Hydrocarbon Wax-containing Adjuvant Patents (Class 430/108.8)
  • Publication number: 20120052434
    Abstract: A toner containing: a non-crystalline polyester resin; a crystalline polyester resin; a releasing agent; a graft-modified polymer; and a colorant, wherein the graft-modified polymer is a polymer having a glass transition temperature of higher than 40° C. but lower than 80° C., and obtained by grafting an acrylic resin onto at least one of a hydrocarbon wax and a crystalline polyester resin, and wherein a SP value of the non-crystalline polyester resin is defined as SP1, a SP value of the crystalline polyester resin is defined as SP2, a SP value of the releasing agent is defined as SP3, and a SP value of the graft-modified polymer is defined as SP4, and SP1, SP2, SP3 and SP4 satisfy relations represented by Formulas (1) to (3): SP1>SP4>SP2>SP3??Formula (1), 0.1<SP1?SP4<1.0??Formula (2), and 0.1<SP4?SP2<1.0??Formula (3).
    Type: Application
    Filed: August 16, 2011
    Publication date: March 1, 2012
    Inventors: Tsuyoshi SUGIMOTO, Naohiro Watanabe, Osamu Uchinokura, Tomoyuki Satoh, Shinya Hanatani, Mamoru Hozumi
  • Patent number: 8124307
    Abstract: Embodiments include a toner having a) a polyester resin derived from a naphthalenic material, a 2-alkyl succinic material, and 2,2-ethyl-butyl-1,3-propanediol, b) a wax, and c) an optional colorant.
    Type: Grant
    Filed: March 30, 2009
    Date of Patent: February 28, 2012
    Assignee: Xerox Corporation
    Inventor: Guerino G. Sacripante
  • Patent number: 8126369
    Abstract: The invention provides an image forming apparatus, comprising: an electrophotographic photoreceptor, a charging unit, an exposure unit, a developing unit, a transfer unit, a fixing unit, and a cleaning unit; the electrophotographic photoreceptor having an outermost layer containing a charge transporting material and at least one curable resin selected from the group consisting of a phenol resin, an epoxy resin and a melamine resin, and the toner having an ammonium ion concentration as determined by ion chromatography of from about 50 ppm to about 300 ppm.
    Type: Grant
    Filed: February 25, 2009
    Date of Patent: February 28, 2012
    Assignee: Fuji Xerox Co., Ltd.
    Inventor: Susumu Yoshino
  • Patent number: 8097391
    Abstract: Provided is a toner for developing electrostatic image which is excellent in shelf stability, and is further excellent in low-temperature fixability so as to be capable of maintaining a high fixing rate even at a low fixing temperature. A toner for developing electrostatic image is used which comprises colored resin particles containing a binder resin, a colorant, and a parting agent, wherein the parting agent is an aliphatic hydrocarbon polymer obtained by polymerizing an aliphatic hydrocarbon monomer.
    Type: Grant
    Filed: January 29, 2007
    Date of Patent: January 17, 2012
    Assignee: Zeon Corporation
    Inventor: Takashi Iga
  • Patent number: 8088544
    Abstract: Nano-sized particles for use in making emulsion aggregation toner particles have a core portion and a shell portion, wherein the core portion of the nano-sized particles includes crystalline resin and the shell portion includes amorphous resin and is substantially to completely free of the crystalline resin.
    Type: Grant
    Filed: July 30, 2007
    Date of Patent: January 3, 2012
    Assignee: Xerox Corporation
    Inventor: Guerino G. Sacripante
  • Patent number: 8084178
    Abstract: A non magnetic toner comprises toner particles each containing at least a binder resin, a colorant and a wax component. The toner further comprises an inorganic fine powder. A storage elastic modulus at 110° C. (G?110) of the non magnetic toner is in a range of 2.00×104 to 2.00×105 dN/m2. A storage elastic modulus at 150° C. (G?150) of the non magnetic toner is in a range of 3.00×103 to 2.00×104 dN/m2. The toner particles are obtained by dispersing a polymerizable monomer composition containing polymerizable monomers, the colorant, the wax component and a low-molecular weight polymer into an aqueous medium, granulating the dispersed polymerizable monomer composition, and polymerizing the polymerizable monomers in granulated particles. The low-molecular weight polymer has a weight average molecular weight (Mw) measured by means of gel permeation chromatography (GPC) in a range of 2000 to 5000.
    Type: Grant
    Filed: June 28, 2006
    Date of Patent: December 27, 2011
    Assignee: Canon Kabushiki Kaisha
    Inventors: Emi Tosaka, Koji Abe, Yushi Mikuriya, Satoshi Handa, Shinya Yachi, Kazumi Yoshizaki, Yasuhiro Hashimoto
  • Publication number: 20110300479
    Abstract: The present invention relates to a toner composition with a broad fusing temperature range and a process for preparing the same. The toner composition according to the present invention creates entanglement between adjacent polymer chains using a non-linear polyester resin having a branch structure, provides elasticity to molten materials by the branch structure when the resin is molten, prevents the molten materials from being transferred to the surface of a roller at a high temperature, and thereby increases the maximum fusing temperature. Therefore, as the average branch number per polyester resin increases, the maximum fusing temperature rises and the fusing temperature range of the toner composition can be widened.
