With Bonded Seal Patents (Class 429/510)
  • Patent number: 8663870
    Abstract: An electrochemical device capable of improving arrangement efficiency of bonded bodies and securing favorable sealing characteristics is provided. An electrolyte membrane 11 has a reaction region 11A sandwiched between a fuel electrode 12 and an oxygen electrode 13 and a peripheral region 11B exposed from between the fuel electrode 12 and the oxygen electrode 13. A connection member 20 has a bent section 23 between two flat sections 21 and 22. Since an adhesive layer 14 is provided in the peripheral section 11B of the electrolyte membrane 11, and the bent section 23 of the connection member 20 is bonded to the adhesive layer 14, arrangement efficiency of a bonded body 10 is improved, and favorable sealing characteristics are secured. The adhesive layer 14 has a structure in which a first contact layer having high adhesion to the electrolyte membrane 11, a barrier layer, a strength retention layer, and a second contact layer having high adhesion to the connection member 20 are sequentially laminated.
    Type: Grant
    Filed: October 18, 2007
    Date of Patent: March 4, 2014
    Assignee: Sony Corporation
    Inventors: Kazuaki Fukushima, Shuji Goto, Sayaka Nanjo, Tetsuro Kusamoto
  • Patent number: 8658327
    Abstract: Various aspects of solid oxide fuel cell (SOFC) technology are described. One specific application includes a seal for connecting an outer surface of a fuel cell to a cell manifold that supports the fuel cell and delivers a fuel mixture to an inside portion of the fuel cell. The seal also separates the fuel mixture from the outer surface at the seal. And the seal is electrically conductive to allow flow of electric current between the outer surface and the cell manifold.
    Type: Grant
    Filed: February 20, 2003
    Date of Patent: February 25, 2014
    Assignee: Acumentrics Corporation
    Inventors: Gary A. Mook, Kevin H. Negrotti, Hugh L. Smith, Norman F. Bessette, Kenneth Shown, Timothy Near, Raymond England
  • Patent number: 8658330
    Abstract: A composite seal having a multilayer elastomeric construction and method for constructing the same is provided. More specifically, the present invention provides a composite seal comprised of a low-durometer elastomer compliant layer coated with, or alternatively encapsulated by, a thin protective layer for securely sealing a bipolar plate and a membrane electrode assembly of a fuel cell. The elastomer compliant layer is preferably a silicone constituent and the thin coat protective layer is preferably a fluoroelastomer or fluoropolymer constituent suitable for bonding to the elastomer compliant layer. The foregoing layers constructing the composite seal are preferably deposited directly onto the aforementioned fuel cell components along a predetermined periphery. The resulting composite seal is thin in construction, resistive to undesired chemical and thermal reactions and provides the necessary compressive compliance without undue stress on the fuel cell assembly.
    Type: Grant
    Filed: November 23, 2012
    Date of Patent: February 25, 2014
    Assignee: Ames Rubber Corporation
    Inventors: Ronald W. Brush, John C. Basta, Crisanto F. del Rosario
  • Patent number: 8652702
    Abstract: Fuel cell systems (10) and related methods for limiting fuel cell slippage are provided. A stacked plurality of adjacent fuel cells (14) collectively forming a fuel cell stack (12). The fuel cells each include a pair of first and second plates (30, 30?, 30?; 32, 32?, 32?) at respective opposite ends thereof. A first fuel cell has a first plate (30, 30?, 30?) in engagement with a second plate (32, 32?, 32?) of a second fuel cell adjacent to the first fuel cell. A slip mitigation arrangement (50, 50?, 50?) between at least one of the pairs of the first and second fuel cells comprises first and second seats (62, 62?, 62?; 64, 64?, 64?) recessed in the engagement surfaces of the first and second conductive plates respectively, and a key member (60, 60?, 60?) having opposite ends seated in the first and the second recessed seats such that relative movement between the first and the second fuel cells is limited.
    Type: Grant
    Filed: March 2, 2009
    Date of Patent: February 18, 2014
    Assignee: United Technologies Corporation
    Inventors: David A. Niezelski, Jeffery G. Lake, Robert A. Love, Jason Bennett Blydenburgh
  • Publication number: 20140030633
    Abstract: The seal comprises a centre layer (5) of electrically insulating material, two metal outer layers (6, 7) bearing patterns (8, 9) able to be deformed by flattening out on the bearing faces (2, 3) to be sealed, so as to hold the seal while providing a sealing barrier to the connections, and intermediate layers (10, 11) of glassy material to provide connection thereto while absorbing deformations due to differential expansions. Applicable to high temperature electrolysis or fuel cells.
    Type: Application
    Filed: April 19, 2012
    Publication date: January 30, 2014
    Applicants: COMMISSARIAT A L'ENERGIE ATOMIQUE ET AUX ENERGIES ALTERNATIVES, TECHNETICS GROUP FRANCE SAS
    Inventors: Francois Palermo, Lionel Bruguiere
  • Publication number: 20140017587
    Abstract: A solid oxide fuel cell bonding material contains a glass ceramic layer containing glass ceramic, and a constrained layer laminated on the glass ceramic layer. A solid oxide fuel cell employing the solid oxide fuel cell bonding material is also described.
