Abstract: A glass composition of the present invention relates to a multicomponent oxide glass composition manufactured by melting glass raw materials, which contains: 10 ppm or more of at least one type of a polyvalent element; minimum valence cations of the polyvalent element in a ratio of the minimum valence cation content to the total polyvalent element content of 5 to 98% in mass ratio; and 0.01 to 2 ?l/g (0° C., 1 atm) of helium.
Abstract: Described herein are alkali-free, boroalumino silicate glasses exhibiting desirable physical and chemical properties for use as substrates in flat panel display devices, such as, active matrix liquid crystal displays (AMLCDs). In accordance with certain of its aspects, the glasses possess good dimensional stability as a function of temperature.
Type:
Application
Filed:
February 9, 2007
Publication date:
August 16, 2007
Inventors:
Paul S. Danielson, Adam J.G. Ellison, Natesan Venkataraman
Abstract: It is an object of the present invention to provide a clad glass composition for graded-index rod lens for covering, during manufacturing, a preform glass composition lens of a graded-index rod lens that does not include PbO, in which the composition substantially does not include PbO, and expressed in mol % includes SiO2: 45 to 65, Na2O: 3 to 30, K2O: 0 to 10, MgO: 0 to 15, BaO: 0 to 20, where Na2O+K2O: 3 to 35 and MgO+BaO: 0 to 25, and furthermore includes B2O3: 0 to 15, ZnO: 0 to 10, TiO2: 0 to 10, Y2O3: 0 to 7, ZrO2: 0 to 7, Nb2O5: 0 to 7, In2O3: 0 to 7, La2O3: 0 to 7, Ta2O5: 0 to 10, where B2O3+ZnO+TiO2+Y2O3+ZrO2+Nb2O5+In2O3+La2to 20, and a content of at least one of TiO2 and La2O3 is substantially 0 mol %.
Abstract: The present invention provides fluorescent glass containing at least 50 mol % of at least one kind of oxide selected from the group consisting of SiO2, GeO2, and P2O5 as a glass constituent of a region containing a Bi ion as a dopant.
Type:
Grant
Filed:
December 3, 2003
Date of Patent:
January 30, 2007
Assignees:
Sumitomo Electric Industries, Ltd., Kyushu University
Abstract: A zinc oxide-alumina-silica-based crystallized glass is provided, containing zinc oxide, alumina and silica as main components, and zirconia as a nucleating agent. The main components are provided in a ratio of 20–30% by mass of zinc oxide, 15–25% by mass of alumina and 50–60% by mass of silica to amount to 100% by mass in total. The nucleating agent is contained in an amount of 3–6 parts by mass based on 100 parts by mass of the main components. The crystallized glass also includes at least one modification component selected from the group consisting of lithium oxide, sodium oxide, potassium oxide, diphosphorus pentoxide, niobium oxide and tantalum oxide in addition to the main components and the nucleating agent.
Abstract: Disclosed are glass compositions, glass fiber compositions, glass fiber battery separators, glass fiber filter media, battery additives and active materials formed with glass compositions disclosed, glass fiber radiation shields, and glass fiber paper compositions. Certain embodiments include, among other components, bismuth oxide. Certain embodiments include about 0.5–30% bismuth oxide of the composition by weight and silica oxide at about 54–70% of the composition by weight. Embodiments may also include other components. For example, zinc oxide can make up about 0.01–3% of the composition by weight.
Type:
Grant
Filed:
July 21, 2004
Date of Patent:
December 5, 2006
Assignee:
Evanite Fiber Corporation
Inventors:
George Zguris, John Windisch, Patrick Svoboda, Yuri Vulfson
Abstract: The invention relates to a polymerizable dental material containing: (a) 3 to 80 wt. % of one or more cationically curable monomers; (b) 3 to 90 wt. % of one or more radio-opaque fillers; (c) 0.01 to 25 wt. % of initiators, retarders and/or accelerators, and; (d) 0 to 25 wt. % of auxiliary agents, whereby the cited percentages each refer to the total weight of the material. Filler (b) is produced by means of a melting method and is selected so that it has a refractive index of nD=1.49–1.54, so that the viscosity of the polymerizable dental material, after a period of at least 9 months during which it was stored at a temperature ranging from 20 to 25° C., has a value of +/?50 % of the initial value measured 24 hours after the polymerizable dental material was produced, and so that the polymerizable dental material has a reactivity of the type that, once polymerization is initiated, the amount of the maximum heat flux generated by the dental material equals at least 0.
