Abstract: Materials with a porous structure including calcium carbonate and magnesium carbonate of mineral origin or from algae or pieces of mollusc shells, formed mainly by together with clays of the bentonite, a-sepiolite and aluminium silicate type. Their industrial use in the removal of acid gases and vapors in fixed and mobile beds and their use as agricultural fertilizers and for water treatment such as mineralization. These materials are shaped like hollow cylinders of the smooth or ribbed, straight, curved, regular or irregular cut macaroni type, and have parallel channels along the longitudinal axis in a number greater than 2 and less than 100 per square centimeter cross section generally known as monolith or honeycomb.

Abstract: This invention provides a mixing method by which a mixing object can be uniformly mixed into a gelled assembly within a short time period. The method for mixing a mixing object into a gelled assembly comprises freezing the gelled assembly; melting the frozen assembly to obtain a sol; mixing the resultant sol and the mixing object; and reconstituting the gelled assembly from the sol into which the mixing object has been mixed.

Abstract: Methods are disclosed herein for improving efficient catalyst utilization in processes including thermal catalysis using dry nanoparticle promoters, rather than salts of metal promoters in liquid form. Using selected process steps, the nanoparticles are more controllably dispersed on primary support particles, for effective use on secondary supports when it desired to bring reactants into contact with the secondary support. Applications that generally make use of these catalysts can be but are not limited to: emission abatement catalysts, generation of syngas, generation of liquid fuels from syngas, safety systems (hydrogen recombination catalysts in nuclear power plants) and many industrial processes.

Abstract: The invention relates to a method of preparing metallic nanoparticles and to the materials thus obtained. More specifically, the invention relates to a method of preparing metallic nanoparticles consisting in: selecting a precursor from the salts, hydroxides and oxides of metallic elements that can be reduced at temperatures below the clay silicate network destruction temperature; and depositing said precursor on a support selected from pseudolaminar phyllosilicate clays. According to the invention the method comprises: (i) a deposition step in which the precursor is deposited on the support: (ii) when the precursor is selected from among salts and hydroxides, a thermal decomposition step in a controlled atmosphere, in which the precursor is subjected to a decomposition process and is transformed into an oxide of the metallic element: and (iii) a reduction step in which the oxide of the metallic element is subjected to a reduction process in a controlled atmosphere.

Abstract: A mercury absorbent comprising a metal sulphide, a support material, a first binder and a second binder, wherein the first binder is a cement binder and the second binder is a high aspect ratio binder having an aspect ratio >2. A mercury removal process comprises contacting a mercury containing feed stream with the absorbent.

Abstract: Sorbents for removal of mercury and other pollutants from gas streams, such as a flue gas stream from coal-fired utility plants, and methods for their manufacture and use are disclosed. Embodiments include brominated sorbent substrate particles having a carbon content of less than about 10%. Other embodiments include one or more oxidatively active halides of a nonoxidative metal dispersed on sorbent substrate particles mixed with activated carbon in an amount up to 30% by weight. Further embodiments include physical blending of a flow modifier into the sorbent composition.

Abstract: Methods are disclosed herein for improving efficient catalyst utilization in processes including thermal catalysis using dry nanoparticle promoters, rather than salts of metal promoters in liquid form. Using selected process steps, the nanoparticles are more controllably dispersed on primary support particles, for effective use on secondary supports when it desired to bring reactants into contact with the secondary support. Applications that generally make use of these catalysts can be but are not limited to: emission abatement catalysts, generation of syngas, generation of liquid fuels from syngas, safety systems (hydrogen recombination catalysts in nuclear power plants) and many industrial processes.

Abstract: The present invention relates to a composition comprising calcined kaolin having a narrow particle size distribution. The composition can have many uses, such as fillers or extenders in paint, plastics, polymers, papermaking, and coating compositions. More generally, the inventive products may be used wherever calcined kaolins are used.

Abstract: The invention relates to a rheological additive comprising illite clay, smectic clay and an attapulgite suitable for controlling the application characteristics of a coating material for porous bodies.

Abstract: A method includes collapsing a polymer on a precursor moiety including a catalyst to form a composite having the polymer and the precursor moiety; and forming a nanoparticle from the composite.

Abstract: The present invention relates to a supported catalyst composition for polymerization of olefins comprising at least two catalytic components; and a polymerization process using that catalyst composition; and a method for its preparation.