    Type: Application
    Filed: September 18, 2013
    Publication date: January 16, 2014
    Applicant: MURATA MANUFACTURING CO., LTD.
    Inventor: Yasuhiko Ueda
  • Patent number: 8628891
    Abstract: A system and method for electrically interconnecting a plurality of fuel cells to provide dense packing of the fuel cells. Each one of a plurality of fuel cells has a plurality of discrete electrical connection points along an outer surface. Electrical connections are made directly between the discrete electrical connection points of adjacent fuel cells so that the fuel cells can be packed more densely. Fuel cells have at least one outer electrode and at least one discrete interconnection to an inner electrode, wherein the outer electrode is one of a cathode and an anode and wherein the inner electrode is the other of the cathode and the anode. In tubular solid oxide fuel cells the discrete electrical connection points are spaced along the length of the fuel cell.
    Type: Grant
    Filed: December 14, 2006
    Date of Patent: January 14, 2014
    Assignee: Acumentrics Corporation
    Inventors: Michael Brown, Norman F. Bessette, II, Anthony F. Litka, Douglas S. Schmidt
  • Patent number: 8628892
    Abstract: A solid oxide fuel cell supplied with a fuel gas and an oxidant gas, including a single cell 4 having a plate-like electrolyte 41, an cathode 42 formed on an upper surface of the electrolyte 41, and a anode 43 formed on a lower surface of the electrolyte 41; a conductive support substrate 2 supporting the single cell 4, and having through-holes 21 that form a supply path for the fuel gas or oxidant gas; and a gas-permeable welding layer 3 sandwiched between the single cell 4 and the support substrate 2, and welded to the single cell 4 and the support substrate 2.
    Type: Grant
    Filed: September 26, 2008
    Date of Patent: January 14, 2014
    Assignee: Dai Nippon Printing Co., Ltd.
    Inventor: Kuniaki Yoshikata
  • Patent number: 8609296
    Abstract: A method and apparatus for making fuel cell components via a roll to roll process are described. Spaced apart apertures are cut in first and second gasket webs that each include adhesives. The first and second gasket webs are transported to a bonding station on conveyers. A membrane web that includes at least an electrolyte membrane is also transported to the bonding station. At the bonding station, a gasketed membrane web is formed by attaching the first and second gasket webs to the membrane web. The first gasket web is attached to a first surface of the membrane web via the adhesive layer of the first gasket web. The second gasket web is attached to a second surface of the membrane web via the adhesive layer of the second gasket web.
    Type: Grant
    Filed: September 12, 2012
    Date of Patent: December 17, 2013
    Assignee: 3M Innovative Properties Company
    Inventors: Daniel M. Pierpont, Eric J. Hanson, Michael T. Hicks, Eric J. Iverson, David J. Miller, Scott A. Ripley
  • Patent number: 8603704
    Abstract: An interlockable bead seal for a bipolar plate is provided. The interlockable bead seal includes a first elongate bead formed on a first plate and a second elongate bead formed on a second plate. The first elongate bead has a sealing surface and the second elongate bead has a trough. An interlockable bipolar plate having the interlockable bead seals, and a fuel cell stack formed from a plurality of the interlockable bipolar plates, are also provided. A lateral slippage between components of the fuel cell stack is militated against by the interlockable bipolar plates.
    Type: Grant
    Filed: March 5, 2012
    Date of Patent: December 10, 2013
    Assignee: GM Global Technology Operations LLC
    Inventors: Mark W. Keyser, Gerald W. Fly
  • Patent number: 8580457
    Abstract: The invention provides a fuel cell stack including a layer of encapsulating material disposed about the separator plate, MEA, and reactant manifold, wherein the reactant manifold is bounded at least in part by the encapsulating material. The fuel cell stack also includes a first opening through the plate body to the first face from the second face, and an open channel in the second face extending from the opening toward a periphery of the plate. The invention also provides a fuel cell stack having a first face including an opening for passage of a reactant therethrough, a first reactant flow field defined thereon, and a first raised surface formed thereon substantially surrounding the opening. The first raised surface is configured and adapted to mate with a second surface on a face of an adjacent plate to create a flow obstruction for encapsulating material.
    Type: Grant
    Filed: June 28, 2007
    Date of Patent: November 12, 2013
    Assignee: Protonex Technology Corporation
    Inventors: Thomas Vitella, Jeff Baldic, Ronald Rezac, Nick Lauder, Seth Avis, Paul Osenar
  • Patent number: 8551668
    Abstract: A sealed and/or reinforced membrane electrode assembly is disclosed. Encapsulation films, each comprising a backing layer and an adhesive layer, are positioned on the edges of at least one face of each gas diffusion substrate such that the adhesive layers impregnate into each gas diffusion substrate. Methods of forming sealed and/or reinforced membrane electrode assemblies are also disclosed.
