surfaces angled toward the phosphor elements, whereby light emitted from the phosphor elements reflects off the reflective elements and travels through the glass face. The reflective elements may be formed of, for example, aluminum, and be directly adjacent to the phosphor, or offset from it.Type: GrantFiled: June 23, 1995Date of Patent: August 12, 1997Assignee: Industrial Technology Research InstituteInventors: David Nan-Chou Liu, Jammy Chin-Ming Huang, Jin-Yuh Lu
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Patent number: 5652477Abstract: For use on the outer surface of a faceplate of a display device such as of the cathode ray tube (CRT) type, a first inner antistatic layer of Sb--SnO.sub.2 (particle size between 5-20 nm) is applied to a thickness in the range of 200-600 nm. The Sb--SnO.sub.2 layer has a high light refractive index (n.sub.1 =1.8) and also provides an antireflection function. After pre-heating the faceplate to a temperature in the range of 35.degree.-50.degree. C., a second intermediate antireflection layer of colloidal TiO.sub.2 (light refractive index n.sub.2 =2.0 and particle size between 5-50 nm) is applied over the first inner layer to a thickness of 100-200 nm. A third outer antireflection layer is then applied over the intermediate layer in the form of a silica gel coating at a temperature in the range of 35.degree.-45.degree. C. with a thickness in the range of 100-200 nm and a light refractive index n.sub.3. The second and third antireflective layers follow the 1/4 wavelength rule, where n.sub.3 .perspectiveto..Type: GrantFiled: November 8, 1995Date of Patent: July 29, 1997Assignee: Chunghwa Picture Tubes, Ltd.Inventors: Hua-Sou Tong, Chung-Min Hu, Mi-Yui Hsu
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Patent number: 5641611Abstract: Items of material are patterned on a substrate by forming a layer of photoresist on the substrate and a layer of metal on the photoresist. The photoresist is patterned to define an opening exposing a portion of the substrate and the metal is patterned to define an aperture smaller than the opening so as to divide the exposed surface of the substrate into shadow areas and a non-shadow area. A first material system is evaporated generally perpendicular to the aperture to form a first organic light emitting diode on the surface of the substrate in the non-shadow area and second and third material systems are evaporated at angles to the aperture to form second and third organic light emitting diodes in the shadow areas. Passivation material is evaporated perpendicularly onto the first diode and at the angle onto the second diode.Type: GrantFiled: August 21, 1995Date of Patent: June 24, 1997Assignee: MotorolaInventors: Chan-Long Shieh, Hsing-Chung Lee
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Patent number: 5637357Abstract: A technique for uniformly depositing particles, especially phosphor particles, onto a display panel and an apparatus for carrying out this technique are set forth in this application. This technique relies on both electrostatically and pneumatically passing charged particles to the display panel so that a uniform coating takes place both on the flat surfaces and on the curved surfaces.Type: GrantFiled: December 28, 1995Date of Patent: June 10, 1997Assignee: Philips Electronics North America CorporationInventors: Gustav A. Stachelhaus, Gary S. Gielincki
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Patent number: 5635006Abstract: The fine-line pattern forming method is to form a pattern by transferring the pattern formed on the blanket of which surface is covered with an elastic material mainly composed of silicone resin, on a substrate on which a tack layer is formed.Type: GrantFiled: June 19, 1990Date of Patent: June 3, 1997Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Hirotoshi Watanabe, Yutaka Nishimura, Koji Matsuo, Noboru Aikawa, Masahide Tsukamoto
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Patent number: 5629051Abstract: A method and apparatus for forming an insulator 62 on one major surface of a uniaxial tension focus mask 25 includes the steps of: positioning a mask sheet 27, having a multiplicity of openings 42 that extend from a first major surface of the mask sheet through a main body portion thereof to an oppositely disposed second major surface, at a distance from a charging gun 72, 172 having a source 74, 174 of a dry-powdered insulative material; charging and directing the dry-powdered insulative material toward the first major surface of the mask to provide a coating of the charged, dry-powdered insulative material thereon, and providing means 70, 272 for preventing the charged, dry-powdered insulative material from extending into the openings 42 and being deposited onto the main body portion of the mask surrounding the openings and the second major surface.Type: GrantFiled: September 18, 1995Date of Patent: May 13, 1997Assignee: Thomson Multimedia, S. A.Inventor: Eugene S. Poliniak
