Multicolor Or Mosaic (e.g., Color T.v. Tube, Etc.) Patents (Class 427/68)
-
Patent number: 4732828Abstract: In a method for a phosphor screen of a cathode ray tube including the steps of forming a photo-tacky layer on a panel of a cathode ray tube, exposing the photo-tacky layer to form an adhesive pattern on the layer, and adhering phosphor powder on the adhesive pattern, in which these exposing and adhering steps are repeated. Before next exposing step, the photo-tacky layer is heated and then exposed after cooled. The heating step prevents the sensitivity of the layer from deterioration occurred by the preceding adhering step.Type: GrantFiled: November 5, 1986Date of Patent: March 22, 1988Assignee: Kabushiki Kaisha ToshibaInventors: Seiji Sagou, Takeo Itou
-
Patent number: 4729907Abstract: An aluminized viewing screen structure for a cathode-ray tube includes a faceplate panel having a barrier coating and a heat absorptive overcoating comprising a plurality of layers overlying the aluminum metal layer. The barrier coating and the overcoating are applied to the panel which is preheated to accelerate drying of the barrier coating and the overcoating. The novel process includes (a) tilting the preheated panel to a 60.degree..+-.10.degree. angle relative to a horizontal plane, (b) loading the tilted panel onto a carrier, (c) and advancing the carrier by means of a conveyor in a first direction, through a spray assembly. A plurality of spray guns are mounted on a reciprocating device which moves up and down, that is, in a second and a third direction which is different from the direction of motion of the conveyor. The spray guns are directed substantially perpendicular to the faceplate panel.Type: GrantFiled: February 24, 1987Date of Patent: March 8, 1988Assignee: RCA CorporationInventors: Samuel B. Deal, Richard A. Lambert
-
Patent number: 4728519Abstract: In order to provide a structure which is not susceptible to the so called "peel-off" phenomenon which tends to occur with arrangements wherein electroluminescent layers are arranged one over the top of each other in discrete overlapping layers, and to avoid the use of yeild reducing etchants which readily attack the electroluminescent material through the inevitable pin holes and cracks which appear in the insulating layers covering the elements during the production of the panel, the light emitting elements are formed in side by side or non-overlapping relationships via a lift off technique. This obviates both the peel-off phenomenon and use of corrosive etchants.Type: GrantFiled: November 16, 1984Date of Patent: March 1, 1988Assignee: Nissan Motor Co., Ltd.Inventor: Satoshi Tanimoto
-
Patent number: 4717590Abstract: A process is disclosed for bonding pigment particles to phosphor particles. The process involves forming a relatively uniform blend of a phosphor, one or more pigments, colloidal silicon dioxide, and water, with the amount of water in the blend being no greater than about 10% by weight, and heating the blend at a temperature of at least about 150.degree. C. to produce a pigmented phosphor having an overcoating of silicon dioxide.Type: GrantFiled: November 28, 1986Date of Patent: January 5, 1988Assignee: GTE Products CorporationInventors: Robert W. Wolfe, Harry O. Schulze
-
Patent number: 4695477Abstract: In coating a smooth glass faceplate panel with phosphor to produce a phosphor screen for use with flat color picture tubes, a basic mask is placed onto the glass faceplate panel. Thereafter; one at a time, one coating mask for each respective color is placed over the basic mask and the phosphor belonging to the respective coating mask is deposited. The phosphor is dispersed in a reactive binder and meets with an activator sprayed on or otherwise applied to the glass faceplate panel.Type: GrantFiled: July 3, 1985Date of Patent: September 22, 1987Assignee: Standard Elektrik Lorenz AGInventor: Uwe Viohl
-
Patent number: 4690832Abstract: A process is disclosed for making a rare earth oxysulfide phosphor resistant to hydrolysis. The process involves adding to a water slurry of the phosphor a sufficient amount of a source of silicon dioxide and a water soluble salt which can be an alkaline earth metal salt or a transition group IIB metal salt with agitation for a sufficient time to form a silicate coating on the phosphor with the cation of the water soluble salt becoming the cation of the silicate coating, the amount of the coating being sufficient to impart hydrolysis resistance thereto. The resulting silicate coated phosphor is then separated from the resulting liquor and heated at a sufficient temperature for a sufficient time in ambient atmosphere to remove essentially all of the water therefrom and to produce the final hydrolysis resistant phosphor.Type: GrantFiled: December 9, 1986Date of Patent: September 1, 1987Assignee: GTE Products CorporationInventor: Ramon L. Yale
