Hydrocarbon Wax-containing Adjuvant Patents (Class 430/108.8)
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Patent number: 7097951Abstract: A toner of the present invention comprises at least a binder resin comprising as a main component a polyester resin, a wax, and a colorant, in which in case of measuring a wettability of the toner with respect to a mixed solvent of methanol and water in terms of an optical transimittance at an optical wavelength of 780 nm, a methanol concentration of the mixed solvent is in a range of 45 to 65% by volume when an optical transmittance is 80% and 10%, respectively; a melt index (MI) is of 0.1 to 10 g/10 min at a temperature of 125° C.Type: GrantFiled: August 29, 2005Date of Patent: August 29, 2006Assignee: Canon Kabushiki KaishaInventors: Syuhei Moribe, Hiroshi Yusa, Takashige Kasuya, Yoshihiro Ogawa
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Patent number: 7087354Abstract: The present invention relates to a toner, comprising a binder resin, a colorant and two kinds of infrared absorbing agents, and having a maximum absorbance of the toner in a wavelength range of 810 to 870 nm that is greater, preferably two or more times greater than the maximum absorbance of the toner in a wavelength range of 870 to 1,000 nm, and also relates to an image-forming method which uses a flash fixing system with a xenon lamp serving as its light source, and is characterized by using the above-mentioned toner.Type: GrantFiled: October 23, 2003Date of Patent: August 8, 2006Assignee: Konica Minolta Business Technologies, Inc.Inventors: Minoru Nakamura, Yoshihiro Mikuriya, Junichi Tamaoki, Masahiro Anno
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Patent number: 7087353Abstract: A non-contact heat fixing toner, comprising a binder resin, a colorant, an infrared absorbing agent, a first wax and a second wax, wherein a difference (X-Y) between the maximum peak temperature (X; ° C.) in the differential thermal curve in the first wax and Tg (Y; ° C.) of the binder resin is within the range from ?5 to +10° C.Type: GrantFiled: October 31, 2003Date of Patent: August 8, 2006Assignee: Konica Minolta Business Technologies, Inc.Inventors: Yoshihiro Mikuriya, Minoru Nakamura, Masahiro Anno, Junichi Tamaoki, Chiyoshi Nozaki
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Patent number: 7088946Abstract: Adjusting a gloss for a print image by adjusting the cooling of the print image. Further, a toner for a printing press adjusting gloss by adjusting cooling includes 1% to 30% aliphatic hydrocarbons, aliphatic acids, aliphatic alcohols or their salts, or olefinic hydrocarbons.Type: GrantFiled: April 12, 2004Date of Patent: August 8, 2006Assignee: Eastman Kodak CompanyInventors: Knut Behnke, Hans-Otto Krause, Frank-Michael Morgenweck, Domingo Rohde, Detlef Schulze-Hagenest, Lars Seimetz, Dinesh Tyagi
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Patent number: 7087355Abstract: Toner particles having at least one toner resin and at least one polyalkylene wax or a wax having a percent crystallinity of 80% or more are described. The wax that is present in the toner particles has a polydispersity of 2.0 or higher or a percent crystallinity of 80% or more, and also preferably has a number average molecular weight of about 2,000 or higher and/or a melting temperature onset of from about 115° C. to about 130° C. Development systems using the toner particles of the present invention are further described. Also, improvements in various properties associated with development systems are further described such as reduced toner dust levels as well as improved toner image abrasion resistance.Type: GrantFiled: March 18, 2005Date of Patent: August 8, 2006Assignee: Eastman Kodak CompanyInventors: Robert D. Fields, Dinesh Tyagi
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Patent number: 7070898Abstract: A toner having a favorable fixability, excelling in charge stability, and capable of forming a image of retaining a high image density and a high resolution in long-term use is provided. That is, the toner of the present invention is a toner obtained by polymerizing a polymerizable monomer composition comprising a polymerizable monomer and a colorant, in which the polymerizable monomer composition is polymerized using a polymerization initiator comprising a redox initiator which includes an organic peroxide with a 10-hour half-life temperature of 86° C. or higher and an reducing agent; the toner has a ratio of a weight-average particle diameter to a number-average particle diameter of 1.40 or less; and the toner has top of a main-peak in a molecular weight range of 5,000 to 50,000 in a molecular weight distribution measured using GPC of the THF-soluble part thereof, including t-butanol with a content of 0.1 to 1,000 ppm.Type: GrantFiled: December 4, 2003Date of Patent: July 4, 2006Assignee: Canon Kabushiki KaishaInventors: Tatsuya Nakamura, Kenji Okado, Akira Hashimoto, Keiji Komoto
