Surfactant Composition For Cleaning Agents (other Than Raw Soap) Patents (Class 510/535)
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Patent number: 7183250Abstract: The present invention is related to a concentrated surfactant composition containing a hydrophobically modified polymer and/or a hydrotrope. The addition of the polymer or hydrotrope to the concentrated surfactant changes the physical properties of the concentrated surfactant, making it easier to process.Type: GrantFiled: June 17, 2003Date of Patent: February 27, 2007Assignee: National Starch and Chemical Investment Holding CorporationInventors: Klein A. Rodrigues, Kevin Beairsto
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Patent number: 7182797Abstract: Improved fuel compositions and fuel additive packages are disclosed which serve to increase the combustion efficiency of conventional fuels while reducing the level of CO2 emissions generated upon the combustion of the fuels. The fuels may be essentially water-free hydrocarbon fuels such as gasoline or diesel fuel, or may be in the form of hydrosols. The additive packages of the invention include sorbitan oleate, a polyoxyethylene alcohol, an alkylene glycol, and an amine.Type: GrantFiled: November 8, 2004Date of Patent: February 27, 2007Inventor: Kenneth Mekonen
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Patent number: 7135450Abstract: The invention provides an excellent means of giving an excellent bleaching effect when a liquid bleaching composition is used as foam. A liquid composition containing (a) hydrogen peroxide, (b) a specific sugar derivative-based surfactant, (c) polyoxyalkylene alkyl ether wherein the carbon number of the alkyl group is 10 to 14 and the mole number of oxyalkylene added on the average is 7 to 12, and (d) water in a specific ratio is foamed and used in bleaching of clothing.Type: GrantFiled: July 24, 2003Date of Patent: November 14, 2006Assignee: Kao CorporationInventors: Masataka Maki, Kazuyoshi Ozaki, Nobuyoshi Yamaguchi
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Patent number: 7125834Abstract: This invention provides the following: an amphiphilic functional substance with lipophilicity, affinity for supercritical CO2, and if necessary hydrophilicity comprising an oligoolefin chain and a perfluoroalkyl group(s) at a single end thereof or at both ends thereof with or without the intervention of a poly(oxyalkylene) chain, which enables the utilization of supercritical CO2 as a reaction medium; a photopolymerizable functional substance comprising an oligoolefin chain and a reversible photopolymerization/dissociation group(s) at a single end thereof or at both ends thereof and a functional substance comprising a photo- and/or thermodissociable polymer obtained by photopolymerization of the aforementioned photopolymerizable functional substance, which can be utilized as recycle polymers; a hydrolyzable functional substance comprising a polymer obtained by chain-elongating plural oligoolefin chains through ester linkages, which can be utilized as a recycle polymer; and a functional substance capable of foType: GrantFiled: November 22, 2001Date of Patent: October 24, 2006Assignee: San-Ei Kougyou CorporationInventor: Takashi Sawaguchi
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Patent number: 7087571Abstract: The invention relates to a series of polyglycoside derivatives that contain water-soluble sulfosuccinate groups introduced into the molecule by reaction with the hydroxyl groups present in the starting polyglycoside molecule, with the chloro material. The preferred products have more than one water-soluble group per molecule and are made with mild reagents to avoid discoloration and mal odor. The most preferred products have between 2 and 3 functional groups per molecule.Type: GrantFiled: January 25, 2005Date of Patent: August 8, 2006Assignee: Colonial ChemicalInventors: Anthony J. O'Lenick, Jr., Dean Smith
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Patent number: 7084101Abstract: The present invention relates to an aqueous based, solvent free degreaser composition, comprising a blend of two nonionic surfactants selected from, alcohol alkoxylate with a fatty alcohol moiety, alkoxylated fatty alcohol, fatty alcohol having oxyethylate moieties, polyoxyalkylene block copolymers, and alkyl phenol alkoxylate.Type: GrantFiled: April 5, 2002Date of Patent: August 1, 2006Assignee: BASF CorporationInventors: Charles O. Kerobo, Michael C. Welch, Suzanne M. Gessner, Sonia J. Patterson
