Abstract: Fuel cell membrane electrode assemblies and fuel cell polymer electrolyte membranes are provided comprising manganese oxides which demonstrate increased durability. Methods of making same are provided.

Abstract: The present invention relates to a polymer blend electrolyte membrane comprising an inorganic polymer having polydimethylsiloxane as a main chain, which has a pore structure at both ends formed by condensation reaction between 3-aminopropyltriethoxysilane and tetraethylorthosilicate, wherein phosphoric acid is chemically linked to an amino group of the pore structure; and a proton-conducting polymer having a cation exchange group at the side chain thereof, as well as a manufacturing method thereof. Generally, proton-conducting electrolyte membranes have significantly reduced ion conductivity at high temperatures. However, proton-conducting electrolyte membranes have advantages in terms of efficiency and cost, and thus it is needed to develop an electrolyte membrane, which has excellent ion conductivity even at high temperature. Accordingly, the present invention aims to provide a polymer blend electrolyte membrane for use at high temperature and a manufacturing method thereof.

Abstract: Fuel cell membrane electrode assemblies and fuel cell polymer electrolyte membranes are provided comprising manganese oxides which demonstrate increased durability. Methods of making same are provided.

Abstract: A structure including a support defining an opening, and a tensilely stressed thin-film membrane disposed to occlude the opening, the membrane contacting at least a portion of the support. The stressed membrane includes a material having a characteristic crack spacing greater than one-half of a minimum dimension of the membrane and less than ten times the minimum dimension. A structure including a support defining a opening having a minimum opening dimension, and a compressively stressed thin-film membrane disposed to occlude the opening, the membrane contacting at least a portion of the support. The stressed membrane includes a membrane material having a critical aspect ratio for buckling that is greater than a ratio of one-half of the minimum opening dimension to a thickness of the membrane, and the critical aspect ratio for buckling is less than a ratio of ten times the minimum opening dimension to the thickness of the membrane.

Abstract: The present invention relates to a solid oxide fuel cell having a gradient structure in which pore size becomes gradually smaller from a porous electrode to an electrolyte thin film in order to form a dense electrolyte thin film of less than about 2 microns and preferably less than 1 micron on the porous electrode.

Abstract: A chemical fullerene derivative is for a proton conducting membrane electrolyte, in which sulfonic acid group SO3M and/or phosphonic acid group PO(OM)2 is directly bonded, but an organic compound is substantially not bonded. A production method is for the chemical fullerene derivative, which uses dimethylacetamide plus water in the case of sulfonation reagent K2SO3 and dioxane in the case of phosphonation reagent LiPO(OEt)2.

Abstract: A process for preparing a composite membrane comprising the steps of: (i) applying to a porous support having an average surface energy of 1 to 30 mN/m a composition having a viscosity of 1 to 5,000 mPa·s; and (ii) increasing the viscosity of the composition to a value higher than 30,000 mPa·s within 30 seconds after the composition has been applied to the support; wherein the composition applied in step (i) has a surface tension that is at least 25 mN/m higher than the average surface energy of the porous support.

Abstract: A polymer electrolyte membrane, a method of manufacturing the same, and a fuel cell including the polymer electrolyte membrane are provided, wherein the polymer electrolyte forms an interpenetrating polymer network (IPN) of a polymer by simple blending of a hydrophobic polyimide having a reactive terminal group and a hydrophilic aromatic polymer having ion conductivity. The polymer electrolyte membrane has reduced swelling properties due to highly dense crosslinking of polyimide through the reactive terminal group, shows high ion conductivity at low humidity, and has methanol crossover suppressing ability. Accordingly, a fuel cell with improved electric and mechanical properties can be provided.

Abstract: Provided is a method for manufacturing an electrode for fuel cells which can manufacture an electrode having superior electric power generation characteristics by enlarging the contact area of a polymer electrolyte with catalyst particles to increase the area of the three-phase interface, resulting in improvement of availability of the catalyst particle surface.

Abstract: Solid anion exchange polymer electrolytes include chemical compounds comprising a polymer backbone with side chains that include guanidinium cations.

