And Solvent Or Emulsifier Or Coating Aid Patents (Class 430/546)
  • Patent number: 5001045
    Abstract: A silver halide color photographic material composed of a support having thereon at least one light-sensitive silver halide emulsion layer, at least one layer thereof containing a yellow coupler represented by formula (I), a sparingly water-soluble epoxy compound represented by formula (II) and a water-insoluble but organic solvent-soluble homopolymer or copolymer: ##STR1## wherein R.sub.11 represents an N-arylcarbamoyl group; and Z.sub.11 represents a group capable of being released by a reaction with the oxidation product of an aromatic primary amine color developing agent; and ##STR2## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4, which may be the same or different, each represents hydrogen, an aliphatic group, an aromatic group, an aliphatic oxycarbonyl group, an aromatic oxycarbonyl group or a carbamoyl group; provided that at least one of R.sub.1, R.sub.2, R.sub.3 and R.sub.4 represents a group other than hydrogen; R.sub.1, R.sub.2, R.sub.3 and R.sub.4 contain a total of 8 to 60 carbon atoms; and R.
    Type: Grant
    Filed: August 22, 1988
    Date of Patent: March 19, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuo Furutachi, Osamu Takahashi
  • Patent number: 4990435
    Abstract: A polymeric latex to load photographically useful compounds into photographic elements comprises, as a dispersed phase, fine particles of a hydrophobic polymer which, for at least 70% of its weight, comprises:(a) repeating units derived from an ethylenic monomer containing a sulfonic or sulfonate group which monomer is capable of forming hydrophilic homopolymers, said units comprising 0.5 to 1.5% by weight of said hydrophobic polymer,(b) repeating units derived from an N-3-oxo-alkyl-substituted acrylamide, said units comprising from 5 to 25% by weight of said hydrophobic polymer, and(c) repeating units derived from acrylic acid ester monomers having a TG lower than 0.degree. C., said units comprising at least 43.5% by weight of said hydrophobic polymer,the remaining polymer weight percentage, from zero to 30%, being formed by repeating units derived from inert monomers and/or cross-linking monomers.
    Type: Grant
    Filed: December 10, 1986
    Date of Patent: February 5, 1991
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Angelo Vallarino, Mauro Besio, Lorenzo Vittore
  • Patent number: 4990431
    Abstract: The invention is performed by providing a first flow of water and surfactant, a second flow comprising solvent, base and photographic material, and mixing said first and second streams and either simultaneously or immediately following thereof neutralizing said streams to prevent hydrolysis of a hydrolyzable surfactant and/or premature precipitation of particles before neutralization. The streams then may be immediately treated for formation into photographic materials. In a preferred method the first and second stream may be brought together immediately prior to a mixer with addition of acid directly into the mixer to neutralize the dispersion of fine particles.
    Type: Grant
    Filed: January 17, 1989
    Date of Patent: February 5, 1991
    Assignee: Eastman Kodak Company
    Inventors: Pranab Bagchi, James T. Beck, Lia A. Crede
  • Patent number: 4988610
    Abstract: The invention provides a composition comprising a hydrophilic colloid and a surface active agent characterised in that the surface active agent is a compound having the formula ##STR1## wherein each of R.sub.1, R.sub.2 and R.sub.3 independently is a substituted or unsubstituted alkyl group or a substituted or unsubstituted aryl group;each of X and Y is --H or --Q.sup.- M.sup.+ ;Q.sup.- is an anion; and,M.sup.+ is a cation;provided that when X is --H, Y is --Q.sup.- M.sup.+ and that when X is --Q.sup.- M.sup.+, Y is --H.Preferred surface active agents include compounds of the above formula wherein R.sub.1, R.sub.2 and R.sub.3 are identical.The anion Q.sup.- is a negatively charged atom or group of atoms preferably comprising a sulphonate group, such as --SO.sub.3.sup.- or --CH.sub.2 SO.sub.3.sup.- or a sulphate group, such as --OSO.sub.3.sup.-.The cation M.sup.+ is a positively charged atom or group of atoms preferably chosen from alkali metal cations, such as Na.sup.+ or ammonium.
    Type: Grant
    Filed: May 30, 1989
    Date of Patent: January 29, 1991
    Assignee: Eastman Kodak Company
    Inventors: Alan R. Pitt, John T. Wear, Rachel Richardson, David Young
  • Patent number: 4987062
    Abstract: A process for preparing a silver halide emulsion is disclosed, which comprises dissolving one or more substantially water-insoluble photographic additives in a solution of an organic solvent containing a surface active agent having a hydrophilic --SO.sub.3 or --OSO.sub.3 group wherein said organic solvent is an alcohol, and then adding the resulting solution to a silver halide emulsion. A small amount of a base, or small amounts of a base and an acid may optionally be present in the mixed solution of the organic solvent and the surface active agent prior to adding the one or more substantially water-insoluble photographic additives.
