Zeolite Patents (Class 502/64)
  • Patent number: 8288302
    Abstract: The present invention relates to a method for preparing substrate-molecular sieve layer complex by vising ultra-sound and apparatuses used therein, more particularly to a method for preparing substrate-molecular sieve layer complex by combining substrate, coupling compound and molecular sieve particle, wherein covalent, ionic, coordinate or hydrogen bond between a substrate and a coupling compound; molecular sieve particle and coupling compound; coupling compounds; coupling compound and intermediate coupling compound is induced by using 15 KHz-100 MHz of ultrasound instead of simple reflux to combine substrate and molecular sieve particles by various processes, further to reduce time and energy, to retain high binding velocity, binding strength, binding intensity and density remarkably, to attach molecular sieve particle uniformly onto all substrates combined with coupling compound selectively, even though substrate with coupling compound and substrate without coupling compound exist together; and apparatuses
    Type: Grant
    Filed: June 23, 2005
    Date of Patent: October 16, 2012
    Assignee: Industry University Cooperation Foundation Sogang University
    Inventors: Kyung Byung Yoon, Jin Seok Lee, Kwang Ha, Yun-Jo Lee, Yong Chang
  • Patent number: 8283273
    Abstract: A metal-modified alkylation catalyst including a metal/zeolite is provided where the metal is one or two selected from the group consisting of yttrium and a rare earth of the lanthanide series other than cerium. Where two metals are used, one may be Ce or La. The metal-promoted zeolite is useful as a molecular sieve aromatic alkylation catalyst for the production of ethylbenzene by the ethylation of benzene in the liquid phase or critical phase. An alkylation product is produced containing ethylbenzene as a primary product with the attendant production of heavier alkylated by-products of no more than 10-60 wt % of the ethylbenzene.
    Type: Grant
    Filed: March 31, 2010
    Date of Patent: October 9, 2012
    Assignee: Fina Technology, Inc.
    Inventors: Kevin Kelly, James Butler
  • Publication number: 20120252658
    Abstract: A honeycomb structure includes a honeycomb unit containing zeolite and an inorganic binder and having a plurality of cell walls to define a plurality of cells extending from a first end face to a second end face of the honeycomb unit along a longitudinal direction of the honeycomb unit. The honeycomb unit is manufactured by molding and firing raw material paste containing zeolite particles and the inorganic binder. The zeolite particles have a D50 of approximately 3.6 ?m or more. An average pore size of the cell walls is more than or equal to approximately 0.10 ?m and less than or equal to approximately 0.50 ?m. An average particle size of the cell walls is more than or equal to approximately 3.6 ?m and less than or equal to approximately 7.0 ?m.
    Type: Application
    Filed: November 24, 2011
    Publication date: October 4, 2012
    Applicant: IBIDEN CO., LTD.
    Inventors: Masafumi KUNIEDA, Yosuke Matsukawa
  • Patent number: 8278237
    Abstract: A catalyst for producing aromatic compounds from lower hydrocarbons while improving activity life stability of methane conversion rate; benzene formation rate; naphthalene formation rate; and total formation rate of benzene, toluene and xylene is formed by loading molybdenum and copper on metallo-silicate serving as a substrate and then calcining the metallo-silicate. When the catalyst is reacted with a reaction gas containing lower hydrocarbons and carbonic acid gas, aromatic compounds are produced. In order to obtain the catalyst, it is preferable that molybdenum and copper are loaded on zeolite formed of metallo-silicate after the zeolite is treated with a silane compound larger than a pore of the zeolite in diameter and having an amino group and a straight-chain hydrocarbon group, the amino group being able to selectively react with the zeolite at a Bronsted acid point of the zeolite. It is preferable that a loaded amount of molybdenum is within a range of from 2 to 12 wt.
    Type: Grant
    Filed: February 13, 2008
    Date of Patent: October 2, 2012
    Assignee: Meidensha Corporation
    Inventors: Shinichi Yamada, Tomohiro Yamada, Yuji Ogawa, Hirokazu Akiyama, Takuya Hatagishi
  • Patent number: 8278235
    Abstract: A cracking catalyst contains a substantially inert core and an active shell, the active shell containing a zeolite catalyst and a matrix. The catalyst is formed by spray-drying a slurry containing water, substantially inert microspheres and a zeolite precursor and crystallizing zeolite in the active shell to create the cracking catalyst. Methods of using the cracking catalyst are also described.
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: October 2, 2012
    Assignee: BASF Corporation
    Inventors: David Matheson Stockwell, John M. Macaoay
  • Patent number: 8263517
    Abstract: Catalysts for dewaxing of hydrocarbon feeds, particularly feeds with elevated sulfur and nitrogen levels, are provided. The dewaxing catalysts include a zeolite with a low silica to alumina ratio combined with a low surface binder, or alternatively the formulated catalyst has a high ratio of zeolite surface area to external surface area.