    Type: Application
    Filed: August 28, 2009
    Publication date: December 8, 2011
    Applicant: EXAX TONER, INC
    Inventors: Eui Joon Choi, Hyun Nam Yoon
  • Publication number: 20110294058
    Abstract: A toner containing a wax, wherein the wax has a mass decrease at 165° C. of 10% by mass or less, a molecular chain consisting of C—H bonds and C—C bonds, and a penetration of 5 mm to 25 mm, wherein a product of a ½ method softening point (° C.) of the toner and an amount of the wax on a surface of the toner is 8 to 20, and wherein the toner is obtained by a method including emulsifying or dispersing in an aqueous medium a toner material liquid, which is a liquid containing a toner material, which contains the wax.
    Type: Application
    Filed: May 24, 2011
    Publication date: December 1, 2011
    Inventors: Masana SHIBA, Takahiro Honda, Tsuneyasu Nagatomo, Naohito Shimota, Ryuta Chiba
  • Publication number: 20110255899
    Abstract: A toner, including a binder; a colorant; and a wax including a molecular chain constituted of only a C—H bond and a C—C bond, and having a melting point of from 50 to 78° C. and a melt viscosity of from 5 to 15 mPa·S at 140° C., wherein the toner has a weight reduction rate of from 0.001 to 0.1% by weight/min when measured by TGA (Thermogarvimetric Analysis) method in an atmosphere at 165° C. for 10 min.
    Type: Application
    Filed: April 13, 2011
    Publication date: October 20, 2011
    Applicant: RICOH COMPANY, LTD.
    Inventors: Yasuaki Iwamoto, Naohito Shimota, Naohiro Watanabe, Satoshi Kojima, Masana Shiba
  • Patent number: 8039185
    Abstract: To provide a toner for developing a latent electrostatic image comprising at least a colorant, a wax, and a binder resin, wherein Iwax (s) is a value measured by FTIR-ATR Spectroscopy before heating a mirror-surfaced pellet formed by compressing and molding the toner, and Iwax (t) is a value measured by FTIR-ATR Spectroscopy after heating the pellet at a surface temperature thereof of 130° C. for 1 minute satisfy Formulae (1), (2), (3), and (4), Iwax (t)?0.2*100/[T½(° C.)]??Formula (1) Iwax (s)?0.26??Formula (2) Iwax (t)?0.50??Formula (3) Iwax (t)>Iwax (s)??Formula (4) wherein both Iwax(s) and Iwax(t) are obtained by a formula: absorbance derived from the wax (2850 cm?1)/absorbance derived from the binder resin (828 cm?1).
    Type: Grant
    Filed: March 16, 2007
    Date of Patent: October 18, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Mitsuyo Matsumoto, Chiyoshi Nozaki, Tsuyoshi Nozaki, Minoru Nakamura, Atsushi Yamamoto
  • Patent number: 8021814
    Abstract: A toner useful for an oilless fixing method, includes a binder resin; a colorant; and 2.0 to 4.5% by weight of a wax which is soluble in n-hexane, based on a total weight of the toner, wherein the wax is dispersed in the toner, the wax forming wax domain particles (DA) comprising wax domain particles (DS) exposed at a surface of the toner and wax domain particles (DI) encapsulated in the toner and not exposed at the surface of the toner, wherein a weight of the DS is greater than a weight of the DI, wherein the toner from which the DS have been eluted with n-hexane comprises vestigial concavities having an area of 0.01 ??m2 or more on the surface of the toner in an amount of from 1 to 7 pcs/4 ?m2, and wherein 60% or more by number of the DA having a particle diameter of 200 nm or more have a spindle or cylindrical shape having an aspect ratio of 4 or more.
    Type: Grant
    Filed: March 19, 2008
    Date of Patent: September 20, 2011
    Assignee: Ricoh Company Limited
    Inventors: Masayuki Hagi, Yoshihiro Mikuriya, Hideaki Yasunaga, Hiroaki Katoh, Kazuoki Fuwa, Yoshitaka Sekiguchi, Satoshi Ogawa, Masahide Inoue
  • Publication number: 20110223530
    Abstract: A toner is provided including a binder resin and a wax having primarily C—H and C—C bonds, and having a melting point of 50 to 90° C., wherein the wax is present in a surface portion of the toner in an amount of from 0.1 to 4.0% by weight, wherein the amount of the wax is determined by Fourier transform infrared spectroscopy attenuated total reflectance (FTIR-ATR); and the use of the toner in an image forming method, image forming apparatus, developer and toner cartridge containing the toner.
