Static Electricity Metal Bleed-off Metallic Stock Patents (Class 428/922)
  • Patent number: 5399398
    Abstract: The improved photomask container which is molded and fabricated from a thermoplastic resin is characterized in that the thermoplastic resin comprises a cellulose ester and that the surface of the molded and fabricated article is saponified with an alkali. The container does not give off malodor, has electric conductivity and is free from the problem of sodium release.
    Type: Grant
    Filed: August 24, 1993
    Date of Patent: March 21, 1995
    Assignee: Toppan Printing Co., Ltd.
    Inventors: Watanabe Toshimitsu, Y. Matsuzawa
  • Patent number: 5397608
    Abstract: The present invention relates to articles, particularly plate or sheet-like articles made of plastic in which very low contents of fine electrically conductive fibers are uniformly dispersed so as to make the articles conductive. It also relates to specific intermediate plastic products, referred to as grains, threads and granules, and the processes for manufacturing each of these products as well as the final conductive articles. The articles can be used as a suitable shielding against radio-frequency and high-frequency electromagnetic radiation or as antistatic plastic articles.
    Type: Grant
    Filed: July 23, 1986
    Date of Patent: March 14, 1995
    Inventor: Lode J. Soens
  • Patent number: 5393610
    Abstract: A method for stabilizing shelf life conductivity of conductive coatings such as polypyrrole or nickel sulfide on a substrate such as fiberglass, by incorporating in such conductive coating a polyphenol or a polysiloxane. The polyphenol is derived from a phenolic material in the form of a phenol-formaldehyde monomer or an oligomer of phenol-formaldehyde, and the polysiloxane is derived from a siloxane. Upon heating, the phenolic material cures to a polyphenol and the siloxane is converted to a polysiloxane, forming the stabilizing material on the conductive polypyrrole or nickel sulfide coated substrate. The phenolic material is preferably incorporated directly into the solution formulation for preparing the conductive nickel sulfide or polypyrrole on the substrate, and the polyphenol stabilizer is formed together with the conductive coating on the substrate by heating.
    Type: Grant
    Filed: February 5, 1993
    Date of Patent: February 28, 1995
    Assignee: Rockwell International Corporation
    Inventors: Edward F. Witucki, William P. Moran, Patricia H. Cunningham, Lyle V. Monney
  • Patent number: 5370981
    Abstract: Antistatically treated plastic formed articles, e.g. photographic film supports, that contain at least two layers on the surface to be antistatically treated, wherein a layer nearer to the plastic surface contains a preparation of a polythiophene that is built up from structural units of the formula ##STR1## wherein R.sub.1 and R.sub.2 independently of each other stand for hydrogen or a C.sub.1 -C.sub.4 -alkyl group or together form an optionally substituted C.sub.1 -C.sub.4 -alkylene group, preferably a methylene group optionally substituted by alkyl groups, a 1,2-ethylene group optionally substituted by C.sub.1 -C.sub.12 -alkyl or phenyl groups, a 1,3-propylene group or a 1,2-cyclohexylene group,and a polyanion, a farther layer contains a film-forming polymer and at least one of the two layers contains an alkoxysilane, are characterized, apart from excellent antistatic properties, by very good layer adhesion.
    Type: Grant
    Filed: March 24, 1993
    Date of Patent: December 6, 1994
    Assignee: Agfa-Gevaert AG
    Inventors: Werner Krafft, Friedrich Jonas, Bavo Muys, Dirk Quintens
  • Patent number: 5368913
    Abstract: Antistatic spunbonded nonwoven fabrics are provided. The fabrics of the invention include a plurality of substantially continuous electrically nonconductive filaments formed of a thermoplastic polymer, a plurality of electrically conductive filaments distributed among the electrically nonconductive filaments throughout the fabric, and a multiplicity of discrete bond sites bonding together the electrically nonconductive and the electrically conductive filaments to form a coherent fabric.
    Type: Grant
    Filed: October 12, 1993
    Date of Patent: November 29, 1994
    Assignee: Fiberweb North America, Inc.
    Inventor: Albert E. Ortega
  • Patent number: 5360658
    Abstract: The present invention relates to antistatic extruded polycarbonate sheets produced from thermoplastic polycarbonates, polyalkylene terephthalates and carbon black, as well as processes for the production of such sheets.