    Type: Grant
    Filed: October 17, 2012
    Date of Patent: October 8, 2013
    Assignee: Johnson Matthey Fuel Cells Limited
    Inventors: Silvain Buche, Adam John Hodgkinson, Catherine Helen de Rouffignac, Jonathan David Brereton Sharman
  • Patent number: 8551672
    Abstract: A packaging structure of a low-pressure molded fuel cell comprises a hot melt adhesive layer, which is formed through a low-pressure molding process using a hot melt adhesive that has specific material properties and will become molten when being heated. The molten hot melt adhesive is injected into the cell via injection holes formed on a housing or a mounting element to flow through a C-sectioned flow channel, so as to tightly enclose and bond to edges of the air cathode and separator for the cell. After the hot melt adhesive is solidified, a chemical-resistant hot melt adhesive layer with good sealing and enclosing ability as well as high adhesion strength and elasticity, being bubble removed at controlled pressure and the hot melt adhesive material is formed to firmly bond to the cell components and tightly seal the cell, so as to effectively prevent electrolyte in the cell from leaking.
    Type: Grant
    Filed: January 5, 2010
    Date of Patent: October 8, 2013
    Assignee: High Tech Battery Inc.
    Inventor: Kuei Yung Wang Chen
  • Patent number: 8546045
    Abstract: An electrochemical device subassembly is provided that includes a membrane electrode assembly and a gasket. The membrane electrode assembly includes an electrolyte membrane having a first major surface, a second major surface opposite the first major surface, and a peripheral edge. The gasket is disposed adjacent the first major surface of the electrolyte membrane at the peripheral edge, and has a plurality of replicated structures that extend greater than about 250 micrometers from a surface of the gasket.
    Type: Grant
    Filed: September 19, 2005
    Date of Patent: October 1, 2013
    Assignee: 3M Innovative Properties Company
    Inventors: Paul M. Boucher, Michael A. Yandrasits, Katherine A. S. Graham, Eric J. Hanson
  • Publication number: 20130196253
    Abstract: A solid oxide fuel cell (SOFC) stack having a glass seal sandwiched between the sealing surfaces of adjacent cassettes, in which at least one cassette includes means for interlocking the glass seal onto the sealing surface of the cassette for improved adhesion and durability of the glass seal. The at least one cassette includes a plurality of perforations configured to receive and lock onto a portion of the glass seal. At least one of the perforations includes a through-hole having an exterior opening on the sealing surface and an interior opening on the interior surface of the cassette. A portion of the glass seal is received in the perforation forming a glass column in the through-hole and a flared glass end on the interior surface surrounding the interior opening. The flared glass end cooperates with the glass column to interlock the glass seal onto the cassette's sealing surface.
    Type: Application
    Filed: January 31, 2012
    Publication date: August 1, 2013
    Applicant: DELPHI TECHNOLOGIES, INC.
    Inventors: ANTHONY J. DE ROSE, SUBHASISH MUKERJEE, RAY BASSETT, KARL JACOB HALTINER, JR.
  • Patent number: 8497048
    Abstract: The present invention provides a fuel cell separator having an airtight gasket, in which a gasket is integrally injection-molded in a region that requires airtightness of a fuel cell separator to maintain airtightness of each flow field of the separator and to smoothly guide the fluid flow in each flow field. For this purpose, the present invention provides a fuel cell separator having an airtight gasket, which is integrally injection-molded on both surfaces of the separator to form a closed curve.
    Type: Grant
    Filed: November 19, 2009
    Date of Patent: July 30, 2013
    Assignees: Hyundai Motor Company, Kia Motors Corporation
    Inventors: Sang Mun Chin, Sae Hoon Kim, Yoo Chang Yang, Suk Min Baeck, Seong Il Heo
  • Patent number: 8486328
    Abstract: Powders of respective metal elements (Mn,Co) constituting a transition metal oxide (MnCo2O4) having a spinel type crystal structure are used as a starting material. A paste containing the mixture of the powders is interposed between an air electrode and an interconnector, and with this state, a sintering is performed, whereby a bonding agent according to the present invention can be obtained. This bonding agent has a “co-continuous structure”. In the “co-continuous structure”, a thickness of an arm portion that links many base portions to one another is 0.3 to 2.5 ?m. The bonding agent includes a spherical particle in which plural crystal faces are exposed to the surface, the particle having a side with a length of 1 ?m or more, among the plural sides constituting the outline of the crystal face. The diameter of the particle is 5 to 80 ?m.
    Type: Grant
    Filed: July 16, 2010
    Date of Patent: July 16, 2013
    Assignee: NGK Insulators, Ltd.
    Inventors: Makoto Ohmori, Toshiyuki Nakamura, Takashi Ryu
  • Patent number: 8475970
    Abstract: Disclosed is a fluororesin-coated polymer film for reinforcing a polymer electrolyte membrane, wherein the fluororesin-coated polymer film is fabricated by forming on at least one side of a polymer film a coating of a reaction product of (A) a fluorine-containing copolymer composed of a fluoroolefin, a cyclohexyl group-containing acrylic ester, and a hydroxyl group-containing vinyl ether, and (B) a crosslinking agent having two or more isocyanate groups. The polymer film according to the present invention not only exhibits sufficiently high initial adhesion strength, with respect to the polymer electrolyte membrane, but also retains thereafter high adhesion strength in actual operating environments.
    Type: Grant
    Filed: January 15, 2009
    Date of Patent: July 2, 2013
    Assignee: W. L. Gore & Associates, Co., Ltd.
