Specified Solid Electrolyte Patents (Class 429/491)
  • Publication number: 20110020724
    Abstract: An electrode for a fuel cell includes a gas diffusion layer contacting with a separator having a channel and a catalyst layer interposed between the gas diffusion layer and an electrolyte membrane. The catalyst layer of the electrode has two portions with different hydrophilicities. A portion of the catalyst layer that faces a channel has a higher hydrophilicity than a portion that does not face a channel. This electrode may control hydrophilicity of the catalyst layer differently according to locations, so it is possible to keep an amount of moisture in an electrode in a suitable way, thereby improving the performance of the cell.
    Type: Application
    Filed: December 23, 2008
    Publication date: January 27, 2011
    Applicant: LG CHEM, LTD.
    Inventors: Hyuk Kim, Seong-Uk Jeong, Chang-Song Lee, Won-Ho Lee
  • Patent number: 7875392
    Abstract: A polymer electrolyte membrane comprising: (a) a fluorinated polymer electrolyte having an ion exchange group, and (b) a basic polymer, wherein, optionally, at least a part of component (a) and at least a part of component (b) are chemically bonded to each other. A method for producing the above-mentioned polymer electrolyte membrane. A membrane/electrode assembly comprising the above-mentioned polymer electrolyte membrane which is securely sandwiched between an anode and a cathode. A polymer electrolyte fuel cell comprising the membrane/electrode assembly.
    Type: Grant
    Filed: June 24, 2004
    Date of Patent: January 25, 2011
    Assignee: Asahi Kasei Chemicals Corporation
    Inventors: Naoto Miyake, Masanobu Wakizoe, Eiji Honda
  • Patent number: 7871735
    Abstract: Ceramic laminate structures, particularly laminate structures including stabilized zirconia compositions, as well as electrodes and electrochemical cells including such laminate structures. The stabilized zirconia composition preferably are selected from scandia-stabilized zirconia and yttria-stabilized zirconia. These laminate structures enhance the overall flexural strength of the electrolyte layer while preserving high electrical conductivity. Such laminate structures may be useful in electrochemical fuel cells such as solid oxide fuel cells.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: January 18, 2011
    Assignee: Nextech Materials, Ltd.
    Inventors: Matthew M. Seabaugh, Katarzyna Sabolsky, Michael J. Day
  • Patent number: 7867667
    Abstract: A polymer electrolyte membrane for a fuel cell includes an ion exchange resin membrane, and an electric conductive polymer. The electric conductive polymer is present along a thickness direction of the ion exchange resin membrane from one side of the ion exchange resin membrane to the interior of the ion exchange resin membrane.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: January 11, 2011
    Assignee: Samsung SDI Co., Ltd.
    Inventor: Min-Kyu Song
  • Patent number: 7867668
    Abstract: A fuel cell is produced using a fuel cell electrolyte layer comprising a hydrogen-permeable metal layer 27 serving as the compact substrate through which the gas supplied to the electrochemical reaction passes, a porous layer formed on the hydrogen-permeable metal layer 27, and an inorganic electrolyte supported in the pores of the porous layer.
    Type: Grant
    Filed: March 28, 2005
    Date of Patent: January 11, 2011
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventor: Naoki Ito
  • Patent number: 7862953
    Abstract: An unsaturated compound including a urethane bond in a main chain and a sulfonic acid group, a phosphoric acid group, an alkylsulfonic acid group, or an alkylphosphoric acid group on a benzene ring in a side chain is provided. In addition, a solid polymer electrolyte membrane containing a compound prepared by polymerizing the above-mentioned compound and an electrolyte membrane-electrode assembly including diffusion layers adhered on both surfaces of the electrolyte membrane are provided. Furthermore, a solid polymer fuel cell using the electrolyte membrane-electrode assembly is provided.
    Type: Grant
    Filed: December 14, 2006
    Date of Patent: January 4, 2011
    Assignee: Canon Kabushiki Kaisha
    Inventors: Keiko Abe, Motokazu Kobayashi, Makoto Kubota
  • Patent number: 7855017
    Abstract: A structural battery includes an anode, cathode and electrolyte which, taken collectively, have sufficient mechanical strength to allow the battery to be used as a structural component of an article of manufacture. The combined anode, cathode and electrolyte have a stiffness between 10 MPa-1000 GPa, and in certain instances have a stiffness between 50 MPa-100 GPa. Also disclosed are solid electrolytes which may be used in structural batteries. The electrolytes are comprised of salts dissolved in a solvent such as a body of polymeric material. The electrolyte has good ionic conductivity and good mechanical properties. The solid electrolyte may be comprised of a body of uncrosslinked polymer or an at least partially crosslinked polymer such as a multifunctional polymer having segments comprised of linear resins and segments comprised of crosslinking resins. Also disclosed are methods for manufacturing the structural batteries.
