Aluminum Or Iron Salt Or Oxide Formed In Situ Patents (Class 428/472.2)
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Patent number: 7267859Abstract: The presently disclosed invention provides for the fabrication of porous anodic alumina (PAA) films on a wide variety of substrates. The substrate comprises a wafer layer and may further include an adhesion layer deposited on the wafer layer. An anodic alumina template is formed on the substrate. When a rigid substrate such as Si is used, the resulting anodic alumina film is more tractable, easily grown on extensive areas in a uniform manner, and manipulated without danger of cracking. The substrate can be manipulated to obtain free-standing alumina templates of high optical quality and substantially flat surfaces PAA films can also be grown this way on patterned and non-planar surfaces. Furthermore, under certain conditions the resulting PAA is missing the barrier layer (partially or completely) and the bottom of the pores can be readily accessed electrically.Type: GrantFiled: November 25, 2002Date of Patent: September 11, 2007Assignee: Massachusetts Institute of TechnologyInventors: Oded Rabin, Paul R. Herz, Mildred S. Dresselhaus, Akintunde I. Akinwande, Yu-Ming Lin
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Patent number: 7244514Abstract: A corrosion resistant part comprises an aluminum alloy part main body, an alumite layer disposed on the part main body, and a corrosion resistant layer disposed on the alumite layer. The part main body has a normal portion and a flawed portion so that the alumite layer comprises a normal portion alumite layer formed on the normal portion and a flawed portion alumite layer formed on the flawed portion, and the corrosion resistant layer comprises a normal portion corrosion resistant layer formed on the normal portion and a flawed portion corrosion resistant layer formed on the flawed portion. The normal portion alumite layer has a thickness between approximately 0.5 microns and approximately 5.0 microns. The corrosion resistant layer is formed from an ionic resin and has a thickness less than or equal to approximately 5 microns.Type: GrantFiled: November 29, 2004Date of Patent: July 17, 2007Assignee: Shimano, Inc.Inventors: Masaaki Hara, Wataru Yamauchi, Kenji Matsuda, Masayoshi Kihara
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Patent number: 7189460Abstract: A high reflectance mirror having a high reflectance in a visible-light region, being excellent in durability such as a moisture resistance, a saltwater resistance, etc. and having small dependence on incident angle (i.e., the fluctuation of the reflectance depending on an incident angle of light is little) is provided. The high reflectance mirror comprises a substrate and a silver film, a low refractive index film and a high refractive index film laminated on the substrate in this order wherein an adhesion improving film is formed on the silver film surface on the opposite side of the substrate, the extinction coefficient of the low refractive index film is at most 0.01, the extinction coefficient of the high refractive index film is at most 0.01, the adhesion improving film is an oxide film and the extinction coefficient of the adhesion improving film is at most 0.1.Type: GrantFiled: June 25, 2004Date of Patent: March 13, 2007Assignee: Asahi Glass Company, LimitedInventors: Naoko Shin, Takuji Oyama, Kazuo Kadowaki
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Patent number: 7153567Abstract: A composite structure forming method comprises the steps of first pre-treating brittle material fine particles to impart an internal strain to the brittle material fine particles, secondly causing the brittle material fine particles in which the internal strain has been created to collide with a substrate surface at high speed or applying a mechanical impact force to the brittle material fine particles containing the internal strain therein provided on the substrate surface, to deform or fracture the brittle material fine particles, re-joining the fine particles through active new surfaces generated by the deformation or fracture, forming an anchor section made of polycrystalline brittle material of which part bites into the substrate surface at a boundary section between the new surfaces and the substrate, and further forming a structure made of polycrystalline brittle material on the anchor section.Type: GrantFiled: October 12, 2000Date of Patent: December 26, 2006Assignees: Toto Ltd., National Institute of Advanced Industrial Science and TechnologyInventors: Jun Akedo, Tomokadsu Ito, Tatsuro Yokoyama, Katsuhiko Mori, Hironori Hatono, Masakatsu Kiyohara, Yuji Aso
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Patent number: 7135075Abstract: An aqueous solution for depositing an inorganic corrosion resistant coating on a metal substrate is disclosed. The aqueous solution comprises a film-forming agent, a supplemental anion, and a substrate activator. The film-forming agent is a vanadate salt that forms the corrosion resistant coating. The supplemental anion accelerates the rate at which the corrosion resistant coating is formed. The substrate activator serves to remove any existing oxides from the metal substrate prior to the formation of the corrosion resistant coating. The present invention additionally covers objects so coated and methods of application.Type: GrantFiled: January 20, 2004Date of Patent: November 14, 2006Assignee: The Ohio State UniversityInventors: Rudolph G. Buchheit, Hong Guan, Valerie N. Laget
