Fluorine And Phosphorus Containing Patents (Class 501/44)
  • Publication number: 20090298668
    Abstract: A fluorophosphate glass containing: P5+ in an amount of 20 to 45 cationic %; Al3+ in an amount of 15 to 35 cationic %; Ba2+ in an amount of 20 to 50 cationic %; F? in an amount of 20 to 50 anionic %; and O2? in an amount of 50 to 80 anionic %. A molar ratio of O2?/P5+ is larger than or equal to 3.5. In addition, a molar ratio of Al3+/P5+ is larger than or equal to 0.45. Furthermore, the Abbe number (?d) of the glass is larger than or equal to 66. Finally a refractive index (nd) of the glass satisfies an expression (1): nd?2.0614?0.0071×?d.
    Type: Application
    Filed: May 29, 2009
    Publication date: December 3, 2009
    Inventor: Mikio Ikenishi
  • Patent number: 7615506
    Abstract: Tungsten-doped tin-fluorophosphate glasses are described herein which exhibit excellent humidity resistance, thermal resistance, and have a low glass transition temperature which makes them suitable for low temperature sealing applications, such as for encapsulating electronic components. In one embodiment, these glasses comprise 55-75% Sn, 4-14% P, 6-24% O, 4-22% F, and 0.15-15% W on a weight percent elemental basis.
    Type: Grant
    Filed: October 6, 2006
    Date of Patent: November 10, 2009
    Assignee: Corning Incorporated
    Inventors: Bruce Gardiner Aitken, Shari Elizabeth Koval, Mark Alejandro Quesada
  • Patent number: 7608551
    Abstract: New and improved compositions of doped and co-doped bismuth fluorophosphate glasses for lasers is disclosed that have a high refractive index (nD) of approximately 1.6 and higher, high transmission in the near infrared part of the spectrum, and a wide glass forming domain. The disclosed glass systems Al(PO3)3—Ba(PO3)2—Bi(PO3)3—BaF2+RFx+dopands use dopants from the group of oxides and or fluorides of rare earth elements Nd, Er, Yb, Tm, Tb, Ho, Sm, Eu and Pr as well as MnO and mixtures thereof over 100 percent (wt %) of the glass-base composition. These glasses have high chemical durability, radiation resistance, efficiency of laser use in the infrared and blue spectrum, and improved duration of luminescence.
    Type: Grant
    Filed: July 5, 2005
    Date of Patent: October 27, 2009
    Inventors: Alfred A. Margaryan, Ashot A. Margaryan
  • Publication number: 20090247387
    Abstract: The present invention provides a fluorophosphate glass containing 30 to 50 cationic % of a phosphorus ingredient in terms of P5+, the glass having, in a nuclear magnetic resonance spectrum, a resonance spectrum which is generated near a reference frequency of 31P and has a shape of Gaussian function. The glass of the invention is reduced in volatility and erosiveness.
    Type: Application
    Filed: March 27, 2009
    Publication date: October 1, 2009
    Applicant: HOYA CORPORATION
    Inventor: Mikio IKENISHI
  • Publication number: 20090247388
    Abstract: The present invention provides a fluorophosphate glass containing phosphorus, oxygen and fluorine as glass ingredients, in which, provided that a refractive index nd of the glass is nd(1) and a refractive index nd after re-melting the glass at 900° C. for 1 hour in a nitrogen atmosphere, cooling the glass to a glass transition temperature and then cooling the glass down to 25° C. at a temperature decrease rate of 30° C. per hour is nd(2), an absolute value of a difference between nd(1) and nd(2) (nd(2)-nd(1)) is equal to or less than 0.00300, and a molar ratio (O2?/P5+) of a content of O2? to a content of P5+ is equal to or more than 3.5. The glass of the invention is reduced in volatility and erosiveness.
    Type: Application
    Filed: March 27, 2009
    Publication date: October 1, 2009
    Applicant: HOYA CORPORATION
    Inventor: Mikio Ikenishi
  • Publication number: 20090247386
    Abstract: The present invention provides a fluorophosphate glass containing more than 3 cationic % and 30 cationic % or less of a phosphorus ingredient in terms of P5+, the glass having a ratio I(1)/I(0) of equal to or less than 0.08 in which I(0) is a strength of a resonance peak generated near a reference frequency of 31P in a nuclear magnetic resonance spectrum and I(1) is a strength of a first-order side band peak of the resonance peak. The glass of the invention is reduced in volatility and erosiveness.
    Type: Application
    Filed: March 27, 2009
    Publication date: October 1, 2009
    Applicant: HOYA CORPORATION
    Inventor: Mikio IKENISHI
  • Patent number: 7595272
    Abstract: A low-dispersion optical glass suitable for producing a quality preform from a molten glass and suitable for precision press-molding, which is a fluorophosphate glass containing, as essential cationic components, P5+, Al3+, at least two members selected from Mg2+, Ca2+, Sr2+ and Ba2+ as divalent cationic components (R2+) and Li+ and containing, by cationic %, 10 to 45% of P5+, 5 to 30% of Al3+, 0 to 20% of Mg2+, 0 to 25% of Ca2+, 0 to 30% of Sr2+, 0 to 33% of Ba2+, 1 to 30% of Li+, 0 to 10% of Na+, 0 to 10% of K+, 0 to 5% of Y3+, and 0 to 15% of B3+, the molar ratio of the content of F? to the total content of F? and O2?, F?/(F?+O2?), being 0.25 to 0.85, the optical glass having a refractive index (Nd) of 1.40 to 1.58 and an Abbe's number (?d) of 67 to 90.
