Copolymer Of Olefinically Unsaturated Hydrocarbon Monomer And Additional Monomer (e.g., Ethylene-vinyl Acetate Copolymers, Etc.) Patents (Class 44/393)
  • Patent number: 11898115
    Abstract: The present invention relates to a nitrogen-containing terpolymer biodiesel solidification point depressant, and a preparation method and application thereof. The preparation method includes the following steps: 1) respectively preparing methylacrylic acid high carbon ester and N-hexadecyl methacrylamide; 2) adding the methylacrylic acid high carbon ester, the N-hexadecyl methacrylamide, and vinyl acetate to a solvent, and adding an initiator for polymerization to yield a methylacrylic acid high carbon ester-N-hexadecyl methacrylamide-vinyl acetate terpolymer, i.e., a nitrogen-containing terpolymer biodiesel solidification point depressant.
    Type: Grant
    Filed: May 27, 2021
    Date of Patent: February 13, 2024
    Assignee: SHANGHAI INSTITUTE OF TECHNOLOGY
    Inventors: Sheng Han, Suya Yin, Dongyuan Jin, Xian Zhu, Taishun Yang, Mingxia Yuan, Xin Li, Hualin Lin, Yuan Xue
  • Patent number: 11359036
    Abstract: The present invention provides an amine-based polymer, a preparation process thereof and use thereof. The amine-based polymer of the present invention is characterized in that said amine-based polymer contains a polymer main chain, and a structure represented by formula (I) is attached onto the polymer main chain, and said structure is attached to the polymer main chain via an attaching end present in at least one of Group G, Group G? and Group A in the structure, wherein each of the groups is defined as in the description. The amine-based polymer of the present invention is suitably used as a detergent, particularly suitably used as a fuel detergent. The amine-based polymer of the present invention is useful as a fuel detergent, and has an extraordinarily excellent detergency and dispersion properties.
    Type: Grant
    Filed: May 31, 2019
    Date of Patent: June 14, 2022
    Assignees: CHINA PETROLEUM & CHEMICAL CORPORATION, RESEARCH INSTITUTE OF PETROLEUM PROCESSING, SINOPEC
    Inventors: Jianrong Zhang, Zuoxin Huang
  • Patent number: 11326002
    Abstract: A polymer composition may include a polymer produced from ethylene, one or more branched vinyl ester monomers, and optionally, vinyl acetate; wherein the polymer has a number average molecular weight ranging from 5 to 10,000 kDa, and a molecular weight distribution ranging from 1 to 60, obtained by GPC.
    Type: Grant
    Filed: October 5, 2020
    Date of Patent: May 10, 2022
    Assignee: Braskem S.A.
    Inventors: Ashley Hanlon, Hadi Mohammadi, Nei Sebastiao Domingues, Jr., Adriane Gomes Simanke, Manoela Ellwanger Cangussu, Markus Busch, Sascha Hintenlang
  • Patent number: 10465854
    Abstract: Disclosed are compositions including up to 20 wt % of a paraffin inhibiting polymer, a refined petroleum distillate and one or more low Log P molecules, wherein the compositions are stable and flow at a temperature between about 0° C. and ?40° C., in many cases between about ?20° C. and ?40° C. The low Log P molecules are non-polymeric, have a Log P of less than 1, are liquids at 20° C. (1 atm), and have boiling points over 60° C., in many cases over 100° C. The compositions are useful paraffin inhibitor concentrates for use in the petroleum industry wherein the concentrates are stable, pumpable, and pourable at temperatures as low as ?40° C. and as high as 60° C.
    Type: Grant
    Filed: April 6, 2017
    Date of Patent: November 5, 2019
    Assignee: Ecolab USA Inc.
    Inventor: Kousik Kundu
  • Patent number: 10435337
    Abstract: An isoalkane alkylate base oil consisting predominantly of long carbon chain molecules having a straight chain of no less than 12 carbons and having at least one branch towards the middle of the straight chain, and characterized by: a) containing <10 wt % n-alkanes, <0.1 wt % olefinic hydrocarbons, and <0.1 wt % aromatic hydrocarbons; b) the at least one branch is a branched alkyl group containing 4 or more carbon atoms; and c) the long carbon chain molecules have two terminal linear unbranched alkyl groups each containing at least 4 carbons. Also, an isoalkane alkylate base oil, characterized by having a total integral of the 13C NMR spectrum wherein more than 25% of the total integral of the 13C NMR spectrum falls within 13C NMR resonances in ranges for linear long chain alkyl groups given by: C1(13.9-14.2 ppm), C2(22.6-22.8 ppm), C3(31.9-32.05 ppm), C4(29.35-29.45 ppm), and C5+(29.6-29.8 ppm).
    Type: Grant
    Filed: December 11, 2017
    Date of Patent: October 8, 2019
    Assignee: Chevron U.S.A. Inc.
    Inventor: Sven Ivar Hommeltoft
  • Patent number: 10259986
    Abstract: A composition for use in various down-hole operations in oil and gas wells. The compositions can include various combinations of certain ethers and other components e.g., esters, alkoxylated alcohols, acidizing agents and hydrocarbon co-solvents. The compositions are useful in a wide variety of down-hole applications particularly well cleaning, filter cake removal and well stimulation techniques e.g., acidizing.