Type:
Grant
Filed:
January 8, 2002
Date of Patent:
August 29, 2006
Assignee:
3M ESPE AG
Inventors:
Stefan Hoescheler, Wolfgang Weinmann, Andrea Stippschild, Susanne Wegner
Abstract: The present invention provides a glass sheet formed on molten tin, that exhibits a high transmittance that is originally inherent to its composition. In this glass sheet, the difference between a visible light reflectance of a surface formed in contact with the molten tin and a visible light reflectance of a surface on the opposite side thereof is not greater than 0.25%. And when the glass sheet's thickness is 4 mm, a light transmittance at 540 nm wavelength is at least 91.5%, and a light transmittance at 450 nm wavelength is at least 91.0%, and after irradiating UV light for 6 hours as specified in the radiation-proofing test according to JIS R3212, a light transmittance at 540 nm wavelength is at least 91.0% and a light transmittance at 450 nm wavelength is at least 90.5%.
Abstract: The invention relates to a method for producing mineral wool, whereby a cracking catalyst having an aluminum oxide content of at least 35% by weight is used as a base material or aggregate. Said catalyst materials produce waste products which are difficult to eliminate in the chemical industry and which can be reused in the production of mineral fibers and can be used in an economical and resource sparing manner.
Abstract: This invention provides a black low thermal expansion high specific rigidity ceramic sintered body having a black tone, manifesting very small thermal expansion at room temperature and abounding in rigidity and specific rigidity, and a method for the production thereof. The black low thermal expansion high specific rigidity ceramic sintered body is characterized by having a chemical composition comprising 8.0–17.2 mass % of MgO, 22.0–38.0 mass % of Al2O3, 49.5–65.0 mass % of SiO2, a total of 0.1–2 mass % of one or more transition elements as reduced to oxides, and 0–2.5 mass % of Li2O, and having the mass ratios satisfy the relationships of (SiO2?8×Li2O)/MgO?3.0 and (SiO2?8×Li2O)/Al2O3?1.2. The method for the production of a black low thermal expansion high specific rigidity ceramic sintered body of this invention is characterized by forming the sintered body in an atmosphere of a non-oxidizing gas at a temperature in the range of 1200–1500° C.
Type:
Grant
Filed:
June 1, 2000
Date of Patent:
June 27, 2006
Assignee:
Nippon Steel Corporation
Inventors:
Jun Sugawara, Hidehiko Morita, Katsumi Hashimoto, Tetsuro Nose
Abstract: Titania-containing silica glass bodies and extreme ultraviolet elements having low levels of striae are disclosed. Methods and apparatus for manufacturing and measuring striae in glass elements and extreme ultraviolet elements are also disclosed.
Type:
Grant
Filed:
March 3, 2003
Date of Patent:
May 30, 2006
Assignee:
Corning Incorporated
Inventors:
Kenneth E. Hrdina, John E. Maxon, Brent R. Mclean
Abstract: Glass formulations, and a method of converting such glass formulations to glass beads having a refractive index of at least 1.59 and a high level of retroreflectivity, are provided. The methods and formulations provide beads also having high levels of resistance to degradation by environmental exposure.
Type:
Grant
Filed:
April 28, 2004
Date of Patent:
May 16, 2006
Assignee:
PQ Corporation
Inventors:
Ufuk Senturk, Michael P. Lanci, Raymond Jackson, John W. Lau
Abstract: Glass for a light filter capable of preventing variation of refractive index in a band-pass filter has a coefficient of thermal expansion within a range from 90×10?7/° C. within a temperature range from ?20° C. to +70° C. and, preferably, Young's modulus of 75 GPa or over and Vickers hardness of 550 or over, and light transmittance for plate thickness of 10 mm of 90% or over within a wavelength range from 950 nm to 1600 nm.