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Patent number: 5620572Abstract: A method and apparatus for coating a CRT screen after assembly. The method and apparatus includes isolating a surface portion of the CRT to be coated from the remaining surface to prevent or minimize coating problems resulting from outgassing and to isolate noncompatible components from the deposition environment.Type: GrantFiled: June 7, 1995Date of Patent: April 15, 1997Assignee: Viratec Thin Films, Inc.Inventors: Erik J. Bjornard, Eric W. Kurman, Debra M. Steffenhagen
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Patent number: 5612085Abstract: Provided is a method for making a thin film on a lens holder to reduce a reflection of light caused by an index difference between a refractive index of air and a refractive index of a lens-barrel of the lens holder. The thin film is formed by dipping the lens holder into a solution of a solvent and a fluororesin compound or by dripping the solution onto the lens holder. The lens holder is removed from the solution. Then, the solvent is removed to thereby form a thin film of the fluororesin compound on the lens holder.Type: GrantFiled: April 4, 1994Date of Patent: March 18, 1997Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Katsuaki Mitani, Masayuki Takahashi, Syunsuke Kimura
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Patent number: 5601468Abstract: Predetermined barrier ribs 2 are filled with three types of pastes of fluorescent substances 3 for R, G, and B by a screen printing method. Next, a sandblasting process is performed through a sandblasting mask 7. Thereafter, a sintering process is performed. Thus, fluorescent screens are formed on a glass substrate 1 and the wall surfaces of barrier ribs 2. As the sandblasting mask 7, a photoresist 4 is used. By a photolithographic method, a desired pattern of the sandblasting mask 7 can be used. In this manner, fluorescent screens can be formed on the wall surfaces of the barrier ribs as well as the glass substrate 1. The fluorescent screens formed on the wall surfaces of the barrier ribs are in such a parabolic shape that a discharging space defined by the fluorescent screen is widened toward a front plate 11.Type: GrantFiled: March 20, 1996Date of Patent: February 11, 1997Assignee: Dai Nippon Printing Co., Ltd.Inventors: Hideaki Fujii, Hiroshi Ishiga, Masatoshi Harayama, Motohiro Oka
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Patent number: 5601467Abstract: An improved electroluminescent display of the type having a substrate on which are applied ITO electrodes having dielectric, phosphor and dielectric stacks positioned thereon is formed with cavities between the stacks which expose a portion of each ITO electrode. The structure is annealed before or after the cavities are cut. Then a metal assist structure applied over the exposed portion of each ITO electrode. A planarization layer is applied over each metal assist structure and metal electrodes are placed to complete the display.Type: GrantFiled: June 19, 1995Date of Patent: February 11, 1997Assignee: Northrop Grumman CorporationInventor: Roger Carroll
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Patent number: 5599579Abstract: A cathode-ray tube has a faceplate on which is formed an anti-reflective coating with at least two layers. The first layer is formed on the outer surface of the faceplate by spin-coating an alcohol solution of an organometallic compound, leaving a porous metal oxide layer. The second layer is formed on the first layer by spin-coating an alcohol solution of silicon alkoxide, leaving a porous silica layer. Both layers are baked, and the first layer is baked or cured before the second layer is applied. The first layer has a higher index of refraction than the second layer.Type: GrantFiled: January 5, 1995Date of Patent: February 4, 1997Assignee: Mitsubishi Denki Kabushiki KaishaInventor: Yasuo Iwasaki
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Patent number: 5587201Abstract: A method for manufacturing a screen having high luminance is provided including the steps of forming a phosphor layer on a black matrix adhered to a panel, forming a filming layer by coating and drying a filming composition containing a decomposable organic polymer and a reducing agent on the phosphor layer, forming a metal layer on the filming layer, and heating the phosphor layer, filming layer and metal layer to a temperature sufficient to decompose the filming layer.Type: GrantFiled: March 30, 1995Date of Patent: December 24, 1996Assignee: Samsung Display Devices Co., Ltd.Inventors: Hwan-chul Rho, Hong-gyu Choi, Jae-myung Kim