    Type: Grant
    Filed: March 27, 2006
    Date of Patent: September 29, 2009
    Assignee: Hoya Corporation
    Inventors: Mikio Ikenishi, Xuelu Zou
  • Patent number: 7521670
    Abstract: The invention discloses a standard for referencing luminescence signals, having an optically transparent base material comprising a lanthanum phosphate glass, a fluorophosphate glass, a fluor-crown glass, a lanthanum glass, a glass-ceramic formed therefrom or a lithium aluminosilicate glass-ceramic, the base material including a bulk doping with at least one constituent which is luminescent and comprises at least one rare earth and/or a nonferrous metal, in particular cobalt, chromium or manganese.
    Type: Grant
    Filed: February 24, 2006
    Date of Patent: April 21, 2009
    Assignees: Schott AG, BAM Bundesanstalt fuer Materialforschung und -pruefung
    Inventors: Axel Engel, Rainer Haspel, Ute Resch-Genger, Katrin Hoffmann, Doris Ehrt, Uwe Kolberg, Joseph S. Hayden, Michael Stelzl
  • Patent number: 7413601
    Abstract: The present invention relates to a particulate kaolin suitable for use as a filler material in compositions for making uncoated paper, the kaolin having a mean particle size ranging from 0.7 ?m to 3 ?m and a shape factor of at least 60. The invention also relates to compositions comprising a particulate kaolin, and methods for making uncoated paper sheets.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: August 19, 2008
    Assignee: Imerys Pigments, Inc.
    Inventor: Marielle Lorusso
  • Publication number: 20080146431
    Abstract: Tungsten-doped tin-fluorophosphate glasses are described herein which exhibit excellent humidity resistance, thermal resistance, and have a low glass transition temperature which makes them suitable for low temperature sealing applications, such as for encapsulating electronic components. In one embodiment, these glasses comprise 55-75% Sn, 4-14% P, 6-24% O, 4-22% F, and 0.15-15% W on a weight percent elemental basis.
    Type: Application
    Filed: October 6, 2006
    Publication date: June 19, 2008
    Inventors: Bruce Gardiner Aitken, Shari Elizabeth Koval, Mark Alejandro Quesada
  • Publication number: 20080132400
    Abstract: Provided is an optical glasses that has high refractivity and low dispersion and anomalous partial dispersion capability and that has excellent processability and devitrification resistance and ensures that the occurrence of striae can be inhibited, the optical glass including an optical glass having a refractive index (nd) of 1.54 to 1.60, an Abbe's number (vd) of 65 to 78, a partial dispersion ratio of 0.530 or more, a specific gravity of 4.0 or less and a viscosity, measured at its liquidus temperature, of 4 dPa·s or more and an optical glass comprising as cationic components, by cationic %, 20 to 50% of p5+, 0.1 to 20% of Al3+, 0.1 to 20% of Mg2+, 0 to 20% of Ca2+, 0 to 20% of Sr2+, 0.1 to 30% of Ba2+ and 0 to 10% of y3+, and further comprising, as anionic components, F? and O2?, wherein the ratio of the content of Mg2+ to the content of Al3+, Mg2+/Al3+, based on cationic %, is 1.2 or less.
    Type: Application
    Filed: December 4, 2007
    Publication date: June 5, 2008
    Applicant: HOYA CORPORATION
    Inventor: Youichi Hachitani
  • Patent number: 7371703
    Abstract: An optical glass wherein an amount of change in refractive index (?n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43 W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.
    Type: Grant
    Filed: September 18, 2003
    Date of Patent: May 13, 2008
    Assignee: Kabushiki Kaisha Ohara
    Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
  • Patent number: 7223808
    Abstract: The invention relates to a method for the production of an adhesive and an adhesive kit for joining similar or different metal surfaces or ceramics, especially in the field of biomedicine. The objective of the invention is to avoid polymerization-linked by-products and disadvantageous effects, in addition to enabling a temporary biocompatible bond between metal and metal or metal and ceramics. The inventive method consist in using a monomer-free polymethylmethacrylate which is mixed with a suitable, non-toxic solvent and a bioactive vitreous-crystalline material with a particle size ranging from 0.05–20?, consisting of 15–45 wt. % CaO, 40–45 wt. % P2O5, 10–40 wt. % ZrO2 and 0.7–3.5 wt. % fluoride, having apatite and calcium zircon phosphate as main crystal phases and a glass phase as an auxiliary component until a flowable mixture is obtained. The invention also relates to an adhesive kit consisting of said components.
