And Titanium, Zirconium, Vanadium, Tungsten, Or Molybdenum Patents (Class 501/46)
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Patent number: 6127297Abstract: In optical glass, P.sub.2 O.sub.5, TiO.sub.2, and Li.sub.2 O are included as essential components together with at least one divalent component, such as ZnO, MgO, and CaO. Such essential component are mixed together to accomplish a sag point not higher than 450.degree. C. and a specific gravity not heavier than 3.0. The optical glass also has water durability not greater than 0.3.Type: GrantFiled: May 13, 1997Date of Patent: October 3, 2000Assignee: Hoya CorporationInventor: Kazuaki Hashimoto
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Patent number: 6103648Abstract: A composition for a bulk conducting glass comprising P.sub.2 O.sub.5, V.sub.2 O.sub.5, PbO, and FeO, the ratio of the molar percentage of P.sub.2 O.sub.5 to V.sub.2 O.sub.5 being in the range of about 1 to about 6, and the P.sub.2 O.sub.5 and V.sub.2 O.sub.5 being present in an aggregate amount of at least about 50 mole percent, the PbO being present in the glass in an amount in excess of 15 mole percent, and the FeO being present in amount of about 0 to about 30 mole percent. The composition may also include MnO or Sb.sub.2 O.sub.3 in an amount of up to about 2 mole percent. The composition may be formed into fibers for use in microchannel plates and other devices where bulk conductivity in glass is advantageous.Type: GrantFiled: May 28, 1998Date of Patent: August 15, 2000Assignee: Circon CorporationInventor: Jay J. L. Yi
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Patent number: 5714244Abstract: A material is impregnated with an aqueous solution containing precursors of a glass-containing phosphate base modified at least by the presence of zinc oxide, then dried and heat treated to form an internal oxidation protection constituted by the modified phosphate glass-containing base. The precursors are introduced into the aqueous solution so as to form a glass-containing base in which the molar ratio between the glass modifying oxides, comprising zinc oxide, and the glass forming oxides, principally comprising or consisting of phosphoric anhydride, is sufficiently high, in particular at least 0.6, preferably 0.9, to confer a resistance to corrosion by moisture on the glass-containing phosphate base.Type: GrantFiled: November 30, 1995Date of Patent: February 3, 1998Assignee: Societe Europeenne de PropulsionInventors: Rodolphe Delaval, Gerard Palavit, Jacques Rey, Michel Laxague, Jacques Thebault
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Patent number: 5702995Abstract: There are provided glass-ceramics having a high lithium ion conductivity which include in mol %______________________________________ P.sub.2 O.sub.5 38-40% TiO.sub.2 25-45% M.sub.2 O.sub.3 (where M is Al or Ga) 5-15% Li.sub.2 O 10-20% ______________________________________and contain Li.sub.1+X (Al, Ga).sub.X Ti.sub.2-X (PO.sub.4).sub.3 (where X is 0 to 0.8) as a main crystal phases. There are also provided glass-ceramics having a high lithium ion conductivity which include in mol % ______________________________________ P.sub.2 O.sub.5 26-40% SiO.sub.2 0.5-12% TiO.sub.2 30-45% M.sub.2 O.sub.3 (where M is Al or Ga) 5-10% Li.sub.2 O 10-18% ______________________________________and contain Li.sub.1+X+Y M.sub.X Ti.sub.2-X Si.sub.Y P.sub.3-Y O.sub.12 (where 0<X.ltoreq.0.4 and 0<Y.ltoreq.0.6) as a main crystal phase.Type: GrantFiled: October 31, 1996Date of Patent: December 30, 1997Assignee: Kabushiki Kaisha OharaInventor: Jie Fu
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Patent number: 5529961Abstract: The subject invention is directed at glasses wherein either a portion of the ZnO or alkali metals, or both, is replaced by Cu.sub.2 O, i.e., monovalent copper. Specifically, the present invention is directed at a glass consisting essentially of, expressed in terms of mole percent on the oxide basis, 28-42% P.sub.2 O.sub.5, 15-30% Cu.sub.2 O, 10-30% R.sub.2 O, wherein R.sub.2 O is selected from the group consisting of 0-15% Li.sub.2 O, 0-20% Na.sub.2 O, and 0-10% K.sub.2 O, and up to a total of 45% of optional ingredients in the indicated proportions selected from the group consisting of 0-10% Al.sub.2 O.sub.3, 0-15% MgO, 0-20% CaO, 0-20% SrO, 0-20% BaO, 0-25% MgO+CaO+SrO+BaO, 0-35% ZnO, 0-10% MnO, 0-2% CeO.sub.2, 0-2% Ln.sub.2 O.sub.3, 0-10 Al.sub.2 O.sub.3 0-10% B.sub.2 O.sub.3, 0-10 Fe.sub.2 O.sub.3 0-10% Al.sub.2 O.sub.3 +B.sub.2 O.sub.3 +Fe.sub.2 O.sub.3, 0-7% MoO.sub.3 0-7% WO.sub.3 0-7% MoO.sub.3 +WO.sub.3, and 0-8% F, the latter as analyzed in weight percent.Type: GrantFiled: December 30, 1994Date of Patent: June 25, 1996Assignee: Corning IncorporatedInventors: Bruce G. Aitken, George H. Beall, James E. Dickinson, Jr.