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Patent number: 7078373Abstract: The detergent composition of the invention contains a combination of an anionic surfactant, a defined nonionic surfactant of high hydrophilic/lipophilic balance (HLB) value, optionally a cationic surfactant, optionally a detergency builder, optionally an inorganic non-builder salt, an optionally a polycarboxylate polymer. Further optional detergent ingredients may also be present. The amount of the anionic surfactant is from 5 to 40, preferably from 7 to 30 wt % and the amount of the nonionic surfactant is from 1 to 20, preferably from 1 to 10 wt %, based on the weight of the total composition.Type: GrantFiled: November 3, 2003Date of Patent: July 18, 2006Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Jacqueline Burrows, Robert John Crawford, Patrick Joseph Norris, David Christopher Thorley
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Patent number: 7045494Abstract: A process for making an alkyl and/or alkenyl oligoglycoside preparation having a magnesium salt concentration of less than about 10 ppm involving the steps of: (a) providing an alkyl and/or alkenyl oligoglycoside preparation having an active substance content of from about 10 to 70% by weight, based on the weight of the preparation; (b) providing an acid component; (c) adjusting the pH of the alkyl and/or alkenyl oligoglycoside preparation to from about 4 to 9.5 by combining the acid component with the alkyl and/or alkenyl oligoglycoside preparation to form a pH-modified alkyl and/or alkenyl oligoglycoside preparation; (d) providing a column charged with an ion exchange resin; and (e) purifying the pH-modified alkyl and/or alkenyl oligoglycoside preparation by passing it through the column of step (d) at a viscosity of from about 20 to 6,000 mPas, and at a temperature of from about 20 to 90° C.Type: GrantFiled: June 12, 2002Date of Patent: May 16, 2006Assignee: Cognis Deutschland GmbH & Co. KGInventors: Thomas Albers, Karl Heinz Schmid, Rainer Eskuchen, Michael Koehler
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Patent number: 7018963Abstract: A water-soluble surfactant composition includes an aliphatic diol and a polyoxyalkylene alkyl ether. A 0.1 wt % aqueous solution of the surfactant composition has a contact angle of at most 60 degrees and a dynamic surface tension at both 1 Hz and 10 Hz of at most 50 mN/m. When used in printing inks and paper coatings, this composition provides excellent wettability, penetrability, foam inhibition and dispersibility, is compatible with environmental concerns, and has no adverse effects on printing and coating equipment.Type: GrantFiled: May 25, 2004Date of Patent: March 28, 2006Assignee: Nissin Chemical Industry Co., Ltd.Inventors: Toru Mizusaki, Shuichiro Shinohara
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Patent number: 6958314Abstract: A petro-chemical free nonionic surfactant is prepared by the alkylation of an alkyl polyglucoside (APG). Under suitable alkylation reaction conditions, the surfactants are preferably prepared by the reaction of an APG with either alkyl halide or an alkyl tosylate. These surfactants are low foaming and exhibit excellent detergency.Type: GrantFiled: March 5, 2003Date of Patent: October 25, 2005Assignee: Master Chemical CorporationInventor: David B. McCall
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Patent number: 6958315Abstract: The invention relates to a series of polyglycoside derivatives that contain water-soluble groups introduced into the molecule by reaction with the hydroxyl groups present in the starting polyglycoside molecule. The preferred products have more than one water-soluble group per molecule and are made with mild reagents to avoid discoloration and mal odor. The most preferred products have between 2 and 3 functional groups per molecule. The compounds are amino functional and betaine functional alkyl polyglucoside.Type: GrantFiled: September 24, 2003Date of Patent: October 25, 2005Assignee: Colonial ChemicalInventors: David Anderson, Dean A. Smith, Anthony J. O'Lenick, Jr.