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Patent number: 5576050Abstract: A film provided on a cathode ray tube is cured by locally subjecting it to a flow of very hot air. The gas flow heats the film without heating the underlying display window. Said gas flow is used to scan the surface.Type: GrantFiled: August 8, 1995Date of Patent: November 19, 1996Assignee: U.S. Philips CorporationInventors: Dirk Van Houwelingen, Johannes A. G. P. Damsteegt, Johannes M. A. A. Compen
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Patent number: 5556664Abstract: There is provided a phosphor screen forming method in which a metal-backing layer formed after baking can be prevented from becoming nonuniform. A phosphor layer (1), an intermediate solution film layer (2), and a lacquer film layer (3) are formed on an inner surface of a panel (P). The intermediate film layer solution contains 1 weight % of oxalic acid. The oxalic acid in the intermediate film layer solution is crystallized by evaporating and drying the intermediate film layer solution and the lacquer, and a crystallized material (4) is grown (FIG. 5A). Thereafter, an aluminum layer (5) is formed on the lacquer film layer (3) (FIG. 5B), and the intermediate solution film layer (2) and the lacquer film layer (3) are removed by baking (FIG. 5C).Type: GrantFiled: September 7, 1994Date of Patent: September 17, 1996Assignee: Sony CorporationInventors: Koichiro Sasa, Shuji Kuramoto, Haruo Kato
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Patent number: 5552178Abstract: A method for preparing an anti-reflective coating is provided which comprises the steps of applying a first coating composition containing an alcohol solution of a silicon alkoxide, at least one metal alkoxide of the formula M(OR).sub.4, an acid and water, where M is a metal selected from the group consisting of Ti, Sn, In and Zr and R is an alkyl group, on the outer surface of a panel to form a first layer; drying the panel at about 40.degree.-80.degree. C. to form a first layer; applying a second coating composition containing an alcohol solution of a silicon alkoxide, a salt selected from the group consisting of KCl, KNO.sub.3, CH.sub.3 COOK, NaCl, NaNO.sub.3, CH.sub.3 COONa, NH.sub.4 Cl, NH.sub.4 NO.sub.3 and CH.sub.3 COONH.sub.4, an acid and water onto the first layer to form a second layer; and heating the first and second layers coated on the outer surface of a panel.Type: GrantFiled: January 28, 1994Date of Patent: September 3, 1996Assignee: Samsung Display Devices Co., Ltd.Inventors: Kang-Il Seo, Dong-Sik Jang, Heon-Soo Kim, Su-Min Jeong
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Patent number: 5547411Abstract: A color cathode ray tube having an improved screen and manufacturing method thereof including a black matrix and a phosphor layer formed on the inner surface of a panel and a metal back covering the tops of the black matrix and the phosphor layer. The metal back is in direct contact with the black matrix and is spaced from the phosphor layer. In the manufacturing method, a film overlapping the black matrix layer is partially removed so as to leave the film above the phosphor layer. This allows the metal back to be applied directly to the black matrix layer and thereby prevents the desquamation of the metal back.Type: GrantFiled: May 31, 1995Date of Patent: August 20, 1996Assignee: Samsung Display Devices Co., Ltd.Inventor: Byeong-yong Lee
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Patent number: 5523114Abstract: For use in a self-emitting color display device such as a cathode ray tube (CRT) having a display screen with a phosphor coating on its inner surface, a surface coating disposed on the display screen's outer surface affords improved color purity, or contrast, by reducing overlap in the color spectrum between two adjacent primary colors, i.e., between red and green and/or between green and blue. An organic dye is added to either an inner antistatic layer or an outer antireflective layer of an antireflective/antistatic outer coating on the display screen, where both of the aforementioned layers contain silane. The dye functions as a color filter absorbing only light within the frequency range between adjacent primary colors, such as between the red and green color phosphors, i.e., in the range of 460-500 nm, and/or between the green and blue color phosphors, i.e., in the range of 560-600 nm. A silane coupling agent is also added to serve as a binding agent bridging the organic dye and silane together.Type: GrantFiled: March 28, 1995Date of Patent: June 4, 1996Assignee: Chung Picture Tubes, Ltd.Inventors: Hua-Sou Tong, Chun-Min Hu, Yu-Chung Yu, Ming-Yu Hsu, Kuo-Chu Wang