Abstract: An electrochemical apparatus having a plurality of ceramic electrochemical cells, a plurality of gas feed members and a plurality of gas discharge members. The electrochemical cell has a first electrode contacting with a first gas, a solid electrolyte layer and a second electrode contacting with a second gas. A gas flow channel for flowing the first gas therethrough, a first through hole and a second through hole are provided in the electrochemical cell. The gas feed member is inserted into the first through hole, the gas discharge member is inserted into the second through hole. The adjacent gas feed members are airtightly coupled to each other thereby forming a gas feed channel, and the adjacent gas discharge members are airtightly coupled to each other thereby forming a gas discharge channel.

Abstract: In a first aging step, a plus electrode electric potential is applied to an anode of a fuel cell, and a minus electrode electric potential is applied to a cathode of the fuel cell. In this state, hydrogen pump operation is performed at maximum current density in use by supplying humidified hydrogen to the anode without supplying any oxygen-containing gas to the cathode. Thus, the hydrogen passes through a solid polymer electrolyte membrane toward the cathode. After the first aging step, in a second aging step, power generation of the fuel cell is performed at the maximum current density.

Abstract: The present invention provides an electrode paste which comprises catalyst particles, a solvent and an varnish which comprises a solvent and an electrode electrolyte for a solid polymer fuel cell electrolyte, wherein the electrode electrolyte comprises a polymer with a structure having a main chain including a polyphenylene, a side chain including a sulfonic acid group and a repeating structural unit represented by formula (C) as a side chain including a nitrogen-containing heterocyclic group; wherein the structural variables are defined herein.

Abstract: A proton conductive membrane capable of sufficient proton conductivity even at low humidities and low temperatures is provided. The proton conductive membrane includes a copolymer including an ion conductive polymer segment (A) and an ion nonconductive polymer segment (B) , the membrane absorbing water when it is soaked in 90° C. water for 30 minutes of which the quantity of water showing freezing temperatures in the range of ?30 to 0° C. is 0.01 to 3.0 g based on 1 g of the copolymer. The copolymer has a structure in which main chain skeletons of the copolymer are covalently bound at aromatic rings thereof through binding groups.

Abstract: The polymer electrolyte membrane for a fuel cell includes a hydrophilically surface-treated polymer particle filler, and a proton conductive polymer. The polymer electrolyte membrane has improved properties in conductivity, swelling, tensile strength and modulus.

Abstract: Disclosed is a method for producing a membrane for direct liquid fuel cells, wherein a polymerizable composition is brought into contact with a porous membrane so that voids of the porous membrane are filled with the polymerizable composition, then the polymerizable composition is cured by polymerization, and after that a halogenoalkyl group in the resin membrane is converted into a quaternary ammonium group. In this method, the polymerizable composition contains (a) an aromatic polymerizable monomer having an aromatic ring wherein one polymerizable group, at least one halogenoalkyl group and a group which is inert to a reaction converting the at least one halogenoalkyl group into a quaternary ammonium group, are bonded together, (b) a crosslinkable polymerizable monomer and (c) a polymerization initiator.

Abstract: A crosslinked object of a polybenzoxazine-based compound formed of a polymerized resultant of a first monofunctional benzoxazine-based monomer or a second multifunctional benzoxazine-based monomer with a crosslinkable compound, an electrolyte membrane including the crosslinked object, a method of preparing the electrolyte membrane, and a fuel cell employing the electrolyte membrane including the crosslinked object. The crosslinked object has a strong acid trapping capability with respect to the benzoxazine-based compound and high mechanical properties due to the crosslinking. The crosslinked object is very stable chemically because of elimination of solubility in polyphosphoric acid. The electrolyte membrane including the crosslinked object has excellent phosphoric acid supplementing capacity at a high temperature and mechanical and chemical stability.

Abstract: There is provided a fuel cell capable of ensuring high safety, and capable of obtaining favorable characteristics such as power density. As a first fluid containing an electrolyte, an ion conductor in which an organic compound which is solid at a room temperature and which has at least one of a sulfonic acid group and a phosphoinic acid group is dissolved in a solvent flows through an electrolyte path arranged between a fuel electrode and an oxygen electrode. Thereby, it is possible to suppress resistance between the fuel electrode and the oxygen electrode low. Also, in the case where the solvent is evaporated due to an environmental change, since that organic compound remains as solid, a surrounding member is unlikely to be corroded.