    Type: Application
    Filed: May 20, 2011
    Publication date: September 15, 2011
    Inventors: Ryota Inoue, Shigeru Emoto, Naohiro Watanabe, Masahide Yamada, Akinori Saitoh, Masahiro Ohki, Tsunemi Sugiyama, Shinichi Wakamatsu, Takayuki Yoshii, Eiji Sawamura
  • Patent number: 8017290
    Abstract: Objects of the present invention are to provide an image forming method and image forming apparatus which can secure stable toner transferability, prevent reverse transfer of the toner back to a latent image bearing member, have excellent fixing ability and produce high-quality images. The image forming method includes a one-component developing step with a toner and transferring step with an intermediate transfer member, wherein the developing step uses a developing roller having a diameter of 8 mm to 15 mm, and the toner has an adherence Fh (nN) of the toner to a flat surface satisfying the relation represented by the formula (1) and adherence Fr (mN) among the toner particles satisfying the relation represented by the formula (2): 15?Fh?50??(1) 100?Fr?400??(2).
    Type: Grant
    Filed: March 6, 2008
    Date of Patent: September 13, 2011
    Assignee: Ricoh Company, Ltd.
    Inventors: Minoru Nakamura, Akira Izutani
  • Patent number: 8007973
    Abstract: A full-color toner kit including yellow, magenta, and cyan toners each including a benzimidazolone, a naphthol, and a copper phthalocyanine colorants, respectively, and resins (A) and (B) each of which having a polyester skeleton and containing a wax, and a resin (C) having a polyester skeleton and containing no wax. Each of the toners has a softening point of from 125° C. to 135° C. The following relationships are satisfied: Ts(A)<Ts(B), Ay+5?Am?Ay+15, and Ac+5?Am?Ac+15, wherein Ts(A) and Ts(B) (° C.) each represent softening points of the resin (A) and (B), respectively, and Ay, Am, and Ac each represent ratios (% by weight) of the amount of the resin (A) to total amount of the resins (A) and (B) in the yellow, magenta, cyan toners, respectively.
    Type: Grant
    Filed: December 27, 2007
    Date of Patent: August 30, 2011
    Assignee: Ricoh Company, Limited
    Inventors: Kazuoki Fuwa, Yoshihiro Mikuriya, Masayuki Hagi, Hideaki Yasunaga, Hiroaki Katoh, Yoshitaka Sekiguchi
  • Publication number: 20110200929
    Abstract: The present invention provides an electrostatic image developing toner capable of improving the dispersibility of wax in the toner and superior in offset resistance and in storageability (heat-resistant storageability) at high temperatures, and a two-component developer which uses this electrostatic image developing toner. The electrostatic image developing toner includes: a binder resin, a colorant, and a release agent, wherein the binder resin contains a polyester resin, and a block copolymer which has a polyolefin backbone unit.
    Type: Application
    Filed: October 23, 2009
    Publication date: August 18, 2011
    Inventors: Toshihiko Karato, Masahide Yamada, Junichi Awamura, Tomomi Suzuki
  • Patent number: 7998648
    Abstract: An electrophotographic developing agent is provided that includes a binder resin, a releasing agent, a colorant, and a charge control agent. By using a binder resin having a high acid value and a mixture of two waxes having different melting points as a releasing agent, a electrophotographic developing agent is obtained, which has excellent fusing property and durability and does not result in hot offset and wrap jamming.
    Type: Grant
    Filed: January 9, 2008
    Date of Patent: August 16, 2011
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Duck-hee Lee, Sang-deok Kim, Seok-hoon Choi, Ki-won Seok
  • Patent number: 7989131
    Abstract: A toner is provided including a binder resin and a wax having primarily C—H and C—C bonds, and having a melting point of 50 to 90° C., wherein the wax is present in a surface portion of the toner in an amount of from 0.1 to 4.0% by weight, wherein the amount of the wax is determined by Fourier transform infrared spectroscopy attenuated total reflectance (FTIR-ATR); and the use of the toner in an image forming method, image forming apparatus, developer and toner cartridge containing the toner.
    Type: Grant
    Filed: September 13, 2006
    Date of Patent: August 2, 2011
    Assignee: Ricoh Company Limited
    Inventors: Ryota Inoue, Shigeru Emoto, Naohiro Watanabe, Masahide Yamada, Akinori Saitoh, Masahiro Ohki, Tsunemi Sugiyama, Shinichi Wakamatsu, Takayuki Yoshii, Eiji Sawamura
  • Publication number: 20110177442
    Abstract: The present disclosure provides processes for producing images of excellent color fidelity when incorporating a magenta toner with a lower colorant loading in addition to a first magenta toner. In embodiments, the magenta pigmented particles may be magenta emulsion aggregation toners. In accordance with the present disclosure, a pair of magenta toners are matched in color, wherein the color of a first magenta toner printed at a predetermined halftone area coverage on a substrate substantially matches the color of the solid (100%) printed patch of the second magenta toner, which is lighter than the first magenta toner, thus avoiding a visible hue shift on the print that would otherwise be objectionable.
