And Titanium, Zirconium, Vanadium, Tungsten, Or Molybdenum Patents (Class 501/46)
  • Publication number: 20080190034
    Abstract: Ceramic materials and articles comprising at least 35 percent by weight Al2O3, and a plurality of cells having an average cell size of less than 3 micrometers.
    Type: Application
    Filed: December 30, 2005
    Publication date: August 14, 2008
    Inventors: Anatoly Z. Rosenflanz, Berkan K. Endres, Thomas J. Anderson
  • Patent number: 7396787
    Abstract: The lead-free, preferably lithium-free, optical glass is useful in imaging, projection, telecommunications, optical communication and/or laser technology, particularly for making precise-pressed optical elements. It has a refractive index nd of 1.50 to 1.57, an Abbé number ?d of 61 to 70. It also has a low transformation temperature of about or below 400° C., good production and processing properties and crystallization resistance. It has a composition, in percent by weight, based on oxide content of P2O5, 40 to 60; Al2O3, 1 to 20; B2O3, 0 to <5; Na2O, 0 to 30; K2O, 0 to 30; Li2O, 0 to <1; ?M2O, >15 to 40; BaO, 1 to 20; ZnO, 1 to 20; SrO, 0 to 5; CaO, 0 to 5; MgO, 0 to 5; and ?MO, 5 to 25. In addition, it may contain standard refining agents, although it is preferably free of arsenic and fluorine.
    Type: Grant
    Filed: January 13, 2005
    Date of Patent: July 8, 2008
    Assignee: Schott AG
    Inventors: Simone Monika Ritter, Ute Woelfel, Silke Wolff
  • Patent number: 7396786
    Abstract: A glass containing 5 to 25 mass % of P2O5, 0 to 15 mass % of B2O3, 0 to 5 mass % of SiO2+GeO2, 21 to 50 mass % of BaO+SrO, 0 to 3 mass % of Li2O+Na2O+K2O, and 35 to 65 mass % of Nb2O5, not substantially containing PbO, satisfying Nb2O5/(BaO+SrO)=0.85 to 2.20, having a dielectric constant of 15 or greater, a dielectric loss of 10.0×10?4 or less, and a resistivity of 1.0×1016 ?·cm or more.
    Type: Grant
    Filed: January 22, 2003
    Date of Patent: July 8, 2008
    Assignee: Kabushiki Kaisha Ohara
    Inventors: Masaaki Miyata, Kazuo Ohara
  • Patent number: 7371703
    Abstract: An optical glass wherein an amount of change in refractive index (?n: difference in refractive index between a state before radiation and a state after radiation) caused by radiation of laser beam at wavelength of 351 nm having average output power of 0.43 W, pulse repetition rate of 5 kHz and pulse width of 400 ns for one hour is 5 ppm or below is provided. The optical glass comprises a fluorine ingredient and/or a titanium oxide ingredient and/or an arsenic oxide ingredient. The optical glass suffers little change in refractive index by radiation of strong light having wavelengths of 300 nm to 400 nm such as ultraviolet laser.
    Type: Grant
    Filed: September 18, 2003
    Date of Patent: May 13, 2008
    Assignee: Kabushiki Kaisha Ohara
    Inventors: Akira Masumura, Muneo Nakahara, Satoru Matsumoto, Tatsuya Senoo
  • Patent number: 7361632
    Abstract: A zinc-containing, water-soluble glass composition comprising from 41 to 54 mole % of P2O5, 10 to 30 mole % of alkali oxides, up to 5 mole % of SO3 and up to 25 mole % of ZnO.
    Type: Grant
    Filed: July 25, 2005
    Date of Patent: April 22, 2008
    Assignee: Reckitt Benckiser N.V.
    Inventor: Karlheinz Ulrich Gerhard Hahn
  • Publication number: 20080085826
    Abstract: The present invention relates to lead and fluorine and preferably lithium free optical glasses for the application areas imaging, projection, telecommunications optical communications engineering, mobile drive and/or laser technology with a refractive index of from 1.60?nd?1.64 and an Abbe number of from 56??d?64, which glasses have a low transformation temperature, namely less than or equal to 590° C., preferably less than or equal to 585° C., more preferred less than or equal to 570° C., which glasses can still further be produced and handled easily and are stable to crystallization. The glasses according to the invention with the following composition (in weight-% based on the oxides) comprise the following components: P2O5 26-35 B2O3 10-15 Al2O3 5.5-10? BaO 25-37 SrO 0-6 CaO ?8-15 ZnO ?3-10 Bi2O3 0-8 Na2O 0-2 K2O 0-2 WO3 ?0-10 La2O3 0-2 Nb2O5 0-1 TiO2 ??0-<1 ?earth alkali oxides ?40 ?alkali oxides 0-2 common refining agents ??0-0.