    Type: Grant
    Filed: March 11, 1993
    Date of Patent: November 1, 1994
    Assignee: Bayer Aktiengesellschaft
    Inventors: Jurgen Schmitz, Hans-Leo Weber, Hans-Josef Fausten, Hans-Wolfgang Schmoranzer, Udo Hansel
  • Patent number: 5354610
    Abstract: Disclosed is a magnetic recording medium which comprises;(a) a non-magnetic support; and provided thereon, in sequence(b) a conductive layer containing carbon black preferably with a DBP absorption of 100 cc/.sub.100g or more, an average particle size of 5 to 30 microns and a pH of less than 5; and(c) a magnetic layer;(I) containing tabular barium ferrite magnetic particles in each of which the axis of easy magnetization is substantially perpendicular to the plane surface and 7 to 30 parts by weight of alpha alumina; and 0.1 to 5 parts by weight, per 100 parts by weight of said magnetic particles, of carbon black with an average particle size of 40 to 300 m.mu.; and(II) is formed on said conductive layer by the wet-on-wet method; a magnetic recording medium according to this invention is improved both in durability and electromagnetic conversion characteristics.
    Type: Grant
    Filed: April 14, 1992
    Date of Patent: October 11, 1994
    Assignee: Konica Corporation
    Inventors: Kimio Ozawa, Hisato Kato, Hiromichi Enomoto, Akihiro Maezawa
  • Patent number: 5346736
    Abstract: A magnetic tape cassette in which critical parts subject to wear are coated with a hard coating such as an ultraviolet-cured resin. Among other effects, the generation of rubbed-off powder is reduced, thereby reducing the amount of data drop-out. Also, the case of the cassette is protected from damage.
    Type: Grant
    Filed: December 15, 1992
    Date of Patent: September 13, 1994
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masato Mizuno, Kengo Oishi
  • Patent number: 5340499
    Abstract: Compositions and methods are described that relate to the use of reaction products of metal compounds and protonic acids for plasticizing and neutralizing acidic, protonated compositions comprising substituted and unsubstituted polyanilines and co-polymers and or mixtures thereof; and for reducing the percolation threshold for conductivity in blends with insulating bulk polymers.
    Type: Grant
    Filed: August 11, 1992
    Date of Patent: August 23, 1994
    Assignee: Neste Oy
    Inventors: Toivo Karna, Jukka Laakso, Timo Niemi, Heikki Ruohonen, Esko Savolainen, Helge Lindstrom, Esa Virtanen, Olli Ikkala, Alejandro Andreatta
  • Patent number: 5338608
    Abstract: Copolymers of perfluoro(1,3-dimethyl-2,2-dioxole) with perfluoro(butenyl vinyl ether) and, optionally, with a third comonomer are amorphous in all monomer proportions, and soluble in perfluoro(2-butyl tetrahydrofuran). These copolymers are suitable in many high technology applications, especially where solubility is important, e.g., in applying coatings to substrates or articles for protection against mechanical, chemical, or environmental hazards. Dipolymers of the present invention have lower glass transition temperatures than dipolymers of perfluoro(1,3-dimethyl-2,2-dioxole) with tetrafluoroethylene having the same monomer proportions.
    Type: Grant
    Filed: November 9, 1993
    Date of Patent: August 16, 1994
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Paul R. Resnick
  • Patent number: 5326966
    Abstract: The present invention relates to a polyester film having an antistatic highly adhesive layer and a process for producing the film, said layer comprising a copolymer (A) and a (co)polymer (B), said copolymer (A) being obtained by copolymerizing ##STR1## N-methylol acrylamide, and optionally an ethylenic compound having a carboxy group, and optionally a comonomer, and said (co)polymer (B) being obtained by copolymerizing ##STR2## and optionally a comonomer. The polyester film of the present invention is useful for magnetic cards and the like.
    Type: Grant
    Filed: October 7, 1992
    Date of Patent: July 5, 1994
    Assignee: Teijin Limited
    Inventors: Masayuki Fukuda, Sadayoshi Miura
  • Patent number: 5324579
    Abstract: A nonwoven textile material useful in dissipating static electric charges containing an electrically conductive polytetrafluoroethylene fiber. An amount of a synthetic fiber may be intermixed with the electrically conductive polytetrafluoroethylene fiber to produce the static dissipative textile material. The nonwoven static dissipative textile material may combine with a porous polymeric membrane to form nonwoven fabric laminate.The nonwoven textile material is useful as a filtration media and may be fabricated into a filter bag.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: June 28, 1994
    Assignee: W. L. Gore & Associates, Inc.
    Inventors: Robert Sassa, Richard Winkelmayer, Jr.