    Type: Grant
    Filed: December 18, 2008
    Date of Patent: September 11, 2012
    Assignee: ExxonMobil Research and Engineering Company
    Inventors: Christine N. Elia, Mohan Kalyanaraman, Lei Zhang, Madhav Acharya, Michael A. Daage, Darden Sinclair, Jocelyn A. Kowalski, Jose G. Santiesteban, Ajit B. Dandekar
  • Patent number: 8263516
    Abstract: A method for manufacturing a DDR zeolite membrane element including the steps of: immersing a porous substrate in a raw material solution, forming a DDR zeolite membrane containing 1-adamanthanamine on a surface of the porous substrate by subjecting a DDR zeolite to hydrothermal synthesis in the presence of DDR zeolite seed crystals, applying a glass paste onto the surface of the porous substrate so as to contact the membrane, and heating the membrane at 500 to 800° C., thereby burning away the 1-adamanthanamine contained in the membrane and melting the glass paste to form a membrane-like glass seal contacting the membrane on the surface of the porous substrate. The method for manufacturing a DDR zeolite membrane element can inhibit the permeation of the DDR zeolite membrane from being hindered in a contact portion between the membrane and the glass seal and inhibit poor seal of the glass seal.
    Type: Grant
    Filed: July 29, 2010
    Date of Patent: September 11, 2012
    Assignee: NGK Insulators, Ltd.
    Inventors: Kenji Yajima, Hisayoshi Nonaka, Toshihiro Tomita
  • Patent number: 8263518
    Abstract: A method of preparing a catalyst comprising selecting a zeolite having a mean particle size of equal to or less than about 6 microns, blending the zeolite with a binder and water to form a paste, shaping the paste into a bound zeolite support, adding a metal to the bound zeolite support to form a metalized catalyst support, and adding at least one halide to the metalized catalyst support to form the catalyst. A catalytic reforming process for converting hydrocarbons to aromatics comprising: contacting a catalyst comprising a silica bound zeolite, a Group VIII metal supported thereby, and at least one halide with a hydrocarbon feed in a reaction zone under reforming conditions and recovering aromatics from the reaction zone, wherein the silica bound zeolite comprises a zeolite having a mean particle size of equal to or less than about 6 microns and a median particle size of equal to or less than about 5 microns.
    Type: Grant
    Filed: December 13, 2007
    Date of Patent: September 11, 2012
    Assignee: Chevron Phillips Chemical Company LP
    Inventor: Gyanesh P. Khare
  • Patent number: 8258070
    Abstract: An emission control catalyst that exhibits improved CO and HC reduction performance includes supported precious group metal catalysts that are coated onto different layers of the substrate for the emission control catalyst. Zeolites of one or more types are added to the emission control catalyst as a hydrocarbon absorbing component to boost the low temperature performance of the emission control catalyst. Y zeolite is used by itself or mixed with other zeolites to enhance hydrocarbon storage at low temperatures.
    Type: Grant
    Filed: November 9, 2009
    Date of Patent: September 4, 2012
    Inventors: Kyle L. Fujdala, Timothy J. Truex, Juan Cai, Chaitanya Sampara
  • Patent number: 8258071
    Abstract: The invention relates to a catalyst that comes in the form of grains, each grain consisting of a core covered by at least one external layer, the core consisting of an acidic porous solid and having a size of between 0.1 micron and 0.4 millimeter, in which the external layer has a uniform thickness with a uniformity criterion C, which is less than 0.30, whereby said uniformity criterion C is defined as being equal to an average, on a number N of catalyst grain samples, of the ratio of the difference between the maximum thickness, Eimax, of the external layer and the minimum thickness, Eimin, of this same layer to the average of these two thicknesses Eimax and Eimin.
    Type: Grant
    Filed: January 13, 2005
    Date of Patent: September 4, 2012
    Assignee: IFP Energies nouvelles
    Inventors: Younes Bouizi, Valentin Valtchev, Loiec Rouleau, Nicolas Bats, Laurent Simon
  • Patent number: 8252709
    Abstract: An object of the present invention is to provide a catalyst for hydrodesulfurization/dewaxing of a hydrocarbon oil, with which sulfur compounds in the hydrocarbon oil can be desulfurized to a high degree and which simultaneously is extremely effective in reducing the wax deposit content; a process for producing the catalyst; and a method of hydrotreatment with the catalyst. The invention relates to a catalyst for hydrodesulfurization/dewaxing of a hydrocarbon oil, comprising a support comprising an inorganic oxide containing at least one crystalline aluminosilicate having a one- or two-dimensional pore path system and, having provided thereon, 10 to 35% by mass of a metal in Group 6 of the Periodic Table, 1 to 10% by mass of a metal in Group 8 of the Periodic Table, and 1.
    Type: Grant
    Filed: September 10, 2007
    Date of Patent: August 28, 2012
    Assignee: Cosmo Oil Co., Ltd.
    Inventors: Yoshinori Kato, Hiroshi Kimura, Kazuyuki Kiriyama, Takashi Fujikawa
  • Patent number: 8252710
    Abstract: Catalyst composition comprising a zeolite and a binder, wherein the zeolite is a Ga containing zeolite and the binder is a La modified kaolin and process for converting lower alkanes to aromatic hydrocarbons, using said catalyst composition. Preferably the aromatic hydrocarbons consist of at least 45 wt % of benzene, toluene and xylenes.
