Readily Visible Image Formation Patents (Class 430/292)
  • Patent number: 6107010
    Abstract: A method for printing on an exposed polymerised thermoplastic or curable layer of the body of a portable data medium, and a portable data medium particularly a chip card, comprising a polymerised layer, are disclosed. The method comprises the steps of mixing a polymerisable thermoplastic or curable binder and at least one light-sensitive compound responsive to laser radiation having a predetermined wavelength in such a way that it changes from a first state to a second coloured state, in order to form a mixture, exposing the mixture to the laser radiation having a predetermined wavelength; and polymerising the mixture to form the polymerised layer of the body of the data medium. The method is particularly suitable for printing on smart cards.
    Type: Grant
    Filed: February 25, 1999
    Date of Patent: August 22, 2000
    Assignee: Gemplus S.C.A.
    Inventors: Isabelle Corniglion, Armand Gellis, Robert Guguelmetti, Christian Leriche, Paul Morgavi, Andre Samat
  • Patent number: 6100009
    Abstract: An image recording medium is disclosed which comprising: an acid generating agent capable of generating an acid by the action of heat or an acid, which is represented by the following formula (1); and a compound of causing variation in the absorption region of from 360 to 900 nm by the intramolecular or intermolecular reaction triggered by the action of an acid:W.sup.1 OP (1)wherein W.sup.1 represents a residue of an acid represented by W.sup.1 OH, and P represents an acid-sensitive substituent capable of splitting off at a temperature of 150.degree. C. or less due to catalysis by W.sup.1 OH.
    Type: Grant
    Filed: October 15, 1998
    Date of Patent: August 8, 2000
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tatsuhiko Obayashi, Junichi Yamanouchi, Atsuhiro Ohkawa
  • Patent number: 6057077
    Abstract: The invention relates to a process for the production of a colored image for color proofing of copy masters for multicolor printing and a layer material for carrying out this process.A positive image of the exposure mask (color separation film) is produced by lamination of a photosensitive material onto a colored layer material, followed by imagewise exposure and peeling-off of a film support, or a negative image of the exposure mask is obtained by imagewise exposure of the photosensitive material before the lamination, accompanied by flood exposure after lamination followed by peeling-off of a film support. The two procedures use the same materials and do not require wet development. For each single-color image, only one lamination step is required.
    Type: Grant
    Filed: June 25, 1998
    Date of Patent: May 2, 2000
    Assignee: Agfa-Gevaert N.V.
    Inventors: Karin Marz, Dieter Mohr
  • Patent number: 6040108
    Abstract: Compositions for making structured color images comprising(a) a soluble pigment precursor which can be transformed to an insoluble pigment by means of chemical, thermal, photolytic or radiation-induced method, and(b) a binder polymer or prepolymer, or a positive or negative resist-type resin which can be structured by crosslinking, polymerization or depolymerization by applying heat or electromagnetic irradiation.The compositions can be applied to optical and thermal recording, printing, and the production of color filters for Liquid Crystal Displays, with high accuracy, high transparency and high stability.
    Type: Grant
    Filed: December 3, 1998
    Date of Patent: March 21, 2000
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ulrich Schadeli, John S. Zambounis, Abul Iqbal, Zhimin Hao, Henri Dubas
  • Patent number: 6030749
    Abstract: A photosensitive resin composition comprising (A) a binder polymer and/or a prepolymer; (B) an ethylenically unsaturated compound; (C) a radical producer capable of producing a free radical upon exposure to an ultraviolet ray of 300 to 400 nm; and (D) an anthraquinone dye capable of exhibiting a color change upon exposure to an ultraviolet ray having a wavelength in the range of 300 to 400 nm in the presence of the radical producer (C). This photosensitive resin composition, upon exposure through a negative mask to an ultraviolet ray of a wavelength in a specific range and of a quantity larger than a threshold value, can form a photoresin product having image and non-image portions which are different in color from each other, and, hence, this composition can advantageously be used in the fields of printing plates and resists.
    Type: Grant
    Filed: March 20, 1992
    Date of Patent: February 29, 2000
    Assignee: Asahi Kasei Kogyo Kabushiki Kaisha
    Inventor: Katsuhiro Takahashi
  • Patent number: 6020106
    Abstract: Transparent molded articles having a high-contrast laser inscription thereon are produced from a polymer mixture consisting ofA) from 40 to 99% by weight of a polymer of an alkyl ester of (meth)acrylic acid,B) from 1 to 50% by weight of a copolymer of styrene and acrylonitrile having an acrylonitrile content of from 8 to 30% by weight,C) from 0 to 50% by weight of rubber particles, andD) from 0 to 20% by weight of additives and processing auxiliaries, by preparing a transparent molded article from the polymer mixture, and exposing the transparent molded article to laser radiation.
