Abstract: A hydrogen-air fuel cell having a mobile element capable of, in closed position, covering the cell cathode in substantially tight fashion.

Abstract: The invention provides a solid oxide fuel cell generation system and a start up method thereof which heat up a reformer and a cell main body without any water and nitrogen gas, and start up for a short time until a power generation and without deteriorating a reliability of the cell. In a solid oxide fuel cell generation system having a power generation cell including an anode, a cathode and a solid electrolyte membrane, a mixing portion for obtaining a mixed gas by mixing a used fuel gas discharged from the anode with a raw fuel, a reducing combustion gas generating apparatus, and a reforming portion, the reducing combustion gas generating apparatus has a starting burner generating a reducing combustion gas, and the mixing portion, the reducing combustion gas generating apparatus, the reforming portion and the anode are coupled alphabetically from an upstream side.

Abstract: A reformer including a vaporization part provided with a supply port through which raw fuel is supplied, the supply port being provided at a central section of a tubular container; and reforming parts provided at both sides of the container, each reforming part containing reforming catalyst that reforms the raw fuel that flows into the reforming part from the vaporization part into fuel gas and provided with a fuel-gas supply port through which the fuel gas is discharged.

Abstract: Disclosed is a method for recovering performance of a fuel cell, which can recover the catalytic properties of a cathode in a reusable state by supplying hydrogen to the cathode of a degraded fuel cell stack for a predetermined period of time and storing the fuel cell stack for a predetermined period of time such that an oxide formed on the surface of platinum (Pt) is removed and, at the same time, the platinum is re-precipitated.

Abstract: A process for forming alkaline earth metal cerate nanoparticles comprises combining a stable cerium oxide aqueous colloidal dispersion with soluble alkaline earth metal salts while maintaining colloidal stability. The resulting alkaline earth metal salts may be calcined to form alkaline earth metal cerate particles having a perovskite structure.

Abstract: There is a manufacturing apparatus for an electrolyte membrane with gaskets by laminating an electrolyte membrane having a predetermined region on which a catalyst layer is formed and a gasket formed with an opening shaped to match the shape of the region of the catalyst layer. The manufacturing apparatus for an electrolyte membrane with gaskets includes a laminating roller that abuts on the gasket to laminate the electrolyte membrane and the gasket. The laminating roller has a surface on which a protrusion is formed. The protrusion is shaped to fit in the opening of the gasket. The manufacturing apparatus for an electrolyte membrane with gaskets includes a roller controller that operates the laminating roller such that the electrolyte membrane and the gasket are laminated while the protrusion is fitted in the opening of the gasket.

Abstract: In a method for making anion electrolyte membrane a fluorinated poly(aryl ether) ionomer is dissolved in a solvent to form a ionomer solution. A crosslink component is added to the ionomer solution, to achieve a transparent solution. An inorganic component precursor and water are introduced to the transparent solution, to form a sol-gel mixture. A crosslink catalyst is mixed with the sol-gel mixture to form a membrane casting solution. The membrane casting solution is coated on a substrate to form a membrane, and heated. The membrane is removed from the substrate.

Abstract: An electrochemical cell includes a first electrode configured to operate as an anode to oxidize a fuel when connected to a load. The first electrode includes a permeable electrode body configured to allow flow of an ionically conductive medium therethrough. An electrode holder includes a cavity for holding the first electrode. A diffuser is positioned in the cavity between the first electrode and the electrode holder with a gap formed between the diffuser and the electrode holder. The diffuser includes openings configured to allow flow of the ionically conductive medium therethrough and to distribute the flow through the first electrode. A second electrode is positioned in the cavity on a side of the first electrode that is opposite the diffuser, and is configured to operate as a cathode when connected to the load and in contact with the ionically conductive medium.

Abstract: In an electrolyte sheet for a solid oxide fuel cell according to the present invention, the number of flaws on at least one of surfaces of the sheet detected by a fluorescent penetrant inspection is 30 points or less in each of sections obtained by dividing the sheet into the sections each measuring 30 mm or less on a side. A unit cell for a solid oxide fuel cell according to the present invention comprises a fuel electrode, an air electrode, and the electrolyte sheet for a solid oxide fuel cell according to the present invention, which is disposed between the fuel electrode and the air electrode. A solid oxide fuel cell of the present invention includes the unit cell for a solid oxide fuel cell according to the present invention.