Abstract: An alkaline-earth aluminosilicate glass having a composition (in % by weight, based on oxide) of SiO2>55-64; Al2O3 13-18; B2O3 0-5.5; M5O 0-7; CaO 5.5-14; SrO 0-8; BaO 6-17; ZrO2 0-2; CeO2 0-0.3; TiO2 0-0.5; CoO 0.01-0.035; Fe2O3 0.005-0.05; and NiO 0-0.
Type:
Grant
Filed:
February 3, 2003
Date of Patent:
January 24, 2006
Assignee:
Schott AG
Inventors:
Christian Kunert, Karin Naumann, Franz Ott, Ottmar Becker
Abstract: Glass comprises essentially 20-70% SiO2, 10-50% TiO2+Nb2O5+SnO2+Ta2O5+WO3+CeO2, 0-50% MgO+CaO+SrO+BaO+ZnO, and 0-30% B2O3+Al2O3, in molar percentage terms based on the oxides; and has a resistivity of at most 1015 ?·cm at 20° C. A method for production of glass is to produce the glass under such a condition that a redox represented by [Fe2+]/([Fe2+]+[Fe3+]) where Fe is present in the glass, is at least 0.6.
Abstract: In one aspect, the invention provides glass beads and optical devices comprising the glass beads. In other aspects, the invention provides methods of making said glass beads and rapid glass screening methods that use glass beads. Glass beads of the invention comprise greater than 80 weight percent silica, active rare earth dopant, and modifying dopant. In another embodiment the glass beads comprise greater than 80 weight percent silica and at least 5 weight percent germania. In another embodiment, glass beads comprise and from about 20 to about 90 anion mole percent of non-oxide anion.
Abstract: An infrared absorption filter consisting of 70 to 98 mol % of SiO2, 1 to 12 mol % of CuO and 1 to 18 mol % of a network modifier oxide than CuO or CdO is provided. A process of fabricating an infrared absorption filter is also provided. The process comprises introducing a divalent copper compound and a compound of a metal species acting as a network modifier oxide in the form of metal ions into a wet gel. The wet gel can be dipped in a dipping solution to precipitate the divalent copper compound and the compound of a metal species acting as the network modifier oxide in the wet gel. The wet gel can be dried and heated, thereby obtaining an infrared absorption glass. The infrared absorption glass can be cut and polished, thereby fabricating a filter.
Abstract: A glass-ceramic composite material for use in forming a multilayered circuit substrate is provided which has a low dielectric constant, but exhibits a relatively high thermal expansion coefficient. Specifically, the glass-ceramic composite material comprises a glass power and a ceramic powder. The glass powder contains: about 30 to 60 mol % of SiO2, about 20 to 40 mol % of BaO, 0 to about 40 mol % of MgO, 0 to about 40 mol % of ZnO, 0 to about 20 mol % of B2O3, with the total content of MgO and ZnO being about 10 to 40 mol %. The ceramic powder contains an alumina powder. The content of the glass powder is set to be at least about 50 wt %. A sintered compact formed by sintering the above glass powder and the above ceramic powder contains a BaO.Al2O3.2SiO2 (BaAl2Si2O8) crystal, and its Q value becomes about 400 or more when a measured frequency is 10 GHz.
Abstract: Nanoscale particles, particle coatings/particle arrays and corresponding consolidated materials are described based on an ability to vary the composition involving a wide range of metal and/or metalloid elements and corresponding compositions. In particular, metalloid oxides and metal-metalloid compositions are described in the form of improved nanoscale particles and coatings formed from the nanoscale particles. Compositions comprising rare earth metals and dopants/additives with rare earth metals are described. Complex compositions with a range of host compositions and dopants/additives can be formed using the approaches described herein. The particle coating can take the form of particle arrays that range from collections of disbursable primary particles to fused networks of primary particles forming channels that reflect the nanoscale of the primary particles. Suitable materials for optical applications are described along with some optical devices of interest.