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Patent number: 5501928Abstract: A method of manufacturing a luminescent screen assembly on an interior surface of a faceplate panel 12 for a color CRT 10 includes the steps of uniformly applying a solution of a material to form an organic conductive (OC) layer and overcoating the OC layer with a solution to form an organic photoconductive (OPC) layer, on the interior surface of the faceplate panel. The OPC layer 34 is conditioned by directing a stream of dry gas thereon to warm the OPC layer to a preheat temperature, while maintaining the panel at a panel temperature less than the preheat temperature. The OPC layer is exposed to IR radiation to rapidly increase the temperature of the OPC layer to a curing temperature, greater than the preheat temperature, to remove some of the volatilizable constituents from the OPC layer, without substantially increasing the temperature of the panel.Type: GrantFiled: December 14, 1994Date of Patent: March 26, 1996Assignee: Thomson Consumer Electronics, Inc.Inventors: Pabitra Datta, Eugene S. Poliniak, Peter M. Ritt, Brian T. Collins, Harry R. Stork
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Patent number: 5470606Abstract: An antistatic coating was provided on a substrate 10 by dispersing latex particles 12 from a polypyrrole compound in an aqueous solution of a hydrolyzed alkoxysilane compound, after which the dispersion was applied to the substrate. The hydrolyzed alkoxysilane compound was converted to silicon dioxide by means of a treatment at an elevated temperature, thereby forming a matrix 14 in which the latex particles 12 axe dispersed and by means of which the latex particles are adhesively secured to the substrate 10. The antistatic coating can particularly be used on the display screen of a cathode ray tube, and, if desired, said coating can simultaneously be used to reduce the light transmission of the display screen.Type: GrantFiled: June 17, 1994Date of Patent: November 28, 1995Assignee: U.S. Philips CorporationInventor: Johannes De Boer
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Patent number: 5464651Abstract: The present invention relates to phosphors, composition containing phosphors and methods of their use. More particularly, it relates to organic phosphors which are amino acid salts compositions containing the phosphors and methods of using those phosphors and compositions to make objects photo-luminescent.Type: GrantFiled: November 18, 1993Date of Patent: November 7, 1995Assignee: Michigan Biotechnology InstituteInventors: Richard Turk, Paul Nowaczyk
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Patent number: 5460980Abstract: The growth of a phosphor layer deposited on a patterned substrate containing a multiplicity of recessed ridges of triangular cross section can be controlled by tailoring the geometry of the recessed ridge structures. During the deposition process, little or no phosphor deposition occurs on the recessed ridge structures, and cracks are formed which separate the otherwise uniformly growing phosphor which is present in other regions of the patterned substrate where more substantial phosphor deposition occurs.Type: GrantFiled: October 17, 1994Date of Patent: October 24, 1995Assignee: Minnesota Mining and Manufacturing CompanyInventors: Nang T. Tran, Kenneth R. Paulson, Bruce A. Sventek
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Patent number: 5435938Abstract: Electrolytes are attached to fluorescent particle surfaces to prevent open spots in cathode-ray tube coatings dried at high temperatures. Electrolytes that are sulfates, nitrates, or chlorides of alkali or alkaline-earth metals are added to a liquid suspension of fluorescent particles which have passed through a cleaning step. Electrolytes are added to the suspension to make the conductivity of the clear top liquid greater than 30 .mu..OMEGA..sup.-1 cm.sup.-1. The fluorescent particle preparation process is finished with a final dehydration and drying step.Type: GrantFiled: March 10, 1994Date of Patent: July 25, 1995Assignee: Nichia Chemical Industries, Ltd.Inventors: Shoichi Bando, Yoshikatsu Aihara