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Patent number: 7056634Abstract: To provide a yellow toner allowing formation of an image with an excellent transparency for an OHP, an excellent coloring power, and an excellent light resistance. In the yellow toner including at least a yellow pigment containing a monoazo compound represented by the following formula (1), the value of a* is in the range of ?5 to +14 when b* is +80 with respect to a transmission chromaticity of an image formed on a transparency sheet. (wherein X1 to X6 each independently denotes a substituent selected from the group consisting of a hydrogen atom, a C1–3 alkyl group, a C1–3 alkoxyl group, a nitro group, a halogen group, a sulfonic group, a sulfamoyl group, a sulfamoyl group substituted with an aromatic group, a carboxyl group, and a carboxylate; each may bond with another to form a benzene ring or an imidazolone ring.Type: GrantFiled: October 9, 2003Date of Patent: June 6, 2006Assignee: Canon Kabushiki KaishaInventors: Atsushi Ishii, Takaaki Kotaki, Satoshi Matsunaga
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Patent number: 7056636Abstract: A dry toner contains at least a toner binder, organic fine particles, a colorant, a wax, a charge control agent, and an external additive. The wax is concentrated in the vicinity of a toner core including the toner binder, colorant and wax. The organic fine particles adhere to the surface of the toner core to form a base toner-particle, the fine particle of charge control agent adhere to the surface of the base toner-particle, and the external additive is located on the surface thereof.Type: GrantFiled: November 14, 2003Date of Patent: June 6, 2006Assignee: Ricoh Company, Ltd.Inventors: Masami Tomita, Fumihiro Sasaki, Toshiki Nanya, Hiroto Higuchi, Shinichiro Yagi, Shigeru Emoto, Tomoyuki Ichikawa, Naohito Shimota, Maiko Kondo, Tadao Takikawa
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Patent number: 7056638Abstract: The present invention is directed to a toner for electrophotography that exhibits excellent hot offset resistance, storability, and glossiness and can obtain a high image-resolution and highly detailed images when used for energy saving apparatuses or as a color toner. The present invention is also directed to a developer, image-forming apparatus, and process cartridge containing such toner, and image-forming process using such toner. The toner of the present invention contains a resin and wax. The wax is dispersed within the resin in a shaped of fine particles to form a toner particle. In the toner particle, more dispersed wax particles are existed in a surface portion of the toner particle than a centric portion of the toner particle.Type: GrantFiled: August 22, 2003Date of Patent: June 6, 2006Assignee: Ricoh Company, Ltd.Inventors: Masami Tomita, Toshiki Nanya, Fumihiro Sasaki, Shigeru Emoto, Shinichiro Yagi, Hiroto Higuchi, Naohiro Watanabe, Tadao Takikawa
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Patent number: 7056637Abstract: Toner particles are described containing at least one toner resin and at least one wax. The wax present in the toner particles has an average domain size of about 1 micron or less. Developer systems, two component and monocomponent, are further described as well development systems and methods for developing an electrostatic image.Type: GrantFiled: June 12, 2003Date of Patent: June 6, 2006Assignee: Eastman Kodak CompanyInventors: Robert D. Fields, Dinesh Tyagi
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Patent number: 7056635Abstract: A toner including a thermoplastic resin; a colorant; a wax; and a crystalline polymer, wherein a DSC endothermic peak temperature of the wax or the crystalline polymer determined by subjecting the toner to a differential scanning calorimetric analysis is lower by not less than 2° C. than a DSC endothermic peak temperature thereof determined when only the wax or the crystalline polymer is subjected to the differential calorimetric analysis.Type: GrantFiled: November 13, 2003Date of Patent: June 6, 2006Assignee: Ricoh Company, Ltd.Inventors: Chiaki Tanaka, Naohiro Watanabe, Takeshi Takada
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Patent number: 7049040Abstract: A toner for development of an electrostatically charged image, said toner comprising a binder resin, a colorant, a function imparting agent, and a charge control agent, wherein said binder resin at least contains a polyolefin resin having a cyclic structure, said polyolefin resin is composed of a resin or resin fraction having a number average molecular weight (Mn), as measured by GPC, of less than 7,500 and a resin or resin fraction having said number average molecular weight of 7,500 or more, and in said polyolefin resin having a cyclic structure, a resin or resin fraction having an intrinsic viscosity (i.v.) of 0.25 dl/g or more, and a number average molecular weight (Mn) of 7,500 or more and a weight average molecular weight (Mw) of 15,000 or more, as measured by the GPC method, is contained in a proportion of less than 50% by weight based on the entire binder resin.Type: GrantFiled: December 25, 1997Date of Patent: May 23, 2006Assignee: Ticona GmbHInventors: Frank Osan, Thomas Wehrmeister, Horst-Tore Land, Toshimi Nishioka, Junichi Fukuzawa, Toru Nakamura, Takuya Hoga, Masayuki Arai, Satoshi Arai
