Polymer Of Monoethylenically Unsaturated Hydrocarbon Patents (Class 428/476.1)
  • Patent number: 7229678
    Abstract: A barrier laminate packaging material comprising from its outermost surface to the innermost surface contacting the contents of the container to be prepared therefrom, a first exterior layer of a low density polyethylene polymer, a paperboard substrate, a first interior layer laminate coating of nylon with a tie resin layer, a blown film layer comprising a first low density polyethylene polymer layer, a tie layer, a first interior layer of EVOH, a second tie layer, a second interior layer of EVOH, a third tie layer and a second interior layer of low density polyethylene polymer, and an innermost product contacting layer of low density polyethylene.
    Type: Grant
    Filed: May 1, 2003
    Date of Patent: June 12, 2007
    Assignee: Evergreen Packaging Inc.
    Inventors: Tricia Susan Reighard, Christopher S. Cleveland, Richard A. Tedford, Jr.
  • Patent number: 7183005
    Abstract: Regrind is mixed with at least one low density metallocene polyethylene to increase the amount of regrind that can be used in a thermoformed article.
    Type: Grant
    Filed: August 20, 2004
    Date of Patent: February 27, 2007
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Anthony Poloso, Allen T Mika
  • Patent number: 7175916
    Abstract: A composite of a resin member bonded to a vulcanized rubber member is obtained with using a rubber member vulcanized with a radical-generating agent (e.g., an organic peroxide) and a thermoplastic resin having at least 2 atoms, on average, selected from H and S atom per molecule, each atom having not less than 0.006 of an orbital interaction energy coefficient S represented by the following formula (1): S=(CHOMO,n)2/|Ec?EHOMO,n|+(CLUMO,n)2/|Ec?ELUMO,n| ??(1) wherein Ec: an orbital energy (eV) of a radical, CHOMO,n: a molecular-orbital coefficient of a highest occupied molecular orbital (HOMO) of an n-th H or S atom constituting a basic unit of the resin, EHOMO,n: an orbital energy (eV) of the HOMO, CLUMO,n: a molecular-orbital coefficient of a lowest unoccupied molecular orbital (LUMO) of the n-th H or S atom constituting the basic unit of the resin, ELUMO,n: an orbital energy (eV) of the LUMO, and above all represent a value calculated by a semiempirical molecular orbital method MOPACPM3.
    Type: Grant
    Filed: January 9, 2002
    Date of Patent: February 13, 2007
    Assignee: Daicel-Degussa Ltd.
    Inventors: Toru Ikuta, Hajime Komada, Mitsuteru Mutsuda
  • Patent number: 7147930
    Abstract: A coextruded heat-shrinkable, biaxially-oriented multilayered packaging film comprising a first layer, a second polymer layer, a third polymer layer, and a fourth polymer layer wherein the first polymer layer comprises a first ethylene/?-olefin copolymer preferably, an ethylene/?-olefin copolymer having an ?-olefin comprising 4–8 pendant carbon atoms, a melting point of less than 105° C., a molecular weight distribution Mw/Mn of from 1–2.7, a melt index of from 6.5–34 g/10 min. at 190° C., and is present in the first layer is an amount of from 50–100%, based on the total weight of said first layer. The second layer comprises a second ethylene/?-olefin copolymer having a melt index of from 0.85–6.0 g/10 min.
    Type: Grant
    Filed: December 16, 2003
    Date of Patent: December 12, 2006
    Assignee: Curwood, Inc.
    Inventors: Thomas Andrew Schell, Gregory Robert Pockat
  • Patent number: 7063885
    Abstract: A multi-layer, thermoplastic film bi-axially oriented at a stretching ratio ? to about 3.0:1 in the machine direction and at a stretching ratio ? about 6.0:1 in the transverse direction, which film comprises a layer a) comprising at least 50 wt. % of a crystalline or partially crystalline co-polyamide characterized by a Tg?100° C. and at least one outer heat-sealing layer b) comprising a polyolefin, said film being further characterized in that it has a % free shrink at 100° C.?3 in each direction.
    Type: Grant
    Filed: February 27, 2001
    Date of Patent: June 20, 2006
    Assignee: Cryovac, Inc.
    Inventors: Eugenio Longo, Roberto Forloni, Gregorio Di Cesare
  • Patent number: 7029734
    Abstract: A multilayer packaging film, package and process for aseptic packaging applications. The multilayer packaging film includes (a) an inner sealant layer comprising a olefin polymer having a Vicat Softening Point greater than 90° C.; (b) an oxygen barrier layer; and (c) an outer layer comprising a polymeric layer selected from olefin polymers and polyester homopolymers or copolymers having a silicone or other hydrogen peroxide resistant exterior coating, said outer layer having a Vicat Softening Point greater than 90° C.
    Type: Grant
    Filed: August 20, 2002
    Date of Patent: April 18, 2006
    Assignee: Curwood, Inc.