    Inventors: Hideki Yamada, Shizu Okazaki, Hiroyoshi Fujimoto
  • Publication number: 20130157173
    Abstract: An adhesive seal member for a fuel cell of the present invention includes a cross-linked product of a rubber composition containing components (A) to (E): (A) at least one rubber component selected from ethylene-propylene rubber and ethylene-propylene-diene rubber, (B) an organic peroxide having a one-hour half-life temperature of 130° C. or less, (C) a crosslinking aid, (D) at least one adhesive component selected from a resorcinol compound and a melamine compound, an aluminate coupling agent, and a silane coupling agent, and (E) a softener having a pour point of ?40° C. or less. If the ethylene-propylene rubber or the ethylene-propylene-diene rubber in (A) the rubber component has an ethylene content of 53% by mass or less, the rubber composition may be devoid of (E) the softener having a pour point of ?40° C. or less.
    Type: Application
    Filed: January 10, 2013
    Publication date: June 20, 2013
    Applicant: TOKAI RUBBER INDUSTRIES, LTD.
    Inventor: TOKAI RUBBER INDUSTRIES, LTD.
  • Patent number: 8455154
    Abstract: A solid oxide fuel cell (SOFC) includes a plurality of subassemblies. Each subassembly includes at least one subcell of a first electrode, a second electrode and an electrolyte between the first and second electrodes. A first bonding layer is at the second electrode and an interconnect layer is at the first bonding layer distal to the electrolyte. A second bonding layer that is compositionally distinct from the first bonding layer is at the interconnect layer, whereby the interconnect partitions the first and second bonding layers. A method of fabricating a fuel cell assembly includes co-firing at least two subassemblies using a third bonding layer that is microstructurally or compositionally distinct from the second bonding layer.
    Type: Grant
    Filed: December 29, 2009
    Date of Patent: June 4, 2013
    Assignee: Saint-Gobain Ceramics & Plastics, Inc.
    Inventors: Oh-Hun Kwon, Yeshwanth Narendar, Rakesh Kapoor
  • Publication number: 20130137014
    Abstract: A bonding layer, disposed between an interconnect layer and an electrode layer of a solid oxide fuel cell article, may be formed from a yttria stabilized zirconia (YSZ) powder having a monomodal particle size distribution (PSD) with a d50 that is greater than about 1 ?m and a d90 that is greater than about 2 ?m.
    Type: Application
    Filed: November 14, 2012
    Publication date: May 30, 2013
    Inventors: Guangyong Lin, Yeshwanth Narendar, John D. Pietras, Qiang Zhao, Robert J. Sliwoski, Caroline Levy, Samuel S. Marlin, Aravind Mohanram
  • Patent number: 8424878
    Abstract: A device including a metal substrate and a ceramic substrate including a back-tapered groove separated from each other by a sealed flexible link. The link includes: a metal element including an end connected to the metal substrate and at another end housed in the groove of the ceramic substrate, the metal element being elastically deformable both in the groove along a direction radial to the groove and, in the separation space between the metal substrate and the ceramic substrate along the separation direction, and a joint-forming mass with a greater thermal expansion coefficient than that of the ceramic substrate and adhesively bonded to the end of the metal element housed in the back-tapered groove, the joint fitting with direct contact a portion of the height of convergent sidewalls of the groove.
    Type: Grant
    Filed: December 22, 2008
    Date of Patent: April 23, 2013
    Assignee: Commissariat a l'energie atomique et aux energies alternatives
    Inventors: Magali Reytier, Philippe Bucci
  • Patent number: 8420278
    Abstract: A solid oxide fuel cell stack having a plurality of cassettes and a glass composite seal disposed between the sealing surfaces of adjacent cassettes, thereby joining the cassettes and providing a hermetic seal therebetween. The glass composite seal includes an alkaline earth aluminosilicate (AEAS) glass disposed about a viscous glass such that the AEAS glass retains the viscous glass in a predetermined position between the first and second sealing surfaces. The AEAS glass provides geometric stability to the glass composite seal to maintain the proper distance between the adjacent cassettes while the viscous glass provides for a compliant and self-healing seal. The glass composite seal may include fibers, powders, and/or beads of zirconium oxide, aluminum oxide, yttria-stabilized zirconia (YSZ), or mixtures thereof, to enhance the desirable properties of the glass composite seal.
    Type: Grant
    Filed: December 30, 2010
    Date of Patent: April 16, 2013
    Assignee: Delphi Technologies, Inc.
    Inventors: Anthony J. De Rose, Subhasish Mukerjee, Karl Jacob Haltiner, Jr.
  • Publication number: 20130089811
    Abstract: A seal assembly includes first and second solid oxide fuel cell components and a self-healing glass between the components. The glass seal includes 35-60 wt % alkaline earth oxide, 2-15 wt % boron oxide, and 25-62 wt % silicone oxide.