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Patent number: 7026086Abstract: A toner formed of at least a binder resin, a colorant, a charge control agent and a wax, is provided with a uniform state of dispersion of the wax and good balance of low-temperature fixability and anti-high-temperature offset characteristic, while exhibiting good developing performances over wide environmental conditions. The toner is characterized in that (a) the binder resin comprises a hybrid resin component having a polyester unit and a vinyl polymer unit, (b) the toner exhibits a loss tangent (tan ?) of 1.0 at a temperature in a range of 80–160° C., and (c) the toner provides a DSC curve showing a heat-absorption peak in a temperature range of 85–130° C. on temperature increase as measured according to differential scanning calorimetry (DSC).Type: GrantFiled: August 6, 2002Date of Patent: April 11, 2006Assignee: Canon Kabushiki KaishaInventors: Ryota Kashiwabara, Satoshi Matsunaga
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Patent number: 7026087Abstract: A toner composition, comprising a binder resin, a wax, a copolymer and a colorant; the copolymer being a copolymer between an ?-olefin, maleic anhydride and maleic anhydride monoester.Type: GrantFiled: September 30, 2003Date of Patent: April 11, 2006Assignee: Konica Minolta Business Technologies, Inc.Inventors: Yoshihiro Mikuriya, Masahiro Anno, Katsunori Kurose, Masahide Inoue
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Patent number: 7022448Abstract: An electrophotographic toner containing: a fixing resin, a colorant, and wax. The wax at least contains hydrocarbon wax having a number-average molecular weight of not higher than 600, and polyethylene wax having a number-average molecular weight of not higher than 600, a melting viscosity of lower than 15 mPa·s at 140° C. and a crystallinity of lower than 95%. A ratio of the hydrocarbon wax to the polyethylene wax is in a range of from 1:10 to 2:1. A maximum of absorption peaks in a heat-up time absorption calorie curve in a DSC curve of the toner measured by a differential scanning calorimeter is at a temperature not higher than 75° C. An onset temperature in absorption of heat is not higher than 65° C.Type: GrantFiled: September 2, 2003Date of Patent: April 4, 2006Assignee: Ricoh Printing Systems, Ltd.Inventors: Shigenori Yaguchi, Ryuuichi Shimizu, Junji Kobayashi, Tadahiro Kaneko, Nobuyoshi Hoshi, Tsuneaki Kawanishi
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Patent number: 7018761Abstract: A toner used for an image forming method comprises steps of: limiting an amount of toner on a surface of a toner carrier by allowing a toner layer limiting member to be pressed to the surface of the toner carrier; and developing an electrostatic latent image formed on an electrostatic latent image carrier using the toner carried and transferred by the toner carrier, based on a non-magnetic single component development system, wherein the toner comprises toner particles having a volume average particle diameter of 3 to 9 ?m, an arithmetic mean value of shape factor of 1.1 to 1.5, a coefficient of variation of shape factor of 16% or less, a ratio of rounded toner particle of 50% by number or more and a coefficient of variation of number particle diameter distribution of 26% or less, and a conveyance index of 2.0 to 10.0.Type: GrantFiled: September 18, 2003Date of Patent: March 28, 2006Assignee: Konica Minolta Holdings, Inc.Inventors: Takao Yamanouchi, Masafumi Uchida, Masahiro Anno, Chikara Tsutsui, Takeshi Arai
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Patent number: 7005224Abstract: The present invention relates to the use of polyolefin waxes which have been prepared by means of metallocene catalysts and have been modified to make them polar in photocopier toners and also to photocopier toners comprising such polyolefin waxes modified to make them polar.Type: GrantFiled: November 25, 2002Date of Patent: February 28, 2006Assignee: Clariant GmbHInventors: Gerd Hohner, Michael Bayer
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Patent number: 6991884Abstract: A chemically prepared toner for electrophotographic printers and method therefor using a unique polymeric dispersant. The chemically prepared toner includes agglomerated polymeric dispersant stabilized pigment particles, a fuser release agent, a charge control agent dispersion, and a self-stabilized essentially surfactant free latex binder. The polymeric dispersant includes at least three segments, a hydrophilic polymeric segment, a hydrophobic polymeric segment, and a protective colloid or reactive surfactant segment. The weight average molecular weight range of the dispersant ranges from about 5,000 to about 30,000, and a hydrophobicity ranging from about 10 to about 90 percent by weight. The chemically prepared toner includes agglomerated toner particles have a unimodal particles size distribution with a number average particle size (N) ranging from about 5.0 to about 8.5 microns and a volume average particle size (V) ranging from about 5.0 to about 8.5 microns.Type: GrantFiled: November 6, 2003Date of Patent: January 31, 2006Assignee: Lexmark International, Inc.Inventors: Jing X. Sun, Bradley Leonard Beach