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Patent number: 6956018Abstract: A polymerizable polyoxyalkylene monoalkyl ether derivative prepared by using a polyoxyalklene monoalkyl ether which gives, in gel permeation chromatography, a chromatogram which satisfies a relation expressed by an equation: S1/S0?0.Type: GrantFiled: July 13, 2004Date of Patent: October 18, 2005Assignee: Nof CorporationInventors: Akinori Itoh, Susumu Honda, Tatsuya Matsui, Yoshihiro Hayashi
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Patent number: 6936581Abstract: Processes are described for preparing anhydrous detergent granules, wherein the processes comprise: (a) providing an alk(en)yl oligoglycoside composition having a residual fatty alcohol content; (b) reducing the fatty alcohol content of the composition to 30% by weight or less to provide a reduced alcohol content alk(en)yl oligoglycoside; and (c) combining the reduced alcohol content alk(en)yl oligoglycoside with one or more detergent additives.Type: GrantFiled: April 10, 2001Date of Patent: August 30, 2005Assignee: Cognis Deutschland GmbH & Co. KGInventors: Rainer Eskuchen, Manfred Weuthen, Ditmar Kischkel, Tycho Michel, Bernhard Gutsche
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Patent number: 6919305Abstract: Solid laundry detergents, dishwashing detergents and cleaners which are obtained by mixing gemini surfactants of the formula (I), R1CH(OH)CHR3(OCH2CH2)nOCHR4CH(OH)R2??(I) in which R1 and R2,independently of one another, are linear or branched alkyl and/or alkenyl radicals having 4 to 22 carbon atoms, R3 and R4, independent of one another, each represents a hydrogen or an alk(en)yl radical having from 1 to 22 carbon atoms and n is a number from 5 to 400, with inorganic or organic carriers.Type: GrantFiled: January 28, 2004Date of Patent: July 19, 2005Assignee: Cognis Deutschland GmbH & Co. KGInventors: Ditmar Kischkel, Manfred Weuthen, Michael Elsner
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Patent number: 6911053Abstract: A method of conferring one or more benefits during the laundering of textile fabrics is disclosed. The method includes contacting the fabric with a modified naturally occurring polysaccharide gum having ?1-4 linkages, and a weight average molecular weight of 250,000 or less.Type: GrantFiled: December 6, 1999Date of Patent: June 28, 2005Assignee: Unilever Home & Personal Care USA, a division of Conopco, Inc.Inventors: Henri Derk Bijsterbosch, Deborah Jane Cooke, Peter Neil Jones
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Patent number: 6903065Abstract: The invention relates to particulate solids comprising more than 90% by weight of natural or synthetic surface-active compounds for which a) the mean particle size of the particulate solid particles is 10 to 3000 ?m, b) the surface-active compounds are solid at room temperature, and c) the surface-active compounds have a melting point of from 25 to 250° C.Type: GrantFiled: May 17, 2002Date of Patent: June 7, 2005Assignee: Bayer AktiengesellschaftInventors: Peter-Roger Nyssen, Dietmar Fuchs, Hans-Peter Müller
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Patent number: 6892739Abstract: The invention relates to the use of tenside agents containing selected non-ionic tensides, for use in cleaning and/or disinfecting processes and/or cleaning and/or disinfecting preparations.Type: GrantFiled: April 11, 2001Date of Patent: May 17, 2005Assignee: Ecolab GmbH & Co. oHGInventors: Thomas Merz, Bernhard Meyer, Khalil Shamayeli
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Patent number: 6881359Abstract: Processes for preparing surfactant granules, wherein the processes comprise: (a) passing a water-containing surfactant preparation through a casting plate, wherein the casting plate vibrates, such that droplets of the preparation are formed; and (b) contacting the droplets with a gaseous drying agent; are described.Type: GrantFiled: January 17, 2001Date of Patent: April 19, 2005Assignee: Cognis Deutschland GmbH & Co. KGInventors: Bernhard Leeners, Udo Steinberner, Bernd Fabry
