Substituted At Coupling Position With Other Than Hydrogen Patents (Class 430/385)
  • Patent number: 4315069
    Abstract: Color photographic material is described in which a yellowish image is formed which can be used to print black and white prints. Also present in the layer is a small amount of a more reactive coupler which produces a colored image to which black and white paper is not sensitive. This more reactive coupler reduces the fog in the highlight areas.Most preferably small amounts of other couplers are present which result in a green or brown image which makes it easier for the operator to focus the image.
    Type: Grant
    Filed: September 11, 1980
    Date of Patent: February 9, 1982
    Assignee: Ciba Geigy AG
    Inventors: John G. V. Scott, Anthony K. Harvey
  • Patent number: 4310618
    Abstract: Novel dye-forming couplers have the structure: ##STR1## wherein: Z represents the atoms to complete, with the attached oxygen atom, the same or different 5-pyrazolone dye-forming coupler moiety, phenol dye-forming coupler moiety or naphthol dye-forming coupler moiety, the * in the ring completed by Z representing the coupling position;R is hydrogen or a coupling-off group;Bl is a blocking group removable, during development, from the coupler moiety completed by Z to which it is directly attached; andn is an integer of 2 to 4.
    Type: Grant
    Filed: May 30, 1980
    Date of Patent: January 12, 1982
    Assignee: Eastman Kodak Company
    Inventors: Jose M. Fernandez, Joseph P. Pepe
  • Patent number: 4304844
    Abstract: A method for forming a cyan dye image by developing an exposed silver halide photographic material with a developer containing a color developing agent in the presence of a cyan coupler, wherein the coupler is a 2,5-diacylaminophenol in which each acylamino group has a substituent containing an oxycarbonyl, sulfonyloxy, oxysulfonyl, arylsulfonamide or arylsulfamoyl group or other organic group containing a sulfone group.
    Type: Grant
    Filed: May 1, 1980
    Date of Patent: December 8, 1981
    Inventors: Wataru Fujimatsu, Yasushi Usagawa, Osamu Sasaki, Katsumi Matsuura
  • Patent number: 4299914
    Abstract: A method for forming a cyan dye image by development of an exposed silver halide photographic material with a developer containing a cyan coupler of the following formula: ##STR1## in which R represents hydrogen atom or an alkyl group having a carbon number of one to twenty; R.sub.1 represents an alkylsulfonamide or alkylsulfamoyl group; R.sub.2 represents an alkyl, aryl group or a 5 or 6-membered heterocyclic group containing a nitrogen, oxygen or sulfur atom; R.sub.3 represents a hydrogen or halogen atom; X represents an alkylene, metaphenylene or orthophenylene group; Z represents a hydrogen atom or a split-off radical; and n has an integral value of one or two.
    Type: Grant
    Filed: May 1, 1980
    Date of Patent: November 10, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Wataru Fujimatsu, Yasushi Usagawa, Osamu Sasaki, Katsumi Matsuura
  • Patent number: 4296200
    Abstract: A silver halide photographic light-sensitive material containing a colorless photographic cyan color forming coupler having, in a position for coupling with an oxidation product of an aromatic primary amine developing agent, a coupling-off group represented by the formula (I):--O--R--S--R.sub.1 (I)wherein R represents a substituted alkylene group or an unsubstituted or substituted alkenylene group, and said alkylene group or alkenylene group may be straight or branched chain; and R.sub.1 represents a substituted or unsubstituted alkyl group, an alkenyl group, an aralkyl group, an aralkenyl group, a cycloalkyl group or a heterocyclic group and said alkyl group, alkenyl group, aralkyl group and aralkenyl group may be straight or branched chain; and said heterocyclic group being connected with a thio group at the position of a carbon atom of the heterocyclic group.
    Type: Grant
    Filed: August 12, 1980
    Date of Patent: October 20, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Yukio Yokota
  • Patent number: 4296199
    Abstract: A silver halide photographic light-sensitive material is described containing a colorless photographic cyan color-forming coupler having, in a position for coupling with an oxidation product of an aromatic primary amine developing agent, a coupling-off group represented by the formula (I)--O--(R.sub.1 S).sub.x (R.sub.2 S).sub.y R.sub.3 (I)wherein R.sub.1 and R.sub.2 each represents an alkylene group; R.sub.3 represents an alkyl group, a cycloalkyl group, an aryl group, or a heterocyclic group; x represents a positive integer; and y represents 0 or a positive integer.The photographic cyan color-forming coupler exhibits excellent dispersibility and color-forming properties.