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Patent number: 5529960Abstract: The subject invention is directed at wherein either a portion of the ZnO or alkali metals, or both, found in prior art glasses, is replaced by Cu.sub.2 O, i.e., cuprous or monovalent copper. In addition to the Cu.sub.2 O substitution, the inventive glass contains a required metal oxide constituent which is necessary to enhance durability. More specifically, the present invention discloses a glass consisting essentially of, expressed in terms of mole percent on the oxide basis, of about 42-54% P.sub.2 O.sub.5, 10-30% Cu.sub.2 O, 10-30% R.sub. O and 3-12% of a component selected from the group consisting of 0-7% MoO.sub.3, 0-10 Fe.sub.2 O.sub.3, 0-10% Al.sub.2 O.sub.3 and 0-7%WO.sub.3. In addition, the composition includes up to a total of 45% of optional ingredients in the indicated proportions selected from the group consisting of 0-15% MgO, 0-20% CaO, 0-20% SrO, 0-20% BaO, 0-25% MgO+CaO+SrO+BaO, 0-35% ZnO, 0-10% MnO, 0-2% CeO.sub.2, 0-10% B.sub.2 O.sub.3, 0-2% Ln.sub.2 O.sub.Type: GrantFiled: December 30, 1994Date of Patent: June 25, 1996Assignee: Corning IncorporatedInventors: Bruce G. Aitken, George H. Beall, James E. Dickinson, Jr.
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Patent number: 5336644Abstract: A sealing glass composition suitable for bonding ceramic surfaces at low temperatures and which includes in weight percent 5-50% thallium oxide, 10-40% vanadium oxide, 5-30% tellurium oxide, 1.5-15% arsenic oxide and 1-5% phosphorous oxide. Other additives may be included, such as bismuth oxide. A paste formulated from said glass and a filler for the purpose of adjusting the fluidity and/or dielectric constant of the paste.Type: GrantFiled: July 9, 1993Date of Patent: August 9, 1994Assignee: Johnson Matthey Inc.Inventors: Masyood Akhtar, Kim C. Le, Jess Pedigo, Charles H. Smith
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Patent number: 5330940Abstract: This invention relates to a fiberizable glass compositions consisting essentially, expressed in terms of mole percent on the oxide basis, of at least 65% total of 5-55% ZnO, 28-40% P.sub.2 O.sub.5, 0.3-5% MoO.sub.3 and 10-35% R.sub.2 O, wherein R.sub.2 O consists of at least two alkali metal oxides in the indicated proportions selected from the group consisting of 0-25% Li.sub.2 O, 0-25% Na.sub.2 O, and 0-25% K.sub.2 O, and up to 35% total of optional ingredients in the indicated proportions selected from the group consisting of 0-10% Al.sub.2 O.sub.3, 0-15% B.sub.2 O.sub.3, 0-15% Al.sub.2 O.sub.3 +B.sub.2 O.sub.3, 0-15% Cu.sub.2 O, 0-25% Sb.sub.2 O.sub.3 0-5% F, 0-35% PbO, 0-35% SnO, 0-35% PbO+SnO, 0-5% ZrO.sub.2, 0-4% SiO.sub.2, 0-20% MgO+CaO+SrO+BaO+MnO, 0-20% MgO, 0-20% CaO, 0-20% SrO, 0-20% BaO and 0-10% MnO, and 0-5% rare earth metal oxide.Type: GrantFiled: July 6, 1992Date of Patent: July 19, 1994Assignee: Corning IncorporatedInventors: Bruce G. Aitken, George H. Beall, Candace J. Quinn
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Patent number: 5328874Abstract: This invention relates to the preparation of a glass exhibiting a transition temperature normally below about 300.degree., a working temperature below about 400.degree., while, at the same time, exhibiting excellent resistance to attack by water. Specifically, the present invention discloses a glass consisting essentially in terms of mole percent on the oxide basis, of 15-35% P.sub.2 O.sub.5, 1-25% SO.sub.3, 30-55% ZnO, 0-25% R.sub.2 O, wherein R.sub.2 O is selected from the group consisting of 0-25% Li.sub.2 O, 0-25% Na.sub.2 O, and 0-25% K.sub.2 O, and up to a total of 15% of optional ingredients in the indicated proportions selected from the group consisting of 0-10% Al.sub.2 O.sub.3, 0-10% MgO, 0-10% CaO, 0-10% SrO, 0-10% BaO, 0-10% MnO, 0-10% transition metal oxides and 0-15% Cl+F, as analyzed in weight percent.Type: GrantFiled: October 18, 1993Date of Patent: July 12, 1994Assignee: Corning IncorporatedInventors: George H. Beall, Joseph E. Pierson
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Patent number: 5286683Abstract: This invention is directed to the production of glasses exhibiting transition temperatures below 375.degree. C., preferably below 350.degree. C., and superior resistance to attack by boiling water. The glasses contain at least 10% copper, as expressed in terms of CuO, the predominant proportion of the copper being present in the Cu.sup.+2 oxidation state. The glasses consist essentially, in mole percent, of______________________________________ Li.sub.2 O 0-15 MgO 0-15 B.sub.2 O.sub.3 0-5 Na.sub.2 O 0-20 CaO 0-20 ZnO 0-37 K.sub.2 O 0-10 SrO 0-20 Sb.sub.2 O.sub.3 0-36 Tl.sub.2 O 0-15 BaO 0-20 CeO.sub.2 0-3 Li.sub.2 O + Na.sub.2 O + 12-30 MgO + 0-25 MoO.sub.3 0-7 K.sub.2 O + Tl.sub.2 O CaO + SrO + BaO CuO 10-50 Al.sub.2 O.sub.3 + B.sub.2 O.sub.3 0-5 RE.sub.2 O.sub.3 0-2 P.sub.2 O.sub.5 28-36 Al.sub.2 O.sub.3 0-5 WO.sub.3 0-7 MnO 0-20 ______________________________________wherein at least two alkali metal oxides are present and up to 12% by weight fluoride may optionally be present.Type: GrantFiled: November 5, 1992Date of Patent: February 15, 1994Assignee: Corning IncorporatedInventor: Bruce G. Aitken