    Type: Grant
    Filed: July 5, 1989
    Date of Patent: January 22, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Fumitaka Terai, Hiroyuki Yamagami, Nobuhiko Uchino, Masaki Okazaki
  • Patent number: 4983507
    Abstract: The present invention provides silver halide color photographic materials having a layer which contains at least one magenta color image-forming oleophilic coupler of the following formulae (I) and/or (II) and at least one of the following formula (III): ##STR1## in which Ar represents a phenyl group which is substituted by at least one substituent selected from the group consisting of a halogen atom, an alkyl group, an alkoxy group, an alkoxycarbonyl group and a cyano group; Y represents an acylamino group or an anilino group; and Z.sub.1 represents a group capable of being removed by coupling, ##STR2## in which X represents a hydrogen atom or a substituent; Z.sub.2 represents a hydrogen atom or a group capable of being removed by coupling;W represents a hydrogen atom, an acyl group or an aliphatic or aromatic sulfonyl group;Za and Zb each represent a methine group, a substituted methine group or --N.dbd.; andX, Z.sub.
    Type: Grant
    Filed: October 26, 1988
    Date of Patent: January 8, 1991
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Osamu Takahashi, Hideaki Naruse, Masakazu Morigaki, Nobutaka Ohki, Nobuo Furutachi
  • Patent number: 4973545
    Abstract: A photographic coupler containing an aryloxysilyl group (--X--O--Y) wherein X is substituted or unsubstituted arylene and Y is a silyl group) is useful in photographic silver halide elements and processes. Such a photographic coupler enables improved dispersibility and improved photographic properties.
    Type: Grant
    Filed: September 14, 1989
    Date of Patent: November 27, 1990
    Assignee: Eastman Kodak Company
    Inventor: Christopher P. Moore
  • Patent number: 4973535
    Abstract: This invention relates to a color photographic silver halide recording material containing a dye image-forming coupler compound and a sulfonamide compound which is capable of altering the spectral absorption properties of a dye formed by reaction of the coupler compound with oxidized developing agent.
    Type: Grant
    Filed: August 12, 1988
    Date of Patent: November 27, 1990
    Assignee: Eastman Kodak Company
    Inventors: Paul B. Merkel, David J. Giacherio
  • Patent number: 4970139
    Abstract: Base and auxiliary solvent solubilized precipitated dispersions of couplers and other photographic materials usually produce very small particle dispersions, and usually such dispersions are extremely highly reactive because of the smallness of the particle size. However, some relatively more hydrophobic couplers, even though they produce small particles when a dispersion is formed by the precipitation technique, lead to extremely unreactive dispersions. The method of this invention constitutes a single step precipitation technique where a permanent high boiling water insoluble coupler solvent is incorporated into the precipitated particles to produce photographically highly active coupler dispersions.
    Type: Grant
    Filed: October 2, 1989
    Date of Patent: November 13, 1990
    Assignee: Eastman Kodak Company
    Inventor: Pranab Bagchi
  • Patent number: 4965179
    Abstract: A novel silver halide color photographic material is described, comprising a support having thereon at least three silver halide emulsion layer units each having a sensitivity to each of three primary colors of blue, green and red, wherein at least one unit among said silver halide emulsion layer units comprises a layer group containing at least two layers each having a different sensitivity and at least one layer in said layer group, which satisfies the following condition (A) or (B):(A) in the case where the silver halide emulsion layer unit is a blue-sensitive or green-sensitive unit, the layer is one to take charge of coloration of a substantially highest density range on a characteristic curve; or(B) in the case where the silver halide emulsion layer unit is a red-sensitive unit, the layer is one other than a layer which is in charge of coloration of a substantially highest density range on a characteristic curve,contains at least one compound of the general formula (I): ##STR1## wherein R.sub.
    Type: Grant
    Filed: December 27, 1988
    Date of Patent: October 23, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Shigeru Kuwashima, Akio Mitsui
  • Patent number: 4959300
    Abstract: A silver halide photographic light-sensitive material which is prevented from softening in gradiation of the toe proportion on the resultant characteristics curve during the storage of the material. The photographic material comprises a support having thereon at least one silver halide emulsion layer, and contains a magenta coupler represented by the following formula M-1 and at least one surface active agent having in the molecule thereof at least two groups selected from the group consisting of a carboxy group and salt thereof, a sulfonic group and a salt thereof and a salt of sulfric ester group. ##STR1## wherein Z represents a group of nonmetal atoms necessary for forming a nitrogen-containing heterocycle which may have a substituent group; X represents a hydrogen atom, or a group capable of being split off upon the reaction with the oxydized product of a color developing agent; and R represents a hydrogen atom or a substituent.
    Type: Grant
    Filed: April 12, 1988
    Date of Patent: September 25, 1990
    Assignee: Konica Corporation
    Inventors: Toyoki Nishijima, Kaoru Onodera
  • Patent number: 4957857
    Abstract: The invention provides stable dispersions of couplers and methods of their formation. The stable dispersions are formed by the use of a nonionic water soluble polymer in combination with an anionic surfactant having a sulfate or sulfonate head group and a hydrophobic group of 8 to 20 carbons. The preferred nonionic water soluble polymers are polyethyleneoxide and polyvinylpyrrolidene.