    Type: Application
    Filed: October 2, 2007
    Publication date: April 10, 2008
    Inventors: Simone Monika Ritter, Ute Woelfel
  • Publication number: 20080039309
    Abstract: The lead-free optical glass can be used in the fields of imaging, sensor technology, microscopy, medical technology, digital projection, photolithography, laser technology, wafer/chip technology, as well as of telecommunications, optical communication engineering and optics/lighting in the automotive sector. It has a refractive index nd of 1.82?nd?2.00 and/or an Abbe number vd of 18?vd?28 with good chemical stability, excellent crystallization stability and the following composition, in wt. based on oxide content, of: P2O5 12-35 Nb2O5 30-50 Bi2O3 ?2-13 GeO2 0.1-7?? Li2O ?6 Na2O ?6 K2O ?6 Cs2O ?6 MgO ?6 CaO ?6 SrO ?6 BaO ???7-<17 ZnO ?6 TiO2 ?7 ZrO2 ?7 WO3 ?2-14 F ??6.
    Type: Application
    Filed: August 8, 2007
    Publication date: February 14, 2008
    Inventors: Silke Wolff, Simone Monika Ritter, Ute Woelfel
  • Publication number: 20080032879
    Abstract: An optical glass suitable for mold forming at a low temperature including, in percent by weight, 9-25 percent of P2O5, 1-20 percent of GeO2, 12-28 percent of Nb2O5, 1-7 percent of TiO2, 0-55 percent of Bi2O3, 0-38 percent of WO3, 0-3 percent of SiO2, 0-5 percent of B2O3, 0-2 percent of Al2O3, 0-5 percent of Li2O, 0-11 percent of Na2O, 0-5 percent of K2O, 0-3 percent of Ta2O5, 0-1 percent of Sb2O3, at most 13 percent of at least one R2O selected from the group consisting of Li2O, Na2O and K2O, and at most 15 percent of at least one XO selected from the group consisting of CaO, SrO, BaO and ZnO. The optical glass essentially contains no environmental and human harmful components, facilitates mass production and is stable against devitrification near its softening temperature.
    Type: Application
    Filed: May 31, 2007
    Publication date: February 7, 2008
    Applicant: Asia Optical Co., Inc
    Inventors: Tsung-yuen Tsai, Hsiang-jen Shih
  • Patent number: 7312169
    Abstract: The present invention provides a high refractive index, high dispersion optical glass for precision molding, being free from harmful materials causing environmental problems, such as lead oxide, etc., and having a low yield temperature, a refractive index (nd) of at least 1.83 and an Abbe number (?d) of at most 26.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented in terms of for making up the glass, by the following chemical composition (wt %): P2O5 15 to 29% B2O3 ?0 to 2% GeO2 ?0 to 14% Sum of P2O5 + B2O3 + GeO2 20 to 35% Li2O ?0 to 5% Na2O ?3 to 14% K2O ?0 to 9% Sum of Li2O + Na2O + K2O ?5 to 15% Nb2O5 ?2 to less than 22% Bi2O3 34 to 60% WO3 ?0 to 5% BaO ?0 to 5% In2O3 ??0 to 7%.
    Type: Grant
    Filed: November 4, 2004
    Date of Patent: December 25, 2007
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Yoshinori Yamamoto, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 7309670
    Abstract: The present invention relates to optical glass having a high refractive index, high dispersion, and a low glass transition temperature; a preform comprised of the optical glass for precision press-molding and a method of manufacturing the same; and an optical element comprised of the optical glass and a method of manufacturing the same.
    Type: Grant
    Filed: April 19, 2004
    Date of Patent: December 18, 2007
    Assignee: Hoya Corporation
    Inventors: Yasuhiro Fujiwara, Xuelu Zou
  • Patent number: 7306845
    Abstract: Nanoscale particles, particle coatings/particle arrays and corresponding consolidated materials are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.
    Type: Grant
    Filed: October 29, 2004
    Date of Patent: December 11, 2007
    Assignee: NeoPhotonics Corporation
    Inventors: Craig R. Horne, Pierre J. DeMascarel, Christian C. Honeker, Benjamin Chaloner-Gill, Herman A. Lopez, Xiangxin Bi, Ronald J. Mosso, William E. McGovern, James T. Gardner, Sujeet Kumar, James A. Gilliam, Vince Pham, Eric Euvrard, Shivkumar Chiruvolu, Jesse Jur
  • Publication number: 20070243991
    Abstract: A substantially alkaline resistant calcium-iron-phosphate (CFP) glass and methods of making and using thereof. In one application, the CFP glass is drawn into a fiber and dispersed in cement to produce glass fiber reinforced concrete (GFRC) articles having the high compressive strength of concrete with the high impact, flexural and tensile strength associated with glass fibers.