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Patent number: 6967070Abstract: An electrophotographic toner comprising a binder resin and a colorant, which is used in electrophotographic process employing a flash fixing system for fixation of a transferred toner image, wherein the binder resin is a polyester resin which partially contains a chloroform-insoluble content; and the toner contains a polypropylene resin and an ester type structure resin represented by the following formula (I); wherein p, q, m and n each represents a positive integer of 16 to 22 and R may be the same or different and each represents a hydrogen atom or a lower alkyl group having 1 to 4 carbon atoms. The electrophotographic toner is capable of remarkably enhancing the fixation strength of the toner and inhibiting the occurrence of voids during the printing and the occurrence of fuming and odor during the fixation.Type: GrantFiled: November 14, 2001Date of Patent: November 22, 2005Assignee: Fuji Xerox Co., Ltd.Inventors: Yasushige Nakamura, Toru Takahashi, Tsuneo Watanuki, Norio Sawatari, Seijiro Ishimaru, Yasuyuki Furuse
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Patent number: 6946229Abstract: A color toner which gives a suitable image gloss and has an excellent color reproducibility, which has sufficient anti-offset properties even when a release oil is not coated on a fixing roller or is coated in only a small amount, and which has excellent transfer properties, durability, and charge stability relative to humidity is disclosed. Also, an image-forming apparatus using the color toner and a toner container filled with the color toner are disclosed. The color toner comprises a continuous phase of a resin containing a urea-modified polyester resin; and a modified resin dispersed in the continuous phase, wherein the modified resin contains a release polymer portion containing a release polymer; and a modified portion containing a plurality of vinyl monomer units, the modified portion having an average ester group concentration of 8% by weight to 30% by weight.Type: GrantFiled: August 26, 2003Date of Patent: September 20, 2005Assignee: Ricoh Company, Ltd.Inventors: Masanori Suzuki, Takuya Saito, Hiroshi Yamashita, Yohichiroh Watanabe, Takeshi Takada, Tsunemi Sugiyama, Satoshi Mochizuki, Yasuaki Iwamoto, Takayuki Koike
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Patent number: 6936394Abstract: An electrostatic latent image on an image-bearing member is developed with a two-component developer comprising a toner and a carrier stored in a developer vessel while supplying as required a replenishing developer to the developer vessel. The replenishing developer comprises 1 wt. part of a carrier and 2-50 wt. parts of a toner, wherein the carrier is a magnetic fine particle-dispersed resin carrier comprising at least inorganic compound particles and a carrier binder resin, and the toner has a weight-average particle size of 3 to 10 ?m and contains 1 to 40 wt. % of solid wax.Type: GrantFiled: February 25, 2002Date of Patent: August 30, 2005Assignee: Canon Kabushiki KaishaInventors: Kenji Okado, Yushi Mikuriya, Kazumi Yoshizaki, Naotaka Ikeda
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Patent number: 6936392Abstract: Disclosed is a developing agent using a binder resin including a styrene-acrylic-series resin, a crystalline polyester resin, a first wax having a melting point higher than the softening point of the crystalline polyester resin, and a second wax having a melting point lower than the softening point of the crystalline polyester resin.Type: GrantFiled: January 15, 2003Date of Patent: August 30, 2005Assignees: Kabushiki Kaisha Toshiba, Toshiba Tec Kabushiki KaishaInventor: Shuitsu Sato
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Patent number: 6929894Abstract: A toner is disclosed which is composed of toner particles containing at least a binder resin, a colorant and a wax, and an external additive. The wax has, in its DSC endothermic curve, a maximum endothermic peak at 55° C. to 80° C. within the temperature range from 30° C. to 160° C., the maximum endothermic peak having a half width of from 2° C. to 7° C., and the binder resin is composed chiefly of a polyester resin. The toner has a dynamic elastic modulus from 5×102 to 1×105 dN/m2 at 140° C., and its ratio to a dynamic elastic modulus at 170° C. is from 0.05 to 50, and the toner contains 10 to 20% by weight of THF-insoluble matter A of a binder resin component after 8 hours from the start of extraction and 1 to 10% by weight of THF-insoluble matter B of the binder resin component after 24 hours from the start of extraction, the ratio of A to B, B/A, being from 0.1 to 0.8. Also disclosed is a fixing method making use of this toner.Type: GrantFiled: July 10, 2002Date of Patent: August 16, 2005Assignee: Canon Kabushiki KaishaInventors: Nobuyoshi Sugahara, Masaaki Taya, Junko Yoshikawa, Takayuki Itakura, Yojiro Hotta
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Patent number: 6929893Abstract: An electrostatic image dry toner composition comprising a binding resin, a colorant, a releasing agent, and two or more kinds of inorganic oxide powders having different volume average primary particle diameters. A surface of at least one kind of the inorganic oxide powders is covered with a coating material selected from the group of 1) a fatty acid metal salt, 2) a wax having a melting point of 40° C. or higher, and 3) a resin having a glass transition temperature of 40° C. or higher.Type: GrantFiled: April 9, 2003Date of Patent: August 16, 2005Assignee: Fuji Xerox Co., Ltd.Inventors: Susumu Yoshino, Motoko Sakai, Yoshifumi Iida, Seiichi Takagi