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Patent number: 6858573Abstract: An anionic surfactant of the formula (I): R2—Y—(O)C—(HR)C—C(HR1)—C(O)—(OA)n—X wherein one of R and R1 is a C6 to C22 linear or branched alkyl or alkenyl, and the other is hydrogen; Y is O, or NH, or —NH—CH2—C(?CH2)—, or —N(CH2—CR3(?CH2))—CH2—C(?CH2)— where R3 is hydrogen or methyl; when Y is O, R2 is hydrogen, or a salt, or a C1 to C6 linear or branched alkyl, or an optionally substituted C3 to C10 linear or branched alkenyl; when Y is NH, or —NH—CH2—(?CH2)—, or —N(CH2—CR3(?CH2))—CH2—C(?CH2)— where R3 is hydrogen or methyl, R2 is hydrogen or methyl; OA is an oxyalkylene group; n is 2 to 100; and X is a group comprising at least one acidic H atom, or a salt thereof, and the use thereof in free radical initiated addition polymerisation, particularly emulsion polymerisation.Type: GrantFiled: July 24, 2003Date of Patent: February 22, 2005Assignee: Imperial Chemical Industries PLCInventors: Johny Denis Grade, Trevor Blease
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Patent number: 6844309Abstract: Ether-capped poly(oxyalkylated) alcohol surfactants having superior grease cleaning abilities and improved spotting/filming benefits are provided.Type: GrantFiled: September 12, 2000Date of Patent: January 18, 2005Assignee: The Procter & Gamble CompanyInventors: Mark Robert Sivik, Glenn Thomas Jordan, IV, Bernard William Kluesener, William Michael Scheper, Donna Jean Haeggberg, Kristen Lynne McKenzie
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Patent number: 6812201Abstract: Surfactant mixtures comprising (a) a nonionic surfactant mixture present in an amount greater than 60% by weight, based on the weight of the surfactant mixture, the nonionic surfactant mixture comprising: (i) at least one alk(en)yl oligoglycoside of the general formula (I), R1O—[G]p (I) wherein R1 represents an alk(en)yl radical having from 4 to 22 carbon atoms, G represents a sugar radical having 5 or 6 carbon atoms and p represents a number from 1 to 10; and (ii) at least one nonionic surfactant of the general formula (II) R2O(CH2CHRO)xH (II) wherein x represents a number of from 1 to 30, each R independently represents a substituent selected from the group consisting of a hydrogen, a methyl group and an ethyl group, and R2 represents a linear alkyl radical having from 16 to 22 carbon atoms; and (b) up to 6% by weight, based on the weight of the surfactant mixture, of one or more anionic surfactants; are described.Type: GrantFiled: March 22, 2002Date of Patent: November 2, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Manfred Weuthen, Karl Heinz Schmid
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Patent number: 6805141Abstract: A rinse agent composition containing: (a) a gemini surfactant corresponding to formula I: R—CHOH—CH2—[OCH2CH2]x—O—CH2—CHOH—R (I) wherein R is a linear or branched alkyl and/or alkenyl radical having from about 4 to 22 carbon atoms, and x is a number from about 5 to 90; and (b) a fatty alcohol alkoxylate corresponding to formula II: R1O[CH2(CH3)CHO]q(CH2CH2O)rH (II) wherein R1 is a linear or branched alkyl and/or alkenyl group having from about 4 to 22 carbon atoms, and q is a number up to about 10, and r is a number from about 1 to 50, and wherein (a) and (b) are present in the composition in a ratio by weight of from about 1:1 to 4:1.Type: GrantFiled: December 12, 2002Date of Patent: October 19, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Michael Elsner, Ditmar Kischke, Manfred Weuthen
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Patent number: 6800599Abstract: The invention relates to a class of detergent compositions for use in hand dishwashing that provides excellent performance as measured by persistence of foam in the presence of oily and fatty types of soils. Testing based on escalating amounts of such soils to the extinction of the foam showed surprising advantage of hand dishwashing composition comprising at least two anionic surfactants and a polyethylene glycol and being essentially free of alkyl polyglucosides.Type: GrantFiled: May 21, 2002Date of Patent: October 5, 2004Assignee: Clariant Finance (BVI) LimitedInventor: Scott D. Manske