    Inventors: Sam Edward Wuest, Richard Roy Bellile
  • Patent number: 7025843
    Abstract: The invention concerns manufactured articles comprising at least two assembled thermoplastic elements, a first element based on polyolefin and a second element based on polyamide. The elements are assembled by being welded together.
    Type: Grant
    Filed: March 15, 2001
    Date of Patent: April 11, 2006
    Assignee: Rhodia Engineering Plastics, S.A.
    Inventor: Nicolangelo Peduto
  • Patent number: 6989198
    Abstract: A multi-layer structure excellent in the barrier properties against alcohol gasoline, particularly hydrocarbon components, and also excellent in the interlayer adhesion, low-temperature impact resistance, heat resistance and chemical resistance is provided. The stractive is a multi-layer structure comprising two or more layers including at least a layer (a) comprising (A) nylon 11 and/or nylon 12 and a layer (b) comprising (B) a polyamide resin (nylon 9T) consisting of a dicarboxylic acid component and a-diamine component, with 60 to 100 mol % of the dicarboxylic acid component being a terephthalic acid and 60 to 100 mol % of the diamine component being a diamine component selected from 1,9-nonanediamine and 2-methyl-1,8-octanediamine, and preferably further including a layer (c) comprising (A) nylon 11 and/or nylon 12 or (C) nylon 6.
    Type: Grant
    Filed: October 14, 2003
    Date of Patent: January 24, 2006
    Assignees: Kuraray Co., Ltd., Ube Industries, Ltd.
    Inventors: Haruhisa Masuda, Yuji Munesawa, Koichi Warino, Tomoharu Nishioka, Yoshio Iwata, Koji Nakamura, Kozo Tamura, Tetsuya Hara
  • Patent number: 6979495
    Abstract: The present invention is directed to a biaxially oriented multi-layer film which comprises: (a) a core layer comprising a syndiotactic propylene homopolymer; and (b) at least one additional layer adjacent to the core layer comprising a polymer which is an ethylene or a propylene homopolymer, ethylene copolymer or terpolymer containing comonomers of propylene and/or butene-1. Optionally, there can be a skin layer applied to the exposed surface of the outer layer. The skin layer and/or the at least one additional layer is a polyolefin selected from the group consisting of isotactic polypropylene, polyethylene, ethylene-propylene random copolymer, ethylene-propylene block copolymer or ethylene-propylene-butene-1 terpolymer.
    Type: Grant
    Filed: December 21, 2001
    Date of Patent: December 27, 2005
    Assignee: ExxonMobil Oil Corporation
    Inventors: Jay K. Keung, Robert G. Peet, Michael T. Heffelfinger
  • Patent number: 6942927
    Abstract: A clear, multilayer polymeric film that is desirable for thermoforming applications. The film in its various embodiments include two inner layers of nylon and/or a core layer of ethylene vinyl alcohol or ethylene vinyl alcohol copolymer sandwiched between the two inner nylon layers. The film also has an outer layer of a heat sealable polymer and may also have an outer layer of nylon. The film is coextruded, blown into a tubular shape, oriented, and cooled by the method of tubular water quenching. The film has various improved physical properties over the prior art, including properties of “memory”, clarity, gloss and low haze.
    Type: Grant
    Filed: April 25, 2002
    Date of Patent: September 13, 2005
    Assignee: Pechiney Emballage Flexible Europe
    Inventors: Mary E. Shepard, Robert J. Blemberg, Scott W. Middleton, Jerry F. Jesse
  • Patent number: 6924013
    Abstract: The present invention relates to a coextrusion binder useful for petrol tanks of HDPE/binder/EVOH or PA/binder/HDPE structure.
    Type: Grant
    Filed: April 6, 2000
    Date of Patent: August 2, 2005
    Assignee: Arkema (formerly ATOFINA)
    Inventors: Jean-Claude Jammet, Christophe Le Roy, Xavier Marical, Jérôme Pascal
  • Patent number: 6908649
    Abstract: This invention relates to a coextruded biaxially stretched tubular film for the durable and crease-free covering of goods packaged in the liquid or pasty state, in particular foodstuffs such as sausage-meat for boiling or cooking or soft cheese, which are heated during and/or after they are packaged.
