Hydrocarbon Wax-containing Adjuvant Patents (Class 430/108.8)
  • Publication number: 20080261140
    Abstract: An electrophotographic developing agent is provided that includes a binder resin, a releasing agent, a colorant, and a charge control agent. By using a binder resin having a high acid value and a mixture of two waxes having different melting points as a releasing agent, a electrophotographic developing agent is obtained, which has excellent fusing property and durability and does not result in hot offset and wrap jamming.
    Type: Application
    Filed: January 9, 2008
    Publication date: October 23, 2008
    Inventors: Duck-hee Lee, Sang-deok Kim, Seok-hoon Choi, Ki-won Seok
  • Patent number: 7432030
    Abstract: A toner for developing an electrostatic latent image includes a binder resin, a colorant and a releasing agent. The releasing agent contains a hydrocarbon component including a linear hydrocarbon component, and the liner hydrocarbon component has a carbon number distribution and an average carbon number N. An amount of a component having a carbon number of from N?4 to N+4 in the releasing agent is 80% by mass or more based on the total mass of the hydrocarbon component of the releasing agent. An amount of a component having a carbon number of N?10 or less in the releasing agent is 0.05% by mass or less based on the total mass of the hydrocarbon component of the releasing agent, and an amount of a component having a carbon number of N+10 or more in the releasing agent is 0.05% by mass or less based on the total mass of the hydrocarbon component of the releasing agent.
    Type: Grant
    Filed: March 15, 2005
    Date of Patent: October 7, 2008
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yosuke Tsurumi, Akira Matsumoto, Mayuko Uda, Hiroshi Nakazawa, Kazufumi Tomita
  • Publication number: 20080233506
    Abstract: A toner useful for an oilless fixing method, includes a binder resin; a colorant; and 2.0 to 4.5% by weight of a wax which is soluble in n-hexane, based on a total weight of the toner, wherein the wax is dispersed in the toner, the wax forming wax domain particles (DA) comprising wax domain particles (DS) exposed at a surface of the toner and wax domain particles (DI) encapsulated in the toner and not exposed at the surface of the toner, wherein a weight of the DS is greater than a weight of the DI, wherein the toner from which the DS have been eluted with n-hexane comprises vestigial concavities having an area of 0.01 ??m2 or more on the surface of the toner in an amount of from 1 to 7 pcs/4 ?m2, and wherein 60% or more by number of the DA having a particle diameter of 200 nm or more have a spindle or cylindrical shape having an aspect ratio of 4 or more.
    Type: Application
    Filed: March 19, 2008
    Publication date: September 25, 2008
    Inventors: Masayuki Hagi, Yoshihiro Mikuriya, Hideaki Yasunaga, Hiroaki Katoh, Kazuoki Fuwa, Yoshitaka Sekiguchi, Satoshi Ogawa, Masahide Inoue
  • Publication number: 20080220357
    Abstract: A toner including a binder resin including a polyester resin and a vinyl resin; a wax; and a colorant, wherein the vinyl resin includes a unit obtained from a radically polymerizable monomer having an alkyloxysilyl group. An image forming apparatus including an image bearing member configured to bear an electrostatic image thereon; a developing device configured to develop the electrostatic image with a developer including the toner to form a toner image on the image bearing member; and a transfer device configured to transfer the toner image onto a receiving material. A process cartridge including an image bearing member; and a developing device configured to develop an electrostatic image on the image bearing member with a developer including the toner, wherein the process cartridge is detachably attached to an image forming apparatus as a unit.
    Type: Application
    Filed: February 5, 2008
    Publication date: September 11, 2008
    Inventors: Chiyoshi Nozaki, Takuya Kadota, Katsunori Kurose, Mitsuyo Matsumoto, Tsuyoshi Nozaki, Yoshimichi Ishikawa, Atsushi Yamamoto, Hiroyuki Murakami
  • Patent number: 7413842
    Abstract: A toner process comprising aggregating or coagulating a latex emulsion comprising a resin, a colorant and wax particles using an amount of polymetal ion coagulant to provide core particles; heating the core particles to provide micron size aggregates; optionally adding a second resin emulsion; adding a sequestering or complexing component and a base to remove the polymetal ion in a controlled manner; further heating the mixture to provide toner particles; and optionally, isolating the toner particles.
    Type: Grant
    Filed: August 22, 2005
    Date of Patent: August 19, 2008
    Assignee: Xerox Corporation
    Inventors: Daryl Vanbesien, David J. Sanders, Raj D. Patel, Christine D. Anderson, Patricia Ann Burns, Nam-Suk Ro
  • Patent number: 7413841
    Abstract: Toner includes aggregated particles including at least resin particles, pigment particles, and wax particles. A fused film of the resin is formed on the surface of the toner. The wax is at least one selected from A: ester wax that has an iodine value of not more than 25, a saponification value of 30 to 300, and an endothermic peak temperature (melting point) of 50° C. to 100° C. based on a DSC method; and B: wax that is obtained by a reaction of alkyl alcohol having a carbon number of 4 to 30, unsaturated polycarboxylic acid or its anhydride, and unsaturated hydrocarbon wax and has an acid value of 1 to 80 mgKOH/g and an endothermic peak temperature (melted point) of 50° C. to 120° C. based on the DSC method.