    Type: Grant
    Filed: June 14, 2002
    Date of Patent: May 29, 2007
    Assignees: Humboldt Universitaet Berlin Carite Universitaetsklinikum (CCM), Bam Bundesanstalt Fuer Materialforschung und -Pruefung, Vita Zahnfabrik H. Rauter GmbH & Co. KG
    Inventors: Wolf-Dieter Müller, Georg Berger, Emil Nagel, Klaus-Peter Lange
  • Patent number: 7192897
    Abstract: Provided are near-infrared light-absorbing glass in which good color compensating characteristics are maintained even without containing harmful arsenic, permitting the thinning of the glass, and having good weatherability and forming properties; a near-infrared light-absorbing element comprised of such glass; a near-infrared light-absorbing filter employing such glass. Also provided, at low cost, are near-infrared light-absorbing glass permitting good color compensating, a near-infrared light-absorbing element comprised of such glass, and a near-infrared light-absorbing filter comprising such elements. The glass comprises cationic components with a certain composition as well as F? and O2? as anionic components. Alternatively, the glass is near-infrared light-absorbing glass, wherein the glass exhibits properties, based on a thickness of 0.
    Type: Grant
    Filed: July 3, 2003
    Date of Patent: March 20, 2007
    Assignee: Hoya Corporation
    Inventors: Rie Yamane, Youichi Hachitani, Xuelu Zou
  • Patent number: 7151064
    Abstract: An optical glass suitable for mold forming having a metal composition in wt % in terms of metal oxides calculated from the composition of the following components: P2O5 34–50%, Li2O 2–9%, Na2O 7–28%, K2O 3–27%, provided that the total of R2O is 17–41% (R: Li, Na, K), Al2O3 6.5–30%, ZnO 0–22%, BaO 0–21%, SrO 0–18%, CaO 0–16%, MgO 0–14%, provided that the total of R?O is 0–34% (R?: Zn, Ba, Sr, Ca, Mg), ZrO2 0–1.5% and F 1.5–32% relative to the total weight of the oxides, and exhibits a glass transition temperature (Tg) of 350° C. or lower and a specific gravity (Sg) of 3.1 or less and is excellent in chemical durability. The optical glass can be press formed at a low temperature of about 270 to 400° C.
    Type: Grant
    Filed: October 29, 2002
    Date of Patent: December 19, 2006
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Otsuka, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 6984261
    Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.
    Type: Grant
    Filed: February 5, 2003
    Date of Patent: January 10, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
  • Patent number: 6878765
    Abstract: A method for producing a component from a glass/polymer mixture where, a component is formed from a mixture of a thermoplastic with a processing temperature T1 and first glass particles with saturated surface bonds and a glass temperature T2<T1, at a temperature T3>T1. By melting the first glass particles, second glass particles are produced with surface bonds which can be saturated. The bonds are saturated by being bonded to the thermoplastic.
    Type: Grant
    Filed: December 13, 2000
    Date of Patent: April 12, 2005
    Assignee: Siemens Aktiengesellschaft
    Inventors: Robert Greiner, Angelo Polese
  • Publication number: 20040198581
    Abstract: Maximizing the glass forming ability of low metal-phosphate content fluoride-based glasses allows the fabrication of large-size “crystal-free” HEL windows. This involves the addition of glass stabilizer oxides such as SiO2, TiO2, Al2O3. In situ quenching is used to fabricate large-scale HEL windows substantially free of crystals, bubbles and striation.
    Type: Application
    Filed: April 1, 2004
    Publication date: October 7, 2004
    Applicant: Infrared Fiber Systems, Inc.
    Inventor: Danh Tran
  • Patent number: 6797657
    Abstract: A host material for Tm3+-doping is provided. The host material is a fluorophosphate glass having a non-zero concentration of Tm3+, cation elements that include at least an alkaline earth, phosphorus, and aluminum, and anion elements that include oxygen (O) and fluorine (F). The fluorine(F)/oxygen (O) ratio (F/(F+O)) for the fluorophosphate glass of the embodiments of the present invention can be in the range of about 0.5 to about 0.85. The fluorophosphate glass further can have an alkali metal concentration of 10 mole % or less to improve durability. The Tm-doped fluorophosphate glass can be incorporated into an amplifier or laser utilized in the 14xx nm wavelength region.
    Type: Grant
    Filed: July 31, 2002
    Date of Patent: September 28, 2004
    Assignee: Corning Incorporated
    Inventors: Adam J.G. Ellison, Lauren K. Cornelius
  • Patent number: 6777358
    Abstract: A glass composition for a seal consists essentially of 70-75 wt % of PbO, 3-7 wt % of PbF2, 5-8 wt % of Bi2O3, 5-7 wt % of B203, 2-5 wt % of ZnO, 1-3 wt % of Fe2O3, 0-2 wt % of CuO, 0-2% of TeO2, and a trace <0.2% of MnO2, the composition having a flow temperature of <350° C. Such seals can be flowed at low temperatures, using different and less environmentally damaging constituents to those used before. Damage to temperature sensitive materials near the seals, can be reduced. Low flow temperatures can be achieved without excessive degradation of properties such as low viscosity, low expansion coefficient, good adhesion to glass and metals, low permeability of air, good long term hydrolytic stability. A filler such as a ceramic powder, is added to match the temperature expansion coefficient to the materials being sealed. It can be used to fix silica fiber into electro-optic devices to achieve hermetic joints with high mechanical stability.