Abstract: A proton conductor includes a metal ion, an oxoanion, and a molecule capable of undergoing protonation or deprotonation, in which the oxoanion and/or the molecule capable of undergoing protonation or deprotonation coordinates to the metal ion to form a coordination polymer. The oxoanion is preferably a monomer. The oxoanion is exemplified by at least one selected from the group consisting of phosphate ion, hydrogenphosphate ion, and dihydrogenphosphate ion. The molecule capable of undergoing protonation or deprotonation is exemplified by at least one selected from the group consisting of imidazole, triazole, benzimidazole, benzotriazole, and derivatives of them.

Abstract: A method to control the heat balance of fuel cell stacks in a fuel cell system, the fuel cell system including at least one fuel cell unit including fuel cell stacks, whose fuel cells include an anode side and a cathode side, as well as an electrolyte interposed therebetween, and a recuperator unit for heat exchange for preheating a supply flow of the cathode side. In the method, a desired portion is separated from the fuel exhaust flow coming from the anode side and adapted to be mixed with the cathode side exit flow before said recuperator unit. Also provided is a fuel cell system implementing the method.

Abstract: A system and method for controlling the speed of a compressor in the event that an airflow meter that measures the airflow from the compressor to the cathode input of the stack fails. When a failure of the airflow meter is detected, an algorithm first deactivates the primary feedback control algorithms used to control cathode pressure and flow, and sets the cathode exhaust valve to a fully open position. The speed of the compressor is controlled by an open loop set-point and the airflow from the compressor is estimated by a model using compressor discharge pressure and the compressor speed. The cathode by-pass valve position is determined by calculating the difference between the requested cathode airflow and the modeled compressor output flow. The position of the by-pass valve is then adjusted using the valve characteristics and the compressor discharge pressure. The estimated airflow to the stack is used to control the maximum stack current.

Abstract: A fuel cell system for an aircraft is stated, which fuel cell system comprises a fuel cell unit and a suction module. The suction module is used to draw oxygen through the fuel cell unit. No vacuum generators are used during cruising flight.

Abstract: A method and system are disclosed for reducing the consumption of safety gas in a fuel cell system having at least one fuel cell unit whose fuel cells include an anode side and a cathode side, as well as an electrolyte interposed therebetween. A supply is provided for supplying the anode with a safety gas, and an exhaust is provided for exhausting the fuel cell unit of a spent safety gas coming from the anode side. The method can adapt a specific percentage of the spent safety gas flow coming from the anode side of the fuel cells to be re-supplied into the anode side of the fuel cells.

Abstract: An apparatus for removing sulfur from a hydrocarbon feed includes a cell having two compartments and a membrane separating the compartments, wherein one compartment is communicated with a hydrogen source and the other compartment is communicated with the hydrocarbon feed to be treated, wherein the membrane comprises a palladium membrane which is modified to have an additional amount of a mix of palladium and other metals (Ni, Ag, Co and Au) between about 4.62*10?3 and 1.62*10?2 g/cm2; and a power source connected across the hydrogen source compartment to generate a current across same, whereby atomic hydrogen is formed from the hydrogen source at a surface of the membrane and diffuses across the membrane to react with the hydrocarbon feed. A process using this apparatus is also provided.

Abstract: An electrochemical fuel cell having an anode, an ion transfer membrane and a cathode has liquid water delivered to the fluid flow channels within the cathode so as to maintain a relative humidity of 100% throughout the fluid flow channels. A calibration method and apparatus is described for determining an optimum quantity or range of quantities of liquid water to be delivered to the cathode fluid flow channels under varying operating conditions. An operating method and apparatus is described that ensures an optimum quantity of liquid water is delivered to the cathode fluid flow channels under varying operating conditions.

Abstract: A system and method for quickly heating a fuel cell stack at fuel cell system start-up. The fuel cell system includes a three-way valve positioned in the anode exhaust that selectively directs the anode exhaust gases to the cathode input of the fuel cell stack so that hydrogen in the anode exhaust gas can be used to heat the fuel cell stack. During normal operation when the fuel cell stack is at the desired temperature, the three-way valve in the anode exhaust can be used to bleed nitrogen to the cathode exhaust.