    Type: Grant
    Filed: December 23, 1988
    Date of Patent: September 18, 1990
    Assignee: Eastman Kodak Company
    Inventor: Krishnan Chari
  • Patent number: 4954432
    Abstract: A silver halide light-sensitive photographic material comprising a support and provided thereon at least one silver halide emulsion layer containing a yellow dye-foming coupler having a formula [A] below and a high boiling organic solvent having a dielectric constant of not more than 6.0; ##STR1## wherein R.sub.1 represents a halogen atom or an alkoxy group having 1 to 4 carbon atoms; R.sub.2 represents a hydrogen atom, a halogen atom, an alkyl group or an alkoxy group; R.sub.3 and R.sub.4 independently represent an alkyl group which is capable of making said coupler non-diffusible in the photographic material; X.sub.1 represents a tertiary butyl group or a p-alkoxy phenyl group; X.sub.2 represents a hydrogen atom or a group which is capable of being split off during color development; and X.sub.3 represents a linking group.
    Type: Grant
    Filed: December 29, 1988
    Date of Patent: September 4, 1990
    Assignee: Konica Corporation
    Inventor: Toyoki Nishijima
  • Patent number: 4954431
    Abstract: A silver halide photographic material containing a specific magenta coupler and a heterocyclic mercapto compound is disclosed. The photographic material is raised in its resistivity to magenta fogging caused by contamination of developer with bleaching solution, without degradation of color reproducibility. The photographic material is comprised of a support having thereon a silver halide emulsion layer and a non-light-sensitive layer and the emulsion layer contains a magenta coupler represented by the following Formula I and at least one of the emulsion layer and the non-light-sensitive layer contains a compound represented by the following formula S.
    Type: Grant
    Filed: June 23, 1989
    Date of Patent: September 4, 1990
    Assignee: Konica Corporation
    Inventors: Toyoki Nishijima, Masaki Tanji
  • Patent number: 4952487
    Abstract: In combination with oil formers of the alkylphenol type, 3-anilinopyrazolones show absorption maxima displaced by about 8 to 12 nm towards longer wavelengths and a blue secondary absorption further displaced towards the UV range and, hence, a reduced yellow secondary density.
    Type: Grant
    Filed: December 28, 1989
    Date of Patent: August 28, 1990
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Gunter Renner, Johannes Sobel, Klaus Wagner, Gunter Junkers, Friedhelm Sommer
  • Patent number: 4948722
    Abstract: Novel pyrazoloazole dye-forming couplers comprising (I) at least one polyether group (A) comprising at least two ether (--O--) groups and (II) having between the group (A) and the pyrazoloazole nucleus a linking group (L) that is capable of increasing the reactivity of the coupler to enable improved dye images in a photographic element and process. These couplers are useful in photographic silver halide elements and processes.
    Type: Grant
    Filed: October 31, 1988
    Date of Patent: August 14, 1990
    Assignee: Eastman Kodak Company
    Inventor: John W. Harder
  • Patent number: 4946770
    Abstract: A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer containing a dispersion, said dispersion comprising oleophilic fine particles containing (a) at least one oil-soluble cyan coupler represented by formula (I) (described herein) capable of forming substantially non-diffusible cyan dye upon coupling with an oxidation product of an aromatic primary amine developing agent, and (b) a water-insoluble, organic solvent-soluble homopolymer or copolymer comprising not more than about 20% by weight of a repeating unit having an acid radical in the main chain or a side chain thereof, wherein the dispersion does not contain high-boiling point organic solvents. The photographic material provides color images excellent in preservability, particularly resistance to dark discoloration and light discoloration in good balance.
    Type: Grant
    Filed: August 13, 1987
    Date of Patent: August 7, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Osamu Takahashi, Tsumoru Hirano, Seiki Sakanoue
  • Patent number: 4945034
    Abstract: A silver halide photographic light-sensitive material is disclosed, which has excellent characteristics peculiar to pyrazoloazole type magenta couplers and yet good suitability to rapid processing, and shows improvement in the gradiation in respect of softening at the toe portion of characteristic curve thereof without impairment of the image preservability and other photographic properties. The photographic material comprises a support having thereon a silver halide emulsion layer containing a silver halide grain having a silver chloride content of not less than 90 mole %, a compound represented by the following Formula I, and a compound capable of deactivating the oxidized product of a color developing agent with a relative reaction rate of not less than 1.6; ##STR1## wherein R.sub.1, R.sub.2 and R.sub.
    Type: Grant
    Filed: January 24, 1989
    Date of Patent: July 31, 1990
    Assignee: Konica Corporation
    Inventors: Masaki Tanji, Toyoki Nishijima
  • Patent number: 4935321
    Abstract: This invention relates to a color photographic silver halide recording material containing a dye image-forming coupler compound and a carbonamide compound which is capable of altering the spectral absorption properties of a dye formed by reaction of the coupler compound with oxidized developing agent.
    Type: Grant
    Filed: November 14, 1989
    Date of Patent: June 19, 1990
    Assignee: Eastman Kodak Company
    Inventor: Paul B. Merkel
  • Patent number: 4933270
    Abstract: The invention provides a method of forming a dispersion of base degradable hydrophobic component for a photographic system. The invention is accomplished by mixing the component, solvent, and surfactant, at an elevated temperature if necessary, metering the mixture of solvent, surfactant, and hydrophobic component to an excess of water with agitation so as to precipitate from the water solvent solution small particles of the hydrophobic component. The small particles then form a stable dispersion, after washing by dialysis or diafiltration, that will not agglomerate during storage prior to use. The preferred photographic component for use in the system of the invention is an ester terminated photographic coupler that would decompose if subjected to the high pH treatment of prior art procedures.