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Patent number: 6797687Abstract: Mixtures comprising: (a) a gemini surfactant of the formula (I) R1—CHOH—CH2—[OCH2CH2]x—O—CH2—CHOH—R (I) wherein each of R and R1 is a linear or branched alkyl and/or alkenyl group having from 4 to 22 carbon atoms and x is a number from about 5 to about 400; (b) polyethylene glycol are useful as components in laundry detergents, dishwashing detergents and cleaners and for improving the wetting behavior on various surfaces.Type: GrantFiled: August 7, 2002Date of Patent: September 28, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Ditmar Kischkel, Hans-Christian Raths, Manfred Weuthen, Michael Elsner
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Patent number: 6794349Abstract: A built particulate laundry detergent composition containing anionic sulphonate or sulphate surfactant and conventional ethoxylated alcohol nonionic surfactant also contains a low level of a highly ethoxylated alcohol nonionic surfactant having an average degree of ethoxylation of from 15 to 40. The composition exhibits increased mildness to the skin without loss of detergency performance.Type: GrantFiled: October 10, 2002Date of Patent: September 21, 2004Assignee: Unilever Home & Personal Care USA, division of Conopco, Inc.Inventors: Rudolfus Johannes Hafkamp, Rob Menting
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Patent number: 6794345Abstract: The invention relates to gemini surfactants, optionally in combination with ingredients customary in dishwashing detergents and cleaners, optionally with further nonionic surfactants and anionic surfactants, and to the use of such gemini surfactants for improving the wetting behavior and the compatibility with plastics, for the simplified preparation of solid cleaners and as foam-suppressing surfactant in rinse aid formulations.Type: GrantFiled: May 6, 2002Date of Patent: September 21, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Michael Elsner, Manfred Weuthen, Hans-Christian Raths
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Patent number: 6786223Abstract: Disclosed herein are hard surface cleaners which provide improved fragrance retention properties to the treated hard surface, and methods for using them. The cleaners include a fragrance, a carrier, and a surfactant selected from ethylene oxide/propylene oxide block copolymers, polyglycosides, ethoxylated alkyl alcohols, and ethylene oxide/propylene oxide copolymers functionalized with a fatty alcohol moiety. The cleaner may also contain water and a base.Type: GrantFiled: July 29, 2002Date of Patent: September 7, 2004Assignee: S. C. Johnson & Son, Inc.Inventors: Michael E. Klinkhammer, Richard S. Valpey, III, Brandon R. Thalmann, Mathew A. Jones, John Tsibouklis, Maureen J. Stone, Richard W. Avery
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Patent number: 6787511Abstract: The invention relates to use of specifically defined polydextrose to induce biphasic liquid formation. Optional use of salt allows less polydextrose to be used to induce biphasic formation.Type: GrantFiled: August 14, 2002Date of Patent: September 7, 2004Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Rajesh Patel, Michael Massaro
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Patent number: 6777384Abstract: The invention relates to gemini surfactants, optionally in combination with ingredients customary in laundry detergents, dishwashing detergents and cleaners, optionally with further nonionic surfactants and anionic surfactants, and to the use of such gemini surfactants for improving the wetting behavior and the compatibility with plastics, for the simplified preparation of solid cleaners and as foam-suppressing surfactant in rinse aid formulations.Type: GrantFiled: May 6, 2002Date of Patent: August 17, 2004Assignee: Cognis Deutschland GmbH & Co., KGInventors: Hans-Christian Raths, Manfred Weuthen, Michael Elsner