Abstract: There is provided a method for the activation of a fuel cell. An exemplary method comprises operating the fuel cell entirely or partially at least briefly in an electrolysis regimen during galvanic operation.

Abstract: A method for refilling a hydrogen reservoir comprising a first hydrogen-storing material comprises establishing a fluid connection between the hydrogen reservoir and a cartridge containing a second hydrogen-storing material. The second hydrogen-storing material releases hydrogen at a pressure sufficient to charge the first hydrogen-storing material. Some embodiments involve heating the second hydrogen-storing material and/or allowing heat to flow between the first and second hydrogen-storing materials.

Abstract: A method for filling a fuel cell system with a fuel during start-up is disclosed, the method including the steps of providing a fuel cell stack having a plurality of fuels cells, each fuel cell having an active area, the fuel cell stack including an anode supply manifold and an anode exhaust manifold, the anode supply manifold and in fluid communication with a source of fuel; providing an anode sub-system in fluid communication with an anode side of the fuel cell stack; and supplying the fuel to the fuel cell stack substantially uniformly and substantially simultaneously to compress any fluids in the fuel cell stack into a volume between an end of each active area adjacent to the anode exhaust manifold and an outlet of the anode sub-system.

Abstract: A fuel cell system arrangement is disclosed for controlling an Oxygen-to-Carbon (O/C) relationship by providing water to an anode side fuel recirculation, pumping the provided water to facilitate a water flow, and evaporating water from the facilitated water flow for generating pressurized steam having at least the motive pressure for a steam jet-ejector. The at least one steam jet-ejector can inject at least part of the steam to the fuel cell system, and entrain part of an essentially low pressure anode exhaust gas stream in the anode side gas recirculation and compress the gas mixture to an intermediate pressure of the fuel feed-in stream for controlling the Oxygen-to-Carbon (O/C) relationship in the fuel side of the fuel cell system.

Abstract: A power generation system and a fuel processor for use within a power generation system. A fuel processor is connected to both a fuel supply line and a water supply line. The fuel processor reacts the hydrocarbon fuel with the water to produce hydrogen gas and raffinate gases. The hydrogen gas is directed into a hydrogen gas line. The raffinate gases are directed into a raffinate gas line. A fuel cell is powered using the hydrogen gas. A heat exchanger is provided that exchanges heat between the fuel supply line, the water supply line, the hydrogen gas line and the raffinate gas line. This enables heat to be recycled. In addition the raffinate gases also travel into a water recovery subsystem. The water recovery subsystem condenses water out of the raffinate gases The recovered water is returned to the system.

Abstract: The present invention provides a hydrogen discharge system for a fuel cell system, which can ensure safety of a fuel cell vehicle by optimizing the dilution of hydrogen discharged from a fuel cell during discharge and ensure silence of the vehicle by reducing noise generated during discharge. For this purpose, the present invention provides a hydrogen discharge system for a fuel cell system including a purge valve for purging hydrogen discharged from a fuel electrode of a fuel cell stack, the hydrogen discharge system including: an ejector mounted to a hydrogen purge line extending from the purge valve to introduce air from the outside; and a post-treatment system connected to an exhaust line of the ejector to remove hydrogen discharged therethrough.

Abstract: A fuel cell system including a fuel cell stack having a plurality of fuel cells, each of the fuel cells including an electrolyte membrane disposed between an anode and a cathode, an anode supply manifold in fluid communication with the anodes of the fuel cells, the anode supply manifold providing fluid communication between a source of hydrogen and the anodes, an anode exhaust manifold in fluid communication with the anodes of the fuel cells, and a fan in fluid communication with the anodes of the fuel cells, wherein the fan controls a flow of fluid through the anodes of the fuel cells after the fuel cell system is shutdown.