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Patent number: 7125610Abstract: A capacitor comprising an aluminum anode and a dielectric layer comprising phosphate doped aluminum oxide and process for making the capacitor. The capacitor has a CV Product of at least 9 ?F-V/cm2 at 250 volts. Furthermore, the capacitor is formed by the process of: forming an aluminum plate; contacting the plate with an anodizing solution comprising glycerine, 0.1 to 1.0%, by weight, water and 0.01 to 0.5%, by weight, orthophosphate; applying a voltage to the aluminum plate and determining an initial current; maintaining the first voltage until a first measured current is no more than 50% of the initial current; increasing the voltage and redetermining the initial current; maintaining the increased voltage until a second measured current is no more than 50% of the redetermined initial current, and continuing the increasing of the voltage and maintaining the increased voltage until a final voltage is achieved.Type: GrantFiled: March 17, 2003Date of Patent: October 24, 2006Assignee: Kemet Electronics CorporationInventors: John Tony Kinard, Anita Melody, legal representative, David Alexander Wheeler, Duane Earl Stenzinger, Albert Kennedy Harrington, Brian John Melody, deceased
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Patent number: 7066228Abstract: A (metal/rubber) composite comprising a rubber matrix reinforced with a metallic body adhering to the rubber matrix by means of an adhesive interphase; the rubber matrix is based on diene elastomer; the metal is a carbon steel, the carbon content of which is between 0.35% and 1.2%; to constitute the adhesive interphase, the carbon steel is coated with a metallic layer bearing aluminium oxides or hydroxides, which itself is covered by an organosilane film providing, as coupling agent, the bond between the aluminium oxides-hydroxides on one hand, and the rubber matrix on the other hand. The invention also relates to articles or semi-finished products made of rubber which are reinforced with or formed by such a composite, in particular tires.Type: GrantFiled: January 28, 2003Date of Patent: June 27, 2006Assignee: Michelin Recherche et Technique S.A.Inventors: Bruno Grimberg, Yves Ravoire, Jean-Claude Tardivat, Le Tu Anh Vo
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Patent number: 7045217Abstract: A plated component used in an outdoor environment comprises a component main unit, a metal coating formed over at least a part of the component main unit, and an oxide coating formed over at least a part of the component main unit.Type: GrantFiled: May 8, 2003Date of Patent: May 16, 2006Assignee: Shimano, Inc.Inventors: Yasushi Nishimura, Yuzuru Uchiyama
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Patent number: 7026059Abstract: The present invention is to provide an ultra-thin copper foil with a carrier which comprises a release layer, a diffusion preventive layer and a copper electroplating layer laminated in this order, or a diffusion preventive layer, a release layer and a copper electroplating layer laminated in this order on the surface of a carrier foil, wherein a surface of the copper electroplating layer is roughened; a copper-clad laminated board comprising the ultra-thin copper foil with a carrier being laminated on a resin substrate; a printed wiring board comprising the copper-clad laminated board on the ultra-thin copper foil of which is formed a wiring pattern; and a multi-layered printed wiring board which comprising a plural number of the above printed wiring board being laminated.Type: GrantFiled: September 17, 2001Date of Patent: April 11, 2006Assignee: Circuit Foil Japan Co., Ltd.Inventors: Akitoshi Suzuki, Shin Fukuda, Kazuhiro Hoshino, Tadao Nakaoka
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Patent number: 7018724Abstract: In an organic EL device comprising a cathode, an anode, and two or more stacked organic layers therebetween including a light emitting layer, an electron injecting organic layer containing an organic salt or complex of a metal having a standard electrode potential of more negative than ?1.8 V at 25° C. is formed close to the cathode by coating, and an organic layer containing a high molecular weight EL material is disposed close to the electron injecting organic layer. A multilayer structure of organic layers can be formed by coating, and the organic EL device has a high luminance, high efficiency, high reliability, long life and ease of handling.Type: GrantFiled: September 28, 2004Date of Patent: March 28, 2006Assignee: TDK CorporaitonInventors: Emiko Kambe, Masahiro Shinkai