-
Patent number: 4680196Abstract: A method is disclosed for use in the manufacture of a color cathode ray tube having a shadow mask with a pattern of minute apertures for color selection. A removable film effective to prevent particle occlusion of the apertures is disposed on at least one side of the mask. The film has an extremely small, substantially uniform thickness dimension, a low index of refraction, and is of such high transparency as to exhibit a negligible optical effect during photoscreening operations.Type: GrantFiled: April 15, 1986Date of Patent: July 14, 1987Assignee: Zenith Electronics CorporationInventor: Leonard Dietch
-
Patent number: 4670296Abstract: The present invention is to positively provide a light pen pick-up phosphor pattern by the application of an inverting method and the selection of its slurry composition. That is, this invention relates to a method for producing a phosphor screen of a cathode ray tube which comprises the steps of forming a photo-sensitive material layer with a predetermined pattern on the inner surface of a cathode ray tube panel, coating on the whole surface of the panel including the photo-sensitive material layer with a phosphor slurry for use in light pen pick-up and removing the photo-sensitive material layer to thereby form a light pen pick-up phosphor pattern which is an inverted pattern of the former pattern.Type: GrantFiled: June 18, 1985Date of Patent: June 2, 1987Assignee: Sony CorporationInventor: Yukio Akiba
-
Patent number: 4657961Abstract: In a phosphor screen of cathode ray tube produced by forming a lacquer film between phosphor layers and a metallic film, when the lacquer film is formed by using a composition comprising a resin component, an organic solvent and a plasticizer in an amount of about 12 to 60% by weight based on the weight of the resin component, the resulting phosphor screen is excellent in adhesive strength of the metallic film and can prevent color mixing and halation.Type: GrantFiled: July 13, 1982Date of Patent: April 14, 1987Assignee: Hitachi, Ltd.Inventors: Masahiro Nishizawa, Hiroshi Yokomizo, Kiyoshi Miura, Osamu Sasaya
-
Patent number: 4656389Abstract: A novel color selection electrode assembly is utilized in screening a pattern of phosphor areas upon the faceplate of a color cathode ray tube. The faceplate, which is formed of a material having a predetermined temperature coefficient of expansion, has registration affording means. The aforesaid assembly comprises an auxiliary mount formed of a material having a temperature coefficient of expansion greater than that of the faceplate and has a central opening of such span as to enable the mount to surround the periphery of the faceplate. Index bosses, cooperable with the faceplate registration affording means, are detachably secured to the mount. A planar metal foil having a predetermined pattern of apertures and formed of a material having a temperature coefficient of expansion not greater than that of the mount is secured to the mount.Type: GrantFiled: October 25, 1985Date of Patent: April 7, 1987Assignee: Zenith Electronics CorporationInventor: Kazimir Palac
-
Patent number: 4652462Abstract: Disclosed herein is a method of producing a phosphor screen of color picture tube wherein a light absorbing material is applied onto the inner surface of a panel, a shadow mask is provided, the surface of film of the light absorbing material is scanned and irradiated with a laser beam via the shadow mask so that portions of the light absorbing material irradiated with the laser beam are heated and burned, thereby to form a black matrix. According to this method, the number of steps for forming the black matrix is decreased, and the quality and yield of the phosphor screen are increased.Type: GrantFiled: August 8, 1985Date of Patent: March 24, 1987Assignee: Hitachi, Ltd.Inventors: Masahiro Nishizawa, Kiyoshi Miura, Osamu Sasaya, Yoshiyuki Odaka
-
Patent number: 4651053Abstract: A display tube such as a cathode ray tube or fluorescent display tube which includes a film layer over the phosphor layer, and including a random copolymer with the following chemical structure: ##STR1## wherein R.sub.1, R.sub.3 represent individually H or CH.sub.3 ; R.sub.2 is H; and X is OH. The layer can be formed over the phosphor layer uniformly and thinly by means of a printing process to thereby shorten the manufacturing process and reduce the cost of manufacture.Type: GrantFiled: December 26, 1984Date of Patent: March 17, 1987Assignee: Sony CorporationInventors: Hiroshi Kato, Toshihisa Kojima, Kazuo Yamazaki
-