    Type: Grant
    Filed: July 25, 2002
    Date of Patent: August 17, 2004
    Assignee: Nortel Networks Limited
    Inventors: Kenneth Snowdon, Christopher Tanner, Timothy Durrant, Christopher Woodend
  • Patent number: 6767854
    Abstract: The invention refers to a material which is chemically long-term stable in a neutral or slightly acid environment and which can be used both as bioactive bone replacement material, e.g. in the form of a coating applied onto metallic prosthesis sticks by thermal spraying, and as substrate material in biotechnology, e.g. in the form of a ceramic sheet. According to the invention, said material comprises 15-45% by weight CaO, 40-45% by weight P2O5, 10-40% by weight ZrO2 and fluoride, said material further comprises two crystalline phases being apatite and calcium zirconium phosphate, and a secondary glass phase. Said material has a very high chemical long-term stability, compared to known materials which can also be produced by means of a melting process.
    Type: Grant
    Filed: June 13, 2002
    Date of Patent: July 27, 2004
    Assignee: Bam Bundesanstalt fuer Materialforschung und Prufung
    Inventors: Georg Berger, Ute Ploska
  • Publication number: 20040063563
    Abstract: An optical glass wherein an amount of change in refractive index (&Dgr;n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.
    Type: Application
    Filed: September 18, 2003
    Publication date: April 1, 2004
    Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
  • Publication number: 20040023786
    Abstract: A host material for Tm3+-doping is provided. The host material is a fluorophosphate glass having a non-zero concentration of Tm3+, cation elements that include at least an alkaline earth, phosphorus, and aluminum, and anion elements that include oxygen (O) and fluorine (F). The fluorine(F)/oxygen (O) ratio (F/(F+O)) for the fluorophosphate glass of the embodiments of the present invention can be in the range of about 0.5 to about 0.85. The fluorophosphate glass further can have an alkali metal concentration of 10 mole % or less to improve durability. The Tm-doped fluorophosphate glass can be incorporated into an amplifier or laser utilized in the 14xx nm wavelength region.
    Type: Application
    Filed: July 31, 2002
    Publication date: February 5, 2004
    Inventors: Adam J.G. Ellison, Lauren K. Cornelius
  • Publication number: 20040018930
    Abstract: A glass composition for a seal consists essentially of 70-75 wt % of PbO, 3-7 wt % of PbF2, 5-8 wt % of Bi2O3, 5-7 wt % of B203, 2-5 wt % of ZnO, 1-3 wt % of Fe2O3, 0-2 wt % of CuO, 0-2% of TeO2, and a trace <0.2% of MnO2, the composition having a flow temperature of <350° C. Such seals can be flowed at low temperatures, using different and less environmentally damaging constituents to those used before. Damage to temperature sensitive materials near the seals, can be reduced. Low flow temperatures can be achieved without excessive degradation of properties such as low viscosity, low expansion coefficient, good adhesion to glass and metals, low permeability of air, good long term hydrolytic stability. A filler such as a ceramic powder, is added to match the temperature expansion coefficient to the materials being sealed. It can be used to fix silica fiber into electro-optic devices to achieve hermetic joints with high mechanical stability.
    Type: Application
    Filed: July 25, 2002
    Publication date: January 29, 2004
    Inventors: Kenneth Snowdon, Christopher Tanner, Timothy Durrant, Christopher Woodend
  • Patent number: 6656859
    Abstract: A family of tellurite glasses and optical components for telecommunication systems, the glasses consisting essentially of, as calculated in cation percent, 65-97% TeO2, and at least one additional oxide of an element having a valence greater than two and selected from the group consisting of Ta, Nb, W, Ti, La, Zr, Hf, Y, Gd, Lu, Sc, Al and Ga, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: December 2, 2003
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Adam J. G. Ellison, Randall E. Youngman
  • Patent number: 6645893
    Abstract: A glass includes (a) a matrix containing a compound of at least one nonmetallic element; and (b) a particle selectively formed in the matrix. This particle is made of the at least one nonmetallic element. A process for producing such glass includes (a) providing a blank glass containing a compound of at least one nonmetallic element; (b) condensing a pulsed laser beam to a focal point in the blank glass such that a particle is selectively formed in the blank glass at a position corresponding to the focal point, the particle being made of the at least one nonmetallic element dissociated from the compound; and (c) moving the focal point in the blank glass to produce a pattern of the particle. The glass is suitable for optical functional elements.
    Type: Grant
    Filed: February 21, 2001
    Date of Patent: November 11, 2003
    Assignee: Central Glass Company, Limited
    Inventors: Kiyotaka Miura, Seiji Fujiwara, Takuya Teshima, Natsuya Nishimura, Yoshinori Kubota
  • Patent number: 6560009
    Abstract: The specification describes rare earth doped fiber amplifier devices for operation in the extended L-band, i.e. at wavelengths from 1565 nm to above 1610 nm. High efficiency and flat gain spectra are obtained using a high silica based fiber codoped with Er, Al, Ge, and P and an NA of at least 0.15.