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Patent number: 7005194Abstract: An aluminum or aluminum alloy member superior in liquid and gaseous corrosion resistance and plasma resistance, which has an anodized film formed thereon which is composed of a porous layer and a non-porous barrier layer whose structure is at least partly boehmite or pseudo-boehmite. Said anodized film is characterized by that the film dissolving rate measured by the test for immersion in a mixture of phosphoric acid and chromic acid (conforming to JIS H8683-2) is less than 120 mg/dm2/15 min, the ratio of area in which corrosion occurs after standing for 2 hours in an atmosphere of argon containing 5% chlorine (at 300° C.) is less than 15%, and the hardness (Hv) of the film is no lower than 420.Type: GrantFiled: January 22, 2004Date of Patent: February 28, 2006Assignee: Kobe Steel, Ltd.Inventors: Koji Wada, Jun Hisamoto
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Patent number: 6955771Abstract: Disclosed are metal oxide sols made by mixing at least one metal alkoxide, wherein the metal is a transition metal, a post-transition metal, an alkali metal, or alkaline earth metal; at least one organosilane; at least one boron oxide compound selected from the group consisting of boric acid, alkoxy boron compounds, hydrocarbyl boric acids, hydrocarbyl hydroxy boron alkoxides, and hydroxy boron alkoxides; and a liquid. Also disclosed are composites containing a polymer and the metal oxide sols.Type: GrantFiled: January 7, 2003Date of Patent: October 18, 2005Assignee: APS LaboratoryInventor: Hong-Son Ryang
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Patent number: 6951691Abstract: This invention relates to a surface treatment method comprising the steps of providing a treating solution containing a specific ammonium compound or aqueous ammonia, and magnesium silicofluoride, heating the treating solution to a temperature of 70 to 100° C., and soaking aluminum or an aluminum alloy in the treating solution; a piston having a surface coated with a film consisting of a mixture of NH4MgAlF6 and MgAlF5.1.5H2O or a mixture of NH4MgAlF6 and MgAl2F8.2H2O; and a sliding member made of aluminum or the like wherein the whole surface of the sliding member or the sliding surface thereof is coated with a film which consists of either of the aforesaid mixtures, has a cubic crystal structure, and shows no crystalline orientation.Type: GrantFiled: June 20, 2003Date of Patent: October 4, 2005Assignee: Suzuki Motor CorporationInventors: Masaya Nomura, Yoshinobu Ozaki
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Patent number: 6933054Abstract: A bearing material for the manufacture of wear-resistant slide bearings made of a Cu—Al-alloy, consisting of 0.01 to 20% Al, optionally further elements, the remainder copper and the common impurities. The slide bearing has for this purpose an outer, wear-reducing cover layer with a range of thickness D=10 nm to 10 ?m and consists exclusively of aluminum oxide.Type: GrantFiled: December 5, 2002Date of Patent: August 23, 2005Assignee: Weiland-Werke AGInventors: Klaus Ohla, Michael Scharf
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Patent number: 6919125Abstract: Ceramic substrates (1) for microelectronic modules are formed in multiple layers (7 & 9) fused into a unitary one-piece assembly. The layers contain the same ceramic material but in different purity so that one outer layer (9) is optimal in composition for bonding to a thick film conductor (11) and the other outer layer (7) is optimal in composition for bonding to a thin film conductor (13). In a dual composition substrate embodiment one layer is formed of a 96% alumina composition and the second layer is formed of a 99.6% alumina composition.Type: GrantFiled: August 1, 2003Date of Patent: July 19, 2005Assignee: Northrop Grumman CorporationInventors: Kriss Allen Bennett, Roy Tom Coyle
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Patent number: 6905775Abstract: Aluminium alloy sheet having on a surface anodic oxide film and an overlying coating consisting essentially of at least one adhesion promoter excluding silanes. Sheet for architectural use carries a paint layer over the adhesion promoter coating. Sheet for automobile use may carry an electroconductive paint primer layer over the adhesion promoter coating. Preferred adhesion promoters are polyacrylic acid and pretreatments containing Cr, Mn, Mo, Si, Ti, Zr and F values.Type: GrantFiled: October 13, 1998Date of Patent: June 14, 2005Assignee: Novelis Inc.Inventors: Eric Barlow, Mark Foster, Chris Pargeter, Peter Karl Ferdinand Limbach
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Patent number: 6899956Abstract: This invention includes improvements to a method for forming a chemical conversion coating on ferrous metal substrates, to the chemical solutions used in the coating and to the articles coated thereby. A first oxidation applies a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, to a ferrous substrate. A coloring procedure (a second oxidation) follows the first oxidation procedure, using a heated oxidizing solution that reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4). The result is the formation of a brown or black finish. An appropriate rust preventive topcoat may seal the substrate. The finish affords protection, a degree of lubricity to aid assembly, break-in of sliding surfaces, provides anti-galling protection and an adherent base for paint finishes.Type: GrantFiled: May 3, 2002Date of Patent: May 31, 2005Assignee: Birchwood Laboratories, Inc.Inventors: William V. Block, Bryce D. Devine