Patent number: 4630097Abstract: A 2D/3D compatible polarized TV system is described which comprises a 3 color TV camera with pairs of adjacent 3D right and left images in each color. The image pairs are scanned to derive pairs of 3D image signals. These 3D signals are presented as 3 color pixels alternately polarized orthogonally. The display may be viewed without glasses to see a 2D color image with either the right or left images suppressed; or with polarized viewers to see a color 3D image. A method of manufacturing orthogonally oriented polarized color pixels is described utilizing inorganic polarizing dipoles electrostatically aligned in a fusible transparent coating.Type: GrantFiled: August 16, 1983Date of Patent: December 16, 1986Inventor: Alvin M. Marks
-
Patent number: 4624861Abstract: Rare earth oxysulfide phosphors and processes for creating the phosphors are disclosed.One process involves wet milling a material comprising a rare earth oxysulfide, removing soluble impurities, drying, forming a relatively uniform admixture comprising the dried material and aluminum oxide with the aluminum oxide content being from about 0.1 to about 1.0 weight percent of the admixture, followed by heating the admixture at a sufficient temperature for a sufficient time to form the phosphor.Another process involves the wet milling, soluble impurity removal and drying steps described above. The dried material is then dry milled without aluminum oxide, and heated as described above.Another process involves the wet milling, soluble impurity removal, drying, dry milling, and heating steps described above except that the material is dry milled with from about 0.1 to about 1.0 weight percent of aluminum oxide.Type: GrantFiled: September 5, 1985Date of Patent: November 25, 1986Assignee: GTE Products CorporationInventors: Ramon L. Yale, Nelson W. Shearer
-
Patent number: 4590092Abstract: On the internal face of the frontal panel forming a color television tube, in order to obtain a cathodoluminescent screen, phosphors are deposited. A layer of aluminum must be deposited on the phosphors. An intermediate smoothening product, later decomposed, permits to obtain a layer of a satisfactory quality. A layer of ammonium tetraborate, forming microcrystals, is deposited on the product, piercing the aluminum layer so as to help the discharge of gases resulting from the decomposition of the intermediary layer.Type: GrantFiled: September 26, 1984Date of Patent: May 20, 1986Assignee: VideocolorInventors: Gabriel Giancaterini, Francisco Pacifici
-
Patent number: 4585673Abstract: Disclosed is a method for applying a continuous protective coating to the surface of individual phosphor particles. The method involves chemical vapor deposition of the protective coating on individual particles of a phosphor powder while the phosphor particles are suspended in a fluidized bed. During the method, the fluidized particles are exposed to the vaporized coating precursor material at a first temperature, which is less than the decomposition temperature of the precursor material, and the precursor material is reacted to form the desired coating material at a second temperature, which is greater than or equal to the temperature at which the precursor material reacts to form the coating material.Type: GrantFiled: April 3, 1985Date of Patent: April 29, 1986Assignee: GTE Laboratories IncorporatedInventor: A. Gary Sigai
-
Patent number: 4582761Abstract: A dispersion for coating a reflective-transmissive surface comprising a mixture of an aqueous dispersion of polyvinyl acetate resin and an aqueous dispersion of an arcylic resin. When applied to such surfaces--for example, the protective glass or plastic of an electronic screen--the coating reduces reflected glare while maintaining the quality of the image transmitted from the screen being viewed. Methods of making and using the dispersion, as well as surfaces treated with the dispersion, are also disclosed.Type: GrantFiled: July 31, 1984Date of Patent: April 15, 1986Inventor: Peter D. Liu
-
Patent number: 4564572Abstract: A process for forming a pattern on the interior side of a face plate of a color picture tube by using a photosensitive composition comprising p-diazo-N,N-dimethylaniline chloride-zinc chloride double salt and a p-diazo-bromophenol chloride-zinc chloride double salt and conducting imagewise exposure of coated film of the photosensitive composition to light and contacting with powder particles at least one time gives higher sensitivity compared with a conventional process.Type: GrantFiled: January 24, 1985Date of Patent: January 14, 1986Assignee: Hitachi, Ltd.Inventors: Hajime Morishita, Kiyoshi Miura, Osamu Sasaya, Saburo Nonogaki
-