Abstract: A proton-conducting structure that exhibits favorable proton conductivity in the temperature range of not lower than 100° C., and a method for manufacturing the same are provided. After a pyrophosphate salt containing Sn, Zr, Ti or Si is mixed with phosphoric acid, the mixture is maintained at a temperature of not less than 80° C. and not more than 150° C., and thereafter maintained at a temperature of not less than 200° C. and not more than 400° C. to manufacture a proton-conducting structure. The proton-conducting structure of the present invention has a core made of tin pyrophosphate, and a coating layer formed on the surface of the core, the coating layer containing Sn and O, and having a coordination number of O with respect to Sn of greater than 6.

Abstract: The present invention relates to a polymer electrolyte membrane that includes a porous polymer matrix and an ion conducting polymer coating membrane formed in the outer surface of single fibers in the porous polymer matrix. The polymer electrolyte membrane can provide excellent mechanical strength, is not deteriorated by heat even at a temperature higher than 100°C., can provide excellent ion conductivity even at non-humidified state. Thus it is suitable for use in a fuel cell that is operated at high temperatures.

Abstract: A planar high temperature fuel cell, a use and a method of manufacture are discloses. The planar high-temperature fuel cell with includes a layer structure. The layer structure includes a cathode layer, an anode layer and a solid electrolyte layer disposed between the cathode layer and the anode layer. Each of the layers are planar. A porous metal structure is used as the support for the layer structure and is also planar.

Abstract: To provide a membrane/electrode assembly for polymer electrolyte fuel cells capable of obtaining a high output voltage even in a high current density region, by providing electrodes having good gas diffusion properties, conductivity, water repellency and durability. A membrane/electrode assembly for polymer electrolyte fuel cells, comprising; an anode and a cathode each having a catalyst layer containing a catalyst and having a gas diffusion layer; and a polymer electrolyte membrane disposed between the catalyst layer of the anode and the catalyst layer of the cathode, characterized in that at least one of the above anode and cathode, has a carbon layer containing a fluorinated ion exchange resin and carbon nanofibers having a fiber diameter of from 1 to 1,000 nm and a fiber length of at most 1,000 ?m, disposed between the catalyst layer and the gas diffusion layer.

Abstract: The electrode for a fuel cell of the present invention includes a carbonaceous electrode substrate, a microporous layer formed on the surface of the electrode substrate with the microporous layer including a carbonized polymer, and nano-carbon formed on the surface of the microporous layer with a catalyst layer coated on the surface of the nano-carbon. Alternatively, an electrode for a fuel cell includes a carbonaceous electrode substrate in which carbon particles are dispersed, a nano-carbon on the electrode substrate with a catalyst layer on the surface of the nano-carbon.

Abstract: The present teachings encompass proton-conductive material comprising a new polymer compound. A proton-conductive electrolyte comprising the proton-conductive material, and a fuel cell comprising the proton-conductive electrolyte are disclosed. A proton-conductive material comprising poly(phosphophenylene oxide) that comprises polyphenylene oxide as the main chain, and at least one phosphonic acid group as a side chain of the main chain, a proton-conductive electrolyte comprising the proton-conductive material, and a fuel cell employing the proton-conductive electrolyte, are also disclosed.

Abstract: A membrane electrode assembly for a fuel cell of the present invention includes an electrolyte membrane (100); and a pair of electrode catalyst layers (110) provided on both surfaces of the electrolyte membrane. Furthermore, in the present invention, a plurality of hydrophilic groups exist along a substantially continuous concentration gradient from a surface of one of the electrode catalyst layers opposite to a surface thereof in contact with the electrolyte membrane to a surface of the other electrode catalyst layer opposite to a surface thereof in contact with the electrolyte membrane in a thickness direction of the electrolyte membrane (100) and the electrode catalyst layers (110). This makes it possible to provide a membrane electrode assembly with water management performed not only in the surfaces but also in the entire assembly in the thickness direction.

Abstract: According to one embodiment, a system includes a structure having an ionically-conductive, electrically-resistive electrolyte/separator layer covering an inner or outer surface of a carbon-containing electrically-conductive hollow fiber and a catalyst coupled to the hollow fiber, an anode extending along at least part of a length of the structure, and a cathode extending along at least part of the length of the structure, the cathode being on an opposite side of the hollow fiber as the anode. In another embodiment, a method includes acquiring a structure having an ionically-conductive, electrically-resistive electrolyte/separator layer covering an inner or outer surface of a carbon-containing electrically-conductive hollow fiber and a catalyst along one side thereof, adding an anode that extends along at least part of a length of the structure, and adding a cathode that extends along at least part of the length of the structure on an opposite side as the anode.