    Type: Grant
    Filed: September 7, 1994
    Date of Patent: June 21, 2005
    Assignee: Wolff Walsrode AG
    Inventors: Michael Hennig-Cardinal von Widdern, Gunter Weber
  • Patent number: 6893672
    Abstract: The present invention relates to a multilayer polymeric film structure and a food package made therefrom. Specifically, the present invention relates to a seven-layer non-EVOH structure having six layers of alternating nylon and adhesive, and a seventh layer of a heat sealable polymer. Either the sixth layer comprising the adhesive or the seventh layer comprising the heat sealable polymer may further comprise a polymer, preferably polybutylene, polypropylene and/or high density polyethylene, that may allow the film structure to be easily peelable when heat sealed. Moreover, the present invention relates to food packages made by the film structures having a easy-open peelable seal component contained therein.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: May 17, 2005
    Assignee: Pechiney Emballage Flexible Europe
    Inventor: Brian Ingraham
  • Patent number: 6887581
    Abstract: The present invention provides a laminate for automobile parts having a layer A made from a polyamide resin composition containing 70-99 wt % of (a) a specific polyamide polymer, and 1-30 wt % of (b-1) an ethylene copolymer containing an epoxy group and/or (b-2) an ethylene copolymer modified by an acid anhydride, and a layer B made from a resin composition containing (c-1) a polyethylene resin modified by an acid anhydride and/or (c-2) a polyethylene resin containing an epoxy group, wherein the layer A and the layer B are heat-sealed, except when (1) the layer A contains (b-1) alone as the ethylene copolymer and the layer B contains (c-2) alone as the polyethylene resin; and when (2) the layer A contains (b-2) alone as the ethylene copolymer and the layer B contains (c-1) alone as the polyethylene resin. The laminate of the present invention is superior in strength, stiffness and gasoline barrier property that the automobile parts are required to have.
    Type: Grant
    Filed: April 26, 2002
    Date of Patent: May 3, 2005
    Assignees: Toyo Boseki Kabushiki Kaisha, Toyoda Gosei Co., Ltd.
    Inventors: Tsutomu Tamura, Hideki Eguchi, Junji Koizumi, Satoru Watanabe
  • Patent number: 6869653
    Abstract: The present invention provides a flowable material container closure assembly having a port tube and a membrane tube. The port tube (I) has a first layer and a second layer, (A) the first layer is a polymer blend and (B) the second layer is disposed coaxially within the first layer; and the membrane tube (II) is disposed coaxially within the port tube, the membrane tube has an outer layer, a core layer and an inner layer.
    Type: Grant
    Filed: January 8, 2001
    Date of Patent: March 22, 2005
    Assignee: Baxter International Inc.
    Inventors: Michael T. K. Ling, William S. Hurst, Lecon Woo, Algirdas Bindokas, Patrick T. Ryan, Scott D. Edwards, Henk P. Blom, Atul R. Khare
  • Patent number: 6861127
    Abstract: Thermoformable plastic films can be formed into bags, pouches, trays, etc. which are useful when packaging foodstuffs and other products. These films enjoy widespread use in the packaging of meat and other oxygen sensitive products due to the gas permeation barrier provided. Thermoformable packaging films comprise one or more layers of thermoplastic, including olefinic copolymers, amorphous and crystalline nylons, ionomeric polymers, and polyolefins. By selecting the type and combination order of thermoplastics, a packaging film was developed that provides excellent impact and abrasion resistance, sealability, thermoformability, and optical clarity.
    Type: Grant
    Filed: October 20, 1999
    Date of Patent: March 1, 2005
    Assignee: Curwood, Inc.
    Inventors: Amy Lou Glawe, Adriana Nobre Rubo, Stephen James Vicik
  • Patent number: 6861125
    Abstract: A flexible packaging film construction which includes an outer layer of formable biaxially oriented polyester which is printed on one side and adhered to a flexible polyamide containing coextruded film.
    Type: Grant
    Filed: April 18, 2001
    Date of Patent: March 1, 2005
    Assignee: Curwood, Inc.
    Inventors: Andrea Maylene Carlson, Gregory Robert Pockat
  • Patent number: 6855387
    Abstract: A composite container having a barrier property and comprising a packaging material which comprises an inner surface layer, a barrier layer, and a base material layer wherein the barrier layer comprises one selected from nylon MXD 6 and a semi-aromatic polyamide resin, which is a copolymer comprising an aromatic polyamide forming component and an aliphatic polyamide forming component wherein the aromatic polyamide forming component comprises an aliphatic diamine and isophthalic acid and/or terephthalic acid, and the aliphatic polyamide forming component comprises a lactam or an aliphatic diamine, and an aliphatic dicarboxylic acid. The above packaging material may also comprise an inner surface layer having a barrier property and a base material layer wherein the inner surface layer having a barrier property comprises the above semi-aromatic polyamide resin.
    Type: Grant
    Filed: February 27, 2003
    Date of Patent: February 15, 2005
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventors: Kazuki Yamada, Hirotaka Tsunoda, Hideki Kurokawa
  • Patent number: 6855406
    Abstract: A polyolefin resin composition comprises (A) 10 to 100 wt % of a propylene/?-olefin random copolymer obtained by random copolymerization of propylene and a C2 to C20 ?-olefin, and having a melting point as measured by DSC of 40 to 115° C. and an ?-olefin content of 5 to 70 mol %, (B) 0 to 90 wt % of a random propylene resin having a melting point as measured by DSC of 120 to 150° C., and (C) an alicyclic saturated hydrocarbon resin having a glass transition point of 20 to 100° C. and a number average molecular weight of 1200 or less, the component (C) being used in an amount of 5 to 100 weight parts per 100 weight parts of the total amount of the components (A) and (B). A single-layer or multilayer film obtained from the polyolefin resin composition can be stretched at a lower temperature than in the conventional one, and a shrink film obtained by such a low-temperature stretching has a higher shrinkage factor than one stretched at a high temperature, and also has a small natural shrinkage factor.