Patent number: 4556620Abstract: Image display including a viewing screen comprising spaced elemental image areas and a light-absorbing matrix of crystalline zinc-iron sulfide particles adjacent to these areas. The display may be made by producing a layer which is tacky in substantially the pattern of the desired matrix, and then contacting crystalline zinc-iron sulfide particles with the tacky pattern, whereby particles adhere to the tacky pattern, thereby producing the desired matrix.Type: GrantFiled: January 16, 1985Date of Patent: December 3, 1985Assignee: RCA CorporationInventor: Robert P. Thompson
-
Patent number: 4551652Abstract: Corrosion of an aluminium film on the display screen of a display tube as a result of an electro-chemical reaction between water and aluminium is substantially prevented by providing the aluminium with an aluminium phosphate layer at the area where it adjoins the carbon particles. This may be done by rinsing or spraying the carbon particles with an at most 2% by weight phosphoric acid solution in water prior to or after providing the aluminium film.Type: GrantFiled: June 1, 1982Date of Patent: November 5, 1985Assignee: U.S. Philips CorporationInventors: Johannes M. A. A. Compen, Cornelis Maan
-
Patent number: 4550032Abstract: An electrically conductive layer on a wall portion of the envelope of an electric discharge tube which comprises an electrically conductive material and at least 5% by weight of silicon dioxide as an adhesive, adheres readily, is hard and can be washed with water.Such a layer can be obtained from a suspension comprising an electrically conductive material and a binder in a solvent, in which the binder is a quaternary ammonium silicate or a solution of silicon dioxide (SiO.sub.2) in phosphoric acid (H.sub.3 PO.sub.4), in which the mol ratio SiO.sub.2 /P.sub.2 O.sub.5 is between 0.3:1 and 20:1.Type: GrantFiled: March 1, 1984Date of Patent: October 29, 1985Assignee: U.S. Philips CorporationInventors: Johannes M. A. A. Compen, Wilhelmus M. P. van Kemenade
-
Patent number: 4547696Abstract: A color tube comprises a panel having a patterned screen of phosphor deposits. The panel includes a registration affording arrangement defined by a first plurality of cavities each comprising an elongated, substantially radially aligned portion formed at a selected peripheral location upon the screen side of the panel. A frame dimensioned to enclose the screen comprises first and second spaced-apart surfaces and a registration affording arrangement defined by a second like plurality of cavities, each also comprising an elongated, substantially radially aligned portion formed at a selected peripheral location upon the frame's first surface. The pluralities of panel and frame cavities are arranged so that, collectively, the axes of the elongated portions of the panel cavities and of the frame cavities exhibit substantially the same radial geometry. A tensed foil color selection electrode having a pattern of apertures has a peripheral portion bonded to the frame's second surface.Type: GrantFiled: January 18, 1984Date of Patent: October 15, 1985Assignee: Zenith Electronics CorporationInventor: Paul Strauss
-
Patent number: 4542038Abstract: A method of manufacturing a cathode-ray tube is provided, wherein in forming a phosphor screen on the inner surface of a faceplate of the cathode-ray tube, the inner surface of the faceplate faces downward while the faceplate is rotated about the axis of the cathode-ray tube, and a liquid material for forming a film is sprayed from a supply nozzle arranged to be substantially perpendicular to the inner surface of the faceplate so as to spray the liquid material on the inner surface of the faceplate along all directions, thereby forming a uniform film throughout the inner surface of the faceplate.Type: GrantFiled: September 27, 1984Date of Patent: September 17, 1985Assignee: Hitachi, Ltd.Inventors: Yoshiyuki Odaka, Kouichi Nakazato, Yoshifumi Tomita
-
Patent number: 4517224Abstract: In a method for preparing a luminescent screen which includes optionally depositing a light-absorbing matrix upon a support, depositing a phosphor-and-binder layer on the support, and then coating the phosphor layer with a film of organic polymeric material, the steps for salvaging the support and matrix, if present, substantially undisturbed while substantially entirely removing the overlying material. In the method, the overlying material is contacted with an aqueous hydroxide-and-peroxide solution until the binder and film are at least partially solubilized. Then, the overlying material is substantially entirely flushed away by flushing, sloshing, or low-pressure spraying with an aqueous medium.Type: GrantFiled: August 18, 1983Date of Patent: May 14, 1985Assignee: RCA CorporationInventor: Lawrence H. Ditty
-
Patent number: 4515827Abstract: Red cathode ray phosphors are coated with a vapor deposited layer of cadmium selenide in order to achieve controlled color shifts in the light output of the phosphors. Such coated phosphors are especially suited for color television and monitor applications.Type: GrantFiled: June 17, 1982Date of Patent: May 7, 1985Assignee: GTE Products CorporationInventors: Robert E. Dodds, David J. Harrigan
