Using Processing Ingredient In Element Patents (Class 430/448)
  • Patent number: 5141843
    Abstract: A developer liquid suited for use in development of photographic silver halide emulsion layer materials which liquid contains:1) hydroquinone or a substituted hydroquinone as sole developing agent or said hydroquinone as main developing agent in combination with an auxiliary developing agent in an amount less than 10 mole % with respect to the main developing agent,2) an inorganic compound yielding free sulphite ions in an amount of at least 5 grams per liter,3) an organic anti-fogging agent corresponding to the following general formula (Z): ##STR1## wherein: X.sup.2 represents an alkyl group or an aryl group including said groups in substituted form or an amino group including said group in substituted form;the amount of anti-fogging agent being in the range of 50 mg to 1 g per liter,4) a polymer containing a plurality of alkylene oxide units, and5) the necessary alkaline material to have in said liquid a pH of at least 10.5. Optional additives can also be present in the developing liquid.
    Type: Grant
    Filed: March 27, 1991
    Date of Patent: August 25, 1992
    Assignee: AGFA-Gevaert N. V.
    Inventors: Richard A. Ooms, Piet Kok, Jean-Marie O. Dewanckele
  • Patent number: 5108880
    Abstract: A water soluble alkaline developer composition useful in the development of exposed silver halide photographic material comprised of a developing agent, a sulfite preservative and a small but effective amount of an amino alcohol compound of the formula ##STR1## wherein each R.sub.1 is a C.sub.2 -C.sub.4 alkyl group and R.sub.2 is a moiety having the structure: (R.sub.1 O).sub.x --R.sub.1 OH wherein x is an integer of from 1 to 3, and R.sub.1 is as defined hereinabove.
    Type: Grant
    Filed: December 20, 1990
    Date of Patent: April 28, 1992
    Assignee: Sun Chemical Corporation
    Inventor: John L. Adkins
  • Patent number: 5037726
    Abstract: A method for forming a direct positive image having a high Dmax and a low Dmin, which comprises image-wise exposing a photographic light-sensitive material having on a support at least one photographic emulsion layer containing unprefogged internal latent image-type silver halide grains and developing the photographic light-sensitive material after or while fogging to form direct positive image, wherein the aforesaid development is performed in the existence of at least one compound selected from the group consisting of compounds represented by formula (I), (II), (III), (IV), (V) or (VI), acid salts of compounds represented by formula (I) to (IV) provided substituents thereof contain an amino group, and acid salts of compound represented by formula (V) or (VI); ##STR1## wherein symbols are defined as in claim 1.
    Type: Grant
    Filed: December 7, 1988
    Date of Patent: August 6, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Noriyuki Inoue
  • Patent number: 4966835
    Abstract: A method for processing a silver halide color photographic material is described, comprising a support having thereon at least one of a silver halide emulsion layer and other hydrophilic colloid layer, wherein the silver halide emulsion layer or other hydrophilic colloid layer contains at least one compound represented by formula (I):A--B (I)wherein A represents a blocking group capable of being cleaved from B during processing and B represents a bleach accelerating agent containing at least one hetero atom linked to A through the hetero atom, wherein said method comprises at least one color developing step and desilvering step comprising a bleach-fixing treatment.
    Type: Grant
    Filed: August 12, 1988
    Date of Patent: October 30, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetunori Matushita, Morio Yagihara, Kei Sakanoue
  • Patent number: 4965177
    Abstract: Potassium iodide (or a related iodide) when incorporated in an alkaline activator for use in a rapid access processor using developer-incorporated, resin-coated paper, (i) produces a cold image tone in black-and-white photographic prints, and (ii) maintains the image tone of a large number of prints within a narrow image tone range over a (one week or one thousand 8.times.10 inch print) design life of the activator solution.
    Type: Grant
    Filed: August 2, 1989
    Date of Patent: October 23, 1990
    Assignee: Eastman Kodak Company
    Inventor: Donald F. McLaen
  • Patent number: 4929535
    Abstract: This invention is a process of quickly forming high contrast negative images, which are useful for photomechanical process, by development-processing a silver halide photographic material containing a hydrazine derivative in at least one of silver halide emulsion layer(s) and other hydrophilic colloid layer(s) after imagewise exposure in the existence of a compound represented by general formula (A); ##STR1## wherein R.sub.1, R.sub.2 and R.sub.3 each represents an alkyl group, a cycloalkyl group, an aryl group, an alkenyl group, a cycloalkenyl group, or a heterocyclic ring residue, these groups may have a substituent; m represents an integer; L represents an m-valent organic group bonded to the P atom through a carbon atom; n represents an integer of 1 to 3; and X represents an n-valent anion; said X may be bonded to L; using a stable processing solution.