    Type: Grant
    Filed: September 26, 1988
    Date of Patent: June 12, 1990
    Assignee: Eastman Kodak Company
    Inventor: Pranab Bagchi
  • Patent number: 4923783
    Abstract: A silver halide photographic material comprising a support having thereon at least one hydrophilic colloid layer containing at least one high boiling point organic solvent and at least one substantially water-insoluble photographically useful reagent both dispersed therein, wherein at least one of the high boiling point organic solvents is a compound represented by formula (I):(ArCOO).sub.n --L (I)(the symbols of which are described herein).By incorporation of a compound of formula (I), reductive fading of cyan dyes formed in the material due to heat, moisture is minimized.A method of processing the silver halide photographic material as imagewise exposed with a color developer containing substantially no benzyl alcohol is also disclosed.
    Type: Grant
    Filed: October 14, 1988
    Date of Patent: May 8, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hidetoshi Kobayashi, Hideaki Naruse
  • Patent number: 4916050
    Abstract: A silver halide light-sensitive photographic material comprising on a support photographic component layers containing a compound of Formula [I] and/or Formula [II]:R.sub.1 OOC--R.sub.2 --COO--R.sub.3 --OOC--R.sub.2 --COO).sub.n R.sub.4 [I],R.sub.5 O--R.sub.6 --OOC--R.sub.7 --COO--R.sub.6).sub.n OR.sub.8 [II]wherein R.sub.1 and R.sub.4 are independently selected from the group consisting of an alkyl group, an alkenyl group, a cycloalkyl group, an aryl group and a heterocyclic group; R.sub.2, R.sub.3, R.sub.6 and R.sub.7 are divalent groups independently selected from the group consisting of an alkylene group, an alkenylene group, a cycloalkylene group and a group of any combination of these groups; R.sub.5 and R.sub.6 each is either an acyl group or a phosphonyl group; and n is an integer of from 1 to 20; is disclosed.
    Type: Grant
    Filed: May 25, 1988
    Date of Patent: April 10, 1990
    Assignee: Konica Corporation
    Inventors: Toyoki Nishijima, Kaoru Onodera
  • Patent number: 4912026
    Abstract: A light-sensitive silver halide photographic material having a support with at least one silver halide emulsion layer containing a dye-forming coupler, where the light-sensitive silver halide photographic material is characterized in that at least one of the silver halide emulsion layers contains (i) the dye-forming coupler dispersed with the use of a high boiling organic solvent having a dielectric constant of 6.0 or less, (ii) silver halide grains containing a gold compound and having silver chloride content of 90 mole % or more, and (iii) a compound represented by General Formula (S) shown below. General Formula (S): ##STR1## where Q is a group of atoms necessary to complete a 5- or 6-membered heterocyclic ring or a 5- or 6-membered ring fused with a benzene ring and M is a hydrogen atom, an alkali metal or an ammonium group.
    Type: Grant
    Filed: March 23, 1989
    Date of Patent: March 27, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Masanobu Miyoshi, Makoto Kajiwara, Kaoru Onodera, Eiichi Sakamoto
  • Patent number: 4910126
    Abstract: A light-sensitive silver halide photographic material comprising a support and provided thereon a silver halide emulsion layer containing a magenta dye-forming coupler represented by formula (M-I) and a compound represented by formula (I): ##STR1## wherein Z represents a group of non-metal atoms necessary to complete a nitrogen-containing heterocylic ring which may have a substituent; X represents a hydrogen atom or a substituent capable of being split off upon reaction with the oxidized product of a color developing agent; and R represents a hydrogen atom or a substituent; ##STR2## wherein R.sup.1, R.sup.2 and R.sup.3 independently represent an aliphatic group or an aromatic group; and l, m, n independently represent 0 to 1 provided that l, m and n are not 1 at the same time is disclosed.
    Type: Grant
    Filed: April 7, 1988
    Date of Patent: March 20, 1990
    Assignee: Konica Corporation
    Inventors: Hirokazu Sato, Shigeto Hirabayashi
  • Patent number: 4910127
    Abstract: A silver halide color photographic light-sensitive material is disclosed, which has excellent rapid processability and is remarkably improved in spectral absorption characteristics and fastness against light of magnet images. The photographic material comprising a support bearing at least one silver halide emulsion layer thereon, and the silver halide emulsion layer containssilver halide grains each containing silver chloride in an amount of not less than 80 mol %, andat least one couplers selected from the group consisting of the couplers represented by the following General Formulas (a), (b) and (c), respectively, or a polymer coupler comprising said coupler, and an anti-discoloring agent, each dispersed in the silver halide emulsion layer by making use of a high boiling organic solvent, provided that a proportion of said high boiling organic solvent to said coupler is not less than 0.6 by weight.
    Type: Grant
    Filed: October 28, 1988
    Date of Patent: March 20, 1990
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Masao Sakaki, Kaoru Onodera
  • Patent number: 4904579
    Abstract: A light-sensitive silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, wherein the silver halide color photographic material comprises at least one layer containing a 5-pyrazolone magenta coupler represented by general formula (I) and a non-color forming, diffusion-resistant carboxylic acid compound: ##STR1## wherein W represents an aryl group; Y represents a carbonamido group, a ureido group or an anilino group; and R represents an alkyl group, an aryl group or a heterocyclic group.The silver halide color photographic material has high sensitivity, high color forming property, good formalin resistivity and good preservability, and provides magenta color images having good stability.