-
Patent number: 4513025Abstract: A single particle penetration phosphor employs La.sub.2 O.sub.2 S:Tb particles as a core particle having a thin layer of La.sub.2 O.sub.2 SO.sub.4 :Tb formed thereon by oxidation to provide a barrier which must be penetrated by excitation electrons to produce narrow bandwidth green spectral emission from the particle. The thin barrier is in turn coated by a layer of YVO.sub.4 :Eu particles which produce narrow bandwidth red spectral emission upon electron excitation. The barrier layer increases the voltage turn on characteristic of the green carrier host thereby causing the electron irradiated phosphor to radiate in the red spectrum for low voltages and in the green spectrum for higher voltages. Additionally, methods are disclosed for synthesizing the above single particle penetration phosphor.Type: GrantFiled: May 11, 1982Date of Patent: April 23, 1985Assignee: Sperry CorporationInventors: Thomas E. Clark, Charles T. Burilla
-
Patent number: 4513024Abstract: A phosphor screen good in quality without greatly lowering brightness can be produced on a cathode-ray tube faceplate by the settling process wherein there is used a suspension of phosphor particles which are susceptible to hydrolysis or dissolution prepared by using an alkaline aqueous solution having a pH of 10 to 13 and if necessary with a small amount of water glass, or the above-mentioned phosphor suspension is poured into a cushion solution having a pH of 10 to 13, said cushion solution being able to contain a small amount of water glass.Type: GrantFiled: August 16, 1982Date of Patent: April 23, 1985Assignee: Hitachi, Ltd.Inventors: Yasukazu Morita, Naomitsu Watanabe
-
Patent number: 4504408Abstract: The present invention is a vapor phase activator pad which produces fluorescent vapor fumes for use in a self-contained fingerprinting kit. The vapor phase activator pad is placed into an enclosed area order to fume an object in the area suspected of containing latent fingerprints. The vapor phase activator pad includes a fluorescent dye impregnated gauze pad and a composition. The composition consists of specified chlorinated organic solvents. The gauze pad is chemically treated with the composition so that when a quantity of alkyl-cyanoacrylate is placed onto the vapor phase activator pad. The vapor phase activator pad generates fluorescent vapors of the chemical cyanoacrylate wherein the latent fingerprints become exposed when an ultraviolet light source is shined on the object suspected of containing the latent fingerprints.Type: GrantFiled: September 23, 1983Date of Patent: March 12, 1985Inventor: William P. Morton
-
Patent number: 4485158Abstract: In a method for preparing a mosaic luminescent screen, islands of dry precoating material are adhered to a glass support surface at the sites of the mosaic parts of the screen. Then, the mosaic parts of the screen are deposited on the islands by the slurry-direct photographic method, including development with a turbulent aqueous developing medium. The use of islands provides the necessary adherence during development of the mosaic parts with a substantial reduction in the amount of precoating that must later be removed.Type: GrantFiled: October 17, 1983Date of Patent: November 27, 1984Assignee: RCA CorporationInventor: Stanley A. Harper
-
Patent number: 4481233Abstract: A process for producing a solid-state color pickup array, which comprises forming a resist mask on a wafer having a solid image pickup array; vapor-depositing a colorant on the wafer having the resist mask and on the resist mask; and removing the resist mask by dissolution, thereby eliminating selectively the colorant film vapor-deposited on the resist mask.Type: GrantFiled: February 16, 1983Date of Patent: November 6, 1984Assignee: Canon Kabushiki KaishaInventors: Hajime Sakata, Kojiro Yokono, Seiichi Takahashi
-
Patent number: 4473634Abstract: The red and blue color cathode ray tube phosphors for color television are pigmented with a coating of an aqueous-insoluble silicate-based glass matrix containing pigment particles. When incorporated into a tridot color cathode ray tube, the contrast of the tube is improved. The coated particles are formed by dispersing the particles in a slurry with a silicate, the pigment particles and an optional wetting agent, and evaporating the slurry to dryness. The dried coated particles are then heated in order to insolubilize the glass matrix, and soluble ions are then removed by washing.Type: GrantFiled: February 12, 1982Date of Patent: September 25, 1984Assignee: GTE Products CorporationInventors: Robert E. Dodds, Carl E. Landmesser, Henry B. Minnier, Harry O. Schulze