    Type: Grant
    Filed: June 30, 1988
    Date of Patent: May 29, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiro Takahashi, Kimitaka Kameoka, Yoshio Inagaki
  • Patent number: 4923787
    Abstract: A photographic element is described which comprises a compound capable of scavenging oxidized developing agent to prevent stain and fog formation in developed color images.
    Type: Grant
    Filed: May 12, 1989
    Date of Patent: May 8, 1990
    Assignee: Eastman Kodak Company
    Inventor: John W. Harder
  • Patent number: 4914016
    Abstract: A silver halide photographic light-sensitive material containing inorganic sulfur or elemental sulfur, and a processing method comprising a step for developing such photographic material with a color developer which contains an aromatic primary amine compound for not more than 60 seconds. Photographic image improved in contrast of the without degradation in sensitivity and fogging can be obtained by the photographic material and the processing method.
    Type: Grant
    Filed: May 27, 1988
    Date of Patent: April 3, 1990
    Assignee: Konica Corporation
    Inventors: Masanobu Miyoshi, Makoto Kajiwara, Shigeo Tanaka, Mitsuhiro Okumura
  • Patent number: 4914003
    Abstract: A novel silver halide photographic material is provided comprising at least one light-sensitive silver halide emulsion layer provided on a support and containing at least one hydrazine compound and at least one amine compound of the general formula (I) in said emulsion layer or at least one of other constituting layers, provided that said hydrazine compound and said amine compound can be present in the same or different layers: ##STR1## wherein R.sup.2 and R.sup.3, which can be the same or different, each represents a substituted or unsubstituted alkyl group or R.sup.2 and R.sup.3 may be linked to each other to form a ring; R.sup.4 represents a substituted or unsubstituted alkyl, aryl or heterocyclic group; A represents a divalent linkage group; X represents --CONR.sup.5 --, --OCONR.sup.5 --, --NR.sup.5 CONR.sup.5 --, --NR.sup.5 COO--, --COO--, --OCO--, --CO--, --NR.sup.5 CO--, --SO.sub.2 NR.sup.5 --, --NR.sup.5 SO.sub.2 --, --SO.sub.2 --, --S-- or --O-- group (in which R.sup.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: April 3, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Nobuaki Inoue
  • Patent number: 4891304
    Abstract: A silver halide photographic material comprising a support having provided thereon at least one silver halide emulsion layer containing a compound represented by formula (I): ##STR1## wherein EAG represents an aromatic group bonding to N.sub.A and capable of accepting an electron;N.sub.A and N.sub.B each represents a nitrogen atom;R.sup.1 represents a lone pair, a .pi.-bond, a .sigma.-bond, or a substituent other than a hyudrogen atom;n represents 2 or 3;m represents 0 when n represents 2, or m represents 1 and N.sub.B has a positive charge when n represents 3;X.sup..crclbar. represents an anion;the groups or bonds represented by R.sup.1 may be combined with each other or may be combined with EAG to form a ring;R.sup.2 represents R.sup.3 --CO--, R.sup.3 --SO.sub.2 --, R.sup.3 --CO--N.dbd.CH--, or R.sup.3 --SO.sub.2 --N.dbd.CH--, wherein R.sup.3 represents an alkyl group, an aryl group, or a heterocyclic group;the group represented by R.sup.2 may be combined with at least one of R.sup.
    Type: Grant
    Filed: March 30, 1989
    Date of Patent: January 2, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koki Nakamura
  • Patent number: 4879204
    Abstract: A silver halide photographic material is described, comprising a support having formed thereon at least one silver halide emulsion layer and at least one light-insensitive hydrophilic colloid layer, wherein at least one of layers consisting of said at least one silver halide emulsion layer and said at least one light-insensitive hydrophilic colloid layer contains a hydrazine derivative, and wherein at least one of said at least one light-insensitive hydrophilic colloid layer that is formed on the uppermost silver halide emulsion layer contains a dye.
    Type: Grant
    Filed: August 16, 1988
    Date of Patent: November 7, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kunio Ishigaki, Toshiro Takahashi, Yuji Mihara, Keiichi Adachi, Shigeru Ohno, Masahiro Okada, Naomi Saeki
  • Patent number: 4873172
    Abstract: A process for forming a superhigh contrast negative image with a stable developer is disclosed, which comprises development processing a silver halide photographic material in the presence of a compound of formula (I) and a compound of formula (II) as defined in the specification.
    Type: Grant
    Filed: August 8, 1988
    Date of Patent: October 10, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shoji Ishiguro, Shigeo Hirano, Tadao Shishido, Akio Miyake
  • Patent number: 4849319
    Abstract: A negative silver halide photographic material comprising a support and at least one silver halide emulsion layer on the support, the emulsion layer or other hydrophilic colloid layer containing a hydrazine derivative, wherein the photographic material further contains an acid polymer and in which the pH of the surface of the photographic material is not more than 5.8. Also, a method for forming a superhigh contrast negative image using the above photographic material is disclosed.