    Type: Grant
    Filed: December 5, 2007
    Date of Patent: August 28, 2012
    Assignee: Saudi Basic Industries Corporation
    Inventors: Balu Shivaji Uphade, Srikant Gopal
  • Publication number: 20120215043
    Abstract: The presently disclosed and claimed inventive concept(s) generally relates to a solid catalyst component comprising a zeolite with a modifier and at least one Group VIII meal alloyed with at least one transition metal. The presently disclosed and claimed inventive concept(s) further relates to a method of making the solid catalyst component and a process of converting mixed waste plastics into low molecular weight organic compounds using the solid catalyst component.
    Type: Application
    Filed: February 14, 2012
    Publication date: August 23, 2012
    Inventor: Anne Mae Gaffney
  • Patent number: 8242041
    Abstract: The invention includes a method for impregnating a molecular sieve primary catalyst with an aromatic co-catalyst, the method comprising contacting the small pore molecular sieve primary catalyst having a porous framework structure with a combination of from at least 50 wt % to about 99.9 wt % of an aromatic co-catalyst and from about 0.1 wt % to less than 50 wt % of a polar impregnation agent containing one or more heteroatoms selected from the group consisting of nitrogen, oxygen, sulfur, phosphorus, and boron, under conditions sufficient to impregnate the porous framework structure of the primary catalyst with the aromatic co-catalyst (and optionally also with the polar impregnation agent), thus forming an integrated catalyst system. Methods for converting oxygenates to olefins using said integrated catalyst system are also described herein.
    Type: Grant
    Filed: January 12, 2009
    Date of Patent: August 14, 2012
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Stephen H. Brown, Guang Cao, Teng Xu
  • Publication number: 20120202680
    Abstract: A process for preparing a zeolite-based monolith including dry-mixing zeolite particles and a temporary binder until homogenization; adding silica and water dispersion; wet-kneading and high-shear mixing until obtaining a homogenous pulp; extrusion-molding the pulp resulting from the previous step; controlled drying of the mold obtained; and oxidizing at a high temperature to obtain the monolith.
    Type: Application
    Filed: March 26, 2010
    Publication date: August 9, 2012
    Applicant: UNIVERSIDAD DEL PAIS VASCO-EUSKAL HERRIKO UNIBERTSITATEA
    Inventors: Asier Aranzabal Maiztegui, Deiene Iturbe Vallejo, María del Pilar González Marcos, José Antonio González Marcos, Juan Ramón González Velasco, Manuel Romero Sáez
  • Publication number: 20120203045
    Abstract: The invention relates to a process for producing a particulate, Si-bonded fluidized-bed catalyst having improved abrasion resistance, which comprises the steps I. provision of an aqueous suspension comprising zeolite particles, II. addition of a silicone resin mixture comprising one or more hydrolyzable silicone resin precondensates and mixing of the aqueous suspension and the silicone resin mixture, III. spray drying of the mixture obtained from step II, with the mixture being homogenized before spray drying, and IV. calcination of the spray-dried fluidized-bed catalyst obtained from step III, and an Si-bonded fluidized-bed catalyst which can be produced by this process and also its use for the nonoxidative dehydroaromatization of C1-C4-aliphatics.
    Type: Application
    Filed: October 6, 2010
    Publication date: August 9, 2012
    Applicant: BASF SE
    Inventors: Joana Coelho Tsou, Sebastian Ahrens, Christian Schneider, Thomas Heidemann, Bilge Yilmaz, Robert Bayer, Michael Schlei, Sebastian Kranz
  • Patent number: 8236419
    Abstract: Material with hierarchical porosity consisting of at least two elementary spherical particles, each one of said particles comprising a matrix based on silicon oxide, mesostructured, having a mesopore diameter ranging between 1.5 and 30 nm and exhibiting amorphous and microporous walls of thickness ranging between 1.5 and 50 nm, said elementary spherical particles having a maximum diameter of 200 microns. The matrix based on silicon oxide can contain aluminium. The preparation of said material is also described.
    Type: Grant
    Filed: August 19, 2008
    Date of Patent: August 7, 2012
    Assignee: IFP Energies nouvelles
    Inventors: Alexandra Chaumonnot, Stephanie Pega, Clement Sanchez, Cedric Boissiere
  • Publication number: 20120190900
    Abstract: A process for the production and use of a molecular sieve blend with improved performance characteristics produced by preparing or obtaining a hydrophilic zeolite, particularly a hydrophilic zeolite 3A with a low SiO2:Al2O3 ratio, preparing or obtaining a hydrophobic silica binder, particularly a hydrophobic colloidal silica, mixing the zeolite with the silica binder to form a mixture, and forming the mixture into the molecular sieve blend.
    Type: Application
    Filed: January 25, 2011
    Publication date: July 26, 2012
    Applicant: ZEOCHEM LLC
    Inventors: Kerry C. Weston, Patrick Purcell
  • Publication number: 20120189489
    Abstract: A complex metal oxide catalyst having a composition including about 5 to about 75 wt % of manganese (Mn); about 5 to about 55 wt % of copper (Cu); and about 3 to about 60 wt % of an active compound, based on a total weight of the complex metal oxide catalyst. The complex metal oxide catalyst has excellent low-temperature activity and improved catalyst efficiency so as to be repeatedly used, and thus is effectively used in a filter module and an air cleaner.
