Silver Compound Sensitizer Patents (Class 430/542)
  • Patent number: 4421846
    Abstract: A photographic element containing a nondiffusible metal complex capable of releasing a diffusible photographically useful group. The complex contains at least one poly-dentate ligand which contains the photographically useful group. The complex may be activated when reduced under alkaline conditions to release the photographically useful group.
    Type: Grant
    Filed: December 23, 1981
    Date of Patent: December 20, 1983
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Satoru Ikeuchi, Masaru Kanbe, Jiro Takahashi, Ryuichiro Kobayashi, Shunji Suginaka, Noboru Mizukura
  • Patent number: 4419439
    Abstract: A process for forming a photographic image comprising imagewise exposing a silver halide photographic light-sensitive material to light and processing the silver halide photographic light-sensitive material with an alkaline processing solution, wherein the improvement comprises the silver halide photographic light-sensitive material contains a compound represented by formula (I) ##STR1## wherein R represents an alkyl group having from 6 to 22 carbon atoms, a substituted alkyl group having from 6 to 22 carbon atoms, an aryl group having from 6 to 22 carbon atoms, a substituted aryl group having from 6 to 22 carbon atoms, an alkenyl group having from 6 to 22 carbon atoms, a substituted alkenyl group having from 6 to 22 carbon atoms or an aralkyl group having from 7 to 22 carbon atoms; X represents an alkyl group having from 1 to 4 carbon atoms, an alkoxy group having from 1 to 6 carbon atoms, or a halogen atom; and n represents an integer from 1 to 3.
    Type: Grant
    Filed: November 16, 1981
    Date of Patent: December 6, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeru Kuwazima, Eiichi Kato, Minoru Yamada
  • Patent number: 4414309
    Abstract: Compounds corresponding to the following general formula ##STR1## wherein R.sup.1 represents hydrogen, an aliphatic or cycloaliphatic group, an aralkyl group, an aryl group, a heterocyclic group or one of the following groups: --CO--alkyl, --CO--aryl, --CO--heterocyclic group, --SO.sub.2 --alkyl, --SO.sub.2 --aryl, --CO--O--alkyl, --CO--NH--NH.sub.2, ##STR2## and R.sup.2 represents hydrogen, an aliphatic or cycloaliphatic group, an aralkyl group, an aryl group, alkoxy, aroxy, carboxyl, carbamoyl, alkoxycarbonyl, an alkyl or aryl group attached through a carbonyl group, cyanogen, an amino group optionally substituted by alkyl, aralkyl, aryl or acyl, or a cyclic amino groupmay be used as additives in the layers of color photographic recording materials to improve the stability of color couplers, in particular magenta couplers, against formaldehyde.
    Type: Grant
    Filed: November 24, 1982
    Date of Patent: November 8, 1983
    Assignee: Agfa-Gavaert Aktiengesellschaft
    Inventors: Hans Langen, Lothar Rosenhahn, Erich Wolff
  • Patent number: 4411987
    Abstract: A silver halide color photographic light-sensitive material containing an unsubstituted or substituted glycoluril as an aldehyde gas scavenger. The silver halide color photographic light-sensitive material of the present invention can avoid the decrease in color density and the formation of fog normally present when the silver halide color photographic light-sensitive material is stored for a long period of time in contact with formaldehyde gas. In addition, the silver halide color photographic light-sensitive material of the present invention has a reduced layer thickness and good film strength.
    Type: Grant
    Filed: November 8, 1982
    Date of Patent: October 25, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Toshiyuki Watanabe, Keiichi Adachi, Tadashi Ogawa
  • Patent number: 4411984
    Abstract: A diphenylamine compound that is a precursor for a phenazine dye comprises, in an ortho position to the amine of the diphenylamine, a sulfonyldiamido group (--NHSO.sub.2 NHR) that is capable of releasing a sulfonylamine fragment upon oxidation. The diphenylamine compound upon oxidation intramolecularly cyclizes to a phenazine dye. The sulfonylamine fragment is capable of thermally releasing ammonia or an amine. The diphenylamine compound and sulfonylamine fragment are useful in imaging such as in photothermography. Ammonia or an amine thermally released from the sulfonylamine fragment enables imaging in imaging materials that are responsive to ammonia or an amine. The diphenylamine compound also generally is a silver halide developing agent.