  • Patent number: 5314732
    Abstract: A film providing electrostatic shielding comprises a first layer of a carrier material and a second layer of a thermoplastic, polymeric material, both layers being electrically insulative, flexible and transparent, and there further being a plurality of thin, conductive slivers suspended in the second layer. The slivers form an essentially two-dimensional, conductive network which is suspended in the second layer, and may be present in an amount as little as 2 g/m.sup.2. The slivers have a melting temperature greater than the melting temperature of the polymeric material, and the polymeric material has a melting temperature lower than that of the carrier material. The film passes at least 70% of visible light.
    Type: Grant
    Filed: June 28, 1991
    Date of Patent: May 24, 1994
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Orville M. Wiste
  • Patent number: 5296307
    Abstract: The use of inorganic additives such as mica in the polyolefin layer of paper polyolefin paper laminates improves the electrical characteristics, gives resistance to discharge, and facilitates reduction of swelling in contact with oil. Accordingly, the present invention provides laminated paper polyolefin paper composites comprising first and second fiber paper layers, and a polyolefin layer comprising an inorganic additive such as mica.
    Type: Grant
    Filed: May 8, 1992
    Date of Patent: March 22, 1994
    Assignee: Electric Power Research Institute, Inc.
    Inventor: Bruce S. Bernstein
  • Patent number: 5290634
    Abstract: The present invention provides a curable antistatic agent polymer excellent in water resistance which is obtained by polymerizing a mixture of polymerizable monomer components comprising two components of a polymerizable vinyl monomer (I) having a sulfonic acid group or a salt thereof as a substituent and a monomer (II) represented by the following formula (II) or a mixture of these two components and an additional polymerizable monomer component in a water-miscible organic solvent or a mixed solvent comprising a water-miscible organic solvent and water in the presence or absence of a resin soluble in said solvent: ##STR1## wherein R.sup.1 and R.sup.2 each represents a hydrogen atom or a methyl group and R.sup.3 represents a hydrogen atom or an alkyl group of 1 to 8 carbon atoms.
    Type: Grant
    Filed: February 4, 1991
    Date of Patent: March 1, 1994
    Assignee: Mitsubishi Paper Mills Limited
    Inventors: Akira Furukawa, Hidetsugu Oda
  • Patent number: 5281472
    Abstract: A polyester film having on at least one side, a primer layer comprising a crosslinked product between (a) a polyurethane having (0.22-33).times.10.sup.-4 gram equivalent/gram of resin, of at least one functional group selected from a carboxyl group and a salt group derived therefrom and (b) a polyepoxy compound, said crosslinked product containing (c) an antistatic agent composed mainly of a compound represented by the following general formula (I) ##STR1## wherein R represents an alkyl group of 4-20 carbon atoms, and M.sub.1 and M.sub.2 each represent an alkali metal ion, an ammonium group or a tertiary amino group, as well as a process for producing said film. The film is useful as a base material for highly processed polyester film products such as magnetic tape, floppy disc, X-ray photographic film, telephone card, OHP, base for printing plate and the like.
    Type: Grant
    Filed: January 2, 1992
    Date of Patent: January 25, 1994
    Assignee: Teijin Limited
    Inventors: Teruo Takahashi, Toshiya Koyama, Sadayoshi Miura
  • Patent number: 5264992
    Abstract: A computer base unit has a keyboard and computer peripherals. A removable workslate, capable of stand-along operation and containing a digitizer display, computer and rechargeable power supply attaches to the base unit through an interlocking connector that holds the workslate in a tilted position and connects the base unit and its peripherals to the workslate computer. The base unit and workslate comprise housings are constructed of a composite comprising layers of woven, resin impregnated fibers and a layer of electromagnetic shielding.
    Type: Grant
    Filed: February 11, 1993
    Date of Patent: November 23, 1993
    Assignee: Tusk, Incorporated
    Inventors: Per Hogdahl, William Hart, Charles Krallman, Kenneth Shaw
  • Patent number: 5262229
    Abstract: A conductive releasable adhesive and method of making same for electrostatic discharge controlled surfaces in which a multiplicity of interlacing electrically conductive fibers is suspended in a releasable adhesional substance forming a conductive matrix throughout the volume of the adhesional substance for facilitating dissipation of electrical charges.
    Type: Grant
    Filed: November 4, 1991
    Date of Patent: November 16, 1993
    Assignee: United Technical Products, Inc.