    Type: Grant
    Filed: October 29, 1987
    Date of Patent: February 27, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Keiji Mihayashi, Hidetoshi Kobayashi
  • Patent number: 4900655
    Abstract: A silver halide color photographic light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer, wherein at least one magenta coupler represented by the formula ##STR1## where the groups in the formula are defined in the specification; is dispersed in the silver halide emulsion layer in the presence of at least one high-boiling organic solvent represented by one of the formulae (II), (III), (IV) and (V): ##STR2## where the groups in the formulae are described in the specification. The a high boiling point organic solvent has a dielectric constant of not less than 4.00 at 25.degree. C. and 10 KHz.
    Type: Grant
    Filed: November 27, 1987
    Date of Patent: February 13, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kiyoshi Nakazyo, Takeshi Hirose, Genichi Hurusawa, Osamu Takahashi, Nobuo Furutachi, Hidetoshi Kobayashi
  • Patent number: 4898811
    Abstract: A color photographic silver halide material which, in at least one silver halide emulsion layer, contains a magenta coupler corresponding to formula I or (II) below ##STR1## in which R.sub.1 represents alkyl, aryl or a ballast group,R.sub.2 represents a ballast group, alkyl or aryl,Z represents hydrogen or a group releasable on reaction with the developer oxidation product,and a compound corresponding to formula (III) ##STR2## in which R.sub.3 represents alkyl, alkoxy, aryl, optionally substituted amino or the residue of a heterocycle,R.sub.4 represents COR.sub.5, NHR.sub.6, S(O).sub.n R.sub.7,K.sub.5 represents OR.sub.8, NHR.sub.8, alkyl, aryl or a heterocycle,R.sub.6 represents SO.sub.2 R.sub.8, COR.sub.8 or CONHR.sub.8,R.sub.7 represents alkyl, aryl or NHR.sub.3,R.sub.8 represents alkyl or aryl andn=0, 1 or 2,with the exception of compounds in which R.sub.3 is a carboxymethoxyphenyl, carboxymethoxy, alkoxycarbonylmethoxy or alkoxycarbonylmethoxyphyl radical substituted at the methylene group.
    Type: Grant
    Filed: December 2, 1988
    Date of Patent: February 6, 1990
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventors: Erich Wolff, Dieter Lowski, Harry Elias
  • Patent number: 4898812
    Abstract: A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, said emulsion layer containing at least one cyan dye forming coupler represented by the general formula (I): ##STR1## wherein, Q.sub.1 contains at least one nitrogen atom and represents a group of atoms that are combined to form, together with a carbon atoms attached thereto a 5- or more membered nitrogen-containing heterocyclic ring;Z.sub.1 represents a hydrogen atom or a group that can be released in a coupling reaction with the oxidation product of a color developing agent;R represents an acyl group or a sulfonyl group; andR' represents a hydrogen atom or an aliphatic group having 1 to 8 carbon atoms which may be substituted with one or more substituents; anda dimer coupler or a polymer coupler may be formed through R, R', Z.sub.1 or Q.sub.1 ;and at least one color development accelerator.The silver halide color photographic material has increased D.sub.max and sensitivity.
    Type: Grant
    Filed: August 7, 1987
    Date of Patent: February 6, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Kozo Aoki, Nobuo Furutachi
  • Patent number: 4892806
    Abstract: The invention provides water soluble surface active compounds having the formula ##STR1## wherein each of R.sup.1 and R.sup.2 independently is hydrogen, substituted or unsubstituted alkyl, substituted or unsubstituted cycloalkyl, or substituted or unsubstituted aryl, provided that not both R.sup.1 and R.sup.2 are hydrogen,and each of x and y independently is an integer from 3 to 6.In a preferred embodiment where discrete compounds are required, R.sup.1 and R.sup.2 are identical and x and y are identical.Particularly preferred compounds are those wherein each of R.sup.1 and R.sup.2 is an alkyl group having from 5 to 8 carbon atoms, more preferably from 6 to 7 carbon atoms, and each of x and y is an integer from 3 to 6.
    Type: Grant
    Filed: September 26, 1988
    Date of Patent: January 9, 1990
    Assignee: Eastman Kodak Company
    Inventors: Catherine B. A. Briggs, Alan R. Pitt
  • Patent number: 4885234
    Abstract: The present invention describes photographic materials containing stable phenolic cyan dye-forming coupler formulations which include a coupler having a p-cyanophenylureido group in the 2 position and an acylamino ballast having a sulfone group in the 5-position of the phenolic ring.
    Type: Grant
    Filed: September 29, 1988
    Date of Patent: December 5, 1989
    Assignee: Eastman Kodak Company
    Inventor: Paul L. Zengerle
  • Patent number: 4882267
    Abstract: A silver halide photographic light-sensitive material having a high color reproducibility is disclosed. The photographic comprises a support having thereon a blue-sensitive silver halide emulsion layer, a green-sensitive silver halide emulsion layer and a red-sensitive silver halide emulsion layer in which the red sensitive emulsion layer contains a non-color-forming compound represented by the following formula [I], a compound represented by the following formula [II] and at least one cyan-forming coupler represented by the following formula [III] or [IV]: ##STR1## The photographic material is improved in spectral aborption, stability and maximum density of the cyan image thereof.