    Type: Grant
    Filed: January 16, 2004
    Date of Patent: August 19, 2008
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventor: Yasuhito Yuasa
  • Patent number: 7407732
    Abstract: An object of the invention is to provide a black toner that can satisfy further the requirement for low energy, high-speed and high performance, a color toner that can be used in an image forming apparatus provided with an oil-less fixation device, and a color toner including the black toner and the color toner. For the black toner, a polyester resin having an acid value of 7 to 20 mgKOH/g is used as the binding resin, and a carboxylic acid-modified paraffin wax having an acid value of 4 to 30 mgKOH/g is used as the wax. For the color toner, polyester resin having an acid value of 7 to 20 mgKOH/g is used as the binding resin, and a carboxylic acid-modified paraffin wax having an acid value of 6 to 25 mgKOH/g is used as the wax.
    Type: Grant
    Filed: June 20, 2003
    Date of Patent: August 5, 2008
    Assignee: Sharp Kabushiki Kaisha
    Inventors: Satoshi Ogawa, Masahiko Kubo, Tadayuki Sawai, Kouji Kida
  • Publication number: 20080182191
    Abstract: An emulsion aggregation toner having toner particles comprising a gel latex, a high Tg latex and at least one wax, wherein the toner fuses at about 170° C. to about 220° C. at process speeds of from about 560 mm/s to about 870 mm/s, wherein the toner exhibits a crease fix property of less than about 60 and a half-toner rub fix property of less than about 0.15. The toner exhibits excellent half-tone rub fix performance and crease fix at high print speeds.
    Type: Application
    Filed: January 31, 2007
    Publication date: July 31, 2008
    Applicant: XEROX CORPORATION
    Inventors: Karen A. MOFFAT, Edward G. ZWARTZ, T. Brian MCANENEY, Fernando P. YULO
  • Publication number: 20080166649
    Abstract: A toner composition having toner particles comprising a gel latex, a high Tg latex, a wax, and a colorant. The gel latex is present in an amount of from about 3 weight percent to about 30 weight percent of the toner composition, the high Tg latex is present in an amount of from about 50 weight percent to about 95 weight percent of the toner composition, the wax is present in an amount of from about 2 weight percent to about 40 weight percent of the toner composition, and the colorant is present in an amount of from about 1 weight percent to about 25 weight percent of the toner composition.
    Type: Application
    Filed: December 13, 2006
    Publication date: July 10, 2008
    Applicant: Xerox Corporation
    Inventors: Karen A. Moffat, Emily L. Moore, Daryl W. Vanbesien, Shigang S. Qiu, Vladislav Skorokhod, Edward G. Zwartz, Juan A. Morales-Tirado, William H. Hollenbaugh
  • Publication number: 20080153018
    Abstract: A non-magnetic toner, including a binder resin; a wax present dispersing in the toner in the shape of a particle; and a colorant, wherein the wax having a particle diameter not less than 2.0 ?m and less than 3.0 ?m is not less than 20% and less than 40% by number based on total number thereof; the wax has a mode value not less than 1.5 ?m and less than 2.0 ?m in a frequency distribution of 0.1 ?m width; and the following relationship is satisfied: 45<XZ/Y<62 wherein X represents a softening point (° C.) of the toner; Y represents a volume-average particle diameter (?m) of the toner; and Z represents a total parts by weight of the wax included in 100 parts by weight of the toner.
    Type: Application
    Filed: December 21, 2007
    Publication date: June 26, 2008
    Inventors: Yoshihiro MIKURIYA, Hideaki Yasunaga, Hiroaki Katoh, Kazuoki Fuwa, Masayuki Hagi, Masahide Inous
  • Patent number: 7389082
    Abstract: An image forming method including the steps of a) forming a mirror image by a toner on a transparent substrate, and b) laminating the toner image carrying surface of the transparent substrate with a light reflecting material through a tacking layer or an adhering layer.
    Type: Grant
    Filed: August 22, 2005
    Date of Patent: June 17, 2008
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventor: Yukio Okamoto
  • Publication number: 20080124142
    Abstract: This is an electrophotographic marking system with the ability to minimize adherence of a marking composition to a fixing component in the system, such as a fuser roll. In this manner, offset is avoided and a better image results on the paper or receiving medium. This is accomplished by using a substituted polyolefin as a release agent that is coated on the surface of the fuser roll.
    Type: Application
    Filed: June 19, 2006
    Publication date: May 29, 2008
    Inventors: David J. Gervasi, Santokh S. Badesha
  • Patent number: 7364827
    Abstract: An electrophotographic toner comprising a resin, a colorant and a release agent which comprises a first wax and a second wax, wherein: (i) the first wax exhibits: an endothermic peak appearing in the range 75-100° C., a peak width at half height of the endothermic peak of 10-40° C., an exothermic peak appearing in the range 70-100° C. and a peak width at half height of the exothermic peak of 10-40° C., in a DSC measurement; (ii) the second wax exhibits: an endothermic peak appearing in the range 60-90° C., a peak width at half height of the endothermic peak of 5° C. or less, an exothermic peak appearing in the range 55-80° C. and a peak width at half height of the exothermic peak of 5° C. or less, in the DSC measurement; (iii) a weight ratio of the first wax to the second wax is between 9:1 and 2:8; and (iv) the resin contains a polar group.