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Patent number: 5427818Abstract: An antiglare/antistatic coating for a cathode ray tube (CRT) is applied to the outer surface of the CRT's faceplate and includes a first inner hygroscopic layer of silane, water, sulfuric acid and an alcohol mixture which may be applied by dipping, spinning or spraying. The coating further includes a second outer layer of silanes, water, acid, epoxy, and a coupling agent balanced with an alcohol mixture which is sprayed onto the first inner layer. The grounded first inner layer possesses high conductivity for antistatic protection, while the second outer layer, which possesses glass-like characteristics, provides antiglare protection by reducing the faceplate's reflectivity. The second outer layer dries as a hard porous coating which resists scratching and allows water vapor to penetrate into the first inner hygroscopic layer to maintain its high conductivity.Type: GrantFiled: August 11, 1994Date of Patent: June 27, 1995Assignee: Chunghwa Picture Tubes, Ltd.Inventors: Hua-Sou Tong, Chun-Min Hu
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Patent number: 5418005Abstract: A method for reclaiming a pigment-attached red-emitting phosphor recovered from a manufacturing process for a color picture tube, which comprises treating the phosphor with an aqueous solution containing NaOH, NaClO and H.sub.2 O.sub.2 and then treating it with a weak acid, whereby the pigment can be prevented from exfoliation by suppressing the dissolution of the binder which attaches the pigment to the phosphor, and blue- and green-emitting phosphors contained as contaminants in the recovered red-emitting phosphor can be completely removed. The method provides a reclaimed red-emitted phosphor with high luminance and a good coating property.Type: GrantFiled: September 24, 1993Date of Patent: May 23, 1995Assignee: Kasei Optonix, Ltd.Inventors: Hideo Endo, Shinsuke Aoki, Chihiro Yoshida
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Patent number: 5415815Abstract: There is disclosed a film composition useful for reducing light glare especially adapted for use in connection with cathode-ray tube or other monitor screens which is formed from a colloidal suspension from between ten percent to thirty percent by weight of an aliphatic thermoplastic urethane resin dissolved in a blend of water, N-methylpyrrolidone and amines, mixed with between seventy percent and ninety percent by weight of Denatured Ethyl Alcohol (190 proof). The colloidal suspension is admixed with an aerosol propellant under pressure, and is deposited on a monitor screen by aerosol deposition to create a film having a thickness of between 0.5 mil and 2 mil. The deposited film dries immediately, and functions to dramatically reduce the glare of light reflecting from the screen monitor.Type: GrantFiled: July 14, 1993Date of Patent: May 16, 1995Inventor: Art Bruno
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Patent number: 5387436Abstract: The invention relates to a method of coating red-luminescing phosphor particles with hematite (.alpha.--Fe.sub.2 O.sub.3), whereby first Fe(OH).sub.3 is deposited on the phosphor particles and subsequently converted into .alpha.--Fe.sub.2 O.sub.3 at a raised temperature. A good adhesion of the hematite pigments to the phosphor particles is achieved in that first an aqueous solution of an iron(III) salt and a complexing agent is prepared, in which the complexing agent and its concentration are so chosen that in combination with Fe.sup.3+ ions complex ions are formed which on the one hand do not yet precipitate at a pH-value which is at least 0.5 higher than the value at which the phosphor particles just fail to be chemically attacked anymore, and which are dissociable at a further increase in the pH-value so that Fe(OH).sub.3 is formed, in that subsequently, if the pH-value is not yet high enough, a basic substance is added to the mixture, in that the pH-value is increased to a value which is at least 0.Type: GrantFiled: November 16, 1993Date of Patent: February 7, 1995Assignee: U.S. Philips CorporationInventors: Cornelis Ronda, Guido Hutten, Michael Bredol, Ulrich Kynast, Thomas Rink
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Patent number: 5372903Abstract: Respective phosphor layers (3R), (3G) and (3B) and a light absorption layer (2) are formed on the inner surface of a panel. An intermediate layer (11) is selectively formed on the surfaces of the respective phosphor layers by using a water soluble liquid having photosensitivity and containing water dispersion vinyl polymer emulsion and partial saponification polyvinyl acetate-system photosensitizer and then a metal-backing layer (12) is formed. A color purity of a phosphor screen can be increased and a brightness thereof can be improved.Type: GrantFiled: February 3, 1993Date of Patent: December 13, 1994Assignees: Sony Corporation, Oji Kako, Co., Ltd.Inventors: Norihiro Tateyama, Katsutoshi Ohno, Tsuneo Kusunoki, Hiroshi Itoh, Shuichi Nakazato, Naoki Isobe