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Patent number: 6884515Abstract: A method for applying a coating system that is applied to a surface of a component for preventing or at least substantially preventing interdiffision between the component surface and a protective thermal layer applied to the component surface when the thermal layer is exposed to elevated temperatures. The method includes applying a carrier layer containing aluminum to the component surface. Next, the layer is heated to a first predetermined temperature for a first predetermined period of time in the substantial absence of oxygen to bond the aluminum with the component surface, the heat dissolving the carrier portion of the aluminum layer. The remaining portion of the aluminum layer is then heated to a second predetermined temperature for a second predetermined period of time to form an oxidized aluminum layer. Finally, at least one protective thermal layer is applied over the oxidized aluminum layer.Type: GrantFiled: December 20, 2002Date of Patent: April 26, 2005Assignee: General Electric CompanyInventors: John Frederick Ackerman, Paul Arszman, Andrew J. Skoog
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Patent number: 6881491Abstract: An aluminum alloy article is cleaned to remove oxides and organic matter from a coatable surface, coated with a composition comprising an organic resin and a fluorine compound, and then heated to an elevated temperature to decompose the organic resin and at least a portion of the fluorine compound. After heating the coated surface is left with a protective oxyfluoride film that prevents blistering and hydrogen pickup and promotes hydrogen degassing from the article.Type: GrantFiled: May 16, 2003Date of Patent: April 19, 2005Assignee: Alcoa Inc.Inventors: Sally A. Jankosky, Susanne M. Opalka, Paula L. Kolek, Joseph P. Harenski, Roger W. Kaufold, Larry F. Wieserman
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Patent number: 6869671Abstract: A thin film based nanoporous alumina template has been developed which allows the in situ removal of an electrically insulating alumina barrier layer at the pore bases. This barrier free nanoporous system has great utility for electrodeposition of a wide variety of nanowire materials. An exemplary multilayer thin film precursor is provided comprising Al (anodization layer), Ti (diffusion barrier) and Pt (active electrode) on a Si substrate. Aluminum anodization in sulfuric acid with a subsequent applied voltage ramping program produces a Pt electrode at the base of the nanopores without the additional steps of alumina removal, barrier layer dissolution, and metal deposition onto the pore bottoms.Type: GrantFiled: June 2, 2003Date of Patent: March 22, 2005Assignee: University of Notre DameInventors: Michael M. Crouse, Albert E. Miller, Juan Jiang, David T. Crouse, Subash C. Basu
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Patent number: 6869684Abstract: In a method of providing a surface with a protection layer having at least a first surface area (2) and a second surface area (1), which surface areas (1, 2) are distinguishable in that the surface areas (1, 2) differ from each other in at least one visual property, parts of the surface situated outside the first surface area (2) are masked with a mask layer which partially covers the surface, and the surface is subjected to an electrochemical treatment (14, 20), whereby non-masked parts of the surface are treated. As the mask layer provided on the surface is a sol-gel layer forming the protection layer in the second surface area (1), a wear-resistant surface-protection layer having visually distinguishable surface areas is provided in an efficient manner. An object which can be obtained by means of the proposed method is also described.Type: GrantFiled: January 27, 2004Date of Patent: March 22, 2005Assignee: Koninklijke Philips Electronics N.V.Inventors: Sjoerd Johannes Franciscus Brattinga, Hans Kuiper, Mattheus Franciscus Langedijk, Ytsen Wielstra
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Patent number: 6849342Abstract: The present invention relates to a method of fabrication and a product, which forms a composite body made of metal and a porous ceramic blank, which adjoins the metallic portion and is infiltrated by the metal, wherein a gradient in properties across the composite portion of the composite body is formed by a heat treatment that reduces some of the oxides across the thickness of the porous ceramic blank. In one embodiment, a gradient from substantial chemical reaction to incomplete chemical reaction of the reducible oxides of the blank with the infiltrated metal is formed inside the composite portion.Type: GrantFiled: November 6, 2000Date of Patent: February 1, 2005Assignee: Robert Bosch GmbHInventors: Otto W. Stenzel, Klaus Czerwinski, Iris Postler, Bernd Reinsch