    Type: Grant
    Filed: December 2, 1987
    Date of Patent: November 21, 1989
    Assignee: Konica Corporation
    Inventors: Shigeto Hirabayashi, Hirokazu Sato
  • Patent number: 4882266
    Abstract: A silver halide color photographic material comprising a support having coated thereon at least one silver halide emulsion layer, in which said silver halide emulsion layer or a layer adjacent thereto contains a pyrazoloazole magenta coupler having at least one substituted alkyl group represented by the formula (I): ##STR1## wherein [A] represents a pyrazoloazole magenta coupler residual group; R.sup.1 is an alkyl group; R.sup.2 and R.sup.3 each is a hydrogen atom or a substituent, provided that both R.sup.2 and R.sup.3 are not hydrogen atoms at the same time; and n is 1, 2 or 3.
    Type: Grant
    Filed: February 7, 1989
    Date of Patent: November 21, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Toshio Kawagishi, Kiyoshi Nakazyo
  • Patent number: 4874688
    Abstract: For incorporation of substantially water-insoluble photographic additives such as couplers into hydrophilic organic colloid layers of silver halide photographic materials, a phthalic acid ester of a formula (I): ##STR1## where R.sub.1 and R.sub.2 may be same or different and each represents a branched alkyl group having no more than 7 carbon atoms, is used so that said additives can effectively be dispersed in the colloid layers. Accordingly, the solubility and dispersibility of the additives is improved; the long-term stability of the additive dispersion is improved, and further and latent image storability and color-forming properties of the photographic material are also improved over the prior art photographic materials.
    Type: Grant
    Filed: March 4, 1988
    Date of Patent: October 17, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takashi Ozawa, Hidetoshi Kobayashi
  • Patent number: 4873182
    Abstract: Alkylenglycol aliphatic diesters are water-immiscible high-boiling organic solvents useful for dispersing hydrophobic photographic additives in hydrophilic colloid compositions which are incorporated into the composing layers of light-sensitive silver halide photographic materials.In particular, said alkylenglycol aliphatic diesters correspond to general formula ##STR1## wherein R.sub.1 and R.sub.2, the same or different, each represents an alkyl group having 1 to 15 carbon atoms, Q represents an acylic hydrocarbon divalent group having 1 to 10 carbon atoms, m represents 0 or 1 and the total number of carbon atoms represented in R.sub.1 +R.sub.2 is at least 6.
    Type: Grant
    Filed: April 28, 1988
    Date of Patent: October 10, 1989
    Assignee: Minnesota Mining and Manufacturing Company
    Inventors: Ivano Delprato, Agostino Baldassarri
  • Patent number: 4868097
    Abstract: A color image is formed by imagewise exposing a photosensitive material comprising at least (a) a photosensitive silver halide, (b) a binder, (c) a dye-providing substance which forms or releases a diffusible dye in response or counter-response to the reduction of the silver halide into silver at elevated temperatures, and (d) a specific-surface-active agent on a support, and heat developing the photosensitive material to form an image.
    Type: Grant
    Filed: April 25, 1988
    Date of Patent: September 19, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Yasuo Aotsuka, Masatoshi Kato, Masakazu Yoneyama
  • Patent number: 4868099
    Abstract: A color photographic recording material having a magenta layer which is prepared from a casting solution containing a 4-equivalent magenta coupler of the pyrazolone series and a thiosulphonic acid ester compound has the properties of 2-equivalent magenta couplers in its coupling reactivity and the properties of 4-equivalent magenta couplers in its speed of color formation.
    Type: Grant
    Filed: September 14, 1988
    Date of Patent: September 19, 1989
    Assignee: Agfa-Gevaert Aktiengesellschaft
    Inventor: Gunter Renner
  • Patent number: 4865963
    Abstract: A silver halide color photographic material comprising a support having thereon at least one silver halide emulsion layer, said silver halide emulsion layer containing a pyrazoloazole series magenta coupler represented by general formula [I] ##STR1## wherein, R.sup.1 and R.sup.2 each represents a hydrogen atom or a substituent; and X represents a hydrogen atom or a releasing group which is released at the reaction with the oxidation product of an aromatic primary amine developing agent; at least one of said R.sup.1 and R.sup.2 is an alkyl group having a secondary or tertiary carbon atom directly bonded to the skeleton, at least one of said R.sub.1 and R.sub.2 is a sulfonamidoalkyl group or a sulfamoylalkyl group; and the magenta coupler may form a dimer or more polymer at the position of said R.sup.1, R.sup.2 or X.By the combined use of high boiling point organic solvent and ultraviolet absorbent, light fastness and coloring property are markedly improved.