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Patent number: 6762208Abstract: The present invention pertains to a method for controlling the foaming of a waterborne composition or an industrial process by the incorporation of a foam controlling agent. The method comprises utilizing as the foam controlling agent a compound of the formula: HOR1R3C—[CH2]n—CR2R4OH R1 and R2 are independently selected from the group of alkyl radicals having from 3 to 6 carbon atoms. R3 and R4 are independently alkyl radicals having from 1 to 2 carbon atoms. n is an integer from 1 to 6. The compound generates an initial (t=0 min.) or a final (t=10 min.) foamed density at least 30% greater than that of a 0.5 wt % aqueous solution of a 12 mole ethoxylate of a C12-C15 primary alcohol (C12-C15E12) when added at 0.2 wt % to the C12-C15E12 solution. The present invention also pertains to an aqueous composition comprising the foam controlling agent.Type: GrantFiled: October 1, 2001Date of Patent: July 13, 2004Assignee: Air Products and Chemicals, Inc.Inventors: Joel Schwartz, Charles James Reader, Wim Peter Stout, Yong Jin Lee, Christine Marie Kretz
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Patent number: 6762157Abstract: An aqueous composition for the reduction or elimination of unpleasant odors from surfaces containing such odors comprises a perfume, a surfactant/solubilizer, a solvent/drying aid, an odor absorber, and, preferably, a buffer to maintain the desired pH. The solution contains minimal or no volatile organic compounds. Due to the specific nature of the combination of the surfactant/solubilizer and the solvent/drying aid, the use of fragrances previously too hydrophobic for use in an aqueous solution is possible, providing a large variety of efficient odor counteractants not previously available. The composition may optionally comprise additional components, such as preservatives, antimicrobials, anti-static compositions, anti-wrinkling agents, insect control agents, moth repellents, UV protectants, water-proofing agents, and textile treatment agents. The aqueous solution may be applied to a variety of surfaces, in sufficient quantity to wet the surface, preferably by spraying.Type: GrantFiled: July 31, 2000Date of Patent: July 13, 2004Assignee: S. C. Johnson & Son, Inc.Inventors: Linda J. Babinski, Karen K. Kristopeit, Francis J. Randall
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Patent number: 6746997Abstract: A process for the preparation of mixed ethoxylated alkyl phenol/alkyl phenol ethoxy sulfate surfactants, such surfactants, and detergent formulations incorporating the same. The mixed surfactants are more tolerant of sodium carbonate, allowing greater amounts of sodium carbonate to be used so that the amount of surfactant can be reduced resulting in overall cost savings in the resultant laundry product.Type: GrantFiled: September 3, 2002Date of Patent: June 8, 2004Assignee: Church & Dwight Co., Inc.Inventors: Charles D. Carr, Archana Gupta
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Patent number: 6730131Abstract: A detergent composition containing a surfactant mixture, the surfactant mixture containing: (a) a nonionic surfactant corresponding to formula (I): R1O(CH2CH2O)nH (I) wherein R1 is a hydrocarbon radical having from about 16 to 18 carbon atoms and n is a number from about 5 to 10, and wherein the nonionic surfactant has an iodine value of from about 20 to 50; and (b) a co-surfactant selected from the group consisting of an alkyl oligoglycoside, an alkenyl oligoglycoside, an alkyl ether sulfate, and mixtures thereof.Type: GrantFiled: December 20, 2001Date of Patent: May 4, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Ansgar Behler, Norbert Huebner, Alfred Festfechtel
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Patent number: 6727209Abstract: The invention relates to use of polydextrose in combination with sucrose to induce biphasic liquid formation. Salt may be optionally used.Type: GrantFiled: August 14, 2002Date of Patent: April 27, 2004Assignee: Unilever Home & Personal Care, USA, division of Conopco, Inc.Inventors: Daniel Pereira, Robert D. Sabin, Rosa Paredes, May Shana'a