    Type: Grant
    Filed: June 19, 1980
    Date of Patent: October 20, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Yukio Yokota
  • Patent number: 4294900
    Abstract: A process for producing a multicolor optical filter by exposing a multilayer color photographic material comprising:(1) a silver halide emulsion layer containing a colored coupler (1b) which has one of cyan, magenta or yellow colors and which forms a dye of one of the other two colors than the color of the colored coupler by a coupling reaction with the oxidation product of an aromatic primary amine color developing agent, and(2) a silver halide emulsion layer containing (i) a silver halide emulsion having a sufficiently high sensitivity that it can be exposed without exposing emulsion layer (1) and without increasing the color density in emulsion layer (1) and (ii) a colored coupler (2b) which has the same color as that of the dye formed by the coupling reaction of the colored coupler (1b) and which forms a cyan, magenta or yellow dye but not the color of the colored coupler (1b) or the color of the dye formed by the coupling reaction of the colored coupler (1b); the exposure is through a stripe or mosaic fi
    Type: Grant
    Filed: February 22, 1980
    Date of Patent: October 13, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Toshiaki Aono
  • Patent number: 4294918
    Abstract: A color photographic silver halide light-sensitive material is described containing a colorless photographic cyan color-forming coupler having, in a position for coupling with the oxidation product of an aromatic primary amine developing agent, as a coupling-off group, at least one alkoxy group substituted with a sulfinyl group represented by the formula (I)-O-R-SO-R.sub.1 (I)wherein R represents a saturated or unsaturated, divalent aliphatic group which may be straight or branched chain and may be substituted; and R.sub.1 represents a substituted or unsubstituted straight or branched chain alkyl group, an alkenyl group, an aralkyl group, an aralkenyl group, a cycloalkyl group, an aryl group or a heterocyclic group; and said heterocyclic group being connected with a sulfinyl group on the position of a carbon atom of the heterocyclic group.
    Type: Grant
    Filed: July 14, 1980
    Date of Patent: October 13, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Yukio Yokota
  • Patent number: 4288532
    Abstract: A silver halide color photographic light-sensitive material comprising a support having thereon at least one silver halide emulsion layer, said photographic light-sensitive material containing at least one cyan color-forming coupler represented by the following general formula (I): ##STR1## wherein l represents 0, 1 or 2; X represents a group capable of being released upon the coupling reaction and having at least 6 carbon atoms; Y represents RCONH--, RNHCO-- or RNHCONH-- wherein R represents a hydrogen atom, a methyl group, an ethyl group or a methyl group substituted with one or more halogen atoms; n represents 1 or 2 and Y may be the same or different when n is 2; and the phenyl group can be substituted with a halogen atom, an alkyl group having 1 to 3 carbon atoms or an alkoxy group having 1 to 3 carbon atoms. The dyes formed from the cyan color-forming couplers have unusually good spectral absorption properties and exceptional fastness to light and heat.
    Type: Grant
    Filed: February 13, 1980
    Date of Patent: September 8, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yoshio Seoka, Kozo Aoki, Yukio Yokota, Seiiti Kubodera
  • Patent number: 4282312
    Abstract: A multilayer color photographic material having at least one red sensitive silver halide emulsion layer containing a cyan coupler of the formula (I): ##STR1## wherein X represents a hydrogen atom or a chlorine atom and n is a positive integer of 8 to 20, is processed by a color developer containing a developing agent of the formula (II): ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a hydrogen atom, a chlorine atom, a methyl group, an ethyl group, a methoxy group or an ethoxy group; R.sub.5 represents an alkyl group having 1 to 4 carbon atoms, an alkoxyalkyl group wherein the number of carbon atoms in said alkyl moiety is 1 to 4, or a group of the formula --(CH.sub.2).sub.m R.sub.6 ; R.sub.6 represents a hydroxy group, a methylsulfonamido group, or an ethylsulfonamido group; and m represents a positive integer of 1 to 4.
    Type: Grant
    Filed: December 18, 1979
    Date of Patent: August 4, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiyuki Watanabe, Takeshi Hirose, Morio Yagihara, Yukio Yokota
  • Patent number: 4268616
    Abstract: A process for forming photographic images comprising a silver image and a dye image, which comprises development processing an imagewise exposed silver halide photographic light-sensitive material in the presence of a carboxy- and sulfo-free naphthalene compound wherein at least two hydrogen atoms in the naphthalene nucleus are substituted at specific positions thereof as indicated in formula (I) below, and a 3-pyrazolidone compound.
    Type: Grant
    Filed: January 18, 1980
    Date of Patent: May 19, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Junkichi Ogawa, Tsutomu Hamanka
  • Patent number: 4254212
    Abstract: A photographic silver halide light-sensitive emulsion containing a cyan color forming colorless coupler having at the coupling position at which the coupler reacts with the oxidation product of an aromatic primary amine developing agent at least one alkoxy group having a sulfonyl group as a substituent and represented by the following general formula (I):--O--R--SO.sub.2 --R.sub.1 (I)wherein R represents a saturated or unsaturated divalent aliphatic group having 1 to 4 carbon atoms which may be straight or branched chain and may be substituted (except those having an aryl group as a substituent on the carbon atom adjacent the oxygen atom bonded to the coupling position); and R.sub.1 represents an aliphatic group, an aromatic group or a heterocyclic group; and wherein R and R.sub.1 can combine directly or through a bonding group to form a ring and an image-forming process.
    Type: Grant
    Filed: August 29, 1979
    Date of Patent: March 3, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Yukio Yokota, Akira Ogawa, Hiroshi Sawaguchi
  • Patent number: 4248962
    Abstract: Photographic couplers which release a photographically useful group by an intramolecular nucleophilic displacement reaction can be used in photographic emulsions, elements and processes to provide a photographically useful group in a controlled manner.