    Type: Grant
    Filed: September 30, 1986
    Date of Patent: September 12, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Nobuo Furutachi, Tadahisa Sato, Seiki Sakanoue, Akio Mitsui, Minoru Sakai, Masakazu Morigaki, Hidetoshi Kobayashi, Nobuo Sakai, Kiyoshi Nakazyo, Takeshi Hirose, Toshio Kawagishi
  • Patent number: 4863840
    Abstract: A silver halide color photographic light-sensitive material is disclosed, which is satifactory in the overall discoloration color balance of a dye image composed of yellow, magenta and cyan dyes in the light discoloration as well as in the dark discoloration and produces little or no yellow color stain when stored being exposed to a light or in the dark over an extensive period of time and which is excellent in the quality of the dye image even when stored over an extensive period of time.The color photographic material comprises a silver halide emulsion layers containing a specific yellow dye-forming coupler, a silver halide emulsion layer containing a specific magenta dye-forming coupler and a silver halide emulsion layer containing two kinds of specific cyan dye-forming couplers, and the respective emulsion layers each contain high-boiling organic solvent having a dielectric constant of not more than 6.0.
    Type: Grant
    Filed: January 13, 1987
    Date of Patent: September 5, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Kazuo Komorita, Kaoru Onodera
  • Patent number: 4857449
    Abstract: A silver halide color photosensitive material comprising, on a support, at least one silver halide photographic emulsion layer comprising an emulsified dispersion of fine lipophilic particles comprising at least one type of oil-soluble coupler which is non-diffusible and which forms a dye by coupling with the oxidized form of a primary aromatic amine color developing agent and at least one type of high boiling point organic solvent, said emulsified dispersion of fine lipophilic particles comprises a dispersion obtained by emulsifying and dispersing a mixed solution which comprises at least one type of coupler, and at least one type of high boiling point organic solvent as mentioned above, and at least one type of homopolymer or copolymer which is water-insoluble and soluble in organic solvent, and which comprises at least one type of repeating unit which does not have acid groups on the main chain or on a side chain, and said silver halide emulsion comprises a monodispersed silver chloride, silver chlorobromi
    Type: Grant
    Filed: February 23, 1988
    Date of Patent: August 15, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Tadashi Ogawa, Osamu Takahashi
  • Patent number: 4840887
    Abstract: A silver halide photographic material is disclosed, which comprises a support having formed thereon at least one silver halide emulsion layer, wherein the silver halide photographic material contains, in the silver halide emulsion layer, other hydrophilic colloid layer(s), or both, a compound represented by formula (I) ##STR1## wherein EAG represents an electron accepting group, --SO.sub.2 -- represents a sulfonylene group; X represents an oxygen atom (--O--), a sulfur atom (--S--) or an atomic group (--N(R.sub.2)--) containing a nitrogen atom; the single bond between --SO.sub.2 and X being cleaved after EAG receives an electron, wherein R.sub.1 and R.sub.2 each represents a simple bond or a group other than a hydrogen atom; said R.sub.1, R.sub.2, EAG may be combined with each other to form a ring; (Time) represents a group capable of releasing a photographically useful group (PUG) upon the cleavage of the SO.sub.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: June 20, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventor: Koki Nakamura
  • Patent number: 4840881
    Abstract: A process for the preparation of a light-sensitive silver halide photographic material comprising a support, a silver halide emulsion layer, and a non-light-sensitive hydrophilic colloid layer which consists essentially of a plurality of layer elements; a process comprises incorporating oil particles into at least one of the elements, so that the oil particle density of the outermost layer element is not the highest of the oil particle densities of all of the elements.
    Type: Grant
    Filed: July 21, 1988
    Date of Patent: June 20, 1989
    Assignee: Konishiroku Photo Industry Co., Ltd.
    Inventors: Yoshikazu Watanabe, Motoaki Tanaka
  • Patent number: 4840878
    Abstract: A method for forming a color image is disclosed, which comprises imagewise exposing a multi-layer silver halide color photographic material comprising a reflective support having provided thereon at least three silver halide emulsion layers different in color sensitivity, each of which separately contains at least one coupler selected from a specific combination of cyan, magenta, and yellow couplers, and processing the exposed material with a color developing solution containing substantially no benzyl alcohol for a period of not more than 2 minutes and a half. A color image excellent in color reproducibility and preservability can be obtained rapidly without using benzyl alcohol.
    Type: Grant
    Filed: September 30, 1988
    Date of Patent: June 20, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Takeshi Hirose, Nobuo Furutachi, Kozo Aoki, Kiyoshi Nakazyo, Genichi Furusawa
  • Patent number: 4839267
    Abstract: Color photographic motion picture elements adapted to form a multicolor photographic dye image and an integral, infrared-absorbing, dye sound track and comprising a 1-hydroxy-2-N-(5-ballasted-thiazol-2-yl)-naphthamide coupler dispersed with the aid of a water-immiscible, high-boiling, oil-type hydrocarbon oil-former, said coupler bearing a phenyl group or a substituted phenyl group at the 4-position of the thiazol-2-yl ring and being capable of forming infrared-absorbing quinone imine dyes by reaction with an oxidized aromatic primary amino developing agent.
    Type: Grant
    Filed: October 21, 1987
    Date of Patent: June 13, 1989
    Assignee: AGFA-Gevaert, N.V.