Type:
Grant
Filed:
March 15, 2002
Date of Patent:
February 1, 2005
Assignee:
NeoPhotonics Corporation
Inventors:
Craig R. Horne, Pierre J. DeMascarel, Christian C. Honeker, Benjamin Chaloner-Gill, Herman A. Lopez, Xiangxin Bi, Ronald J. Mosso, William E. McGovern, James T. Gardner, Sujeet Kumar, James A. Gilliam, Vince Pham, Eric Euvrard, Shivkumar Chiruvolu, Jesse Jur
Abstract: Aqueous dispersion comprising silicon/titanium mixed oxide powder with a BET surface area of 5 to 500 m2/g which has been prepared by flame hydrolysis and has a titanium dioxide content of 0.5 to 20 wt. %, based on the powder, water and at least one pH-regulating substance which can be removed completely from the reaction mixture on heating, the aqueous dispersion having a solids content of between 40 and 80 wt. %. A green body produced therefrom with a green density of between 40 and 85%. A shaped glass article of optical quality with a coefficient of thermal expansion of not more than 0.5×10?6/K produced from the green body.
Type:
Grant
Filed:
February 25, 2003
Date of Patent:
February 1, 2005
Assignee:
Degussa AG
Inventors:
Monika Oswald, Klaus Deller, Helmut Mangold, Gerrit Schneider, Rolf Clasen, Markus Hornfeck
Abstract: The invention relates to a silica yarn and to woven or nonwoven fabrics produced from said yarn, which comprises 30 to 1500 ppm by weight of aluminum and 10 to 200 ppm by weight of titanium in oxidized form, the sum of the mass of the chemical elements different from Si and O being less than 5000 ppm by weight, the following elements being absent or present in a very small quantity: boron, sodium, calcium, potassium and lithium. The fabrics comprising this silica yarn have an excellent high-temperature withstand and thus retain their flexibility for a long time at above 600° C. They are useful especially in uses requiring good high-temperature flexibility, such as for furnace seals.
Abstract: In order to suppress production of devitrifying stones such as barium disilicate and strontium silicate and to achieve a high X-ray absorbability, a CRT panel glass does not substantially contain PbO and contains, in mass percent, 9-9.5% SrO and 8.5-9% BaO. In addition, the value of SrO/(SrO+BaO) is set to 0.50-0.53. Therefore, the CRT panel glass has an X-ray absorption coefficient of 28.0 cm−1 or more at 0.6 Å.
Abstract: Glass for a light filter capable of preventing variation of refractive index in a band-pass filter has a coefficient of thermal expansion within a range from 90×10−7/° C. to 120×10−7/° C. within a temperature range from −20° C. to +70° C. and, preferably, Young's modulus of 75 GPa or over and Vickers hardness of 550 or over, and light transmittance for plate thickness of 10 mm of 90% or over within a wavelength range from 950 nm to 1600 nm.
Abstract: There is provided a glass-ceramic which is suitable for use as a light filter. The glass-ceramic has Young's modulus (GPa) within a range from 95 to 120 and includes 5.3-8 weight percent of Al2O3, 0.5-3.5 weight percent of ZrO2 and 71-81 weight percent of SiO2, based respectively on the total content of the oxides. The glass-ceramic preferably has, as its predominant crystal phases, (a) lithium disilicate (Li2O.2SiO2) and (b) at least one of &agr;-quartz (&agr;-SiO2) and &agr;-quartz solid solution (&agr;-SiO2 solid solution), has specific gravity within a range from 2.4 to 2.6 and has a coefficient of thermal expansion within a range from 65×10−7/° C. to 130×10−7/° C. within a temperature range from −50° C. to +70° C.
Abstract: The ultraviolet/infrared absorbent low transmittance glass consists of base glass including: 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO (a total amount of MgO and CaO is between 5 to 15 wt. %); 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O (a total amount of Na2O and K2O is between 10 to 20 wt. %); and 0 to 5 wt. % B2O3; and colorants including: 1.2 to 2.2 wt. % total iron oxide (T-Fe2O3) expressed as Fe2O3; greater than 0.03 wt. % CoO; less than 0.0001 wt. % Se; and 0 to 0.2 wt. % NiO. The glass has a visible light transmittance measured by the illuminant A of not greater than 12% in case that the glass has a thickness of 4 mm. The glass has almost neutral color such as bluish green shade or deep green shade, low visible light transmittance, low solar energy transmittance and low ultraviolet transmittance, so that it is useful for windows of vehicles or buildings particularly for thickness and weight reduction of a privacy preventing glass.