    Type: Application
    Filed: September 21, 2009
    Publication date: April 11, 2013
    Inventors: John E. Holowczak, Sonia Tulyani, Elllen Y. Sun, Jean Yamanis
  • Patent number: 8404398
    Abstract: According to an embodiment, a gas delivery device for a fuel cell system includes a hollow ceramic element comprising a dielectric material having at least one groove in one end face of the ceramic element and a first metal tube, wherein an end of the first metal tube is inserted into the groove of the hollow ceramic element. According to an embodiment, a fuel cell system includes a fuel cell stack or column, a gas delivery line fluidly connected to the stack or column, and a coefficient of thermal expansion compensator/isolator located in the gas delivery line, where the coefficient of thermal expansion compensator/isolator includes a hollow ceramic element made of a dielectric material having at least one groove in one end face of the ceramic element, a first metal tube, where an end of the first metal tube is inserted into the groove of the hollow ceramic element, and a hollow flexible element which compensates for differences in coefficients of thermal expansion between components of the fuel cell system.
    Type: Grant
    Filed: August 11, 2009
    Date of Patent: March 26, 2013
    Assignee: Bloom Energy Corporation
    Inventors: Martin Perry, Michael Petrucha, Andy Ta, Brandon Snow
  • Publication number: 20130065157
    Abstract: The present disclosure provides an end plate for a fuel cell including a sandwich insert, in which a metal insert has a sandwich insert structure including a plurality of stacked plates, thereby securing strength and achieving a lightweight structure. The sandwich insert is manufactured by staking two or more plates, each having a specific shape, followed by injection molding the sandwich insert with a plastic injection molded body, thereby securing strength and also achieving a lightweight structure, contrary to a conventional integral metal insert.
    Type: Application
    Filed: December 6, 2011
    Publication date: March 14, 2013
    Applicants: HYUNDAI MOTOR COMPANY, DAEWON KANG UP CO., LTD., KIA MOTORS CORPORATION
    Inventors: Jung Do Suh, Sae Hoon Kim, Byung Ki Ahn, Jin Yong Park, Ji Yong Kim
  • Patent number: 8383283
    Abstract: A fuel cell includes an electrolyte matrix having a cathode side with a cathode disposed thereon and an anode side with an anode receiving portion and a sealing portion positioned peripherally to the anode receiving portion. The anode receiving portion has an anode disposed thereon. A fuel conduit has one or more one sealing platforms and having an opening extending through the fuel conduit. The anode is positioned in the opening. The fuel cell includes one or more devices for preventing the occurrence an electrical short circuit between the cathode and the sealing platform. The device for preventing the electrical short circuit is aligned with the sealing portion and sealing platform and is positioned on the electrolyte matrix, the cathode and/or the sealing platform.
    Type: Grant
    Filed: April 15, 2009
    Date of Patent: February 26, 2013
    Assignee: FuelCell Energy, Inc.
    Inventors: Chao-yi Yun, Mohammad Farooque, Abdelkader Hilmi, Richard Johnsen, Gengfu Xu
  • Patent number: 8372556
    Abstract: A fuel cell having a pair of bipolar plates is provided. Each of the bipolar plates has a nested active area and a non-nested feed area which also may serve as active area. An electrolyte membrane is disposed between a pair of electrodes and a pair of diffusion medium layers. Each of the diffusion medium layers is disposed adjacent the nested active areas and non-nested feed areas of the bipolar plates. A porous, electrically conductive spacer is disposed between one of the diffusion medium layers and one of the bipolar plates. A fuel cell stack having the fuel cell is also provided.
    Type: Grant
    Filed: February 8, 2010
    Date of Patent: February 12, 2013
    Assignee: GM Global Technology Operations LLC
    Inventor: Steven G. Goebel
  • Patent number: 8372237
    Abstract: A continuous process for applying subgaskets to surfaces of CCM subassemblies, comprising: a) preparation of a roll (A), wherein on each of two surfaces, electrocatalytic layers longitudinally distributed at regular intervals are applied; b) preparation of two subgasket rolls (B) wherein, on a subgasket sheet, in correspondence to the position of the electrocatalytic layers in the roll (A), openings are made; the percent ratio (subgasket opening area)/(electrocatalytic layer area) being between 90% and 99%; c) hot lamination of two rolls (B) with the roll (A); the step being carried out so that the perimeter of the openings of the two rolls (B) falls inside the area of the electrocatalytic layers, and obtaining a roll (C), wherein on each of the two surfaces of the sheet formed of a CCM sequence (roll (A)) a subgasket sheet (roll (B)) is applied.
    Type: Grant
    Filed: December 27, 2006
    Date of Patent: February 12, 2013
    Assignee: Solvay Solexis S.p.A.
    Inventors: Luca Merlo, Alessandro Ghielmi, Vincenzo Arcella
  • Patent number: 8361674
    Abstract: The invention relates to the field of electrochemical cells and fuel cells, more specifically to polymer-electrolyte-membrane fuel cells (PEMFC) and direct methanol fuel cells (DMFC). A multi-layer membrane-electrode-assembly (ML-MEA) comprising two electrically conductive bipolar plates and a membrane-electrode-assembly (MEA) bonded together by means of an electrically insulating adhesive material is disclosed. The adhesive material, preferably a polyurethane-based system, is in direct contact with the protective film layers attached to front side and the back side of the MEA, thus contamination of the ionomer membrane and/or the electrode layers with adhesive components is avoided. Multi-layer MEAs with improved long term stability and life time are obtained. The products are used for the manufacture of low temperature PEMFC and DMFC stacks.