    Inventors: Bruce G. Lampert, William Klein
  • Patent number: 5244728
    Abstract: A photographic paper coated with a polyolefin resin layer on each surface, one of the free surfaces of one of the polyolefin layers bearing a print retaining antistatic layer, the print retaining antistatic layer consisting essentially of an aluminum modified colloidal silica and an antistatic agent in a binder polymer, the binder polymer consisting essentially of an addition product of from about 30 to 78 mol % of an alkyl methacrylate wherein the alkyl group has from 3 to 8 carbon atoms, from about 2 to about 10 mol % of an alkali metal salt of an ethylenically unsaturated sulfonic acid and from 20 to about 65 mol % of a vinyl benzene, the polymer having a glass transition point of from 30.degree. to 65.degree. C.
    Type: Grant
    Filed: February 24, 1992
    Date of Patent: September 14, 1993
    Assignee: Eastman Kodak Company
    Inventors: Wayne A. Bowman, Mario D. DeLaura, Norman S. Edgett
  • Patent number: 5236818
    Abstract: A coating of a mixture of sodium orthosilicate together with a silica sol and a silane coupling agent provides antistatic protection when overcoated with a gelatin containing photographic construction.
    Type: Grant
    Filed: November 2, 1992
    Date of Patent: August 17, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Robert L. Carlson
  • Patent number: 5224363
    Abstract: This invention relates to a method of making a protective garment, a garment produced in accordance with the method, and a strand material used in the method and garment. The strand material comprises cut resistant material such as Kevlar, aramid, metallic, and combined Kevlar and metallic strands, or the like, which are extrusion coated with vinyl, polyurethane or other suitable fluid impervious material. Coating the strands with fluid impervious material results in a cut resistant high strength fabric which is resistant to staining. The method comprises manipulating the strand material using substantially conventional textile fabric forming technology such as knitting to form a fabric and a garment, and may include coating the finished garment to achieve enhanced characteristics. One such characteristic which may be achieved is to make a garment fluid impervious, by coating a substrate with fluid impervious materials such as flexible urethane to protect the wearer.
    Type: Grant
    Filed: June 27, 1991
    Date of Patent: July 6, 1993
    Assignee: Golden Needles Knitting & Glove Co., Inc.
    Inventor: Roger I. Sutton
  • Patent number: 5217767
    Abstract: Flexible sheet materials and envelopes are described which are useful for packaging electronic components. The sheet material includes an electrically insulating film with a conductive layer on the upper surface and an antistatic layer carried by the lower surface The antistatic layer includes a fluoroaliphaticsulfonamide polyether compound. Optionally a tie layer may be included between the film and the antistatic layer.
    Type: Grant
    Filed: December 18, 1991
    Date of Patent: June 8, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Gustav Gutman, Maynard E. Skrivseth
  • Patent number: 5213887
    Abstract: A bilayer coating of layers of inorganic metal oxide sol and a layer of a chitosan salt provides improved antistatic properties over a polymeric film substrate.
    Type: Grant
    Filed: September 3, 1991
    Date of Patent: May 25, 1993
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: William A. Huffman
  • Patent number: 5213882
    Abstract: A nonwoven textile material useful in dissipating static electric charges containing an electrically conductive polytetrafluoroethylene fiber. An amount of a synthetic fiber may be intermixed with the electrically conductive polytetrafluoroethylene fiber to produce the static dissipative textile material. The nonwoven static dissipative textile material may combine with a porous polymeric membrane to form nonwoven fabric laminate.The nonwoven textile material is useful as a filtration media and may be fabricated into a filter bag.
    Type: Grant
    Filed: December 18, 1991
    Date of Patent: May 25, 1993
    Assignee: W. L. Gore & Associates, Inc.
    Inventors: Robert Sassa, Richard Winkelmayer, Jr.
  • Patent number: 5208103
    Abstract: The present invention provides a cover tape used for packaging of electronic parts in the form of a chip, which comprises an outer layer, an intermediate layer and an adhesion layer and which is heat-sealable to a plastic carrier tape having at given intervals pockets for accommodation of chip type electronic parts, characterized in that the outer layer is a biaxially oriented film, the intermediate layer is a polyolefin film which causes its own cohesive failure to enable peeling, and the adhesion layer consists of a dispersion of conductive fine powders of tin oxide or the like in a thermoplastic resin.
    Type: Grant
    Filed: October 30, 1991
    Date of Patent: May 4, 1993
    Assignee: Sumitomo Bakelite Company Limited
    Inventors: Tomoharu Miyamoto, Shigeru Maeda
  • Patent number: 5194327
    Abstract: An antistatic polyester film comprises a polyester film having provided on one or both surfaces thereof a thin layer of a mixed composition, wherein(1) the mixed composition is composed essentially of(A) a polyester polyacrylic copolymer (component A);(B) an anion-type high molecular weight antistatic agent (component B);(C) a fine particle having an average particle diameter of no greater than about 0.5 .mu.m (component C); and(D) a wetting agent (component D); and wherein(2) said components A, B, C, and D are present in amounts of about 20 to about 80 parts by weight, about 15 to about 70 parts by weight, about 5 to about 40 parts by weight, and 0 to about 30 parts by weight, respectively, per 100 parts by weight in total of the components A, B and C. Also, a method for producing such antistatic polyester film is described.