Abstract: Glass comprises essentially 20-70% SiO2, 10-50% TiO2+Nb2O5+SnO2+Ta2O5+WO3+CeO2, 0-50% MgO+CaO+SrO+BaO+ZnO, and 0-30% B2O3+Al2O3, in molar percentage terms based on the oxides; and has a resistivity of at most 1015 &OHgr;·cm at 20° C. A method for production of glass is to produce the glass under such a condition that a redox represented by [Fe2+]/([Fe2+]+[Fe3+]) where Fe is present in the glass, is at least 0.6.
Abstract: Germanium-silicon oxide, germanium-silicon oxynitride and silica-germania-titania materials and oxynitride materials suitable for fabricating optical waveguides for liquid crystal based cross-connect optical switching devices have a refractive index of from about 1.48 to about 1.52 at 1550 nm, and a coefficient of thermal expansion at room temperature of from about 3×10−6° C.−1 to about 4.4×10−6° C.−1. The compositions are adjusted so that the refractive index of the germanium-silicon oxide, germanium-silicon oxynitride or silica-germania-titania material is closely matched to the refractive index of a typical liquid crystal material whereby improved optical performance of a liquid crystal based cross-connect optical switching device is achieved.
Type:
Grant
Filed:
July 27, 2001
Date of Patent:
July 27, 2004
Assignee:
Corning Incorporated
Inventors:
Ikerionwu A. Akwani, Robert A. Bellman, Lynn B. Simpson
Abstract: Rolls include a core and a glass outer coating on the core. The glass can be electrically charged and discharged. The outer coatings have smooth finishes and controlled electrical properties. The outer coatings can also provide selected mechanical, chemical and thermal properties. The rolls can be used in various applications in which controlled electrical properties are desired. For example, the rolls can be used as charge donor rolls in electrostatographic imaging apparatus.
Type:
Grant
Filed:
May 31, 2000
Date of Patent:
May 11, 2004
Assignee:
Xerox Corporation
Inventors:
Christopher D. Blair, Timothy R. Jaskowiak
Abstract: It is an object of the present invention to provide a clad glass composition for graded-index rod lens for covering, during manufacturing, a preform glass composition lens of a graded-index rod lens that does not include PbO, in which the composition substantially does not include PbO, and expressed in mol % includes SiO2: 45 to 65, Na2O: 3 to 30, K2O: 0 to 10, MgO: 0 to 15, BaO: 0 to 20, where Na2O+K2O: 3 to 35 and MgO+BaO: 0 to 25, and furthermore includes B2O3: 0 to 15, ZnO: 0 to 10, TiO2: 0 to 10, Y2O3: 0 to 7, ZrO2: 0 to 7, Nb2O5: 0 to 7, In2O3: 0 to 7, La2O3: 0 to 7, Ta2O5: 0 to 10, where B2O3+ZnO+TiO2+Y2O3+ZrO2+Nb2O5+In2O3+La2O3+Ta2O5: 0 to 20, and a content of at least one of TiO2 and La2O3 is substantially 0 mol %.
Abstract: Glazing, thermally tempered to required standards, are produced more readily by tempering panes having a high coefficient of thermal expansion (greater than 93×10−7 per degree Centigrade) and for a low Fracture Toughness (less than 0.72 MPam½). Use of glasses selected according to the invention enables thin glazings (especially glazings less than 3 mm thick) to be tempered to automotive standard with improved yields using conventional tempering methods, and thicker glazings to be tempered at lower quench pressure than required hitherto. Suitable glasses include glasses comprising, in percentages by weight, 64 to 75% SiO2, 0 to 5% Al2O3, 0 to 5% B2O3, 9 to 16% alkaline earth metal oxide other than MgO, 0 to 2% MgO, 15 to 18% alkali mental oxide and at least 0.