    Type: Grant
    Filed: July 14, 2015
    Date of Patent: April 16, 2019
    Assignee: Sasol Performance Chemicals GmbH
    Inventors: Nelson Akaighe, Jorge Fernandez, Christian Jones
  • Patent number: 10113101
    Abstract: A composition of co-polymers, surfactants and solvents is provided for use in methods of reducing paraffin and wax deposition from crude oils in storage and transportation vessels.
    Type: Grant
    Filed: October 27, 2014
    Date of Patent: October 30, 2018
    Assignee: Ecolab USA Inc.
    Inventors: Nestor U. Soriano, Jr., Kim B. Peyton, Kim R. Smith, Joseph L. Stark, Dennis R. Compton
  • Patent number: 10041013
    Abstract: A fuel composition comprising a Fischer-Tropsch derived middle distillate fuel and a middle distillate flow improver, the remainder being another fuel component or mixture of fuel components. The other fuel component is selected from petroleum derived middle distillate fuel, hydrogenated vegetable oil, fatty acid methyl esters, and other Fischer Tropsch products. The Fischer-Tropsch derived middle distillate fuel is more than 80% v/v of the total composition; the maximum weight content in the carbon number distribution of the n-paraffins in the Fischer-Tropsch derived middle distillate fuel is below C16 and the weight ratio of iso to normal paraffins in the Fischer-Tropsch derived middle distillate fuel is 3.5:1 or higher. The middle distillate flow improver is a substituted ethylene polymer.
    Type: Grant
    Filed: December 19, 2013
    Date of Patent: August 7, 2018
    Assignee: SHELL OIL COMPANY
    Inventors: Mylin Camero, Mary Ann Dahlstrom, Paul Anthony Stevenson
  • Patent number: 9908955
    Abstract: A copolymer with high chemical homogeneity, consisting of (A) 50 to 30% by weight of ethylene, (B) 50 to 70% by weight of C4- to C24-hydrocarbyl ester of (meth)acrylic acid, (C) 0 to 5% by weight of (meth)acrylic acid and (D) 0 to 10% by weight of copolymerizable monomers, obtainable by polymerizing a mixture of 80 to 60% by weight of ethylene, 20 to 40% by weight of (meth)acrylic acid and 0 to 10% by weight of copolymerizable monomers in a backmixing, continuous polymerization apparatus, and subsequently polymer-analogously esterifying the resulting copolymer with C4- to C24-hydrocarbinols. The inventive copolymer is suitable for improving the cold flow properties of fuel oils, for lowering the lower mixing temperature of cold flow improver additives into fuel oils, and for improving the filterability of fuel oils comprising cold flow improver additives.
    Type: Grant
    Filed: March 22, 2016
    Date of Patent: March 6, 2018
    Assignee: BASF SE
    Inventors: Frank-Olaf Maehling, Jan Strittmatter, Irene Troetsch-Schaller, Ivette Garcia-Castro, Michael Schroers, Uwe Rebholz
  • Patent number: 9664666
    Abstract: A test apparatus for qualifying compositions used to reduce scale deposition in fluid, e.g., wax deposition in crude oil, is disclosed. The test apparatus includes a first reservoir capable of holding a first fluid, and a second rotatable reservoir disposed within the first reservoir, the second reservoir capable of holding a second fluid. The apparatus includes a fluid inlet through which the second fluid enters the second reservoir, and a fluid outlet through which the second fluid exits the second reservoir, wherein a bottom surface of the second rotatable reservoir is configured to be at least partially submerged in the first fluid so that precipitate from the first fluid can be deposited thereon.
    Type: Grant
    Filed: November 5, 2014
    Date of Patent: May 30, 2017
    Assignee: Chevron U.S.A. Inc.
    Inventors: David Michael Lavenson, Ramachandran Venkatesan, Lee David Rhyne, Laurence Ann Washington
  • Patent number: 9464249
    Abstract: The present invention relates to an aviation fuel composition comprising a) a jet fuel; b) an alkyl ester or a mixture of alkyl esters obtained from reaction between i) saturated fatty acids with carbon chain length ranging from 8 to 10 (C8-C10 saturated fatty acids); and ii) monohydric alcohols with carbon chain length ranging from 1 to 4 (C1-C4 monohydric alcohols); wherein the alkyl ester or mixture of alkyl esters can be blended with jet fuel in an amount up to 50% (vol/vol).
    Type: Grant
    Filed: November 24, 2006
    Date of Patent: October 11, 2016
    Assignee: MALAYSIAN PALM OIL BOARD
    Inventors: Yuen May Choo, Sit Foon Cheng, Ah Ngan Ma, Yusof Basiron
  • Patent number: 8979951
    Abstract: The invention provides terpolymers of ethylene, at least one ethylenically unsaturated ester and propene, which a) contain from 12.0 to 16.0 mol % of structural units derived from at least one ethylenically unsaturated ester, b) contain from 1.0 to 4.0 methyl groups derived from propene per 100 aliphatic carbon atoms, and c) have fewer than 6.5 methyl groups stemming from chain ends per 100 CH2 groups. and also their use as cold additives for middle distillates.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: March 17, 2015
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bettina Siggelkow, Werner Reimann, Matthias Krull, Markus Kupetz
  • Publication number: 20150068109
    Abstract: The invention relates to a hydrocarbon composition, which can be used as a fuel and/or fuel oil, containing a petroleum component (A) and a component of a biological origin (B), wherein the component of a biological origin is present in a quantity of up to 75% by volume with respect to the total composition.