    Type: Application
    Filed: March 30, 2007
    Publication date: October 18, 2007
    Inventors: Richard K. Brow, Signo T. Reis, Mariano Velez, Delbert E. Day
  • Publication number: 20070225146
    Abstract: Optical glasses are described, which are useful for imaging, sensors, microscopy, medical technology, digital protection, photolithography, laser technology, wafer/chip technology, as well as telecommunication, optical communications engineering and optics/lighting in the automotive sector, with a refractive index of 1.80?nd?1.95 and an Abbe value from 19??d?28 with excellent chemical resistance and stability to crystallization. These optical glasses have a composition, in weight % based on oxide content, of: P2O5, 14-35; Nb2O5, 45-50; Li2O, 0-4; Na2O, 0-4; K2O, 0.5-5; BaO, 17-23; ZnO, 0.1-5; TiO2, 1-<5; ZrO2, 06; and Sb2O3, 0.1-2.
    Type: Application
    Filed: March 16, 2007
    Publication date: September 27, 2007
    Inventors: Silke Wolff, Stefanie Hansen, Ute Woelfel
  • Patent number: 7245066
    Abstract: A flat panel display spacer has a sintered body containing A12O3, TiC, MgO, and TiO2, whereas the sintered body includes 35 to 55 wt % of MgO with respect to the total weight of A12O3, TiC, MgO, and TiO2.
    Type: Grant
    Filed: July 28, 2004
    Date of Patent: July 17, 2007
    Assignee: TDK Corporation
    Inventors: Yukio Kawaguchi, Atsushi Hitomi, Kazumitsu Tanaka, Takao Matsumoto, Masahiro Itoh, Kenichi Jinguji, Tsutomu Koyanagi, Katsuyuki Kurachi
  • Patent number: 7141525
    Abstract: The present invention provides a high refractive index, high dispersion optical glass for precision molding, being free from harmful materials causing environmental problems, such as lead oxide, etc., and having a low yield temperature (At), i.e. at most 580° C., a refractive index (nd) of at least 1.89 and an Abbe number (?d) of at most 23.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented in terms of for making up the glass, by the following chemical composition (wt %): P2O5 3 to 20% B2O3 0 to 5% GeO2 more than 14 to 37% Sum of P2O5 + B2O3 + GeO2 24 to 43% Li2O 0 to 5% Na2O 0 to 8% K2O 0 to 10% Sum of Li2O + Na2O + K2O 1 to 10% Nb2O5 0 to 50% Bi2O3 12 to 67% BaO 0 to 5% WO3 0 to 12%.
    Type: Grant
    Filed: November 4, 2004
    Date of Patent: November 28, 2006
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Yoshinori Yamamoto, Koichi Tsuchiya, Naruhito Sawanobori, Shinobu Nagahama
  • Patent number: 7115536
    Abstract: A rare earth containing glass nominally based on the ternary P2O5—WO3—Na2O-Ln2O3 compositional space, with WO3>30-65 mole %, Na2O 15-35 mole %, P2O5 5-65 mole %, Ln2O3 (Ln=one or more cations selected from lanthanum or any of the rare earth oxides) up to the limit of solubility; with optional additives, MoO3 being a preferred additive, that can be employed alone or in combination at levels up to 15 mole %.
    Type: Grant
    Filed: March 5, 2003
    Date of Patent: October 3, 2006
    Assignee: Schott Glass Technologies, Inc.
    Inventors: Joseph Hayden, Sally Pucilowski, Bianca Schreder, Ulrich Peuchert, Ruediger Sprengard, Martin Letz
  • Patent number: 7060640
    Abstract: An optical glass comprises, in mass percent, 15–35% of P2O5, 40–60% of Nb2O5, 0.5% to less than 15% of Na2O and 3% to less than 25% of BaO, has a ratio in mass % of (BaO+Nb2O5)/{(TiO2+WO3)×3+Bi2O3+Nb2O5}>1.0; is free of Pb and As; and has a refractive index (nd) within a range from 1.78 to 1.90 and an Abbe number (?d) within a range from 18 to 27.
    Type: Grant
    Filed: July 10, 2003
    Date of Patent: June 13, 2006
    Assignee: Kabushiki Kaisha Ohara
    Inventors: Michiko Ogino, Yoshio Mori, Masahiro Onozawa
  • Patent number: 7033966
    Abstract: An optical glass which contains at least 20 mol % of TeO2 and has an internal transmittance of at least 80% in a thickness of 2 mm to a light having a wavelength of 405 nm and a refractive index of at least 1.85 to the same light, and which contains no alkali metal oxide or contains alkali metal oxides in a total amount of at most 15 mol %.
    Type: Grant
    Filed: May 19, 2004
    Date of Patent: April 25, 2006
    Assignee: Asahi Glass Company, Limited
    Inventors: Tomoyuki Kobayashi, Minoru Sekine, Naoki Sugimoto, Syuji Matsumoto
  • Patent number: 7018566
    Abstract: The invention concerns novel compounds derived from La2Mo2O9 and their use as ion conductors.