Type:
Grant
Filed:
March 1, 2002
Date of Patent:
March 30, 2004
Assignee:
Pilkington plc
Inventors:
Ashley Carl Torr, Louise Sara Butcher, Kevin Jones, Alan Charles Woodward
Abstract: The honeycomb structure of the present invention is formed from a nonwoven fabric in which a biologically soluble fiber is used, and exhibits superior biological solubility and high heat resistance.
Abstract: Extremely high solids content silica dispersions are useful for forming green bodies of near net shape as compared to the shape of the bodies after sintering. The green bodies are particularly useful for sintering to form low impurity-containing crucibles for single crystal silicon production.
Type:
Grant
Filed:
March 1, 2002
Date of Patent:
March 2, 2004
Assignee:
Wacker-Chemie GmbH
Inventors:
Fritz Schwertfeger, Johann Weis, Peter Ritter, Achim Molter, Wolfgang Schweren, Volker Frey, Hans-Peter Scherm
Abstract: A glass ceramic having properties of low thermal expansion, high transmittance in a visible light region and low specific gravity, and a glass ceramic substrate made of the glass ceramic are provided. The glass ceramic has a crystal phase containing a &bgr;-quartz solid solution precipitated by heat treatment of a matrix glass for a glass ceramic, and the matrix glass has a glass composition comprising 55 to 70 mol % of SiO2, 13 to 23 mol % of Al2O3, 11 to 21 mol % of an alkali metal oxide, provided that the alkali metal oxide contains 10 to 20 mol % of Li2O and contains 0.1 to 3 mol % of Na2O and K2O in total, 0.1 to 4 mol % of TiO2 and 0.1 to 2 mol % of ZrO2, the total content of said components being at least 95 mol %, and further comprising 0 to less than 0.2 mol % of BaO, 0 to less than 0.1 mol % of P2O5, 0 to less than 0.3 mol % of B2O3 and 0 to leas than 0.1 mol % of SnO2.
Abstract: A pyrogenic process is used to prepare alkali-doped silica particles. Particles produced by this process exhibit homogeneous doping, reduced agglomeration, greater stability and higher removal rates. Aqueous dispersions containing alkali-doped pyrogenic silica with average particle size less than 100 nm are used for polishing surfaces (CMP).
Type:
Grant
Filed:
December 21, 2001
Date of Patent:
January 13, 2004
Assignee:
Degussa AG
Inventors:
Wolfgang Lortz, Christoph Batz-Sohn, Helmut Mangold, Gabriele Perlet, Werner Will
Abstract: A glass ceramic composition which consists essentially of an inorganic material powder having a melting point or a glass transition point of at least 1,000° C. and a glass powder having a glass transition point of from 450 to 800° C., wherein the average of the major axes L of particles of the above inorganic material powder is from 0.5 to 15 &mgr;m, and the average of the ratios L/W of the major axes L to the minor axes W is at most 1.4. Further, a glass ceramic composition which consists essentially of, as represented by mass percentage, from 10 to 58% of an inorganic material powder having a melting point or a glass transition point of at least 1,000° C. and from 42 to 90% of a glass powder having a glass transition point of from 450 to 800° C., wherein the glass powder consists essentially of, as represented by mol %, SiO2: 35 to 70%, B2O3: 0 to 30%, Al2O3: 3 to 18%, MgO: 0 to 40%, CaO: 0 to 19%, BaO: 0 to 35% and ZnO: 0 to 9%.
Abstract: A glass for covering electrodes, which consists, as represented by mass percentage based on the following oxides, essentially of:
Mass percentage
PbO
44 to 68%
Bi2O3
0 to 18%,
B2O3
19 to 23%,
SiO2
1.2 to 5%,
Al2O3
2 to 6%,
ZnO
4 to 9%,
CuO
0.1 to 0.5%,
In2O3
1.1 to 2%,
SnO2
0 to 1%, and
CeO2
0 to 1%.
Abstract: An optical amplifying glass comprising a matrix glass and from 0.001 to 10% by mass percentage of Tm doped to the matrix glass, wherein the matrix glass contains from 15 to 80 mol % of Bi2O3 and further contains at least one component selected from the group consisting of SiO2, B2O3 and GeO2.