    Type: Application
    Filed: January 20, 2012
    Publication date: July 26, 2012
    Applicant: Samsung Electronics Co., Ltd.
    Inventors: Myung-jong Kwon, Sik-sun Choi, Duck-hee Lee, Jun-cheol Bae, Hae-ree Joo, Do-hoon Kim, Sang-woong Kim, Sang-hyun Park, Chang-ick Lee
  • Patent number: 8226740
    Abstract: An inorganic material that consists of at least two elementary spherical particles, each of said spherical particles comprising metal nanoparticles that are between 1 and 300 nm in size and a mesostructured matrix with an oxide base of at least one element X that is selected from the group that consists of aluminum, titanium, tungsten, zirconium, gallium, germanium, tin, antimony, lead, vanadium, iron, manganese, hafnium, niobium, tantalum, yttrium, cerium, gadolinium, europium and neodymium is described, whereby said matrix has a pore size of between 1.5 and 30 nm and has amorphous walls with a thickness of between 1 and 30 nm, said elementary spherical particles having a maximum diameter of 10 ?m. Said material can also contain zeolitic nanocrystals that are trapped within said mesostructured matrix.
    Type: Grant
    Filed: August 17, 2007
    Date of Patent: July 24, 2012
    Assignee: IFP Energies nouvelles
    Inventors: Alexandra Chaumonnot, Aurelie Coupe, Clement Sanchez, Cedric Boissiere, David Grosso
  • Publication number: 20120178615
    Abstract: A modified zeolite catalyst derived from a zeolite of a structural type which consists of a one-dimensional micropore structure of channels made from rings containing between 8 and 12 silicon/aluminium atoms is disclosed. It consists substantially of a plurality of crystallites having additional mesoporosity whose volume is in the range 0.09 to 0.25 ml3g?1 as measured by nitrogen absorption at 77° K and calculated by the BJH method. The mesoporosity may be introduced into the crystallites by e.g. treatment with aqueous sodium hydroxide at a pH at 25° C. in excess of 8 for an extended period at elevated temperature. The catalyst shows improved resistance to catalyst deactivation and greater selectivity to higher hydrocarbons when used to e.g. oligomerize light alkenes e.g. propene or the butenes.
    Type: Application
    Filed: June 22, 2010
    Publication date: July 12, 2012
    Applicant: BP Corporation North America, Inc.
    Inventors: Avelino Corma, Cristina Martinez, Eric J. Doskocil, George Yaluris
  • Patent number: 8211818
    Abstract: A honeycomb structural body includes at least one honeycomb unit which has a longitudinal direction. The at least one honeycomb unit includes plural cell walls, an inorganic binder, and inorganic particles. The plural cell walls extends along the longitudinal direction from one end face to another end face of the at least one honeycomb unit to define plural cells. The inorganic particles include ceria particles, and a ceramic material which has a degree of self-sintering lower than a degree of self-sintering of the ceria particles.
    Type: Grant
    Filed: October 9, 2008
    Date of Patent: July 3, 2012
    Assignee: Ibiden Co., Ltd.
    Inventors: Masafumi Kunieda, Shinnosuke Goto, Toshiyuki Miyashita
  • Patent number: 8207084
    Abstract: According to at least one aspect of the present invention, a urea-resistant catalytic unit is provided. In at least one embodiment, the catalytic unit includes a catalyst having a catalyst surface, and a urea-resistant coating in contact with at least a portion of the catalyst surface, wherein the urea-resistant coating effectively reduces urea-induced deactivation of the catalyst. In at least another embodiment, the urea-resistant coating includes at least one oxide from the group consisting of titanium oxide, tungsten oxide, zirconium oxide, molybdenum oxide, aluminum oxide, silicon dioxide, sulfur oxide, niobium oxide, molybdenum oxide, yttrium oxide, nickel oxide, cobalt oxide, and combinations thereof.
    Type: Grant
    Filed: June 23, 2009
    Date of Patent: June 26, 2012
    Assignee: Ford Global Technologies, LLC
    Inventors: Yisun Cheng, Yinyan Huang, Christine Kay Lambert
  • Patent number: 8207388
    Abstract: A catalytic composition is described for the transalkylation of aromatic hydrocarbons comprising a zeolite and an inorganic binder, characterized by an extra-zeolitic porosity, i.e. the porosity obtained by adding the mesoporosity and the macroporosity fractions present in the catalytic composition, higher than or equal to 0.7 cc/g, which is such as to consist for a fraction of at least 30% of pores having a diameter greater than 100 nanometers. These catalytic compositions have a crushing strength not lower than 1.7 kg/mm and an apparent density not higher than 0.5 g/cc. A process is also described for the transalkylation of polyalkylated aromatic hydrocarbons which uses these catalytic compositions.
    Type: Grant
    Filed: December 15, 2003
    Date of Patent: June 26, 2012
    Assignee: Polimeri Europa S.p.A.