    Type: Grant
    Filed: February 13, 2003
    Date of Patent: February 15, 2005
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hiroshi Takayasu, Norihide Inoue
  • Patent number: 6846551
    Abstract: A multilayer film structure having at least two layers wherein the first layer comprises poly(ethylene) having a density range from about 0.93 g/cc to 0.97 g/cc; and a second layer comprising poly(ethylene) having a density range from 0.89 g/cc to 0.93 g/cc wherein the second layer is capable of forming a heat seal. The multilayer film structure is capable of being laminated to another film structure or a packaging film component. The packages of the present invention are useful for the packaging of flowable materials.
    Type: Grant
    Filed: December 22, 1999
    Date of Patent: January 25, 2005
    Assignee: Pechiney Emballage Flexible Europe
    Inventors: Roger P. Genske, Russell P. Gehrke, Erin M. Duffy
  • Patent number: 6846534
    Abstract: Described is a membrane comprising a microlayer polymeric composite having at least about 10 microlayers. The microlayers are each individually up to about 100 microns thick and alternate between at least one gas barrier material and at least one elastomeric material. The membrane can be formed into a pressurized bladder or cushioning device for many applications, including footwear and hydropneumatic accumulators.
    Type: Grant
    Filed: May 23, 2003
    Date of Patent: January 25, 2005
    Assignee: Nike, Inc.
    Inventors: Henry W. Bonk, David J. Goldwasser, Paul H. Mitchell
  • Patent number: 6846530
    Abstract: A multilayered packaging film having good antifog performance that is suitable for use in food packaging. The multilayered film comprises a nylon film having first and second surfaces; a silicone oil on the first surface of the nylon film; and a sealant film on the second surface of the nylon film, either directly or via an intermediate adhesive tie layer. An antifog composition is either contained within at least part of the sealant film or is coated on a surface of the sealant film opposite the nylon film. The silicone oil effectively blocks the migration of the antifog composition into the nylon film when the multilayered film is stored in roll form.
    Type: Grant
    Filed: March 5, 2002
    Date of Patent: January 25, 2005
    Assignee: Honeywell International Inc.
    Inventors: Simon J. Porter, Jeffrey D. Moulton, Yuan-Ping Robert Ting
  • Patent number: 6838167
    Abstract: A printing and copying paper capable of printing or copying images distinctly on a large scale, without becoming curled or being blocked up in or sent out of machines as two or more than two of the papers being superposed, by means of high temperature high speed printing or copying machines, in which toners are to be fixed at high temperature, comprising a sheet of paper, a white polyethylene coating layer coating on the surface of the paper, said layer being laminated with a transparent heat resistant resin coating layer, or a transparent heat resistant resin film to form a glossy surface, and a transparent polyethylene coating layer coating on the back surface of the paper, said layer being coated with a transparent heat resistant resin coating liquid which is mixed with matting agents.
    Type: Grant
    Filed: March 11, 2003
    Date of Patent: January 4, 2005
    Assignees: Kokuyo Co., Ltd., Kisokaseisangyou Co., Ltd.
    Inventors: Yoshifumi Sokabe, Shin Nakashima
  • Patent number: 6838141
    Abstract: A hose of a laminated structure which comprises a rubber layer composed of a rubber composition, and a laminate including a metal foil and a resin, the rubber composition including: (A) a rubber including at least one of an ethylene-propylene-diene terpolymer and an ethylene-propylene copolymer; (B) a peroxide vulcanizing agent; (C) a resorcinol compound; and (D) a melamine resin. The hose is light in weight, less costly, and has excellent gas barrier properties.
    Type: Grant
    Filed: August 19, 2002
    Date of Patent: January 4, 2005
    Assignee: Tokai Rubber Industries, Ltd.
    Inventors: Ayumu Ikemoto, Motoshige Hibino, Hidehito Ikeda, Kazutaka Katayama
  • Publication number: 20040234797
    Abstract: A multilayer film includes a first and second outer layer each including a polymer; and an internal layer including an oxygen scavenger; where one of the first and second outer layers includes a blend of a polymer and an antifog agent, where the antifog agent includes one or more of glycerol fatty acid ester, polyglycerol fatty acid ester, polyethylene glycol fatty acid ester, polyethylene glycol alkyl ether, ethoxylated alkyl phenol, sorbitan ester, ethoxylated sorbitan ester, and alkanol; and wherein the first outer layer includes more than 3% and less than 8%, by weight of the first outer layer, of antifog agent. Unexpected improvements in oxygen scavenging and/or antifog properties of the film are obtained by the combination of the oxygen scavenger and antifog agent.