    Type: Grant
    Filed: April 5, 2001
    Date of Patent: March 28, 2006
    Assignee: Centre National de la Recherche Scientifique
    Inventors: François Goutenoire, Philippe Lacorre
  • Patent number: 7005396
    Abstract: The present invention provides a composition for use in forming an enamel cover coat from which baked-on foods can be removed without the need for pyrolysis or highly alkaline cleaners. The enamel cover coat preferably exhibits no chipping or other surface defects subsequent to a 2.0 mm Plum Jam Test and an acid resistance of A or better according to ISO 2722. The composition according to the invention includes a glass component including at least a first glass frit comprising a low SiO2 glass frit. Preferably, the glass component includes a blend of the first glass frit and at least a second glass frit. Preferably, the first glass frit includes by weight from about 30% to about 45% P2O5, from about 20% to about 40% Al2O3, from about 15% to about 35% Li2O+Na2O+K2O, up to about 15% B2O3, up to about 15% MgO+CaO+SrO+BaO+ZnO, up to about 10% TiO2+ZrO2, and up to about 10% SiO2.
    Type: Grant
    Filed: June 25, 2001
    Date of Patent: February 28, 2006
    Assignee: Ferro France-S.A.R.L.
    Inventors: Sophie Espargillière, Andreas Schanné, Francois Roques
  • Patent number: 7001858
    Abstract: Glass fiber which substantially has the following composition as represented by mol percentage and has a glass transition temperature higher than 300° C. and lower than 400° C.: Li2O+Na2O+K2O: 5 to 35%, P2O5: 20 to 27%, SO3: 3 to 20%, ZnO: 10 to 55%, MgO: 0 to 20%, ZnO+MgO: 10 to 55%, Al2O3: 1 to 5%, and B2O3: 8 to 20%.
    Type: Grant
    Filed: February 12, 2003
    Date of Patent: February 21, 2006
    Assignees: Asahi Glass Company, Limited, Asahi Fiber Glass Company, Limited
    Inventors: Hideki Nakagawa, Yoshiro Niino, Yoshinao Kobayashi
  • Patent number: 6995101
    Abstract: An optical glass having a high refractive index and high dispersion characteristics suitable for application to precision press molding to precisely mold final products without requiring grinding or polishing. An optical glass can be prepared exhibiting a refractive index in the range of from 1.75 to 2.0, and an Abbé number in the range of from 20 to 28.5. Optical parts comprised of this glass; press-molding materials comprised of this glass; methods of manufacturing the same; and methods of manufacturing molded glass products employing these materials. A suitable optical glass is composed of the following in molar percent: 15–30% P2O5; 0.5–15% B2O3; 5–25% Nb2O5; 6–40% WO3; 4–45% of at least one of Li2O, Na2O or K2O; 1–5% K2O; 2–9% TiO2; and 0–30% (excluding 30%) of at least one RO selected from among BaO, ZnO, and SrO; with the total content of the above-stated components being equal to or more than 95 percent.
    Type: Grant
    Filed: June 29, 2001
    Date of Patent: February 7, 2006
    Assignee: Hoya Corporation
    Inventors: Xuelu Zou, Hiromasa Tawarayama, Kazutaka Hayashi, Hiroshi Kawazoe
  • Patent number: 6984261
    Abstract: The invention relates to uses of glasses and glass-ceramics in dental and orthodontic applications.
    Type: Grant
    Filed: February 5, 2003
    Date of Patent: January 10, 2006
    Assignee: 3M Innovative Properties Company
    Inventors: Kevin M. Cummings, Jacqueline C. Rolf, Anatoly Z. Rosenflanz, Richard P. Rusin, Jerome E. Swanson
  • Patent number: 6878765
    Abstract: A method for producing a component from a glass/polymer mixture where, a component is formed from a mixture of a thermoplastic with a processing temperature T1 and first glass particles with saturated surface bonds and a glass temperature T2<T1, at a temperature T3>T1. By melting the first glass particles, second glass particles are produced with surface bonds which can be saturated. The bonds are saturated by being bonded to the thermoplastic.
    Type: Grant
    Filed: December 13, 2000
    Date of Patent: April 12, 2005
    Assignee: Siemens Aktiengesellschaft
    Inventors: Robert Greiner, Angelo Polese
  • Patent number: 6875714
    Abstract: An optical glass consists essentially, expressed in term of weight percent, of: P2O5: 20.0 to 30.0%, B2O3: 0.5 to 10.0%, Nb2O5: 5.0 to 50.0%, WO3: 15.0 to 27.0%, Bi2O3: 0.1 to 3.0%, ZnO: 1.0 to 7.0%, Li2O: 0 to 8.0%, Na2O: 0 to 15.0%, K2O: 0 to 15.0%, and Li2O+Na2O+K2O: 5.0 to 20.0%.
    Type: Grant
    Filed: April 25, 2003
    Date of Patent: April 5, 2005
    Assignee: Minolta Co., Ltd.
    Inventor: Manabu Izuki
  • Patent number: 6849334
    Abstract: Nanoscale particles, particle coatings/particle arrays and corresponding consolidated materials are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.