    Type: Grant
    Filed: December 4, 1996
    Date of Patent: February 1, 2000
    Assignee: BASF Aktiengesellschaft
    Inventors: Graham Edmund Mc Kee, Martin Welz, Andreas Deckers, Daniel Wagner, Paul Otto Damm, Hans-Josef Oslowski
  • Patent number: 5958651
    Abstract: Artwork is imparted to plastic discs such as CDs, CD ROMs, and DVDs (digital video discs) by exposing a layer of photoresist material on a substrate to light from an original image of the artwork. The material of the photoresist layer is exposed to different depths by different intensity light from different image regions. Where the image is dark, the exposure is to relatively shallow, random depths. Where the image is light, the full thickness of the photoresist layer is exposed. Development of the photoresist layer removes the exposed photoresist material. The surface features of the developed photoresist layer and any uncovered substrate are transferred to a member used in forming a surface of the plastic disc, thereby visibly embossing the image in the disc.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: September 28, 1999
    Assignee: WEA Manufacturing Inc.
    Inventors: Peter van Hoof, John Joseph Parette, John F. Pierzga
  • Patent number: 5942370
    Abstract: A method of producing a three-dimensional object having selected elements which are colored differently than other elements of the object comprising the steps of:(a) providing a film of a photohardenable composition containing a photoresponsive agent,(b) radiating the film in a cross-sectional pattern of the object to be formed,(c) selectively irradiating one or more portions of the cross-sectional pattern corresponding to the selected elements which are desired to be colored differently with radiation which activates the photoresponsive agent, the photoresponsive agent thereby producing color in or removing color from the selected irradiated portions of the cross-sectional pattern,(d) repeating steps a, b, and c to form successive adjacent cross-sectional pattern of the object, and(e) integrating the cross-sectional patterns together to provide the three-dimensional object, wherein the curing and coloring steps are conducted using actinic radiation.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: August 24, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventor: Douglas C. Neckers
  • Patent number: 5879855
    Abstract: Compositions for making structured color images comprising (a) a soluble pigment precursor which can be transformed to an insoluble pigment by means of chemical, thermal, photolytic or radiation-induced method, and (b) a binder polymer or prepolymer, or a positive or negative resist-type resin which can be structured by crosslinking, polymerization or depolymerization by applying heat or electromagnetic irradiation. The compositions can be applied to optical and thermal recording, printing, and the production of color filters for Liquid Crystal Displays, with high accuracy, high transparency and high stability.
    Type: Grant
    Filed: November 18, 1994
    Date of Patent: March 9, 1999
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Ulrich Schadeli, John S. Zambounis, Abul Iqbal, Zhimin Hao
  • Patent number: 5853952
    Abstract: There is disclosed a color developing resin composition comprising a base polymer, a dialdehyde represented by the general formula OHC--R.sup.1' --CHO, a diamine represented by the general formula H.sub.2 N--R.sup.2' --NH.sub.2 (at least one of R.sup.1' and R.sup.2' is an aromatic group), a compound which produces an acid by light irradiating and a resin which is crosslinked with the acid.
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: December 29, 1998
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Toru Ushirogouchi, Makoto Nakase, Akira Yoshizumi, Naoko Kihara, Takuya Naito, Naomi Shida, Koji Asakawa
  • Patent number: 5811219
    Abstract: A pigment-dispersed photoresist composition for a color filter of liquid crystal display, which comprises a photosensitive resin composition comprising a binder resin, a multifunctional acrylate monomer or oligomer, a polyene compound containing at least unsaturated group the main chain of which may be substituted with esters or urethanes, a multifunctional thiol compound, a photopolymerization initiator, a sensitizer, a soft polymerization inhibitor and an organic solvent, and a pigment-dispersed composition comprising pigment, a polymeric dispersing agent and/or a pigment-derived dispersing agent in combination with a surfactant a leveling agent, a slip agent, an antifoaming agent and an organic solvent, is disclosed.
    Type: Grant
    Filed: January 18, 1996
    Date of Patent: September 22, 1998
    Assignee: Cheil Synthetics Incorporation
    Inventors: Tae Whan No, Dae Woo Im, Soon Sik Kim, Sang Woon Lee
  • Patent number: 5741621
    Abstract: A process for preparing an image on a substrate by applying a photoimageable composition on a first substrate, wherein the photoimageable composition, having a solids content from 25 to 60 weight percent, contains a partially neutralized acid-containing polymer formed from a precursor polymer having an acid number from 90 to 160 prior to neutralization and wherein 1 to 15% of acid-containing groups of the precursor polymer are neutralized with base; an ethylenically unsaturated monomer; a photoinitiator or photoinitiating system, water; 0-5% by weight a solution polymer, based on the weight of total polymer present in the composition; and 0-25% by weight of an organic solvent based on the total weight of the organic solvent and water; wherein the liquid composition is present as a stable emulsion, and wherein the liquid composition has a Brookfield viscosity, at 25.degree. C.