    Type: Application
    Filed: May 23, 2003
    Publication date: November 25, 2004
    Applicant: Cryovac, Inc.
    Inventors: Dwight W. Schwark, Drew Speer
  • Patent number: 6811844
    Abstract: The invention relates to a multilayer packaging comprising at least one cellulosic fibrous material substrate, and at least one polymeric film coated on the cellulosic substrate, where the polymeric film is made of at least one barrier layer comprising an olefin polymer, and at least one sealant layer comprising an amorphous polyamide, the sealant layer being a layer positioned so that it may contact the packaged product.
    Type: Grant
    Filed: December 19, 2002
    Date of Patent: November 2, 2004
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Yves M. Trouilhet
  • Patent number: 6805927
    Abstract: Laminates include a thermoplastic substrate layer, a clear coat layer, and a tie layer between the substrate and clear coat layers. The tie layer most preferably includes a first layer adjacent the thermoplastic substrate layer which is comprised of a polyolefin, and a second layer adjacent to the clear coat layer which is comprised of a polyamide. Most preferably, the substrate layer is TPO and the clear coat layer is PVF. The laminates may be employed to manufacture a variety of shaped articles, most preferably automotive trim components.
    Type: Grant
    Filed: August 16, 2002
    Date of Patent: October 19, 2004
    Assignee: Guardian Industries Corporation
    Inventors: Subir K. Dey, Subhash H. Patel, Marino Xanthos
  • Publication number: 20040180164
    Abstract: A multilayered packaging film having good antifog performance that is suitable for use in food packaging. The multilayered film comprises a nylon film having first and second surfaces; a sealant film positioned on the first surface of the nylon film, either directly on the first surface of the nylon film or via an intermediate adhesive; an antifog composition contained within at least part of the sealant film or coated on a surface of the sealant film opposite the nylon film; and a protective film applied onto the second surface of the nylon film.
    Type: Application
    Filed: March 29, 2004
    Publication date: September 16, 2004
    Applicant: Honeywell International Inc.
    Inventor: Simon J. Porter
  • Publication number: 20040180165
    Abstract: A multilayered packaging film having good antifog performance that is suitable for use in food packaging. The multilayered film comprises a nylon film having first and second surfaces; a sealant film positioned on the first surface of the nylon film, either directly on the first surface of the nylon film or via an intermediate adhesive; an antifog composition contained within at least part of the sealant film or coated on a surface of the sealant film opposite the nylon film; and a protective film applied onto the second surface of the nylon film.
    Type: Application
    Filed: March 29, 2004
    Publication date: September 16, 2004
    Applicant: Honeywell International Inc.
    Inventor: Simon J. Porter
  • Patent number: 6787224
    Abstract: A cover tape for packaging electronic components, which can prevent troubles associated with the peeling strength or trouble appearing during mounting of the electronic components, which can be produced at a low cost, and which is transparent; that is, a cover tape has a peeling strength not too high and not too low and small in difference between the maximum value and the minimum value and which has high transparency. Specifically, the cover tape for packaging electronic components, which can be heat-sealed to a plastic-made carrier tape having pockets capable of storing electronic components, formed regularly therein and which is made of (A) a biaxially oriented film layer made of polyester, a polypropylene or a nylon and (B) a thermoplastic resin layer composed of 100 parts by weight of an ethylene copolymer and 10 to 100 parts by weight of polystyrene, laminated to one side of the layer A.
    Type: Grant
    Filed: June 26, 2002
    Date of Patent: September 7, 2004
    Assignee: Sumitomo Bakelite Company Limited
    Inventors: Hisao Nakanishi, Masayuki Hiramatsu
  • Patent number: 6780522
    Abstract: Described is a single or multi-layered film having at least one polyamide layer (I) containing dispersed nanoscale nucleating particles. The smallest components of the dispersed nanoscale nucleating particles in layer (I) have an extension of less than 100 nm in at least one randomly selected direction for each component, based on a weighted average of all components of the dispersed nanoscale nucleating particles. Crystalline structures emanating from the surface of the dispersed nanoscale nucleating particles are formed after the layer (I) is cooled from the molten state at a rate of from 10 to 20° C. per minute. The dispersed nanoscale nucleating particles are present in the polyamide layer (I) in an amount of from 10 ppm to 3000 ppm, based on the total weight of layer (I).