    Type: Grant
    Filed: November 9, 2006
    Date of Patent: December 21, 2010
    Assignee: The United States of America as represented by the Secretary of the Army
    Inventors: James F. Snyder, Robert H. Carter, Eric D. Wetzel
  • Patent number: 7846610
    Abstract: An electrolyte membrane with high durability is provided. The electrolyte membrane includes a porous film containing a nitrogen-containing heterocyclic ring or a cyano group, and a proton conductive component existing in pores of the porous film, wherein the proton conductive component includes a polymer compound containing at least a nitrogen-containing heterocyclic ring, a cyano group, and an acidic group in one molecule.
    Type: Grant
    Filed: October 18, 2007
    Date of Patent: December 7, 2010
    Assignee: Canon Kabushiki Kaisha
    Inventors: Motokazu Kobayashi, Makoto Kubota, Keiko Abe
  • Patent number: 7842431
    Abstract: A mixture, cation conductor and electrochemical device using same are provided. The mixture and a cation conductor, in which cations can be moved without humidification even in a range of temperatures less than or equal to the boiling point of water, or an electrochemical device such as a fuel cell using them. A fuel electrode and an oxygen electrode, which are oppositely arranged with an electrolyte film in between, is provided. The electrolyte film contains a first compound formed of an imidazole derivative containing N having an unshared electron pair and a second compound of at least one selected from the group consisting of compounds having structures shown below.
    Type: Grant
    Filed: February 2, 2005
    Date of Patent: November 30, 2010
    Assignee: Sony Corporation
    Inventors: Kazuaki Fukushima, Takuro Hirakimoto, Shuichi Takizawa, Atsushi Nishimoto, Kazuhiro Noda
  • Publication number: 20100297527
    Abstract: Composite electrolyte materials include composites comprising 8YSZ in a range of 50-95%, balance 3YSZ. Either the 8YSZ or the 3YSZ can be substituted with a composition having the general formula A1-x-yBxCy where: A=Zr0.84Y0.16O2; B=at least one of the following: Zr1-xDxO2 where: D=at least one of the group Mg, Ca, Sc, and Y, and x=0.03 to 0.16; and Ce1-xRExO2 where: RE=at least one rare-earth element and x=0.05 to 0.20; C=Al2O3 where y=0 to 0.20. The composite electrolyte materials are useful in solid state electrochemical devices such as solid oxide fuel cells and electrolyzers.
    Type: Application
    Filed: January 28, 2010
    Publication date: November 25, 2010
    Applicant: UT-BATTELLE, LLC
    Inventors: Timothy R. Armstrong, Beth L. Armstrong, John J. Henry, JR.
  • Patent number: 7838166
    Abstract: A method of manufacturing a solid oxide fuel cell module involves the steps of co-sintering the respective fuel electrodes, and the respective electrolytes, subsequently forming a dense interconnector out of a dense interconnector material, or an interconnector material which turns dense by sintering in at least parts of the solid oxide fuel cell module, in contact with the respective fuel electrodes, and the respective electrolyte, and forming an air electrode on the respective electrolytes before electrically connecting the respective electrodes with the respective first parts of the interconnectors electrically connecting the respective electrodes with the respective first parts of the respective interconnectors via respective second parts of the interconnectors which have a density less than the respective first parts.
    Type: Grant
    Filed: March 31, 2004
    Date of Patent: November 23, 2010
    Assignee: Tokyo Gas Co., Ltd.
    Inventors: Yoshio Matsuzaki, Kenjiro Fujita, Teruhiro Sakurai, Kei Ogasawara
  • Patent number: 7829218
    Abstract: Aspects of the present invention provide a proton conductive electrolyte suitable for a fuel cell material and a fuel cell including the proton conductive electrolyte. More particularly, aspects of the present invention provide a proton conductive electrolyte that has good proton conductivity and can be used to form a membrane having good flexibility. As a result, the proton conductive electrolyte can be used in a fuel cell, the electrolyte membrane of a fuel cell or the electrodes thereof, and can provide a solid polymer fuel cell having high current density, high power and long life-time in a dry environment (relative humidity of 50% or less) at an operating temperature of 100 to 200° C.
    Type: Grant
    Filed: January 9, 2007
    Date of Patent: November 9, 2010
    Assignee: Samsung SDI Co., Ltd
    Inventors: Hiroko Endo, Hiroyuki Nishide, Atsuo Sonai, Takahiro Tago
  • Patent number: 7824820
    Abstract: An electrolyte membrane having a porous base material having pores filled with a first polymer capable of conducting a proton, wherein the porous base material comprises i) at least one second polymer selected from the group consisting of polyolefins and ii) a third polymer having double bond in the polymer, and contains a crosslinked second polymer wherein molecules of the second polymer are crosslinked with one another; and a fuel cell, particularly a solid polymer fuel cell, more specifically a direct methanol polymer fuel cell, using the electrolyte membrane. The electrolyte membrane is excellent in the inhibition of permeation of methanol, exhibits no or reduced change in its area, and is excellent in proton conductivity.