    Type: Grant
    Filed: April 22, 1991
    Date of Patent: March 16, 1993
    Assignee: Teijin Limited
    Inventors: Teruo Takahashi, Sadayoshi Miura
  • Patent number: 5192613
    Abstract: Electrographic recording element with reduced humidity sensitivity comprising(1) a base, e.g., paper, polymer film,(2) a conductive layer of a continuous coating of an electroconductive composition comprising(a) polymeric binder,(b) electroconductive powder comprising amorphous silica or a silica-containing material in association with a two-dimensional network of antimony-containing tin oxide crystallites in which the antimony content ranges from 1 to about 30% by weight of tin oxide; and(3) a dielectric layer.Mixtures of two or more different sized electroconductive powder particles can be used.The electrographic recording element is useful for recording high-speed computer element, e.g., in geophysical mapping, weather map printing, architectural and engineering drawings, etc.
    Type: Grant
    Filed: November 30, 1990
    Date of Patent: March 9, 1993
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Ray A. Work, III, Clifford E. Milner, Sarah J. Kintner, James E. Genthe, Stephen Strella, Charles R. Iacovella
  • Patent number: 5182169
    Abstract: The present invention relates to a polyester film having an antistatic highly adhesive layer and a process for producing the film, said layer comprising a copolymer (A) and a (co)polymer (B), said copolymer (A) being obtained by copolymerizing ##STR1## N-methylol acrylamide, and optionally an ethylenic compound having a carboxy group, and optionally a comonomer, and said (co)polymer (B) being obtained by copolymerizing ##STR2## and optionally a comonomer. The polyester film of the present invention is useful for magnetic cards and the like.
    Type: Grant
    Filed: December 13, 1990
    Date of Patent: January 26, 1993
    Assignee: Teijin Limited
    Inventors: Masayuki Fukuda, Sadayoshi Miura
  • Patent number: 5180615
    Abstract: A flexible sheet material and bags made therefrom for packaging electrostatically sensitive items such as electronic circuit boards. The sheet has a metal layer and an antistatic layer. The outer surface of the bag has a high non-conductive surface resistivity greater than or equal to 10.sup.8 ohms/square, yet the bag protects the packaged item from static voltage by preventing the capacitive coupling of the voltage through the bag to the item packaged therein.
    Type: Grant
    Filed: December 13, 1989
    Date of Patent: January 19, 1993
    Assignee: W.R. Grace & Co.-Conn.
    Inventor: Marvin R. Havens
  • Patent number: 5175033
    Abstract: A flexible sheet material and bags made therefrom for packaging electrostatically sensitive items such as electronic circuit boards. The sheet has a metal layer that is adhesively laminated to an antistatic polymeric layer, the instant bag being of improved metal layer to antistatic layer adhesion. The metal outer surface of the bag has a high non-conductive surface resistivity greater than or equal to 10.sup.8 ohms/square, yet the bag protects the packaged item from static voltage by preventing the capacitive coupling of the voltage through the bag to the item packaged therein.
    Type: Grant
    Filed: June 22, 1990
    Date of Patent: December 29, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventor: Marvin R. Havens
  • Patent number: 5165985
    Abstract: A method of making a flexible, transparent film providing electrostatic shielding by applying a plurality of thin, conductive slivers to a sheet having a dimensionally stable layer and a thermoplastic layer, the slivers being applied to the thermoplastic layer, and then laminating a cover sheet over the thermoplastic layer, the cover sheet being formed of the same material as the thermoplastic layer. The thermoplastic layer is heated to its melting pint, and the cover sheet is extruded and laminated in a molten state whereby the cover sheet blends with the thermoplastic layer to form a single, homogenous layer. The slivers form an essentially two-dimensional, conductive network which is suspended in the homogenous layer.
    Type: Grant
    Filed: June 28, 1991
    Date of Patent: November 24, 1992
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Orville M. Wiste, Santosh Collison, Vijay A. Kumar
  • Patent number: 5160775
    Abstract: This invention relates to an antistatic mat, for example, a chair mat used for computer operation, a floor mat to be used at a room door, in an elevator or in front of an elevator door, and a car floor mat, and more particularly relates to an antistatic mat which is capable of instantly discharging the static electricity charged on a human body, removing a disagreeable sensation which is occasionally generated by the discharging of the static electricity.