    Type: Application
    Filed: November 10, 2014
    Publication date: March 12, 2015
    Applicants: ENI S.p.A., UOP LLC
    Inventors: Franco BALDIRAGHI, Silvia GUANZIROLI, Giovanni FARACI, Luigina Maria Flora SABATINO, Terry Louise MARKER, John Anthony PETRI
  • Patent number: 8968428
    Abstract: The invention provides additive mixtures comprising A) at least one terpolymer of ethylene, propene and at least one ethylenically unsaturated ester, which i) contains from 6.0 to 12.0 mol % of structural units derived from at least one ethylenically unsaturated ester having a C1- to C3-alkyl radical, ii) contains from 0.5 to 4.0 methyl groups derived from propene per 100 aliphatic carbon atoms, iii) has fewer than 8.0 methyl groups stemming from chain ends per 100 CH2 groups, and B) from 0.5 to 20 parts by weight, based on A), of at least one further component which is effective as a cold additive for mineral oils and is selected from B1) copolymers of ethylene and ethylenically unsaturated compounds whose content of ethylenically unsaturated compounds is at least 2 mol % higher than the content of ethylenically unsaturated esters in the terpolymer defined under A), B2) comb polymers, and B3) mixtures of B1) and B2), and also their use as a cold additive for middle distillates.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: March 3, 2015
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Bettina Siggelkow, Werner Reimann, Matthias Krull, Ulrike Neuhaus, Markus Kupetz, Andre Graf
  • Publication number: 20150052803
    Abstract: To provide a gas oil composition providing superior low temperature performance as compared with the conventional techniques. The gas oil composition, wherein a sulfur content is 1 ppm by mass or less, an aromatic content is 1% by mass or less, a C5-C15 paraffin content is 30% to 85% by mass, a C20-C27 paraffin content is 3% to 20% by mass, and a isoparaffin content is 50% to 75% by mass, contains a cold flow improver at 20 ppm to 1000 ppm by mass.
    Type: Application
    Filed: February 20, 2013
    Publication date: February 26, 2015
    Applicant: JX Nippon Oil & Energy Corporation
    Inventors: Takuya Niitsuma, Marie Iwama, Kazuya Nasuno, Tsukasa Kousaka
  • Patent number: 8961622
    Abstract: The invention thus provides terpolymers of ethylene, at least one ethylenically unsaturated ester and propene, which have i) from 4.0 to 12.0 mol % of structural units derived from at least one ethylenically unsaturated ester having a C4- to C20-alkyl radical, ii) from 0.5 to 4.0 methyl groups derived from propene per 100 aliphatic carbon atoms, and iii) fewer than 8.0 methyl groups stemming from chain ends per 100 CH2 groups.
    Type: Grant
    Filed: July 17, 2007
    Date of Patent: February 24, 2015
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Bettina Siggelkow, Werner Reimann, Matthias Krull
  • Patent number: 8911516
    Abstract: A quaternized copolymer obtainable by: (A) copolymerization of straight-chain, branched or cyclic, ethylenically unsaturated C2 to C100 hydrocarbons, which may bear oxygen- or nitrogen-functional substituents which cannot be reacted with amines to give amides or imides or with alcohols to give esters, with ethylenically unsaturated C3- to C12-mono- or dicarboxylic acids or acid derivatives, which can be reacted with amines to give amides or imides or with alcohols to give esters, to give a copolymer with a number-average molecular weight of 500 to 20 000; (B) partial or full amidation or imidation or esterification of the carboxylic acid functions by reacting them with oligoamines having 2 to 6 nitrogen atoms or alcoholamines, each of which comprises primary or secondary nitrogen atom or a hydroxyl group and a quaternizable tertiary nitrogen atom; (C) partial or full quaternization of the tertiary nitrogen atom with a quaternizing agent.
    Type: Grant
    Filed: June 24, 2011
    Date of Patent: December 16, 2014
    Assignee: Basf SE
    Inventors: Wolfgang Grabarse, Hannah Maria Koenig, Christian Tock, Cornelia Roeger-Goepfert, Ludwig Voelkel, Harald Boehnke
  • Patent number: 8790426
    Abstract: Quaternized terpolymer formed from (A) ethylene, (B) C2-C14-alkenyl esters of one or more aliphatic C1-C20-monocarboxylic acids or C1-C24-alkyl esters of acrylic acid or of methacrylic acid and (Cq) ethylenically unsaturated monomers which comprise at least one tertiary nitrogen atom which is partly or fully in quaternized form. The quaternized terpolymer is suitable as a fuel additive for reducing or preventing deposits, for reducing fuel consumption and for minimizing power loss in direct-injection diesel engines, especially in diesel engines with common-rail injection systems.