    Type: Grant
    Filed: December 8, 2005
    Date of Patent: April 29, 2008
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Takamasa Ueda, Kazuya Isobe
  • Publication number: 20080090163
    Abstract: A process for preparing a toner, includes solvent flashing wax and resin together to emulsify the resin and wax to a sub-micro size; mixing the wax and resin emulsion with a colorant, and optionally a coagulant to form a mixture; heating the mixture at a temperature below a glass transition temperature of the resin to aggregate the resin, colorant, and wax, to form aggregated particles; heating the aggregated particles and coalescent agent at a temperature above the glass transition temperature of said resin, to coalesce the aggregated particles to form toner particles, optionally cooling the mixture; and isolating the toner particles.
    Type: Application
    Filed: October 13, 2006
    Publication date: April 17, 2008
    Applicant: XEROX CORPORATION
    Inventors: Enno E. AGUR, Guerino G. SACRIPANTE, Michael S. HAWKINS, Edward G. ZWARTZ
  • Patent number: 7354687
    Abstract: Dry electrographic toner compositions are provided comprising a plurality of dry toner particles, wherein the toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions. The dry electrographic toner composition comprises a wax associated with the dry toner particles, wherein substantially all of the wax is associated with the toner particle at the surface thereof. Methods of making electrographic toner compositions are also provided comprising preparing polymeric binder particles comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions, preparing toner particles, drying the toner particles, and milling the dry toner particles in the presence of a wax component to provide a dry toner particle composition having the wax associated with the toner particles.
    Type: Grant
    Filed: October 31, 2004
    Date of Patent: April 8, 2008
    Assignee: Samsung Electronics Company
    Inventors: Leonard Stulc, Ronald J. Moudry, Zbigniew Tokarski, Charles W. Simpson, Gay L. Herman, A. Kristine Fordahl, James A. Baker
  • Patent number: 7351509
    Abstract: A toner is disclosed including toner particles containing a binder resin and a colorant. The binder resin contains a vinyl resin. In the high-temperature GPC-RALLS-viscometer analysis of the o-dichlorobenzene-soluble matter of the toner, a weight-average molecular weigh of absolute molecular weights measured with a viscosity detector is in a specific range. In the o-dichlorobenzene-soluble matter, a component with the absolute molecular weight of 10,000 or less and a component with the absolute molecular weight of 1,000,000 or more are present in specific proportions, respectively. The intrinsic viscosity of the toner is in a specific range.
    Type: Grant
    Filed: December 17, 2004
    Date of Patent: April 1, 2008
    Assignee: Canon Kabushiki Kaisha
    Inventors: Shuhei Moribe, Nobuyuki Okubo, Tsutomu Onuma, Shinichiro Abe, Koji Nishikawa
  • Patent number: 7344813
    Abstract: A toner includes particles of a resin, an optional colorant, a first wax and a second wax, where the toner particles are prepared by an emulsion aggregation process. Additional waxes can also be added for different properties.
    Type: Grant
    Filed: May 5, 2005
    Date of Patent: March 18, 2008
    Assignee: Xerox Corporation
    Inventors: Maura A. Sweeney, Grazyna E. Kmiecik-Lawrynowicz, Matthew L. Fabrizio, Robert D. Bayley, Karen A. Moffat, David J. Sanders, Enno E. Agur, Daryl W. Vanbesien
  • Publication number: 20080063965
    Abstract: A process for preparing a toner includes mixing a polymeric resin emulsion, a colorant dispersion, and a wax to form a mixture; optionally adding a coagulant to the mixture; heating the mixture at a temperature below a glass transition temperature of the polymeric resing to aggregate the polymeric resin, colorant, and wax, to form aggregated particles; and adding a coalescent agent to the aggregated particles; heating the aggregated particles and coalescent agent at a temperature above the glass transition temperature of the polymeric resin, to coalesce the aggregated particles to form toner particles, optionally cooling the mixture, and isolating the tone particles.
    Type: Application
    Filed: September 8, 2006
    Publication date: March 13, 2008
    Applicant: Xerox Corporation
    Inventors: Zhen Lai, Richard Fong, Yuhua Tong, Chieh-Min Cheng, Amy A. Grillo, Paul F. Smith, Paul J. Gerroir, Beng S. Ong
  • Patent number: 7326507
    Abstract: The present invention relates to a toner and process for preparing a toner for reproduction of a metallic, preferably golden or silvery, hue by a printing process, especially for electrophotography. A congeneric process and/or a congeneric toner is preserved with regard to its metallic hue and at the same time not to impair the essential properties of the toner for the printing process in which it is to be used. At least one metallic pigment is provided with a coating of silicate and subsequently with an organic layer and combining the thus obtained particle with toner material.