Abstract: Block copolymer that can be formed into an ion—Conductive membrane are provided. The block copolymer of the invention includes a first polymer block and a second polymer block attached to the first polymer block. The second polymer block has a main polymer chain and one or more side chains extending from the main polymer chain. The one or more side chains include at least one substitutent for proton transfer. Block copolymers utilizing phosphoric acid groups are also provided.

Abstract: A self-humidifying proton exchange membrane (PEM) composition, a membrane-electrode assembly, and a fuel cell. The PEM composition comprises (a) a proton-conducting polymer; (b) a catalyst that promotes the chemical reaction between hydrogen and oxygen molecules to generate water in the membrane, and (c) a deliquescent material dispersed in this polymer. The amount of catalyst is preferably 0.01%-50% by weight on the basis of the polymer weight. The catalyst is preferably a metal catalyst selected from the group consisting of platinum, gold, palladium, rhodium, iridium, ruthenium, and mixtures and alloys thereof. Suitable deliquescent materials include, but are not limited to, calcium chloride, calcium bromide, potassium biphosphate, potassium acetate and combinations thereof. A deliquescent material absorbs and retains an essentially constant amount of moisture to keep the proton mobile in the PEM structure.

Abstract: The invention relates to membrane-electrode assemblies for the electrolysis of water (electrolysis MEAs), which contain an ion-conducting membrane having a front and rear side; a first catalyst layer on the front side; a first gas diffusion layer on the front side; a second catalyst layer on the rear side, and a second gas diffusion layer on the rear side. The first gas diffusion layer has smaller planar dimensions than the ion-conducting membrane, whereas the second gas diffusion layer has essentially the same planar dimensions as the ion-conducting membrane (“semi-coextensive design”). The MEAs also comprise an unsupported free membrane surface that yields improved adhesion properties of the sealing material. The invention also relates to a method for producing the MEA products. Pressure-resistant, gastight and cost-effective membrane-electrode assemblies are obtained, that are used in PEM water electrolyzers, regenerative fuel cells or in other electrochemical devices.

Abstract: A proton conducting polymer is described herein which generally comprises a proton donating polymer and a Lewis acid. The Lewis acids may comprise one or more rare earth triflates. The proton conducting polymer exhibits excellent proton conductivity in low humidity environments.

Abstract: An ion-conductive composite membrane and a method of manufacturing the same, the membrane including phosphate platelets, a silicon compound, and a Keggin-type oxometalate and/or Keggin-type heteropoly acid, wherein the phosphate platelets are three-dimensionally connected to each other via the silicon compound. An electrolyte membrane having an ion-conductive inorganic membrane or an ion-conductive organic/inorganic composite membrane effectively prevents crossover of liquid fuel without the reduction of ion conductivity in a liquid fuel cell, thereby allowing for the production of fuel cells having excellent performance.

Abstract: The present invention relates to a high temperature proton-conducting polymer membrane, a preparation method thereof, a membrane-electrode assembly using the same and a fuel cell containing the same. More particularly, it relates to a proton-conducting polymer membrane enabling fuel cell operation under high temperature and normal pressure condition, wherein sulfoalkyl or sulfoaryl groups are introduced between layers of metal phosphate and cation exchange groups are present in side chains, a preparation method thereof and a membrane-electrode assembly using the proton exchange membrane and a fuel cell containing the same.

Abstract: Noble metal catalysts and methods for producing the catalysts are provided. The catalysts are useful in applications such as fuel cells. The catalysts exhibit reduced agglomeration of catalyst particles as compared to conventional noble metal catalysts.