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Patent number: 6835459Abstract: A conductive and weldable anti-corrosion composition for coating metal surfaces which contains: (a) 5 to 40 wt. % of an organic binder containing: (aa) at least one epoxide resin (ab) at least one hardener selected from cyanoguanidine, benzoguanamine and plasticised urea resin (ac) at least one amine adduct selected from polyoxyalkylenetriamine and epoxide resin/amine adducts (b) 0 to 15 wt. % of an anti-corrosion pigment (c) 40 to 70 wt. % of a conductive pigment selected from powdered zinc, aluminum, graphite, molybdenum sulfide, carbon black and iron phosphide (d) 0 to 45 wt. % of a solvent; and a lacquered metal structural part which has a conductive organic layer.Type: GrantFiled: November 6, 2002Date of Patent: December 28, 2004Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Wolfgang Lorenz, Andreas Kunz, Eva Wilke
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Patent number: 6821633Abstract: In at least one aspect, the invention relates to an entirely or substantially chromium-free conversion coating composition and process for conversion coating metal surfaces that provides corrosion resistance. In at least another aspect, the present invention relates to an article having a metal surface that is at least partially coated with an entirely or substantially chromium-free conversion coating that provides corrosion resistance. In certain embodiments, the conversion coating composition comprises water and (A) dissolved fluorometallate anions selected from the group consisting of TiF6−2, ZrF6−2, HfF6−2, SiF6−2, AlF6−3, GeF6−2, SnF6−2, BF4−, and mixtures thereof and (B) a water-soluble polymer which is a Mannich adduct of poly(4-vinyl phenol) and N-methyl ethanolamine. In other embodiments, the composition also comprises (C) a water-soluble polymer which is a Mannich adduct of poly(4-vinyl phenol) and N-methyl glucamine.Type: GrantFiled: May 16, 2003Date of Patent: November 23, 2004Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)Inventors: Jianping Liu, Patrick A. Scalera, Shawn E. Dolan
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Patent number: 6818313Abstract: A corrosion-inhibiting coating, process, and system that provides a tight, adherent zinc- or zinc-alloy coating that is directly deposited onto steel or cast iron surfaces for enhanced corrosion protection. A process for applying the coating is also provided. The process includes the application of two sequential aqueous baths. The first bath contains a precursor zinc compound while the second bath contains a reducing agent to deposit the zinc directly upon the steel or cast iron.Type: GrantFiled: July 24, 2002Date of Patent: November 16, 2004Assignee: University of DaytonInventors: Andrew W. Phelps, Jeffrey A. Sturgill
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Patent number: 6815095Abstract: A binderless stimulable phosphor screen is provided, comprising a vapor deposited phosphor layer on a support, wherein between the support and the phosphor layer a ceramic layer is present, wherein said ceramic layer preferably comprises a mixture of pigments so that the optical density of the phosphor screen is higher for the stimulating wavelength than for the stimulated emission wavelength of the vapor deposited phosphor.Type: GrantFiled: November 21, 2002Date of Patent: November 9, 2004Assignee: AGFA-GevaertInventors: Paul Leblans, Luc Struye, Ludo Joly
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Patent number: 6811900Abstract: When plural-layer ceramic coatings are formed on a surface of an grain-oriented silicon steel sheet after finish annealing according to the invention, TiNO coating is formed as a first coating layer by a hollow cathode process under an application of a high bias voltage to the steel sheet, whereby ceramic tension coatings having excellent coating adhesion property and hence tension applying effect can be formed. As a result, ultra-low iron loss grain-oriented silicon steel sheets having an excellent iron loss property even after stress relief annealing at high temperatures for a long time can be stably obtained.Type: GrantFiled: January 28, 2003Date of Patent: November 2, 2004Assignee: JFE Steel CorporationInventor: Yukio Inokuti
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Patent number: 6811893Abstract: A thermoplastic resin-coated aluminum plate is provided which is less liable to develop ply separation or cracks in a resin coating film during drawing or ironing and on which the resin coating film is less likely to peel off the aluminum plate. A semi-non-porous anodized film is formed on at least one side of the aluminum plate, a coating layer is formed on the semi-non-porous anodized film, and a thermoplastic resin coating film is formed on the coating layer.Type: GrantFiled: May 13, 2003Date of Patent: November 2, 2004Assignees: Mitsubishi Plastics, Inc., Mitsubishi Aluminum Co., Ltd.Inventors: Yoshio Wakayama, Keitaro Yamaguchi, Nobuhiro Sakata