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Patent number: 5369331Abstract: The present invention provides a pigment-attached blue-emitting phosphor having attached a blue pigment which has fastness and chemical stability and is excellent in reflection spectrum characteristics, and a color cathode-ray tube having a blue-emitting fluorescent layer containing the blue pigment formed on the inner surface of a face plate.The present invention also provides a pigment-attached blue-emitting phosphor having a CoO.ZnO.SiO.sub.2 type blue pigment attached thereto, and a color cathode-ray tube provided with a blue-emitting fluorescent layer containing the blue pigment particles on the inner surface of a face plate.Type: GrantFiled: February 3, 1993Date of Patent: November 29, 1994Assignee: Kasei Optonix, Ltd.Inventors: Tomohito Mizukami, Chihito Funayama, Yasuo Oguri
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Patent number: 5368886Abstract: A color cathode-ray tube having a fluorescent screen of red-, blue- and green-emitting phosphors as image elements of a fluorescent layer, wherein at least one of said phosphors is coated with a double oxide of zinc and aluminum.Type: GrantFiled: November 15, 1993Date of Patent: November 29, 1994Assignee: Kasei Optonix Ltd.Inventors: Hideo Tono, Masaru Naito, Tomohiro Miyazaki
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Patent number: 5366758Abstract: This invention relates to a method of coating an inner surface of a funnel of a cathode ray tube with lining graphite acting as an inner conductive film between a screen portion and a high voltage side, i.e., an electron gun of the cathode ray tube. According to the method, the lining graphite is coated on the entire inner surface of the funnel with the exception of only an area of the portion of the surface, on which a getter or a frittable getter is located.Type: GrantFiled: April 8, 1992Date of Patent: November 22, 1994Inventor: Hyung I. Jang
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Patent number: 5352478Abstract: A plasma display panel comprises a front plate disposed on the side of a viewer, a rear plate disposed in parallel and opposing the front plate, and cell barriers arranged between the front and rear plates of matrix shape or linear shape. The cell barrier is formed of a material including a phosphor. The cell barriers are formed by printing multiple times a phosphor paste containing glass frit in an overlapped manner by a screen printing method. The cell barrier is formed in another method in which a positive pattern of cell barriers are formed on the front or rear plate by using photo resist, a slurry containing a phosphor fills in portions except for the pattern of the photo resist, and the photo resist is thereafter removed to thereby form cell barriers. In the case of the cell barrier of a color display PDP, the cell barrier may be composed of a material containing phosphor of different colors each with a width corresponding to a one half width of the cell barrier.Type: GrantFiled: April 17, 1992Date of Patent: October 4, 1994Assignee: Dai Nippon Insatsu Kabushiki KaishaInventors: Toru Miyake, Yoshiki Kudo, Naoshige Higuchi
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Patent number: 5340673Abstract: A method of forming a phosphor screen in which a color filter layer is formed between a phosphor layer and an inner surface of a panel having a slurry in which a fine particle pigment and transparent particles are dispersed into a photosensitive liquid coated on the inner surface of the panel. Then, the color filter layer is formed by exposure and development. When the color filter layer that constitutes one portion of a phosphor screen of a color cathode ray tube is formed in this manner, an adhesive force with which the color filter layer is bonded onto the panel can be increased and a transmittance of the color filter layer can be improved.Type: GrantFiled: March 22, 1993Date of Patent: August 23, 1994Assignee: Sony CorporationInventors: Norihiro Tateyama, Katsutoshi Ohno, Tsuneo Kusunoki
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Patent number: 5336080Abstract: A cathode-ray tube phosphor is manufactured by coating, on the surfaces of phosphor particles, a mixture of a metal alginate containing at least one type of a metal selected from the group consisting of Zn, Al, and an alkali earth metal and at least one type of a water-soluble binder selected from the group consisting of gum arabic, gelatin, polymethacrylamide, and polyvinyl alcohol.Type: GrantFiled: December 17, 1992Date of Patent: August 9, 1994Assignee: Nichia Chemical Industries, Ltd.Inventors: Miyuki Sumitomo, Ichiro Takeoka, Shoichi Bando
