The Nitrogen And A Nitro Group Bonded Directly To The Same Benzene Ring (e.g., Nitroanilines, Etc.) Patents (Class 504/347)
  • Patent number: 6753298
    Abstract: Compositions for controlling diseases caused by protozoans of the genus Neospora, which are characterized in that they comprise one or more active compounds which inhibit the microtubulin system of plants.
    Type: Grant
    Filed: December 2, 2002
    Date of Patent: June 22, 2004
    Assignee: Bayer AG
    Inventors: Gisela Greif, Folker Lieb, Carl Fedtke
  • Patent number: 6673748
    Abstract: The present invention provides a method for the synergistic control of undesirable plants such as Poa, Polygonum and Setaria which comprises applying to the plants or their locus a synergistically effective amount of a combination of a dinitroaniline compound and an imidazolinone compound. Further provided are synergistic herbicidal compositions comprising dinitroaniline and imidazolinone compounds.
    Type: Grant
    Filed: April 4, 2000
    Date of Patent: January 6, 2004
    Assignee: BASF Aktiengesellschaft
    Inventor: Pascal Foessel
  • Patent number: 6617280
    Abstract: The present invention provides a continuous process for the preparation of a stable aqueous suspension concentrate composition of pendimethalin, alone or in combination with another pesticide, which comprises mixing a molten stream of pendimethalin with a cold aqueous stream containing coformulants plus seed crystals of orange pendimethalin.
    Type: Grant
    Filed: August 24, 2001
    Date of Patent: September 9, 2003
    Assignee: BASF Aktiengesellschaft
    Inventors: Jean-Paul Fafchamps, Jean-Michel Villanueva
  • Publication number: 20030125211
    Abstract: The present invention relates to a homogenous adjuvant blend for use in spray carriers containing herbicides. The homogenous adjuvant blend includes a nitrogen fertilizer, a pH adjuster, modified vegetable oil, and a blend of nonionic surfactants having high, intermediate, and low hydrophilic-lipophilic balance (HLB).
    Type: Application
    Filed: November 14, 2001
    Publication date: July 3, 2003
    Applicant: North Dakota State University
    Inventors: Zenon J. Woznica, Calvin Messersmith, John Nalewaja
  • Patent number: 6566308
    Abstract: The invention relates to a stable emulsifiable concentrate (EC) for crop protection active compounds which comprises (a) one or more crop protection active compounds, (b) 150 to 500 g/l of one or more adjuvants, (c) optionally one or more organic, non-polar solvents, (d) an emulsifying surfactant system forming an oil in water emulsion when the formulation is added to water, which essentially consists of one or more non-ionic surfactants, and one or more anionic surfactants, (e) a water-miscible polar aprotic solvent or one or more dimethyl dicarboxylates, and (f) optionally an antifoam agent, and to the use of such a suspension as a pesticide.
    Type: Grant
    Filed: December 17, 1999
    Date of Patent: May 20, 2003
    Assignee: BASF Aktiengesellschaft
    Inventor: Michael Aven
  • Publication number: 20020128154
    Abstract: The present invention provides a continuous process for the preparation of a stable aqueous suspension concentrate composition of pendimethalin, alone or in combination with another pesticide, which comprises mixing a molten stream of pendimethalin with a cold aqueous stream containing coformulants plus seed crystals of orange pendimethalin.
    Type: Application
    Filed: August 24, 2001
    Publication date: September 12, 2002
    Applicant: Intellectual Property Department BASF Aktiengesellschaft
    Inventors: Jean-Paul Fafchamps, Jean-Michel Villanueva
  • Patent number: 6444618
    Abstract: The novel emulsifiable concentrate (EC) formulation comprising at least one pesticidal crop protection active compound, at least one non-polar organic solvent, optionally, at least one polar aprotic cosolvent, an emulsifying surfactant system enabling an oil-in-water emulsion to be formed when the formulation is added to water, and at least one defoaming or foam breaking agent selected from the group consisting of perfluoroalkylphosphonic acids, perfluoroalkylphosphinic acids and perfluoroaliphatic polymeric esters is useful for combating pests or diseases caused by pests at a locus by treating the locus with a composition obtained from emulsifying the EC in water.