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Patent number: 5281560Abstract: Lead-free, tin phosphate glasses contain 25-50 mole percent P.sub.2 O.sub.5, 30-70% SnO, 0-15% ZnO, the mole ratio of SnO:ZnO being greater than 5:1, and an effective amount up to 25% total of at least one oxide in the indicated proportion selected from the group consisting of up to 25% R.sub.2 O, wherein R.sub.2 O consists of 0-25% Li.sub.2 O, 0-25% Na.sub.2 O, and 0-25% K.sub.2 O, up to 20% B.sub.2 O.sub.3, up to 5% Al.sub.2 O.sub.3, up to 5% SiO.sub.2, and up to 5% WO.sub.3. The glasses are particularly useful as sealing glass frits in sealing material to join component parts in electrical and electronic devices. The sealing glass material may contain mill additions to reduce the effective coefficient of thermal expansion in a seal, as well as a strength reinforcing additive having a coefficient of thermal expansion preferably below 120.times.10.sup.-7 /.degree.C.Type: GrantFiled: June 21, 1993Date of Patent: January 25, 1994Assignee: Corning IncorporatedInventors: Gaylord L. Francis, Robert Morena
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Patent number: 5246890Abstract: Lead-free, SnO-ZnO-P.sub.2 O.sub.5 glasses contain 25-50 mole percent P.sub.2 O.sub.5 and SnO and ZnO in amounts such that the mole ratio of SnO:ZnO is in the range of 1:1 to 5:1. Optionally, the glasses may contain up to 20 mole percent of modifying oxides including up to 5 mole percent SiO.sub.2, up to 20 mole percent B.sub.2 O.sub.3 and up to 5 mole percent Al.sub.2 O.sub.3, as well as one or more crystallization promoters selected from 1-5 mole percent zircon and/or zirconia and 1-15 mole percent R.sub.2 O. The glasses are particularly useful as sealing glass frits in sealing material to join component parts in articles such as cathode ray tubes. The sealing glass material may contain mill additions to reduce the effective coefficient of thermal expansion in a seal.Type: GrantFiled: August 3, 1992Date of Patent: September 21, 1993Assignee: Corning IncorporatedInventors: Bruce G. Aitken, Dana C. Bookbinder, Margaret E. Greene, Robert M. Morena
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Patent number: 5246892Abstract: Faraday rotation glass having a practically sufficiently large Verdet's constant, which contains 60 to 75 mol % of P.sub.2 O.sub.5, 10 to 20 mol % of Tb.sub.2 O.sub.3 and 10 to 25 mol % of K.sub.2 O and having substantially no platinum inclusion.Type: GrantFiled: June 22, 1992Date of Patent: September 21, 1993Assignee: Hoya CorporationInventors: Hiroaki Yanagita, Hisayoshi Toratani, Tomoko Kasuga
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Patent number: 5234871Abstract: The invention relates to a glass consisting essentially of______________________________________ P.sub.2 O.sub.5 43-59 SiO.sub.2 0-9 Al.sub.2 O.sub.3 7-11 Li.sub.2 O 0-15 Na.sub.2 O 0-15 K.sub.2 O 0-15 MgO 0-15 CaO 0-0.5 BaO 0-7 ZnO 0-7 CeO.sub.2 0-0.5 CuO 7-21 V.sub.2 O.sub.5 0.07-0.7 Pr.sub.6 O.sub.11 0-1.5 Nd.sub.2 O.sub.3 0-1.5 Nb.sub.2 O.sub.5 0-3 B.sub.2 O.sub.3 0-3 Y.sub.2 O.sub.3 0-3 Cr.sub.2 O.sub.3 0-1 ______________________________________having a photopic transmission of at least 10% at full rated voltage and a color space of NVIS Green A or B. The glass is useful in the production of optical filters for use with light sources in order to render said sources compatible with night vision imaging systems.Type: GrantFiled: November 27, 1991Date of Patent: August 10, 1993Assignee: Schott Glass Technologies, Inc.Inventor: David G. Krashkevich
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Patent number: 5217818Abstract: A substrate material for a magnetic head, which comprises an oxide composed mainly of WO.sub.3 and has a thermal expansion coefficient of 100 to 130.times.10.sup.-7 /.degree. C., and a magnetic head using the substrate material.Type: GrantFiled: March 15, 1990Date of Patent: June 8, 1993Assignee: Matsushita Electric Industrial Co., Ltd.Inventors: Mitsuo Satomi, Ken Hirota, Koichi Kugimiya
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Patent number: 5196381Abstract: A low-K crystallizable glass composition having a softening point of 550.degree.-800.degree. C., consisting essentially of mole % of:41-70% P.sub.2 O.sub.5 ;10-48% MgO, ZnO or mixtures thereof;2-20% Al.sub.2 O.sub.3, Cr.sub.2 O.sub.3 or mixtures thereof;0-10% alkali metal oxide(s);0-10% CaO, SrO, BaO or mixtures thereof;0-10% SiO.sub.2 ;0-20% B.sub.2 O.sub.3 ;0-10% ZrO.sub.2, TiO.sub.2 or mixtures thereof; and0-10% Fe.sub.2 O.sub.3, with the provisos that:(i) a=n(b+3c+d+e+2f+3g), wherein n=0.8-1.0, anda=mole % P.sub.2 O.sub.5 ;b=mole % MgO, ZnO or mixtures thereof;c=mole % Al.sub.2 O.sub.3, Cr.sub.2 O.sub.3 or mixtures thereof;d=mole % M.sub.2 O, where M=Na, K, Rb, Cse=mole % M'O, where M'=Ca, Sr, Baf=mole % ZrO.sub.2, TiO.sub.2 or mixtures thereof;g=mole % Fe.sub.2 O.sub.3, (where Ln is any of the rare earth elements), or mixtures thereof;(ii) the total amount of alkali oxides, CaO, SrO, and BaO does not exceed 10 mole %;(iii) the total amount of ZrO.sub.2, TiO.sub.2, and Fe.sub.2 O.sub.Type: GrantFiled: January 16, 1990Date of Patent: March 23, 1993Assignee: E. I. Du Pont de Nemours and CompanyInventors: Yung-Haw Hu, Michael A. Saltzberg, Robert D. Shannon