    Type: Application
    Filed: January 19, 2010
    Publication date: July 21, 2011
    Applicant: XEROX CORPORATION
    Inventors: Daryl W. Vanbesien, Karen Ann Moffat, Yi Xin Gong, Edul N. Dalal, Jing Wang, Richard P.N. Veregin, Jordan H. Wosnick, Cuong Vong, Valerie M. Farrugia
  • Publication number: 20110177441
    Abstract: The present disclosure provides processes for producing images of excellent color fidelity when incorporating a cyan toner with a lower colorant loading in addition to a first cyan toner. In embodiments, the cyan pigmented particles may be cyan emulsion aggregation toners. In accordance with the present disclosure, a pair of cyan toners are matched in color, wherein the color of a first cyan toner printed at a predetermined halftone area coverage on a substrate substantially matches the color of the solid (100%) printed patch of the second cyan toner, which is lighter than the first cyan toner, thus avoiding a visible hue shift on the print that would otherwise be objectionable. In embodiments, the light cyan toner is color matched by adding a hue-adjusting colorant or combination of colorants which absorb wavelengths of light between 500 and 600 nanometers, and optionally adding a shade-adjusting colorant or combination of colorants which absorb wavelengths of light between 400 and 500 nanometers.
    Type: Application
    Filed: January 19, 2010
    Publication date: July 21, 2011
    Applicant: Xerox Corporation
    Inventors: Daryl W. Vanbesien, Karen Ann Moffat, Yi Xin Gong, Edul N. Dalal, Jing Wang, Richard P.N. Veregin, Jordan H. Wosnick, Cuong Vong, Valerie M. Farrugia
  • Patent number: 7972758
    Abstract: The invention provides a toner for development of an electrostatic image, which has colored particles containing a crystalline polyester resin having a melting temperature Tm1 (° C.) of approximately 50 to approximately 100° C., a non-crystalline polyester resin, and a coloring agent, the temperature Tm2 (° C.) of an endothermic peak derived from the crystalline polyester resin in a first process of raising temperature and the temperature Tm3 (° C.
    Type: Grant
    Filed: June 11, 2007
    Date of Patent: July 5, 2011
    Assignee: Fuji Xerox Co., Ltd.
    Inventor: Hirokazu Hamano
  • Publication number: 20110151369
    Abstract: Toner having good dispersibility of a pigment and a release agent therein and having excellent low temperature fixability is provided. The toner includes a binder resin, a pigment and a release agent, and the binder resin includes a graft polymer in which abietic acids and a fatty acid are grafted to a polyfunctional epoxy resin. Image is formed using such a toner.
    Type: Application
    Filed: December 22, 2010
    Publication date: June 23, 2011
    Inventors: Yasuhiro Shibai, Nobuhiro Maezawa
  • Publication number: 20110151368
    Abstract: An electrophotographic toner including a binder, a colorant and a releasing agent, and a method of preparing the electrophotographic toner.
    Type: Application
    Filed: September 15, 2010
    Publication date: June 23, 2011
    Applicant: Samsung Electronics Co., Ltd
    Inventors: Jin-mo Hong, Jae-hwan Kim, Kyeong Pang, Su-bum Park, Jeong-hyun Lee, Mi-rim Cho
  • Publication number: 20110136055
    Abstract: A toner having good dispersibility of a pigment and a release agent therein and having excellent low temperature fixability is provided. The toner includes a binder resin, a pigment and a release agent, and the binder resin includes a graft polymer in which abietic acids and an unsaturated fatty acid are grafted to a vinyl resin. An image is formed using such a toner.
    Type: Application
    Filed: December 2, 2010
    Publication date: June 9, 2011
    Inventors: Yasuhiro SHIBAI, Satoru ARIYOSHI
  • Patent number: 7955772
    Abstract: The invention relates to a dry toner, containing a platelet-type metal effect pigment or a plurality of platelet-type metal effect pigments and at least one resinous constituent, wherein the metal effect pigment or the metal effect pigments is/are additionally provided with a coating preferably suitable for improving the mechanical stability, and that this coating is additionally modified with at least one organic layer, which organic layer is selected from the group consisting of organofunctional silanes, organofunctional titanates, organofunctional zirconates, phosphonic acids, and phosphonates. The invention further relates to processes for the production of the dry toner and to the use thereof. Furthermore, the invention relates to a toner cartridge and to printed products.
    Type: Grant
    Filed: November 22, 2005
    Date of Patent: June 7, 2011
    Assignee: Eckart GmbH
    Inventors: Thomas Schuster, Hans-Jörg Kremitzl
  • Publication number: 20110129773
    Abstract: A toner including a binder resin comprising a modified polyester having an ester bond and a chemical bond other than the ester bond, and a crystalline polyester; and a release agent comprising a microcrystalline wax comprising a hydrocarbon having 20 to 80 carbon atoms which comprises 55 to 70% by weight of a linear hydrocarbon. The microcrystalline wax has an acid value of from 0.1 to 20 mgKOH/g and a melting point of from 65 to 90° C. The melting point is a temperature at which a local maximum endothermic peak is observed in a differential thermal curve measured by differential scanning calorimetry (DSC). The release agent is dispersed in the toner with a dispersion diameter of from 0.06 to 1.50 ?m.