    Type: Grant
    Filed: March 15, 2002
    Date of Patent: February 1, 2005
    Assignee: NeoPhotonics Corporation
    Inventors: Craig R. Horne, Pierre J. DeMascarel, Christian C. Honeker, Benjamin Chaloner-Gill, Herman A. Lopez, Xiangxin Bi, Ronald J. Mosso, William E. McGovern, James T. Gardner, Sujeet Kumar, James A. Gilliam, Vince Pham, Eric Euvrard, Shivkumar Chiruvolu, Jesse Jur
  • Patent number: 6841493
    Abstract: The present invention is directed to a glass composition comprising, based on mole %, 15-35% MO where M is selected from BaO, CaO, MgO, PbO, SrO and mixtures thereof, 30-60% TiO2, 10-30% B2O3, 1-7% P2O5, 0-3% Li2O and 2-16% Ln2O3 where Ln is selected from the group of rare earth elements and mixtures thereof. The invention is further directed to the glass composition incorporated in a thick film composition or a castable dielectric composition comprising a dispersion of finely divided solids comprising, based on solids: (a) 30-100 wt. % the glass composition; (b) 0-50 wt. % ceramic filler; both dispersed in a solution of (c) an organic polymeric binder; and (d) a volatile organic solvent. The invention is still further directed to the castable dielectric composition used in a method of forming a high K green tape by casting a thin layer of the castable dispersion onto a flexible sheet and heating the cast layer to remove the volatile organic solvent.
    Type: Grant
    Filed: March 17, 2003
    Date of Patent: January 11, 2005
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Yong Cho, Kenneth Warren Hang
  • Publication number: 20040266602
    Abstract: The present invention relates to optical glass having a high refractive index, high dispersion, and a low glass transition temperature; a preform comprised of the optical glass for precision press-molding and a method of manufacturing the same; and an optical element comprised of the optical glass and a method of manufacturing the same.
    Type: Application
    Filed: April 19, 2004
    Publication date: December 30, 2004
    Applicant: HOYA CORPORATION
    Inventors: Yasuhiro Fujiwara, Xuelu Zou
  • Publication number: 20040176236
    Abstract: A rare earth containing glass nominally based on the ternary P2O5 —WO3—Na2O—Ln2O3 compositional space, with WO3>30-65 mole %, Na2O 15-35 mole %, P2O5 5-65 mole %, Ln2O3 (Ln=one or more cations selected from lanthanum or any of the rare earth oxides) up to the limit of solubility; with optional additives, MoO3 being a preferred additive, that can be employed alone or in combination at levels up to 15 mole %.
    Type: Application
    Filed: March 5, 2003
    Publication date: September 9, 2004
    Applicant: SCHOTT GLASS TECHNOLOGIES, INC.
    Inventors: Joseph Hayden, Sally Pucilowski, Bianca Schreder, Ulrich Peuchert, Ruediger Sprengard, Martin Letz
  • Patent number: 6767854
    Abstract: The invention refers to a material which is chemically long-term stable in a neutral or slightly acid environment and which can be used both as bioactive bone replacement material, e.g. in the form of a coating applied onto metallic prosthesis sticks by thermal spraying, and as substrate material in biotechnology, e.g. in the form of a ceramic sheet. According to the invention, said material comprises 15-45% by weight CaO, 40-45% by weight P2O5, 10-40% by weight ZrO2 and fluoride, said material further comprises two crystalline phases being apatite and calcium zirconium phosphate, and a secondary glass phase. Said material has a very high chemical long-term stability, compared to known materials which can also be produced by means of a melting process.
    Type: Grant
    Filed: June 13, 2002
    Date of Patent: July 27, 2004
    Assignee: Bam Bundesanstalt fuer Materialforschung und Prufung
    Inventors: Georg Berger, Ute Ploska
  • Patent number: 6743743
    Abstract: Optical glasses and optical articles comprised of the optical glass are disclosed. One of which comprises, by means of weight percentages, more than 32 percent and not more than 45 percent P2O5, more than 0.5 percent and not more than 6 percent Li2O, more than 5 percent and not more than 22 percent Na2O, 6-30 percent Nb2O5, 0.5-10 percent B2O3, 0-35 percent WO3, 0-14 percent K2O, and 10-24 percent Na2O+K2O, and the total of all the above components is not less than 80 percent.
    Type: Grant
    Filed: January 29, 2002
    Date of Patent: June 1, 2004
    Assignee: Hoya Corporation
    Inventor: Koichi Sato
  • Patent number: 6656859
    Abstract: A family of tellurite glasses and optical components for telecommunication systems, the glasses consisting essentially of, as calculated in cation percent, 65-97% TeO2, and at least one additional oxide of an element having a valence greater than two and selected from the group consisting of Ta, Nb, W, Ti, La, Zr, Hf, Y, Gd, Lu, Sc, Al and Ga, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.