    Type: Grant
    Filed: January 26, 2005
    Date of Patent: February 5, 2008
    Assignee: Eastman Kodak Company
    Inventors: Detlef Schulze-Hagenest, Udo Dräger, Dinesh Tyagi
  • Patent number: 7320850
    Abstract: A magenta toner is provided which contains at least a binder resin, a colorant, and a wax, in which a maximum heat-absorption peak temperature as measured using a differential scanning calorimeter, a reflectance at a predetermined wavelength when measured in a powder state by spectroscopic analysis, and lightness when measured in a powder form are in specific ranges. A full-color image is formed using the magenta toner as a pale magenta toner in combination with a deep magenta toner. According to the present invention, it becomes possible to form a vivid image which has reduced graininess and roughness from a low-density region to a high-density region, ensures a sufficient fixing temperature region, has a color reproduction range wider that the conventional one, and has high transparency on an OHP sheet.
    Type: Grant
    Filed: July 14, 2004
    Date of Patent: January 22, 2008
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takayuki Itakura, Yuko Sato, Hiroyuki Fujikawa, Nobuyoshi Sugahara, Hirohide Tanikawa
  • Patent number: 7309553
    Abstract: An oilless toner including at least (A) a cyclic olefin resin; (B) a resin having one or more carbon-carbon double bonds therein; and (C) a wax.
    Type: Grant
    Filed: July 23, 2002
    Date of Patent: December 18, 2007
    Assignee: Ricoh Company Limited
    Inventors: Kunihiko Tomita, Naoki Iwata
  • Patent number: 7306886
    Abstract: Dry electrographic toner compositions are provided comprising a plurality of dry toner particles, wherein the toner particles comprise polymeric binder comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions. The dry electrographic toner composition comprises a wax associated with the dry toner particles, wherein a substantial portion of the wax is entrained in the toner particle and a substantial portion of the wax is associated with the toner particle at the surface thereof. Methods of making electrographic toner compositions are also provided comprising preparing polymeric binder particles comprising at least one amphipathic copolymer comprising one or more S material portions and one or more D material portions, and milling the particles before or after formulation as toner particles with wax in the liquid carrier prior to drying to form the dry toner composition.
    Type: Grant
    Filed: October 31, 2004
    Date of Patent: December 11, 2007
    Assignee: Samsung Electronics Company
    Inventors: Gay L. Herman, Ronald J. Moudry, Zbigniew Tokarski, Charles W. Simpson, Leonard Stulc, A. Kristine Fordahl, James A. Baker
  • Patent number: 7300735
    Abstract: An electrophotographic toner contains a resin, a colorant and a releasing agent. The releasing agent has a solidifying point of from 79° C. to 109° C., and one peak in an endothermic curve measured by a differential scanning calorimeter. A difference between temperature to give a maximum endothermic peak of the releasing agent and an end-set temperature of the releasing agent is within 10° C. A melt viscosity of the releasing agent at 110° C. is in a range of from 4 mPa·s to 9 mPa·s. The releasing agent in one particle of the toner forms 3 or more domains. Domains having a ratio of a major axis to a minor axis which is in a range of from 5 to 15 occupy 90% or more by number based on the total number of domains.
    Type: Grant
    Filed: August 31, 2004
    Date of Patent: November 27, 2007
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yosuke Tsurumi, Hiroshi Nakazawa, Kazufumi Tomita, Shuji Sato, Akira Matsumoto
  • Patent number: 7291434
    Abstract: The present invention provides a toner for electrostatically charged image development comprising at least a binder resin, a colorant and a releasing agent. The releasing agent satisfies the following equations (1) and (2): 0.1??*a?1.0??(1) 1.1??*b/?*a?3.5??(2) wherein ?*a represents a complex viscosity (Pa·s) determined from a first dynamic viscoelasticity measurement at a measuring frequency of the releasing agent of 6.28 rad/s, ?*b represents a complex viscosity (Pa·s) determined from a second dynamic viscoelasticity measurement at a measuring frequency of the releasing agent of 62.8 rad/s, and each of the first and second dynamic viscoelasticities is measured in a temperature range from a temperature that is 15° C. lower than the melting point of the releasing agent to a temperature that is 15° C. higher than the melting point of the releasing agent.
    Type: Grant
    Filed: June 18, 2004
    Date of Patent: November 6, 2007
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Takao Ishiyama, Masakazu Iijima, Tomohito Nakajima, Satoshi Yoshida, Eisuke Iwazaki
  • Patent number: 7286781
    Abstract: A toner for developing a latent image includes, at least, a binder resin, a releasing agent, a coloring agent and a fluidizing agent. A melting point Tw of the releasing agent is higher than or equals to a softening temperature Ts of the developer measured by a capillary rheometer of a constant shear stress type. The melting point Tw of the releasing agent is lower than or equals to a melting temperature Tm of the developer measured by ½ method. Using the above described toner, it becomes possible to print a full color image at a high speed without causing an offset phenomena or sheet jam.