    Type: Grant
    Filed: May 3, 1982
    Date of Patent: October 25, 1983
    Assignee: Eastman Kodak Company
    Inventor: Rolf S. Gabrielsen
  • Patent number: 4395478
    Abstract: A radiation-sensitive emulsion for use in forming a direct-positive image is disclosed. The emulsion is comprised of core-shell silver halide grains. The shell portions of the grains contain polyvalent metal ions to reduce rereversal.
    Type: Grant
    Filed: November 12, 1981
    Date of Patent: July 26, 1983
    Assignee: Eastman Kodak Company
    Inventor: Harry A. Hoyen
  • Patent number: 4390606
    Abstract: A color-forming para-sulfonamidodiphenylamine dye precursor in a photographic material and process enables formation of a sulfonimide dye image by means of cross-oxidation without the need for a coupling reaction. The color-forming para-sulfonamidodiphenylamine dye precursor is useful in a photographic silver halide material for producing (i) a dye image, or (ii) a dye image and silver image. The exposed photographic material is processed to produce (a) a positive dye image, (b) a negative dye and negative silver image, (c) a negative dye image or (d) a positive dye image and a positive silver image.
    Type: Grant
    Filed: July 1, 1982
    Date of Patent: June 28, 1983
    Assignee: Eastman Kodak Company
    Inventors: Rolf S. Gabrielsen, Patricia A. Graham, James E. Klijanowicz, Max H. Stern
  • Patent number: 4383029
    Abstract: Disclosed in this invention is a recording medium characterized by forming on the support a recording layer containing a metastable sensitive substance which is an intermediate product of a reaction between a first colorless or light-colored material containing the S atoms released by light irradiation and a second colorless or light-colored material which develops color as it is sulfurized by said S atoms.
    Type: Grant
    Filed: May 27, 1982
    Date of Patent: May 10, 1983
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Noboru Yamada, Mutsuo Takenaga, Kenichi Nishiuchi
  • Patent number: 4374923
    Abstract: A direct positive silver halide photographic light-sensitive material is described comprising a support having coated thereon at least one light-sensitive silver halide photographic emulsion layer, wherein at least one layer of the light-sensitive silver halide photographic emulsion layers and other hydrophilic colloid layers contains a compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.2 can each represent a hydrogen atom, an aliphatic group, an aromatic group, or a heterocyclic group; R.sup.3 represents a hydrogen atom or an aliphatic group; R.sup.4 represents a hydrogen atom, an aliphatic group, or an aromatic group; and X represents a divalent aromatic group.
    Type: Grant
    Filed: November 17, 1981
    Date of Patent: February 22, 1983
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeo Hirano, Tadao Sugimoto, Nobuyuki Tsujino
  • Patent number: 4368246
    Abstract: In a photographic material for producing a dye image or a dye image and silver image comprising (1) a photographic metal salt, such as photographic silver halide, and (2) a dye precursor, improved images are provided by means of a color-forming para-sulfonamidodiphenylamine dye precursor having one to two sulfonamido groups in positions ortho to the --NH-- moiety separating the two phenyl groups of the sulfonamidodiphenylamine and wherein the sulfonamidodiphenylamine, in oxidized form, intramolecularly reacts to produce a sulfonamido-substituted phenazine dye. An exposed photographic material containing the color-forming sulfonamidodiphenylamine dye precursor is processed to produce a negative phenazine dye-enhanced silver image. Alternatively, the exposed photographic material is processed to produce a positive phenazine dye image.
    Type: Grant
    Filed: July 6, 1981
    Date of Patent: January 11, 1983
    Assignee: Eastman Kodak Company
    Inventors: Rolf S. Gabrielsen, Patricia A. Graham, James E. Klijanowicz
  • Patent number: 4366240
    Abstract: 5- or 6-membered .alpha.-lactones of phenolic compounds, in which the phenyl ring carries a hydroxyl or amino group in its 2- or 4-position to the lactonized phenolic hydroxyl group and in which the lactone ring carries an electron accepting substituent, so that the lactone ring is readily cleavable at pH values of from 10 to 13 to form an electron donor compound (ED-compound) having a redox potential of less than +0.255 V determined against a normal calomel electrode at pH 0 are useful ED precursor compounds for non-diffusing reducible color providing compounds.