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Patent number: 6924074Abstract: The present invention aims to provide a toner for electrophotography having both good image-fixing properties and good image-reproducibility and image fidelity. The toner contains a coloring agent, a binder resin, and wax. In the toner, the binder resin contains cyclized rubber, the cyclized rubber contains cis1,4-polyisoprene at a portion excluding a cyclized portion of the cyclized rubber. The present invention also provides an image-forming process cartridge, an image-forming apparatus, an image-forming process, each of which utilizes the toner for electrophotography.Type: GrantFiled: May 28, 2003Date of Patent: August 2, 2005Assignee: Ricoh Company, Ltd.Inventor: Kunihiko Tomita
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Patent number: 6899985Abstract: The present invention relates to a toner for developing an electrostatic latent image comprising a binder resin, a colorant, a first wax, and a second wax whose kind is different from that of the first wax, wherein the toner is prepared by a kneading-grinding method and integrated domains of the first wax and the second wax are dispersed in the binder resin.Type: GrantFiled: July 23, 2002Date of Patent: May 31, 2005Assignee: Minolta Co., Ltd.Inventors: Masahide Inoue, Chikara Tsutsui, Yoshihiro Mikuriya, Yoshitaka Sekiguchi, Takeshi Arai, Megumi Aoki, Masahiro Anno
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Patent number: 6897003Abstract: The invention provides a toner which can maintain sufficient image density upon continuous copying in a recycle system even under any environmental conditions without causing troubles such as fogging and toner dusting. The toner for recycle system comprises toner particles which contain, as a binder resin, at least a cycloolefin copolymer resin and, as a releasing agent, at least a polypropylene wax, and fine silica particles adhered to the surface of said toner particles. This toner is used for a toner recycling type developing method, in which the toner remaining on the surface of the photosensitive member is recovered into the developing device and is reused.Type: GrantFiled: August 26, 2002Date of Patent: May 24, 2005Assignee: Tomoegawa Paper Co., Ltd.Inventors: Yoshiaki Harada, Moriyuki Goto
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Patent number: 6852461Abstract: A binder resin includes a first polyester resin having a high softening point Sp1, a second polyester resin having a softening point Sp2 higher than the softening point Sp1, a first wax having a melting point Mp1 higher than the softening point Sp2, and a second wax having a melting point Mp2 lower than the softening point Sp2.Type: GrantFiled: August 29, 2002Date of Patent: February 8, 2005Assignees: Kabushiki Kaisha Toshiba, Toshiba Tec Kabushiki KaishaInventors: Shuitsu Sato, Takashi Urabe, Yasuhito Noda
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Patent number: 6846602Abstract: The object of the present invention is to provide a full-color toner for oil-less fixing that is able to maintain adequate image density over a long period of time in all types of environments even in the case of continuous printing of a large number of sheets, does not result in the occurrence of problems such as black spots (BS) caused by filming on the photosensitive member or fusing to developing members, demonstrates high image quality similar to that of silver halide photographs, namely, adequate glossiness, color mixing property (color reproduction property) and transparency as full-color images for printed images, and is able to demonstrate adequate optical transmittance in OHP images. In order to achieve the object, the present invention provides a full-color toner for oil-less fixing comprising a cyclo-olefin copolymer resin as a binder resin and a wax or waxes added as a release agent at the total weight of 7.Type: GrantFiled: October 4, 2002Date of Patent: January 25, 2005Assignees: Tomoegawa Paper Co., Ltd., Ticona GmbHInventors: Yoshihito Suwa, Toru Nakamura
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Patent number: 6838220Abstract: A toner for developing an electrostatic image, a process for producing the same, a developer for developing an electrostatic image and a process for forming an image are disclosed. The toner contains a resin, a colorant and a releasing agent, in which the toner has protrusions having a height of about from 0.05 to 2 ?m, a part of the protrusions encompasses the releasing agent, and a proportion of elements derived from the releasing agent is about 10% by atom or less based on elements on a surface of the toner that is quantitatively determined by X-ray photoelectron spectroscopy.Type: GrantFiled: June 20, 2001Date of Patent: January 4, 2005Assignee: Fuji Xerox Co., Ltd.Inventors: Yasuo Matsumura, Takao Ishiyama, Hiroshi Takano, Masaaki Suwabe, Shuji Sato
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Publication number: 20040265718Abstract: The present invention provides a toner comprising a binder resin, a colorant and an infrared absorbing agent, wherein tan&dgr; (loss elastic modulus G″/storage elastic modulus G′) of the toner at 120° C. is in the range of 3 to 6, and an image-forming method using the toner in which toner images on a recording medium are light irradiated by a flash lamp having a light-emitting energy of 1.0 to 5.0 J/cm2 so that the toner images are fixed on the recording medium.Type: ApplicationFiled: January 26, 2004Publication date: December 30, 2004Applicant: Konica Minolta Business Technologies, Inc.Inventors: Minoru Nakamura, Yoshihiro Mikuriya, Masahide Inoue, Masahiro Anno