    Type: Grant
    Filed: April 12, 2005
    Date of Patent: January 29, 2013
    Assignee: Umicore AG & Co. KG
    Inventors: Ralf Zuber, Knut Fehl, Peter Seipel, Sven Bornbaum
  • Patent number: 8343686
    Abstract: Tubular objects having two or more concentric layers that have different properties are joined to one another during their manufacture primarily by compressive and friction forces generated by shrinkage during sintering and possibly mechanical interlocking. It is not necessary for the concentric tubes to display adhesive-, chemical- or sinter-bonding to each other in order to achieve a strong bond. This facilitates joining of dissimilar materials, such as ceramics and metals.
    Type: Grant
    Filed: July 28, 2006
    Date of Patent: January 1, 2013
    Assignee: The Regents of the University of California
    Inventors: Lutgard DeJonghe, Craig Jacobson, Michael Tucker, Steven Visco
  • Patent number: 8338056
    Abstract: A tubular fuel cell includes an inner current collector, a membrane-electrode assembly, and seal portions provided at the axial end portions of the membrane-electrode assembly, respectively. The membrane-electrode assembly includes an inner catalyst layer provided on the inner current collector, an electrolyte membrane provided on the inner catalyst layer, and an outer catalyst layer provided on the electrolyte membrane. The axial length of the outer catalyst layer is shorter than the axial lengths of the electrolyte membrane and the outer catalyst layer. The axial end face of the outer catalyst layer and the axial end face of the inner catalyst layer are located on the opposite sides of the seal portion in each side of the tubular fuel cell.
    Type: Grant
    Filed: November 9, 2006
    Date of Patent: December 25, 2012
    Assignee: Toyota Jidosha Kabushiki Kaisha
    Inventors: Masahiro Imanishi, Haruyuki Nakanishi, Shigeaki Murata, Hirokazu Ishimaru, Yuichiro Hama, Yoshihisa Tamura
  • Patent number: 8338057
    Abstract: A gasket for sealing internal surfaces of a fuel cell and formed of compressible material, the gasket comprising a first sealing surface and a second sealing surface for providing a fluid seal against opposing faces of a first fluid flow field plate and a second fluid flow field plate respectively, the gasket further comprising a third sealing surface for sealing against an outer perimeter region of a first surface of a membrane electrode assembly, the third sealing surface being entirely enclosed within a boundary defined by an inner perimeter of the second sealing surface.
    Type: Grant
    Filed: May 14, 2007
    Date of Patent: December 25, 2012
    Assignee: Intelligent Energy Limited
    Inventors: Peter David Hood, Simon Edward Foster
  • Publication number: 20120295183
    Abstract: An electrochemical device includes a ceramic electrode, a metallic interconnect, and a ceramic bond material that bonds the ceramic electrode and the metallic interconnect together. The ceramic material includes manganese-cobalt-oxide that is electrically conductive such that electric current can flow between the ceramic electrode and the metallic interconnect.
    Type: Application
    Filed: February 8, 2010
    Publication date: November 22, 2012
    Inventors: Jean Yamanis, Dustin Frame, Lei Chen, Ellen Y. Sun
  • Patent number: 8309268
    Abstract: A sealed and/or reinforced membrane electrode assembly is disclosed. Encapsulation films, each comprising a backing layer and an adhesive layer, are positioned on the edges of at least one face of each gas diffusion substrate such that the adhesive layers impregnate into each gas diffusion substrate. Methods of forming sealed and/or reinforced membrane electrode assemblies are also disclosed.
    Type: Grant
    Filed: August 2, 2004
    Date of Patent: November 13, 2012
    Assignee: Johnson Matthey Fuel Cells Limited
    Inventors: Silvain Buche, Adam John Hodgkinson, Catherine Helen de Rouffignac, Jonathan David Brereton Sharman
  • Patent number: 8298717
    Abstract: A fuel cell unit (1) according to the present invention comprises a fuel cell (6) having an inner electrode layer (16), an outer electrode layer (20) and a through passage (15); and inner and outer electrode terminals (24, 26) fixed at the opposite ends (6a, 6b) of the fuel cell (6). The fuel cell (6) has an inner electrode peripheral surface (21) electrically communicating with the inner electrode layer (16) and an outer electrode peripheral surface (22) electrically communicating with the outer electrode layer (20). The inner and outer electrode terminals are respectively disposed so that they cover over the inner and outer electrode peripheral surfaces (21, 22) and they are electrically connected thereto. The inner and outer electrode terminals have respective connecting passages which are communicated with the through passage (15).
    Type: Grant
    Filed: December 9, 2011
    Date of Patent: October 30, 2012
    Assignee: Toto Ltd.
    Inventors: Naoki Watanabe, Akira Kawakami
  • Patent number: 8293426
    Abstract: Solid-oxide fuel cell (SOFC) stack assembly designs are consistently investigated to develop an assembly that provides optimal performance, and durability, within desired cost parameters. A new design includes a repeat unit having a SOFC cassette and being characterized by a three-component construct. The three components include an oxidation-resistant, metal window frame hermetically joined to an electrolyte layer of a multi-layer, anode-supported ceramic cell and a pre-cassette including a separator plate having a plurality of vias that provide electrical contact between an anode-side collector within the pre-cassette and a cathode-side current collector of an adjacent cell. The third component is a cathode-side seal, which includes a standoff that supports a cathode channel spacing between each of the cassettes in a stack. Cassettes are formed by joining the pre-cassette and the window frame.