    Type: Grant
    Filed: November 20, 1987
    Date of Patent: July 18, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Senzo Sasaoka, Hiroshi Hayashi
  • Patent number: 4845019
    Abstract: The methods and apparatus disclosed herein provide commercially viable means to selectively improve the input and output characteristics of photosensitive materials, especially the output contrast variables. The present invention allows commercially available photosensitive material such as the high contrast Ilford Cibachrome Copy CCO Paper.RTM. to display dramatically improved color balance and contrast range characteristics when making reproductions from slides or prints. Recreational, professional and military photo duplication techniques are greatly improved by the present invention.
    Type: Grant
    Filed: October 29, 1987
    Date of Patent: July 4, 1989
    Assignee: Visicon Laboratories, Inc.
    Inventor: Quentin D. Vaughan, IV
  • Patent number: 4822728
    Abstract: A color image, wherein granularity is reduced under conditions allowing any sharpness loss to be kept under control, is obtained by image-wise exposing and developing in an alkaline water solution containing a color developer a silver halide color photographic element comprising a support base and at least a silver halide emulsion layer containing dispersed a non-diffusing hydrophobic coupler which upon reactiong with an oxidized developing agent forms a non-diffusing dye, characterized by the fact that said emulsion contains dispersed therein oil droplets, said droplets containing said non-diffusing coupler dissolved therein, and furthermore polymer particles in a quantity sufficient to obtain controlled smearing of the image-forming dye.
    Type: Grant
    Filed: December 11, 1987
    Date of Patent: April 18, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Marco Loiacono, Angelo Vallarino
  • Patent number: 4818659
    Abstract: A silver halide photographic material for use in a bright room is disclosed comprising a support having thereon at least two silver halide emulsion layers, each of the emulsion layers having a different sensitivity and comprising silver chloride grains or silver chlorobromide grains having at least about 80 mol % silver chloride, each of the silver halide emulsions layers containing from about 1.times.10.sup.-7 mol to about 1.times.10.sup.-4 mol of a rhodium salt per mol of silver, wherein the sensitivity of the lower emulsion layer (the emulsion layer coated nearer to the support) is higher than the sensitivity of the upper emulsion layer (the emulsion layer coated farther from the support) and at least one of the silver halide emulsion layers or different hydrophilic colloid layers contains a hydrazine derivative and at least one of the silver halide emulsion layers of different hydrophilic colloid layers contains a dry compound having a .sup..lambda. max of from about 400 nm to about 550 nm.
    Type: Grant
    Filed: April 7, 1987
    Date of Patent: April 4, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiro Takahashi, Ken-ichi Kuwabara, Kimitaka Kameoka, Masahiro Okada
  • Patent number: 4810623
    Abstract: A process for developing a photographic material containing on a support an image-wise exposed silver halide emulsion layer of which the silver halide is substantially silver chloride and in which the photographic material before its exposure contains already at least one silver halide developing agent in a hydrophilic colloid binder in waterpermeable relationship with the silver halide, said process containing the step of contacting the exposed photographic material with an aqueous alkaline liquid, called activator liquid, being initially substantially free from developing agent(s), said contacting being not followed by a silver complex diffusion transfer processing, characterized in that said aqueous alkaline liquid contains a primary and/or secondary amine.
    Type: Grant
    Filed: February 18, 1988
    Date of Patent: March 7, 1989
    Assignee: Agfa-Gevaert N.V.
    Inventors: Hendrik E. Kokelenberg, Benedictus J. Jansen
  • Patent number: 4803149
    Abstract: A silver halide photographic material for a bright room and a process for producing the photographic material are disclosed, wherein the silver halide photographic material for a bright room comprises a support having thereon at least one silver halide emulsion layer containing silver chloride grains or silver chlorobromide grains containing at least 80 mol % silver chloride, at least one of said silver halide emulsion layer or another hydrophilic colloid layer(s) present containing a yellow dye making the silver halide photographic material substantially insensitive to visible light of 420 n.m. or more and an ultraviolet absorbent in an amount sufficient to reduce the specific sensitivity of the silver halide emulsion at 360 n.m. to 1/2 or lower than 1/2 thereof in the absence of the ultraviolet absorbent, and the .gamma. value of the silver halide photographic material being at least 10.
    Type: Grant
    Filed: October 6, 1986
    Date of Patent: February 7, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiro Takahashi, Ken-ichi Kuwabara, Masahiro Okada
  • Patent number: 4761362
    Abstract: An image forming process capable of providing photographic images having extremely high contrast and high resolution for use in photoengraving is disclosed, which comprises processing an image-wise exposed silver halide light-sensitive material having at least two silver halide emulsion layers on a support, one of said emulsion layers providing a contrasty gradation and the other of said emulsion layers providing a soft tone gradation, with a hydrazine contrast development system, a tetrazolium contrast development system or a lith development system, wherein the gamma (.gamma.) value of the portion having a density (D) from 0.3 to 1.5 on the characteristic curve obtained is less than 10 and the gamma (.gamma.) value of the portion having a density (D) from 1.5 to 3.0 is at least 10.