    Type: Application
    Filed: November 3, 2010
    Publication date: June 2, 2011
    Inventors: Hyo SHU, Fumihiro Sasaki, Hiroshi Yamashita, Masaki Watanabe, Junichi Awamura, Tsuyoshi Sugimoto, Teruki Kusahara, Satoshi Ogawa, Ryota Inoue, Daisuke Inoue
  • Patent number: 7939232
    Abstract: A toner or two-component developer is obtained by mixing, aggregating, and heating resin particles, colorant particles, and wax particles in an aqueous medium. A gel permeation chromatography (GPC) measurement of the resin particles shows that a weight-average molecular weight is 10000 to 60000, and the ratio of the weight-average molecular weight to a number-average molecular weight is 1.5 to 6. The wax particles include at least a first wax and a second wax. An endothermic peak temperature (melting point Tmw1 (° C.)) of the first wax based on a DSC method is 50° C. to 90° C. An endothermic peak temperature (melting point Tmw2 (° C.)) of the second wax based on the DSC method is at least 5° C. to 50° C. higher than Tmw1. Thus, the toner can have a smaller particle size and a sharp particle size distribution without requiring a classification process, can achieve a longer life, and can suppress transfer voids or scattering during transfer.
    Type: Grant
    Filed: November 1, 2005
    Date of Patent: May 10, 2011
    Assignee: Panasonic Corporation
    Inventors: Yasuhito Yuasa, Hidekazu Arase, Masahisa Maeda
  • Publication number: 20110104605
    Abstract: The disclosure provides an electrographic toner having a core layer, which includes a binder, a colorant and two or more types of releasing agents, and a shell layer covering the core layer, and a method of preparing the same.
    Type: Application
    Filed: November 2, 2010
    Publication date: May 5, 2011
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Jae-hwan KIM, Kyeong Pang, Jin-mo Hong, Su-bum Park, Jeong-hyun Lee, Mi-rim Cho
  • Patent number: 7932011
    Abstract: An electrophotographic toner comprising a resin and a colorant, wherein: (i) a toner particle comprises a domain in the toner particle, the domain comprising a polar wax having a first polar group and a non-polar wax; and (ii) the resin contains a second polar group.
    Type: Grant
    Filed: February 24, 2006
    Date of Patent: April 26, 2011
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Takamasa Ueda, Mikio Koyama, Kazuya Isobe
  • Publication number: 20110091801
    Abstract: The present disclosure provides toners and methods for their production. In embodiments, the amount of coagulant utilized in producing those toners may be less than amounts currently in use, which may have a beneficial effect by reducing the time for coalescence. Modified waxes may also be utilized which provide excellent gloss and charging characteristics.
    Type: Application
    Filed: October 15, 2009
    Publication date: April 21, 2011
    Applicant: XEROX CORPORATION
    Inventors: Mark E. Mang, Grazyna Kmiecik-Lawrynowicz, Maura A. Sweeney, Timothy L. Lincoln
  • Publication number: 20110086304
    Abstract: The present disclosure provides toners and methods for their production. In embodiments, the toner may include a core/shell configuration, with a non-crosslinked resin and a crosslinked resin in the core, with a second non-crosslinked resin in the shell, pigment/pigments and a wax possessing both branched and linear carbons.
    Type: Application
    Filed: October 8, 2009
    Publication date: April 14, 2011
    Applicant: Xerox Corporation
    Inventors: Daniel W. Asarese, Grazyna E. Kmiecik-Lawrynowicz, Samir Kumar, Maura A. Sweeney, Siddhesh N. Pawar, Robert D. Bayley
  • Publication number: 20110086303
    Abstract: An emulsion aggregation toner composition includes toner particles including: an unsaturated polymeric resin, such as amorphous resins, crystalline resins, and combinations thereof; an optional colorant; an optional wax; an optional coagulant; and an IR absorber. The use of an IR absorber may permit formation of color toners that have uniform gloss and crease properties, i.e., the IR absorbers may prevent gloss and crease differences between color and black toners.
    Type: Application
    Filed: October 9, 2009
    Publication date: April 14, 2011
    Applicant: Xerox Corporation
    Inventors: Ke Zhou, Edward Graham Zwartz, Karen Ann Moffat, Guerino G. Sacripante
  • Publication number: 20110086302
    Abstract: An emulsion aggregation toner composition includes toner particles including: an unsaturated polymeric resin, such as amorphous resins, crystalline resins, and combinations thereof; an optional colorant; an optional wax; an optional coagulant; and an IR absorber. The use of an IR absorber may permit formation of color toners that have uniform gloss and crease properties, i.e., the IR absorbers may prevent gloss and crease differences between color and black toners.