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Patent number: 6835517Abstract: A toner including at least a binder resin; a colorant; a charge controlling agent; and a wax (B), in which the charge controlling agent comprises a compound selected from the group consisting of: an aromatic oxycarboxylic acids, derivatives of aromatic oxycarboxylic acid, salts of aromatic oxycarboxylic acids and salts of derivatives of aromatic oxycarboxylic acids; and a zirconium compound (A), and in which the zirconium compound (A) and the wax (B) have a weight ratio (A/B) satisfying the following relationship: 3.0≦(A/B)×100≦60.Type: GrantFiled: May 21, 2002Date of Patent: December 28, 2004Assignee: Ricoh Company, Ltd.Inventors: Maiko Kondo, Yasuaki Iwamoto, Fumihiro Sasaki, Hiroto Higuchi, Bing Shu, Yasushi Koichi
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Publication number: 20040241564Abstract: A toner for electrostatic image development, containing a resin binder containing a polyester, a colorant, and a releasing agent containing an ester wax and a petroleum wax; and a process for preparing a toner for electrostatic image development, including the step of melt-kneading raw materials for the above toner, wherein the melt-kneading step is carried out with an open-roller type kneader. The toner for electrostatic image development is used for the development of a latent image formed in electrophotography, electrostatic recording method, electrostatic printing method or the like.Type: ApplicationFiled: May 21, 2004Publication date: December 2, 2004Applicant: KAO CORPORATIONInventors: Yasuhiro Hidaka, Hisakazu Tajima
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Publication number: 20040229142Abstract: In a magnetic toner having toner particles containing at least a binder resin and a magnetic material, the binder resin is chiefly composed of a resin having a polyester unit synthesized using as a catalyst a tin compound represented by the following Formula (1), and the magnetic material has a number-average particle diameter of form 0.1 &mgr;m to 0.Type: ApplicationFiled: April 6, 2004Publication date: November 18, 2004Inventors: Tadashi Dojo, Nene Shibayama, Yuichi Mizoo, Yusuke Hasegawa
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Publication number: 20040224246Abstract: Of developing agents each having a binder containing a polyester resin having an acidic value, wax having a softening point higher than that of the binder, and wax having a softening point lower than that of the binder, the acidic value of a black developing agent is made higher than that of a color developing agent.Type: ApplicationFiled: February 26, 2004Publication date: November 11, 2004Applicants: KABUSHIKI KAISHA TOSHIBA, TOSHIBA TEC KABUSHIKI KAISHAInventors: Shuitsu Sato, Takashi Urabe, Yasuhito Noda, Takahito Kabai, Yuichi Hori, Taishi Takano
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Patent number: 6808851Abstract: A process for the preparation of emulsion aggregation toner particles with high pigment loading having a reduced number of wax protrusions on the surface of the toner particles and fewer coarse toner particles. The process includes the introduction of a wax having a molecular weight between about 500 and 2,500, or a blend of waxes having different a molecular weight between 500 and 2,500.Type: GrantFiled: January 15, 2003Date of Patent: October 26, 2004Assignee: Xerox CorporationInventors: Joseph A. Bartel, Patricia A. Burns, Raj D. Patel, Enno E. Agur, Danielle C. Boils, Edward G. Zwartz, Paul J. Gerroir, Maria N. V. McDougall
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Publication number: 20040209181Abstract: A toner for developing latent electrostatic images is in the form of particles prepared by dissolving or dispersing each component of a composition in an organic solvent to form a solution or dispersion, the composition containing at least a resin reactive with a compound having an active hydrogen group, a compound having an active hydrogen group, a coloring agent, a releasing agent, and a graft polymer C of a polyolefin resin A on which a vinyl resin B has been at least partially grafted; dispersing the solution or dispersion in an aqueous medium; reacting the reactive resin with the compound having an active hydrogen group; removing the organic solvent during or after the step of reacting; and washing and drying particles formed by removing the organic solvent.Type: ApplicationFiled: January 21, 2004Publication date: October 21, 2004Inventors: Hiroto Higuchi, Masami Tomita, Fumihiro Sasaki, Shigeru Emoto, Naohito Shimota, Maiko Kondo, Takahiro Honda, Junichi Awamura, Shinichiro Yagi, Toshiki Nanya, Tadao Takikawa
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Publication number: 20040209178Abstract: The present invention provides a cyan toner including: one or plural heat-absorption peaks in a temperature range of 30 to 200° C. in a heat-absorption curve obtained by using a differential scanning calorimeter; a maximal value of a maximum heat-absorption peak temperature in the range of 65 to 150° C.; and a reflectance of 45 to 80% at a wavelength of 500 nm, a reflectance of 5 to 30% at a wavelength of 600 nm, and a brightness L* of 45 to 75, when measured in a powder form by spectroscopic analysis. The present invention thus provides a cyan toner capable of forming an image with reduced graininess and roughness from a low-density region to a high-density region and ensured a sufficient fixing temperature region, and a method for forming an image using the cyan toner.Type: ApplicationFiled: March 5, 2004Publication date: October 21, 2004Inventors: Takayuki Itakura, Yoshinobu Baba, Yuko Sato, Nobuyoshi Sugahara, Kazuo Terauchi, Takaaki Kotaki, Hirohide Tanikawa