    Type: Grant
    Filed: August 21, 2001
    Date of Patent: May 6, 2003
    Assignee: Lucent Technologies Inc.
    Inventors: Matthew Julius Andrejco, Inger Pihl Byriel, Bera Palsdottir
  • Publication number: 20030040421
    Abstract: New and improved compositions of doped fluorophosphate glasses for lasers have a high refractive index (nD) of approximately 1.6 to 1.7, high transmission in the near infrared part of the spectrum and a wide glass forming domain. These glass systems, Ba(PO3)2-Al(PO3)3-BaF2-Dopants, utilize dopants from the group of oxides or fluorides of the rare earth elements Nd, Er, Yb, Tm, Tb, Ho and Pr as well as MnO and mixtures thereof. The composition of glass includes chemical durability, efficiency of laser use in the infrared spectrum and improved duration of luminescence. It is emphasized that this abstract is provided to comply with the rules requiring an abstract that will allow a searcher or other reader to quickly ascertain the subject matter of the technical disclosure. It is submitted with the understanding that it will not be used to interpret or limit the scope or meaning of the claims.
    Type: Application
    Filed: January 21, 2002
    Publication date: February 27, 2003
    Inventor: Alfred A. Margaryan
  • Patent number: 6499317
    Abstract: A synthetic quartz glass for optical use, to be used by irradiation with light within a range of from the ultraviolet region to the vacuum ultraviolet region, which contains fluorine, which has a ratio of the scattering peak intensity of 2250 cm−1 (I2250) to the scattering peak intensity of 800 cm−1 (I800), i.e. I2250/I800, of at most 1×10−4 in the laser Raman spectrum, and which has an absorption coefficient of light of 245 nm of at most 2×10−3 cm−1.
    Type: Grant
    Filed: October 17, 2000
    Date of Patent: December 31, 2002
    Assignee: Asahi Glass Company, Limited
    Inventors: Yoshiaki Ikuta, Shinya Kikugawa, Noriaki Shimodaira, Akio Masui, Shuhei Yoshizawa
  • Patent number: 6495481
    Abstract: New and improved compositions of doped and co-doped germanium fluorophosphate glasses for laser hosts and fiber amplifiers have a high refractive index (nD) 1.67-1.70, high transmission in the near infrared part of the spectra (to 6 micron) and a wide glass-forming domain. These glass systems [BaGe4O9—Ba(PO3)2—RFx] contain (mol %): BaF2, CaF2, MgF2, BiF3, PbF2 of 10 to 70 percent and GeO2 7.31 to 58.48 percent, P2O5 of 4.81 to 38.50 percent, BaO of 7.86 to 62.94 percent where dopants and co-dopants are over 100 percent (in wt %): Nd2O3(NdF3) of 0.5 to 15 percent, Er2O3(ErF3) of 0.2 to 12 percent, Yb2O3(YbF3) of 1.0 to 15 percent, Ho2O3(HoF3) of 1.0 to 10 percent, Pr2O3(PrF3) of 0.5 to 12 percent, Tm2O3(TmF3) of 0.2 to 10 percent, Tb2O3(TbF3) of 0.1 to 10 percent, MnO(MnF2) of 0.5 to 20 percent.
    Type: Grant
    Filed: May 21, 2001
    Date of Patent: December 17, 2002
    Assignee: Nano Technologies
    Inventor: Alfred A. Margaryan
  • Patent number: 6429162
    Abstract: The invention relates to a family of erbium-doped fluorophosphate glasses for use in optical signal amplification and which are doped, for 100 parts by weight constituted by: P2O5 15-40 MgF2 0-10 Al2O3  0-5 CaF2 0-25 MgO  0-9 SrF2 0-25 CaO  0-9 BaF2 0-20 SrO  0-9 KHF2 0-2 BaO  0-45 K2TiF6 0-2 AlF3  5-25 with up to 10 parts by weight of erbium oxide. The glasses according to the present invention exhibit a high gain and very flat spectrum over the 1550 nm bandwidth. These glass compositions are particularly well suited for use in fiber or planar optical amplification in WDM and similar applications.
    Type: Grant
    Filed: March 3, 2000
    Date of Patent: August 6, 2002
    Assignee: Corning Inc.
    Inventor: Michel Prassas
  • Patent number: 6352950
    Abstract: A family of alkali-tungsten-tellurite glasses that consist essentially of, as calculated in mole percent, 10-90% TeO2, at least 5% W03 and at least 0.5% R2O where R is Li, Na, K, Cs, Tl and mixtures, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: March 5, 2002
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Adam J. G. Ellison
  • Patent number: 6344425
    Abstract: A family of fluorotellurite glasses, the composition of which consist essentially of, as calculated in mole percent, 30-75% TeO2, 15-60% ZnF2 and 0.005-10% of an oxide of erbium, thulium or holmium, and amplifying optical components produced from these glasses.