    Type: Grant
    Filed: December 23, 1996
    Date of Patent: April 21, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Richard Joseph Kempf, John Haetak Choi, Harvey Walter Taylor, Jr.
  • Patent number: 5721077
    Abstract: A photosensitive colored material mainly composed of an aromatic polyamide or polyimide resin having a photosensitive group in its molecule, a coloring matter, and a solvent, wherein; said solvent comprises a first solvent component capable of independently dissolving said resin alone and a second solvent component having a smaller surface tension than said first solvent component and incapable of independently solving said resin; and the content of said first solvent component is larger than the content of said second solvent component.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: February 24, 1998
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hideaki Takao, Kazuya Ishiwata, Noriyuki Nakai, Naoya Nishida, Tatsuo Murata
  • Patent number: 5721089
    Abstract: A photosensitive colored material mainly composed of an aromatic polyamide or polyimide resin having a photosensitive group in its molecule, a coloring matter, and a solvent, wherein; said solvent comprises a first solvent component capable of independently dissolving said resin alone and a second solvent component having a smaller surface tension than said first solvent component and incapable of independently solving said resin; and the content of said first solvent component is larger than the content of said second solvent component.
    Type: Grant
    Filed: May 19, 1994
    Date of Patent: February 24, 1998
    Assignee: Canon Kabushiki Kaisha
    Inventors: Hideaki Takao, Kazuya Ishiwata, Noriyuki Nakai, Naoya Nishida, Tatsuo Murata
  • Patent number: 5712223
    Abstract: A dye-donor or recording element comprising a support having thereon a dye layer comprising a yellow dye in a polymeric binder, the dye having the formula: ##STR1## wherein: R.sup.1, R.sup.2, R.sup.3 and R.sup.4 each independently represents hydrogen, halogen, hydroxy, nitro, a substituted or unsubstituted alkyl or alkoxy group of from 1 to about 6 carbon atoms, a substituted or unsubstituted phenyl group, an alkylazo group, or an arylazo group;or any two adjacent R.sup.1, R.sup.2, R.sup.3 and R.sup.4 groups may be taken together with the phenyl ring to which they are attached to form a fused ring system; andZ.sup.1 and Z.sup.2 each independently represents hydrogen or a moiety having a Hammet Sigma (meta) Constant greater than 0.3, such as cyano, esterified carboxy, amide, benzoxazole, alkylsulfonyl, arylsulfonyl; or may be taken together to form a group having a Hammer Sigma (meta) Constant greater than 0.3.
    Type: Grant
    Filed: September 16, 1996
    Date of Patent: January 27, 1998
    Assignee: Eastman Kodak Company
    Inventors: Charles David DeBoer, Douglas Robert Robello, Lee William Tutt
  • Patent number: 5712025
    Abstract: Monochrome and polychrome color proofs, for the graphic arts industry, having an image carrier containing two layers A and B to control optical dot growth are described. Layer A contains at least one polyolefin and, in a preferred embodiment, a light-reflecting white pigment. Layer B contains at least one binder, at least one light-reflecting white pigment at between 50% and 90% by weight relative to Layer B, and at least one light-absorbing pigment. A process and a means for preparing such monochrome and polychrome color proofs are described.
    Type: Grant
    Filed: August 28, 1996
    Date of Patent: January 27, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Bernhard Metzger, Ursula Annerose Kraska, Mario Grossa
  • Patent number: 5707777
    Abstract: A positive-working light-sensitive composition which comprises:(a) 0.5 to 80% by weight of a compound which has at least one group capable of being decomposed by an acid and whose solubility in an alkaline developer is increased by an acid;(b) 0.01 to 20% by weight of a disulfone compound represented by the following formula (I);R.sup.1 --SO.sub.2 --SO.sub.2 --R.sup.2 (I)wherein R.sup.1 and R.sup.2 may be the same or different and represent a substituted or unsubstituted alkyl, alkenyl or aryl group; and(c) 5 to 99.49% by weight of a resin insoluble in water and soluble in an alkaline water,wherein the compound of the component (a) has a molecular weight of not more than 2,000 and a boiling point of not less than 150.degree. C. and wherein a film of the composition having a thickness of 1 .mu.m has an optical density determined at 248 nm of not more than 1.4 before exposure to light and the optical density of the composition determined at 248 nm is reduced by exposure to light of 248 nm.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: January 13, 1998
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiaki Aoai, Tadayoshi Kokubo
  • Patent number: 5677107
    Abstract: A method for producing a three-dimensional object having selected elements which are colored differently than other elements of the object comprising the steps of: (a) providing a film of a photohardenable composition containing a photoresponsive agent; (b) irradiating the film in a cross-sectional pattern of the object to be formed; (c) selectively irradiating one or more portions of the cross-sectional pattern corresponding to the selected elements which are desired to be colored differently with radiation which activates the photoresponsive agent, the photoresponsive agent thereby producing color in or removing color from the selected irradiated portions of the cross-sectional pattern; (d) repeating the steps a, b and c to form successive adjacent cross-sectional patterns of the object; and (e) integrating the cross-sectional patterns together to provide the object.