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Patent number: 5334409Abstract: A cathode ray tube having an antistatic and non-glare coating with a controlled and uniform degree of unevenness, can be produced by the process which comprises the steps of mixing an alcohol solution of an acid and a partially hydrolyzed alkylsilicate monomer with an amount of water being of at least four times greater than the number of moles of the alkylsilicate; applying the mixed solution to the outer surface of the panel by spin coating; followed by heating the resulting coating to a temperature in the range of 150.degree. to 200.degree. C. to form an antistatic and non-glare coating.Type: GrantFiled: July 7, 1992Date of Patent: August 2, 1994Assignee: Samsung Electron Devices Co., Ltd.Inventors: Chang-min Sohn, Su-min Jeong
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Patent number: 5334410Abstract: The following steps are performed in a method of lacquering the luminophore layer of a colour picture tube:the luminophore layer is first prewetted,a first aqueous dispersion of a lacquer is applied to the prewetted luminophore layer,this first dispersion is fully dried and heated to above the film formation temperature of the lacquer, thereby producing a first lacquer film,a second aqueous dispersion is applied directly to the first lacquer film, where the said second aqueous dispersion has exactly the same components as the first dispersion and the concentration of the components in the second dispersion corresponds at least to a large extent to the concentration of these components in the first dispersion, andthis second dispersion is fully dried and heated to above the film formation temperature of the lacquer, thereby producing a second lacquer film.Type: GrantFiled: November 5, 1991Date of Patent: August 2, 1994Assignee: Nokia Unterhaltungselektronick GmbHInventors: Heinz Beckerle, Rolf Reidinger
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Patent number: 5330791Abstract: A method of reclaiming a phosphor from a recovered phosphor slurry containing carbon, a bichromate, and polyvinyl alcohol, comprises, (a) a decomposition treatment step of adding an alkali to the recovered phosphor slurry after the slurry is heated to prepare a phosphor suspension having an alkali concentration of 0.5N or less in the slurry, and adding an oxidizing agent in an amount of 1.0 to 20.0 wt % with respect to a dry solid component of the suspension, (b) a weak acid treatment step of separating a phosphor from the suspension, and adding a weak acid to a suspension obtained by adding water to the separated phosphor, thereby adjusting a pH to be 3.0 to 5.0, and (c) a surface treatment step of treating the surface of the phosphor separated from the suspension.Type: GrantFiled: April 16, 1993Date of Patent: July 19, 1994Assignee: Nichia Kagaku Kogyo K.K.Inventors: Yoshikatsu Aihara, Tomokazu Suzuki, Yoshiaki Shizuki, Shoichi Bando, Katsunori Uchimura
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Patent number: 5326588Abstract: A method for manufacturing a screen of a color cathode ray tube, comprising the steps of: (a) coating an adhesion strengthening layer over the inner surfaces of a panel and a panel skirt; (b) coating black matrix stripes and fluorescent stripes on the adhesion strengthening layer in the panel; (c) coating a pyrolysis mitigating layer on said adhesion strengthening layer within the panel skirt; (d) coating an organic film on the black matrix and fluorescent stripes; and (e) coating a thin metal film on the resultant structure. The pyrolysis of the poly vinyl alcohol is delayed during baking by the acryl emulsion contained in the pyrolysis mitigating layer. This process prevents swelling up and peeling off of the thin metal film during the baking step, and reduces inferior products that result from the peeling off of pieces of the metal layer.Type: GrantFiled: July 3, 1991Date of Patent: July 5, 1994Assignee: Samsung Electronic Devices Co., Ltd.Inventor: Hang-ku Ji
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Patent number: 5322707Abstract: The present invention discloses a phosphor slurry composition for color Braun tubes comprising deionized water, phosphor powder, polyvinyl alcohol, sodium dichromate, ethyl silicate and zinc sulfate. A color Braun tube manufactured using a phosphor slurry composition of the present invention shows an excellent mirror reflection effect and high luminescent brightness.Type: GrantFiled: July 9, 1993Date of Patent: June 21, 1994Assignee: Samsung Electron Devices Co. Ltd.Inventors: Ikchull Ihm, Minho Kim
