Identified Synthetic Polymeric Binder Contained In Nonradiation Sensitive Processing Composition Permeable Layer Other Than An Image Receiving Or Neutralizating Layer Patents (Class 430/215)
  • Patent number: 4345016
    Abstract: A color photographic sensitive material containing a polymer comprising at least 1 mol % of a repeating unit represented by formula (I) ##STR1## wherein A represents a divalent group, n is 1 or 2, R.sub.1 represents hydrogen, a halogen atom or an alkyl group, and R.sub.2, R.sub.3, and R.sub.4 each represents hydrogen, a halogen atom, an alkyl group, an aryl group, an alkoxy group, an aryloxy group, an alkylthio group, an arylthio group, an amino group, an acylamino group, or a sulfonamide group, and R.sub.3 and R.sub.4 together can form an aromatic ring, provided that the total of carbon atoms of R.sub.2, R.sub.3, and R.sub.4 is 60 or less.
    Type: Grant
    Filed: July 1, 1981
    Date of Patent: August 17, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Osamu Takahashi, Nobutaka Ohki, Kozo Aoki
  • Patent number: 4328301
    Abstract: A photographic assembly for the photographic diffusion transfer process is provided wherein a stripping layer is used consisting of a graft copolymer of gelatin which has been substantially fully reacted with a dicarboxylic acid anhydride selected from phthalic anhydrides, succinic anhydrides, glutaric anhydrides and a monomer of a vinyl ester, a vinyl ether, an acrylic ester, an acrylic ether, a methacrylic ester or a methacrylic ether or a mixture thereof. These stripping layers exhibit good dry adhesion to the emulsion layer and to the mordant layer and moderate wet adhesion.
    Type: Grant
    Filed: September 18, 1980
    Date of Patent: May 4, 1982
    Assignee: Ciba-Geigy AG
    Inventor: Peter J. Wright
  • Patent number: 4314020
    Abstract: Photographic assemblages, elements, receiving elements and cover sheets comprise a combination of two timing layers and a neutralizing layer. The outermost timing layer contains photographic addenda, such as development inhibitors, for substantially terminating development of the silver halide emulsion. The timing layer next to the neutralizing layer has a much longer breakdown time so that it is permeated by the alkaline processing composition only after silver halide development has been substantially terminated.
    Type: Grant
    Filed: August 4, 1980
    Date of Patent: February 2, 1982
    Assignee: Eastman Kodak Company
    Inventors: Kenneth J. Reed, Patrick H. Saturno, Gerald L. Ducharme
  • Patent number: 4312937
    Abstract: This disclosure relates to production of a photographic film assembly substantially free of optical pinholes for use as a base for negatives in self-developing film packs. The assembly comprises a paper layer and first and second layers of polyolefin adhered to opposite sides of the paper layer. The paper layer has a caliper of about 2 mils to about 4.5 mils and a basis weight of about 55 g/m.sup.2 to about 125 g/m.sup.2. The first and second polyolefin layers each have a layer weight of about 10 g/m.sup.2 to about 48 g/m.sup.2. Carbon black is uniformly dispersed in at least two out of the three layers. The total amount of carbon black in the assembly is about 2.5 g/m.sup.2 to about 4.0 g/m.sup.2.
    Type: Grant
    Filed: April 11, 1980
    Date of Patent: January 26, 1982
    Assignee: Schoeller Technical Papers, Inc.
    Inventors: Klaus B. Kasper, William L. Quartz, William H. Myers
  • Patent number: 4307174
    Abstract: Disclosed herein are heat-activatable adhesive compositions containing a water-dispersible polyester which comprisesA. an acid component comprising:(1) from about 8 to about 16 mole percent of units derived from at least one dicarboxylic acid having an ionic iminosulfonyl moiety containing a monovalent cation as an imino nitrogen substituent;(2) from about 40 to about 70 mole percent of units derived from at least one dicarboxylic acid selected from the group consisting of aliphatic dicarboxylic acids having the formula HOOC--(CH.sub.2).sub.
    Type: Grant
    Filed: January 29, 1981
    Date of Patent: December 22, 1981
    Assignee: Eastman Kodak Company
    Inventors: John M. Noonan, Robert C. McConkey
  • Patent number: 4304850
    Abstract: A photographic element for color diffusion transfer which includes a timing layer comprising a polymeric latex made up of (1) a conjugated diene monomer, (2) and ethylenically unsaturated acid monomer or salt, and (3) an ethylenically unsaturated monomer, which monomers are within certain percentage ranges.