    Type: Grant
    Filed: February 17, 1981
    Date of Patent: December 28, 1982
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Wolfgang Lassig, Ernst Meier, Siegfried Schleger
  • Patent number: 4358532
    Abstract: A photographic element containing a compound represented by formula (I) ##STR1## wherein G represents --OR.sup.1 or --NHR.sup.2, R.sup.1 represents hydrogen or a hydrolyzable moiety, R.sup.2 represents hydrogen or an alkyl group containing from 1 to 50 carbon atoms, Z represents a photographically useful group, A represents an atomic group forming an aromatic ring, Ball represents an organic immobilizing group on the aromatic ring, which cntains from 8 to 50 carbon atoms, m represents an integer of 1 or 2, X represents a divalent organic group, Nu represents a nucleophilic group, and n represents an integer of 1 or 2, and X with the nucleophilic group Nu is capable of forming a 5- to 12-membered ring by oxidation having an electrophilic center at the carbon atom substituted by the --NHSO.sub.2 Z group.
    Type: Grant
    Filed: July 15, 1981
    Date of Patent: November 9, 1982
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Koichi Koyama, Shinsaku Fujita
  • Patent number: 4351898
    Abstract: A single emulsion layer photographic material such as a film or print material composed of a mixture of separate silver halide grains that are separately responsive to different colors of light and thereafter are treated to provide a colored image of the subject.
    Type: Grant
    Filed: January 3, 1978
    Date of Patent: September 28, 1982
    Inventor: Richard J. Goldberg
  • Patent number: 4350754
    Abstract: There are described novel compounds which are represented by the formula ##STR1## wherein R is ##STR2## A is sulfur or selenium; X represents the nonmetallic atoms necessary to form a nucleus which completes a five or six membered heterocyclic moiety; R.sub.1 is H or lower alkyl; R.sub.2 is H or a hydrolyzable group; and R.sub.3 is H, alkyl or a hydrolyzable group. The compounds are useful in photographic applications and provide controlled release of a photographically useful material during processing of photographic elements with an aqueous alkaline processing composition.
    Type: Grant
    Filed: June 12, 1981
    Date of Patent: September 21, 1982
    Assignee: Polaroid Corporation
    Inventors: James R. Bartels-Keith, Anthony J. Puttick
  • Patent number: 4328299
    Abstract: Polychromatic glass articles and methods of producing such articles are disclosed in which the glass is activated by exposure to ultraviolet radiation and contains as a sensitizing agent an oxide of copper, samarium, terbium, praeseodymium, or europium.
    Type: Grant
    Filed: July 23, 1980
    Date of Patent: May 4, 1982
    Assignee: Corning Glass Works
    Inventors: George H. Beall, Syed N. Hoda, Richard W. Waldron
  • Patent number: 4286045
    Abstract: An image forming material comprising a support having thereon a layer composed of a Ge-S composition or a Ge-S-X composition wherein X represents at least one element selected from the group consisting of Al, Si, Mg, Ti, V, Mn, Co, Ni, Sn, Zn, Pd, In, Se, Te, Fe, I, P and O which undergoes a structural change capable of being detected optically, electrically or chemically upon exposure imagewise to light wherein the Ge-S or Ge-S-X composition layer has a thickness of at least about 300 A and contains therein at least one element selected from the group consisting of Ag, Cu and Pb in an amount of more than 2 atoms of Ag, Cu and/or Pb based on 100 atoms of the Ge-S composition or the Ge-S-X composition.
    Type: Grant
    Filed: November 15, 1979
    Date of Patent: August 25, 1981
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Akira Nahara, Yoshihiro Ono, Tomizo Namiki, Shigeo Harada, Yuzo Mizobuchi, Tomoaki Ikeda
  • Patent number: 4277558
    Abstract: Silver halide photographic material containing hydroquinones and benzoquinones as anti-stain agents.