Abstract: An immobilizing structure for use in immobilizing a ceramic monolith in a catalytic converter employs a molding which comprises finely divided metal oxide and fibers which do not represent a health risk, has a density of 100-240 kg/m3, and has a compression to at least 96% of its original thickness at a pressure of 1 bar applied for a period of 5 minutes, and exhibits a recovery of this compression to more than 70% of its initial value within about one minute after removal of the pressure.
Abstract: An alkali-free glass applicable to a light transparent glass substrate in a liquid crystal display essentially consists, by weight, of basic elements of 40-70% SiO2, 6-25% Al2O3, 5-20% B2O3, 0-10% MgO, 0-15% CaO, 0-30% BaO, 0-10% SrO, and 0-10% ZnO, and a fining agent of a combination of 0.05-3% Sb2O3 and at least one of 0.05-2% SnO2 and 0.005-1% Cl2, which fining agent makes the resultant glass free from bubbles without the use of toxic As2O3 which has been known as the fining agent in the art.
Type:
Application
Filed:
November 18, 2002
Publication date:
July 3, 2003
Applicant:
NIPPON ELECTRIC GLASS CO., LTD.
Inventors:
Jun Naka, Toshiharu Narita, Shinkichi Miwa, Shigeru Yamamoto
Abstract: Titanium is added in the form of atoms, a colloid, or ions to a glass to be subjected to laser processing in which the ablation or vaporization caused by the energy of an absorbed laser light is utilized. Since titanium can be incorporated into the glass through melting, the threshold value for processing can be easily regulated by changing the amount titanium to be added and a material having evenness in processability can be obtained.
Abstract: An alkali-free glass applicable to a light transparent glass substrate in a liquid crystal display essentially consists, by weight, of basic elements of 40-70% SiO2, 6-25% Al2O3, 5-20% B2O3, 0-10% MgO, 0-15% CaO, 0-30% BaO, 0-10% SrO, and 0-10% ZnO, and a fining agent of a combination of 0.05-3% Sb2O3 and at least one of 0.05-2% SnO2 and 0.005-1% Cl2, which fining agent makes the resultant glass free from bubbles without the use of toxic As2O3 which has been known as the fining agent in the art.
Type:
Grant
Filed:
July 17, 2001
Date of Patent:
April 15, 2003
Assignee:
Nippon Electric Glass Co. Ltd.
Inventors:
Jun Naka, Toshiharu Narita, Shinkichi Miwa, Shigeru Yamamoto
Abstract: A silicate based composition for optical glass used as a substrate for thin film optical interference filters having a stable transmission band center wavelength and bandwidth has a relatively high coefficient of thermal expansion, high Young's modulus and high optical transmittance in the near infrared (NIR) wavelength range of about 950 nm to about 1600 nm. The coefficient of thermal expansion of the glass composition is adjustable to particular values to result in minimal wavelength shift in filters made by depositing thin films of particular dielectric materials onto a substrate made of the glass, the composition being varied from a preferred baseline composition consisting of about 43.2% SiO2, 7% Al2O3, 12.7% CaO, 7.3% SrO, 7.8% Li2O, 13.2% Na2O, 8.0% K2O, 0.7% ZrO, and 0.1% Sb2O3, the baseline composition having a coefficient of thermal expansion of about 112×10−7/° C. over the temperature range of −30° C. to +70° C., a Young's modulus E of 88.
Abstract: The decorative vitreous beads of the present invention have a hard, solid, substantially vitreous, unitary body comprised primarily of silica and having a generally spherical form, with the largest dimension being in the range between ⅛ inch to 2 inches. The body by weight comprising 35% to 70% of silica and the remaining ingredients by weight are from 65% to 30% for a total of 100% taken from the group comprising potash, soda, calcia, strontia, alumina, zinc oxide, boric oxide, zirconia, magnesia and potassium. Methods are further disclosed for making the decorative beads comprising mixing together a batch of minerals in powder state comprising by weight 35% to 70% of silica and the remaining oxides by weight from 65% to 30% for a total of 100% taken from a group comprising the oxides mentioned previously. The mixed batch is placed in the container which is inserted into a kiln.