    Type: Grant
    Filed: July 1, 1980
    Date of Patent: December 8, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Mikio Koyama, Satoru Ikeuchi, Noboru Mizukura, Hideaki Iwama
  • Patent number: 4299895
    Abstract: A photographic element comprising a support, a layer containing an image dye ligand or dye ligand forming material and a layer containing a dye mordant, wherein the mordant layer has associated therewith:(1) a polymer containing groups which form coordination complexes with metal ions; and(2) a source of metal ions.The polymer holds the metal ions in the vicinity of the dye mordant so that the metal ions can metallize the dye or dye forming material at the image receiving layer. These complexes, elements, and receiving elements are particularly useful in diffusion transfer processes. Novel polymers are also described.
    Type: Grant
    Filed: December 10, 1979
    Date of Patent: November 10, 1981
    Assignee: Eastman Kodak Company
    Inventors: William C. Archie, Jr., Gerald A. Campbell
  • Patent number: 4298674
    Abstract: Diffusion transfer films and processes are disclosed wherein the processing composition includes a light-reflecting pigment and a pH-sensitive optical filter agent, and the image-receiving element carries a layer containing a substantially non-diffusible agent adapted to decolorize optical filter agent immediately adjacent the interface between said processing composition and said layer containing said decolorizing agent.
    Type: Grant
    Filed: April 24, 1980
    Date of Patent: November 3, 1981
    Assignee: Polaroid Corporation
    Inventors: Edwin H. Land, Leon D. Cerankowski, Neil Mattucci
  • Patent number: 4298682
    Abstract: Two-sheet diffusion transfer assemblages, photographic elements and dye image-receiving elements are described wherein an overcoat layer is present on the photographic element or the dye image-receiving element superposed thereon. The overcoat layer comprises either silica or an ionic polyester in a hydrophilic colloid which prevents spontaneous delamination during the lamination period, yet permits satisfactory peel-apart afterwards.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: November 3, 1981
    Assignee: Eastman Kodak Company
    Inventor: John F. Bishop
  • Patent number: 4297431
    Abstract: A diffusion control layer comprising a polymerization product of a monomer capable of undergoing .beta.-elimination in an alkaline environment is disclosed for use in diffusion transfer film units, as an interlayer or overcoat in photosensitive elements, or as a timing layer or overcoat in image-receiving elements.
    Type: Grant
    Filed: March 14, 1980
    Date of Patent: October 27, 1981
    Assignee: Polaroid Corporation
    Inventor: Charles I. Sullivan
  • Patent number: 4297432
    Abstract: Photographic elements, two-sheet diffusion transfer assemblages containing such elements, and dye image-receiving elements are described. The photographic element comprises a support, a neutralizing layer, a timing layer, a vinylidene chloride polymeric layer, a polymeric primer layer, and at least one silver halide emulsion layer having a dye image-providing material associated therewith. The vinylidene chloride polymeric layer and the polymeric primer layer prevent unwanted transfer of portions of the emulsion layer to a receiver when the receiver and photographic element are peeled apart. The polymeric primer layer can be either a particular ionic vinyl polymer or a particular ionic polyester.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: October 27, 1981
    Assignee: Eastman Kodak Company
    Inventors: Wayne A. Bowman, John F. Bishop, John M. Noonan
  • Patent number: 4296195
    Abstract: Two-sheet diffusion transfer assemblages and photographic elements are described which contain a primer layer located between a polymeric acid layer and a timing layer. The primer layer prevents unwanted transfer of portions of the emulsion layer to the receiver when the receiver and photographic element are peeled apart. The primer layer comprises:(a) a mixture of gelatin and cellulose nitrate, or(b) a mixture of an acrylic acid copolymer and a particular acrylic acid terpolymer, or(c) an acrylic acid copolymer as described herein.
    Type: Grant
    Filed: August 1, 1980
    Date of Patent: October 20, 1981
    Assignee: Eastman Kodak Company
    Inventors: John F. Bishop, Wayne A. Bowman
  • Patent number: 4294907
    Abstract: Diffusion transfer films and processes are disclosed wherein the processing composition includes a light-reflecting pigment and an optical filter agent, and the image-receiving layer carries over it a layer containing a substantially non-diffusible agent adapted to decolorize optical filter agent immediately adjacent the interface between said processing composition and said decolorizing layer.
    Type: Grant
    Filed: April 24, 1980
    Date of Patent: October 13, 1981
    Assignee: Polaroid Corporation
    Inventors: Irena Y. Bronstein-Bonte, Edward P. Lindholm, Lloyd D. Taylor
  • Patent number: 4292390
    Abstract: Integral diffusion transfer photographic film unit is described, comprising at least two support layers, at least one of which is transparent, having laminated therebetween at least one silver halide emulsion layer in association with a dye-image-providing material and an image-receiving layer, and a processing composition to be distributed between the two support layers, wherein at least one marginal portion of the integral film unit is masked by a masking material having formed on at least one surface thereof a pressure-sensitive or heat-sensitive adhesive layer containing an acid or an acid-releasing material.