    Type: Grant
    Filed: December 29, 1986
    Date of Patent: August 2, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Senzo Sasaoka, Shigenori Moriuchi, Kimitaka Kameoka, Kazunobu Katoh, Yoshio Inagaki
  • Patent number: 4755448
    Abstract: A negative type silver halide photographic material and a method for forming a super high contrast negative image using the photographic material are disclosed. The photographic material comprises a support, at least one silver halide emulsion layer on the support, and at least one light-insensitive colloid layer on the support, said emulsion layer or light-insensitive hydrophilic colloid layer containing a hydrazine derivative, and further contains the tertiary amine salt of an acid polymer.
    Type: Grant
    Filed: September 4, 1986
    Date of Patent: July 5, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Kazunobu Katoh
  • Patent number: 4752560
    Abstract: This invention is directed to a photographic element containing a radiation-sensitive silver halide emulsion layer and a cyclic thioether compound comprised of at least one oxygen atom and at least three sulfur atoms, each of said atoms being separated from one another by a divalent alkylene group.
    Type: Grant
    Filed: September 8, 1986
    Date of Patent: June 21, 1988
    Assignee: Eastman Kodak Company
    Inventors: Rejane R. Benard, Gerard Friour, Marcel L. Riveccie
  • Patent number: 4740452
    Abstract: The present invention provides a process for preparing a negative image of high contrast comprising developing an exposed silver halide photographic material which is substantially a surface latent image-type material in the presence of a hydrazine derivative, wherein said material is processed with a water-soluble alkaline developer having a pH value of from 10.5 to 12.3 and at least comprising the following components (1) through (3):(1) a dihydroxybenzene-type developing agent;(2) 0.3 mole/liter (developer) or more of a sulfite preservative; and(3) from 0.01 to 0.30 mole/liter (developer) of a compound of formula (A) ##STR1## in which R.sub.2 represents an alkyl group having from 3 to 6 carbon atoms; R.sub.3 and R.sub.4 each represents an alkyl or hydroxyalkyl group having from 1 to 10 carbon atoms.The formed negative images are of high contrast and are almost free from silver stain. The sensitivity is high and the dot image quality is good.
    Type: Grant
    Filed: May 22, 1986
    Date of Patent: April 26, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Eiichi Okutsu, Mitsunori Hirano
  • Patent number: 4737442
    Abstract: A silver halide photographic material for use in the field of graphic arts and a process for forming a high-contrast negative image using the same, wherein the silver halide emulsion layer or another layer of the silver halide photographic material provided on the support contains at least one compound represented by the formula (I) and at least one blocked development restrainer compound represented by the formula (II): ##STR1##
    Type: Grant
    Filed: April 18, 1986
    Date of Patent: April 12, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Tetunori Matusita, Nobuaki Inoue
  • Patent number: 4722884
    Abstract: A negative silver halide photographic light-sensitive material is provided, having a silver halide emulsion layer, which layer comprises silver haloiodide grains prepared in the presence of an iridium salt in an amount of 1.times.10.sup.-8 to 1.times.10.sup.-5 mole per one mole of silver, wherein the silver iodide content in the surface part of said grain is larger than the average silver iodide content in said grain, and additionally containing in said emulsion layer or in some other hydrophilic colloid layer, a compound of formula (I):R.sub.1 --NHNH--CHO (I)wherein R.sub.1 represents an aliphatic group or an aromatic group. Said photographic light-sensitive material is, after being exposed imagewise, developed with a developer containing 0.15 mole/l or more sulfite ion and having a pH value of 9.5-12.3, to form negative images having ultra-high contrast.
    Type: Grant
    Filed: July 23, 1985
    Date of Patent: February 2, 1988
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Senzo Sasaoka, Kenichi Kuwabara, Kimitaka Kameoka
  • Patent number: 4702999
    Abstract: Disclosed are novel antifoggant precursors having the general formula (I) or (II) which are sufficiently stable in a wealkyl acidic medium, are markedly effective in restraining over-development fog and besides cause little loss of sensitivity: ##STR1## (wherein Y represents oxygen atom or ##STR2## X represents OR.sub.3 when Y is oxygen atom and R.sub.3 when Y is ##STR3## where R.sub.1 and R.sub.2 each represents hydrogen atom, alkyl group aryl group and R.sub.3 represents hydrogen atom, alkyl group or phenyl group; R.sub.4 -R.sub.6 each represent hydrogen atom, halogen atom, alkyl group, carboxyl group, alkoxycarbonyl group or phenyl group, R.sub.4 and R.sub.5 may form together a benzene ring; R.sub.7 represents hydrogen atom, alkyl group or phenyl group; and A represents a heterocyclic group of the mercapto antifoggant.) ##STR4## (wherein X, Y, R.sub.4 -R.sub.5 and A are the same as defined for the general formula (I) and R.sub.4 and R.sub.5 or R.sub.5 and R.sub.6 may form together a benzene ring.).