    Type: Grant
    Filed: April 25, 2011
    Date of Patent: July 29, 2014
    Assignee: BASF SE
    Inventors: Ivette Garcia Castro, Cornelia Roeger-Goepfert, Wolfgang Grabarse, Klaus Muehlbach, Ludwig Voelkel, Harald Boehnke, Christian Tock
  • Publication number: 20140166287
    Abstract: Polymer formulations comprising at least two different solvents having a flashpoint ?60° C., and polymeric compositions obtainable by free-radical polymerization of at least one alkyl (meth)acrylate in the presence of at least one ethylene-vinyl ester copolymer. Multistage process for producing such formulations and the use of such formulations as pour point depressants for crude oils, mineral oils or mineral oil products.
    Type: Application
    Filed: December 17, 2013
    Publication date: June 19, 2014
    Applicant: BASF SE
    Inventors: Dieter Faul, Ivette Garcia Castro, Kai Gumlich, Maria Heuken, Rouven Konrad, Karin Neubecker, Stefen Frenzel
  • Publication number: 20140165457
    Abstract: Polymeric compositions obtainable by free-radical polymerization of at least two different alkyl (meth)acrylates in the presence of at least one ethylene-vinyl ester copolymer, the alkyl (meth)acrylates used being a mixture comprising alkyl (meth)acrylates having linear C12- to C60-alkyl radicals and different alkyl (meth)acrylates having linear C1- to C11-alkyl radicals and/or branched C4- to C60-alkyl radicals and/or cyclic C5- to C20-alkyl radicals. The use of such polymeric compositions as pour point depressants for crude oils, mineral oils or mineral oil products.
    Type: Application
    Filed: December 17, 2013
    Publication date: June 19, 2014
    Applicant: BASF SE
    Inventors: Ivette Garcia Castro, Kai Gumlich, Stefan Frenzel, Maria Heuken, Rouven Konrad, Karin Neubecker
  • Publication number: 20140144070
    Abstract: The present invention is a polymer having structural units, units of formula I, units of formula II and units of either formula IIIa or formula IIIb: The polymer improves the low-temperature properties of fuel oils from petroleum sources and especially from vegetable or animal sources.
    Type: Application
    Filed: January 31, 2014
    Publication date: May 29, 2014
    Applicant: Infineum International Limited
    Inventors: Carl Waterson, Christopher J. Booth
  • Patent number: 8734542
    Abstract: The invention relates to the use of at least one oil-soluble compound B) which acts as a nucleating agent for paraffin crystallization and which is selected from ethylene copolymers and 2 to 10.5 mole % of at least one ethylenically unsaturated carbonic ester for improving the response of cold flow improvers for mineral oils C), which are different from B), in middle distillates that contain at least one ashless, nitrogenous detergent additive A), which is an oil-soluble, amphiphilic compound that comprises at least one alkyl or alkenyl group bound to a polar group, said alkyl or alkenyl group having 10 to 500 C atoms and the polar group having 2 or more nitrogen atoms.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: May 27, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Matthias Krull, Robert Janssen
  • Patent number: 8721744
    Abstract: A copolymer with high chemical homogeneity, consisting of (A) 50 to 30% by weight of ethylene, (B) 50 to 70% by weight of C4- to C24-hydrocarbyl ester of (meth)acrylic acid, (C) 0 to 5% by weight of (meth)acrylic acid and (D) 0 to 10% by weight of copolymerizable monomers, obtainable by polymerizing a mixture of 80 to 60% by weight of ethylene, 20 to 40% by weight of (meth)acrylic acid and 0 to 10% by weight of copolymerizable monomers in a backmixing, continuous polymerization apparatus, and subsequently polymer-analogously esterifying the resulting copolymer with C4- to C24-hydrocarbinols. The inventive copolymer is suitable for improving the cold flow properties of fuel oils, for lowering the lower mixing temperature of cold flow improver additives into fuel oils, and for improving the filterability of fuel oils comprising cold flow improver additives.
    Type: Grant
    Filed: July 5, 2011
    Date of Patent: May 13, 2014
    Assignee: BASF SE
    Inventors: Frank-Olaf Maehling, Jan Strittmatter, Irene Troetsch-Schaller, Ivette Garcia Castro, Michael Schroers, Uwe Rebholz
  • Publication number: 20140107005
    Abstract: The use is described of polymers which contain, in copolymerized form, an ?-olefin, a vinyl ester and an ester of an ?,?-unsaturated carboxylic acid as an additive for fuel oils and lubricants and in particular as a cold flow improver in fuel oils. En addition, the fuel oils and lubricants additized with these polymers; and also additive packages comprising such polymers are described.
    Type: Application
    Filed: December 20, 2013
    Publication date: April 17, 2014
    Applicant: BASF SE
    Inventors: Wolfgang Ahlers, Andreas Fechtenkoetter, Frank-Olaf Maehling, Irene Troetsch-schaller, Ansgar Eisenbeis
  • Patent number: 8642521
    Abstract: The use is described of polymers which contain, in copolymerized form, an ?-olefin, a vinyl ester and an ester of an ?,?-unsaturated carboxylic acid as an additive for fuel oils and lubricants and in particular as a cold flow improver in fuel oils. In addition, the fuel oils and lubricants additized with these polymers; and also additive packages comprising such polymers are described.