    Inventors: Marcel J. Monbaliu, Paul L. Van Meerbeeck
  • Patent number: 4837136
    Abstract: A silver halide photographic material is described comprising a support having coated thereon at least one silver halide emulsion layer, wherein at least one of the silver halide emulsion layer and other hydrophilic colloid layer contains a nondiffusible photographically useful compound having a sulfo group and a group represented by the following general formula (I): ##STR1## wherein R.sub.1 and R.sub.2 each represents an aliphatic group having at least 2 carbon atoms and r represents 0 or 1.The compounds represented by the general formula (I) are photographically useful compounds which impart excellent photographic properties to silver halide photographic materials, including improved dispersibility.
    Type: Grant
    Filed: October 9, 1986
    Date of Patent: June 6, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Seiji Ichijima, Yasuhiro Shimada, Jun Arakawa
  • Patent number: 4828974
    Abstract: A photographic light-sensitive material containing a novel gelatin hardener is disclosed, which comprises as a gelatin hardener at least one compound represented by formula (I) ##STR1## wherein R.sup.1 and R.sup.2 each represents a substituted or unsubstituted alkyl group, a substituted or unsubstituted aryl group, or a substituted or unsubstituted aralkyl group, or R.sup.1 and R.sup.2 together represent a nitrogen-containing heterocyclic ring; R.sup.3 represents a hydrogen atom, a halogen atom, an alkyl group, an aryl group, an aralkyl group, or an alkoxy group; and R.sup.4 represents a chemical bond, or an alkylene group, an arylene group, or a divalent group composed of these groups. The compound represented by formula (I) provides rapid hardening progress, prevents after-hardening, and does not undergo hardening inhibition when applied to silver halide color photographic materials.
    Type: Grant
    Filed: May 11, 1987
    Date of Patent: May 9, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Hisashi Okamura, Hiroshi Kawamoto
  • Patent number: 4827019
    Abstract: Photographic coupler solvents comprising aromatic carboxylic esters such as phthalates and isophthalates having bulky or branched ester substituents are described for incorporation in photographic emulsions and elements. The solvents are preferably employed in the cyan layer to protect the cyan dye against ferrous ion reduction. The solvents also provide improvements in yellow dye stability to light, cyan dye stability in the dark and magenta dye stability to heat and light.
    Type: Grant
    Filed: January 12, 1987
    Date of Patent: May 2, 1989
    Assignee: Eastman Kodak Company
    Inventor: Sundaram Krishnamurthy
  • Patent number: H706
    Abstract: A silver halide color photosensitive material is disclosed, characterized in that a lipophilic fine grain dispersed in at least one hydrophilic colloidal layer formed on a support contains at least one compound of formula (I) and at least one compound of formula (II):R.sub.1 --SO.sub.2.M.sub.1 (I)R.sub.2 --SO.sub.3.M.sub.2 (II)wherein each of R.sub.1 and R.sub.2 represents an aliphatic group having 8 or more carbon atoms, an aromatic group having 8 or more carbon atoms or a heterocyclic group having 8 or more carbon atoms; each of M.sub.1 and M.sub.2 represents a hydrogen atom or an inorganic or organic salt-forming atom or atomic group; also M.sub.1 represents a protective group to be hydrolyzed with alkali; and sodium dodecylbenzenesulfonate is excluded from the compounds of formula (II). The combined use of the compounds of formulae (I) and (II) can effectively control the formation of stains on the processed white ground after the lapse of time without substantially lowering the maximum color density.
    Type: Grant
    Filed: August 29, 1988
    Date of Patent: November 7, 1989
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Osamu Takahashi, Nobuo Furutachi, Masakazu Morigaki
  • Patent number: H817
    Abstract: A photographic light-sensitive material comprising a support having provided thereon at least one silver halide emulsion layer, wherein said light-sensitive material contains:(1) a compound represented by formula (I):PWR--Time--.sub.t PUG (I)wherein PWR represents a group capable of releasing (Time--.sub.t PUG upon being reduced; PUG represents a photographically useful group; Time represents a group capable of releasing PUG through a reaction subsequent to the release from PWR in the form of --Time--.sub.t PUG; and t represents 0 or 1, and(2) a polymer comprising at least 10 repeating units derived from the same monomer and having a molecular weight of 1000 or more. The photographic light-sensitive material exhibits both high activity of a compound capable of releasing a photographically useful group during development processing and preservation stability before development processing.
    Type: Grant
    Filed: April 29, 1988
    Date of Patent: September 4, 1990
    Assignee: Fuji Photo Film Co., Ltd.
    Inventors: Masaharu Toriuchi, Keizo Koya
  • Patent number: H830
    Abstract: A novel silver halide color photographic material containing a desilvering accelerator releasing compound, which comprises at least one light-sensitive silver halide emulsion layer on a support, wherein at least one of said emulsion layer and a non-light sensitive hydrophilic layer(s) contains at least one compound represented by the formula (I)PWR--Time--.sub.t BA (I)wherein PWR represents a group which undergoes reduction to release (Time--.sub.t BA; BA represents a group which becomes a desilvering accelerator after being released; Time represents a group which releases BA through a reaction after being released from PWR as (Time--.sub.t BA; and t represents an integer of 0 or 1.
    Type: Grant
    Filed: May 2, 1988
    Date of Patent: October 2, 1990
    Inventors: Naoyasu Deguchi, Shinji Ueda, Koki Nakamura