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Patent number: 5188990Abstract: Low temperature sealing glass compositions comprising 35 to 80% by weight TeO.sub.2, 15 to 50% V.sub.2 O.sub.5 and 0.1 to 20% Nb.sub.2 O.sub.5, ZrO.sub.2 and/or ZnO.Type: GrantFiled: November 21, 1991Date of Patent: February 23, 1993Assignee: VLSI Packaging MaterialsInventors: Maurice E. Dumesnil, Leo Finkelstein
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Patent number: 5179046Abstract: A fusion sealing material containing a mill addition, a sealing tape cast from the material, and a method of producing the tape. The material is composed of a low temperature glass, a mill addition that lowers the effective coefficient of thermal expansion of the glass in a seal and an organic medium. The sealing tape is prepared by hot mixing the solids with a liquefied medium, such as a high melting alcohol, and casting the hot mix onto a cold sheet to immediately solidify the medium.Type: GrantFiled: October 7, 1991Date of Patent: January 12, 1993Assignee: Corning IncorporatedInventors: Gaylord L. Francis, Ronald E. Johnson
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Patent number: 5164343Abstract: Ion-exchangeable phosphate glass compositions containing in mole percent from about 50 to 70% P.sub.2 O.sub.5, from about 5 to 30% Li.sub.2 O, from about 5 to 25% MO, where M is selected from the group consisting of Be, Mg, Ca, Sr, Ba, and Zn, and about 5 to 30% X.sub.2 O.sub.3, where X is selected from the group consisting of Al, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu are provided. In another aspect, the phosphate glass compositions of the present invention also contain in mole percent up to 10% R.sub.2 O, where R is selected from the group consisting of Na, K, Rb and Cs. Solarization inhibitors and minor amounts of anhydrous fluorides and chlorides are also included in some embodiments. Optical quality phosphate glass articles formed of the phosphate glass compositions of the present invention are readily ion- exchangeable when contacted with certain salts. Optical quality phosphate glass articles are also provided having good thermal shock resistance.Type: GrantFiled: May 22, 1991Date of Patent: November 17, 1992Assignee: Kigre, Inc.Inventor: John D. Myers
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Patent number: 5122484Abstract: This invention relates to a glass exhibiting a transistion temperature no higher than 425.degree. C. and excellent resistance to attack by water consisting essentially, expressed in terms of weight percent on the oxide basis, of about:______________________________________ P.sub.2 O.sub.5 38-50 MoO.sub.3 0-10 Al.sub.2 O.sub.3 0-5 WO.sub.3 0-10 Na.sub.2 O 2-10 MoO.sub.3 + WO.sub.3 2-15 Li.sub.2 O 0.75-5 SnO.sub.2 0-10 K.sub.2 O 2-10 Cl 0-8 (analyzed) Na.sub.2 O + Li.sub.2 O + 5-25 Sn.sub.2 O + MoO.sub.3 + 2-25 K.sub.2 O WO.sub.3 + Cl ZnO 28-40 ______________________________________and being essentially free of PbO.Type: GrantFiled: May 23, 1991Date of Patent: June 16, 1992Assignee: Corning IncorporatedInventors: George H. Beall, James E. Dickinson, Jr., Robert M. Morena
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Patent number: 5084421Abstract: An improved sliver-glass paste for bonding a semiconductive element to a substrate comprising silver flake, glass frit, a surfactant, a thixotrope and a low boiling paraffinic hydrocarbon solvent.Type: GrantFiled: July 27, 1990Date of Patent: January 28, 1992Assignee: Johnson Matthey, Inc.Inventor: Thomas L. Herrington
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Patent number: 5076876Abstract: A stable Tl.sub.2 O.sub.3, V.sub.2 O.sub.5, P.sub.2 O.sub.5 glass composition for a die attach paste requiring no resin and having a glassy edge temperature of below about 350.degree. C.Type: GrantFiled: February 21, 1990Date of Patent: December 31, 1991Assignee: Diemat, Inc.Inventor: Raymond L. Dietz
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Patent number: 5075262Abstract: An improved silver-glass paste for bonding a semiconductive element to a substrate comprising a metal resinate. A surfactant containing lyophilic and lyophobic groups may also be included.Type: GrantFiled: February 21, 1990Date of Patent: December 24, 1991Assignee: Johnson Matthey, Inc.Inventors: My N. Nguyen, Mark A. Blocker
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Patent number: 5066621Abstract: Described is a sealing glass composition comprising, in wt. %, 13-50% lead oxide, 20-50% vanadium oxide, 2-40% tellurium oxide, up to 40% selenium oxide, up to 10% phosphorous oxide, up to 5% niobium oxide, up to 20% bismuth oxide, up to 5% copper oxide and up to 10% boron oxide and an electrically conductive formulation comprising, in wt. %, 50-77% silver, 8-34% of a sealing glass composition as described previously, 0.2-1.5% resin and thixotrope and 10-20% organic solvent.Type: GrantFiled: June 21, 1990Date of Patent: November 19, 1991Assignee: Johnson Matthey Inc.Inventor: Masyood Akhtar