    Type: Application
    Filed: October 9, 2009
    Publication date: April 14, 2011
    Applicant: XEROX CORPORATION
    Inventors: Ke Zhou, Edward Graham Zwartz, Karen Ann Moffat, Guerino G. Sacripante, T. Brian McAneney, Jordan H. Wosnick, Valerie M. Farrugia
  • Patent number: 7923189
    Abstract: The invention relates to hydrophobic salts of layer-like metal hydroxides, which are obtainable by adding to a layer-like metal hydroxide salt, which contains trivalent, divalent and optionally monovalent metal cations and one or more organic anions A of the formula (1) X—R—Y??(1), wherein X denotes hydrogen, hydroxyl, carboxyl, sulfato or sulfo; Y denotes carboxyl, sulfato or sulfo, and R denotes an aliphatic, cycloaliphatic, heterocycloaliphatic, olefinic, cycloolefinic, heterocycloolefinic, aromatic, heteroaromatic, araliphatic or heteroaraliphatic radical having 2 to 50 C atoms, wherein one or more substituents from the group consisting of hydroxyl, amino, halogen, C1-C22-alkyl, C1-C22-alkoxy, C1-C22-alkylene-(CO)—O—(CH2CH2O)0-50-alkyl, C1-C22-alkylene-(CO)—O—(CH2CH2O)0-50-haloalkyl, carboxyl, sulfo, nitro or cyano can be present, in dispersion, with intensive thorough mixing, one or more hydrophobic compounds from the group consisting of waxes and metal soaps in an amount of from 0.2 to 200 wt.
    Type: Grant
    Filed: May 6, 2005
    Date of Patent: April 12, 2011
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventor: Eduard Michel
  • Patent number: 7923190
    Abstract: In a toner containing at least a binder resin, a colorant, an ester compound and a low-melting material, the ester compound is an ester of dipentaerythritol with a carboxylic acid having 18 or more to 25 or less carbon atoms, and, where the melting point of the ester compound is represented by Tm(A) (° C.) and the melting point of the low-melting material is represented by Tm(B) (° C.), the toner satisfies the relationship of: Tm(B)?Tm(A)+5.
    Type: Grant
    Filed: October 13, 2009
    Date of Patent: April 12, 2011
    Assignee: Canon Kabushiki Kaisha
    Inventors: Michihisa Magome, Tadashi Dojo, Eriko Yanase, Takashi Matsui, Tomohisa Sano, Akira Sakakibara, Shuichi Hiroko
  • Patent number: 7914963
    Abstract: The present invention is a toner that includes a polymeric binder and a polyethylene wax or ester wax. A dispersing agent of poly(ethylene vinyl acetate) is included in the toner that dispersed the wax and reduces the amount of free wax particles.
    Type: Grant
    Filed: December 12, 2007
    Date of Patent: March 29, 2011
    Assignee: Eastman Kodak Company
    Inventors: Robert D. Fields, Charles T. Havens, Peter S. Alexandrovich, Dinesh Tyagi
  • Patent number: 7910275
    Abstract: Embodiments include a chemical toner composition having a first resin including a styrene vinyl copolymer and having a Tg of from about 46 to about 56° C., b) a second resin including a styrene vinyl copolymer having a Tg of from about 55 to about 65° C., c) a distilled wax having a heat of crystallization and a heat of enthalpy, both from about 1.0 to about 4.0 J/g for every weight percent of the wax used in the chemical toner composition, and wherein the wax has a peak melting point of from about 70 to about 99° C., and d) a colorant, wherein the chemical toner has a gloss of from about 30 to about 80 GGU.
    Type: Grant
    Filed: November 14, 2005
    Date of Patent: March 22, 2011
    Assignee: Xerox Corporation
    Inventors: Raj D. Patel, David J. Sanders, Christine Anderson, Allan K. Chen, Daryl W. Vanbesien, Patricia A. Burns
  • Patent number: 7910276
    Abstract: Disclosed herein are emulsion aggregation toner particles having less than about 15 atomic percent oxygen in relation to a total atomic percent of 100 for all elements on the surface thereof. Such toner particles exhibit lower marks on print defects.
    Type: Grant
    Filed: July 12, 2007
    Date of Patent: March 22, 2011
    Assignee: Xerox Corporation
    Inventors: Karen A. Moffat, Juan A. Morales-Tirado, Thomas P. Debies, William H. Hollenbaugh, Jr., Emily L. Moore, Nancy S. Hunt
  • Publication number: 20110065038
    Abstract: Processes for producing emulsion aggregation toners are provided. In embodiments, methods of the present disclosure may be utilized to produce toners suitable for low melt applications, including use in flexible packaging applications, where low pile height is desired for low cost and flexibility. In embodiments, the EA toners may include small particles having a shell with a high amount of resin, which optimizes the charging characteristics of the toner.