Abstract: The present invention relates to an animal litter comprising a carrier material of calcium silicate, which is at least coated with sodium-containing bentonite, the animal litter comprising a complexing agent for complexing free calcium ions and/or a component forming poorly soluble salts with calcium ions, and to a process for preparing it.

Abstract: An animal litter such as a clay material is treated to reduce the bulk density thereof by contacting the clay material with an aqueous electrolyte solution and then heating at an elevated temperature. Substantial reductions in bulk density have been achieved without reducing the absorption capacity of the clay granule.

Abstract: The invention relates to a method for improving vermiculite's intake of ammonium, in which method heating of the crude vermiculite is conducted to a temperature where vermiculite's third dehydration step takes place, the temperature being lower than the temperature where vermiculite's fourth dehydration/dehydroxylation step takes place. The invention relates also to use of the obtained vermiculite and to an absorption material, comprising vermiculite material and additives, where at least 50% of the vermiculite material comprises vermiculite, which has undergone the third dehydration step but not the fourth dehydration/dehydroxylation step. The invention relates also to use of thermally treated and ammonium doped vermiculite as fertilizer/soil conditioner.

Abstract: The invention concerns an absorbent composition comprising: (a) at least 50 wt.-% of the overall composition have a particle size of less than 150 ?m and are comprised of at least one absorbent component; and (b) at least 1.0 wt.-% of the overall composition have a particle size of at least 250 ?m and are comprised of at least one particulate component, and its preferred uses.

Abstract: The invention relates to a method for producing an adsorbent, in particular a bleaching earth, wherein a clay material having: a surface area of 180 to 300 m2/g; a total pore volume of 0.5 to 0.7 ml/l; wherein at least 60% of the total pore volume are provided by pores having a pore diameter of at least 140 A, at least 40% of the total pore volume is provided by pores having a pore diameter of less than 250 A and at least 15% of the total pore volume are provided by pores having a pore diameter of 140 to 250 A; and said clay material having an amorphous structure according to XRD data; is activated by an activation procedure. Further, the invention relates to an adsorbent as obtained by the method and a method for purification of oils, fats and biofuels.

Abstract: This invention is directed to hydrocracking catalysts and hydrocracking processes employing a magnesium aluminosilicate clay. The magnesium aluminosilicate clay has a characteristic 29Si NMR spectrum. The magnesium aluminosilicate clay is the product of a series of specific reaction steps. Briefly, the magnesium aluminosilicate clay employed in the catalyst and process of the present invention is made by combining a silicon component, an aluminum component, and a magnesium component, under aqueous conditions and at an acidic pH, to form a first reaction mixture and subsequently the pH of the first reaction mixture is adjusted to greater than about 7.5 to form a second reaction mixture. The second reaction mixture is allowed to react under conditions sufficient to form the magnesium aluminosilicate clay. The resulting magnesium aluminosilicate clay combines high surface area and activity for use in hydrocracking catalysts and processes.

Abstract: The disclosed invention relates to a blended hydrous kaolin clay product comprising a platy coarse kaolin clay and a fine, hydrous kaolin clay. The blended kaolin clay product is suitable for use as a raw material component in the formation of cordierite products.

Abstract: A radioactive containment composition may be created for containing radionuclides from a radioactive material by mixing a clay mineral with water. This mixture may form an aqueous clay suspension. The mixture can be refined by filtering to remove coarse material. The aqueous clay suspension may be applied to a radioactive material, allowing the radionuclides to be exchanged with cations in the aqueous clay suspension. The resulting aqueous slurry, a silver-based solution may be added to produce a suspension. The suspension may be collected, heated and analyzed.

Abstract: Stable catalyst carrier impregnating solutions can be prepared using a component of a Group VIB metal, e.g., molybdenum, at high concentration, a component of a Group VIII metal, e.g., nickel, at low concentration, and a phosphorous component, e.g., phosphoric acid, at a low concentration, provided that the Group VIII metal is in a substantially water-insoluble form and a particular sequence of addition of the components is followed, even when a substantially water-insoluble form of the Group VIB component is used. The resulting stabilized impregnating solution can be supplemented with additional Group VIII metal in water-soluble form to achieve increased levels of such metal in the final catalyst. Furthermore, uncalcined catalyst carriers impregnated with the stable solution and subsequently shaped, dried and calcined, have unexpectedly improved performance when used in the hydroprocessing of heavy hydrocarbon feedstocks.