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Patent number: 6808864Abstract: Disclosed is a support for a lithographic printing plate obtained by subjecting an aluminum plate to a graining treatment and an anodizing treatment, the support comprising at least any one of Mn in a range from 0.1 to 1.5 wt % and Mg in a range from 0.1 to 1.5 wt %; Fe of 0 to 1 wt %; Si of 0 to 0.5 wt %; Cu of 0 to 0.2 wt %; at least one kind of element out of the elements listed in items (a) to (d) below in a range of content affixed thereto, (a) 1 to 100 ppm each of one or more kinds of elements selected from a group consisting of Li, Be, Sc, Mo, Ag, Ge, Ce, Nd, Dy and Au, (b) 0.Type: GrantFiled: September 10, 2002Date of Patent: October 26, 2004Assignee: Fuji Photo Film Co., Ltd.Inventors: Hirokazu Sawada, Akio Uesugi
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Publication number: 20040209092Abstract: A laminate composite that includes a phosphoric acid anodized metal layer that includes an anodic film of from between about 0.005 mils to about 0.015 mils thick as measured through standard acid dissolution testing; an adhesive layer; a top layer adhered to the metal layer at least in part by the adhesive layer; and wherein the metal includes a metal chosen from the group that includes an aluminum and an aluminum alloy.Type: ApplicationFiled: April 18, 2003Publication date: October 21, 2004Inventor: Shannon D. Near
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Publication number: 20040185279Abstract: This invention relates to an improved component for a plasma processing system, and more particularly, to fasteners for internal chamber parts in a plasma processing chamber. Further, this invention relates to a method of manufacturing such a fastener.Type: ApplicationFiled: January 27, 2004Publication date: September 23, 2004Applicant: TOKYO ELECTRON LIMITEDInventor: Steven T. Fink
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Publication number: 20040175587Abstract: A corrosion inhibitor is described which includes several supramolecular oxo-anion compositions useful for preventing the propagation of pit corrosion on aluminum and aluminum alloys. The oxo-anion compositions preferably include soluble polymeric oxidic acids comprising combinations of molybdenum, phosphorous, tungsten, and silicon. These compositions are useful as corrosion inhibitors in high-moisture, corrosive environments, such as radiators and cooling systems. For low-moisture environments, these oxo-anion compositions can be reacted with a counter-ion, such as various metals, including, but not limited to the rear earth metals, to form a soluble salt. The salt can then be adsorbed onto a carrier, such as paint pigments, which can then be applied to the surfaces of aluminum and aluminum alloys. These surface adsorbates then become sparingly soluble and are gradually released over time in the presence of an aqueous corrosive agent so as to prevent propagation of pit corrosion.Type: ApplicationFiled: March 18, 2004Publication date: September 9, 2004Inventor: Martin William Kendig
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Publication number: 20040167257Abstract: Disclosed are nanocomposites made of guest metal nanoparticles and metal oxide sols made by mixing at least one metal alkoxide, at least one organosilane, at least one boron oxide compound, and a liquid. Also disclosed are dielectric composites containing a dielectric material such as a polymer and the nanocomposites.Type: ApplicationFiled: April 30, 2003Publication date: August 26, 2004Inventor: Hong-Son Ryang
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Publication number: 20040159824Abstract: Disclosed are metal oxide sols made by mixing at least one metal alkoxide, wherein the metal is a transition metal, a post-transition metal, an alkali metal, or alkaline earth metal; at least one organosilane; at least one boron oxide compound selected from the group consisting of boric acid, alkoxy boron compounds, hydrocarbyl boric acids, hydrocarbyl hydroxy boron alkoxides, and hydroxy boron alkoxides; and a liquid. Also disclosed are composites containing a polymer and the metal oxide sols.Type: ApplicationFiled: January 7, 2003Publication date: August 19, 2004Inventor: Hong-Son Ryang
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Patent number: 6777098Abstract: A marking (3 to 5) is provided in a surface (8) of an element (1) which comprises a substrate (6) of aluminum or an alloy thereof and an anodized outer layer (7) in that a region (10) of the surface (8) is irradiated with a laser beam such that at least one visual property of the surface (8) in said region (10) is changed and a visual marking (3 to 5) is obtained which is observable to the human eye. The laser beam penetrates the anodized outer layer (7) at least to a major degree and induces the change in the at least one visual property substantially locally only in a zone (9) where the anodized outer layer (7) adjoins the substrate (6).Type: GrantFiled: April 28, 2003Date of Patent: August 17, 2004Assignee: Koninklijke Philips Electronics N.V.Inventor: Keng Kit Yeo