    Type: Grant
    Filed: May 6, 1996
    Date of Patent: October 14, 1997
    Assignee: Spectra Group Limited, Inc.
    Inventor: Douglas C. Neckers
  • Patent number: 5672410
    Abstract: A process for preparing embossed, finely-divided, thin, bright-metal particles which process comprises forming an embossed release surface to at least one side of a carrier sheet, depositing a metal film onto the release surface so that the metal film conforms to the embossed surface, solubilizing the release surface, removing the metal film from the carrier sheet, and breaking the thin metal film into embossed particles having an average diameter of between 25 to 50 microns. The film may also take the form of an optical stack.
    Type: Grant
    Filed: February 9, 1993
    Date of Patent: September 30, 1997
    Assignee: Avery Dennison Corporation
    Inventors: Richard G. Miekka, Dennis R. Benoit, Richard M. Thomas, James P. Rettker, Karl Josephy
  • Patent number: 5665522
    Abstract: Positive-acting no-process printing plates are disclosed in which a stable visual or print-out image is obtained upon exposure of the plate to actinic radiation. The visual image is obtained by incorporation into the photosensitive layer, a dye which is irreversibly bleached upon exposure of the printing plate. For example, an acid which is generated upon exposure of a photopolymer to radiation may be used to bleach a dye of this invention. The visual or print-out images produced are useful in the production cycle and are stable to basic environments that may be encountered in the production setting.
    Type: Grant
    Filed: May 2, 1995
    Date of Patent: September 9, 1997
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Dennis E. Vogel, Robert J. Balchunis, James P. Gardner, George V.D. Tiers, Kim M. Vogel
  • Patent number: 5637438
    Abstract: Described is a photosensitive material for producing metal-colored images, comprisingA) a flexible transparent plastic support film,B) a photosensitive layer comprising a polymeric binder, a photosensitive substance and a pearl luster pigment, and optionallyC) a thermoplastic adhesion-promoting layer.The material of the invention makes it possible to produce color-proofing images for metal-colored multicolor prints by combining metal-colored single-color images with single-color images in the usual primary colors as desired.
    Type: Grant
    Filed: November 23, 1994
    Date of Patent: June 10, 1997
    Assignee: AGFA-Gevaert AG
    Inventors: Karin Maerz, Silvia Neumann, Dieter Mohr
  • Patent number: 5635284
    Abstract: Monochrome and polychrome color proofs, for the graphic arts industry, having an image carrier containing two layers A and B to control optical dot growth are described. Layer A contains at least one polyolefin and, in a preferred embodiment, a light-reflecting white pigment. Layer B contains at least one binder, at least one light-reflecting white pigment at between 50% and 90% by weight relative to Layer B, and at least one light-absorbing pigment. A process and a means for preparing such monochrome and polychrome color proofs are described.
    Type: Grant
    Filed: October 14, 1994
    Date of Patent: June 3, 1997
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Bernhard Metzger, Ursula A. Kraska, Mario Grossa
  • Patent number: 5633118
    Abstract: A process of forming a single color image comprising:a) imagewise exposing, by means of a laser, a dye-ablative recording element comprising a support having thereon, in order, a hydrophilic dye-receiving layer, a hydrophobic dye-barrier layer, and a hydrophilic, water-soluble, infrared-absorbing layer which absorbs at a given wavelength of the laser used to expose the element, thereby imagewise heating the infrared-absorbing layer and the dye-barrier layer, causing them to ablate;b) removing the ablated infrared-absorbing layer and dye-barrier layer material;c) contacting the imagewise-exposed element with an aqueous ink solution and thereby removing the remaining infrared-absorbing layer; andd) drying the element to obtain a single color image in the ablative recording element.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: May 27, 1997
    Assignee: Eastman Kodak Company
    Inventors: Mitchell S. Burberry, Lee W. Tutt, Sharon W. Weber
  • Patent number: 5633119
    Abstract: A process of forming a single color image comprising:a) imagewise exposing, by means of a laser, a dye-ablative recording element comprising a support having thereon, in order, a hydrophilic dye-receiving layer and a hydrophobic dye-barrier layer, at least one of the dye-receiving layer and the dye-barrier layer having an infrared-absorbing material therein or in a layer therebetween to absorb at a given wavelength of the laser used to expose the element, thereby imagewise heating the dye-barrier layer and causing it to ablate;b) removing the ablated dye-barrier layer material;c) contacting the imagewise-exposed element with an aqueous ink solution; andd) drying the element to obtain a single color image in the ablative recording element.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: May 27, 1997
    Assignee: Eastman Kodak Company
    Inventors: Mitchell S. Burberry, Lee W. Tutt
  • Patent number: 5587272
    Abstract: This invention makes available processes for preparing images, especially color proofs. A layer with imagewise tacky and nontacky areas is toned. Toner adhering to the tacky areas is transferred first onto a temporary support and from there onto an image receptor.