    Type: Grant
    Filed: May 30, 1980
    Date of Patent: September 29, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kazunobu Katoh, Teruyoshi Makino
  • Patent number: 4288523
    Abstract: Novel polymers comprising recurring units capable of undergoing .beta.-elimination in an alkaline environment are disclosed for use in diffusion control layers in diffusion transfer film units.
    Type: Grant
    Filed: March 14, 1980
    Date of Patent: September 8, 1981
    Assignee: Polaroid Corporation
    Inventor: Lloyd D. Taylor
  • Patent number: 4269925
    Abstract: Polymeric optical filter agents and photographic products and processes using same are disclosed. The polymeric optical filter agents are pH-sensitive optical filter agents comprising polymeric backbone units having the following hydrazone moiety: ##STR1## where R is a group which can provide a double bond for conjugation with the ##STR2## portion of the moiety to provide light-absorbing capability for the agent at a pH above its pKa, and X represents a substituent of R providing at least one electron-withdrawing group. The polymeric pH-sensitive optical filter agents have a highly colored light-absorbing form at a pH above the pKa and are substantially non-absorbing at a pH below the pKa. The polymeric optical filter agents are useful in photographic film units and processes for the protection of photoexposed photosensitive elements against the occurence of fogging during in-light development.
    Type: Grant
    Filed: October 29, 1979
    Date of Patent: May 26, 1981
    Assignee: Polaroid Corporation
    Inventors: Derek H. R. Barton, Irena Y. Bronstein-Bonte, Lloyd D. Taylor
  • Patent number: 4268604
    Abstract: In a photographic element for the color diffusion transfer process including a neutralizing system for reducing the pH of an aqueous alkaline developing solution which comprises a neutralizing layer and a timing layer wherein the timing layer is positioned on or under the neutralizing layer in direct or indirect contact therewith such that the aqueous alkaline developing solution reaches the neutralizing layer through the timing layer, the improvement which comprises said timing layer comprising a mixture of at least one polymer latex the minimum film forming temperature of which is 35.degree. C. or less (Group I) and at least one polymer latex the minimum film forming temperature of which is more than 35.degree. C.
    Type: Grant
    Filed: April 19, 1979
    Date of Patent: May 19, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Yoshida, Shinji Sakaguchi
  • Patent number: 4267262
    Abstract: In a photographic element for the color diffusion transfer process having a neutralizing system comprising a neutralizing layer and a timing layer, the improvement which comprises said timing layer containing a mixture of acetyl cellulose and a polymer represented by the general formula (I): ##STR1## wherein A represents a repeating unit represented by the general formula (II): ##STR2## wherein R.sub.2 represents a hydrogen atom, a halogen atom, or a methyl group; R.sub.3 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, ##STR3## R.sub.4 represents an alkyl group or an aralkyl group; R.sub.5 and R.sub.6, which may be the same or different, each represents an alkyl group, an aryl group, or an aralkyl group; and a represents 0 or 1; R.sub.
    Type: Grant
    Filed: April 3, 1979
    Date of Patent: May 12, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yukio Karino, Shinji Sakaguchi, Yoshio Sakakibara
  • Patent number: 4256614
    Abstract: Novel photographic processing compositions including a polymeric oxime viscosity-increasing reagent for processing an exposed film unit to provide a photographic image. While this photographic image may be in black-and-white or in color and prepared by any of the heretofore known systems, of particular interest are color diffusion transfer systems for preparing a color image viewable without separation of any of the components or layers of the photographic product. The invention also includes a novel class of polymeric oximes which may be employed in such compositions.
    Type: Grant
    Filed: November 5, 1979
    Date of Patent: March 17, 1981
    Assignee: Polaroid Corporation
    Inventor: Lloyd D. Taylor
  • Patent number: 4256826
    Abstract: A bleach-fix sheet for use in color photographic processes comprises a support having thereon a bleaching agent, a fixing agent and a hardened hydrophilic binder. In a preferred embodiment, the bleach-fix sheet is useful to bleach and fix a retained image in a color image diffusion transfer unit.