    Type: Grant
    Filed: December 6, 2001
    Date of Patent: December 2, 2003
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Adam J. G. Ellison, Randall E. Youngman
  • Publication number: 20030220182
    Abstract: An optical glass consists essentially, expressed in term of weight percent, of: P2O5: 20.0 to 30.0%, B2O3: 0.5 to 10.0%, Nb2O5: 5.0 to 50.0%, WO3: 15.0 to 27.0%, Bi2O3: 0.1 to 3.0%, ZnO: 1.0 to 7.0%, Li2O: 0 to 8.0%, Na2O: 0 to 15.0%, K2O: 0 to 15.0%, and Li2O+Na2O+K2O: 5.0 to 20.0%.
    Type: Application
    Filed: April 25, 2003
    Publication date: November 27, 2003
    Inventor: Manabu Izuki
  • Patent number: 6566289
    Abstract: The present invention provides a composition for use in forming a white porcelain enamel coating on aluminized or galvanized steel. The composition according to the present invention includes a solids portion including a glass component and a white pigment. The glass component includes one or more glass frits including by weight from about 30% to 50% P2O5, from about 15% to about 30% Al2O3, from about 8% to about 40% X2O where X=Na and/or K, up to about 30% TiO2, up to about 12% B2O3, up to about 10% K2O, up to about 10% ZnO, up to about 8% SiO2, up to about 7% La2O3, up to about 5% Li2O, and up to about 15% F. The white pigment include TiO2.
    Type: Grant
    Filed: August 17, 2001
    Date of Patent: May 20, 2003
    Assignee: Ferro France - S.A.R.L.
    Inventors: Alain Aronica, Emmanuel Marinho, David Coutouly, Luc Allemeersch, Christophe Reb
  • Patent number: 6528442
    Abstract: To provide an optically transparent film containing 0.01 to 20% by weight glass forming oxide consisting of Nb2O5, V2O5, B2O3, SiO2, and P2O6; 0.01 to 20% by weight Al2O3 or Ga2O3; and 0.01 to 5% by weight hard oxide of ZrO2 and TiO2 as required; balance being ZnO, and a sputtering target for forming such a film. This sputtering target reduces occurrence of particles during sputtering, decreases the number of interruption or discontinuance of sputtering to improve production efficiency, and forms a protective film for optical disks with large transmittance and low reflectance.
    Type: Grant
    Filed: December 7, 2000
    Date of Patent: March 4, 2003
    Assignee: Nikko Materials Company, Limited
    Inventors: Katsuo Kuwano, Hideo Takami
  • Patent number: 6511931
    Abstract: The present invention provides a ground coat composition for use in forming an enamel layer on sheet steel that exhibits good spot acid resistance, a satin finish, good bond, and is easy-to-clean. The composition according to the invention includes a glass component that includes a blend of from about 40% to about 70% by weight of a first glass portion including one or more alkali aluminophosphate frits, up to about 30% by weight of a second glass portion including one or more zirconia-phosphate frits, and up to about 30% by weight of a third glass portion including one or more alkali borosilicate frits.
    Type: Grant
    Filed: July 16, 2001
    Date of Patent: January 28, 2003
    Assignee: Ferro Corporation
    Inventor: Charles A. Baldwin
  • Patent number: 6485622
    Abstract: Lithium ion conductive glass-ceramics comprise in mol %: P2O5 30-45% SiO2 0-15% GeO2 + TiO2 25-50% in which GeO2 0-50% TiO2 0-50% ZrO2 0-8% M2O3 0<-10% where M is an element or elements selected from the group consisting of In, Fe, Cr, Sc, Y, La, Ce, Pr, Nd, Sm, Eu, Gd, Th, Dy, Ho, Er, Tm, Yb and Lu Al2O3 0-12% Ga2O3 0-12% Li2O 10-25% and contain Li1+X(M, Al, Ga)X(Ge1−YTiY)2−X(PO4)3 (where 0<X≦0.8 and 0≦Y≦1.0) as a predominant crystal phase. A solid electrolyte, an electric cell and a gas sensor utilizing these glass-ceramics are also provided.
    Type: Grant
    Filed: September 27, 1999
    Date of Patent: November 26, 2002
    Assignee: Kabushiki Kaisha Ohara
    Inventor: Jie Fu
  • Patent number: 6432851
    Abstract: A durable low Tg Sb-stabilized Mo+W phosphate based glass composition exhibiting superior resistance to attack by boiling water, humidity and acids resulting from the addition of Sb to Mo+W phosphate based glass compositions. Specifically, the present invention discloses a glass composition comprising in mol % on the oxide basis, of 0-40% R2O where R includes the alkali metals (Li, Na, K, Rb or Cs) as well as Ag and Tl, 0-20% XO where X includes the alkaline earth metals (Mg, Ca, Sr or Ba) as well as Cu, Zn, Cd and Pb, 15-80% MoO3+WO3, 0.5-60% Sb2O3, and 10-40% P2O5. Additionally, the Sb-stabilized Mo+W phosphate based glass composition can contain a total of 0-5%, in mole percent (mol %) on the oxide basis, of glass forming oxides including, but not limited to, B2O3, Al2O3, SiO2, TeO2, Ga2O3, GeO2, transition metal and rare earth metal oxides, or mixtures thereof.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: August 13, 2002
    Assignee: Corning Incorporated
    Inventor: Bruce G. Aitken
  • Publication number: 20020061809
    Abstract: The present invention provides a composition for use in forming a white porcelain enamel coating on aluminized or galvanized steel. The composition according to the present invention includes a solids portion including a glass component and a white pigment. The glass component includes one or more glass frits including by weight from about 30% to 50% P2O5, from about 15% to about 30% Al2O3, from about 8% to about 40% X2O where X=Na and/or K, up to about 30% TiO2, up to about 12% B2O3, up to about 10% K2O, up to about 10% ZnO, up to about 8% SiO2, up to about 7% La2O3, up to about 5% Li2O, and up to about 15% F. The white pigment include TiO2.