    Type: Grant
    Filed: March 6, 2003
    Date of Patent: November 2, 2010
    Assignee: Nitto Denko Corporation
    Inventors: Takeo Yamaguchi, Kazushige Yamamoto, Shin-ichi Nakao
  • Patent number: 7816052
    Abstract: A proton conductive electrolyte including a polymerized polyurethane, polyethylene(metha)acrylic acid (PEAA), and a cross-linking agent mixture; a method of preparing the same; an electrode including a support and a catalyst layer, the catalyst layer including a supported catalyst and a polymerized mixture of a polyurethane based compound and a polyethylene(metha)acrylic acid; a method of preparing the electrode; and a fuel cell including the proton conductive electrolyte and/or the electrode. The proton conductive electrolyte can be prepared at lower costs than conventionally used polybenzimidazole and NAFION and can be easily formed into a membrane with a controlled thickness by casting. The polymer electrolyte membrane has high mechanical strength, flexibility, and excellent ionic conductivity. The electrode remains stable under high temperature operation, a strong binding force is maintained between the support and the catalyst layer, and the electrode has excellent ionic conductivity.
    Type: Grant
    Filed: May 26, 2006
    Date of Patent: October 19, 2010
    Assignee: Samsung SDI Co., Ltd.
    Inventors: Myung-dong Cho, Jung-ock Park
  • Patent number: 7816053
    Abstract: A membrane-electrode assembly having superior hot water resistance has a membrane containing an aromatic polymer having a repeating unit expressed by general formula (1): in which A represents independently either —CO— or —SO2—; B represents independently an oxygen atom or sulfur atom; R1 to R8, which may be identical or different from each other, represent a hydrogen atom, fluorine atom, alkyl group, phenyl group or nitrile group; R9 to R24, which may be identical or different from each other, represent a hydrogen atom, alkyl group or phenyl group; and ‘a’ represents an integer of 0 to 4.
    Type: Grant
    Filed: June 6, 2006
    Date of Patent: October 19, 2010
    Assignee: Honda Motor Co., Ltd.
    Inventors: Nagayuki Kanaoka, Masaru Iguchi, Hiroshi Sohma
  • Publication number: 20100233575
    Abstract: According to the invention there is provided a method of conduction including the steps of providing a quaternary ammonium compound, and causing the quaternary ammonium compound to conduct ionically.
    Type: Application
    Filed: March 26, 2007
    Publication date: September 16, 2010
    Applicant: IONIC POLYMER SOLUTIONS LIMITED
    Inventors: Ian David Brotherston, John Lindley Bancroft
  • Publication number: 20100233578
    Abstract: The present invention relates to a process for the preparation of electrochemical catalysts of the polymer electrolytes-based fuel cells. With the process of the present invention, high catalyst activity while uniformly supporting a large amount of metal particles on a surface of a support can be achieved. Also, the present invention provides a process for the preparation of electrochemical catalysts of the polymer electrolytes-based fuel cells capable of using a small amount of toxic solvent without an additional high-temperature hydrogen annealing.
    Type: Application
    Filed: December 4, 2007
    Publication date: September 16, 2010
    Applicant: Hanwha Chemical Corporation
    Inventors: Byungchul Jang, Youngsu Jiong, Youngtaek Kim
  • Publication number: 20100233576
    Abstract: An interconnector, or bipolar plate, for a high-temperature solid electrolyte fuel cell is composed of a sintered chromium alloy which has sintering pores and contains >90% by weight of Cr, from 3 to 8% by weight of Fe and optionally from 0.001 to 2% by weight of at least one element of the group of rare earth metals. The chromium alloy contains from 0.1 to 2% by weight of Al and the sintering pores are at least partially filled with an oxidic compound containing Al and Cr. The interconnector has a high impermeability to gas and dimensional stability.
    Type: Application
    Filed: March 11, 2010
    Publication date: September 16, 2010
    Applicant: PLANSEE SE
    Inventors: Marco Brandner, Wolfgang Kraussler, Gerhard Leichtfried, Andreas Venskutonis
  • Patent number: 7794893
    Abstract: Provided are a polymer electrolyte membrane, which includes an ion conductive domain having high continuity and a non-ion conductive domain and has a high strength, and a membrane electrode assembly and a fuel cell each using the polymer electrolyte membrane. The polymer electrolyte membrane includes a block copolymer having an ion conductive block and a non-ion conductive block and has a micro-phase separation structure constituted of an ion conductive domain including the ion conductive block and a non-ion conductive domain including the non-ion conductive block.