    Type: Grant
    Filed: December 7, 1995
    Date of Patent: December 24, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Mario Grossa, Udo D. Bode, Manfred Sondergeld, Karl-Heinz Wiedenmann, Ronald J. Convers, Steven M. Kalo, Ashok K. Kudva
  • Patent number: 5578412
    Abstract: A photosensitive element comprising, in order a support; a photosensitive layer comprising a photosensitive composition; and a layer comprising a thermally sensitive material; wherein the thermally sensitive material is (a) incompatible with the photosensitive composition, (b) non-tacky and non-blocking at room temperature, and (c) tackifiable at 70.degree. C. to 120.degree. C. and a process for using these elements is described. The photosensitive element may be in sheet or roll form.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: November 26, 1996
    Assignee: E. I. DuPont de Nemours and Company
    Inventors: Robert P. Held, Massimo Pizzocri, Harvey W. Taylor
  • Patent number: 5573887
    Abstract: The invention relates to a method of transferring an image of a master pattern by an intermediate carrier being a laser copy of the master pattern onto a carrier, for example a plate of metal. The surface of the carrier is provided on one side with a layer of a couch or with a layer of a lacquer or with a layer of a thermoplastic or elastomeric material or with a powder coating which is dried at an increased temperature. The material forming the image penetrates under the action of heat and pressure into the layer or the powder coating thus softened which is subsequently after-baked. A weather-resistant and scratch-resistant copy of the master pattern is provided.
    Type: Grant
    Filed: October 31, 1994
    Date of Patent: November 12, 1996
    Assignee: Intron Ingenieur-Unternehmung AG
    Inventor: Karl Genz
  • Patent number: 5565301
    Abstract: A process for forming a colored image comprising, in order:(A) imagewise exposing to actinic radiation a photosensitive element comprising a carrier support, a carrier surface, a first adhesive layer and a first photosensitive layer,(B) developing the exposed first photosensitive layer,(C) laminating to the element a transfer element comprising a transfer support, and a transfer surface layer which is adjacent to a colored pattern in the element of step (A) with the proviso that the transfer element does not have an adhesive layer which transfers to the colored pattern,(D) removing said carrier support and said carrier surface, revealing said first adhesive layer,(E) laminating the element the element from step (D) to a permanent support wherein the first adhesive layer is adjacent to the permanent support; and(F) removing said transfer support and said transfer surface layer.
    Type: Grant
    Filed: August 2, 1993
    Date of Patent: October 15, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Gregory A. Bodager
  • Patent number: 5534380
    Abstract: A tonable, aqueous-processable, photosensitive element and process for forming a colored image from said element is described. The element comprises a support and a tonable, aqueous-processable photosensitive layer, said photosensitive layer consisting essentially of (a) an aqueous-processable, photoinsolubilizable photosensitive composition comprising a photosensitive material, and (b) a water-soluble plasticizer, wherein said photosensitive material is present in sufficient amount to insolubilize said photosensitive layer on exposure to actinic radiation, said photosensitive composition is present in sufficient amount to form a layer when said photosensitive layer is coated, and said plasticizer is present in sufficient amount to make said photosensitive layer.
    Type: Grant
    Filed: November 28, 1994
    Date of Patent: July 9, 1996
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Gregory A. Bodager, Bruce M. Monroe
  • Patent number: 5534373
    Abstract: A photosensitive material comprising (A) a flexible transparent film support, (B) a colored photosensitive layer which contains an organic binder (B1) a dye or a colored pigment (B2), a compound (B3), which forms a strong acid on exposure to radiation, and a compound (B4) which has at least one group cleavable by the acid, and (C) an adhesion-promoting layer which contains a thermoplastic polymer which has a softening temperature in the range from 40.degree. to 200.degree. C., wherein the adhesion (a.sub.1) of the unexposed photosensitive layer (B) to the adhesion-promoting layer (C) is less than the adhesion (a.sub.3) of the unexposed photosensitive layer (B) to the film support (A) and than the cohesions of the layers (B) and (C), and the adhesion (a.sub.3 ') of the exposed photosensitive layer (B) to the film support (A) is less than the adhesion (a.sub.