    Inventors: Elena Bencini, Gianni Girotti
  • Patent number: 8207078
    Abstract: A close coupled three-way catalyst for purification of exhaust gas of motor vehicle and the preparation thereof. The support is selected from cordierite honeycomb ceramic materials having a pore volume of 0.25-0.35 ml/g. The coating layer is the mixture of hexaaluminate and perovskite-type composite oxide, cerium-zirconium solid solution, rare-earth oxide and alumina, alkali-earth oxide and zeolite having a high Si/Al ratio. The active components are palladium-rhodium, rare-earth oxide and transition metal in the hexaaluminate and perovskite-type composite oxide. The catalyst has not only the function of low-temperature catalytic oxidation of hydrocarbons, but also the function of reduction of nitrogen oxides, and can be used for purifying the exhaust gas of motor vehicles using gasoline, liquid gas, or CNG as fuel.
    Type: Grant
    Filed: February 14, 2007
    Date of Patent: June 26, 2012
    Assignee: East China University of Science and Technology
    Inventors: Guanzhong Lu, Yun Guo, Zhigang Zhang
  • Publication number: 20120157735
    Abstract: A process for producing a supported mesoporous and microporous material, comprises contacting a support with a template to produce a supported template, and contacting the supported template with one or more microporous material precursor to produce a supported microporous material-template composite, and subsequently removing the template from the supported microporous material-template composite to produce the supported mesoprous and microporous material. A composition comprising a supported mesoprous and microporous material produced by this process can be used for methane dehydroaromatization.
    Type: Application
    Filed: June 23, 2009
    Publication date: June 21, 2012
    Inventors: Xinhe Bao, Ding Ma, Wenjie Shen, Lijun Gu
  • Patent number: 8202601
    Abstract: A honeycomb structure includes at least one honeycomb unit having opening ratio (P) of at least approximately 50% and at most approximately 65% and a cell density ? of at least approximately 31/cm2 and at most approximately 93/cm2. The honeycomb unit includes an inorganic binder and at least approximately 230 g/L of zeolite in which L represents an apparent volume. The honeycomb unit further includes and a plurality of cell walls extending from a first end to a second end of the honeycomb unit along a longitudinal direction of the honeycomb unit to define cells. The cell walls have a surface roughness Ra of at least approximately 1 ?m and at most approximately 30 ?m.
    Type: Grant
    Filed: December 24, 2008
    Date of Patent: June 19, 2012
    Assignee: Ibiden Co., Ltd.
    Inventors: Kazushige Ohno, Masafumi Kunieda, Takahiko Ido
  • Patent number: 8202815
    Abstract: In one embodiment, a catalyst composition comprises from about 5 weight percent to about 70 weight percent of silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal. In another embodiment, a method for processing hydrocarbons comprises hydro-treating the hydrocarbons in the presence of a catalyst composition, wherein the catalyst comprises from about 5 weight percent to about 70 weight percent silica-alumina; from about 30 weight percent to about 90 weight percent alumina; and from about 0.01 weight percent to about 2.0 weight percent of a group VIII metal.
    Type: Grant
    Filed: December 26, 2008
    Date of Patent: June 19, 2012
    Assignee: General Electric Company
    Inventors: Gregg Anthony Deluga, Daniel Lawrence Derr
  • Patent number: 8196755
    Abstract: A process for the production of a composite membrane, one or more microporous separation layers comprising a zeolite of the MFI type being produced by hydrothermal synthesis on a porous substrate, wherein one or more additives from the group consisting of linear (C1-C4)-alcohols, ammonia, primary, secondary and tertiary amines having in each case (C1-C4)-alkyl radicals, (C1-C4)-aminoalcohols and (C3-C4)-ketones are added to the synthesis solution for the hydrothermal synthesis.
    Type: Grant
    Filed: May 21, 2007
    Date of Patent: June 12, 2012
    Assignee: BASF SE
    Inventors: Armin Diefenbacher, Hartwig Voss, Gunter Schuch, Manfred Noack, Ingolf Voigt, Hannes Richter, Juergen Caro
  • Publication number: 20120142520
    Abstract: A catalyst system is disclosed for catalytic pyrolysis of a solid biomass material. The system comprises an oxide, silicate or carbonate of a metal or a metalloid. The specific combined meso and macro surface area of the system is in the range of from 1 m2/g to 100 m2/g. When used in a catalytic process the system provides a high oil yield and a low coke yield. The liquid has a relatively low oxygen content.
    Type: Application
    Filed: April 22, 2010
    Publication date: June 7, 2012
    Applicant: KIOR INC.
    Inventors: Robert Bartek, Michael Brady, Dennis Stamires
  • Patent number: 8187992
    Abstract: The invention is directed to a catalytic principle based on zeolite crystallites attached to support or incorporated in a matrix and a catalytically active principle incorporated in the zeolite, the said crystallites having a diameter of between 20 and 300 nm and said catalytically active principle having a formula corresponding to: CoMn2(O)(R—COO)6 L1k1 L2k2 wherein: R is an optionally substituted C1-C4 alkyl; L1 is an optionally substituted nitrogen containing carboxylic acid or salts thereof; L2 is selected from the group consisting of H2O, an optionally substituted C1-C4 alkyl containing carboxylic acid, an optionally substituted C5-C6 cycloalkyl or heterocycle, an optionally substituted C5-C6 heteroaryl or aryl; and k1+k2=3; wherein the zeolite has an Si/Al atomic ratio of at least 8, as well as to a method for the oxidation of alkyl aromatics compounds employing the catalytic principle.