    Type: Grant
    Filed: July 25, 2005
    Date of Patent: October 23, 2007
    Assignee: Oki Data Corporation
    Inventor: Kenji Koido
  • Patent number: 7267919
    Abstract: A toner of the present invention comprises at least a binder resin comprising as a main component a polyester resin, a wax, and a colorant, in which in case of measuring a wettability of the toner with respect to a mixed solvent of methanol and water in terms of an optical transimittance at an optical wavelength of 780 nm, a methanol concentration of the mixed solvent is in a range of 45 to 65% by volume when an optical transmittance is 80% and 10%, respectively; a melt index (MI) is of 0.1 to 10 g/10 min at a temperature of 125° C.
    Type: Grant
    Filed: March 20, 2006
    Date of Patent: September 11, 2007
    Assignee: Canon Kabushiki Kaisha
    Inventors: Syuhei Moribe, Hiroshi Yusa, Takashige Kasuya, Yoshihiro Ogawa
  • Patent number: 7267920
    Abstract: The present invention provides a toner for developing an electrostatic latent image comprising of: toner particles containing at least a binder resin, a colorant and a releasing agent; wherein a volume-average particle diameter of the toner particles is in a range of about 5 to 8 ?m; an average of shape factor SF1 of the toner particles is in a range of about 125 to 140; and an arithmetical mean undulation height of the surface of the toner particles at the 90% point on the cumulative distribution curve is in a range of about 0.15 to 0.25 ?m. Further, the present invention provides an electrostatic latent image developer containing the toner. The invention also provides a method for producing the toner.
    Type: Grant
    Filed: September 9, 2004
    Date of Patent: September 11, 2007
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Hiroshi Nakazawa, Yutaka Sugizaki, Kazufumi Tomita, Shuji Sato, Akira Matsumoto, Yosuke Tsurumi, Masanobu Ninomiya, Takao Ishiyama
  • Publication number: 20070190442
    Abstract: A toner is provided prepared by a wet granulation method, comprising a binder resin and a colorant, wherein the toner adsorbs ammonia (NH3) in an amount of from 70 to 400 ?mol/m2 per unit of specific surface area and carbon dioxide (CO2) in an amount of not greater than 10 ?mol/m2 per unit of specific surface area.
    Type: Application
    Filed: February 13, 2007
    Publication date: August 16, 2007
    Inventors: Minoru NAKAMURA, Chiyoshi Nozaki, Tsuyoshi Nozaki, Atsushi Yamamoto
  • Publication number: 20070184374
    Abstract: An electrophotographic toner is disclosed, comprising a binding resin, a colorant and a releasing agent, wherein the releasing agent comprises a first releasing agent component and a second releasing agent component, the first releasing agent component is a straight chain hydrocarbon compound exhibiting a melting point of 50 to 100° C. and the second releasing agent component is a branched hydrocarbon compound exhibiting a melting point of 50 to 100° C., and the second releasing agent component accounting for 5% to 90% by mass of the total amount of the first and second releasing agent components.
    Type: Application
    Filed: January 23, 2007
    Publication date: August 9, 2007
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Shiro HIRANO, Yoshiyasu MATSUMOTO, Masaaki KONDO, Junya ONISHI, Aya SHIRAI
  • Patent number: 7252914
    Abstract: A toner for electrophotography fulfilling both the fixability and the void resistance at high level, and forms a high-quality image. The toner for electrophotography contains: a binder resin; and a wax component which contains: a first wax having an endothermic peak in a temperature region of 60 to 90° C., the endothermic peak occurring in the temperature-rising stage of a DSC curve determined by a differential scanning calorimeter, and having a molecular weight distribution (weight-average molecular weight (Mw)/number-average molecular weight (Mn)) of 1.5 or less, and substantially not containing a component having 500 Mw or less; and at least any of a second wax having an endothermic peak in a temperature region of 100 to 150° C. and the molecular weight distribution of 5 to 20; and a third wax having an endothermic peak in a temperature region of 150 to 170° C. and the molecular weight distribution of 1.1 or more.
    Type: Grant
    Filed: October 24, 2002
    Date of Patent: August 7, 2007
    Assignee: Fuji Xerox Co., Ltd.
    Inventors: Yasushige Nakamura, Tomoaki Tanaka, Seijiro Ishimaru, Sadaaki Yoshida, Yoshimichi Katagiri
  • Publication number: 20070178399
    Abstract: Disclosed is an electrophotographic image forming method which comprises steps of forming a toner image on an image support, fixing the toner image on the image support in a fixing nip section of a fixing device employing a contact heating system and the toner contains a first releasing agent, a dynamic viscosity of the first releasing agent is 4-20 mm2/sec; and a fixing temperature in the fixing nip section of the fixing device is 75-100° C. higher than a melting point of the first releasing agent.