    Type: Grant
    Filed: April 23, 2008
    Date of Patent: September 14, 2010
    Assignee: Canon Kabushiki Kaisha
    Inventors: Mamiko Kumagai, Kenji Yamada, Kazuhiro Yamauchi
  • Patent number: 7781120
    Abstract: A solid oxide fuel cell device assembly comprising: (i) at least one solid oxide fuel cell device including one electrolyte sheet sandwiched between at least one pair of electrodes; and (ii) a non-steel frame fixedly attached to said at least one fuel cell device without a seal located therebetween.
    Type: Grant
    Filed: May 16, 2007
    Date of Patent: August 24, 2010
    Assignee: Corning Incorporated
    Inventors: Michael Edward Badding, Jacqueline Leslie Brown, Cameron Wayne Tanner
  • Patent number: 7776486
    Abstract: A separator material effective for decreasing the weight of fuel cells is provided which is lightweight, has good corrosion resistance, and exhibits a minimized increase in electrical contact resistance during use for a long period. Titanium or a titanium alloy is prepared by melting so as to contain not greater than 5 mass % B, thereby forming a titanium-based material in which fine TiB-type boride particles are precipitated and dispersed. The material is then etched in an aqueous acidic solution such that some of the TiB-type boride particles are exposed on the surface through the passive film formed thereon.
    Type: Grant
    Filed: February 26, 2007
    Date of Patent: August 17, 2010
    Assignee: Sumitomo Metal Industries, Ltd.
    Inventors: Yoshio Tarutani, Akira Seki, Takashi Maeda, Wataru Takahashi, Takashi Doi
  • Patent number: 7767358
    Abstract: A dense ceramic electrolyte membrane supported by symmetrical porous ceramic electrolyte layers. The thin (t<100 microns) electrolyte layer is sandwiched between two fugitive-containing electrolyte support layers that become highly porous after firing. The heat treated fugitive-containing support layers form a skeletal structure of strongly adhered electrolyte with an interpenetrating network of pores that extends well always from the electrolyte surface. The porous layers can be infiltrated with a range of electrode materials or precursors to form a solid oxide fuel cell or other electrochemical cell as well as electrochemical cell stacks. The supported ceramic membrane provides electrochemical performance advantages and reduces warpage during sintering compared to conventional structures.
    Type: Grant
    Filed: May 31, 2005
    Date of Patent: August 3, 2010
    Assignee: NexTech Materials, Ltd.
    Inventors: Matthew M. Seabaugh, Katarzyna Sabolsky, Edward M. Sabolsky, Michael J. Day
  • Publication number: 20100183946
    Abstract: A sulfonated poly(arylene sulfone) contains an unsaturated bond. A cross-linked material may be formed from the sulfonated poly(arylene sulfone), and a clay nanocomposite may include the sulfonated poly(arylene sulfone) or the cross-linked material. A fuel cell includes the clay nanocomposite.
    Type: Application
    Filed: January 4, 2010
    Publication date: July 22, 2010
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Yeong-suk CHOI, Sang-ouk Kim, Sun-hwa Lee, Won-jun Lee
  • Patent number: 7745061
    Abstract: An electrolyte membrane for a fuel cell includes: a proton conductive material in which hollow inorganic fine particles having through-holes on the surface of the hollow inorganic fine particles, are filled with an electrolyte resin; and a non-proton conductive polymer.
    Type: Grant
    Filed: November 6, 2008
    Date of Patent: June 29, 2010
    Assignees: National University Corporation Shizuoka University, Toyota Jidosha Kabushiki Kaisha
    Inventors: Tatsuo Fujinami, Takuya Mase, Masayoshi Takami
  • Patent number: 6890576
    Abstract: The invention describes the manufacture of a frozen dessert, akin to sorbet, but having the organoleptic properties of ice cream from cooled milk whey. The milk whey could contain desired amount of fat, ranging from little to no fat, depending upon the quality and caloric value of the end product desired. Suitable sweetening agents and binders are added to the whey, which is subjected to a process of simultaneous agitation, aeration and freezing, resulting in a frozen dessert with an over run.
    Type: Grant
    Filed: December 21, 2000
    Date of Patent: May 10, 2005
    Inventors: Niranjan Chhotalal Mehta, Robert Paget
  • Patent number: 5397577
    Abstract: A method for obtaining beta casein by separating it from para kappa casein involving the use of rennet casein is disclosed.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: March 14, 1995
    Assignee: Eurial - Parc Club du Perray
    Inventors: Christine Le Magnen, Jean-Jacques Maugas