Abstract: A honeycomb structure includes at least one honeycomb unit. The at least one honeycomb unit has a longitudinal direction and cell walls extending from one end face to another end face along the longitudinal direction to define cells. The at least one honeycomb unit includes an inorganic binder, and zeolite ion-exchanged with plural kinds of metal ions.

Abstract: A honeycomb structure includes a honeycomb unit containing zeolite and an inorganic binder and having cell walls extending from one end to another end along a longitudinal direction of the honeycomb unit to define cells. An amount of zeolite contained per apparent unit volume of the honeycomb unit is approximately 230 g/L or more. A thickness X mm of the cell walls is in a range from approximately 0.15 mm to approximately 0.35 mm. A mathematical formula 40X+20?Y?40X+30 is satisfied when a porosity of the cell walls is defined as Y %.

Abstract: A hemostatic device for promoting the clotting of blood includes a gauze substrate, a clay material disposed on the gauze substrate, and also a polyol such as glycerol or the like disposed on the gauze substrate to bind the clay material. When the device is used to treat a bleeding wound, at least a portion of the clay material comes into contact with blood emanating from the wound to cause the clotting. A bandage that can be applied to a bleeding wound to promote the clotting of blood includes a flexible substrate and a gauze substrate mounted thereon. The gauze substrate includes a clay material and a polyol. A hemostatic sponge also includes a gauze substrate and a dispersion of hemostatic material and a polyol on a first surface of the substrate.

Abstract: Novel compositions of matter comprising a cationic layered material and a second compound. The second compound has a reflection in its XRD pattern at 18.5 degrees two-theta, and s second reflection at 29 degrees two-theta. The composition of matter may be used in hydrocarbon conversion, purification, and synthesis processes, such as fluid catalytic cracking and hydroprocessing. The materials are especially suitable for the reduction of SOx and NOx emissions and the reduction of the sulfur and nitrogen content in fuels like gasoline and diesel.

Abstract: The invention relates to a composition comprising anionic clay and rare earth metal hydroxy carbonate. This composition can suitably be used in FCC for the reduction of NOx and/or SOx emissions, the reduction of the S and/or N-content in fuels, and as a metal trap. The composition can be prepared by precipitating a divalent metal salt, a trivalent metal salt, and a rare earth metal salt to form a precipitate, calcining the precipitate at 200-800° C., and rehydrating the precipitate in the presence of a carbonate source to form a composition comprising anionic clay and a rare earth metal hydroxy carbonate.

Abstract: The use of two mercury and arsenic removal media: A) a sulfur-impregnated organoclay; and B) a coupling agent-reacted organoclay, wherein the coupling agent preferably contains a mercapto, disulfide, tretrasulfide and/or polysulfide end group provides mercury removal media having increased reactivity, stability, and synergistic mercury removal ability. The preferred mercury removal media described herein is prepared by reacting an organophilic clay containing onium ions A) with elemental sulfur; and B) with a sulfur-containing coupling agent, preferably containing a mercapto, disulfide, tetrasulfide, and/or polysulfide moiety.

Abstract: Sorbents for removal of mercury and other pollutants from gas streams, such as a flue gas stream from coal-fired utility plants, and methods for their manufacture and use are disclosed. Embodiments include brominated sorbent substrate particles having a carbon content of less than about 10%. Other embodiments include one or more oxidatively active halides of a nonoxidative metal dispersed on sorbent substrate particles mixed with activated carbon in an amount up to 30% by weight.

Abstract: After newly attaching an interior-finishing vinyl wall covering onto at least one of a wall, floor and ceiling of a building, or after completion of washing/renovation of the vinyl wall covering, a liquid or slurry coating material containing a titanium oxide, a layered silicate mineral, and a silver ion and/or a copper ion, is sprayed or applied onto a surface of the vinyl wall covering. Subsequently the coating material is naturally dried to form a thin transparent coating layer. In a process of renovating the vinyl wall covering, the coating layer is removed by washing with water or wiping with water to completely remove various stains. The present invention makes it possible to allow any worker, i.e., even an unskilled worker, to fully renovate an interior-finishing material, such as a vinyl wall covering, without difficulty and at low cost.

Abstract: The present invention includes a microporous or mesoporous composition of matter in which the composition is formed continuously or semi-continuously in a heated reactor zone, including a rotary calciner or a rotary screw as a means for conveying the synthesis mixture, at a temperature between 200° C. and 500° C. with a residence time less than 24 hours. The reagents are solid and liquid reagents in which the solid reagents have a weight percent between 45% and 98% of the total reagents. The invention also includes a continuous or semi-continuous process for the hydrothermal manufacture of the microporous or mesoporous composition.