    Type: Grant
    Filed: January 26, 2000
    Date of Patent: September 3, 2002
    Assignee: BASF Aktiengesellschaft
    Inventors: Michael Aven, Friedrich Schmidt
  • Patent number: 6112459
    Abstract: It has been known that water having a pH value of 5.5 to 7.5 is suited for the rearing of fresh-water fish and hydroponic cultivation of plants. Bottom soils or filtering media prepared by mixing carbonates of alkali metals or alkali-earth metals with volcano-ash-base soils and sintering the mixture into granules. When used in water tanks or reservoirs for fish rearing or hydroponic cultivation, the bottom soils or filtering media thus prepared provide favorable environments for such rearing and cultivation.
    Type: Grant
    Filed: May 28, 1998
    Date of Patent: September 5, 2000
    Assignee: Hirose Co., Ltd.
    Inventor: Mitsuru Hirose
  • Patent number: 5985793
    Abstract: A novel method is provided wherein plants are first treated with an exogenous chemical (e.g., glyphosate herbicide) and then sequentially treated with a liquid accession agent which provides improved biological (e.g., herbicidal) effectiveness such that plants are controlled with lower rates of the applied exogenous chemical (e.g., glyphosate herbicide). Sequential application has been demonstrated to reduce the antagonism to herbicidal effectiveness that can be exhibited when the accession agent is added to a herbicide in a tank mix or simple coformulation. Typical accession agents employed in the disclosed method include a class of surfactants known as superwetting agents, such as certain organosilicone-based and fluorocarbon-based surfactants.
    Type: Grant
    Filed: August 14, 1997
    Date of Patent: November 16, 1999
    Assignee: Monsanto Company
    Inventors: Joseph J. Sandbrink, James M. Warner, Daniel R. Wright, Paul C. C. Feng
  • Patent number: 5922915
    Abstract: A simple and inexpensive process is described for reducing the concentration of N-nitroso-containing compounds. The process is applicable for compositions comprising N-nitroso-containing compounds and other desired compounds wherein the N-nitroso-containing compounds thermally decompose at a temperature below the decomposition temperature of the desired compounds. For compositions comprising N-nitroso-pendimethalin in Pendimethalin, the process requires heating the mixture to a temperature greater than about 120.degree. C., and holding the Pendimethalin at that temperature for a time effective to decompose the N-nitroso-pendimethalin present in the mixture. Volatile decomposition products are advantageously removed from the composition.
    Type: Grant
    Filed: May 11, 1998
    Date of Patent: July 13, 1999
    Assignee: SRM Chemical, Ltd., Co.
    Inventors: Lowell J. Lawrence, Stefan Kwiatkowski
  • Patent number: 5906961
    Abstract: An adjuvant composition containing at least an alkanolamide surfactant and optionally other surfactants or pesticides or formulation aids. The surfactant preferably is reacted with a fatty acid. The process preferably takes places without the use of alkoxylation.