Abstract: The presently disclosed subject matter relates to Managed Ecosystem Fermentation (MEF) which is a continuous microbial process utilizing a managed ecosystem approach employing dozens to thousands of species of microorganisms, occurring in a controlled artificial environment and consuming organic materials without benefit of sterilization. The process of utilizing this fermentation for the consumption of organic materials on a continuous basis is within the scope of this disclosed subject matter. The process of separating chemicals as industrial chemicals from this fermentation on a continuous basis is within the scope of this disclosed subject matter. The process of separating biomass useful as high protein animal feed or fertilizer from this fermentation on a continuous (or semi-continuous) basis is within the scope of this disclosed subject matter.

Abstract: An anion conducting electrolyte membrane with high performance where the electric conductivity and the water uptake are balanced, and a method of manufacturing the same are disclosed. The anion conducting electrolyte membrane comprises: a polymeric material which consists of fluorine polymer, olefinic polymer, or aromatic polymer; weak base quaternary salt obtained by the reaction of grafts introduced by graft polymerizing vinyl monomer which contains halogenated alkyl groups using radiation and strong organic bases.

Abstract: The fuel cell system of the present invention has: a fuel cell including an electromotive unit comprising a fuel electrode, an oxidant electrode, and an electrolyte sandwiched by these electrodes; a fuel supply unit for supplying a fuel to the fuel electrode; and an oxidant supply unit for supplying an oxidant to the oxidant electrode. A product reduction mechanism unit is provided to reduce a fuel oxidation product produced at the fuel electrode when power is generated by the fuel cell. Based on this, decline in energy density due to the fuel and the fuel oxidation product and by-product can be prevented, without having a mechanism to discharge the fuel and the fuel oxidation product and by-product to the outside of the fuel cell.

Abstract: A fuel cell system (1), especially in a motor vehicle, includes at least one fuel cell (2) for generating electricity, at least one reformer (3) for generating a reformat gas, a fuel supply means (13) for feeding fuel to the reformer (3), a recycling means (83), which has a recycling line (31) connected to the reformer (3) for feeding anode waste gas of the fuel cell (2) to the reformer (3), and an air supply means (17), which has an air line (18) connected to the reformer (3) separately from the recycling line (31) for feeding air to the reformer (3). To increase performance, the fuel supply means (13) may be designed such that fuel can be introduced with it into the recycling line (31).

Abstract: An elongated fuel processor assembly is coupled to a fuel cell stack for producing a reformate for consumption by the fuel cell stack. The elongated fuel processor assembly includes an annular core having a thermal conduction mass for conducting heat, an annular reformer surrounding and supported by the annular core, and a vaporizer surrounding and supported by the annular core.

Abstract: Hydrogen generating apparatus that is capable of controlling the amount of hydrogen generation. The hydrogen generating apparatus has an electrolyzer, a first electrode, a second electrode, a switch, which is located between the first electrode and the second electrode, a flow rate meter, which measures an amount of hydrogen generation in the second electrode, and a switch controller, which receives a set value, compares the amount of hydrogen generation measured by the flow rate meter with the set value, and controls an on/off status of the switch. The amount of hydrogen generation can be controlled by use of on/off time and/or on/of frequency of the switch.

Abstract: In a fuel cell stack, fuel, such as often hydrogen, electrochemically reacts with an oxidant, such as ambient air, and electric energy is generated from chemical energy. During the reaction, a proton exchange membrane (PEM) separates the fuel from the oxidant during the electrochemical process. A supply system for the fuel cell stack comprises an adjustable humidifying device for humidifying a supply gas which is supplied to the fuel cell stack, as a function of a control signal; and a dehumidifying device, which is configured to dehumidify an exhaust gas that is formed from the supply gas conducted through the fuel cell stack, and to discharge the same as a dehumidified exhaust gas. A controller, which generates the control signal, is configured from a programming and/or switching point of view to generate the control signal based on the gas temperature of the dehumidified exhaust gas.

Abstract: A fuel cell system is disclosed that employs a humidifier and an oxygen sensor for measuring the oxygen concentration in the cathode exhaust gas from the fuel cell stack to determine a system diagnostic, such as a fluid leak from or across the humidifier.

Abstract: A fuel cell module that can accommodate a single fuel cell stack efficiently and that can enhance power generation efficiency, and a fuel cell device comprising the fuel cell module.