    Type: Grant
    Filed: January 21, 2011
    Date of Patent: February 4, 2014
    Assignee: BASF SE
    Inventors: Wolfgang Ahlers, Andreas Fechtenkoetter, Frank-Olaf Maehling, Irene Troetsch-Schaller, Ansgar Eisenbeis
  • Patent number: 8628590
    Abstract: The invention relates to the use of at least one oil-soluble olefin copolymer B) which acts as a nucleating agent for paraffin crystallization for improving the response of cold flow improvers for mineral oils C), which are different from B), in middle distillates that contain at least one ashless, nitrogenous detergent additive A), which is an oil-soluble, amphiphilic compound that comprises at least one alkyl or alkenyl group bound to a polar group, said alkyl or alkenyl group having 10 to 500 C atoms and the polar group having 2 or more nitrogen atoms.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: January 14, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Matthias Krull, Robert Janssen
  • Patent number: 8628591
    Abstract: The invention relates to the use of at least one oil-soluble compound B) which acts as a nucleating agent for paraffin crystallization and which is selected from substantially linear hydrocarbons with at least 22 C atoms, for improving the response of cold flow improvers for mineral oils C) in middle distillates that contain at least one ashless, nitrogenous detergent additive A), which is an oil-soluble, amphiphilic compound that comprises at least one alkyl or alkenyl group bound to a polar group, said alkyl or alkenyl group having 10 to 500 C atoms and the polar group having 2 or more nitrogen atoms.
    Type: Grant
    Filed: June 17, 2008
    Date of Patent: January 14, 2014
    Assignee: Clariant Finance (BVI) Limited
    Inventors: Matthias Krull, Werner Reimann, Robert Janssen
  • Publication number: 20130239465
    Abstract: The cold flow of middle distillate fuels may be improved by adding an effective improving amount of one or more alpha-olefin compositions. The compositions include, but are not necessarily limited to, polymers of alpha-olefins per se, copolymerized or grafted alpha-olefins with maleic anhydride, acrylic acid, vinyl acetate, alkyl acrylates, methacrylic acid, and/or alkyl methacrylates. These resulting copolymers or grafted polymers may be blended with alkylphenol-formaldehyde resins, which in turn may be blended with ethylene-vinyl acetate (EVA) copolymer. In a non-limiting example, the cold filter plugging point (CFPP) may be synergistically improved as compared with the expected additive effect of using the components separately.
    Type: Application
    Filed: March 6, 2013
    Publication date: September 19, 2013
    Applicant: Baker Hughes Incorporated
    Inventors: Ben Morgan, John A. Schield, Paul J. Biggerstaff, Kimchi T. Phan, Jack Bradford Ward
  • Patent number: 8491674
    Abstract: A flow improver for biodiesel fuels, comprising an ?-olefin polymer with a weight average molecular weight of 50,000 to 500,000 that is obtained by polymerization of an ?-olefin mixture (C), wherein the mole ratio (A)/(B) of an ?-olefin (A) with 10 carbon atoms and an ?-olefin (B) with 14 to 18 carbon atoms is (A)/(B)=10/90 to 60/40.
    Type: Grant
    Filed: April 18, 2011
    Date of Patent: July 23, 2013
    Assignee: NOF Corporation
    Inventor: Hideki Kawamoto
  • Publication number: 20130104448
    Abstract: A diesel fuel additive for use in association with bio-diesel fuel and/or petroleum derived diesel fuel having one or more pour-point depressant(s), wherein the pour-point depressant(s) polyglycerol polyricinoleate. Augmentive agents may include at least one of ethylene vinyl acetate and polyethylene vinyl acetate and at least one polyglycerol ester of mixed fatty acids.
    Type: Application
    Filed: November 29, 2012
    Publication date: May 2, 2013
    Applicant: The Penray Companies, Inc.
    Inventor: The Penray Companies, Inc.
  • Patent number: 8349033
    Abstract: A diesel fuel additive for use in association with bio-diesel fuel and/or petroleum derived diesel fuel having one or more solvent(s) and one or more pour-point depressant(s), wherein the pour-point depressant(s) include a polyglycerol ester, such as polyglycerol polyricinoleate and/or polyglycerol esters of mixed fatty acids. Augmentive agents may include ethylene vinyl acetate and/or polyethylene vinyl acetate.
    Type: Grant
    Filed: June 2, 2008
    Date of Patent: January 8, 2013
    Assignee: The Penray Companies, Inc.
    Inventor: Steven A. Muth
  • Publication number: 20120277133
    Abstract: This invention relates to functionalized polymers derived from functionalized monomers. The functionalized polymer may be reacted with an enophilic reagent (e.g., maleic anhydride) to form an enophilic reagent modified functionalized polymer. The functionalized polymer may be further reacted with one or more additional reagents, e.g., an oxygen-containing reagent (e.g., alcohol, polyol), a nitrogen-containing reagent (e.g., amine, polyamine, aminoalcohol), a metal, a metal compound, or a mixture of two or more thereof. The invention relates to lubricants, functional fluids, fuels, dispersants, detergents and polymer compositions.