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Publication number: 20040140221Abstract: An anodizing solution, and method of anodizing, comprising suspending at least one aluminium substrate in an anodizing solution and applying an anodizing current to the anodizing solution. The anodizing solution comprises 0.01-5%, by weight, sodium silicate and 0.01-5%, by weight, &agr;-amino acid.Type: ApplicationFiled: January 21, 2003Publication date: July 22, 2004Inventors: John Tony Kinard, Brian John Melody, Albert Kennedy Harrington, David Alexander Wheeler
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Publication number: 20040131917Abstract: The present invention provides for an end plate for an electrochemical cell. The end plate is a metal plate having at least one manifold region with at least one connection port to permit the passage of a fluid therethrough. The nd plate has a corrosion resistant coating applied to the at least one manifold region including the at least one connection port. A method for producing the end plate is also disclosed.Type: ApplicationFiled: August 13, 2003Publication date: July 8, 2004Inventors: Antonio Gennaro Mazza, David G. Frank, Nathaniel lan Joos
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Publication number: 20040115449Abstract: A display panel is formed by coating an opaque support layer with at least one layer carrying an image. The opaque support layer provides the necessary stiffness to the panel.Type: ApplicationFiled: November 24, 2003Publication date: June 17, 2004Applicant: Eastman Kodak CompanyInventors: Jeffrey Cooke, Philip Smith
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Patent number: 6743513Abstract: The invention described herein is a bioactive composite material comprising thin layers of bioactive glass reinforced with thin ductile metallic layers, and the use of this material in bone replacement procedures.Type: GrantFiled: September 20, 2001Date of Patent: June 1, 2004Assignee: USBiomaterials CorporationInventors: John J. Mechlosky, Jr., Zheng Chen, Daniel Clupper
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Patent number: 6713199Abstract: A multilayer structure, used especially as a material of high relative permittivity, includes a plurality of separate layers, each having a thickness of less than 500 Å, and based on hafnium dioxide (HfD2), zirconium dioxide (ZrO2) and alumina (Al2O3). In practice, the hafnium dioxide, zirconium dioxide and alumina layers form alloys of formula HfxZrAlyOz. Advantageously, the stoichiometry of the HfxZrAlyOz alloys varies from one layer to another.Type: GrantFiled: December 24, 2002Date of Patent: March 30, 2004Assignee: MemscapInventor: Lionel Girardie
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Patent number: 6713188Abstract: We have discovered that the formation of particulate inclusions at the surface and the interior of an aluminum alloy article interferes with the performance of the article when a surface of the article is protected by an anodized coating. We have also discovered that the formation of such particulate inclusions can be controlled to a large extent by controlling the concentration of particular impurities present in the alloy used to fabricate the aluminum alloy article.Type: GrantFiled: January 27, 2003Date of Patent: March 30, 2004Assignee: Applied Materials, IncInventors: Shun Wu, Clifford C. Stow, Hong Wang, Yixing Lin, Brian West
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Publication number: 20040050710Abstract: Metal articles having a durable visible marking on a smooth Type III hard anodized surface particularly useful for shock absorber tubes are produced by applying an alkaline solution to the anodized surface for not less than about 15 seconds at temperature of 100°-140° F.; applying a pattern of lacquer based solvent ink to said surface; and sealing the applied pattern by applying a liquid selected from the group consisting of nickel acetate, cobalt acetate and boiling water to said pattern.Type: ApplicationFiled: September 13, 2002Publication date: March 18, 2004Inventor: Peter Yan
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Patent number: 6703135Abstract: A system and method for providing a coating for protecting a surface from corrosion are provided. The method involves providing a system of layers on a light metal or light metal alloy substrate. The system of layers includes a nonconductive layer adjacent the substrate, followed by a conductive layer, an intermediate layer, and an decorative external layer.Type: GrantFiled: August 28, 2000Date of Patent: March 9, 2004Assignee: Fraunhofer-Gesellschaft zur Fordering der angewandten Forschung e.V.Inventors: Andreas Dietz, Volker Von Der Heide
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Patent number: 6702553Abstract: A highly porous alumina material and a method for applying such material that is useful in the hot section of a jet aircraft engine. In order to manufacture the porous alumina, an aluminum-based metal/alumina material known in the art is first placed onto a metal alloy substrate. The aluminum-based metal is then dissolved using a solution that will not affect the alumina or the underlying substrate. The alumina is then washed with deionized water and dried. The resulting alumina has a porosity in the range of about 20% to about 45%. The alumina has globular interconnected surface features in the range of about 0.5 &mgr;m to about 20 &mgr;m.Type: GrantFiled: October 3, 2002Date of Patent: March 9, 2004Assignee: General Electric CompanyInventor: Mark D. Gorman