    Type: Application
    Filed: November 21, 2006
    Publication date: August 2, 2007
    Inventors: Makoto Kobayashi, Shingo Fujimoto, Takao Yamanouchi, Kazuya Isobe, Hirofumi Koga
  • Publication number: 20070178397
    Abstract: An electrophotographic toner is disclosed, comprising a binding resin, a colorant and a releasing agent, wherein the releasing agent comprises a first releasing agent component of a monoester compound represented by formula (1) and a second releasing agent component composed of a hydrocarbon compound having a branched chain structure, and the first releasing agent component accounting for 40% to 98% by mass of the total amount of the first and second releasing agent components: R1—COO—R2 ??(1) wherein R1 and R2 are each independently a hydrocarbon group having 13 to 30 carbon atoms.
    Type: Application
    Filed: January 22, 2007
    Publication date: August 2, 2007
    Applicant: KONICA MINOLTA BUSINESS TECHNOLOGIES, INC.
    Inventors: Takao YAMANOUCHI, Shingo FUJIMOTO, Makoto KOBAYASHI, Kazuya ISOBE, Hirofumi KOGA
  • Patent number: 7250243
    Abstract: A nonmagentic one-component toner for an electrophotographic image forming apparatus includes a toner with toner particles, a binder resin having a coloring agent, a charging control agent, and a release agent, and an external additive added to the toner particles. The external additive includes approximately 0.1 to 3.0 wt % of silica having a charge opposite to the toner particles, approximately 0.1 to 3.0 wt % of silica having a same charge as the toner particles, and approximately 0.1 to 4.0 wt % of titanium dioxide.
    Type: Grant
    Filed: May 12, 2004
    Date of Patent: July 31, 2007
    Assignee: Samsung Electronics Co., Ltd.
    Inventors: Duck-hee Lee, Jong-moon Eun
  • Patent number: 7250241
    Abstract: The present invention provides a toner that exhibits excellent low-temperature fixing properties, offset resistance, and has excellent storage stability in a developing machine. The toner has, in a DSC curve obtained by measuring the toner with differential scanning calorimeter, a glass transition temperature (Tg1) measured in a first scan of 50.0 to 70.0° C. and a temperature difference (Tg1?Tg2) between the glass transition temperature (Tg1) measured in the first scan and a glass transition temperature (Tg2) measured in a second scan ranging from 3.0 to 20.0° C.
    Type: Grant
    Filed: May 5, 2005
    Date of Patent: July 31, 2007
    Assignee: Canon Kabushiki Kaisha
    Inventors: Yasukazu Ayaki, Koji Abe
  • Publication number: 20070166635
    Abstract: A toner is provided including a binder resin, a colorant, and a release agent, which has a volume average particle diameter (Dv) of from 3 to 9 ?m, and wherein the binder resin and the release agent form a sea-island structure in which the island formed of the release agent is dispersed in the sea formed of the binder resin in a cross-sectional image of the toner obtained by a transmission electron microscope (TEM), and the following relationships are satisfied: IB>IA and IB>IC, wherein each of IA, IB, and IC represents an area ratio (%) of the island in an outermost region (A) of the cross-sectional image of the toner, an intermediate region (B) thereof located under the outermost region (A), and an innermost region (C) thereof located under the intermediate region (B); and a method of preparing the toner.
    Type: Application
    Filed: January 18, 2007
    Publication date: July 19, 2007
    Inventors: Atsushi Yamamoto, Chiyoshi Nozaki, Tsuyoshi Nozaki, Minoru Nakamura, Yoshimichi Ishikawa
  • Patent number: 7229734
    Abstract: In the toner comprising at least a colorant, a releasing agent and a binder resin, the releasing agent being a mixture of carnauba wax and non-paraffin wax, the binder resin contains a polyester resin having an acid value of 7 to 20 mg KOH/g. An electrophotographic negatively charged full color toner having good fixing property, glossiness, transparency, and releasability without coating a fixing oil to a fixing apparatus.
    Type: Grant
    Filed: March 22, 2004
    Date of Patent: June 12, 2007
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Masahiko Kubo
  • Patent number: 7223509
    Abstract: In the toner comprising at least a colorant, a releasing agent and a binder resin, the releasing agent being a mixture of carnauba wax and non-paraffin wax, the binder resin contains a polyester resin comprising a cyclohexane dimethanol of a polyhydric alcohol ingredient as an essential ingredient and having an acid value of 5 to 20 mg KOH/g. An electrophotographic negatively charged full color toner having good fixing property, glossiness, transparency, and releasability without coating a fixing oil to a fixing apparatus.
    Type: Grant
    Filed: March 22, 2004
    Date of Patent: May 29, 2007
    Assignee: Sharp Kabushiki Kaisha
    Inventor: Masahiko Kubo
  • Patent number: 7217486
    Abstract: The present invention provides a toner containing toner mother particles containing a binder resin and a colorant having added thereinto external additives, e.g., positively electrifiable silica fine particles, negatively electrifiable silica fine particles, titanium oxide fine particles and a long chain fatty acid or a salt thereof, wherein the external additives are added by multistage process, thereby is low in desorption of external additives, has the electrification property for a long period of time, shows high flowability and transfer efficiency, and is not accompanied by the reduction of image density.