    Type: Grant
    Filed: November 19, 1999
    Date of Patent: February 5, 2002
    Assignee: Corning Incorporated
    Inventor: Bruce G. Aitken
  • Patent number: 6306783
    Abstract: A tin borophosphate glass for use in sealing materials includes, by mole, 30 to 80% of SnO, 5 to 60% of B2O3, and 5 to 24% of P2O5 as main components. The glass is free of lead but is of equal quality to those of conventional lead-containing sealing glasses. The glass can provide a satisfactory sealing material.
    Type: Grant
    Filed: February 2, 2000
    Date of Patent: October 23, 2001
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Toshio Yamanaka
  • Patent number: 6284685
    Abstract: Devices are made comprising a tin-phosphorous oxyfluoride glass, which has been exposed to light, preferably shorter in wavelength than the absorption edge of the glass, to change the refractive index change of the glass. The glasses can be used to form planar and fiber devices, including core/clad structures for guiding light.
    Type: Grant
    Filed: March 23, 2000
    Date of Patent: September 4, 2001
    Assignee: Corning Incorporated
    Inventors: Nicholas F. Borrelli, Robert W. Boyd, Stojan Radic, Paul A. Tick
  • Patent number: 6281151
    Abstract: The present invention relates to a transparent glass-ceramic material which includes a glass matrix and a crystalline phase of lanthanum fluoride crystals in the glass matrix, where the transparent glass-ceramic material contains no silica. The present invention further relates to a method of producing the transparent glass-ceramic material.
    Type: Grant
    Filed: January 24, 2000
    Date of Patent: August 28, 2001
    Assignee: Corning Incorporated
    Inventor: Paul A. Tick
  • Patent number: 6277775
    Abstract: A GeAs sulphide glass family of transparent glasses having transmission far into the infrared portion of the spectrum, containing a source of phosphorus ion as a co-dopant to effect dispersion of a rare earth metal ion dopant in the glass, an optical component comprising the glass, and a method of dispersing a rare earth metal ion in the glass.
    Type: Grant
    Filed: January 25, 2000
    Date of Patent: August 21, 2001
    Assignee: Corning Incorporated
    Inventor: Bruce G. Aitken
  • Patent number: 6277776
    Abstract: A low temperature fluorophosphate glass useful for joining single-mode fluoride and silica optical fibers includes 5 to 7 mol % InF3, 20 to 35 mol % PbF2 and 57.5 to 75 mol % P2O5. An alkali for maintaining a low glass transition temperature can be included. Up to 25% (glass molar basis) of the P2O5 can be replaced by PbO.
    Type: Grant
    Filed: June 21, 1999
    Date of Patent: August 21, 2001
    Assignee: IPG Photonics Corporation
    Inventors: Alexis Clare, Wesley King, Ian Grainge Clarke
  • Patent number: 6223563
    Abstract: The invention reflects discovery of a liquid phase doping technique that, unlike previous techniques, exhibits very little fluorine depletion upon subsequent heating. The invention involves the steps of providing a silica sol comprising a tetraalkylammonium hydroxide and a di-, tri-, or tetraalkylammonium fluoride, the sol having pH of about 10 to about 14, adding a gelling agent to the sol to induce gelation, casting or extruding the sol to form a gel body, and then drying, heat treating, and sintering the body. Advantageously, the fluorine-containing compound is tetramethylammonium fluoride.
    Type: Grant
    Filed: March 17, 2000
    Date of Patent: May 1, 2001
    Assignee: Lucent Technologies Inc.
    Inventors: Charles C Bahr, Jr., Suhas Bhandarkar, Michael P Bohrer
  • Patent number: 5977003
    Abstract: A ceramic particulate material which comprises particles having an irregular three dimensional surface profile having jagged projections and a median particle diameter of 200 micrometers or less, the particles being fractals produced by comminution of foamed ceramic material. The material may be such that in a sphere of rotation of the particle, from 30% to 80% of the volume of the sphere is void, the remainder being continuous solid material. The material may be produced by a process which includes providing a suspension of ceramic forming particles e.g., of an aluminosilicate such as clay, in a liquid medium; incorporating a gas in the liquid medium before or after formation of the suspension therein to produce a foamed suspension; extruding the foamed suspension; optionally drying the extrudate formed thereby; calcining the extrudate; and comminuting the calcined material, e.g. by crushing. The material may be used as a substitute for diatomite.
    Type: Grant
    Filed: September 18, 1996
    Date of Patent: November 2, 1999
    Assignee: ECC International Ltd.
    Inventors: Nicholas John Goodwin Wilshaw, Jonathan Andrew Hearle, Mathew Thomas Rundle
  • Patent number: 5885913
    Abstract: A prefabricated part made of vitreous fused silica for use as a refractory, and in particular, for use in repairing coke ovens, which contains over 90% by weight of SiO.sub.2. The prefabricated part includes about 20 to 50% by weight of vitreous fused silica having 1 to 6 mm grain size, 20 to 40% by weight of vitreous fused silica having 0.1 to 1 mm grain size, 15 to 35% by weight of finely ground vitreous fused silica having grains less than 0.1 mm in size, 1 to 10% of finely ground vitreous fused silica having a specific surface area according to BET larger than 20 m.sup.2 per gram, 1 to 10% by weight of cement and 0.1 to 8% by weight of a phosphorous compound.