Abstract: An aluminosilicate transparent glass has corrosion resistance in the form of mass loss of 4.0 mg or below per 1cm2 of the surface of a specimen upon holding the specimen for five hours in sodium hydroxide solution having concentration of 300 mg(L under test pressure of 50 MPa at 250° C. The glass has a coefficient of thermal expansion within a range from 35×10−7/° C. to 50×10−7/° C. within a temperature range from 100° C to 300° C. The glass has also powdered glass mass loss rate of 0.1% or below in terms of water resistance, acid resistance and alkali resistance.
Abstract: A graded index lens is obtained by treating a raw glass material having a rod shape by ion exchange using silver to form a refractive index distribution in the radial direction of the rod, wherein the raw glass material comprises a glass composition of the following components:
15<Na2O≦30 mol %;
10<Al2O3≦25 mol %;
27.5≦SiO2≦55 mol %;
3≦B2O3≦18 mol %;
2.5≦MgO≦18 mol %;
0≦Ta2O5≦5 mol %;
0≦La2O3≦3 mol %;
0≦BaO≦3 mol %; and
0≦ZrO2≦3 mol %.
Abstract: An alkali-free glass applicable to a light transparent glass substrate in a liquid crystal display essentially consists, by weight, of basic elements of 40-70% SiO2, 6-25% Al2O3, 5-20% B2O3, 0-10% MgO, 0-15% CaO, 0-30% BaO, 0-10% SrO, and 0-10% ZnO, and a fining agent of a combination of 0.05-3% Sb2O3 and at least one of 0.05-2% SnO2 and 0.005-1% Cl2, which fining agent makes the resultant glass free from bubbles without the use of toxic As2O3 which has been known as the fining agent in the art.
Type:
Grant
Filed:
August 20, 1997
Date of Patent:
January 21, 2003
Assignee:
Nippon Electric Glass Co., Ltd.
Inventors:
Jun Naka, Toshiharu Narita, Shinkichi Miwa, Shigeru Yamamoto
Abstract: A glass including SiO2, Na2O, MgO, Al2O3, and cobalt oxide, wherein the cobalt oxide is 4.5-85 wt % as an oxide of CoO or 4.9-91 wt % as an oxide of Co3O4.
Abstract: A process for producing a glass for cathode ray tubes, having a Sb2O3 content of from 0 to 0.19% as represented by mass percentage and containing H2O, which process comprises a step of melting a raw material in an atmosphere under a pressure of P0 to obtain a molten glass, and a step of vacuum degassing the molten glass in an atmosphere under a pressure PA which is lower than P0, wherein the pressure P of the molten glass is made to be at most (6.1 W+0.06) atm in the vacuum degassing step, wherein W is the content of said H2O as represented by mass percentage.
Abstract: The ultraviolet/infrared absorbent low transmittance glass consists of base glass including: 65 to 80 wt. % SiO2; 0 to 5 wt. % Al2O3; 0 to 10 wt. % MgO; 5 to 15 wt. % CaO (a total amount of MgO and CaO is between 5 to 15 wt. %); 10 to 18 wt. % Na2O; 0 to 5 wt. % K2O (a total amount of Na2O and K2O is between 10 to 20 wt. %); and 0 to 5 wt. % B2O3; and colorants including: 1.2 to 2.2 wt. % total iron oxide (T-Fe2O3) expressed as Fe2O3; greater than 0.03 wt. % CoO; less than 0.0001 wt. % Se; and 0 to 0.2 wt. % NiO. The glass has a visible light transmittance measured by the illuminant A of not greater than 12% in case that the glass has a thickness of 4 mm. The glass has almost neutral color such as bluish green shade or deep green shade, low visible light transmittance, low solar energy transmittance and low ultraviolet transmittance, so that it is useful for windows of vehicles or buildings particularly for thickness and weight reduction of a privacy preventing glass.
Abstract: Glass for a light filter capable of preventing variation of refractive index in a band-pass filter has a coefficient of thermal expansion within a range from 90×10−7/° C. to 120×10−7/° C. within a temperature range from −20° C. to +70° C. and, preferably, Young's modulus of 75GPa or over and Vickers hardness of 550 or over, and light transmittance for plate thickness of 10 mm of 90% or over within a wavelength range from 950 nm to 1600 nm.