    Type: Application
    Filed: August 17, 2001
    Publication date: May 23, 2002
    Applicant: Ferro France S.A.R.L.
    Inventors: Alain Aronica, Emmanuel Marinho, David Coutouly, Luc Allemeersch, Christophe Reb
  • Patent number: 6376399
    Abstract: Alkali tungstate, molybdate and vanadate glasses, and telecommunications components embodying such glasses, the compositions of the glasses consisting essentially of 15-70 mol percent of at least one oxide selected from the group consisting of WO3, MoO3 and VO2.5, 0-35% CrO3, 0-15% UO3, the total WO3 plus MoO3 plus VO2.5 plus CrO3 plus UO3 being 50-70%, 20-50% R2O where R represents at least two elements selected from the group consisting of Li, Na, K, Rb, Cs, Ag and T1, and optionally containing 0-10% MO where M is selected from the groups of elements consisting of Ca, Ba, Sr, Mg, Cd, Pb, 0-5 % X2O3 where x is at least one element selected from the group consisting of Al, Ga, In and Bi, 0-5% of at least one transition metal oxide, 0-15% P2O5 and/or TeO2 and 0-5% of a rare earth oxide selected from the lanthanide series.
    Type: Grant
    Filed: January 24, 2000
    Date of Patent: April 23, 2002
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Matthew J. Dejneka
  • Publication number: 20020042337
    Abstract: An optical glass having a high refractive index and high dispersion characteristics that is suited to application to precision press molding to precisely mold the shape of final products for objectives not requiring grinding or polishing. An optical glass exhibiting a refractive index in the range of from 1.75 to 2.0, an Abbé number in the range of from 20 to 28.5. Optical parts comprised of this glass; press-molding materials comprised of this glass; methods of manufacturing the same; and methods of manufacturing molded glass products employing these materials.
    Type: Application
    Filed: June 29, 2001
    Publication date: April 11, 2002
    Inventors: Xuelu Zou, Hiromasa Tawarayama, Kazutaka Hayashi, Hiroshi Kawazoe
  • Patent number: 6355586
    Abstract: A low melting point glass consisting essentially of, as represented by mol % based on the following oxides: Mol % SnO   2 to 37.5, ZnO 5 to 73, P2O5 16 to 50,  Li2O 0 to 9,  Na2O 0 to 9,  K2O 0 to 9,  Al2O3 0 to 20, B2O3 0 to 30, SiO2 0 to 20, MgO 0 to 35, CaO 0 to 35, SrO 0 to 35, BaO 0 to 35, In2O3 0 to 10, WO3 0 to 10, wherein SnO+ZnO+P2O5+B2O3 is at least 76 mol %, Li2O+Na2O+K2O is from 0 to 9 mol %, MgO+CaO+SrO+BaO is from 0 to 35 mol %, and the molar ratio of SnO to ZnO is less than 1.
    Type: Grant
    Filed: January 31, 2000
    Date of Patent: March 12, 2002
    Assignee: Asahi Glass Company, Limited
    Inventors: Hiroshi Usui, Yasuko Dotani, Ryuichi Tanabe, Tsuneo Manabe
  • Patent number: 6352950
    Abstract: A family of alkali-tungsten-tellurite glasses that consist essentially of, as calculated in mole percent, 10-90% TeO2, at least 5% W03 and at least 0.5% R2O where R is Li, Na, K, Cs, Tl and mixtures, that may contain a lanthanide oxide as a dopant, in particular erbium oxide, and that, when so doped, is characterized by a fluorescent emission spectrum having a relatively broad FWHM value.
    Type: Grant
    Filed: May 31, 2000
    Date of Patent: March 5, 2002
    Assignee: Corning Incorporated
    Inventors: Bruce G. Aitken, Adam J. G. Ellison
  • Patent number: 6333282
    Abstract: The present invention provides an optical glass for precision molding, having excellent properties, i.e. yield temperature (At) of at most 550° C., refractive index (nd) of at least 1.83 and Abbe number (&ngr;d) of at most 26.0 and further providing a low softening property as well as an improved mass production property with less coloration, which is represented, in term of atoms for making up the glass, by the following chemical composition (wt %) P2O5 14.0 to 31.0% B2O3   0 to 5.0% GeO2   0 to 14.0% Sum of P2O5 + B2O3 + GeO2 14.0 to 35.0% Li2O   0 to 6.0% Na2O  2.5 to 14.0% Sum of Li2O + Na2O  2.5 to 15.0% Nb2O5 22.0 to 50.0% WO3   0 to 30.0% Bi2O3  5.0 to 36.0% BaO   0 to 22.0%.