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Patent number: 6800412Abstract: A toner for dry developing, containing a colorant, a binder including a modified polyester, and wax particles dispersed in the binder, wherein that portion of the wax particles having a dispersion diameter of 0.1-3 &mgr;m accounts for at least 70% by number of the wax particles.Type: GrantFiled: October 9, 2003Date of Patent: October 5, 2004Assignee: Ricoh Company, Ltd.Inventors: Tsunemi Sugiyama, Masami Tomita, Shigeru Emoto, Hiroshi Yamashita
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Publication number: 20040191661Abstract: The toner having a significantly improved dispersibility of a colorant in toner particles is provided. The present invention provides a dry toner comprising: (i) a binder resin; (ii) a colorant; (iii) at least one of metallophthalocyanine and a metallophthalocyanine derivative having a central metal selected from the group consisting of Cr, Fe, Co, Ni, Zn, Mn, Mg, and Al; and (iv) a polymer containing 0.5 to 20% by mass of a base unit derived from a specific polymerizable monomer having an amide group.Type: ApplicationFiled: March 10, 2004Publication date: September 30, 2004Inventors: Manabu Ohno, Motoya Fukushima, Hitoshi Itabashi, Yasushi Katsuta, Emi Tosaka, Norikazu Fujimoto
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Publication number: 20040191657Abstract: In the toner comprising at least a colorant, a releasing agent and a binder resin, the releasing agent being a mixture of carnauba wax and non-paraffin wax, the binder resin contains a polyester resin comprising a cyclohexane dimethanol of a polyhydric alcohol ingredient as an essential ingredient and having an acid value of 5 to 20 mg KOH/g. An electrophotographic negatively charged full color toner having good fixing property, glossiness, transparency, and releasability without coating a fixing oil to a fixing apparatus.Type: ApplicationFiled: March 22, 2004Publication date: September 30, 2004Inventor: Masahiko Kubo
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Publication number: 20040191659Abstract: A toner having a favorable fixability, excelling in charge stability, and capable of forming a image of retaining a high image density and a high resolution in long-term use is provided. That is, the toner of the present invention is a toner obtained by polymerizing a polymerizable monomer composition comprising a polymerizable monomer and a colorant, in which the polymerizable monomer composition is polymerized using a polymerization initiator comprising a redox initiator which includes an organic peroxide with a 10-hour half-life temperature of 86° C. or higher and an reducing agent; the toner has a ratio of a weight-average particle diameter to a number-average particle diameter of 1.40 or less; and the toner has top of a main-peak in a molecular weight range of 5,000 to 50,000 in a molecular weight distribution measured using GPC of the THF-soluble part thereof, including t-butanol with a content of 0.1 to 1,000 ppm.Type: ApplicationFiled: December 4, 2003Publication date: September 30, 2004Inventors: Tatsuya Nakamura, Kenji Okado, Akira Hashimoto, Keiji Komoto
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Publication number: 20040191658Abstract: In the toner comprising at least a colorant, a releasing agent and a binder resin, the releasing agent being a mixture of carnauba wax and non-paraffin wax, the binder resin contains a polyester resin having an acid value of 7 to 20 mg KOH/g. An electrophotographic negatively charged full color toner having good fixing property, glossiness, transparency, and releasability without coating a fixing oil to a fixing apparatus.Type: ApplicationFiled: March 22, 2004Publication date: September 30, 2004Inventor: Masahiko Kubo
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Patent number: 6790577Abstract: A toner for developing an electrostatically charged image, which is constituted with a microcapsule toner particle composed of a core and a shell, the core comprising a colorant and a binder resin containing an olefin copolymer having a cyclic structure, said olefin copolymer having a glass transition temperature ranging from −20° C. to less than 60° C. and a number average molecular weight ranging from 100 to 20,000, and the shell comprising a coating resin for the core, and/or a shell comprising a resin for coating the core containing an olefin copolymer having a cyclic structure, said olelin copolymer having a glass transition temperature ranging from 60° C. to 180° C. and a number average molecular weight ranging from 1,000 to 100,000. Since this toner is excellent in anti-spent toner effect, transfer properties, fixing ability, and offset-free properties, it is applicable to electrostatically charge image type copiers, printers, etc.Type: GrantFiled: November 4, 2002Date of Patent: September 14, 2004Assignee: Ticona GmbHInventor: Toru Nakamura