Abstract: The water gas shift catalyst for a reformer of a fuel cell system where a supporter includes a clay and ZnO filled between layers of the clay; and an active material including CuO supported on the supporter.

Abstract: The use of two mercury and arsenic removal media: A) a sulfur-impregnated organoclay; and B) a coupling agent-reacted organoclay, wherein the coupling agent preferably contains a mercapto, disulfide, tretrasulfide and/or polysulfide end group provides mercury removal media having increased reactivity, stability, and synergistic mercury removal ability. The preferred mercury removal media described herein is prepared by reacting an organophilic clay containing onium ions A) with elemental sulfur; and B) with a sulfur-containing coupling agent, preferably containing a mercapto, disulfide, tetrasulfide, and/or polysulfide moiety.

Abstract: A carrier and a catalyst useful for the oxidation of ethylene to ethylene oxide which uses the carrier. The carrier is composed of an inert, refractory solid support such as alpha alumina and has a surface exhibiting a plurality of nanometer scale protrusions projecting outwardly from the surface, and has a catalytically effective amount of silver thereon.

Abstract: The invention relates to a process for the epoxidation of an olefin, wherein the concentration of the olefin oxide in the outlet is greater than about 2.2% by volume. More particularly, the invention relates to a process for the epoxidation of ethylene by contacting a feed including at least ethylene and oxygen with an improved epoxidation catalyst. The catalyst which has improved selectivity in the epoxidation process at high productivities, includes a solid support having a surface, which has a first mode of pores that have a diameter ranging from about 0.01 ?m to about 5 ?m and having a differential pore volume peak in the range from about 0.01 ?m to about 5 ?m. The surface also has a second mode of pores, which is different from the first mode of pores, having a diameter ranging from about 1 ?m to about 20 ?m and have a differential pore volume peak in the range from about 1 ?m to about 20 ?m.

Abstract: A gas storage assembly that has an enclosure within which are disposed at least about 100 inorganic tubules are present for each cubic micron of volume of the enclosure. The assembly has a storage capacity of at least 20 grams of hydrogen per liter of volume of the enclosure.

Abstract: A catalyst for use in the Fischer-Tropsch process, and a method to prepare the catalyst is disclosed. The catalyst of the present invention has a higher surface area, more uniform metal distribution, and smaller metal crystallite size than Fischer-Tropsch catalysts of the prior art.

Abstract: A molecular sieve-containing catalyst for cracking hydrocarbons, comprising molecular sieve, refractory inorganic oxide, clay and a metal component, wherein the amount of said molecular sieve is from 1 to 90% by weight, the refractory inorganic oxide is from 2 to 80% by weight, the clay is from 2 to 80% by weight, and the metal component is from 0.1 to 30% by weight, calculated as the oxide of said metal having its maximum valence state, based on the total amount of the catalyst, wherein said metal component exists essentially in a reduction state and is one or more metals selected from the group consisting of metals of Group IIIA (other than aluminum), and metals of Group IVA, VA, IB, IIB, VB, VIB and VIIB, and non-noble metals of Group VIII of the periodic table. The catalyst has higher cracking activity and higher sulfur reduction activity.

Abstract: Process for the preparation of an additive-containing anionic clay comprising the steps of (a) preparing a physical mixture of a divalent and a trivalent metal compound, (b) calcining the physical mixture at a temperature in the range 200-800° C. without performing a prior aging or shaping step, thereby forming a product containing at least 5 wt % of a rehydratable compound, and (c) rehydrating the calcined mixture in aqueous suspension containing an additive to form the additive-containing anionic clay. This process provides a simple and cost-effective way of preparing additive-containing anionic clays. The process does neither require aging or reaction steps before calcination, nor does it require precipitation of metal salts or the handling of inhomogeneous slurries.

Abstract: The invention relates to a method for forming a material of a metal oxide supported on a support particle by the steps of. a) providing a precursor mixture comprising a solution containing one or more metal cations and (i) a surfactant; or (ii) a hydrophilic polymer; with the precursor mixture further including support particles; and b) treating the precursor mixture from (a) above by heating to remove the surfactant or hydrophilic polymer and form metal oxide having nano-sized grains, wherein at least some of the metal oxide formed in step (b) is deposited on or supported by the support particles and the metal oxide has an oxide matrix that includes metal atoms derived solely from sources other than the support particles.