    Type: Grant
    Filed: February 24, 1986
    Date of Patent: October 27, 1987
    Assignee: Mitsubishi Paper Mills, Ltd.
    Inventors: Minoru Ohashi, Satoshi Kaneko
  • Patent number: 4699873
    Abstract: A negative silver halide photographic light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer is disclosed. At least one of the silver halide emulsion layers or another hydrophilic colloidal layer of the material contains a hydrazine derivative and a compound represented by the formula:R.sub.1 --S--S--R.sub.2wherein R.sub.1 and R.sub.2, which may be the same or different, each represents an aliphatic group, an aromatic group or a heterocyclic group, or when R.sub.1 and R.sub.2 are both aliphatic groups they may together form a ring. The material can rapidly form a superhigh contrast image using a stable processing solution.
    Type: Grant
    Filed: January 29, 1986
    Date of Patent: October 13, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshiro Takahashi, Shigeo Hirano
  • Patent number: 4681836
    Abstract: A silver halide photographic material having at least one silver halide emulsion layer which contains silver halide grains containing from 1.times.10.sup.-8 to 8.times.10.sup.-6 mole of a rhodium salt per mole of silver, and containing in said emulsion layer or another hydrophilic colloidal layer a compound represented by formula (I)R.sup.1 -NHNH-G-R.sup.2 (I)wherein R.sup.1 represents an aliphatic group or an aromatic group; R.sup.2 represents a hydrogen atom, a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, a substituted or unsubstituted alkoxy group, or a substituted or unsubstituted aryloxy group; and G represents a carbonyl group, a sulfonyl group, a sulfoxy group, a phosphoryl group, or an N-substituted or unsubstituted imino group; is exposed to imagewise pattern of light and then development-processed with a developer containing 0.15 mole/liter or more of sulfite ion and having a pH adjusted to from 9.5 to 12.
    Type: Grant
    Filed: November 20, 1986
    Date of Patent: July 21, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Inoue, Yoshio Inagaki, Kimitaka Kameoka
  • Patent number: 4678741
    Abstract: A silver halide photographic material having on a support at least one hydrophilic colloid layer and at least one silver halide emulsion layer containing tabular silver halide grains having a grain diameter of at least 5 times the thickness of the grains and at least one compound represented by general formula (I) ##STR1## wherein R.sup.1 represents a methyl group and R.sup.2 represents an alkyl group, a substituted alkyl group, an aryl group, or a substituted aryl group.
    Type: Grant
    Filed: April 14, 1986
    Date of Patent: July 7, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Sumito Yamada, Masaki Okazaki
  • Patent number: 4675277
    Abstract: A heat developable light-sensitive material comprising a support having provided thereon at least a light-sensitive silver halide, a binder, and a compound capable of ring-closure to produce a benzimidazole ring upon heat development can be developed to an increased maximum density with less fogging at a relatively low temperature in a short period of time.
    Type: Grant
    Filed: September 25, 1985
    Date of Patent: June 23, 1987
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Sato, Hiroshi Kitaguchi, Hiroyuki Hirai
  • Patent number: 4661438
    Abstract: Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by quaternized aromatic oxatellurazinium salts. The aromatic oxatellurazinium salts can be initially incorporated in the photographic element as manufactured or during processing.
    Type: Grant
    Filed: January 31, 1986
    Date of Patent: April 28, 1987
    Assignee: Eastman Kodak Company
    Inventors: Rosemary Przyklek-Elling, Wolfgang H. H. Gunther, Roger Lok
  • Patent number: 4650746
    Abstract: This invention relates to a photographic element comprising a support, and coated on the support at least one negative-working photographic emulsion comprising radiation-sensitive silver halide grains capable of forming a surface latent image and a binder, and in the support or in a remaining hydrophilic colloid layer coated on the support in an amount sufficient to increase contrast, a hydrazine compound of the formula ##STR1## wherein R.sup.1 is a phenyl nucleus having a Hammet sigma value-derived electron withdrawing characteristic of less than +0.30.
    Type: Grant
    Filed: July 12, 1979
    Date of Patent: March 17, 1987
    Assignee: Eastman Kodak Company
    Inventors: Joseph M. Simson, Harold E. Jordan
  • Patent number: 4636460
    Abstract: Photographic recording materials which contain a developer substance or a precursor thereof produce better results if in addition they contain a sulphite, a disulphite or a compound capable of releasing sulphite in the photographic material.