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Patent number: 5053360Abstract: Ion-exchangeable phosphate glass compositions containing in mole percent from about 50 to 70% P.sub.2 O.sub.5, from about 5 to 30% Li.sub.2 O, from about 5 to 25% MO, where M is selected from the group consisting of Be, Mg, Ca, Sr, Ba, and Zn, and about 5 to 30% X.sub.2 O.sub.3, where X is selected from the group consisting of Al, Y, La, Ce, Pr, Nd, Pm, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm, Yb and Lu are provided. In another aspect, the phosphate glass compositions of the present invention also contain in mole percent up to 10% R.sub.2 O, where R is selected from the group consisting of Na, K, Rb and Cs. Solarization inhibitors and minor amounts of anhydrous fluorides and chlorides are also included in some embodiments. Optical quality phosphate glass articles formed of the phosphate glass compositions of the present invention are readily ion-exchangeable when contacted with certain salts. Optical quality phosphate glass articles are also provided having good thermal shock resistance.Type: GrantFiled: June 29, 1989Date of Patent: October 1, 1991Assignee: Kigre, Inc.Inventor: John D. Myers
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Patent number: 5039631Abstract: A strengthened high lanthanide-containing glass has the composition of, in mole percent______________________________________ SiO.sub.2 54-75 B.sub.2 O.sub.3 5-17 Li.sub.2 O 0-4 Na.sub.2 O 3-18 K.sub.2 O 0-4 Al.sub.2 O.sub.3 0-7 PbO 0-4 MgO 0-3 CaO 0-3 SrO 0-3 BaO 0-3 ZnO 0.1-10 TiO.sub.2 0-5 Ln.sub.2 O.sub.3 3-7 V.sub.2 O.sub.5 + Cr.sub.2 O.sub.3 + Mn.sub.2 O.sub.3 0-5 Fe.sub.2 O.sub.3 + CoO + NiO + CuO As.sub.2 O.sub.3 /Sb.sub.2 O.sub.3 0-0.4 ______________________________________wherein Ln is La, Ce, Pr, Sm, Eu, Gd, Tb, Dy, Ho, Er, Tm and/or Yb.Type: GrantFiled: January 11, 1990Date of Patent: August 13, 1991Assignee: Schott Glass Technologies, Inc.Inventors: David Krashkevich, Yuiko T. Hayden
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Patent number: 5013360Abstract: Fluid, stable glasses useful for low-temperature sealing applications are made by adding jointly bismuth oxide, zinc oxide, phosphorus pentoxide, titania and/or zirconium oxide to the lead oxide vanadium oxide binary. The phosphorus pentoxide may be replaced partially or entirely with niobium pentoxide and/or tantalum oxide.Sealing glass compositions comprising these low-melting lead-vanadia glasses in powder form and refractory fillers of lower thermal expansion for use in hermetically sealing semiconductor devices in ceramic packages are disclosed. Group V metal oxides, particularly niobium-containing oxides, are preferred fillers. Silver metal is a preferred filler for making die-attach compositions.Type: GrantFiled: September 15, 1989Date of Patent: May 7, 1991Assignee: VLSI Packaging Materials, Inc.Inventors: Leo Finkelstein, Maurice E. Dumesnil, Richard R. Tetschlag
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Patent number: 5013697Abstract: A sealing glass composition comprising, in wt. %, 30-70% lead oxide, 30-60% vanadium oxide, 1-10% phosphorous oxide, 0-30% bismuth oxide, 0.5 to 5% niobium oxide, and 1-15% of at least one oxide from the group consisting of tellurium oxide and selenium oxide.Type: GrantFiled: June 21, 1990Date of Patent: May 7, 1991Assignee: Johnson Matthey Inc.Inventor: Masyood Akhtar
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Patent number: 4996171Abstract: Silver-filled glass pastes useful for the attachment of silicon semi-conductor devices (dies) to substrates comprise particulate silver and a lead phosphate glass, together with conventional organic components. The pastes have low bonding temperatures, and give good adhesion at firing temperatures of 350.degree. to 460.degree. C.Type: GrantFiled: December 22, 1988Date of Patent: February 26, 1991Assignee: Johnson Matthey Public Limited CompanyInventors: Nigel M. Davey, Gordon G. Ferrier
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Patent number: 4943541Abstract: Glass ceramics used as dental material, artifical bone, etc. which contain 0.01 to 25 parts by weight of alkali metal oxides (R.sub.2 O), such as Li.sub.2 O, Na.sub.2 O, K.sub.2 O, Rb.sub.2 O, and Cs.sub.2 O, in 100 parts by weight of CaO-Al.sub.2 O.sub.3 -P.sub.2 O.sub.5 system material. During the casting for obtaining the glass ceramics, the molten fluid is sufficiently distributed to the fine corners of a mold, and the temperature for crystallization is low. Also, the time required for the crystallization is short and the crystalline formed shows no internal defects, and has high bending strength.Type: GrantFiled: May 13, 1988Date of Patent: July 24, 1990Assignee: Kyushu Refractories Co., Ltd.Inventors: Akira Watanabe, Yoshimitsu Takeuchi, Seiji Kihara, Makoto Mitsudo