    Type: Grant
    Filed: July 24, 1995
    Date of Patent: March 23, 1999
    Assignee: Lichtenberg Feuerfest GmbH
    Inventors: Jean-Marie Delcloy, Jean-Marc Leroy, Edmund Goerenz
  • Patent number: 5755998
    Abstract: According to the present invention, there is provided a fluorophosphate fluorescent glass, capable of converting invisible ultraviolet rays into visually observable visible rays with a high efficiency and available for controlling the optical axis of a laser beam such as excimer laser, etc. The feature of this fluorescent glass consists in a fluorophosphate fluorescent glass capable of exhibiting fluorescence in the visible region, having a chemical composition comprising, at least, (I) phosphorus (P), oxygen (O) and fluorine (F), as glass constituting components, and (II) at least one member selected from the group consisting of divalent europium, terbium, samarium and manganese, as a fluorescent agent, the divalent europium being contained as an essential component and at least one of samarium and manganese being contained as an essential component when terbium is contained.
    Type: Grant
    Filed: November 20, 1996
    Date of Patent: May 26, 1998
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Masaaki Yamazaki, Masaaki Otsuka, Shinobu Nagahama, Naruhito Sawanobori
  • Patent number: 5750448
    Abstract: The invention relates to a copper(II) oxide-containing aluminophosphate glass having good chemical resistance, very good devitrification stability, high transmission at wavelengths in the range from 350 to 550 nm and a refractive index n.sub.d of from 1.52 to 1.54. The glass has the following composition (in % by weight, based on oxide): Al.sub.2 O.sub.3 4-9; P.sub.2 O.sub.5 67-75; BaO 0.5-6; CaO 0.1-1; MgO 0-4; SrO 0-1; ZnO 0.2-1; .SIGMA.BaO+CaO+MgO+SrO+ZnO 3.5-7; Na.sub.2 O 1.5-5; K.sub.2 O 2.5-3.5; Li.sub.2 O 0.5-5; .SIGMA.Na.sub.2 O+K.sub.2 O+Li.sub.2 O 5-13; SiO.sub.2 0-1; B.sub.2 O.sub.3 1-2.5; AS.sub.2 O.sub.3 0.1-0.5; Cl.sup.- 0-0.3; F.sup.- O-1.3; CeO.sub.2 0.2-0.4; CuO 1-6; with K.sub.G =.SIGMA.Al.sub.2 O.sub.3 +SiO.sub.2 +CeO.sub.2 /.SIGMA.P.sub.2 O.sub.5 +B.sub.2 O.sub.3 0.06-0.125.
    Type: Grant
    Filed: December 11, 1996
    Date of Patent: May 12, 1998
    Assignee: Schott Glaswerke
    Inventors: Danuta Grabowski, Uwe Kolberg, Alwin Weitzel, Magdalena Winkler-Trudewig
  • Patent number: 5714244
    Abstract: A material is impregnated with an aqueous solution containing precursors of a glass-containing phosphate base modified at least by the presence of zinc oxide, then dried and heat treated to form an internal oxidation protection constituted by the modified phosphate glass-containing base. The precursors are introduced into the aqueous solution so as to form a glass-containing base in which the molar ratio between the glass modifying oxides, comprising zinc oxide, and the glass forming oxides, principally comprising or consisting of phosphoric anhydride, is sufficiently high, in particular at least 0.6, preferably 0.9, to confer a resistance to corrosion by moisture on the glass-containing phosphate base.
    Type: Grant
    Filed: November 30, 1995
    Date of Patent: February 3, 1998
    Assignee: Societe Europeenne de Propulsion
    Inventors: Rodolphe Delaval, Gerard Palavit, Jacques Rey, Michel Laxague, Jacques Thebault
  • Patent number: 5639702
    Abstract: Glass colored in yellow, having transmission in the visible light range of the spectrum, which is produced by blending or adding an iodine compound to a matrix of glass having transmission in the visible light range of the spectrum or to the raw materials thereof. The glass has a yellow color of high excitation purity, is stable in color, and has good spectral properties.
    Type: Grant
    Filed: May 27, 1994
    Date of Patent: June 17, 1997
    Assignee: Kirin Beer Kabushiki Kaisha
    Inventors: Katuhiro Imashita, Shuichi Yokokura
  • Patent number: 5635109
    Abstract: According to the present invention, there is provided a fluorescent glass of the present invention is capable of converting invisible ultraviolet rays into visually observable visible rays with a high efficiency and available for controlling the optical axis of a laser beam such as excimer laser, etc. The feature of this fluorescent glass consists in a Tb- or Eu-containing fluorophosphate fluorescent glass having a chemical composition comprising, at least, phosphorus (P), oxygen (O) and fluorine (F), and further containing Tb or Eu as a fluorescent agent, and specifically comprising, in terms of atoms for making up the glass (mol %):______________________________________ P 1.about.15 Al 1.about.18 Mg 0.about.12 Ca 0.about.18 Sr 0.5.about.21 Ba 0.5.about.28 Zn 0.about.3.5 R 0.about.10 Ln 0.8.about.8 Ln' 0.about.6.5 Ce 0.about.0.2 O 4.about.55 F 15.about.