    Type: Application
    Filed: September 15, 2009
    Publication date: March 17, 2011
    Applicant: XEROX CORPORATION
    Inventors: Guerino G. Sacripante, Maria Jimena Loureiro, Cuong Vong, Richard P.N. Veregin, Michael S. Hawkins, Edward Graham Zwartz
  • Publication number: 20110033793
    Abstract: Toners are provided which may be suitable for use in cold fusing pressure apparatus. The toners include low molecular weight amorphous resins having low softening points and low molecular weights, compared with resins utilized in conventional emulsion aggregation toners for low melt fusing applications.
    Type: Application
    Filed: August 4, 2009
    Publication date: February 10, 2011
    Applicant: XEROX CORPORATION
    Inventors: Allan K. Chen, Guerino G. Sacripante
  • Publication number: 20110020745
    Abstract: The present invention relates to, in the toner including toner particles having a biding agent resin, colorings and a release agent, an electrostatic image developing toner, its composition, and a preparation method thereof. The electrostatic image developing toner is prepared by the method comprising: (1) preparing an inorganic dispersion medium; (2) dispersing/dissolving a polymerizable monomer mixture; (3) micronizing the liquid obtained in step (2) in the liquid obtained in step (1) with high shear force in order to create droplets; (4) performing radical polymerization of the micronized droplets obtained in step (3); (5) aggregating particles obtained in step (4); (6) fusing the aggregate obtained in step (5); (7) cleaning and drying the toner obtained by step (6); and (8) adding additives to impart electrification and fluidity to a toner obtained by step (7).
    Type: Application
    Filed: March 12, 2009
    Publication date: January 27, 2011
    Inventors: Jae-Goang Yu, Ho-Geun Jo
  • Publication number: 20110008722
    Abstract: Toners are provided which include a resin including at least one baroplastic polymer. The baroplastic polymer, in embodiments, may be a block copolymer with discrete low glass transition temperature (Tg) domains and high Tg domains that plasticize one another at ambient temperature when subjected to pressures of from about 500 psi (about 3.45 MPa) to about 10,000 psi (about 69 MPa), enabling them to be extruded and molded without heat. The resulting polymers, in turn, may then be utilized to form toners.
    Type: Application
    Filed: July 10, 2009
    Publication date: January 13, 2011
    Applicant: XEROX CORPORATION
    Inventors: Jordan H. Wosnick, Karen Ann Moffat
  • Patent number: 7862971
    Abstract: An emulsion aggregation toner having toner particles comprising a gel latex, a high Tg latex and at least one wax, wherein the toner fuses at about 170° C. to about 220° C. at process speeds of from about 560 mm/s to about 870 mm/s, wherein the toner exhibits a crease fix property of less than about 60 and a half-toner rub fix property of less than about 0.15. The toner exhibits excellent half-tone rub fix performance and crease fix at high print speeds.
    Type: Grant
    Filed: January 31, 2007
    Date of Patent: January 4, 2011
    Assignee: Xerox Corporation
    Inventors: Karen A. Moffat, Edward G. Zwartz, T. Brian McAneney, Fernando P. Yulo
  • Patent number: 7858280
    Abstract: A toner formed of a toner composition containing a resin and a plasticizer, wherein the following relationships (1) and (2) are satisfied: Tg2r>Tg2t??(1), and Tg1t?Tg2t>Tg1r?Tg2r??(2), wherein Tg1r represents the peak of the resin for the first temperature rise and Tg2r represents the peak of the resin for the second temperature rise when a differential scanning calorimeter (DSC) measurement is performed for the resin, Tg1t represents the peak of the toner comprising the resin for the first temperature rise and Tg2t represents the peak of the toner comprising the resin for the second temperature rise when a differential scanning calorimeter (DSC) measurement is performed for the toner.
    Type: Grant
    Filed: January 26, 2006
    Date of Patent: December 28, 2010
    Assignee: Ricoh Company, Ltd.
    Inventors: Tsuyoshi Sugimoto, Hiroshi Yamashita, Hiroto Higuchi
  • Publication number: 20100310980
    Abstract: A toner, including a colorant; a binder resin; a release agent; and a fixing supplemental component, wherein the toner has a storage elastic modulus G? (Pa) satisfying the following conditions: 5.0×104<G?<5.0×105 at 80° C. 1.0×104<G?<1.0×105 at 90° C. 5.0×103<G?<5.0×104 at 100° C. 1.0×103<G?<1.0×104 at 120° C. 1.0×103<G?<1.0×104 at 150° C.
    Type: Application
    Filed: May 11, 2010
    Publication date: December 9, 2010
    Inventors: Tsuyoshi Sugimoto, Naohito Shimota, Hiroshi Yamashita, Satoshi Ogawa, Masana Shiba, Junichi Awamura, Tsuneyasu Nagatomo, Masaki Watanabe
  • Publication number: 20100297546
    Abstract: Toner particles are provided which may, in embodiments, include a core and a shell. In embodiments, charge control agents may be co-emulsified with a resin utilized to form a shell. The shell may prevent a crystalline resin in the core from migrating to the toner surface. Inclusion of the charge control agent in the shell itself may provide the resulting toner particles with desirable charge characteristics and sensitivity to relative humidity.