    Type: Grant
    Filed: January 16, 2004
    Date of Patent: May 15, 2007
    Assignee: Seiko Epson Corporation
    Inventors: Hiroshi Kato, Nobuhiro Miyakawa
  • Patent number: 7217484
    Abstract: Disclosed is an oil-less toner composition exhibiting good low temperature release and stripping in fixing, enhanced surface gloss of fixed image, and/or OHP transparency. By controlling one or more properties, such as the relative thermal energy input during the EA aggregation/coalescence process, using a wax having a certain dispersion size (D50), molecular weight and/or melting temperature, the toner particle produced thereby can achieve optimal surface wax protrusion with a surface wax content of about 12 to about 25 weight percent. This is based on the total amount of wax in the toner, as determined by x-ray photoelectron spectroscopy (XPS). The contamination of wax on developing rolls, photoreceptor and carriers, which lowers the reliability of the developer, is suppressed with the present exemplary embodiment.
    Type: Grant
    Filed: April 3, 2006
    Date of Patent: May 15, 2007
    Assignee: Xerox Corporation
    Inventors: Vincenzo Marcello, David Kurceba, Nancy Hunt, Cheih-Min Cheng, Tie Hwee Ng
  • Patent number: 7211361
    Abstract: An image formation apparatus includes a development unit using a developer support having a conductive surface layer, and a control unit for causing an idle operation of the developer support to be performed at a predetermined timing in a non-print state.
    Type: Grant
    Filed: April 10, 2006
    Date of Patent: May 1, 2007
    Assignee: Seiko Epson Corporation
    Inventor: Akira Arai
  • Patent number: 7208252
    Abstract: Magnetic toner compositions, conductive developer compositions, and methods for producing images in a hybrid jumping development system, more specifically, in a magnetic ink character recognition system, are disclosed. The developer compositions contain coated magnetic toner particles and coated carrier particles. The toner compositions include a resin, colorant, wax, magnetic component, and surface additives of coated silica, titania, and zinc stearate.
    Type: Grant
    Filed: June 30, 2004
    Date of Patent: April 24, 2007
    Assignee: Xerox Corporation
    Inventors: Michael L. Grande, William H. Hollenbaugh, Jr.
  • Patent number: 7183032
    Abstract: A toner for electrostatic image development, containing a resin binder containing a polyester, a colorant, and a releasing agent containing an ester wax and a petroleum wax; and a process for preparing a toner for electrostatic image development, including the step of melt-kneading raw materials for the above toner, wherein the melt-kneading step is carried out with an open-roller type kneader. The toner for electrostatic image development is used for the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.
    Type: Grant
    Filed: May 21, 2004
    Date of Patent: February 27, 2007
    Assignee: Kao Corporation
    Inventors: Yasuhiro Hidaka, Hisakazu Tajima
  • Patent number: 7169524
    Abstract: The present invention provides a toner comprising a binder resin, a colorant and an infrared absorbing agent, wherein tan ? (loss elastic modulus G?/storage elastic modulus G?) of the toner at 120° C. is in the range of 3 to 6, and an image-forming method using the toner in which toner images on a recording medium are light irradiated by a flash lamp having a light-emitting energy of 1.0 to 5.0 J/cm2 so that the toner images are fixed on the recording medium.
    Type: Grant
    Filed: January 26, 2004
    Date of Patent: January 30, 2007
    Assignee: Konica Minolta Business Technologies, Inc.
    Inventors: Minoru Nakamura, Yoshihiro Mikuriya, Masahide Inoue, Masahiro Anno
  • Patent number: 7160660
    Abstract: In a magnetic toner having toner particles containing at least a binder resin and a magnetic material, the binder resin is chiefly composed of a resin having a polyester unit synthesized using as a catalyst a tin compound represented by the following Formula (1), and the magnetic material has a number-average particle diameter of form 0.1 ?m to 0.3 ?m: (RCOO)2Sn??Formula (1) wherein R represents an alkyl group having 5 to 15 carbon atoms. This magnetic toner can attain a stable image density without dependence on environment and enables formation of high-grade images over a long period of time without causing scratches of latent image bearing members.
    Type: Grant
    Filed: April 6, 2004
    Date of Patent: January 9, 2007
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tadashi Dojo, Nene Shibayama, Yuichi Mizoo, Yusuke Hasegawa
  • Patent number: 7147980
    Abstract: A toner having toner particles each comprising at least a binder resin, a wax, and a colorant is used in an image forming apparatus which has a fixing means comprising a belt-shaped heating member and a pressurizing member. The binder resin contains a resin formed by a reaction between an epoxy group of a vinyl resin (A) having the epoxy group and a carboxyl group of a resin (B) having at least a polyester unit and the carboxyl group. The toner has a storage elastic modulus at a temperature of 80° C. (G? 80) in the range of 1×105 to 1×108 Pa and has a storage elastic modulus at a temperature of 160° C. (G? 160) in the range of 1×101 to 1×104 Pa.