    Type: Application
    Filed: March 23, 2012
    Publication date: November 1, 2012
    Inventors: Stephen A. DiBiase, Syed Q.A. Rizvi, Georgeta Hategan
  • Publication number: 20120167455
    Abstract: The present invention provides a gas oil composition that can achieve environment load reduction, low temperature properties and low fuel consumption all together and is suitably used in a winter season. The gas oil composition comprises an Ft synthetic base oil in an amount of 60 percent by mass or more on the basis of the total mass of the composition and has a sulfur content of 5 ppm by mass or less, an aromatic content of 10 percent by volume or less, an oxygen content of 100 ppm or less, an end point of 360° C. or lower, an insoluble content after an oxidation stability test of 0.5 mg/100 mL or less, an HFRR wear scar diameter (WS1.4) of 400 ?m or smaller and a specific relation in normal paraffin contents and the total content thereof.
    Type: Application
    Filed: March 12, 2012
    Publication date: July 5, 2012
    Applicant: JX NIPPON OIL & ENERGY CORPORATION
    Inventor: Hideaki SUGANO
  • Patent number: 8163043
    Abstract: Palm-based biodiesel formulations with enhanced cold flow properties are provided including the following: (I) A biodiesel formulation comprising not more than 40 vol % palm-based biodiesel and not less than 60 vol % petroleum-based file 1 oil; (II) A biodiesel formulation comprising not more than 20 wt % palm-based biodiesel and not less than 80 wt % alkyl ester of C6-C18 saturated or unsaturated fatty acid, or a mixture thereof; (III) A biodiesel formulation comprising approximately 0.1-1.0% (wt/vol) of a polyalkyl methacrylate (PAMA) additive and a palm-based biodiesel blend comprising i) not more than 40 vol % palm-based biodiesel; and ii) not less than 60 vol % petroleum-based fuel oil; (IV) A biodiesel formulation comprising approximately 0.1-5.0% (wt/vol) of a polyalkyl methacrylate (PAMA) additive and a palm-based biodiesel having unsaturation level of not less than 60%.
    Type: Grant
    Filed: June 9, 2006
    Date of Patent: April 24, 2012
    Assignee: Malaysian Palm Oil Board
    Inventors: Yuen May Choo, Ah Ngan Ma, Yusof Basiron, Chee Liang Yung, Sit Foon Cheng
  • Publication number: 20110313054
    Abstract: The present invention relates to a branched copolymer obtainable by an addition polymerisation process and uses and compositions thereof comprising a hydrophilic component, said polymer comprising: i) a residue of at least one monofunctional monomer comprising one polymerisable double bond per molecule and a molecular weight of less than 1000 Daltons; ii) a residue of at least one multifunctional monomer comprising at least two polymerisable double bonds per molecule and a molecular weight of less than 1000 Daltons; and wherein the end termini of the copolymer chains comprise one or more of a residue of a chain transfer agent; an initiator or a terminal group derived from a termination reaction; wherein; the molar ratio of the monofunctional monomer to multifunctional monomer is between 50:1 to 2.5:1 respectively; and wherein the hydrophilic component is comprised solely of at least 1 mole % of one or more monofunctional monomer which is/are comprised of hydrophilic monomer each with a solubility of 0.
    Type: Application
    Filed: February 9, 2010
    Publication date: December 22, 2011
    Applicant: Unilever PLC
    Inventors: Paul Hugh Findlay, Brodyck James Lachlan Royles, Neil John Simpson, Sharon Todd, Steven Paul Rannard, Jonathan Victor Mark Weaver, Roselyne Marie Andree Baudry
  • Publication number: 20110271586
    Abstract: A terpolymer formed from (A) ethylene, (B) (i) C2- to C14-alkenyl esters of one or more aliphatic C1- to C20-monocarboxylic acids or (ii) C1- to C24-alkyl esters of acrylic acid or methacrylic acid and (C) olefinically unsaturated hydrocarbons selected from (iii) five- to seven-membered cycloalkenes and (iv) ?-olefins having 6 to 20 carbon atoms. The terpolymer mentioned is suitable as a cold flow improver in middle distillate fuels. It lowers the lower mixing temperature of cold flow improver additives into middle distillate fuels and improves the filterability of middle distillate fuels comprising cold flow improver additives.
    Type: Application
    Filed: May 5, 2011
    Publication date: November 10, 2011
    Applicant: BASF SE
    Inventors: Frank-Olaf MÄHLING, Jan Strittmatter, Irene Trötsch-Schaller, Ivette Garcia Castro, Thomas Zelinski
  • Patent number: 8043388
    Abstract: The invention includes a method of reducing drag in a pipeline and/or improving the combustion efficiency of a fuel burning device by adding a grafted polymer to a hydrocarbon product. The invention also includes a method of improving the combustion efficiency of a gasoline engine by adding a grafted polymer to fuel and combusting the fuel within the gasoline engine, the grafted polymer having a viscoelastic effect in gasoline in the gasoline engine to generally correspond to a duration of the intake stroke/compression stroke/fuel burn sequence in a gasoline engine.