    Type: Grant
    Filed: May 29, 1997
    Date of Patent: May 25, 1999
    Assignee: Helena Chemical Company
    Inventors: Johnnie R. Roberts, Greg Volgas
  • Patent number: 5866514
    Abstract: A pesticidal composition to noxious organisms which comprises a diarylalkane and an active component effective for killing or repelling noxious organisms and the diarylalkane is at least one member selected from the group consisting of butyl diphenylmethane, butyl-1,1-diphenylethane and butyl-1,2-diphenylethane. The used diarylalkane has a high dissolving power to the effective component, a high boiling point and a high flash point with low unpleasant smell and does not deteriorate the effective component in the pesticidal composition.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: February 2, 1999
    Assignee: Nippon Petrochemicals Company, Limited
    Inventors: Kunio Sugisawa, Yasuo Togami, Toshikatsu Shouko
  • Patent number: 5776855
    Abstract: The invention relates to a new solid storage and marketing presentation for phytosanitary compositions based on any active substance which is little soluble in water or insoluble in water and solid at ambient temperature; these active substances are especially selected from herbicides presenting the said features; these herbicides comprise bramoxynil, ioxynil and their esters as well as. dinitroanilines, especially butralin, pendimethalin, flumetralin and oryzalin.It is in the form of flakes based on a film-forming material which is water-soluble and brittle after drying, and throughout which are dispersed especially the particles of active material.This solid storage and marketing presentation may be prepared by maly of an installation comprising a rotating drying drum (1) on which a thin layer of a dispersion (D) of particles of active substance in an aqueous solution of a film-forming material which is brittle at the dry state is applied.
    Type: Grant
    Filed: July 10, 1996
    Date of Patent: July 7, 1998
    Assignee: CFPI AGRO
    Inventors: Joseph Schapira, Jacques Vincent, Ange-Claude Guerin, Jean-Paul Fournials
  • Patent number: 5770545
    Abstract: This invention relates to pendralin ?2,6-dinitro-N-(1-ethylpropyl)-4-tert-butylaniline!, preemergence and postemergence herbicidal methods and herbicidal compositions employing pendralin.
    Type: Grant
    Filed: March 14, 1997
    Date of Patent: June 23, 1998
    Assignee: SRM Chemical, Ltd. Co.
    Inventors: Lowell J. Lawrence, Terry L. Johnson, Stephan Kwiatkowski, Paul D. Smith
  • Patent number: 5744423
    Abstract: A method and device are used for controlling growth of plants in pavement splits by preventing seeds from germinating and by preventing growth of plants from existing roots in the vicinity of the splits. The growth of plants is controlled for extended periods of time (2 to 20 years). A pre-emergence herbicide and a systemic herbicide are incorporated into a polymeric matrices. The polymeric matrices are formed into shaped objects, such as, bands or cords which are then inserted into splits. The split is then filled with a sealer which permits easy migration of the herbicides therethrough. The herbicides gradually released from the shaped objects at a rate sufficient to maintain a minimal effective level of herbicide outside said sealer for a predetermined period of time.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 28, 1998
    Assignee: Battelle Memorial Institute
    Inventors: Peter Van Voris, Dominic A. Cataldo, Frederick G. Burton, W. Eugene Skiens
  • Patent number: 5679619
    Abstract: The present invention relates to novel stable aqueous suspension concentrate or aqueous flowable compositions of the low-melting dinitroaniline pesticide, pendimethalin, in combination with secondary herbicide(s) melting at temperatures greater than 70.degree. C. or herbicides which are water soluble. Uniquely, pendimethalin may be present in the compositions of the invention in a ratio of orange crystal form to yellow crystal form of 4:96, up to totally orange crystal form. Additionally are provided methods for preparing the compositions containing pendimethalin alone or in combination with the secondary herbicides.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: October 21, 1997
    Assignee: American Cyanamid Company
    Inventors: Leonard John Morgan, Mark Bell
  • Patent number: 5654258
    Abstract: A solid, water dispersible, storage-stable trifluralin formulation comprises trifluralin supported inside porous, finely divided carrier particles, optionally together with at least one compatible wetting agent and/or dispersant additive, wherein the trifluralin is in the orange polymorphic form and the particles of the formulation are size-stable.
    Type: Grant
    Filed: September 13, 1995
    Date of Patent: August 5, 1997
    Assignee: Daratech Pty. Ltd.