Abstract: A membrane-electrode assembly (MEA) 1 has a solid polymer electrolyte membrane 2. The membrane 2 has ion-conductive domains 3 and non-ion-conductive domains 4 and an electrode catalyst 5. The electrode catalyst 5 is present selectively on surface sites of the solid polymer electrolyte membrane 2 which corresponds to the ion-conductive domains 3 rather than surface sites of the membrane 2 which corresponds to the non-ion-conductive domains 4. A spray liquid containing the electrode catalyst and a solvent is applied onto a surface of the membrane 2 by electrostatic spray deposition to selectively adhere the electrode catalyst 5 on the surface sites of the membrane 2 which corresponds to the ion-conductive domains 3. The membrane 2 is preferably subjected to a hydrophilization treatment before being sprayed with the spray liquid.

Abstract: The present invention provides a solid electrolyte with high ion-conductivity which is cheap and exhibits high conductivity in an alkaline form, and stably keeps high conductivity because of a small amount of the leak of a compound bearing conductivity even in a wet state. The invention is useful in an electrochemical system using the solid electrolyte, such as a fuel cell. The solid electrolyte with high ion-conductivity comprises a hybrid compound which contains at least polyvinyl alcohol and a zirconic acid compound, and also a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine, obtained by hydrolyzing a zirconium salt or an oxyzirconium salt in a solution including water, polyvinyl alcohol, a zirconium salt or an oxyzirconium salt and a nitrogen-containing organic compound having a structure of amine, quaternary ammonium compound and/or imine coexist, removing a solvent and contacting with alkali.

Abstract: An ion-conductive composite membrane and a method of manufacturing the same, the membrane including phosphate platelets, a silicon compound, and a Keggin-type oxometalate and/or Keggin-type heteropoly acid, wherein the phosphate platelets are three-dimensionally connected to each other via the silicon compound. An electrolyte membrane having an ion-conductive inorganic membrane or an ion-conductive organic/inorganic composite membrane effectively prevents crossover of liquid fuel without the reduction of ion conductivity in a liquid fuel cell, thereby allowing for the production of fuel cells having excellent performance.

Abstract: A polymer electrolyte having a repetitive structure represented by the following formula (1): wherein B represents a single bond or a bivalent group, A represents a bivalent aromatic group, Y represents —SO2—, —SO— or —CO—, R1 represents a substituent, n1 represents an integer of from 0 to 3, L represents a perfluoroalkylene group, and M represents an ionic group.

Abstract: A c-axis-oriented HAP thin film synthesized by seeded growth on a palladium hydrogen membrane substrate. An exemplary synthetic process includes electrochemical seeding on the substrate, and secondary and tertiary hydrothermal treatments under conditions that favor growth along c-axes and a-axes in sequence. By adjusting corresponding synthetic conditions, an HAP this film can be grown to a controllable thickness with a dense coverage on the underlying substrate. The thin films have relatively high proton conductivity under hydrogen atmosphere and high temperature conditions. The c-axis oriented films may be integrated into fuel cells for application in the intermediate temperature range of 200-600° C. The electrochemical-hydrothermal deposition technique may be applied to create other oriented crystal materials having optimized properties, useful for separations and catalysis as well as electronic and electrochemical applications, electrochemical membrane reactors, and in chemical sensors.

Abstract: A polymer electrolyte membrane includes a cross-linking reaction product between a hydrophilic polymer and a cross-linking agent represented by Formula 1 below wherein R1 is substituted or unsubstituted C1-C20 alkyl group, substituted or unsubstituted C6-C20 aryl group, or substituted or unsubstituted C2-C20 heteroaryl group; and n is an integer in the range of 1 to 5. The polymer electrolyte membrane may be prepared by preparing a composition for forming a polymer electrolyte membrane including the hydrophilic polymer, the cross-linking agent represented by Formula 1 and a solvent, applying the composition for forming a polymer electrolyte membrane to a supporting substrate; and heat treating the composition for forming the polymer electrolyte membrane to form the polymer electrolyte membrane. A fuel cell or other device includes the polymer electrolyte membrane. The polymer electrolyte membrane has low solubility to a strong acid and excellent ionic conductivity.

Abstract: The present invention relates to a material for an electrochemical device, especially a fuel cell, an electrolyzer or a storage battery, comprising a matrix and activated boron nitride contained in the matrix.

Abstract: In the present invention, a material having a structure represented by formula (1) or (2) (wherein W equals N or C) is used as a solid electrolyte for a fuel cell. An electrolyte membrane having a small fuel crossover and a fuel cell having excellent ion conductivity and service capacity are obtained.