    Type: Grant
    Filed: August 2, 2010
    Date of Patent: October 25, 2011
    Assignee: Himmelsbach Holdings, LLC
    Inventors: Paul F. Waters, John B. Waters
  • Patent number: 8034131
    Abstract: A method of inhibiting deposit formation in a jet fuel at temperatures above 150° C., whilst not substantially adversely affecting the water separability of the jet fuel. The method includes the step of adding at least one copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or a derivative thereof to the jet fuel; wherein the copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or derivative thereof is copolymerized with a nitrogen-containing, amine-containing or amide-containing monomer; or the copolymer, terpolymer or polymer of an ester of acrylic acid or methacrylic acid or derivative thereof includes nitrogen-containing, amine-containing or amide-containing branches.
    Type: Grant
    Filed: November 12, 2004
    Date of Patent: October 11, 2011
    Assignee: Infineum International Limited
    Inventors: Andrew C. Sutkowski, Roger W. Glyde
  • Patent number: 7988748
    Abstract: Mineral oil compositions with trace portions of additives contain as additive a comb polymer containing ester linkages, either based on a) ethylene-vinylester copolymers modified by hydroxy groups or glycidyl groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and b) partially imidated and/or partially esterified maleic anhydride copolymers, wherein in the comb polymer based on a) and b) the modified ethylene-vinylester copolymer component is connected by means of ester linkages to the partially imidated and/or partially esterified maleic anhydride copolymer component, or a comb polymer containing ester linkages based on c) ethylene-vinylester copolymers modified by acid and/or acid anhydride groups with molecular mass weight averages from 3000 to 50000 and an ethylene portion of 50 to 90 mass %, and d) polyalcohols partially esterified with C12-C40-monocarboxylic acids wherein in the comb polymer based on c) and d) the ethylene-vinylester copolymer c
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: August 2, 2011
    Assignee: Leuna Polymer GmbH
    Inventors: Hiltrud Täubert, Wolfgang Haubold, Konrad Bühler, Torsten Meyer
  • Publication number: 20110118159
    Abstract: The use is described of polymers which contain, in copolymerized form, an ?-olefin, a vinyl ester and an ester of an ?,?-unsaturated carboxylic acid as an additive for fuel oils and lubricants and in particular as a cold flow improver in fuel oils. In addition, the fuel oils and lubricants additized with these polymers; and also additive packages comprising such polymers are described.
    Type: Application
    Filed: January 21, 2011
    Publication date: May 19, 2011
    Applicant: BASF Aktiengesellschaft
    Inventors: Wolfgang AHLERS, Andreas Fechtenkötter, Frank-Olaf Mähling, Irene Trötsch-Schaller, Ansgar Eisenbeis
  • Patent number: 7942941
    Abstract: The present invention generally relates to oil compositions, primarily to fuel oil and petroleum compositions produced there from susceptible to wax formation at low temperatures, to polymeric amides for use with such fuel oil compositions, and to methods for their manufacture.
    Type: Grant
    Filed: April 5, 2005
    Date of Patent: May 17, 2011
    Assignee: Akzo Nobel N.V.
    Inventors: Rodney Lee Cravey, Stephen L. Mead
  • Publication number: 20110067295
    Abstract: The present invention is related to the use of formulations of new random copolymers and terpolymers, synthesized by a method of semi continuous emulsion polymerization, and that function as flow improvers, lowering the pour point and reducing the viscosity of Mexicans crude oils, which have gravities within the range of 9 to 30° API.
    Type: Application
    Filed: September 21, 2010
    Publication date: March 24, 2011
    Applicant: INSTITUTO MEXICANO DEL PETROLEO
    Inventors: Laura Verónica CASTRO SOTELO, Eugenio Alejandro FLORES OROPEZA, Gabriel CENDEJAS SANTANA, Marcelo LOZADA Y CASSOU, Flavio Salvador VÁZQUEZ MORENO
  • Patent number: 7909894
    Abstract: Embodiments of the present invention are directed toward systems and methods of providing a low-emissions diesel fuel for use in cold climates. Such fuels may be prepared by a Fischer-Tropsch process and include a pour point depressant. Furthermore, the fuel is used in conjunction with a heated fuel delivery system so that low cloud points are not necessary. Fuels prepared according to embodiments of the present invention may be produced in higher yields than otherwise possible because a higher paraffin wax content can be tolerated, thus obviating the need to remove or exclude the wax. These fuels are characterized by a sulfur content less than 1 ppm, a cetane number greater than 60, an aromatics content less than 1 wt %, and a difference between the cloud and pour points that is greater than about 5° C. The present fuel may be prepared by a Fischer-Tropsch synthesis from any number of carbon-containing sources such natural gas, coal, petroleum products, and combinations thereof.
    Type: Grant
    Filed: October 31, 2007
    Date of Patent: March 22, 2011
    Assignee: Chevron U.S.A. Inc.
    Inventor: Dennis J. O'Rear
  • Patent number: 7863390
    Abstract: Esterified polyalkene/UAR copolymer reaction products useful as (1) a friction modifier for lubricating oils such as automatic transmission fluids to improve torque capacity and anti-shudder durability and for continuous variable transmissions (CVTs), (2) a friction modifier for fuels or (3) a cold flow improver for diesel fuels are provided. The esterified copolymer reaction product may be used as is or can be further derivatized (e.g., by post treatment of the esterified copolymer reaction product with, for example, ethylene carbonate or boric acid).