    Type: Grant
    Filed: April 19, 1995
    Date of Patent: July 9, 1996
    Assignee: Agfa-Gevaert AG
    Inventors: Stephan J. W. Platzer, Andrea Buchmann, Gerhard Buhr
  • Patent number: 5529883
    Abstract: A photosensitive material comprising (A) a flexible transparent film support, (B) a colored photosensitive layer which contains an organic binder (B1) a dye or a colored pigment (B2), a compound (B3), which forms a strong acid on exposure to radiation, and a compound (B4) which has at least one group cleavable by the acid, and (C) an adhesion-promoting layer which contains a thermoplastic polymer which has a softening temperature in the range from 40.degree. to 200.degree. C., wherein the adhesion (a.sub.1) of the unexposed photosensitive layer (B) to the adhesion-promoting layer (C) is less than the adhesion (a.sub.3) of the unexposed photosensitive layer (B) to the film support (A) and than the cohesions of the layers (B) and (C), and the adhesion (a.sub.3 ') of the exposed photosensitive layer (B) to the film support (A) is less than the adhesion (a.sub.
    Type: Grant
    Filed: August 10, 1994
    Date of Patent: June 25, 1996
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Stephan J. W. Platzer, Andrea Buchmann, Gerhard Buhr
  • Patent number: 5514519
    Abstract: A method for producing a three-dimensional object having selected elements which are colored a different color than the color of other elements of the object, comprising the steps of:a. providing a film of a photohardenable composition containing a photoresponsive agent,b. irradiating the film in a cross-sectional pattern of the object to be formed so as to form hardened areas in the film.c. selectively irradiating one or more portions of the cross-sectional pattern corresponding to the selected elements which are desired to be colored a different color than the color of other elements of the object with radiation which activates the photoresponsive agent, the photoresponsive agent thereby producing color in or removing color from the selectively irradiated portions of the cross-sectional pattern, the steps being performed with radiation of a different wavelength than the radiation used in performing step b,d. repeating steps a, b and c to form successive adjacent cross-sectional patterns of the object, ande.
    Type: Grant
    Filed: April 7, 1994
    Date of Patent: May 7, 1996
    Assignee: Spectra Group Limited, Inc.
    Inventor: Douglas C. Neckers
  • Patent number: 5489621
    Abstract: A light-shielding light-sensitive resin composition containing at least (1) an alkali soluble binder, (2) a photopolymerization initiator, (3) an addition-polymerizable monomer having an ethylenically unsaturated double bond, and (4) at least two coloring agents, wherein the light-shielding light-sensitive resin composition is characterized in that said resin composition is equivalent or close to a black color in terms of hue and, when formed into a light-shielding light-sensitive resin layer having a layer thickness of 1 to 3 micrometers, has a transmittability in a visible ray region of 2 or less and a ratio of the transmittability in the visible region to the transmittability in the UV region of 1:1 to 20:1.
    Type: Grant
    Filed: May 12, 1994
    Date of Patent: February 6, 1996
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morimasa Sato, Masayuki Iwasaki, Takekatsu Sugiyama
  • Patent number: 5474875
    Abstract: A photosensitive mixture useful for producing relief and printing plates consists essentially of(a) at least one block copolymer of styrene, butadiene and/or isoprene,(b) at least one photopolymerizable olefinically at least monounsaturated organic compound,(c) at least one photoinitiator, and(d) at least one azo dye.
    Type: Grant
    Filed: November 28, 1994
    Date of Patent: December 12, 1995
    Assignee: BASF Lacke+Farben
    Inventors: Thomas Loerzer, Thomas Telser, Thomas Zwez
  • Patent number: 5462834
    Abstract: Photographic images may be produced on a backing such as paper and polyester sheets, from photographic negatives which encompass line rendering, design comps, copy, complex color separation or the like with water-based varnishes and pigments, the resulting images closely resembling, if not exactly, the same image in its commercially printed form. Thus all aspects of color proofs produced by this invention provide greatly improved predictability as to the appearance of the final printed job, with a further improvement of cost savings over conventional techniques of preparing color proofs. Also, said proofing method can be used to provide a "transfer" so that one may transfer the colored image or images to a more suitable or required backing.
    Type: Grant
    Filed: January 6, 1994
    Date of Patent: October 31, 1995
    Inventors: Edward L. Weller, Jr., Edward J. Renkor, Edward L. Weller, III
  • Patent number: 5455142
    Abstract: An image formation process uses two light-sensitive elements comprising first and second adhesive light-sensitive layers which become nonadhesive upon exposure to light, respectively, and first and second toner elements comprising toner layers (a') and (b') of hues (a) and (b), respectively.
    Type: Grant
    Filed: October 21, 1992
    Date of Patent: October 3, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yohnosuke Takahashi, Hideyuki Nakamura, Fumiaki Shinozaki, Shinji Tsuno
  • Patent number: 5451485
    Abstract: A dye-ablative recording element comprising a support having thereon an interlayer containing an inorganic hydrate salt, the interlayer being overcoated with a dye layer comprising an image dye dispersed in a polymeric binder, and the dye layer having an infrared-absorbing material associated therewith.