-
Patent number: 4469766Abstract: For formation of a cathode-ray tube phosphor screen by causing a fluorescent material to adhere to a particle-accepting sticky surface formed uniformly on the inner surface of a face plate, phosphor particles are placed on the inner surface of the face plate and caused to slide physically over the particle-accepting sticky surface so as to be stuck thereto.Type: GrantFiled: November 18, 1982Date of Patent: September 4, 1984Assignee: Hitachi, Ltd.Inventors: Masahiro Nishizawa, Kiyoshi Miura, Hiroshi Yokomizo, Osamu Sasaya, Yoshifumi Tomita
-
Patent number: 4463075Abstract: An improved process for providing positive electrical connection between the shadow mask, the conductive coating and the aluminum film by way of the mask-supporting studs is disclosed. The process is for use in the manufacture of a cathode ray tube having a face panel including a rearwardly extending skirt with a seal land for attachment to a funnel having a mating seal land. The face panel and skirt receive an internal coat of electrically conductive dag. The face panel has an inner surface for receiving a pattern of discrete phosphor deposits overlaid with an electrically conductive aluminum film. The tube includes a shadow mask for color selection receiving a high voltage, and held dependent adjacent to the face panel by a plurality of metal studs extending inwardly from the skirt.Type: GrantFiled: July 12, 1982Date of Patent: July 31, 1984Assignee: Zenith Electronics CorporationInventors: Kenneth L. Fritsch, William A. Jordan, Hugo A. Lopez
-
Patent number: 4452861Abstract: Article of manufacture comprises a solid core particle individually encapsulated with a film consisting essentially of alkyl 2-cyanoacrylate polymeric material. The film may be produced in situ by agitating a mixture of core particles having adsorbed water on the surfaces thereof in a nonaqueous liquid containing dissolved alkyl 2-cyanoacrylate monomer, whereby the monomer and adsorbed water react and deposit the film on the surfaces of the particles.Type: GrantFiled: May 20, 1982Date of Patent: June 5, 1984Assignee: RCA CorporationInventors: Fumio Okamoto, Katsuhiro Kato
-
Patent number: 4451504Abstract: Fine particle size phosphors are adhered to the back of the aperture mask of a cathode ray tube by spraying a dispersion of such particles in a coating vehicle containing a temporary binder, and baking to remove the binder. The adhered phosphor is useful in providing information about the location of the scanning electron beams during tube operation.Type: GrantFiled: May 20, 1983Date of Patent: May 29, 1984Assignee: North American Philips Consumer Electronics Corp.Inventors: Anthony V. Gallaro, Gordon T. Foreman
-
Patent number: 4445526Abstract: A system and method for continuously maintaining the specific gravity and viscosity of the slurry applied to a television picture tube includes a container for dispensing slurry to the faceplate of such a tube and for receiving excess slurry from the faceplate. The level of slurry in the container is held constant by the addition of materials to the container. The first added material has a specific gravity greater than that of the material dispensed to the faceplate. The second material has a viscosity which is greater than that of the material dispensed to the faceplate. The quantity of the third material is determined by the specific gravity and viscosity corrections required to bring the parameters of the slurry in the first container to the preselected values. By adding the three materials to the dispenser in accordance with error signals representative of the three parameters, the specific gravity, viscosity and level are continuously held within specified limits.Type: GrantFiled: September 30, 1981Date of Patent: May 1, 1984Assignee: RCA CorporationInventor: John W. Woestman
-
Patent number: 4440831Abstract: Improved zinc silicate phosphor particles are made by using silicic acid particles in the range from 0.7 to 10 micrometers coated with Mn.sub.2 O.sub.3 .multidot.xH.sub.2 O and then a layer of ZnO particles about an order of magnitude smaller which are fired to form the phosphors. The particle size is held within the range preferred and preferably is even narrower. The particles are not milled or mechanically crushed. Instead, the ZnO powder prevents agglomeration during firing. Baths are provided for formation of the particles prior to firing. Brightness and persistance are improved over conventional phosphors.Type: GrantFiled: June 30, 1981Date of Patent: April 3, 1984Assignee: International Business Machines CorporationInventors: James M. Brownlow, Ifay F. Chang
-