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Publication number: 20040175643Abstract: The present invention provides a toner: comprising a binder resin comprising a polyester unit, a colorant, a releasing agent, and inorganic fine particles; has a weight average particle diameter of 3.0-6.5 &mgr;m; has an average circularity of particles in the toner each having a circle-equivalent diameter of 2 &mgr;m or more of 0.920-0.945; has a BET specific surface area of 2.1-3.5 m2/g; and has a permeability of light of a wavelength of 600 nm in a liquid having dispersed the toner in a 45 vol % methanol aq. of 30-80%. The present invention also provides a two-component developer: comprising the toner and a magnetic carrier comprising magnetic core particles coated by a coating layer; and has a number average particle diameter of 15-80 &mgr;m. Using the toner and the two-component developer enables a high-quality image to be formed at a high speed even in an oilless fixing system.Type: ApplicationFiled: March 5, 2004Publication date: September 9, 2004Inventors: Yoshinobu Baba, Yuko Sato, Ryoichi Fujita, Takaaki Kotaki, Nobuyoshi Sugahara, Kazuo Terauchi, Takayuki Itakura
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Publication number: 20040175640Abstract: The invention provides an electrostatic charge image developing toner containing a fixing resin and a wax, characterized in that in a DSC curve measured by a differential scanning calorimeter for the wax, a maximum endothermic peak of endothermic peaks at temperature up is less than 70° C., on-set temperature attributable to the maximum endothermic peak is above 50° C., and lowest on-set temperature of on-set temperatures attributable to endothermic peaks except the maximum endothermic peak is in a range of from 30° C. to 40° C.Type: ApplicationFiled: March 1, 2004Publication date: September 9, 2004Applicant: Hitachi Printing Solutions, Ltd.Inventors: Tsuneaki Kawanishi, Junji Kobayashi, Ryuuichi Shimizu, Shigenori Yaguchi, Hirobumi Ouchi
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Publication number: 20040175642Abstract: To provide a color toner which is effective in mitigating contamination of a charging member, which is good at low temperature fixing in high-speed copying, and which is excellent in blocking resistance and electrification stability in continuous copying. Provided is a color toner containing at least a binder resin, a colorant, and a releasing agent, in which: (i) the binder resin contains at least a polyester unit; (ii) a weight average particle diameter of the color toner is greater than 6.5 &mgr;m and equal to or less than 11 &mgr;m; (iii) an average circularity A of particles in the color toner each having a circle-equivalent diameter of 3 &mgr;m or more satisfies the relationship of 0.915≦A≦0.Type: ApplicationFiled: March 5, 2004Publication date: September 9, 2004Inventors: Tetsuya Ida, Yasuhiro Ichikawa, Hirohide Tanikawa, Nozomu Komatsu
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Patent number: 6787279Abstract: The present invention is a random copolymer and its use to compatibilize the components of mixtures of immiscible polymeric materials used in the preparation of toner formulations.Type: GrantFiled: June 20, 2001Date of Patent: September 7, 2004Assignee: Lexmark International, Inc.Inventors: Bryan Patrick Livengood, George P. Marshall, John Melvin Olson
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Publication number: 20040170912Abstract: A non-magnetic toning system for inclusion in a magnetic toning system is disclosed. Further the invention is directed to the process of color imaging, which can be divided into two main categories: (1) line, highlight, or imaging, wherein a permanent toned image of a color, including black, is produced using toner particles of a single color; and (2) process, or “near photographic” color imaging, wherein a permanent toned image is produced by selectively blending or mixing toner particles of two or more primary colors. The invention is directed to an interchangeable Non-Magnetic Toning System (“NMTS”) using specific toners in compatible printing machines. The NMTS using specific toners will be useful in printing machines currently on the market using magnetic toning systems.Type: ApplicationFiled: December 5, 2003Publication date: September 2, 2004Inventor: Michael W. Brennan
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Patent number: 6783909Abstract: Electrostatic image developing toner includes fixing resin; and wax. The wax is hydrocarbon-based wax. The wax is containing, as its constitutional components, first wax and second wax. The first wax is higher than 1.5 in ratio of weight average molecular weight (Mw) to number average molecular weight (Mn), lower than 10 mPa·s in melt viscosity at 140° C. and higher than 75% and not higher than 85% in degree of crystallinity. The second wax is not higher than 1.5 in ratio of weight average molecular weight (Mw) to number average molecular weight (Mn), lower than 10 mPa·s in melt viscosity at 140° C. and higher than 85% and not higher than 95% in degree of crystallinity.Type: GrantFiled: January 10, 2003Date of Patent: August 31, 2004Assignee: Hitachi Printing Solutions, Ltd.Inventors: Tsuneaki Kawanishi, Ryuuichi Shimizu, Shigenori Yaguchi, Junji Kobayashi, Tadahiro Kaneko, Nobuyoshi Hoshi