    Type: Grant
    Filed: December 27, 1990
    Date of Patent: November 3, 1992
    Assignee: Daiwa Company, Ltd.
    Inventor: Kohei Yamada
  • Patent number: 5160374
    Abstract: A semi-insulating coating or surface layer is applied over insulating materials such as a circuit board or wiring harness or feedthrough insulator. The paint is electrically fixed to ground and as a result leaks away charge buildup before large pulse discharges occur. For example, pure tin oxide particles in phenoxy resin binder forms a paintable application for the invention.
    Type: Grant
    Filed: July 24, 1990
    Date of Patent: November 3, 1992
    Assignee: The United States of America as represented by the Secretary of the Air Force
    Inventors: Arthur R. Frederickson, Joseph E. Nanevicz, Jeffrey S. Thayer, Dean B. Parkinson
  • Patent number: 5154886
    Abstract: By using a specific polymer material for handling, shipping, and storage, integrated circuits are protected from both corrosion and electrostatic discharge. This enclosure material includes a polymer matrix with both carbon black and a metal embedded. Suitable metals include copper, iron, cobalt, and manganese.
    Type: Grant
    Filed: July 27, 1990
    Date of Patent: October 13, 1992
    Assignee: AT&T Bell Laboratories
    Inventors: John P. Franey, Thomas E. Graedel
  • Patent number: 5147714
    Abstract: An antistatic laminated fabric having conductive tie yarns and a non-woven scrim which is laminated between two conductive sheets of PVC film. In one embodiment, all yarns in the warp direction are of the same denier, and the yarns in the weft direction are likewise all of the same denier. In another embodiment, heavier yarns are laid in regular intervals in both fabric directions.
    Type: Grant
    Filed: November 9, 1990
    Date of Patent: September 15, 1992
    Assignee: ABC Industries, Inc.
    Inventors: James R. Ellison, Robert W. Hoy
  • Patent number: 5143675
    Abstract: A synthetic resin molded article having a good antistatic property, which including a synthetic resin substrate and a film of an antistatic polymer formed on the surface of the substrate. The antistatic polymer is prepared by polymerizing an anionic monomer represented by the formula (I) or a mixture of the anionic monomer and a monomer copolymerizable therewith: ##STR1## R.sub.2, R.sub.3, R.sub.4 and R.sub.5 independently represent an alkyl, aryl or aralkyl group which may have a substituent, n is 0, 1 or 2, B is an alkylene, arylene or aralkylene group which may have an ester bond, and R.sub.6 is H or an alkyl group.
    Type: Grant
    Filed: September 6, 1990
    Date of Patent: September 1, 1992
    Assignee: Mistubishi Rayon Co., Ltd.
    Inventors: Naoki Yamamoto, Hiroki Hatakeyama
  • Patent number: 5118578
    Abstract: A method of forming an electrically conductive floor or wall coating that includes: applying to the surface of the floor or wall a first coating consisting essentially of a conductive pigment A, an inorganic binder in which the pigment is dispersed, and a hardener; allowing the first coating to become tack free, and applying to the first coating a second coating consisting of a conductive pigment B, a non-conductive pigment C, a binder in which pigements B and C are dispersed, and a flow control substance; and allowing the second coating to become dry to the touch.
    Type: Grant
    Filed: December 11, 1989
    Date of Patent: June 2, 1992
    Assignee: Coatings/Composites
    Inventors: Albert J. Berger, Cir C. Engay
  • Patent number: 5110669
    Abstract: A polymeric laminate and packaging material produced therefrom have (a) at least one conductive layer and (b) at least one static dissipative layer comprising a polymer composition having dispersed therein a non-volatile ionizable metal salt, said static dissipative layer being in electrical contact with the conductive layer. Such a laminate is found to provide shielding and static dissipation suitable for packaging of electrostatically sensitive items such as electronic components.
    Type: Grant
    Filed: September 28, 1989
    Date of Patent: May 5, 1992
    Assignee: The Dow Chemical Company
    Inventors: Thomas M. Knobel, Christian Dubouchet, Lance L. Black
  • Patent number: 5110639
    Abstract: A packaging material for photosensitive materials which is a multilayer film comprising two coextruded multilayer inflation films wherein the amount of antistatic agent (wt. %) of an outer layer is more than 1.2 times greater than the antistatic agent content (wt. %) of a inner layer. In the packaging material of the invention, the necessary amount of antistatic agent to prevent static trouble bleeds out of the surface of the outer layer in a short time, and thereafter, the bleeding amount is almost constant. Therefore, the packaging material is excellent in heat sealability, appearance and touch and does not cause development problems.