    Type: Grant
    Filed: March 4, 1994
    Date of Patent: September 19, 1995
    Assignee: Eastman Kodak Company
    Inventors: Linda Kaszczuk, Lee W. Tutt, Richard W. Topel, Jr., Steven Evans
  • Patent number: 5439775
    Abstract: An image formation process uses two light-sensitive elements comprising first and second adhesive light-sensitive layers which become nonadhesive upon exposure to light, respectively, and first and second toner elements comprising toner layers (a') and (b') of hues (a) and (b), respectively.
    Type: Grant
    Filed: December 14, 1994
    Date of Patent: August 8, 1995
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yohnosuke Takahashi, Hideyuki Nakamura, Fumiaki Shinozaki, Shinji Tsuno
  • Patent number: 5436112
    Abstract: This invention provides novel ethylenically unsaturated urethane monomers and photoreactive compositions comprising such monomers as essential constituents. The monomers can be photopolymerized or photocrosslinked and are useful in coating systems and multilayer color proofing systems. Additionally, they offer superior advantages such as significantly reduced migration between layers in multilayer color proofing systems.
    Type: Grant
    Filed: April 1, 1994
    Date of Patent: July 25, 1995
    Assignee: Hoechst Celanese Corporation
    Inventors: Shane Hsieh, Wojciech A. Wilczak
  • Patent number: 5427894
    Abstract: A process for preparing images on tonable, light-sensitive layers using a transfer material comprising (a) a support, (b) a transfer layer containing in its binder a finely divided powder or a finely divided powder and a dissolved dye, and (c) a cover layer containing a binder and/or discrete, inert particles is described. Such transfer materials can be used to make color proof prints having high resolution, reproducible color density, low dot growth, and no troublesome background fog.
    Type: Grant
    Filed: June 12, 1992
    Date of Patent: June 27, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Bernhard Metzger
  • Patent number: 5411822
    Abstract: A shadow mask includes a mask substrate having vertical and horizontal axes passing through a center of the substrate, and a number of substantially rectangular apertures. The apertures are arranged so that a plurality of vertical trains of apertures extending parallel to the vertical axis are arranged at predetermined intervals in the direction of the horizontal axis. Each of the apertures other than the apertures located on the vertical axis has a pair of outer corners distant from the vertical axis, a pair of inner corners less distant from the vertical-axis side, and a pair of bulging portions extending from the outer corners, respectively, outward in the horizontal direction. The farther each of the apertures is located from the vertical axis, the longer the bulging portions extend outward.
    Type: Grant
    Filed: August 18, 1993
    Date of Patent: May 2, 1995
    Assignee: Kabushiki Kaisha Toshiba
    Inventors: Yasuhisa Ohtake, Seiji Sago, Yasushi Magaki
  • Patent number: 5401603
    Abstract: A tonable, aqueous-processable, photosensitive element and process for forming a colored image from said element is described. The element comprises a support and a tonable, aqueous-processable photosensitive layer, said photosensitive layer consisting essentially of (a) an aqueous-processable, photoinsolubilizable photosensitive composition comprising a photosensitive material, and (b) a water-soluble plasticizer, wherein said photosensitive material is present in sufficient amount to insolubilize said photosensitive layer on exposure to actinic radiation, said photosensitive composition is present in sufficient amount to form a layer when said photosensitive layer is coated, and said plasticizer is present in sufficient amount to make said photosensitive layer.
    Type: Grant
    Filed: February 15, 1994
    Date of Patent: March 28, 1995
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Gregory A. Bodager, Bruce M. Monroe
  • Patent number: 5397683
    Abstract: A photochemical method of making a tactile design comprises the steps of exposing to light a selected portion of photo-sensitive layer-supported by a substrate; applying a decorative coating to the photo-sensitive layer; applying a photo-sensitive emulsion over the decorative coating; exposing to light the same selected portion of the photo-sensitive emulsion; and removing the photo-sensitive emulsion, the decorative coating, and the photo-sensitive layer from the non-selected portions. The tactile design comprises a layer of photo-sensitive material fixedly attached to a selected portion of a substrate wherein the layer has been exposed to light and the layer projects away from the surface of the substrate a sufficient distance to be sensitive to the touch. At least one decorative coating is fixedly attached to the photo-sensitive layer.
    Type: Grant
    Filed: March 24, 1993
    Date of Patent: March 14, 1995
    Inventor: Gerald Roland
  • Patent number: 5395737
    Abstract: An imaging element is disclosed comprising on a support a dye precursor and a color developer arranged in the same layer or in separate layers characterized in that a specific type of monomers according to one of formulas (I) or (II) and a photoinitiator is present in a layer containing said dye precursor and/or color developer. The imaging element of the invention can used as photosensitive as well as heat-sensitive imaging element for obtaining an image.