Abstract: The use of a sulfur-impregnated organoclay provides a mercury or arsenic removal media having increased reactivity, stability, and mercury removal ability. The Hg/As removal media described herein is prepared by impregnating an organophilic clay with elemental (free state) sulfur. Alternatively, the clay can be made organophilic by onium ion reaction prior to or simultaneously with impregnating the organoclay with sulfur.

Abstract: The present invention relates to a solid, acid catalyst for the preparation of polytetrahydrofuran, polytetrahydrofuran copolymers, diesters or monoesters of these polymers by polymerization of tetrahydrofuran in the presence of at least one telogen and/or comonomer, which has a BET surface area of at least 160 m2/g and an acid center density of at least 0.05 mmol/g for pKa values of from 1 to 6, to a process for preparing it and to a process for the polymerization of cyclic ethers over this catalyst.

Abstract: The invention relates to a process for producing granules and to a granule obtained by the process. In the process, a clay material is used which has a specific surface area of more than 150 m2/g, a pore volume of more than 0.45 ml/g and a cation exchange capacity of more than 15 meq/100 g.

Abstract: The present invention relates to a solid, acid catalyst for the preparation of polytetrahydrofuran, polytetrahydrofuran copolymers, diesters or monoesters of these polymers by polymerization of tetrahydrofuran in the presence of at least one telogen and/or comonomer, which has a BET surface area of at least 160 m2/g and an acid center density of at least 0.05 mmol/g for pKa values of from 1 to 6, to a process for preparing it and to a process for the polymerization of cyclic ethers over this catalyst.

Abstract: The invention relates to a catalyst composition, a method of making the same and its use in a process for converting synthesis gas to alcohols. The catalyst composition comprises an anionic clay hydrotalcite and a catalytically active metal component, such as rhodium, manganese, cobalt, copper, and a mixture thereof.

Abstract: This invention relates to a process for the preparation of a fluid catalytic cracking catalyst with improved attrition resistance. According to this preparation process, an aqueous slurry comprising a zeolite, day, and poly aluminum chloride is spray-dried and subsequently calcined, the poly aluminum chloride having the formula [Al2(OH)yCl6-y]x, wherein x is at least 1 and y is greater than 2 and smaller than 4.

Abstract: A layered catalyst is disclosed for use in transalkylation of polyalkylated benzenes. The catalyst comprises an inner core material with a molecular sieve bonded over the core, The process minimizes the cracking of the alkyl groups during the transalkylation reaction.

Abstract: A method for producing an adsorbing agent, an absorbing agent obtained by the method, and its use as bleaching earth, in particular for refining oils and fats, is described. In the method according to the invention, a raw clay with a specific surface area of more than 200 m2/g, an ion exchange capacity of more than 40 meq/100 g and a pore volume of more than 0.5 ml/g is used. At least 40% of the pore volume are provided by pores which have a pore diameter of at least 14 nm, and at most 25% of the pore volume are provided by pores which have a diameter of less than 7.5 nm. Surface activation with an acid gives an adsorbing agent which has a bleaching activity which partly exceeds that of high performance bleaching earths obtained by intensive dealuminization and washing with strong acid.

Abstract: Disclosed are an animal litter, a process for preparing the animal litter, and a method for removal of animal waste. The method for removal of animal waste comprises providing a copra residue, such as copra cake or copra oil cake, allowing an animal to excrete waste into the litter, and removing at least a portion of the soiled litter. An animal litter in accordance with the disclosed teachings includes a copra residue in combination with one or more absorbent materials, such as clay, whole ground grain, spent grain germ, or any other absorbent material. The process for preparing the animal litter comprises blending copra residue with one or more absorbent materials. The animal litters disclosed herein may include other ingredients, such as additional absorbent materials, preservatives, and so forth.

Abstract: Disclosed in this specification is an apparatus for storing hydrogen which is comprised of molecular hydrogen, halloysite rods, and a supporting substrate wherein hydrogen is stored within the lumen of the halloysite rods.

Abstract: The disclosure relates to metal nanoparticle compositions and methods of making such nanoparticle compositions that are useful for the production of electrically conductive features and catalysts.

Abstract: A flexible adsorbent body comprising, a thermoplastic polymer matrix and a porous adsorbing material, wherein said body possesses a flexural module of elasticity at 23° C. greater than about 10 MPa.