    Type: Grant
    Filed: July 10, 1990
    Date of Patent: May 5, 1992
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Mutsuo Akao
  • Patent number: 5102712
    Abstract: A method of applying a conformal coating to a printed circuit board and components attached thereto while leaving selected components attached thereto uncoated, comprises the steps of providing a printed circuit board having a multiplicity of components attached thereto, including selected components that are not to be coated; enclosing the selected components within conductive protective enclosures sized to enclose the selected components therein and thereby protect those components from the intrusion of conformal coating material, the enclosures having sufficient electrical conductivity to discharge electrostatic charges therefrom when one of the enclosures is contacted by an electrically conductive medium, thereby protecting the components attached to the printed circuit board from damage due to the discharge of electrostatic charges from the enclosures; applying a conformal coating to the printed circuit board, thereby conformal coating the enclosures and the components which are not protected by the encl
    Type: Grant
    Filed: February 13, 1990
    Date of Patent: April 7, 1992
    Assignee: Conductive Containers, Inc.
    Inventors: Roger J. Peirce, Raymond P. Becker
  • Patent number: 5096761
    Abstract: A masking film suitable for masking during electrostatic spray painting is disclosed. In one embodiment the masking film is made from an acid copolymer/quaternary amine mixture which is permanently antistatic. The acid copolymer is a copolymer of (i) a major amount by mol % of an alpha-olefin of the formula RCH.dbd.CH.sub.2 wherein R is H or C.sub.1 to C.sub.8 alkyl, and (ii) a minor amount by mol % of an alpha,beta-ethylenically unsaturated carboxylic acid. The quaternary amine is of the formula [(R.sup.1)(R.sup.2)(R.sup.3)(R.sup.4)N].sup.+ [X].sup.- wherein R.sup.1 is selected from H, aryl, or C.sub.1 to C.sub.50 alkyl optionally having one or more non-contiguous C.dbd.O or NHC.dbd.O or --S-- or --O-- in the carbon chain, or the same as R.sup.2 ; each of R.sup.2, R.sup.3, and R.sup.4 is the same or different and selected from H, C.sub.1 to C.sub.18 alkyl optionally substituted with one or more OH or from --(R.sup.5 --O).sub.a --H where a is an integer from 1 to 10 and R.sup.
    Type: Grant
    Filed: July 25, 1990
    Date of Patent: March 17, 1992
    Assignee: W. R. Grace & Co.-Conn.
    Inventors: William P. Roberts, Charles R. Morgan, Marvin R. Havens
  • Patent number: 5094909
    Abstract: Disclosed is a plastic film comprising a support and an antistatic layer, provided thereon, comprising a reaction product of a water-soluble electroconductive polymer, hydrophobic polymer particles and a hardening agent, characterized in that the hydrophobic polymer particles are stabilized by a surfactant having at least five ethylene oxide chains.
    Type: Grant
    Filed: June 6, 1990
    Date of Patent: March 10, 1992
    Assignee: Konica Corporation
    Inventors: Noriki Tachibana, Yoichi Saito, Toshiaki Yamazaki
  • Patent number: 5093205
    Abstract: A synthetic resin shaped article having good antistatic properties, composed of a substrate, at least part of which is covered with a synthetic resin surface layer integrated with the substrate. This shaped article is prepared by polymerizing 100 wt. parts of a mixture comprising (A) more than 20 wt. % of a monomer of the formula (I): ##STR1## wherein R.sub.1 is H or CH.sub.3, R.sub.2, R.sub.3 and R.sub.4 are H or C.sub.1-9 alkyl, m is from 1 to 10, and X.sup.- is an anion, (B) less than 79.99 wt. % of a monomer having one unsaturated double bond and (C) 0.01-10 wt. % of a monomer having at least two unsaturated double bonds; subsequently adding (D) up to 190 wt. parts of a monomer having one unsaturated double bond and (E) up to 10 wt.
    Type: Grant
    Filed: December 8, 1989
    Date of Patent: March 3, 1992
    Assignee: Mitsubishi Rayon Company Ltd.
    Inventors: Naoki Yamamoto, Hiroki Hatakeyama
  • Patent number: 5089325
    Abstract: In a method for plating one side of a woven fabric sheet, a backing layer is applied to one side of the sheet. The sheet and backing layer are wetted in an electrolytic solution containing metallic ions to be deposited on one side of the fabric sheet only. Air bubbles trapped in interstices of the fabric weave and beneath the backing sheet prevent the electrolytic solution from soaking through the fabric sheet. Electrodes bond the metal ions on the wetted fabric thereto. The backing sheet is then removed. The resulting fabric is coated only on one side and the interstices are not filled in by plating material. The fabric is useful as the outermost layer in a composite laminate for an aircraft skin.