    Inventors: Darren James Park, Gottfried Lichti
  • Patent number: 5635447
    Abstract: A herbicide composition which comprises a herbicide and a small but herbicide absorption enhancing effective amount of a water soluble, non-aromatic polyorganic acid or a salt or copolymer thereof such as polyaspartic acid.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: June 3, 1997
    Assignee: Donlar Corporation
    Inventor: J. Larry Sanders
  • Patent number: 5624884
    Abstract: The present invention relates to novel stable aqueous suspension concentrate or aqueous flowable compositions of the low-melting dinitroaniline pesticide, pendimethalin, in combination with secondary herbicide(s) melting at temperatures greater than 70.degree. C. or herbicides which are water soluble. Uniquely, pendimethalin may be present in the compositions of the invention in a ratio of orange crystal form to yellow crystal form of 4:96, up to totally orange crystal form. Additionally are provided methods for preparing the compositions containing pendimethalin alone or in combination with the secondary herbicides.
    Type: Grant
    Filed: June 7, 1995
    Date of Patent: April 29, 1997
    Assignee: American Cyanamid Company
    Inventors: Leonard J. Morgan, Mark Bell
  • Patent number: 5510534
    Abstract: The present invention is directed to a process for reducing the nitrosamine content in a herbicide derived from dinitroaniline. The herbicide is treated with an aqueous solution of alkaline or ammonium persulfate in a proportion of at least 0.5% w/w relative to the weight of the herbicide to form an aqueous suspension. The suspension is heated to at least 70.degree. C., and the herbicide is separated from the suspension.
    Type: Grant
    Filed: March 23, 1995
    Date of Patent: April 23, 1996
    Assignee: Atanor S.A.
    Inventors: Maria D. C. Breglia De Belcoure, Marta M. D. C. Ruiz
  • Patent number: 5461027
    Abstract: Pendimethalin microencapsulated in a microcapsule comprised of a water-soluble film forming polymer. The present invention also includes a method of microencapsulating low-melting agriculturally active materials, such as pendimethalin. The microencapsulation process comprises the steps of heating pendimethalin to a molten state. The molten pendimethalin is then combined with an aqueous solution of a water-soluble, film-forming polymer at a temperature sufficient to maintain the pendimethalin in its molten state. The pendimethalin is then emulsified in the aqueous solution so that the pendimethalin has a primary particle size of between approximately 0.1 and 10 microns. The resulting dispersion or emulsion is then spray dried at a temperature between approximately 50.degree. C. and 220.degree. C. so as to microencapsulate the pendimethalin in the polymer. Compounds for promoting the rapid solidification of the pendimethalin am also disclosed.
    Type: Grant
    Filed: October 27, 1993
    Date of Patent: October 24, 1995
    Assignee: Griffin Corporation
    Inventor: Elliot Bergman
  • Patent number: 5403813
    Abstract: A controlled release agricultural composition comprising an aqueous dispersion of: 1) a water insoluble matrix comprising a viscous oil (i.e., a hydrocarbon crude oil or post-refining residual oil) selected from the group consisting of bitumen, abietic acid, ester derivatives of abietic acid, carboxylic acid containing materials, and carboxylic acid ester containing materials, and 2) at least one active ingredient, which has a melting point of less than 140.degree. C. and is soluble in the viscous oil matrix, selected from the group consisting of herbicides, insecticides, fungicides, and nematicides.
    Type: Grant
    Filed: January 18, 1993
    Date of Patent: April 4, 1995
    Assignee: Daratech Proprietary Limited
    Inventors: Gottfried Lichti, Anthony G. Flynn, Alexander Serban, Darren J. Park, William R. Jackson, Janine J. Kibblewhite, Paul A. Horne, Daryl K. Wood, Jin L. Chen
  • Patent number: 5385948
    Abstract: A solvent for producing emulsifiable concentrates from agriculturally active chemicals which are insoluble in water comprises an alkoxyalkyl lactam such as butoxy propyl pyrrolidone. An agriculturally active chemical and the alkoxyalkyl lactam are admixed optionally with co-solvents, emulsifiers and surfactants to produce a stable emulsifiable concentrate. The concentrate is dilutable with water at the point of use to produce either macro or micro emulsions which are themselves stable to assure even application.