Patent number: 4424265Abstract: There are disclosed a composition for making a picture tube fluorescent screen characterized by essentially consisting of a light-sensitive resin at least having recurring units (1) and (2) represented by the formulas: ##STR1## wherein R and X.sup.- have the same meanings as defined in the specification, and CaS-based phosphor particles which are dispersed in an aqueous medium, and a method of making a picture tube fluorescent screen using the same.According to this invention, it is possible to make a picture tube exhibiting an excellent light emitting efficiency and a contrast by a simple process.Type: GrantFiled: September 20, 1982Date of Patent: January 3, 1984Assignee: Tokyo Shibaura Denki Kabushiki KaishaInventors: Norio Koike, Kunihiro Ikari
-
Patent number: 4423128Abstract: There are disclosed a composition for making a picture tube fluorescent screen characterized by essentially consisting of a light-sensitive resin at least having recurring units (1) and (2) represented by the formulas: ##STR1## wherein R and X.sup.- have the same meanings as defined in the specification, and CaS-based phosphor particles surface-coated with SiO.sub.2 which are dispersed in an aqueous medium, and a method of making a picture tube fluorescent screen using the same.According to this invention, it is possible to make a picture tube exhibiting an excellent light emitting efficiency and a contrast by a simple process.Type: GrantFiled: September 20, 1982Date of Patent: December 27, 1983Assignee: Tokyo Shibaura Denki Kabushiki KaishaInventors: Norio Koike, Takeshi Takahara, Yasuhiro Shirakawa, Kunihiro Ikari
-
Patent number: 4409313Abstract: A photosensitive composition improved in sensitivity by adding a salt of a compound represented by the general formula: ##STR1## (wherein R.sub.1 and R.sub.2 each represents a straight chain alkyl group, and X, Y and Z each represents H, a straight chain alkyl group or an alkoxy group, but two or more of X, Y and Z can not be H at the same time) to an aromatic diazonium salt which gets sticky upon exposure to light.Type: GrantFiled: September 29, 1982Date of Patent: October 11, 1983Assignee: Hitachi, Ltd.Inventors: Hajime Morishita, Takahiro Kohashi, Saburo Nonogaki, Motoo Akagi, Nobuaki Hayashi, Shoichi Uchino
-
Patent number: 4398119Abstract: Red cathode ray phosphors are coated with a vapor deposited layer of cadmium selenide in order to achieve controlled color shifts in the light output of the phosphors. Such coated phosphors are especially suited for color television and monitor applications.Type: GrantFiled: September 19, 1980Date of Patent: August 9, 1983Assignee: GTE Products CorporationInventors: Robert E. Dodds, David J. Harrigan
-
Patent number: 4393118Abstract: A pigmented phosphor is prepared by coating phosphor particles with a coating of finely powdered carbon and colloidal silica.Type: GrantFiled: November 18, 1981Date of Patent: July 12, 1983Assignee: GTE Products CorporationInventors: Harry L. Marshall, Alan R. Schwartz
-
Patent number: 4391885Abstract: A fluorescent screen of a cathode ray tube is prepared by forming a film of photosensitive sticky substance, for example, an aqueous solution of a copolymer of a complex salt of diazonium salt and zinc chloride, on an inner surface of a face plate of the tube, exposing the film to light to render portions thereof sticky, applying a powdery substance, for example, phosphors of three colors, onto the film to cause the powdery substance to adhere to the portions of the film rendered sticky, removing excess powder to form a film pattern of the powdery substance, causing the substance responsible for stickiness to ooze out onto the film pattern, applying another powdery substance, for example, graphite onto the film pattern and removing an excess of another powder substance, thus forming the fluorescent screen. The invention is applicable to the manufacture of a fluorescent screen for use in a color picture tube, a monochromatic picture tube and a penetration tube.Type: GrantFiled: March 24, 1982Date of Patent: July 5, 1983Assignee: Hitachi, Ltd.Inventors: Yoshifumi Tomita, Hiromitsu Nakai
-
Patent number: 4382979Abstract: A method of manufacturing a fluorescent display apparatus divided into a plurality of sections each having a plurality of anode conductors disposed on a base plate made of an insulating material, wherein phosphor layers are applied on the anode conductors in each of the sections using phosphors of different luminous colors to obtain a plurality of display sections for illuminating different luminous colors upon impingement of electrons, comprising the steps of forming a first phosphor paste comprising a phosphor compound capable of emitting a particular luminous color, a volatile solvent and a solid film forming element decomposable by the application of heat at a temperature higher than the volatilization temperature of the solvent; forming a second phosphor paste consisting of a phosphor compound capable of emitting a particular luminous color different from that of the first phosphor paste and a volatile solvent; screen printing the first paste to the anode conductors of at least one section of the displayType: GrantFiled: October 6, 1980Date of Patent: May 10, 1983Assignee: Futaba Denshi Kogyo K.K.Inventors: Kazunori Tanaka, Hitoshi Toki, Hisashi Miyazawa, Goro Eto