    Type: Grant
    Filed: February 4, 1991
    Date of Patent: February 18, 1992
    Assignee: The Boeing Company
    Inventor: James F. Covey
  • Patent number: 5089327
    Abstract: An anti-static paper sheet for use in high pressure laminates comprised of Pontiac hardwood, high alpha hardwood, and cotton linters, the sheet being initially treated with a wet strength resin and saturated with a water soluble polycationic quaternary ammonium polymer which is free from metallic salts in an amount of at least about one pound of polymer to 1000 square feet of sheet material having a basis weight of about 75 pounds per ream, the anti-static polymer being applied at a temperature of from about 135.degree. F. to about 155.degree. F.
    Type: Grant
    Filed: April 4, 1989
    Date of Patent: February 18, 1992
    Assignee: The Sorg Paper Company
    Inventor: Frank L. Cessna
  • Patent number: 5084339
    Abstract: Disclosed is a plastic film comprising a support and an antistatic layer, provided thereon, comprising a reaction product of a water-soluble electroconductive polymer, hydrophobic polymer particles and a curing agent, characterized in that the hydrophobic polymer has a polyalkylene oxide chain.
    Type: Grant
    Filed: May 10, 1990
    Date of Patent: January 28, 1992
    Assignee: Konica Corporation
    Inventors: Noriki Tachibana, Yoichi Saito, Toshiaki Yamazaki
  • Patent number: 5082730
    Abstract: Disclosed herein are a stretched antistatic laminate film comprising at least one coating layer containing a polymer having pyrrolidium rings in the main molecular chain, and a polyester film layer, a magnetic recording medium using the same, and a recording material for heat sensitive transfer printing using the same.
    Type: Grant
    Filed: December 2, 1988
    Date of Patent: January 21, 1992
    Assignee: Diafoil Company, Limited
    Inventors: Naohiro Takeda, Yuzo Otani, Nariaki Okajima, Masahiro Kita
  • Patent number: 5073425
    Abstract: Decoration polyvinyl chloride surface covering structures are described which have antistatic or static dissipative capabilities. Several features are described herein which can be taken advantage of to lower the normal conductivity of the polyvinyl chloride sheet and yet still maintain an attractive or decorative appearance.
    Type: Grant
    Filed: October 7, 1988
    Date of Patent: December 17, 1991
    Assignee: Armstrong World Industries, Inc.
    Inventors: Martin Dees, Jr., Richard E. Felter, Deborah L. Musser
  • Patent number: 5071699
    Abstract: The present invention provides for an anti-static flexible fabric material formed from woven, axially oriented crystalline polypropylene yarn, said fabric further characterized as having a coating of a flexible, thermoplastic polymer on one or both sides of the fabric. Anti-static properties are imparted to the fabric by formulating the thermoplastic coating to contain from about 0.2 to about 8% by weight of a polyol ester (preferably glycerol) of a C.sub.10 to C.sub.28 fatty acid. The polypropylene yarn may optionally itself also contain a lesser amount of the polyol ester of a C.sub.10 to C.sub.28 fatty acid to provide a fabric having even more enhanced anti-static properties. In another embodiment, the polypropylene yarn may additionally have interwoven therewith or in contact therewith at intervals conductive yarns to provide even more enhanced anti-static properties.
    Type: Grant
    Filed: February 7, 1991
    Date of Patent: December 10, 1991
    Assignee: Exxon Chemical Patents Inc.
    Inventors: Robert J. Pappas, O. Lee Reedy
  • Patent number: H1104
    Abstract: A method for dissipating static electrical energy from air cushion vehicles hen operating more particularly in cold, low humidity environments, which method involves fabricating the skirt assembly from a flexible sheet material of at least semiconductive character which will provide a suitable dissipating grounding pathway to discharge potential static electrical energy generated during the aforesaid operation thereof. The method includes utilizing a coated flexible fabric material having at least one of its opposite surfaces coated with an elastomeric abrasion-resistant material, and embedding a plurality of electrically conductive flexible strands at least partially within said flexible fabric material, or alternatively embedding electrically conductive particles or fibers in a generally uniformly manner throughout a forming of its elastomeric composition.
    Type: Grant
    Filed: March 2, 1990
    Date of Patent: September 1, 1992
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventor: Richard A. Cavanagh