    Type: Grant
    Filed: May 21, 1980
    Date of Patent: July 7, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Shoji Kikuchi, Toshio Yajima, Kenichi Kishi, Takashi Sasaki, Keiichi Mori, Haruhiko Sato
  • Patent number: 4263397
    Abstract: A photographic product comprising, in a package, a light-sensitive silver halide photographic material having a silver halide emulsion layer coated on a support, characterized in that said silver halide emulsion layer contains a sensitizing or desensitizing dye and that the oxygen permeability of the package is below 5.times.10.sup.2 cc/m.sup.2. 24 hrs. atm. under a condition at 20.degree. C. and 0% of relative humidity and further that the sealed package is under a condition that a partial pressure of an oxygen-gas in the package is not more than 1/6 atmospheres at an initial stage.
    Type: Grant
    Filed: May 19, 1978
    Date of Patent: April 21, 1981
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Akira Horikoshi, Zene Kumagai
  • Patent number: 4250245
    Abstract: Hydroquinone esters are incorporated in photographic elements for color diffusion transfer assemblages and release a competing developer upon contact with a processing composition, to terminate further dye release. The hydroquinone esters are employed in a concentration sufficient, upon hydrolysis, to reduce substantially all the silver in the silver halide emulsion.
    Type: Grant
    Filed: August 17, 1979
    Date of Patent: February 10, 1981
    Assignee: Eastman Kodak Company
    Inventors: Guy Gehin, Eva Fage
  • Patent number: 4242428
    Abstract: An inorganic system of color photography in which colored images are recorded with compositions comprising a mixture of an iridescent pigment of the type displaying an interference-reinforced reflection color, and finely divided particles of a photosensitive material, such as a silver halide, which can be developed to give black or other light absorbing particles which will absorb light wavelengths complementary to the interference-reinforced reflection color of the iridescent pigment. The system does not require organic dyes in the final image, which is highly light-stable, and uses much smaller amounts of silver than conventional black and white photography.
    Type: Grant
    Filed: October 21, 1977
    Date of Patent: December 30, 1980
    Inventor: Chester Davis
  • Patent number: 4228235
    Abstract: A color photographic material having stabilized dye images is described which has a compound with the formula: ##STR1## where R and R.sub.2 individually represent an alkyl group, R represents an n-valent organic group and n is an integer of from 1 to 6.
    Type: Grant
    Filed: January 8, 1979
    Date of Patent: October 14, 1980
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kyohei Okonogi, Mikio Sato, Katsuo Mogaki, Takashi Sasaki, Takashi Uchida
  • Patent number: 4199355
    Abstract: Photographic elements, processes for forming images in photographic elements and new compounds are disclosed. Generally, the invention relates to improved immobile compounds which can be used to provide positive images from negative recording-developing photographic materials such as negative silver halide emulsions. The compounds contain a photographically useful group such as a dye or dye precursor and are capable of releasing said photographically useful group under alkaline conditions, and are also capable of reaction with an oxidized silver halide developing agent before substantial release of said photographically useful group occurs, to provide a reaction product having a substantially lower rate of release of said photographically useful group.
    Type: Grant
    Filed: June 24, 1975
    Date of Patent: April 22, 1980
    Assignee: Eastman Kodak Company
    Inventors: Jerald C. Hinshaw, Paul B. Condit
  • Patent number: 4184872
    Abstract: An inorganic system of color photography in which colored images are recorded with compositions comprising a mixture of an iridescent pigment of the type displaying an interference-reinforced reflection color, and finely divided particles of a photosensitive material, such as a silver halide, which can be developed to give black or other light absorbing particles which will absorb light wavelengths complementary to the interference-reinforced reflection color of the iridescent pigment. The system does not require organic dyes in the final image, which is highly light-stable, and uses much smaller amounts of silver than conventional black and white photography.
    Type: Grant
    Filed: November 3, 1976
    Date of Patent: January 22, 1980
    Inventor: Chester Davis