    Type: Grant
    Filed: July 30, 1993
    Date of Patent: March 7, 1995
    Assignee: Agfa-Gevaert, N.V.
    Inventors: Wolfgang Podszun, Herman J. Uytterhoeven, Michael Muller
  • Patent number: 5374496
    Abstract: An image forming method is conducted by subjecting a dry silver salt image forming medium to imagewise exposure and heating to form a light-absorbing organic compound. Thereafter, the medium is subjected to polymerization exposure to imagewise polymerize the medium based on the formation pattern of the light-absorbing compound. The light-absorbing organic compound has specific sensitivities to light in order to maximize contrast.
    Type: Grant
    Filed: September 10, 1993
    Date of Patent: December 20, 1994
    Assignee: Canon Kabushiki Kaisha
    Inventors: Kenji Kagami, Akihiro Mouri, Masato Katayama, Kazuo Isaka, Tetsuro Fukui, Susumu Nakamura, Masao Suzuki
  • Patent number: 5372910
    Abstract: A process for preparing images on a tonable, light-sensitive layer using a transfer layer containing at least 20 percent by weight of a toner and a polymer with a maximum tensile strength of at least 2 N/mm.sup.2 as a binder. The pigmented transfer layers can be used in color proofing processes requiring high resolution, reproducible color density and low dot gain.
    Type: Grant
    Filed: November 3, 1993
    Date of Patent: December 13, 1994
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Bernhard Metzger, Helmet H. Frohlich
  • Patent number: 5373039
    Abstract: A resin composition suitable for marking with a laser and a method for laser marking said resin are provided. The resin composition comprises a thermoplastic resin, one or more compounds selected from the group consisting essentially of (i) tetrazole compounds, and (ii) sulfonylhydrazide, nitroso and azo compounds having a decomposition temperature of at least 210.degree. C., and carbon black.
    Type: Grant
    Filed: May 25, 1993
    Date of Patent: December 13, 1994
    Assignee: General Electric Company
    Inventors: Kenichi Sakai, Takuro Kitamura, Hideki Kato
  • Patent number: 5372917
    Abstract: The present invention provides a recording material utilizing a reaction between a colorless or light-colored dye precursor and a color developer capable of forming a color upon coming into contact with the dye precursor, the recording material being characterized in that the material comprises at least one compound serving as the dye precursor and represented by the formula (1), and an acidic substance serving as the color developer ##STR1## wherein R.sub.1 to R.sub.6, p and q are defined in the specification. At least one selected from the group consisting of phenolic compounds of the formulae (10), (11) and (12) and phenolic resin having a partial structure of the formula (13) can be used, as required, to further improve the color forming properties and change the color of recorded images from reddish purple or purple to blue or dark blue.
    Type: Grant
    Filed: June 29, 1993
    Date of Patent: December 13, 1994
    Assignee: Kanzaki Paper Manufacturing Co., Ltd.
    Inventors: Tetsuo Tsuchida, Tatsuya Meguro, Takaaki Kouro, Haruo Omura
  • Patent number: 5368991
    Abstract: Disclosed is a photosensitive resin composition for use in a light-shielding film, comprising a photosensitive resin and a light-shielding coloring material, wherein light transmission properties after formation of the light-shielding film are controlled by the light-shielding coloring material so that (i) the light transmission through the light-shielding film is 1% or more in at least one wavelength of a light wavelength region of from 330 nm to less than 425 nm, and (ii) the light transmission through the light-shielding film is 2% or less in a light wavelength region of from 425 to 650 nm.
    Type: Grant
    Filed: July 21, 1993
    Date of Patent: November 29, 1994
    Assignee: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Kiyoshi Uchikawa, Hiroshi Komano, Toshimi Aoyama, Katsuyuki Ohta
  • Patent number: 5364739
    Abstract: An X-Ray sensitive composition including one or several photopolymerizable monomer or photocrosslinkable polymer systems and thermochromic substances which can be used in a dry X-Ray reproduction process. The process is based on the different dielectric constants and dielectric losses exhibited by a monomer and the corresponding polymer or a polymer and the crosslinked polymer and the reaction of certain thermochromic substances which exhibits a specific threshold temperature above which these substances change from a colorless form to a color stable form. The X-Ray sensitive element is exposed according to a pattern of X-Ray with spatial modulation providing an X-Ray image to form a latent image of polymerized or crosslinked zones and unpolymerized or non crosslinked zones.
    Type: Grant
    Filed: February 13, 1992
    Date of Patent: November 15, 1994
    Assignee: Board of Regents, The University of Texas System
    Inventor: Jean J. Robillard