    Type: Grant
    Filed: October 30, 1995
    Date of Patent: June 3, 1997
    Assignee: Sumita Optical Glass, Inc.
    Inventor: Masaaki Otsuka
  • Patent number: 5555342
    Abstract: A planar waveguide and a process for making a planar waveguide is disclosed. The waveguide has a layer of doped host material formed on a substrate. The host material is a trivalent material such as a metal fluoride, wherein the metal is selected from the Group III B metals and the lanthanide series rare earth metals of the Mendeleevian Periodic Table. The dopant is a rare earth metal such as erbium. The waveguide has an emission spectrum with a bandwidth of about 60 nm for amplification of an optical signal at a wavelength of about 1.51 .mu.m to about 1.57 .mu.m. The waveguide is made by forming the layer of doped host material on a substrate. The film is formed by evaporating materials from two separate sources, one source for the dopant material and a separate source for the host material and forming a film of the evaporated materials on a substrate.
    Type: Grant
    Filed: January 17, 1995
    Date of Patent: September 10, 1996
    Assignee: Lucent Technologies Inc.
    Inventors: Christoph J. Buchal, Theo Siegrist
  • Patent number: 5364819
    Abstract: A Faraday rotator glass composition based on a fluoride glass, phosphate glass, fluorophosphate glass or a mixture thereof is doped with a lanthanide in a concentration sufficient to provide a Verdet constant above at least 2870 deg/Tesla-meter [(1 min/cm-Oe).times.(1.667.times.10.sup.4)=1 deg/Tesla-meter] and optical transmission above at least 50 percent in a 25 mm thick polished glass sample at least at one wavelength in the 200 to 400 nm wavelength region. The Faraday rotator glass also includes monovalent non-lanthanide cations such as Na, Li, K or mixtures thereof in a concentration sufficient to provide a Verdet constant above at least 2870 deg/Tesla-meter and optical transmission above at least 50 percent in a 25 mm thick polished glass sample at least at one wavelength in the 200 to 400 nm wavelength region.
    Type: Grant
    Filed: April 28, 1993
    Date of Patent: November 15, 1994
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: James L. Dexter, David G. Cooper, Douglas H. Blackburn, David C. Cranmer, Dale A. Kauffman
  • Patent number: 5328874
    Abstract: This invention relates to the preparation of a glass exhibiting a transition temperature normally below about 300.degree., a working temperature below about 400.degree., while, at the same time, exhibiting excellent resistance to attack by water. Specifically, the present invention discloses a glass consisting essentially in terms of mole percent on the oxide basis, of 15-35% P.sub.2 O.sub.5, 1-25% SO.sub.3, 30-55% ZnO, 0-25% R.sub.2 O, wherein R.sub.2 O is selected from the group consisting of 0-25% Li.sub.2 O, 0-25% Na.sub.2 O, and 0-25% K.sub.2 O, and up to a total of 15% of optional ingredients in the indicated proportions selected from the group consisting of 0-10% Al.sub.2 O.sub.3, 0-10% MgO, 0-10% CaO, 0-10% SrO, 0-10% BaO, 0-10% MnO, 0-10% transition metal oxides and 0-15% Cl+F, as analyzed in weight percent.
    Type: Grant
    Filed: October 18, 1993
    Date of Patent: July 12, 1994
    Assignee: Corning Incorporated
    Inventors: George H. Beall, Joseph E. Pierson
  • Patent number: 5286683
    Abstract: This invention is directed to the production of glasses exhibiting transition temperatures below 375.degree. C., preferably below 350.degree. C., and superior resistance to attack by boiling water. The glasses contain at least 10% copper, as expressed in terms of CuO, the predominant proportion of the copper being present in the Cu.sup.+2 oxidation state. The glasses consist essentially, in mole percent, of______________________________________ Li.sub.2 O 0-15 MgO 0-15 B.sub.2 O.sub.3 0-5 Na.sub.2 O 0-20 CaO 0-20 ZnO 0-37 K.sub.2 O 0-10 SrO 0-20 Sb.sub.2 O.sub.3 0-36 Tl.sub.2 O 0-15 BaO 0-20 CeO.sub.2 0-3 Li.sub.2 O + Na.sub.2 O + 12-30 MgO + 0-25 MoO.sub.3 0-7 K.sub.2 O + Tl.sub.2 O CaO + SrO + BaO CuO 10-50 Al.sub.2 O.sub.3 + B.sub.2 O.sub.3 0-5 RE.sub.2 O.sub.3 0-2 P.sub.2 O.sub.5 28-36 Al.sub.2 O.sub.3 0-5 WO.sub.3 0-7 MnO 0-20 ______________________________________wherein at least two alkali metal oxides are present and up to 12% by weight fluoride may optionally be present.
    Type: Grant
    Filed: November 5, 1992
    Date of Patent: February 15, 1994
    Assignee: Corning Incorporated
    Inventor: Bruce G. Aitken