    Type: Grant
    Filed: April 10, 2001
    Date of Patent: August 24, 2004
    Assignee: Wolff Walsrode AG
    Inventors: Holger Eggers, Andreas Gasse, Gregor Kaschel, Rainer Brandt, Bernd Eilers
  • Patent number: 6764729
    Abstract: A heat-shrinkable backseamed casing film comprises a first layer, a second layer, and a third layer, with the first and third layers being outer layers and the second layer being between the first layer and the third layer. The first outer layer serves as an inside casing layer, and comprises polyolefin; the second layer comprises polyester and/or polyamide; the third layer serves as an outside casing layer and comprises polyolefin, polystyrene, and/or polyamide. The second layer has a thickness of at least about 5% of a total thickness of the heat-shrinkable casing film. Alternatively, the first layer comprises polyolefin and has a surface energy level of less than about 34 dynes/cm; the second layer comprises a polyamide having a melting point of at least 300° F.; and the third layer comprises polyolefin, polystyrene and/or polyamide. A package comprises a cooked meat product within the backseamed casing.
    Type: Grant
    Filed: January 18, 2001
    Date of Patent: July 20, 2004
    Assignee: Cryovac, Inc.
    Inventors: Ram K. Ramesh, Michael J. Rosinski
  • Patent number: 6746757
    Abstract: The present invention relates to a multilayered molding comprising at least two of a layer A and a layer B, in which the layers A are formed on both sides of the layer B, each layer A comprises a same or different thermoplastic resin compositions, the layer A has a flexural modulus according to ASTM D790 of not less than 5,000 kg/cm2, the layer B comprises a thermoplastic resin composition and has a flexural modulus according to ASTM D790 of not more than 5,000 kg/cm2, and the ratio of flexular modulus of the layer A to flexural modulus of the layer B is not less than 5.
    Type: Grant
    Filed: February 16, 2000
    Date of Patent: June 8, 2004
    Assignee: Mitsubishi Engineering-Plastics Corporation
    Inventors: Kiyoji Takagi, Akihiro Kokubo, Koji Nishida
  • Patent number: 6746738
    Abstract: The present invention relates to a coextrusion binder comprising: 5 to 30 parts of a polymer (A), itself comprising a blend of a polyethylene (A1) of relative density between 0.935 and 0.980 and of a polymer (A2) chosen from elastomers, very low-density polyethylenes and ethylene copolymers, the (A1)+(A2) blend being cografted with an unsaturated carboxylic acid; 95 to 70 parts of a polyethylene (B) of relative density between 0.930 and 0.950; the blend of (A) and (B) being such that: its relative density is between 0.930 and 0.950, the content of grafted unsaturated carboxylic acid is between 30 and 10,000 ppm, the MFI (melt flow index) measured according to ASTM D 1238 at 190° C./21.6 kg is between 5 and 100. This binder is particularly useful for petrol tanks of structure: HDPE/binder/EVOH or PA/binder/HDPE.
    Type: Grant
    Filed: April 6, 2000
    Date of Patent: June 8, 2004
    Assignee: Atofina
    Inventors: Christophe Le Roy, Xavier Marical, Jérôme Pascal
  • Patent number: 6743523
    Abstract: The present invention provides a multilayer film. The film has a first layer of a blend of a first component selected from the group of: (1) ethylene and a-olefin copolymers having a density of less than about 0.
    Type: Grant
    Filed: March 16, 2000
    Date of Patent: June 1, 2004
    Assignee: Baxter International Inc.
    Inventors: Lecon Woo, Sherwin Shang, Michael T. K. Ling, Yuan-pang Samuel Ding, Tahua Yang, Craig Sanford
  • Patent number: 6740394
    Abstract: Multi-layer film laminate is described having at least 4 layers comprising at least one layer (I) as surface layer vapor-coated with aluminum or SiOx or a metal oxide from main groups 2 or 3, a gas barrier layer (II), at least one further layer (III) vapor-coated with aluminum or SiOx or a metal oxide from main groups 2 or 3 and a heat-sealable layer (IV), wherein the vapor-coated surface of layer (I) is adjacent to the following layer. Their use as high gas barrier films as wrapping of vacuum insulation panels is also described.
    Type: Grant
    Filed: September 21, 2001
    Date of Patent: May 25, 2004
    Assignee: Wipak Walsrode GmbH & Co. KG
    Inventors: Sven Jacobsen, Christian Kuckertz, Rainer Brandt
  • Patent number: 6740422
    Abstract: Described is a flexible, multilayered film comprising, (i) an outer layer composed substantially of polyamide containing nanodispersed filing material (e.g., in an amount of from 0.1 and 3 wt. %), and (ii) at least one additional polyamide layer. The multilayered film of the present invention may be produced by flat film or blown film methods. Also described is a method of using the multilayered film of the present invention as a packaging for foodstuff.
    Type: Grant
    Filed: April 9, 2001
    Date of Patent: May 25, 2004
    Assignee: Wolff Walsrode AG
    Inventors: Holger Eggers, Gregor Kaschel
  • Patent number: 6720046
    Abstract: A low scalping laminate material for a container for food packaging includes a core layer of paper or paperboard, a polymeric coating applied to one side of the core layer and a combination of layers disposed on an opposing side of the core layer. The combination of layers includes a first barrier layer disposed adjacent the core layer, a first tie layer adjacent the first barrier layer, a second barrier layer adjacent the first tie layer, a second tie layer adjacent the second barrier layer and a second polymeric coating adjacent the second tie layer. The second polymeric coating is configured for a food contacting surface. The first and second barrier layers are formed from an admixture of an aromatic polyamide resin and polyamide 6, and the first and second tie layers are formed from one of a modified polyethylene and a polyolefin. A carton formed from the low scalping laminate is disclosed.