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Patent number: 4933030Abstract: A stable Tl.sub.2 O.sub.3, V.sub.2 O.sub.5, P.sub.2 O.sub.5 glass composition for a die attach paste requiring no resin and having a glassy edge temperature of below about 350.degree. C.Type: GrantFiled: June 21, 1989Date of Patent: June 12, 1990Inventor: Raymond L. Dietz
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Patent number: 4920081Abstract: This invention relates to the preparation of glasses exhibiting low transition temperatures with excellent chemical durability. The glasses consist essentially, in mole %, of:______________________________________ P.sub.2 O.sub.5 44-58 Al.sub.2 O.sub.3 + 4-10 Na.sub.2 O + Li.sub.2 O 10-45 B.sub.2 O.sub.3 Al.sub.2 O.sub.3 0-7 Na.sub.2 O 10-30 Cu.sub.2 O 0-20 B.sub.2 O.sub.3 0-10 Li.sub.2 O 0-30 Li.sub.2 O + Cu.sub.Type: GrantFiled: October 17, 1988Date of Patent: April 24, 1990Assignee: Corning IncorporatedInventors: George H. Beall, Candace J. Quinn
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Patent number: 4874724Abstract: This invention is directed to the production of glass-ceramic articles exhibiting an apparent annealing point in excess of 400.degree. C. and excellent resistance to moisture attack, the articles consisting essentially, in mole percent, of:______________________________________ Li.sub.2 O 5-25 ZnO 35-50 Na.sub.2 O 0-15 Al.sub.2 O.sub.3 0.75-6 K.sub.2 O 0-10 P.sub.2 O.sub.5 29-37. Li.sub.2 O + Na.sub.2 O + K.sub.Type: GrantFiled: October 17, 1988Date of Patent: October 17, 1989Assignee: Corning IncorporatedInventors: George H. Beall, Joseph E. Pierson, Candace J. Quinn
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Patent number: 4826536Abstract: The invention relates to a structured kaolinitic pigment having improved physical and optical characteristics when incorporated as a filler or coating pigment in paper. The pigment consists of porous aggregates of kaolin particles which are chemically bonded together. The pigment may be produced by chemically reacting a particulate kaolin with a metal chloride, such as silicon tetrachloride, and with urea or an organic amine. The process is conducted under conditions such that the kaolinite structure is not altered.Type: GrantFiled: January 9, 1987Date of Patent: May 2, 1989Assignee: E.C.C America Inc.Inventors: Rasik H. Raythatha, E. Wayne Andrews
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Patent number: 4748137Abstract: This invention is directed to the production of essentially lead-free glass compositions demonstrating softening points below 500.degree. C. and coefficients of thermal expansion somewhat below 88.times.10.sup.-7 /.degree.C. The glasses consist essentially, in weight percent on the oxide basis, of______________________________________ Li.sub.2 O 1-4 Na.sub.2 O + K.sub.2 O 0-12 ZnO 20-30 CaO 0-7 B.sub.2 O.sub.3 32-42 SrO 0-10 Al.sub.2 O.sub.3 2-5 BaO 0-15 ZrO.sub.2 2-6 CaO + SrO + BaO 0-15 P.sub.2 O.sub.5 6-10 V.sub.2 O.sub.5 0-22 Na.sub.2 O 0-8 Bi.sub.2 O.sub.3 0-16 K.sub.2 O 0-8.40 V.sub.2 O.sub.5 + Bi.sub.2 O.sub.3 5-25 ______________________________________wherein a minimum of 5% V.sub.2 O.sub.5 +Bi.sub.2 O.sub.3 is required in the presence of a least 2% Na.sub.2 O or 5% K.sub.2 O, and a minimum of 9% V.sub.2 O.sub.5 +Bi.sub.2 O.sub.3 is required in the essential absence of Na.sub.2 O or K.sub.2 O, but in the presence of at least 3% CaO or 6% SrO or 9% BaO.Type: GrantFiled: May 20, 1987Date of Patent: May 31, 1988Assignee: Corning Glass WorksInventor: Jaroslava M. Nigrin
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Patent number: 4743302Abstract: Fluid, stable glasses that are useful for low temperature sealing applications are made by adding jointly bismuth oxide, zinc oxide, and phosphorus pentoxide to the lead oxide-vanadium oxide binary. The phosphorous pentoxide may be replaced partially or entirely with niobium pentoxide and/or tantalum pentoxide. Additives and fillers may be incorporated into the glass composition to enhance the fluidity or adhesive characteristics of the glass, alter its coefficient of linear thermal expansion or make it suitable for die attach application. Group V metal oxides, particularly niobium pentoxide, are preferred fillers for altering the coefficient of linear thermal expansion. Similarly these Group V metal oxides may also be added as particulate fillers to lead borate, lead borosilicate and zinc borate glasses. Silver metal is a preferred filler for making die attach compositions.Type: GrantFiled: January 20, 1987Date of Patent: May 10, 1988Assignee: VLSI Packaging Materials, Inc.Inventors: Maurice E. Dumesnil, Leo Finkelstein
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Patent number: 4741849Abstract: The glass composition is particularly applicable for ferrite constituents used for a highly efficient magnetic head. The composition essentially consists of (a) 55-70 wt % of V.sub.2 O.sub.5, (b) 18-wt % of P.sub.2 O.sub.5, (c1) up to 10 wt % of at least one alkaline metal oxide selected from Na.sub.2 O, K.sub.2 O, Rb.sub.2 O, and Cs.sub.2 O and (c3) up to 10 wt % of Tl.sub.2 O. The composition is in a non-crystalline state during reheating and has a softening temperature of 310.degree. C.-400.degree. C. and a thermal expansion coefficient of 70-130.times.10.sup.-7 /.degree.C.Type: GrantFiled: January 12, 1987Date of Patent: May 3, 1988Assignee: Hitachi, Ltd.Inventors: Takashi Naito, Takashi Namekawa, Satoru Ogihara