    Type: Grant
    Filed: September 30, 2008
    Date of Patent: October 23, 2012
    Assignee: Battelle Memorial Institute
    Inventors: K. Scott Weil, Kerry D. Meinhardt, Vincent L. Sprenkle
  • Publication number: 20120231371
    Abstract: A system for fabricating a fuel cell component in which a deposition mechanism deposits loading material particles onto the fuel cell component and an actuation mechanism actuates the deposition mechanism. A unit provides a tape fixing agent to the fuel cell component and loaded material particles so as to retain the particles on the fuel cell component. Other fuel components are retained to the fuel cell component also using a tape fixing agent.
    Type: Application
    Filed: March 19, 2012
    Publication date: September 13, 2012
    Inventors: Salvador E. Correa, Thomas M. Lucas, Lawrence J. Novacco
  • Patent number: 8227136
    Abstract: A unitized electrode assembly for a fuel cell comprising an electrolyte membrane, a subgasket, and a sealing bead disposed therebetween is disclosed. The sealing bead adapted to fill a tenting region formed between the membrane and the subgasket to maximize an operating life of the electrolyte membrane by militating against wear of membrane expansion during use of the fuel cell.
    Type: Grant
    Filed: October 30, 2008
    Date of Patent: July 24, 2012
    Assignee: GM Global Technology Operations LLC
    Inventors: Scott L. Peters, Craig S. Gittleman
  • Patent number: 8227145
    Abstract: An interlockable bead seal for a bipolar plate is provided. The interlockable bead seal includes a first elongate bead formed on a first plate and a second elongate bead formed on a second plate. The first elongate bead has a sealing surface and the second elongate bead has a trough. An interlockable bipolar plate having the interlockable bead seals, and a fuel cell stack formed from a plurality of the interlockable bipolar plates, are also provided. A lateral slippage between components of the fuel cell stack is militated against by the interlockable bipolar plates.
    Type: Grant
    Filed: March 18, 2008
    Date of Patent: July 24, 2012
    Assignee: GM Global Technology Operations LLC
    Inventors: Mark W. Keyser, Gerald W. Fly
  • Patent number: 8222571
    Abstract: An apparatus for curing an electrolyte membrane of a fuel cell is disclosed, by which curing can be performed by preventing a surface of an electrolyte layer from swelling. The present invention includes an oven body, a vacuum sucking plate entering the oven body while the electrolyte membrane having an electro-catalyst liquid sprayed thereon is attached to an upper surface of the vacuum sucking plate, a magazine provided within the oven body to sequentially load a plurality of vacuum sucking plates to enter the oven body in a horizontal state, and an air-sucking terminal provided to a rear side of the magazine to sustain a vacuum state of the vacuum sucking plate by being connected to the vacuum sucking plate loaded in the magazine.
    Type: Grant
    Filed: September 29, 2006
    Date of Patent: July 17, 2012
    Assignees: Nordson Sangsan Ltd.
    Inventor: Byung Kook Yoon
  • Patent number: 8197990
    Abstract: A fuel cell, having improved sealing against leakage, includes a sealant disposed over the peripheral portions a membrane electrode assembly such that the cured sealant penetrates a gas diffusion layer of the membrane electrode assembly. The sealant is applied through liquid injection molding techniques to form cured sealant composition at the peripheral potions of the membrane electrode assembly. The sealant may be thermally cured at low temperatures, for example 130° C. or less, or may be cured at room temperature through the application of actinic radiation.
    Type: Grant
    Filed: January 16, 2007
    Date of Patent: June 12, 2012
    Assignee: Henkel Corporation
    Inventors: Matthew P. Burdzy, Brian R. Einsla, Kevin J. Welch
  • Patent number: 8197989
    Abstract: A fuel cell, having improved sealing against leakage, includes a fuel cell component having a cured sealant, wherein the cured sealant includes a telechelic-functional polyisobutylene, an organhydrogenosilane crosslinker, a platinum catalyst and a photoinitiator. The fuel cell component may be a cathode flow field plate, an anode flow field plate, a resin frame, a gas diffusion layer, an anode catalyst layer, a cathode catalyst layer, a membrane electrolyte, a membrane-electrode-assembly frame, and combinations thereof.
    Type: Grant
    Filed: January 16, 2007
    Date of Patent: June 12, 2012
    Assignee: Henkel Corporation
    Inventors: Anthony F. Jacobine, John G. Woods, Steven T. Nakos, Matthew P. Burdzy, Brian R. Einsla, Kevin J. Welch
  • Patent number: 8173320
    Abstract: A fuel cell stack includes a membrane electrode assembly including an electrolyte membrane and electrode catalyst layers sandwiching the electrolyte membrane; metal separators that define gas channels, the metal separators being respectively disposed at both surfaces of the membrane electrode assembly; a current collector from which electromotive force is derived, the current collector being in contact with at least one of the metal separators; and joining parts that join the metal separator to the current collector at portions where the metal separator contacts the current collector.
    Type: Grant
    Filed: May 15, 2007
    Date of Patent: May 8, 2012
    Assignee: Nissan Motor Co., Ltd.