    Type: Grant
    Filed: June 11, 1985
    Date of Patent: January 13, 1987
    Assignee: Agfa Gevaert Aktiengesellschaft
    Inventors: Heinz Meckl, Helmut Kampfer, Helmut Haseler
  • Patent number: 4624913
    Abstract: A silver halide photographic light-sensitive material is described, comprising at least one light-sensitive silver halide emulsion layer on a support, wherein the emulsion in said light-sensitive silver halide emulsion layer comprises a silver iodobromide emulsion containing 3 mol % or more of iodide, and at least one of said light-sensitive emulsion layer or another hydrophilic colloid layer contains a polyoxyethylene type surface active agent and at least one of said light-sensitive emulsion layer or another hydrophilic colloid layer contains a meso-ionic triazolium compound represented by formula (I) ##STR1## wherein X represents a sulfur ion or --N--R.sup.4, and R.sup.1, R.sup.2, R.sup.3, and R.sup.4 each represents a hydrogen atom or a substituted or nonsubstituted alkyl group, aryl group, or heterocyclic group, or R.sup.1 and R.sup.2, R.sup.2 and R.sup.3 or R.sup.3 and R.sup.4 can together form a heterocyclic ring.
    Type: Grant
    Filed: February 11, 1985
    Date of Patent: November 25, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuaki Miyasaka, Koki Nakamura, Shigeki Yokoyama
  • Patent number: 4619886
    Abstract: A process for forming a high contrast negative image by developing an exposed substantial surface latent image type silver halide photographic light-sensitive material in the presence of hydrazines, which comprises using a developing solution having a pH value of 10.5 to 12.3 and containing at least(1) a developing agent,(2) 0.25 mol/l or more of sulfite, and(3) a compound represented by the following general formula (I): ##STR1## wherein R.sub.1, R.sub.2, R.sub.3, R.sub.4 and R.sub.5, which may be the same or different, each represents a hydrogen atom, a hydroxyl group, an alkyl group, an alkoxy group or a substituted alkyl group. According to the process, the development processing time required is shortened in the case of forming a high contrast negative image with a stable developing solution using hydrazines.
    Type: Grant
    Filed: March 21, 1985
    Date of Patent: October 28, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Eiichi Okutsu
  • Patent number: 4617258
    Abstract: A silver halide photographic material is disclosed. It contains per 100 g of silver at least 40 mg of a water-soluble compound comprising an element of group VIII of the periodic table and having a molecular weight of at least 100, and 1.2 to 120 mg of a black-and-white silver halide developing agent. The material has improved gradation characteristics and is subject to minimum variation in photographic characteristics.
    Type: Grant
    Filed: March 25, 1986
    Date of Patent: October 14, 1986
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Hiroshi Menjo, Nobuo Sakamoto, Yoshikazu Watanabe
  • Patent number: 4615970
    Abstract: A silver halide photographic material containing at least one of compounds represented by formula (I) and salts thereof in at least one hydrophilic colloidal layer of the silver halide photographic material gives photographic images having stable and excellent quality without being accompanied by the increased formation of fog and increased changes of sensitivity and gradation upon high temperature processing: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted alkenyl group, a substituted or unsubstituted cycloalkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted heterocyclic ring group; or one or both of said R.sub.1 and R.sub.2 and said R.sub.3 and R.sub.4 combine with each other to form a ring.
    Type: Grant
    Filed: December 6, 1984
    Date of Patent: October 7, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tetsuro Kojima, Koki Nakamura, Takashi Toyoda
  • Patent number: 4610954
    Abstract: A silver halide photographic light-sensitive material for obtaining a silver image comprising a water-impermeable support having at least one silver halide emulsion layer, and containing in association with the emulsion layer a compound selected from the group consisting of: (a) a compound represented by the following general formula (I): ##STR1## (b) a compound represented by the following general formula (II): ##STR2## and (c) a combination of a compound represented by the following general formula (III) and a compound represented by the following general formula (IV): ##STR3## (all the symbols are as defined in the appended claims), and a method of forming silver images using the above-defined silver halide photographic light-sensitive material, are disclosed.
    Type: Grant
    Filed: November 8, 1984
    Date of Patent: September 9, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaaki Torigoe, Yoshio Inagaki, Tadao Shishido
  • Patent number: 4607001
    Abstract: Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by aromatic tellurochalcogenides. The aromatic tellurochalcogenides can be initially incorporated in the photographic element as manufactured or during processing.
    Type: Grant
    Filed: April 4, 1985
    Date of Patent: August 19, 1986
    Assignee: Eastman Kodak Company
    Inventors: Roger Lok, Wolfgang H. H. Gunther
  • Patent number: 4607000
    Abstract: Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by amido substituted aromatic tellurochalcogenides. The amido substituted aromatic tellurochalcogenides can be initially incorporated in the photographic element as manufactured or during processing.