Abstract: Combustion heaters having internal combustion chambers are located adjacent the end cells of a stack of fuel cells to directly, conductively heat the end cells during cold start-up of the stack. Similar heater(s) may also be located within the stack when cold starting under extremely cold conditions. A method of combustion thawing a fuel cell stack is described.

Abstract: There are included a gas-liquid separator (14) that performs gas-liquid separation on fuel exhaust gas exhausted from a fuel cell (11), a combustion section (13) that combusts hydrogen in the separated fuel exhaust gas, a heat exchanger (15) that performs heat exchange on combustion exhaust gas generated by the combustion, to condense moisture in the combustion exhaust gas and obtain combustion exhaust gas condensed water, and a degasifier (16) that removes carbon dioxide gas from the combustion exhaust gas condensed water and the fuel exhaust gas condensed water separated in the gas-liquid separator (14), and the degassed condensed water is stored in condensed water tank (18).

Abstract: A power supply device is provided. The power supply device includes a fuel cell, a hydrogen generator, a check valve and an exhaust valve. The fuel cell has a hydrogen inlet and a hydrogen outlet. The hydrogen generator is connected to the hydrogen inlet and used for generating hydrogen. The check valve is disposed in the hydrogen inlet and used for preventing the hydrogen within the fuel cell from flowing to the hydrogen generator, and preventing exterior air from entering the fuel cell. The exhaust valve is disposed in the hydrogen outlet for exhausting the hydrogen within the fuel cell.

Abstract: A fuel container according to the present invention includes a container body (15), a fuel (10) provided in the container body (15), a draining port (9) provided to the container body (15) for supplying the fuel (10) to the outside of the container body (15), a fluid introduction unit (19) which introduces into the container body (15) a fluid corresponding to flow-out of the fuel (10) from the draining port (9), and a swelling member (17) which connects to the fluid introduction unit (19) and swells in the container body (15) by absorbing the fluid.

Abstract: Disclosed is a composite electrolyte membrane for a fuel cell. The composite electrolyte membrane includes a polybenzimidazole-based polymer and a metal-grafted porous structure. The composite electrolyte membrane is doped with phosphoric acid. The metal-containing porous structure is present in an amount of 0.1 to 30% by weight, based on the weight of the polymer. The presence of the metal-containing porous structure allows the fuel cell electrolyte membrane to have excellent thermal properties and high proton conductivity.

Abstract: A fuel cell system includes: a power generation stack (1) composed by stacking a plurality of fuel cells (10); and a hydrocarbon-oxidizing device (2) disposed on an upstream side of the power generation stack (1) in a fuel supply passage (8). The hydrocarbon-oxidizing device (2) directly and electrochemically oxidizes hydrocarbons with a carbon number of 2 or more, which are contained in fuel gas, or decomposes the hydrocarbons and electrochemically oxidizes carbon obtained by decomposing the hydrocarbons.

Abstract: An object is to suppress the degradation of durability due to a heat concentration while performing a rapid warm-up operation as necessary, when starting a fuel cell system at temperatures below freezing point.

Abstract: A system and method for detecting small hydrogen leaks in an anode of a fuel cell system. The method includes determining that a shut-down sequence has begun, and if so, deplete the cathode side of a fuel cell stack of oxygen. The method then increases the pressure of the anode side of the fuel cell stack to a predetermined set-point, and monitors the pressure decay of the anode side of the stack. The method compares the rate of pressure decay to an expected pressure decay rate, and if the measured pressure decay rate exceeds the expected pressure decay rate by a certain threshold, determines that a potential leak exists.

Abstract: The plant (10) includes a molten metal anode (44) passing through a fuel cell (12) anode inlet (46) having a first interrupted flow generator (104), then into an anode flow field (42) of the fuel cell (12), and leaving the anode flow field (42) through an anode outlet (48) having a second interrupted flow generator (113). The molten anode (44) then flows into a reduction reactor (50) where the oxidized anode (44) is reduced by a reducing fuel (61). The molten anode (44) is then cycled back into the first interrupted flow generator (104) and anode flow field (42). Interrupting flow of the molten anode (44) prevents electrical continuity between the anode inlet (46) and the anode outlet (48) through the molten anode (44) within the anode flow field (42). This facilitates stacking the planar fuel cells in series within a fuel cell stack to build voltage.