-
Patent number: 4374866Abstract: To obtain the desired light-intensity distribution in lighthouses for exposing color-picture-tube screens, use is made of light filters. The filter disclosed is obtained by spraying droplets of an opaque paint onto a suitable transparent support.Type: GrantFiled: July 15, 1981Date of Patent: February 22, 1983Assignee: International Standard Electric CorporationInventors: Nadezda Blahna, Bruno Fischer
-
Patent number: 4350514Abstract: When fusing together a panel having a fluorescent film and a metallic reflective film, and a funnel with an electroconductive film in a baking furnace for manufacturing a cathode ray tube, oxygen containing air is forced into the furnace.Type: GrantFiled: May 14, 1981Date of Patent: September 21, 1982Assignee: Hitachi, Ltd.Inventors: Masatoshi Akiyama, Shigeki Kitamura, Junichi Tetsu, Koichi Nakazato
-
Patent number: 4339475Abstract: A method of forming a fluorescent screen for a cathode ray tube comprises forming a phosphor layer on the inner surface of a panel, coating the panel inner surface and the phosphor layer with an aqueous emulsion of water insoluble filming resin in order to form a base layer which is evaporative, forming a metal film upon the base layer and evaporating organic substances of the base layer coated upon the panel inner surface. The phosphor layer, while it is still wet, is coated with the aqueous emulsion of water insoluble filming resin of which pyrolysis temperature is not greater than 420.degree. C. to form the substrate layer.Type: GrantFiled: March 20, 1980Date of Patent: July 13, 1982Assignee: Hitachi, Ltd.Inventors: Misturu Hinosugi, Kouichi Nakasato
-
Patent number: 4331752Abstract: In a method of forming a fluorescent screen of a color picture tube by a dry process, the method comprises a first step of precoating an emulsion containing a powder of acryl resin on an inner surface of a face plate of the color picture tube to form a primary coating, a second step of coating on the primary coating a photosensitive composition consisting essentially of a diazonium salt to form a thin film, a third step of exposing to light a selected portion of the thin film to render the same to become adhesive, a fourth step of depositing a powder of a phosphor on the selected portion to form a phosphor layer of a first color and a fifth step of repeating the third and fourth steps to form phosphor layers of second and third colors.Type: GrantFiled: September 8, 1980Date of Patent: May 25, 1982Assignee: Hitachi, Ltd.Inventors: Hiroshi Yokomizo, Masahiro Nishizawa, Yoshifumi Tomita, Kiyoshi Miura, Osamu Sasaya
-
Patent number: 4327123Abstract: A method of metallizing a phosphor screen including the steps of coating the phosphor screen with an aqueous emulsion containing an acrylic copolymer, drying the coating and depositing a metal layer on the dry coating, the copolymer consists essentially of about34 to 80 weight percent of one member of the group consisting of methyl methacrylate and ethyl methacrylate,20 to 60 weight percent ethyl acrylate and1 to 14 weight percent methacrylic acid.The emulsion may contain minor amounts of (a) colloidal silica, (b) water-soluble polymer and/or (c) dispersing agent.Type: GrantFiled: February 20, 1981Date of Patent: April 27, 1982Assignee: RCA CorporationInventors: Aaron W. Levine, Kazimiera D. Tomeczek, Stanley A. Harper
-
Patent number: RE32498Abstract: A fluorescent screen of a cathode ray tube is prepared by forming a film of photosensitive sticky substance, for example, an aqueous solution of a copolymer of a complex salt of diazonium salt and zinc chloride, oN an inner surface of a face plate of the tube, exposing the film to light to render portions thereof sticky, applying a powdery substance, for example, .[.phosphors of three colors.]. .Iadd.graphite.Iaddend., onto the film to cause the powdery substance to adhere to the portions of the film rendered sticky, removing excess powder to form a film pattern of the powdery substance, causing the substance responsible for stickiness to ooze out onto the film pattern, applying another powdery substance, for example, .[.graphite.]. .Iadd.titanium oxide .Iaddend.onto the film pattern and removing an excess of another powder substance, thus forming the fluorescent screen.Type: GrantFiled: July 5, 1985Date of Patent: September 8, 1987Assignee: Hitachi, Ltd.Inventors: Yoshifumi Tomita, Hiromitsu Nakai