    Type: Grant
    Filed: January 9, 2004
    Date of Patent: December 12, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takayuki Itakura, Takaaki Kotaki, Yasuhiro Ichikawa, Takaaki Kaya, Wakashi Iida, Hiroyuki Fujikawa, Kazuhiko Hayami, Nobuyoshi Sugahara, Yojiro Hotta
  • Patent number: 7144667
    Abstract: The invention provides an electrostatic charge image developing toner containing a fixing resin and a wax, characterized in that in a DSC curve measured by a differential scanning calorimeter for the wax, a maximum endothermic peak of endothermic peaks at temperature up is less than 70° C., on-set temperature attributable to the maximum endothermic peak is above 50° C., and lowest on-set temperature of on-set temperatures attributable to endothermic peaks except the maximum endothermic peak is in a range of from 30° C. to 40° C.
    Type: Grant
    Filed: March 1, 2004
    Date of Patent: December 5, 2006
    Assignee: Ricoh Printing Systems, Ltd.
    Inventors: Tsuneaki Kawanishi, Junji Kobayashi, Ryuuichi Shimizu, Shigenori Yaguchi, Hirobumi Ouchi
  • Patent number: 7138213
    Abstract: The present invention provides a cyan toner including: one or plural heat-absorption peaks in a temperature range of 30 to 200° C. in a heat-absorption curve obtained by using a differential scanning calorimeter; a maximal value of a maximum heat-absorption peak temperature in the range of 65 to 150° C.; and a reflectance of 45 to 80% at a wavelength of 500 nm, a reflectance of 5 to 30% at a wavelength of 600 nm, and a brightness L* of 45 to 75, when measured in a powder form by spectroscopic analysis. The present invention thus provides a cyan toner capable of forming an image with reduced graininess and roughness from a low-density region to a high-density region and ensured a sufficient fixing temperature region, and a method for forming an image using the cyan toner.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: November 21, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Takayuki Itakura, Yoshinobu Baba, Yuko Sato, Nobuyoshi Sugahara, Kazuo Terauchi, Takaaki Kotaki, Hirohide Tanikawa
  • Patent number: 7132210
    Abstract: An image-forming color toner contains at least a colorant, a resin (A), a modified resin (B) and a wax (a) as a mold releasing agent, the image-forming color toner having a phase separated structure comprising the modified resin (B) as a domain in the resin (A) as a continuous phase, and wax (a) being effectively contained the modified resin (B). The modified resin (B) has a wax part containing a wax component (b), and a modified part formed of a vinyl monomer unit and an average ester group concentration of 8% by weight to 30% by weight.
    Type: Grant
    Filed: June 28, 2005
    Date of Patent: November 7, 2006
    Assignee: Ricoh Company, Ltd.
    Inventors: Masanori Suzuki, Yohichiroh Watanabe, Keiko Shiraishi, Toyoshi Sawada, Takuya Saito, Masashi Nagayama
  • Patent number: 7129013
    Abstract: A toner for developing latent electrostatic images is in the form of particles prepared by dissolving or dispersing each component of a composition in an organic solvent to form a solution or dispersion, the composition containing at least a resin reactive with a compound having an active hydrogen group, a compound having an active hydrogen group, a coloring agent, a releasing agent, and a graft polymer C of a polyolefin resin A on which a vinyl resin B has been at least partially grafted; dispersing the solution or dispersion in an aqueous medium; reacting the reactive resin with the compound having an active hydrogen group; removing the organic solvent during or after the step of reacting; and washing and drying particles formed by removing the organic solvent.
    Type: Grant
    Filed: January 21, 2004
    Date of Patent: October 31, 2006
    Assignee: Ricoh Company, Ltd.
    Inventors: Hiroto Higuchi, Masami Tomita, Fumihiro Sasaki, Shigeru Emoto, Naohito Shimota, Maiko Kondo, Takahiro Honda, Junichi Awamura, Shinichiro Yagi, Toshiki Nanya, Tadao Takikawa
  • Patent number: 7112395
    Abstract: To provide a color toner which is effective in mitigating contamination of a charging member, which is good at low temperature fixing in high-speed copying, and which is excellent in blocking resistance and electrification stability in continuous copying. Provided is a color toner containing at least a binder resin, a colorant, and a releasing agent, in which: (i) the binder resin contains at least a polyester unit; (ii) a weight average particle diameter of the color toner is greater than 6.5 ?m and equal to or less than 11 ?m; (iii) an average circularity A of particles in the color toner each having a circle-equivalent diameter of 3 ?m or more satisfies the relationship of 0.915?A?0.960; (iv) a permeability B (%) of the color toner in a 45 vol % aqueous solution of methanol satisfies the relationship of 10?B?70; and (v) an endothermic curve obtained through differential thermal analysis (DSC) measurement of the color toner has one or multiple endothermic peaks in the temperature range of 30 to 200° C.
    Type: Grant
    Filed: March 5, 2004
    Date of Patent: September 26, 2006
    Assignee: Canon Kabushiki Kaisha
    Inventors: Tetsuya Ida, Yasuhiro Ichikawa, Hirohide Tanikawa, Nozomu Komatsu