    Type: Grant
    Filed: April 4, 1985
    Date of Patent: August 19, 1986
    Assignee: Eastman Kodak Company
    Inventors: Wolfgang H. H. Gunther, Roger Lok
  • Patent number: 4604339
    Abstract: A method of developing silver halide photographic material which contains a light-sensitive silver halide emulsion and an internally-fogged silver halide emulsion, in which the internally-fogged emulsion has internal fogging nuclei at a depth of 0.02.mu. or more below the surface of the grains is disclosed. The photographic material is developed in the presence of at least one compound selected from the group consisting of tetraazaindenes containing at least one mercapto group, purines containing at least one mercapto group, triazaindenes containing at least one mercapto group and pentaazaindenes containing at least one mercapto group, to increase photographic speed, contrast and maximum density as well as remove uneven stain.
    Type: Grant
    Filed: November 30, 1983
    Date of Patent: August 5, 1986
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadao Sugimoto, Hideo Ikeda, Hiroyuki Mifune, Koki Nakamura
  • Patent number: 4598040
    Abstract: There is provided a developer for use in a one-step process for the development of exposed film resulting in an exposurewise pattern of silver particles which are large enough to be used as printing elements in ink-printing techniques, providing a wide range of densities in the developed film. The developer is based on a buffered system of a developing agent, a sulfinic acid salt of the type HO-R-SO.sub.2.M..times.H.sub.2 O where R is a hydrocarbyl group and M is a cation, and a formaldehyde source, with conventional adjuvants such as anti-fogging agents and the like. Instead of the sulfinic acid salt defined above there may be used any compound which upon dissociation in a aqueous medium results in the same active ionic species.
    Type: Grant
    Filed: September 12, 1983
    Date of Patent: July 1, 1986
    Inventors: Yoel Netz, Arnold Hoffman
  • Patent number: 4581330
    Abstract: Radiation sensitive silver halide photographic elements are disclosed which are protected from fog by aromatic oxatellurazinium salts. The aromatic oxatellurazinium salts can be initially incorporated in the photographic element as manufactured or during processing.
    Type: Grant
    Filed: February 19, 1985
    Date of Patent: April 8, 1986
    Assignee: Eastman Kodak Company
    Inventors: Wolfgang H. H. Gunther, Roger Lok
  • Patent number: 4551419
    Abstract: A silver halide photographic material which contains a light-sensitive silver halide emulsion and an internally fogged silver halide emulsion is development-processed in the presence of at least one compound selected from the group consisting of compounds represented by the general formulae (I) and (II) and at least one azaindene having a mercapto group to exhibit high photographic speed, high contrast and high maximum image density:R.sub.1 --(R.sub.3).sub.l X}.sub.n R.sub.3 '--R.sub.2 (I)wherein R.sub.1 and R.sub.2 each represents a hydrogen atom, an aryl group, an aryl group, or a heterocyclic group; R.sub.3 and R.sub.3 ' each represents an alkylene group, an arylene group, a heterocyclic group; X presents ##STR1## R.sub.4 represents a hydrogen atom or --R.sub.5 --Y}.sub.m R.sub.5 '--R.sub.6 ; R.sub.5 and R.sub.5 ' have the same meanings as R.sub.3 and R.sub.3 '; R.sub.6 has the same meaning as R.sub.1 and R.sub.2 ; Y represents ##STR2## R.sub.7 has the same meaning as R.sub.1 and R.sub.
    Type: Grant
    Filed: February 10, 1984
    Date of Patent: November 5, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadao Sugimoto, Hideo Ikeda, Koki Nakamura
  • Patent number: 4518685
    Abstract: A silver halide photographic light-sensitive material which comprises a support having thereon a light-sensitive silver halide emulsion layer, wherein the photographic light-sensitive material contains a blocked photographic agent therein represented by formula (I): ##STR1## wherein A represents a photographic agent moiety which is bonded to a blocking moiety through a hetero atom or a group which is bonded to a blocking moiety through a hetero atom and capable of releasing a photographic agent upon a subsequent reaction after the group is released; Y represents a hydrogen atom or a substituent; and Z represents an atomic group necessary to form a carbocyclic ring or a heterocyclic ring.The precursor of photographic agent is completely stable during the preservation of the photographic light-sensitive material and releases a photographic agent at a desired time upon the processing of the photographic light-sensitive material.