    Type: Application
    Filed: May 20, 2009
    Publication date: November 25, 2010
    Applicant: Xerox Corporation
    Inventors: Ke Zhou, Maria N.V. McDougall, Karen A. Moffat, Richard P.N Veregin, Enno E. Agur
  • Publication number: 20100291481
    Abstract: A toner including: a binder resin containing at least a polyester resin (A) and a polyester resin (B) as main components; a colorant; a release agent; and a graft polymer containing a polyolefin resin and a vinyl resin, wherein the polyester resin (A) is a condensation product resulting from condensation polymerization between an alcohol component containing a dihydric alcohol compound, and a carboxylic acid component containing a rosin compound, and the rosin compound occupies 5% by mass or more of the total amount of the alcohol component and the carboxylic acid component, and wherein the polyester resin (B) is a condensation product resulting from condensation polymerization between an alcohol component containing a dihydric alcohol compound which includes at least an alkylene oxide adduct of a bisphenol compound represented by General Formula (1) below, and a carboxylic acid component:
    Type: Application
    Filed: May 11, 2010
    Publication date: November 18, 2010
    Inventors: Saori YAMADA, Hisashi Nakajima, Shinya Nakayama, Yohichiroh Watanabe
  • Patent number: 7816063
    Abstract: The present invention relates to a toner which has good property such as fixability, coloring power, developability, durability, and environmental stability and so on. More specifically, the present invention relates to a color toner containing at least a binder resin, a colorant, and a wax, in which: a wax concentration of an extract obtained by dispersing the toner into n-hexane at a concentration of 15 mg/cm3 at 23° C. and by subjecting the resultant dispersion to extraction treatment at 23° C. for 1 minute is in the range of 0.080 to 0.500 mg/cm3; an average circularity of particles each having a circle-equivalent diameter of 3 ?m or more in the toner is in the range of 0.925 to 0.965; and a content of the wax is in the range of 1 to 15 parts by mass with respect to 100 parts by mass of the binder resin.
    Type: Grant
    Filed: February 6, 2009
    Date of Patent: October 19, 2010
    Assignee: Canon Kabushiki Kaisha
    Inventors: Akira Hashimoto, Yojiro Hotta, Wakashi Iida, Kazuhiko Hayami, Hirohide Tanikawa, Yasuhiro Ichikawa
  • Patent number: 7799500
    Abstract: Disclosed is an electrophotographic image forming method which comprises steps of forming a toner image on an image support, fixing the toner image on the image support in a fixing nip section of a fixing device employing a contact heating system and the toner contains a first releasing agent, a dynamic viscosity of the first releasing agent is 4-20 mm2/sec; and a fixing temperature in the fixing nip section of the fixing device is 75-100° C. higher than a melting point of the first releasing agent.
    Type: Grant
    Filed: November 21, 2006
    Date of Patent: September 21, 2010
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Makoto Kobayashi, Shingo Fujimoto, Takao Yamanouchi, Kazuya Isobe, Hirofumi Koga
  • Patent number: 7785760
    Abstract: A toner is provided including a binder resin, a colorant, and a release agent, which has a volume average particle diameter (Dv) of from 3 to 9 ?m, and wherein the binder resin and the release agent form a sea-island structure in which the island formed of the release agent is dispersed in the sea formed of the binder resin in a cross-sectional image of the toner obtained by a transmission electron microscope (TEM), and the following relationships are satisfied: IB>IA and IB>IC, wherein each of IA, IB, and IC represents an area ratio (%) of the island in an outermost region (A) of the cross-sectional image of the toner, an intermediate region (B) thereof located under the outermost region (A), and an innermost region (C) thereof located under the intermediate region (B); and a method of preparing the toner.
    Type: Grant
    Filed: January 18, 2007
    Date of Patent: August 31, 2010
    Assignee: Ricoh Company Limited
    Inventors: Atsushi Yamamoto, Chiyoshi Nozaki, Tsuyoshi Nozaki, Minoru Nakamura, Yoshimichi Ishikawa
  • Publication number: 20100203439
    Abstract: Environmentally friendly toner particles are provided which may, in embodiments, include a bio-based amorphous polyester resin, optionally in combination with another amorphous resin and/or a crystalline resin. Toner particles may, in embodiments, have a core-shell configuration, with the shell formed of the bio-based amorphous polyester resin, the amorphous polyester resin, the crystalline polyester resin, or combinations thereof.
    Type: Application
    Filed: February 6, 2009
    Publication date: August 12, 2010
    Applicant: Xerox Corporation
    Inventors: Ke Zhou, Richard P.N. Veregin, Gwynne McAneney-Lannen, Edward G. Zwartz, Maria N.V. McDougall, Guerino Sacripante, Karen A. Moffat