    Type: Grant
    Filed: December 20, 2005
    Date of Patent: May 29, 2012
    Assignee: Process Design Center B.V.
    Inventors: Herman Jozef Claudius De Meyer, Johannes Maria Franciscus Sijben
  • Patent number: 8183172
    Abstract: A catalyst is described which comprises at least one zeolite with structure type EUO, at least one zeolite selected from IM-5 zeolite and zeolites with structure type MFI, MOR, BEA and MTW, at least one group VIII metal, at least one group IIIA metal and at least one porous mineral matrix. The catalyst of the invention is used in a process for isomerizing a feed comprising aromatic compounds containing 8 carbon atoms per molecule.
    Type: Grant
    Filed: November 3, 2006
    Date of Patent: May 22, 2012
    Assignee: IFP Energies Nouvelles
    Inventors: Emmanuelle Guillon, Eric Sanchez, Sylvie Lacombe
  • Publication number: 20120122660
    Abstract: An oxidation catalyst comprises an extruded solid body comprising: 10-95% by weight of at least one binder/matrix component; 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof; and 0-80% by weight optionally stabilised ceria, which catalyst comprising at least one precious metal and optionally at least one non-precious metal, wherein: (i) a majority of the at least one precious metal is located at a surface of the extruded solid body; (ii) the at least one precious metal is carried in one or more coating layer(s) on a surface; (iii) at least one metal is present throughout the extruded solid body and in a higher concentration at a surface; (iv) at least one metal is present throughout the extruded solid body and in a coating layer(s) on a surface; or (v) a combination of (ii) and (iii).
    Type: Application
    Filed: February 1, 2011
    Publication date: May 17, 2012
    Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
    Inventors: Paul Joseph Andersen, Todd Ballinger, David Bergeal, Hsiao-Lan Chang, Hai-Ying Chen, Julian Cox, Ralf Dotzel, Rainer Leppelt, Jörg Werner Münch, Hubert Schedel, Duncan John William Winterborn
  • Patent number: 8177961
    Abstract: The present invention relates to new crystalline molecular sieve SSZ-75 prepared using a tetramethylene-1,4-bis-(N-methylpyrrolidinium) dication as a structure-directing agent, and its use in catalysts for hydrocarbon conversion reactions.
    Type: Grant
    Filed: January 14, 2010
    Date of Patent: May 15, 2012
    Assignee: Chevron U.S.A. Inc.
    Inventors: Stacey Zones, Allen Burton, Theodorus Ludovicus Michael Maesen, Berend Smit, Edith Beerdsen
  • Publication number: 20120116143
    Abstract: A lower olefin producing catalyst which has high olefin production efficiency and maintains its activity for a long period of time when lower olefins are produced from an oxygen-containing compound, which is a solid catalyst used in producing lower olefins from an oxygen-containing compound, includes a solid-state catalyst component containing an MFI-type zeolite, in which, at a position where the shortest distance to the outer surface is maximum among all positions inside a structure of the solid catalyst, the thickness defined as a distance twice the shortest distance from the point to the outer surface is in a range of from 0.1 to 2.0 mm, and a method for producing lower olefins.
    Type: Application
    Filed: December 21, 2011
    Publication date: May 10, 2012
    Applicants: MITSUBISHI CHEMICAL CORPORATION, JGC CORPORATION
    Inventors: Atsushi Okita, Kazunori Honda, Chizu Inaki, Jumpei Takahashi, Masashi Yamaguchi, Yumiko Yoshikawa, Shinji Iwade, Tohru Setoyama
  • Publication number: 20120110988
    Abstract: A NOx absorber catalyst comprising an extruded solid body comprises either: (A) 10-95% by weight of at least one binder/matrix component; and 5-90% by weight of a zeolitic molecular sieve, a non-zeolitic molecular sieve or a mixture of any two or more thereof, which catalyst comprising at least one metal comprising (a) at least one precious metal; and (b) at least one alkali metal or at least one alkaline earth metal, wherein (a) and (b) are carried in one or more coating layer(s) on a surface of the extruded solid body; or (B) 10-95% by weight of at least one binder/matrix component; and 5-80% by weight optionally stabilised ceria, which catalyst comprising at least one metal comprising (a) at least one precious metal; and (b) at least one alkali metal or at least one alkaline earth metal.
    Type: Application
    Filed: February 1, 2011
    Publication date: May 10, 2012
    Applicant: JOHNSON MATTHEY PUBLIC LIMITED COMPANY
    Inventors: Ralf Dotzel, Rainer Leppelt, Elizabeth Hazel Mountstevens, Jörg Werner Münch, Paul Richard Phillips, Hubert Schedel, Daniel Swallow
  • Publication number: 20120108415
    Abstract: A method is described for forming an aluminosilicate-zeolite layer on an aluminium-containing substrate which is transferred into an aqueous reaction dispersion containing silicon and optionally aluminium as network-forming elements, wherein, irrespective of whether or not aluminium is present in the aqueous reaction dispersion, the molar ratio of the aluminium in the aqueous reaction dispersion, optionally 0, to the sum of the designated network-forming elements contained in the aqueous reaction dispersion ranges between 0 and about 0.4, the aqueous reaction dispersion containing the aluminium-containing substrate is heated, and aluminium is extracted from the aluminium-containing substrate for the aluminosilicate-zeolite formation process, and the layer of an aluminosilicate-zeolite is formed on the aluminium-containing substrate by in situ direct crystallization.