    Type: Grant
    Filed: April 17, 1984
    Date of Patent: May 21, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Morio Yagihara, Akihiko Ikegawa, Mitsunori Ono, Yuji Mihara
  • Patent number: 4493888
    Abstract: A silver halide photographic light-sensitive material containing a diffusion resistant coupler, a light-sensitive silver halide and at least one organic metal complex represented by the following general formula (I) in the same layer or different layers on a support. ##STR1## wherein M represents a divalent metal atom; R.sup.1 and R.sup.2, which may be the same or different, each represents an alkyl group having from 1 to 5 carbon atoms, a hydroxyalkyl group having from 1 to 5 carbon atoms, an alkoxyalkyl group having from 2 to 10 carbon atoms or an alkylsulfonamidoalkyl group having from 2 to 10 carbon atoms, or R.sup.1 and R.sup.2 may be bonded each other to form a heterocyclic ring together with the nitrogen atom; R.sup.3, represents a hydrogen atom, an alkyl group having from 1 to 5 carbon atoms or an alkoxy group having from 1 to 5 carbon atoms; and R.sup.4 and R.sup.
    Type: Grant
    Filed: July 15, 1983
    Date of Patent: January 15, 1985
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Katsusuke Endo, Eiichi Kato, Nobutaka Ohki, Takatoshi Ishikawa
  • Patent number: 4465762
    Abstract: A method for forming a color image comprising color developing a color photographic silver halide light-sensitive material containing at least one compound represented by formula (I) ##STR1## wherein X is a hydrogen atom or an acetyl group, R is an aryl group, and each of R.sub.1, R.sub.2, R.sub.3, and R.sub.4 is a hydrogen atom, an alkyl group, or an aryl group,using a color developer containing a p-phenylenediamine-based and/or p-aminophenol-based color developing agent and without performing black-and-white development.
    Type: Grant
    Filed: March 3, 1982
    Date of Patent: August 14, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takatoshi Ishikawa, Takashi Nakamura, Kotaro Nakamura
  • Patent number: 4451555
    Abstract: The present invention deals with novel antifogging compounds and their use in a method of photographic reproduction comprising developing a photographic material having at least one exposed silver halide emulsion layer in the presence of a 1-phenyl-5-mercaptotetrazole compound wherein the phenyl group bears a substituent comprising at least one thioether function.
    Type: Grant
    Filed: November 25, 1981
    Date of Patent: May 29, 1984
    Assignee: AGFA-GEVAERT, N.V.
    Inventors: Robert J. Pollet, Antoon L. Vandenberghe, Roger A. Spriet
  • Patent number: 4447522
    Abstract: A method of forming a photographic image which comprises development processing with an alkaline activator solution a silver halide photographic light-sensitive material comprising a support having thereon at least one surface latent image type silver halide emulsion layer, and containing in at least one layer selected from the silver halide emulsion layer and another hydrophilic colloid layer(1) a developing agents;(2) an acylhydrazine compound represented by formula (I):R.sup.1 NHNHCOR.sup.2 (I)wherein R.sup.1 represents an unsubstituted or substituted aryl group or alkyl group; and R.sup.2 represents a hydrogen atom, or an unsubstituted or substituted aryl group or alkyl group; and(3) at least one compound represented by formula (II): ##STR1## wherein each of W.sup.1 and W.sup.2 can represent a hydrogen atom or an aliphatic group or W.sup.1 and W.sup.2 are bonded each other to form a ring; W.sup.3 represents a divalent aliphatic group; Q.sup.
    Type: Grant
    Filed: April 18, 1983
    Date of Patent: May 8, 1984
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeo Hirano, Yoshihiro Takagi
  • Patent number: 4423140
    Abstract: Photographic silver halide emulsions are protected against latent image fading by aromatic latent image stabilizing compounds having the structure: ##STR1## wherein: R.sup.1 is hydrogen, alkyl, or aryl;R.sup.2 and R.sup.3 are each individually hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, or aminocarbonyl;X is a middle chalcogen;Z represents the atoms completing an aromatic nucleus;n is an integer of 1 or 2; andM.sup..sym.n is a cation of valence n chosen from the group consisting of an onium ion, an ion from Group IA or IIA, and a metal ion from Group IIB, VIIB, IVA, or VA.
    Type: Grant
    Filed: June 25, 1298
    Date of Patent: December 27, 1983
    Assignee: Eastman Kodak Company
    Inventor: Arthur H. Herz
  • Patent number: RE32195
    Abstract: Photographic silver halide emulsions are protected against latent image fading by aromatic latent image stabilizing compounds having the structure: ##STR1## wherein: R.sup.1 is hydrogen, alkyl, or aryl;R.sup.2 and R.sup.3 are each individually hydrogen, alkyl, alkoxy, carboxy, alkoxycarbonyl, or aminocarbonyl;X is a middle chalcogen.[.;.]. .Iadd.chosen from the class consisting of sulfur and selenium; .Iaddend.Z represents the atoms completing an aromatic nucleus;n is an integer of 1 or 2; andM.sup..sym.n is a cation of valence n chosen from the group consisting of an onium ion, an ion from Group IA or IIA, and a metal ion from Group IIB, VIIB, IVA, or VA.
    Type: Grant
    Filed: April 4, 1985
    Date of Patent: July 1, 1986
    Assignee: Eastman Kodak Company
    Inventor: Arthur H. Herz