    Type: Grant
    Filed: June 14, 2001
    Date of Patent: April 13, 2004
    Assignee: Tetra Laval Holdings & Finance, S.A.
    Inventors: Stuart Schwartz, Tsuyoshi Baba, Nils Toft
  • Patent number: 6689472
    Abstract: An apparatus for manufacturing an extruded plastic product, the apparatus including at least one rotor and at least one stator defining a clearance having a feed gap between them, the rotor and stator collectively including a groove for moving material to be extruded from a feed zone of the apparatus to a shear zone of the apparatus upon rotation of the rotor and a countergroove for facilitating the extrusion of the material, the groove and countergroove being disposed on opposite sides of the feed gap, the countergroove having a thread that is opposite in direction to a thread of the groove, the groove having a cross-section that is substantially unchanging, the countergroove being disposed substantially along an entire length of the shear zone, the groove, countergroove and clearance forming a processing cavity having a volume that is the volumes of grooves, countergrooves and the clearance, the processing cavity having a cross-sectional area that decreases continuously along at least a part of an axis of t
    Type: Grant
    Filed: August 28, 2001
    Date of Patent: February 10, 2004
    Assignee: Uponor Innovation AB
    Inventors: Jyri Järvenkylä, Kari Kirjavainen, Michael Sjöberg
  • Patent number: 6685861
    Abstract: Oxygen barrier polyamide compositions exhibiting high oxygen scavenging capability suitable for extended shelf-life, packaging applications. Thus a polyamide composition comprises a polyamide homopolymer, copolymer, or blends thereof, and at least one polyamide reactive, oxidizable polydiene or oxidizable polyether. The polyamide products are particularly suited to making barrier packaging articles such as monolayer or multi-layer films, sheets, thermoformed containers and coinjection/coextrusion blow molded bottles comprising PET, polyolefin or polycarbonate as structural layers. Such articles are useful in a variety of oxygen-sensitive food, beverage, pharmaceutical and health care product packaging applications.
    Type: Grant
    Filed: January 4, 2002
    Date of Patent: February 3, 2004
    Assignee: Honeywell International Inc.
    Inventors: Murali K. Akkapeddi, Timothy J. Kraft, Edward P. Socci
  • Patent number: 6677013
    Abstract: A multilayer plastic container comprises a layer of a polypropylene and a layer of EVOH directly adjacent the layer of polypropylene wherein at least one of the polypropylene and EVOH layers comprises an adhesive such as maleic anhydride concentrate mixed therein to adhere the layer of polypropylene to the layer of EVOH.
    Type: Grant
    Filed: April 16, 1999
    Date of Patent: January 13, 2004
    Assignee: Pechiney Emballage Flexible Europe
    Inventors: Kevin James Curie, Randolph Lee Davidson, Sahin Emre
  • Patent number: 6670004
    Abstract: A laminated nylon air brake tubing is formed from outer and inner layers of nylon 11 or nylon 12 with inner layers of nylon 6. The nylon 6 and nylon 11 or 12 layers are adhered together by a tie layer. The tie layer is preferably a nylon 6-12 or an anhydride modified polyolefin. The air brake tubing has improved high temperature strength and low temperature impact resistance characteristics.
    Type: Grant
    Filed: August 2, 2000
    Date of Patent: December 30, 2003
    Assignee: Saint-Gobain Performance Plastics Corporation
    Inventor: Edward A. Green
  • Patent number: 6667101
    Abstract: The present invention relates to a thermoformable multilayer film comprising in succession: a protective layer (A); a transparent layer (B) comprising (by weight the total amount being 100%) 0 to 100% of a fluoropolymer (B1) and 100 to 0% of a polymer (B2) essentially consisting of alkyl (meth)acrylate units; a layer (C) based on a polyamide with amine terminal groups; a layer (D) consisting of a polyolefin functionalized by an unsaturated carboxylic acid anhydride; a bonding layer (E) made of a polyolefin, said film being obtained by coextruding the various layers, said film being used to cover various substrates, for example by injection-moulding the substrate in the melt onto the multilayer film placed in the bottom of an injection mould, the layer (A) of the film being placed against the wall of the mould.