    Type: Application
    Filed: March 1, 2010
    Publication date: May 3, 2012
    Applicant: SORTECH AG
    Inventors: Ralph Herrmann, Wilhelm Schwieger, Jurgen Bauer
  • Publication number: 20120108873
    Abstract: A method of making a catalyst containing nanosize zeolite particles supported on a support material is disclosed. A process for making styrene or ethylbenzene by reacting toluene with a C1 source over a catalyst containing nanosize zeolite particles supported on a support material is disclosed.
    Type: Application
    Filed: November 3, 2010
    Publication date: May 3, 2012
    Applicant: Fina Technology, Inc.
    Inventors: Sivadinarayana Chinta, Joseph L. Thorman
  • Publication number: 20120087838
    Abstract: A catalyst system includes a first catalytic composition and a second catalytic composition. The first catalytic composition includes a homogeneous solid mixture, which includes a first catalytic material disposed on a first substrate. The pores of the solid mixture have an average diameter of greater than about 45 nanometers. The second catalytic composition includes at least one of a zeolite or a second catalytic material disposed on a second substrate. The second catalytic material includes an element selected from the group that includes tungsten, titanium, and vanadium.
    Type: Application
    Filed: October 6, 2010
    Publication date: April 12, 2012
    Applicant: General Electric Company
    Inventors: Benjamin Hale Winkler, Dan Hancu, Daniel George Norton, Ashish Balkrishna Mhadeshwar
  • Patent number: 8153543
    Abstract: A method for preparing a composite of zeolite-fiber substrate includes the steps of reacting a fiber substrate or a zeolite with a linking compound to form an intermediate of linking compound-fiber substrate or zeolite-linking compound, and preparing the composite of zeolite-linking compound-fiber substrate by linking the intermediate of linking compound-fiber substrate to the fiber substrate or linking the intermediate of zeolite-linking compound to the zeolite, in which the linking is induced by sonication.
    Type: Grant
    Filed: October 27, 2005
    Date of Patent: April 10, 2012
    Assignee: Industry-University Cooperation Foundation Sogang University
    Inventors: Kyung Byung Yoon, Jin Seok Lee, Nak-Cheon Jeong
  • Publication number: 20120077666
    Abstract: Described are catalysts for the hydrogenation, hydroisomerisation, hydrocracking and/or hydrodesulfurisation, of hydrocarbon feedstocks, the catalysts comprising a substantially binder free bead type support material comprising 5 to 60 wt. % of at least one crystalline molecular sieve material and 40 to 95 wt. % of non-crystalline, non-zeolitic silica-alumina and a catalytically active component comprising precious metals. Also described are methods for making catalyst supports by the dropwise addition of an aqueous sol of inorganic salts of aluminum and silicon, having dispersed therein the crystalline molecular sieve material, through an oil-phase to a water phase, thus providing homogeneous beads that are obtained without a separate shape-forming step.
    Type: Application
    Filed: December 2, 2011
    Publication date: March 29, 2012
    Applicant: BASF Corporation
    Inventor: Marius Vaarkamp
  • Publication number: 20120058034
    Abstract: Extruded honeycomb catalyst bodies and methods of manufacturing same. The catalyst body includes a first oxide selected from the group consisting of tungsten oxides, vanadium oxides, and combinations thereof, a second oxide selected from the group consisting of cerium oxides, lanthanum oxides, zirconium oxides, and combinations thereof, and a zeolite.
    Type: Application
    Filed: February 26, 2010
    Publication date: March 8, 2012
    Inventors: Steven Bolaji Ogunwumi, Mallanagouda Dyamanagouda Patil, Yuming Xie, Hao Cheng, Shudong Wang
  • Publication number: 20120058018
    Abstract: A silico-alumino phosphate includes Si, Al, and P. A ratio of an amount of substance of Si to a sum of an amount of substance of Al and an amount of substance of P is approximately 0.22 or more and approximately 0.33 or less. An acid point is approximately 1.2 mmol/g or more. A honeycomb structural body includes a honeycomb unit. The honeycomb unit includes the silico-alumino phosphate and an inorganic binder. The honeycomb unit has a plurality of through-holes divided by a plurality of partition walls and arranged in a longitudinal direction of the honeycomb unit. An exhaust gas conversion apparatus includes the honeycomb structural body, a holding sealing member and a metal pipe. The holding sealing member is provided at an outer peripheral portion of the honeycomb structural body. The honeycomb structural body and the holding sealing member are installed in the metal pipe.
    Type: Application
    Filed: August 26, 2011
    Publication date: March 8, 2012
    Applicant: IBIDEN CO., LTD.