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Patent number: 4698318Abstract: A phosphate glass ceramic which can be utilized especially as biomaterial in medicine and biology. The object of the invention is to provide a glass ceramic extensively adapted to bone, possessing adjustable biologically active characteristics. Another object of the invention is to produce a glass ceramic free of SiO.sub.2 or low in SiO.sub.2, of high P.sub.2 O.sub.5 and CaO content, possessing adjustable biologically active characteristics. The object is solved, whereby an initial glass of the composition having the mass percentages of Al.sub.2 O.sub.3 3-21, CaO 8-26, R.sub.2 O 10-25, P.sub.2 O.sub.5 43-58, is provided under the condition that R.sub.2 O can contain up to 25% of mass of Na.sub.2 O and up to 18% of mass of K.sub.2 O, and is thermally treated after melting, to provide the new phosphate glass ceramic. The main crystal phases are apatite and aluminiumorthophosphate. The phosphate glass ceramic can contain additions of SiO.sub.2, B.sub.2 O.sub.3, F.sup.-, MgO, FeO, Fe.sub.2 O.sub.3, TiO.sub.2.Type: GrantFiled: November 1, 1984Date of Patent: October 6, 1987Assignee: VEB Jenaer GlaswerkInventors: Jurgen Vogel, Wolfram Holand, Werner Vogel
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Patent number: 4626514Abstract: Dental materials using calcium phosphate glass-ceramics and having the color tone with high approximation to that of natural teeth. In those dental materials, calcium phosphate composite, nickel oxide and one or more other type of compounds selected from oxides of iron, manganese, cerium, titanium and tungsten, are contained as coloring component. Also, if necessary, Al.sub.2 O.sub.3 and/or SiO.sub.2 is contained as a color assisting agent in that composite. The calcium phosphate glass-ceramic according to this invention consists of the same components as that of natural teeth. Besides, it is possible to adjust the color tone delicately to match with the color tone of each individual`s teeth. Moreover, the coloring components are incorporated in crystals of calcium phosphate. Consequently, they cause no elution during use and are therefore ideal as dental material.Type: GrantFiled: March 27, 1986Date of Patent: December 2, 1986Assignee: Kyushu Refractories Co., Ltd.Inventors: Akira Watanabe, Yoshimitsu Takeuchi, Hiroyasu Tokuda, Seiji Kihara, Yasuhiro Makino, Keiji Kamegawa
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Patent number: 4612295Abstract: A glass for an eye glass lens comprising a SiO.sub.2 (or B.sub.2 O.sub.3)-CaO-Nb.sub.2 O.sub.5 system as a basic system and having a refractive index of 1.79 or more, an Abbe number of 32 to 38 and a specific gravity of less than 3.6 is disclosed.Type: GrantFiled: April 26, 1984Date of Patent: September 16, 1986Assignee: Hoya CorporationInventor: Hiroji Sagara
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Patent number: 4544695Abstract: A polymeric flame retardant composition comprises low melting temperature phosphate-sulfate glass compositions in an amount of from about 10 to about 100 parts by weight per 100 parts by weight of said polymer. Desirably, the polymer is a halogen-containing polymer. The phosphate-sulfate combination has been found to produce synergistic results.Type: GrantFiled: September 13, 1984Date of Patent: October 1, 1985Assignee: The B. F. Goodrich CompanyInventor: Ronald E. Myers
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Patent number: 4476233Abstract: A phosphate optical glass comprises P.sub.2 O.sub.5 of 40-55 weight percents, R.sub.2 O of 20-40 weight percents (wherein R is an alkali metal or a mixture of alkali metals selected from the group consisting of Li, Na and K), TiO.sub.2 of 8-20 weight percents, WO.sub.3 of 1-12 weight percents (providing that the WO.sub.3 content be less than TiO.sub.2), As.sub.2 O.sub.3 of 0.1-4 weight percents, MgO of 0-7, CaO of 0-11, BaO of 0-12, ZnO of 0-12 PbO of 0-18, Nb.sub.2 O.sub.5 of 0-20, Ta.sub.2 O.sub.5 of 0-10, SiO.sub.2 of 0-3, ZrO.sub.2 of 0-3, La.sub.2 O.sub.3 of 0-3, Y.sub.2 O.sub.3 of 0-3 and F of 0-5.Type: GrantFiled: September 12, 1983Date of Patent: October 9, 1984Assignee: Nippon Kogaku K.K.Inventor: Hiroyuki Kodama
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Patent number: 4455384Abstract: The chemical durability of alkali phosphate glasses is improved by incorporation of up to 23 weight percent of nitrogen. A typical phosphate glass contains: 10 to 60 mole % of Li.sub.2 O, Na.sub.2 O or K.sub.2 O; 5-40 mole % of BaO or CAO; 0-1 to 10 mole % of Al.sub.2 O.sub.3 ; and 40-70 mole % of P.sub.2 O.sub.5. Nitrides, such as AlN, are the favored additives.Type: GrantFiled: December 8, 1982Date of Patent: June 19, 1984Assignee: The United States of America as represented by the United States Department of EnergyInventors: Delbert E. Day, James A. Wilder, Jr.