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Patent number: 5316785Abstract: The present invention is directed to a method of and apparatus for forming a coating film on an inner surface of a panel of a cathode ray tube. In this case, slurries are injected into the panel, the panel is rotated on its own axis so as to uniformly coat the slurries on the panel and a recovering hood is moved in an opposing relation to the panel in synchronism with the revolution of the panel to thereby recover the slurries. Therefore, particularly when the slurries are recovered, the slurries can be prevented from being scattered, thereby avoiding the surroundings from being splattered.Type: GrantFiled: September 27, 1991Date of Patent: May 31, 1994Assignee: Sony CorporationInventors: Kunihiko Yanai, Yasuo Tanaka, Yasunori Niwa
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Patent number: 5310504Abstract: The present invention discloses a phosphor slurry composition for color Braun tubes comprising deionized water, phosphor powder, polyvinyl alcohol, sodium dichromate, ethyl silicate and zinc sulfate. A color Braun tube manufactured using a phosphor slurry composition of the present invention shows an excellent mirror reflection effect and high luminescent brightness.Type: GrantFiled: August 6, 1992Date of Patent: May 10, 1994Assignee: Samsung Electron Devices Co., Ltd.Inventors: Ikchull Ihm, Minho Kim, Ichull Ihm
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Patent number: 5286585Abstract: A method of forming a phosphor layer on the screen panel of a cathode-ray tube include the steps of charging phosphor slurry on the inside of the screen panel, rotating the screen panel to spread the phosphor slurry forming the phosphor layer, and exposing the screen panel to a light disposed in front of the inside of the screen panel and a plurality of lights disposed in front of the outside of the screen.Type: GrantFiled: December 23, 1991Date of Patent: February 15, 1994Assignee: Goldstar Co., Ltd.Inventor: Jae K. Lee
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Patent number: 5277840Abstract: A phosphor paste composition is disclosed, which uses as an organic binder an acrylic polymer obtained by copolymerizing an alkyl methacrylate as a principal component with a specific amount of at least one monomer selected from unsaturated carboxylic acids and hydroxyalkyl (meth)acrylates. Also disclosed is a phosphor paste composition making use of a phosphor having a volume average particle size in a range of 1-7 .mu.m, with particles having a particle size of 1-9 .mu.m accounting for at least 60 wt.%. These phosphor paste compositions have excellent firing characteristics and provide phosphor coatings excellent in both light-emitting characteristics and resolution.Type: GrantFiled: April 24, 1992Date of Patent: January 11, 1994Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Norihisa Osaka, Yukihiro Ikegami
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Patent number: 5264478Abstract: The present invention discloses a filming liquid composition for color Braun tubes comprising deionized water, an acrylic emulsion, ammonium oxalate, ethyl silicate, and titanium oxide, aluminium oxide or a mixture thereof. The color Braun tube manufactured using the filming liquid composition shows the characteristics of high reflection efficiency of the aluminium vacuum evaporation film and excellent luminescent brightness of the color Braun tube.Type: GrantFiled: August 6, 1992Date of Patent: November 23, 1993Assignee: Samsung Electron Devices Co., Ltd.Inventors: Minho Kim, Ikchull Ihm
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Patent number: 5256463Abstract: A method for manufacturing a phosphor screen used in a color CRT takes the steps of multilayering a red phosphor layer, a green phosphor layer, a blue phosphor layer, and a non-luminescent layer being laid between the adjacent color phosphor layer, cutting the multilayered block into filmy pieces toward the thickness, adhering or pressurizing the filmy cut pieces on a glass plate for front panel of the color CRT, and burning the cut pieces. This method makes it possible to efficiently manufacture a high-definition and high-resolution color phosphor screen and form fine RGB stripes. This method, thus, may apply to a small-sized CRT about which the realization of the high-definition and high-resolution color phosphor screen has been difficult.Type: GrantFiled: May 31, 1991Date of Patent: October 26, 1993Assignee: Mitsubishi Rayon Co., Ltd.Inventors: Norihisa Osaka, Yukihiro Ikegami