    Type: Grant
    Filed: August 14, 1978
    Date of Patent: March 17, 1981
    Assignee: Eastman Kodak Company
    Inventors: Gerhard Popp, Patrick H. Saturno, Keith H. Stephen
  • Patent number: 4256827
    Abstract: In a photographic element for the color diffusion transfer process including a neutralizing system for reducing the pH of an aqueous alkaline developing solution which comprises a neutralizing layer and a timing layer, wherein the timing layer is positioned on or under the neutralizing layer in direct or indirect contact therewith such that the aqueous alkaline developing solution reaches the neutralizing layer through the timing layer, the improvement which comprises the timing layer comprising a polymer latex which is produced by emulsion polymerization of each of at least one monomer selected from the group consisting of monomers of Group (A), at least one monomer selected from the group consisting of monomers of Group (B) and at least one monomer selected from the group consisting of monomers of Group (C), wherein said Group (A) monomers are represented by the following formula (I): ##STR1## wherein R represents a hydrogen atom or a methyl group; T represents a hydrogen atom or an aliphatic group; Q repre
    Type: Grant
    Filed: April 19, 1979
    Date of Patent: March 17, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuhiro Noguchi, Shinji Sakaguchi, Takashi Yoshida
  • Patent number: 4254208
    Abstract: A process for producing a photographic material, which comprises dispersing, in a solution of an organic resin, a material which is incompatible with the organic resin to form a dispersion, coating the resulting dispersion on at least one side of a support to form a coated layer, and then drying the coated layer, the material dispersed being a solid at ordinary temperature and in a liquid phase during the dispersing, whereby the coated layer when dried contains solid particles dispersed therein due to solidification of the dispersed material.The present invention also provides a photographic material obtained by the above process.
    Type: Grant
    Filed: February 14, 1977
    Date of Patent: March 3, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sumitaka Tatsuta, Masuhiko Hirose, Hiroshi Amari
  • Patent number: 4250243
    Abstract: In a photographic element for the color diffusion transfer process including a neutralizing system for reducing the pH of an aqueous alkaline developing solution which comprises a neutralizing layer and a timing layer, wherein the timing layer is positioned on or under the neutralizing layer in direct or indirect contact therewith such that the aqueous alkaline developing solution reaches the neutralizing layer through the timing layer, the improvement which comprises the timing layer comprising a polymer latex which is produced by emulsion polymerization of (1) each of (A) at least one monomer selected from the group consisting of ethylene-type monomers having at least a free carboxylic acid group, a free sulfonic acid group or a free phosphoric acid group or a salt thereof, (B) at least one monomer selected from the group consisting of monomers represented by the following general formula (1) ##STR1## wherein X is a hydrogen atom, a methyl group or a --COOR.sup.
    Type: Grant
    Filed: September 14, 1979
    Date of Patent: February 10, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Yoshida, Shinji Sakaguchi
  • Patent number: 4229516
    Abstract: A composition comprising a mixture of (1) from 5 to 95 percent by weight of a copolymer comprising from 55 to 85 percent by weight of vinylidene chloride, 5 to 35 percent by weight of an ethylenically unsaturated monomer, and 0 to 20 percent by weight of an ethylenically unsaturated carboxylic acid, and (2) from 5 to 95 percent by weight of a polymeric carboxy-ester-lactone, is useful as a temporary barrier between reactants in photographic products. The barrier is particularly useful as a process timing layer in color image transfer film units.
    Type: Grant
    Filed: October 2, 1978
    Date of Patent: October 21, 1980
    Assignee: Eastman Kodak Company
    Inventor: Edward P. Abel
  • Patent number: 4202694
    Abstract: Novel photographic processing compositions including a polymeric oxime viscosity-increasing reagent for processing an exposed film unit to provide a photographic image. While this photographic image may be in black-and-white or in color and prepared by any of the heretofore known systems, of particular interest are color diffusion transfer systems for preparing a color image viewable without separation of any of the components or layers of the photographic product. The invention also includes a novel class of polymeric oximes which may be employed in such compositions.
    Type: Grant
    Filed: April 7, 1978
    Date of Patent: May 13, 1980
    Assignee: Polaroid Corporation
    Inventor: Lloyd D. Taylor
  • Patent number: 4193795
    Abstract: A photographic element comprising a support, a layer containing certain photographically useful and/or active fragments and a layer containing a dye mordant composition comprising a polymer having recurring units of the formula selected from the group consisting of: ##STR1## wherein: R.sup.2 is hydrogen or alkyl;R.sup.1 is hydrogen, alkyl or aryl;L is a linking group;W is an electron-withdrawing group;X is a leaving group; andn is 0 or 1.The polymeric mordants covalently bond with dyes or dye precursors and are especially useful in diffusion transfer processes.
    Type: Grant
    Filed: May 15, 1978
    Date of Patent: March 18, 1980
    Assignee: Eastman Kodak Company
    Inventors: Gerald A. Campbell, Hyman Cohen, Lewis R. Hamilton, George Villard
  • Patent number: 4190447
    Abstract: A cover sheet for an integral imaging receiver element comprises a support, a neutralizing layer, at least one timing layer and an alkali permeable hydrophilic layer. The cover sheet may also contain a second alkali permeable layer coated over the alkali permeable hydrophilic layer to promote adhesion of the cover sheet to the other components of the film unit. The photographic film units containing the cover sheets are substantially free from dark spot imperfections and are resistant to delamination of the unit.
    Type: Grant
    Filed: December 18, 1978
    Date of Patent: February 26, 1980
    Assignee: Eastman Kodak Company
    Inventors: Michael K. Coil, Robert A. Sylvester