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Patent number: 4439530Abstract: An optical glass comprising, in % by weight,18 to 38% P.sub.2 O.sub.5 ;3 to 30% Na.sub.2 O+K.sub.2 O,with the proviso of0 to 30% Na.sub.2 O and0 to 30% K.sub.2 O;8 to 65% PbO;1 to 45% Ta.sub.2 O.sub.5 ;0 to 20% Nb.sub.2 O.sub.5 ;0 to 15% TiO.sub.2 +WO.sub.3 ;0 to 25% BaO+CaO+ZnO+SrO+MgO,with the proviso of0 to 25% BaO,0 to 5% CaO,0 to 25% ZnO,0 to 20% SrO, and0 to 10% MgO;0 to 15% B.sub.2 O.sub.3 ;0 to 3% Li.sub.2 O;0 to 3% Al.sub.2 O.sub.3 ;0 to 3% ZrO.sub.2 ;0 to 3% Y.sub.2 O.sub.3 ;0 to 3% Gd.sub.2 O.sub.3 ; and0 to 3% La.sub.2 O.sub.3.Type: GrantFiled: January 20, 1983Date of Patent: March 27, 1984Assignee: Hoya CorporationInventor: Hidemi Tajima
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Patent number: 4391915Abstract: Optical components can be pressed with such a precision that grinding and polishing of the formed components is not necessary, from glasses containing 45-55 wt. % P.sub.2 O.sub.5, 3.5-9 wt. % Al.sub.2 O.sub.3, 5-20 wt. % K.sub.2 O, 0-3 wt. % Li.sub.2 O, 8-15% BaO, 4.5-9 wt. % ZnO, 0-6 wt. % MgO, 0-18 wt. % PbO, 0-1 wt. % SiO.sub.2, 0-3 wt. % B.sub.2 O.sub.3, 0-2 wt. % TiO.sub.2.Type: GrantFiled: December 7, 1981Date of Patent: July 5, 1983Assignee: U.S. Philips CorporationInventors: Gertraud A. A. Meden-Piesslinger, Johannes H. P. Van de Heuvel
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Patent number: 4366253Abstract: Phosphate glass compositions are described comprising from 8 to 35 wt % P.sub.2 O.sub.5, from 8 to 48 wt % SiO.sub.2 and GeO.sub.2, provided that the GeO content is not more than 6 wt %, from 3 to 18 wt % B.sub.2 O.sub.3, from 16 to 28 wt % Al.sub.2 O.sub.3, and from 8 to 33 wt % CaO, MgO, SrO, and BaO, provided that the sum of the MgO, SrO, and BaO contents is not more than 15 wt %, andwherein the sum of the above-described oxides comprises at least 88 wt % of the total composition and the ratio of the sum of the CaO, MgO, SrO and BaO contents to the P.sub.2 O.sub.5 content ranges from 0.6/1 to 1.Type: GrantFiled: August 11, 1980Date of Patent: December 28, 1982Assignee: Fuji Photo Film Co., Ltd.Inventor: Motohiko Yagi
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Patent number: 4342943Abstract: A glass composition is disclosed that is useful as a solder glass for sealing components together. However, the glass is also especially adapted for use as an electric resistance film for coating the inner neck or funnel portions of a cathode ray tube to reduce arcing. The glass composition includes primarily the oxides of vanadium and phosphorous with the preferred addition of either zinc oxide or lead oxide. Still other metal oxides may be optionally included such as oxides of barium, antimony, lithium, manganese, silicon, boron, molybdenum and mixtures thereof.Type: GrantFiled: October 17, 1979Date of Patent: August 3, 1982Assignee: Owens-Illinois, Inc.Inventor: Edward A. Weaver
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Patent number: 4314031Abstract: Glass compositions in the tin-phosphorus-oxyfluoride composition system exhibiting very low glass transition temperatures and capable of being modified by the addition of selected constituents to exhibit excellent stability in a humid environment, are described.Type: GrantFiled: June 17, 1980Date of Patent: February 2, 1982Assignee: Corning Glass WorksInventors: Leon M. Sanford, Paul A. Tick