    Type: Grant
    Filed: February 16, 1993
    Date of Patent: January 31, 1995
    Assignee: ISP Investments Inc.
    Inventors: Ratan K. Chaudhuri, Kolazi S. Narayanan, Lowell R. Anderson
  • Patent number: 5374607
    Abstract: Phytopharmaceutical wettable powder comprising at least one phytopharmaceutical active substance which is solid at ambient temperature and at least one pulverulent inert filler, characterized by the fact that the constitutive particles of the filler constitute a support or carrier for the active substance comprised within a liquid composition, said active substance being selected from the group comprising:the esters of the family of the parahydroxybenzonitriles of the group comprising bromoxynil octanoate, bromoxynil heptanoate, bromoxynil butyrate, ioxynil octanoate, ioxynil heptanoate, ioxynil butyrate,the triazines of the group comprising simazine, atrazine and ametryne,the dinitroanilines of the group comprising butraline, pendimethaline, trifluraline, orizaline,the substituted ureas of the group comprising diuron, isoproturon, ethidimuron,the sulphonylureas of the group comprising especially chlorsulfuron.
    Type: Grant
    Filed: January 3, 1994
    Date of Patent: December 20, 1994
    Assignee: C F P I
    Inventors: Joseph Schapira, Jacques Schild, Jacques Pecheur, Ange C. Guerin, Dominique Ambrosi, Jean-Jacques Fuchs, Bernard Guyenet
  • Patent number: 5362707
    Abstract: The present invention relates to new plant-protection suspo-emulsions. More specifically, the invention relates to a suspo-emulsion of a solid active substance, having a melting point greater than or equal to 45.degree. C. and which is substantially insoluble in water. The suspo-emulsion comprises at least one oil; a first surface-active system comprising at least sucroglycerides; the solid active substance; and either (A) a nonionic or anionic surface-active agent, or (B) a second surface-active system containing sucroglycerides and at least one compound selected from the group consisting of an alkoxylated triglyceride, an alkoxylated fatty acid, a sorbitan ester, and an alkoxylated sorbitan ester, and optionally a phospholipid.
    Type: Grant
    Filed: December 10, 1991
    Date of Patent: November 8, 1994
    Assignee: Rhone-Poulenc Chimie
    Inventors: Jean-Francois Fiard, Jean-Michel Mercier, Marie-Luce Prevotat
  • Patent number: 5317004
    Abstract: Agriculturally active materials, such as pesticides, herbicides and the like and a process for microencapsulating said materials. The present invention includes trifluralin having a polymorphic form characterized by a yellow color and a melting point of approximately 41.degree.-43.degree. C. The present invention also includes a method of using the yellow polymorphic form of trifluralin as a herbicide. In addition, the present invention includes a method of microencapsulating low-melting agriculturally active materials, such as trifluralin. The microencapsulation process comprises the steps of heating a low-melting, water-immiscible, agriculturally active material to a molten state. The molten active material is then combined with an aqueous solution of a water-soluble, film-forming polymer at a temperature sufficient to maintain the active material in its molten state.