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Patent number: 6699603Abstract: A stainless steel with a passive state fluorinated film formed thereon, which is easy to construct and does not produce particles even when it is welded, and a device using the same. The stainless steel does not cause leakage even when said film is formed on a sealing surface of a joint and a valve seat surface. The stainless steel is characterized in that at least a part of the surface coated with a passive state fluorinated film not thicker than 190Å consisting of a metal fluoride as a main component.Type: GrantFiled: December 26, 2001Date of Patent: March 2, 2004Assignee: Stella Chemifa Kabushiki KaishaInventors: Tadahiro Ohmi, Hirohisa Kikuyama, Masayuki Miyashita, Hiroto Izumi, Takanobu Kujime
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Patent number: 6695931Abstract: This invention is a method for forming a chemical conversion coating on ferrous metal substrates, the chemical solutions used in the coating and the articles coated thereby. By modifying and combining the features of two existing, but heretofore unrelated, coating technologies, a hybrid conversion coating is formed. Specifically, a molecular iron/oxygen-enriched intermediate coating, such as a dicarboxylate or phosphate, is applied to a ferrous substrate by a first oxidation. The intermediate coating pre-conditions the substrate to form a surface rich in molecular iron and oxygen in a form easily accessible for further reaction. This oxidation procedure is followed by a coloring procedure using a heated (about 120-220° F.) oxidizing solution containing alkali metal hydroxide, alkali metal nitrate, alkali metal nitrite or mixtures thereof, which reacts with the iron and oxygen enriched intermediate coating to form magnetite (Fe3O4).Type: GrantFiled: January 2, 2003Date of Patent: February 24, 2004Assignee: Birchwood Laboratories, Inc.Inventors: Keith N. Ravenscroft, William V. Block
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Patent number: 6692838Abstract: The invention includes a composition of matter which is resistant to metal dusting and a method for preventing metal dusting on metal surfaces exposed to carbon supersaturated environments.Type: GrantFiled: March 15, 2002Date of Patent: February 17, 2004Assignee: ExxonMobil Research and Engineering CompanyInventors: Trikur Anantharaman Ramanarayanan, ChangMin Chun
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Patent number: 6692839Abstract: A titanium based composite which includes a Ti(Al,O) base matrix, discrete ceramic particles, and an oxide layer on the surface of the composite. The discrete ceramic particles are integrally associated with the Ti(Al,O) base matrix and the oxide layer, so that at a temperature of above about 600° C., the composite is substantially resistant to oxidation and spallation.Type: GrantFiled: April 9, 2002Date of Patent: February 17, 2004Assignee: Titanox Developments LimitedInventors: Deliang Zhang, Wei Gao, Danyang Ying, Zhengwei Li, Zhihong Cai, Jing Liang
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Patent number: 6692836Abstract: A composite material having an aluminum substrate, an intermediate layer located on one side of the substrate, and an optically active multilayer system applied to the intermediate layer. The multilayer system includes three layers. The two upper layers are dielectric and/or oxide layers and the bottom layer is a metallic layer applied to the intermediate layer. In order to controllably and selectively set the absorptivity and reflectivity in various wavelength regions, the intention also being to ensure good processability, in particular deformability, a high thermal conductivity and high long-term thermal and chemical stability of the material, the top layer is a dielectric layer, preferably an oxide, fluoride or nitride layer of chemical composition MeOz, MeFr, MeNs, with a refractive index n<1.8. The middle layer is a chromium oxide layer of chemical composition CrOx. The bottom layer of gold, silver, copper, chromium, aluminum and/or molybdenum.Type: GrantFiled: December 20, 2001Date of Patent: February 17, 2004Assignee: Alanod Aluminium-Veredlung GmbH & Co. KGInventors: Werner Reichert, Klaus Ganz
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Patent number: 6689487Abstract: A ceramic thermal barrier coating on a substrate wherein the coating comprises primary columnar grains that extend transversely of a surface of the substrate and that include integral secondary columnar grains extending laterally therefrom relative to a respective column axis. The secondary columnar grains typically extend from the primary columnar grains at an acute angle of less than 90 degrees relative to the column axis of the primary columnar grains. The coating structure exhibits reduced thermal conductivity as compared to a conventional thermal barrier coating.Type: GrantFiled: December 21, 2001Date of Patent: February 10, 2004Assignee: Howmet Research CorporationInventor: Kenneth S. Murphy