    Type: Grant
    Filed: December 22, 1978
    Date of Patent: February 3, 1981
    Assignee: Eastman Kodak Company
    Inventor: Philip T. S. Lau
  • Patent number: 4239851
    Abstract: A silver halide photographic light-sensitive material and a process for preparing the same are disclosed wherein an oil-soluble photographic additive and, in particular, a cyan coupler is dissolved in an epoxy compound of the formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents an alkyl group or substituted alkyl group containing 1 to 40 carbon atoms, an alkoxycarbonyl group or substituted alkoxycarbonyl group containing 1 to 40 carbon atoms, or a hydrogen atom, provided that R.sub.1, R.sub.2, R.sub.3 and R.sub.4 do not represent hydrogen atoms at the same time and that the sum of the number of carbon atoms of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 is 8 to 60, and R.sub.1, R.sub.2, R.sub.3 and R.sub.4 may be the same or different and may combine to form a ring; or in an epoxy compound formed by linking two compounds of said formula (I) which may be the same or different through any of R.sub.1 to R.sub.4 or the ring formed by R.sub.1 to R.sub.4.
    Type: Grant
    Filed: February 1, 1979
    Date of Patent: December 16, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Aoki, Yukio Yokota
  • Patent number: 4228233
    Abstract: A photographic silver halide light-sensitive emulsion containing a cyan dye forming, colorless coupler having, at the coupling position, an alkoxy group having at least one sulfonamido or sulfamoyl group as a substituent and represented by one of the following general formulae (I) and (II): ##STR1## wherein R represents a saturated or unsaturated, divalent aliphatic group (except those having an aryl group as a substituent on the carbon atom adjacent the oxygen atom bonded to the coupling position); R.sub.1, R.sub.3 and R.sub.4, which may be the same or different, each represents a hydrogen atom, an aliphatic group, or an aromatic group; and R.sub.2 represents an aliphatic group, an aromatic group or a heterocyclic group; and wherein R.sub.3 and R.sub.
    Type: Grant
    Filed: September 22, 1978
    Date of Patent: October 14, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Yukio Yokota
  • Patent number: 4208210
    Abstract: A process for forming an optical sound track comprising applying ultraviolet light exposure to an optical sound track area of a multi-layer color photographic light-sensitive material comprising a support, color image-forming silver halide emulsion layers consisting of at least one blue-sensitive silver halide emulsion layer containing a yellow dye-forming coupler, at least one red-sensitive silver halide emulsion layer containing a cyan dye-forming coupler, and at least one green-sensitive silver halide emulsion layer containing a magenta dye-forming coupler, and at least one ultraviolet light-sensitive silver halide emulsion layer (sound track forming layer) containing a non-diffusible silver bleach inhibitor and an infrared dye-forming coupler which forms a dye having an absorption maximum at wavelengths longer than 725 nm, wherein at least one layer interposed between the ultraviolet light-sensitive silver halide emulsion layer and the support contains a non-diffusible ultraviolet absorbant.
    Type: Grant
    Filed: March 24, 1977
    Date of Patent: June 17, 1980
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadao Sakai, Masayoshi Kawai
  • Patent number: 4207111
    Abstract: A color photosensitive material having a support and a silver halide photosensitive layer which material includes a coupler represented by the following formulas (IV), (V) or (VI) having therein a group represented by formula (I), said coupler being capable of forming an azomethine dye on coupling with the oxidation product of an aromatic primary amine developer: ##STR1## wherein the substituents on the above formulas is herein defined, is described, said couplers capable of giving improved light fastness.
    Type: Grant
    Filed: December 27, 1977
    Date of Patent: June 10, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Mitsuto Fujiwhara, Takashi Sasaki, Takashi Uchida
  • Patent number: 4182886
    Abstract: Pyridone dyestuffs of the formula ##STR1## are provided wherein R.sub.1 is hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical or an optionally substituted amino group, R.sub.2, R.sub.3, R.sub.4 each independently represent hydrogen, halogen, alkoxy, or optionally substituted alkyl or cycloalkyl, R.sub.5 and R.sub.6 each independently represent hydrogen or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical or R.sub.5 and R.sub.6, R.sub.3 and R.sub.5 and R.sub.4 and R.sub.6 form heterocyclic rings, Y is hydrogen or hydroxy, --CN, --COOR.sub.7, --CONR.sub.7 R.sub.8 or --COR.sub.7 or an optionally substituted alkyl, aralkyl, cycloalkyl, aryl or heterocyclic radical, and Z represents --CN, --COOR.sub.9, --CONR.sub.9 R.sub.10, --SO.sub.3 H, --SO.sub.3 .crclbar. or --COR.sub.9, where R.sub.7, R.sub.8, R.sub.9 and R.sub.
    Type: Grant
    Filed: February 21, 1978
    Date of Patent: January 8, 1980
    Assignee: Ciba-Geigy Aktiengesellschaft
    Inventors: Rainer Kitzing, John G. V. Scott, Terence C. Webb, Graham Evans