Abstract: This invention concerns a high temperature fuel cell with mixed anionic and protonic conduction having a protonic conduction reforming membrane directly coupled to a solid oxide fuel cell with conduction by oxygen ions, enabling use of a gradually reforming anode generating carbon deposits to be avoided. The reverse operation of the present invention outside the reforming stage forms a high water temperature electrolyser to produce hydrogen efficiently without having to separate it from water as is the case with current systems.

Abstract: An electronically insulating proton conductor (C) is adhered or deposited as a film on a dense phase proton permeable material (D) in a thicknees such that the composite C/D has a proton conductivity in a preferred intermediate temperature range of 175-550° C. The composite C/D is incorporated in a high temperature electrolyte membrane electrolyte assembly (MEA), which is incorporated into a fuel cell that can operate in this intermediate temperature range. The fuel cell in turn is incorporated into a fuel cell system having a fuel reformer in the flow field of a fuel mixture entering the fuel cell or in a mode where the fuel cell receives fuel from an external reformer.

Abstract: A solid electrolyte type fuel cell which incorporates a metal separator comprising a base material of a metal other than silver or a silver alloy which is plated with silver or a silver alloy. The fuel cell can achieve improved efficiency for electricity generation with no increase of the resistance of the metal separator, even when it is operated at a low temperature.

Abstract: The present invention can provide a polymer electrolyte membrane having power generation characteristics with a high output and long life and a polymer electrolyte fuel cell using the same. The present invention provides a polymer electrolyte membrane having a porous polymer film and a proton conducting component present in a hole of the porous polymer film, characterized in that the proton conducting component has a compound having a proton conducting group and a bicyclo ring structure.

Abstract: The process described herein provides a simple and cost effective method for making crack free, high density thin ceramic film. The steps involve depositing a layer of a ceramic material on a porous or dense substrate. The deposited layer is compacted and then the resultant laminate is sintered to achieve a higher density than would have been possible without the pre-firing compaction step.

Abstract: An electrolytic membrane comprising a porous membrane substrate containing a cross-linked polymer electrolyte having at least a structural component shown by following chemical formula 1: wherein A represents a repeating unit having an aromatic hydrocarbon group substituted by at least a sulfonic acid group, B represents a repeating unit having one of a nitrogen-containing hetero ring compound residue, and the sulfate, hydrochloride or organic sulfonate thereof, C represents a repeating unit having a cross-linked group, and X, Y and Z represent mol fractions of respective repeating units in the chemical formula 1, with 0.34?X?0.985, 0.005?Y?0.49, 0.01?Z?0.495 and Y?X and Z?X, provided that, in the repeating unit A, a ratio of the aromatic hydrocarbon group substituted by at least a sulfonic acid group is 0.3 to 1.0, and the number of the sulfonic acid group in the aromatic hydrocarbon group is 1 to 3.

Abstract: According to the invention, a fuel cell system features a fuel cell (14) having a solid polymer electrolyte membrane (4), and an antioxidant residing in or contacting the solid polymer electrolyte membrane (4), for inactivating active oxygen.

Abstract: A membrane electrode assembly for solid polymer electrolyte fuel cells exhibits higher proton conductivity and superior thermal resistance, in which the solid polymer electrolyte membrane has a nitrogen atom and a sulfonic acid group, and a principal chain of a constitutional unit is a phenylene bond, is provided. In particular, the membrane electrode assembly for solid polymer electrolyte fuel cells preferably contains the sulfonated polyarylene expressed by the formula (1).

Abstract: An interconnect structure is disclosed for use in solid oxide electrolytic devices that use chrome-containing components, such as solid oxide fuel cells and solid oxide oxygen-generators. The invention provides a reliable and durable interconnect for both structural and electrical components of such devices. In general, the interconnect structure relies on a dual-layer, high-temperature seal which provides an effective diffusion barrier for both chrome and oxygen. As a result of the described interconnect, corrosion or loss in electrical conductivity in such solid oxide electrolytic devices is avoided. Also, a novel structure for such solid oxide electrolytic devices is disclosed, which provides an economical and high-integrity structure that utilizes the disclosed interconnect structure. A result of the present invention is that thin film solid oxide fuel cells and solid oxide oxygen generators may be fabricated using only metal alloys as bulk components.