    Type: Grant
    Filed: August 9, 2000
    Date of Patent: December 25, 2001
    Assignee: Sumita Optical Glass, Inc.
    Inventors: Koji Nakahata, Koichi Tsuchiya, Shinobu Nagahama
  • Patent number: 6315881
    Abstract: A solid electric cell includes a case, a negative electrode, a positive electrode and a solid electrolyte. The negative electrode, positive electrode and solid electrolyte are disposed in the case in such a manner that the negative electrode opposes the positive electrode through the solid electrolyte. The solid electrolyte is made of an alkali ion conductive glass-ceramic having ion conductivity no less than 10−3S/cm at room temperature. A gas sensor includes a case, a negative electrode, a positive electrode, a solid electrolyte and a layer for which an electromotive force corresponding to the concentration of the gas is produced between the two electrodes. In the case, the negative electrode opposes the positive electrode through the solid electrolyte. The solid electrolyte is made of an alkali ion conductive glass-ceramic having ion conductivity no less than 10−3S/cm at room temperature.
    Type: Grant
    Filed: April 9, 1999
    Date of Patent: November 13, 2001
    Assignee: Kabushiki Kaisha Ohara
    Inventor: Jie Fu
  • Patent number: 6309989
    Abstract: A tin-borophosphate glass of the present invention has main components of SnO, B2O3, and P2O5, consists essentially of, by mole % representation, 30-70% SnO, 5-30% B2O3, and 24-45% (24% exclusive) P2O5, and satisfies a condition of B2O3/P2O5≧0.20 by mole ratio.
    Type: Grant
    Filed: November 29, 1999
    Date of Patent: October 30, 2001
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Takemi Kikutani
  • Patent number: 6306783
    Abstract: A tin borophosphate glass for use in sealing materials includes, by mole, 30 to 80% of SnO, 5 to 60% of B2O3, and 5 to 24% of P2O5 as main components. The glass is free of lead but is of equal quality to those of conventional lead-containing sealing glasses. The glass can provide a satisfactory sealing material.
    Type: Grant
    Filed: February 2, 2000
    Date of Patent: October 23, 2001
    Assignee: Nippon Electric Glass Co., Ltd.
    Inventor: Toshio Yamanaka
  • Patent number: 6194333
    Abstract: A dielectric composition for a plasma display panel that is capable of satisfying the required characteristics of a dielectric applied to an barrier rib and a dielectric layer of a plasma display panel. The dielectric composition includes a parent glass of P2O5—PbO—K2O group and an oxide filler. The dielectric has relatively low sintering temperature and dielectric constant, a high reflectivity and a reduced amount of PbO component, so that it can minimize an environment contamination and reduce a weight of the device.
    Type: Grant
    Filed: April 27, 1999
    Date of Patent: February 27, 2001
    Assignee: LG Electronics Inc.
    Inventor: Byung Gil Ryu
  • Patent number: 6156684
    Abstract: In a light polarization control element using a stress-optical coefficient glass, the stress-optical coefficient glass is substantially composed of a phosphorous acid glass containing 20 to 60 percent by weight of P.sub.2 O.sub.5 and 40 to 73 percent by weight of BaO and PbO.
    Type: Grant
    Filed: June 16, 1998
    Date of Patent: December 5, 2000
    Assignee: Hoya Corporation
    Inventors: Kouichi Sato, Kazuo Tachiwana
  • Patent number: 6153127
    Abstract: The present invention relates to an optical thin film containing titanium oxide, cerium oxide and bismuth oxide, wherein the content ratio of the titanium oxide, cerium oxide, and bismuth oxide is within the area expressed by four-cornered shape ABCD consisting of A (4,1,95), B (98,1,1), C (20,79,1), and D (3,14,83) in term of coordinate points (TiO.sub.2 mol percent, CeO.sub.2 mol percent, and Bi.sub.2 O.sub.3 mol percent) of the mol ratio when being converted to oxides of TiO.sub.2, CeO.sub.2, and Bi.sub.2 O.sub.3. Furthermore, with the invention, a comparatively high refractive index film layer and a comparatively low refractive index film layer are alternately laminated at least three layers on a transparent glass substrate, at least two layers of said three layers are high refractive index films, and at least one layer of said high refractive index films is said optical thin film.
    Type: Grant
    Filed: December 21, 1998
    Date of Patent: November 28, 2000
    Assignee: Nippon Sheet Glass Co., Ltd.
    Inventors: Koichiro Nakamura, Koichi Maeda