    Type: Grant
    Filed: March 17, 2009
    Date of Patent: January 4, 2011
    Assignee: Chevron Oronise Company LLC
    Inventor: Kenneth D. Nelson
  • Patent number: 7857871
    Abstract: This invention provides a composition and a method of using a composition containing an imidazoline, optionally containing a paraffin inhibitor, for improving the pour point of liquid hydrocarbons, such as crude oil and petroleum fuel, and/or inhibiting or reducing the formation of paraffin deposits in such liquids.
    Type: Grant
    Filed: September 6, 2005
    Date of Patent: December 28, 2010
    Assignee: Baker Hughes Incorporated
    Inventors: Richard L. Martin, Harold L. Becker, Dora Galvan
  • Publication number: 20100293842
    Abstract: The invention relates to a method for producing additive mixtures for fuel oils by mixing at least two additive components in a dynamic mixer or a lamination mixer. The invention further relates to additive mixtures obtained by said method and fuel oil compositions containing said additive mixtures.
    Type: Application
    Filed: January 21, 2009
    Publication date: November 25, 2010
    Applicant: BASF SE
    Inventors: Wolfgang Kasel, Irene Troetsch-Schaller, Peter Spang, Frank-Olaf Maehling, Andreas Daiss, Andreas Bauder, Anja Vinckier, Stefan Hirsch, Matthias Frohberger, Siegfried Willert, Peter Schaeffler, Stephan Hoffmann
  • Publication number: 20100297565
    Abstract: The invention includes a method of reducing drag in a pipeline and/or improving the combustion efficiency of a fuel burning device by adding a grafted polymer to a hydrocarbon product. The invention also includes a method of improving the combustion efficiency of a gasoline engine by adding a grafted polymer to fuel and combusting the fuel within the gasoline engine, the grafted polymer having a viscoelastic effect in gasoline in the gasoline engine to generally correspond to a duration of the intake stroke/compression stroke/fuel burn sequence in a gasoline engine.
    Type: Application
    Filed: August 2, 2010
    Publication date: November 25, 2010
    Inventors: Paul F. Waters, John B. Waters
  • Patent number: 7837748
    Abstract: Disclosed are fuel compositions for internal combustion engines comprising as a predominant component organic distillates which exhibit suitable physical properties, and a low-sulfur fraction of an alkylated petroleum feedstock which, for example, consisted of material boiling between about 60° C. and about 345° C. More particularly, compositions of the invention comprise low-boiling, low-sulfur, blending components, advantageously obtained by a process for converting sulfur-containing organic compounds which are unwanted impurities, to higher boiling products by alkylation and removing the higher boiling products by fractional distillation. Products can be used directly as transportation fuels and/or blending components to provide fuels which are more friendly to the environment.
    Type: Grant
    Filed: September 15, 2006
    Date of Patent: November 23, 2010
    Assignee: BP Corporation North America Inc.
    Inventors: Graham W. Ketley, Michael Hodges
  • Publication number: 20100281762
    Abstract: The disclosure relates to the use as an additive improving the resistance to cold and the filterability of motor fuels, of at least one copolymer including: 78 to 87% in moles of at least one alpha-olefin, preferably at least ethylene, 12 to 18% in moles of at least one vinyl ester, preferably at least vinyl acetate, 1 to 4% in moles of at least one alpha-beta unsaturated mono carboxylic acid ester, preferably at least ethyl-2,hexyl acrylate.
    Type: Application
    Filed: December 23, 2008
    Publication date: November 11, 2010
    Applicant: Total Raffinage Marketing
    Inventors: Erwan Chevrot, Laurent Dalix, Frédéric Tort
  • Publication number: 20100275508
    Abstract: The disclosure relates to the synthesis and the use of copolymers based on ethylene and/or of propylene and of vinyl ester(s) modified by grafting, effective for improving both the resistance to cold and the lubricity of liquid hydrocarbons in particular the middle distillates originating from the distillation of petroleum and crude oils, in particular those with a low sulphur content and relates to a copolymer including: a) units derived from ethylene of formula A —(CH2—CH2)n1— and/or propylene of formula A? —((CH3)CH2—CH2)n2 with n1+n2=n ranging from 98 to 643, preferably ranging from 124 to 515; n1 being advantageously equal to n; b) units of formula B: —(CH2—CHOOCR1)m-x— in which R1 represents a C1-C15 linear or branched alkyl group preferably methyl, propyl, and/or a C5 to C15 branched alkyl group, in which the branching is situated at any point of the alkyl radical, preferably in position 2 or 3 of the alkyl chain; preferably chosen from the preferred C5-C15 vinyl comonomers, preferably chosen from t
    Type: Application
    Filed: December 23, 2008
    Publication date: November 4, 2010
    Applicant: TOTAL RAFFINAGE MARKETING
    Inventors: Nelly Dolmazon, Géraldine Papin, Frédéric Tort, Valérie Heroguez