Abstract: During a process of shutting down a fuel cell power plant (11) the exits (28) of the anodes (14) are vented (76-77) under liquid (57). The liquid may be that of a coolant accumulator (57) of a fuel cell stack (12) cooled by conduction and convection of sensible heat into liquid coolant (FIG. 1) or evaporatively cooled (FIG. 4). The vent (77) may be under liquid all of the time (FIGS. 1, 3 and 4) or only after the stack has been drained of coolant (FIG. 2). The vent (77) may be the only vent for the anode exits (FIG. 3), or there may also be a purge vent valve (31) (FIGS. 1 and 4).

Abstract: Devices and methods are provided for generating electrical power using a capacitor. The capacitor has a catalytic working electrode, a dielectric, and a counter electrode. Power is generated by flowing a fuel (e.g., hydrogen gas) over the working electrode, charging the capacitor (e.g. by applying a voltage), flowing an oxidant (e.g., oxygen gas) over the working electrode, and connecting the electrodes to a resistive load, which allows current to flow through the load, between the electrodes. The inverse device (i.e., oxidant first, then fuel) functions similarly.

Abstract: A fuel cell system a includes a cooling water temperature raising unit that raises the temperature of a fuel cell stack by passing discharge gas of a process burner or hydrogen gas of a fuel processing unit and cooling water that is heated by the discharge gas of the process burner through flow paths formed on opposing surfaces of cooling separators formed of a metal and installed between a plurality of cells in the stack. Thus in the fuel cell system, when the temperature of the stack needs to be rapidly raised, for example, during a start up operation of the fuel cell system, the temperature of the stack can be rapidly raised using discharge gas at a high temperature or combustion heat of hydrogen gas, and heated cooling water, and thereby, significantly reducing the time required for the fuel cell system to be in regular operation.

Abstract: A fuel cell stack comprising a fuel inlet and an oxidant inlet for allowing the supply of a fuel and an oxidant to the fuel cell stack, respectively, and a fuel outlet and an oxidant outlet for allowing the removal of an anode exhaust and a cathode exhaust from the fuel cell stack, respectively, wherein the fuel outlet is fluidly connected to a high frequency purge valve.

Abstract: To provide a process for forming a polymer electrolyte membrane having good durability and few wrinkles, a polymer electrolyte membrane capable of forming a catalyst layer, or a catalyst layer; a process for producing a fluorinated ion exchange resin fluid, or a paste for forming a catalyst layer, which can be used for such a forming process; and a process for producing a membrane/electrode assembly for a polymer electrolyte fuel cell having good durability and power generation properties. A fluorinated ion exchange resin fluid obtained by subjecting a powder or pellets of a fluorinated ion exchange resin having cation exchange groups to hydrogen peroxide treatment, followed by mixing with a solvent, is used.

Abstract: The present invention discloses an integrated SOFC system powered by natural gas. Specifically, a SOFC-O cell is combined with a SOFC-H cell so as to take advantage of the high operating temperature and steam reforming capabilities of the SOFC-O cell as well as the higher fuel conversion efficiency of the SOFC-H cell.

Abstract: A fuel cell includes a reforming unit, a carbon monoxide decreasing unit, a fuel cell, a burner unit and a raw gas supply device. At the star-up operation of the fuel cell system, an amount of combustion air delivered to the burner unit by an air blower is adjusted according to a total amount of a raw gas to be supplied to the burner unit and an amount of a desorbed raw gas desorbed out of raw gas components adsorbed to at least one of catalysts in a fuel processor.

Abstract: When stopping an operation of a fuel cell power plant, a controller (30) first stops fuel gas supply to an anode (2), then supplies a dry oxidant gas to a cathode (3) such that the output voltage of the fuel cell stack (1) decreases. The controller (30) then connects a secondary battery (31) to the fuel cell stack (1) so as to consume an output power generated by a reaction of the residual fuel gas in the anode (2). After this processing, the controller (30) replaces the residual fuel gas in the anode (2) with dry oxidant gas, then maintains the fuel cell stack (1) in a closed state, thereby preventing local cell formation in the anode due to mixing of the residual fuel gas with oxidant gas, and hence preventing corrosion of a catalyst layer of the cathode (3) due to local cell corrosion.