    Type: Grant
    Filed: January 26, 2001
    Date of Patent: December 23, 2003
    Assignee: Atofina
    Inventors: David Silagy, Jose Teixeira Pires, Philippe Bussi, Anthony Bonnet
  • Patent number: 6656548
    Abstract: A laminate comprising first and second polymeric films. One of the films is heat shrinkable and the other of the first and second films is non-heat shrinkable. At least one of the first and second films has an oxygen permeance of no more than about 150 cm3/m2·atm·24 hours at 23° C. and 0% relative humidity. The first film comprises an outer layer which, even when untreated, has a surface energy of at least 0.034 J/m2, and at least about 10 weight percent of one or more polymers having a Vicat softening point of at least about 65° C. The first film outer layer forms a first outer surface of the laminate. The outer layer of the second film forms the second outer surface of the laminate. The laminate has an improved ability to be sealed about a forming shoe without necking down.
    Type: Grant
    Filed: September 18, 2000
    Date of Patent: December 2, 2003
    Assignee: Cryovac, Inc.
    Inventors: Scott W. Beckwith, Ram K. Ramesh, Michael J. Rosinski
  • Patent number: 6656601
    Abstract: The adhesive ethylene copolymer composition of the invention comprises a specific long-chain branched ethylene/&agr;-olefin copolymer (or this copolymer and its graft-modified product) and a tackifier (or a specific ethylene/vinyl acetate copolymer), and has specific density, MFR, crystallinity and graft quantity. The composition containing the tackifier can form a layer having good adhesive force to polystyrene resins, ABS resin, polyacrylonitrile resins and ethylene/vinyl acetate copolymer saponified resins even in an atmosphere of high temperatures. The composition containing the ethylene/vinyl acetate copolymer can form a layer having good adhesive force to polyester resins, polycarbonate resins, polyvinylidene chloride resins and ethylene/vinyl acetate saponified resins even in an atmosphere of high temperatures. The other adhesive ethylene copolymer composition of the invention comprises a blend of a graft-modified linear ethylene/&agr;-olefin copolymer and an olefin elastomer.
    Type: Grant
    Filed: October 10, 2000
    Date of Patent: December 2, 2003
    Assignee: Mitsui Chemicals Inc.
    Inventors: Hideshi Kawachi, Yuji Sawada, Haruhiko Tanaka
  • Patent number: 6645640
    Abstract: The present invention provides a multilayered polyamide film having at least two polyamide resin layers, which develops less than 10 pinholes when evaluated for pinhole resistance by flexing it 1,000-times at 25° C. and which has an elongation of 6 mm or less at 120° C. in vertical pitch evaluation. This film has excellent resistance to pinholes and is well suited for lamination.
    Type: Grant
    Filed: September 20, 2001
    Date of Patent: November 11, 2003
    Assignee: Gunze Limited
    Inventor: Hiroki Kuriu
  • Patent number: 6641882
    Abstract: An object of the present invention is to: eliminate the need to provide a tool such as a pair of scissors for partly opening a packaging bag; and allow the packaging bag to be partly opened easily when it is heated in a microwave oven, based on an increase in internal pressure caused by vapors associated with heating. To attain this object, the present invention provides a packaging bag made using as a material a synthetic resin film adapted for a microwave oven, wherein a layer constituting an inner surface is formed of a blend of a straight chain low-density polyethylene resin and a polybutene-1 resin, and one of opposite heat sealed portions perpendicular to a film flowing direction has a portion with a smaller heat seal width at an appropriate position.
    Type: Grant
    Filed: November 27, 2000
    Date of Patent: November 4, 2003
    Assignee: Daiwa Gravure Co., Ltd.
    Inventor: Yukihiko Shibata
  • Patent number: 6638588
    Abstract: A multilayer permeable film structure having high temperature capabilities comprising a first, perforated sealable layer; a second primer layer and a third outer layer is disclosed. The multilayer permeable film structure can be heat sealed to a formed tray containing a volatile material.
    Type: Grant
    Filed: June 16, 2000
    Date of Patent: October 28, 2003
    Assignee: Pechiney Emballage Flexible Europe
    Inventors: William E. Bowen, Michael Stecker
  • Patent number: 6635324
    Abstract: A medical grade tubing that includes a layer of ultra low density polyethylene that has been let down, or drawn down, in diameter approximately 10% to about 50% in an extrusion process and an inner layer of an RF responsive material, the tubing allowing for the selective connection of the tubing to another tubing using a sterile welding device.
    Type: Grant
    Filed: January 21, 1998
    Date of Patent: October 21, 2003
    Assignee: Baxter International, Inc.
    Inventors: Ludwig Wolf, Jr., Michael T. K. Ling
  • Patent number: 6632521
    Abstract: Polymeric films having at least one outer layer consisting of a blend of low density polyethylene and a poly-(alkylstyrene) can be heat sealed to non-woven webs such as paper to produce peel openable packages, for example for medical equipment. Such packages can be peeled open with low fiber lift from the non-woven webs.
    Type: Grant
    Filed: June 8, 2001
    Date of Patent: October 14, 2003
    Assignee: Rexam Medical Packaging Ltd
    Inventors: Roy Christopherson, David Thomas Stell