    Type: Grant
    Filed: November 12, 1992
    Date of Patent: May 31, 1994
    Assignee: Griffin Corporation
    Inventors: John Misselbrook, Larry J. McKinney, James H. Lefiles, Edwin F. Hoff, Jr., Elliot Bergman
  • Patent number: 5312798
    Abstract: There is disclosed a herbicidal composition comprising as active ingredients a herbicidally effective amount of (a) an iminothiazoline compound of the formula: ##STR1## wherein R.sup.1 is halogen, halo(C.sub.1 -C.sub.2)alkyl, halo(C.sub.1 -C.sub.2)alkoxy or halo(C.sub.1 -C.sub.2)alkylthio; R.sup.2 is C.sub.1 -c.sub.2 alkyl, chroline, bromine or iodine; R.sup.3 is C.sub.1 -C.sub.6 alkyl, C.sub.3 -C.sub.6 cycloalkyl, C.sub.3 -C.sub.6 cycloalkoxy or C.sub.1 -C.sub.6 alkoxy, all of which are optionally substituted with at least one substituent selected from halogen, C.sub.1 -C.sub.2 alkyl and C.sub.1 -C.sub.2 alkoxy; R.sup.4 is hydrogen or halogen; and (b) at least one of herbicidal triazine compounds, herbicidal uracil compounds, herbicidal urea compounds, herbicidal dinitro aniline compounds, norflurazon, dimethazon, imazaquin and imazethapyr. Also disclosed is a method for controlling undesired weeds by use of the herbicidal composition.
    Type: Grant
    Filed: September 11, 1992
    Date of Patent: May 17, 1994
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Shinichi Kawamura, Izumi,Keiichi, Junichi Sato, Yuzuru Sanemitsu, Ryo Sato, Tatsuhiro Hamada, Hideyuki Shibata
  • Patent number: 5296450
    Abstract: The present invention relates to water dispersible granular compositions comprising a dinitroaniline herbicide and a dispersion enhancing agent and to a process for the preparation of said compositions. Such compositions are storage stable and contain desirable dispersion properties.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: March 22, 1994
    Assignee: American Cyanamid Company
    Inventors: Joseph Kimler, Robert Kubisch
  • Patent number: 5294594
    Abstract: The present invention relates to water dispersible granular compositions comprising a dinitroaniline herbicide and a dispersion enhancing agent and to a process for the preparation of said compositions. Such compositions are storage stable and contain desirable dispersion properties.
    Type: Grant
    Filed: December 23, 1992
    Date of Patent: March 15, 1994
    Assignee: American Cyanamid Company
    Inventors: Joseph Kimler, Robert Kubisch
  • Patent number: 5294595
    Abstract: Herbicidal compounds of the formula ##STR1## in which, for example, X is Br, Cl or F; Y is Cl or Br, R.sup.2 is CHF.sub.2, R.sup.3 is CH.sub.3, R is alkyl, dialkylamino, carboxymethyl, hydroxy, haloalkyl, or aryl, and R.sup.1 is H, Na, lower alkyl or --SO.sub.2 R.
    Type: Grant
    Filed: March 22, 1993
    Date of Patent: March 15, 1994
    Assignee: FMC Corporation
    Inventor: George Theodoridis
  • Patent number: 5194263
    Abstract: Agrochemical and other particulate compositions are formed by coacervation. The coacervate is preferably formed from two water soluble coacervating polymers and stabilizes the particles against agglomeration. The coacervate is preferably formed from a relatively low molecular weight cationic polymer and a relatively high molecular weight anionic polymer.
    Type: Grant
    Filed: August 26, 1991
    Date of Patent: March 16, 1993
    Assignee: Allied Colloids Limited
    Inventors: Peter Chamberlain, John G. Langley
  • Patent number: 5181952
    Abstract: In accordance with this invention, a porous sheet material is provided at intervals with bodies of a polymer which contain a 2,6-dinitroaniline. The sheet material is made porous to permit free passage of water. It may be either a perforated sheet or a woven or non-woven textile material. A particularly desirable embodiment is a non-woven fabric of non-biodegradable material. This type of material is known as a "geotextile" and is used for weed control, prevention of erosion on slopes, and other landscaping purposes. In order to obtain a root repelling property, a dinitroaniline is blended with a polymer which is attached to the geotextile or other porous material.
    Type: Grant
    Filed: June 11, 1990
    Date of Patent: January 26, 1993
    Assignee: Battelle Memorial Institute
    Inventors: Frederick G. Burton, Dominic A. Cataldo, John F. Cline, W. Eugene Skiens, Peter Van Voris