    Inventors: Koshi Takata, Takahito Osada, Atsushi Miyazawa, Motoharu Obika, Motoki Yaginuma
  • Patent number: 8148032
    Abstract: A fuel cell includes a membrane electrode assembly and first and second metal plates sandwiching the membrane electrode assembly. The first metal plate has positioning ribs for positioning the outer region of the membrane electrode assembly. The first and second metal plates are positioned in alignment with each other by the first and second insulating bushings attached to first and second positioning holes of the first and second metal plates. Further, the first and second metal plates sandwiching the membrane electrode assembly are fastened together by a plurality of metal clip members.
    Type: Grant
    Filed: March 29, 2005
    Date of Patent: April 3, 2012
    Assignee: Honda Motor Co., Ltd.
    Inventors: Seiji Sugiura, Shuhei Goto, Ryugo Suzuki, Narutoshi Sugita, Yoshihiro Nakanishi
  • Patent number: 8119302
    Abstract: A method is provided for making an edge-sealed fuel cell membrane electrode assembly comprising the steps of: i) providing a suitable membrane electrode assembly lay-up; ii) positioning a suitable annular layer of a thermoplastic; and iii) applying pressure and heat sufficient to melt impregnate the thermoplastic into the fluid transport layer or layers of the membrane electrode assembly lay-up and simultaneously bond the fluid transport layer or layers to the polymer electrolyte membrane of the membrane electrode assembly lay-up. The polymer electrolyte membrane of the membrane electrode assembly lay-up may be perforated in its outer sealing area. Membrane electrode assemblies made according to the method of the present invention are also provided.
    Type: Grant
    Filed: June 29, 2005
    Date of Patent: February 21, 2012
    Assignee: 3M Innovative Properties Company
    Inventors: Michael Andrew Yandrasits, David Adrian Ylitalo, Douglas Willard Kado
  • Patent number: 8114555
    Abstract: A method of manufacture includes an electrochemical cell structure having a first conductive member and a second conductive member. The first conductive member is spaced from the second conductive member. An adhesive is disposed between the first conductive member and the second conductive member. The adhesive has a solid state and a liquid state. The adhesive is liquefied to form a seal between the first conductive member and the second conductive member.
    Type: Grant
    Filed: April 29, 2011
    Date of Patent: February 14, 2012
    Assignee: Hamilton Sundstrand Corporation
    Inventors: Andrei Leonida, Robert J. Roy, Kurt Matthew Critz
  • Patent number: 8097381
    Abstract: A solid oxide fuel cell generator is provided for electrochemically reacting a fuel gas with a flowing oxidant gas at an elevated temperature to produce power. The generator includes a generator section receiving a fuel gas and a plurality of elongated fuel cells extending through the generator section and having opposing open fuel cell ends for directing an oxidant gas between opposing plena in the generator. A sealant defines a seal on the fuel cells adjacent at least one of the fuel cell ends. The sealant is a modified lanthanum borate aluminosilicate glass composition having a minimal amount of boron oxide and silica, and in which the sealant maintains substantially constant physical characteristics throughout multiple thermal cycles.
    Type: Grant
    Filed: October 24, 2007
    Date of Patent: January 17, 2012
    Assignee: Siemens Energy, Inc.
    Inventors: Robert Draper, Gong Zhang, Roswell J. Ruka, Kevin P. Litzinger, Paolo R. Zafred, Richard A. Basel
  • Patent number: 8097380
    Abstract: A fuel cell unit (1) according to the present invention comprises a fuel cell (6) having an inner electrode layer (16), an outer electrode layer (20) and a through passage (15); and inner and outer electrode terminals (24, 26) fixed at the opposite ends (6a, 6b) of the fuel cell (6). The fuel cell (6) has an inner electrode peripheral surface (21) electrically communicating with the inner electrode layer (16) and an outer electrode peripheral surface (22) electrically communicating with the outer electrode layer (20). The inner and outer electrode terminals are respectively disposed so that they cover over the inner and outer electrode peripheral surfaces (21, 22) and they are electrically connected thereto. The inner and outer electrode terminals have respective connecting passages which are communicated with the through passage (15).
    Type: Grant
    Filed: September 14, 2007
    Date of Patent: January 17, 2012
    Assignee: Toto Ltd.
    Inventors: Naoki Watanabe, Akira Kawakami
  • Publication number: 20110287339
    Abstract: A fuel cell includes a unit cell, a cell fixing member and a welding portion. The unit cell includes a first electrode layer, an electrolyte layer surrounding the first electrode layer, a second electrode layer surrounding the electrolyte layer while exposing an end portion of the electrolyte layer, and a coating layer formed by coating a mixture of ceramic and metal on the exposed end portion of the electrolyte layer. The cell fixing member includes a flow tube inserted into the unit cell, a fixing tube provided to an outside of the flow tube, and a connecting portion connecting the fixing tube and the flow tube to each other and to restrict an insertion depth of the electrolyte layer and the first electrode layer. The welding portion fixes and seals the coating layer and the inner circumferential surface of the fixing tube to each other.
    Type: Application
    Filed: October 20, 2010
    Publication date: November 24, 2011
    Inventors: Jun-Won Suh, Ho-Jin Kweon