    Inventors: Masafumi Kunieda, Yosuke Matsukawa, Takunari Murakami
  • Patent number: 8128880
    Abstract: An NOx reduction catalyst and an exhaust system using the same may include an NOx reduction catalyst mounted at an exhaust pipe through which exhaust gas passes, wherein the NOx reduction catalyst includes first and second catalyst layers coated on a carrier, the first catalyst layer being disposed close to the exhaust gas, and the second catalyst layer being disposed close to the carrier, wherein a portion of nitrogen oxide contained in the exhaust gas is oxidized while passing through the first catalyst layer, and the oxidized nitrogen oxide is stored in the second catalyst layer, wherein the nitrogen oxide stored in the second catalyst layer is released through a substitution reaction with an additionally injected fuel, and wherein the released nitrogen oxide is reduced by the additionally injected fuel in the first catalyst layer.
    Type: Grant
    Filed: October 22, 2009
    Date of Patent: March 6, 2012
    Assignee: Hyundai Motor Company
    Inventors: Jin Ha Lee, Hyokyung Lee, Sangmin Lee, Jun Sung Park
  • Patent number: 8124555
    Abstract: Titanium-MWW zeolite is prepared by heating a gel formed from a titanium compound, a silicon source, a boron source, an MWW-templating agent, and water at a temperature in the range of 35° C. to 75° C. for a period of 8 to 30 hours to form a pre-crystallized gel, and heating the pre-crystallized gel to a temperature in the range of 160° C. to 190° C. for a period of 5 or more days to form the titanium-MWW zeolite. The zeolite, after it is contacted with an acid, is useful in olefin epoxidation with hydrogen peroxide.
    Type: Grant
    Filed: February 1, 2010
    Date of Patent: February 28, 2012
    Assignee: Lyondell Chemical Technology L.P.
    Inventors: Beaven S. Mandimutsira, Jay F. Miller
  • Patent number: 8110679
    Abstract: Nanofilms useful for filtration are prepared from oriented amphiphilic molecules and oriented macrocyclic modules. The amphiphilic species may be oriented on an interface or surface. The nanofilm may be prepared by depositing or attaching an oriented layer to a substrate. A nanofilm may also be prepared by coupling the oriented macrocyclic modules to provide a membrane.
    Type: Grant
    Filed: July 31, 2008
    Date of Patent: February 7, 2012
    Assignee: Covalent Partners LLC
    Inventors: Joshua W. Kriesel, Timothy B. Karpishin, Donald B. Bivin, Grant Merrill, Martin S. Edelstein, Thomas H. Smith, Jeffery A. Whiteford, Robert T. Jonas, Mark Micklatcher, Serena Joshi
  • Patent number: 8105969
    Abstract: A solid catalyst, such as a molecular sieve catalyst or solid acid catalyst, is supported by a binder, such as amorphous silica or alumina, wherein the binder is charged with metal ions to form an ion-modified binder. The ion-modified binder is capable of attachment to polar contaminants and inhibit their contact with the catalyst. The catalyst can be a zeolite and can be the catalyst for an alkylation reaction, such as the alkylation of benzene with ethylene.
    Type: Grant
    Filed: December 29, 2008
    Date of Patent: January 31, 2012
    Assignee: Fina Technology Inc.
    Inventors: Joseph E Pelati, Taylor Rives
  • Patent number: 8105968
    Abstract: Solid acid catalysts for use in alkylation processes are described. The solid acid catalysts include a multimetallic (e.g. bimetallic, trimetallic or tetrametallic) component that performs a hydrogenating function for the reactivation (or regeneration) of the catalyst in the presence of hydrogen. The multimetallic catalyst includes a noble metal such as platinum or palladium. The invention also relates to alkylation processes using the multimetallic solid acid catalysts having a multimetallic component for hydrogenation.
    Type: Grant
    Filed: October 4, 2007
    Date of Patent: January 31, 2012
    Assignee: Lummus Technology Inc.
    Inventors: Anne Mae Gaffney, Philip Jay Angevine, Cheun Yuan Yeh, Johannes Hendrik Koegler, Jingguang Chen, Emanuel Hermanus van Broekhoven
  • Publication number: 20120022224
    Abstract: Embodiments of an invention disclosed herein relate to particles made from zeolite catalysts and their use in oligomerization processes. In particular, shaped particles (for example, spheroid particles) are made from compositions including the contact product of at least one zeolite catalyst and at least one binder.
    Type: Application
    Filed: June 9, 2011
    Publication date: January 26, 2012
    Inventors: Geraldine Tosin, Marcel J. G. Janssen, Paul Hamilton, Georges M.K. Mathys
  • Publication number: 20120022279
    Abstract: A catalyst is described which comprises at least one IZM-2 zeolite and at least one matrix, said zeolite having a chemical composition expressed as the anhydrous base in terms of moles of oxides by the following general formula: XO2: aY2O3: bMnO, in which X represents at least one tetravalent element, Y represents at least one trivalent element and M is at least one alkali metal and/or alkaline-earth metal, a and b respectively representing the number of moles of Y2O3 and MnO; and a is in the range 0.001 to 0.5, b is in the range 0 to 1 and n is in the range 1 to 2. Said catalyst is used in various processes for the transformation of hydrocarbon feeds.
    Type: Application
    Filed: July 21, 2009
    Publication date: January 26, 2012
    Applicant: IFP Energies nouvelles
    Inventors: Amandine Cabiac, Nicolas Cadran, Emmanuelle Guillon, Vincent Lecocq, Sylvie Maury