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Patent number: 6723135Abstract: A laundry detergent composition containing a surfactant system having: (a) an alkyl and/or alkenyl oligoglycoside; (b) from about 5 to 35% by weight of a fatty alcohol; and (c) up to 2% by weight water, all weights being based on the weight of the surfactant system.Type: GrantFiled: September 19, 2001Date of Patent: April 20, 2004Assignee: Cognis Deutschland GmbH & Co. KGInventors: Rainer Eskuchen, Ditmar Kischkel, Manfred Weuthen, Michael Koehler, Werner Leinemann
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Patent number: 6713442Abstract: A built particulate laundry detergent composition containing anionic sulphonate or sulphate surfactant and conventional ethoxylated alcohol nonionic surfactant also contains a low level of a highly ethoxylated alcohol nonionic surfactant having an average degree of ethoxylation of from 15 to 40, and a low level of a textile softening clay. The composition exhibits increased mildness to the skin without loss of detergency performance, and the softness of washed fabrics is significantly improved despite the low level of softening clay present.Type: GrantFiled: October 10, 2002Date of Patent: March 30, 2004Assignee: Unilever Home & Personal Care USA division of Conopco, Inc.Inventors: Rudolfus Johannes Hendrikus Hafkamp, Rob Menting, Antje Minke Wierenga
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Patent number: 6686330Abstract: Compositions including ether-capped poly(oxyalkylated) alcohol wetting agents. The wetting agents are low-foaming and have good biodegradability, and can be used in a variety of applications, for example in polymer, anti-foaming, biocidal, coating, fertilizer, pharmaceutical, and drilling fluid compositions.Type: GrantFiled: December 8, 2000Date of Patent: February 3, 2004Assignee: The Procter & Gamble CompanyInventors: Glenn Thomas Jordan, IV, William Michael Scheper, Mark Robert Sivik, Bernard William Kluesener, Kristen Lynne McKenzie
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Patent number: 6683042Abstract: Disclosed is a novel granulation method, wherein a surface active foam obtained by foaming a flowable component that contains a surface active agent with a gaseous medium is used as granulation adjuvant. The surface active foam has an average pore size of less than 10 mm.Type: GrantFiled: March 29, 2001Date of Patent: January 27, 2004Assignee: Henkel Kommanditgesellschaft auf Aktien (Henkel KGaA)Inventors: Bernd Larson, Wilfried Raehse, Markus Semrau, Matthias Sunder
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Patent number: 6680412Abstract: Alcohol alkoxylates of the formula (I) R1—O—(CH2—CHR5—O—)r(CH2—CH2—O—)n(CH2—CHR6—O—)s(CH2—CHR2—O—)mH (I) where R1 is an at least singly branched C4-22-alkyl R2 is C3-4-alkyl R5 is C1-4-alkyl R6 is methyl or ethyl n is an average value from 1 to 50 m is an average value from 0 to 20 r is an average value from 0 to 50 s is an average value from 0 to 50, where m is at least 0.5 if R5 is methyl or ethyl or r is 0, or alcohol alkoxylates of the formula (II) R3—O—(CH2—CH2—O—)p(CH2—CHR4—O—)qH (II) where R3 is branched or unbranched C4-22-alkyl R4 is C3-4-alkyl p is an average value of from 1 to 50 q is an average value of from 0.5 to 20 are used as low-foam or foam-suppressing surfactants.Type: GrantFiled: October 7, 2002Date of Patent: January 20, 2004Assignee: BASF AktiengesellschaftInventors: Helmut Gümbel, Martin aus dem Kahmen, Norbert Wagner, Klaus Taeger
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Patent number: 6666217Abstract: A cleaning composition containing a gemini surfactant corresponding to formula I: R—CHOH—CH2—[OCH2CH2]x—O—CH2—CHOH—R (I) wherein R is a linear or branched alkyl and/or alkenyl radical having from about 4 to 22 carbon atoms, and x is a number from about 5 to 90.Type: GrantFiled: May 3, 2002Date of Patent: December 23, 2003Assignee: Cognis Deutschland GmbH & Co. KGInventors: Michael Elsner, Manfred Weuthen, Hans-Christian Raths
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Patent number: 6624132Abstract: The present invention relates to a liquid enzyme cleaning composition in which the enzyme is stable at alkaline pH and in the presence of water at concentrations of at least about 50 to about 60 weight percent. In one embodiment, the composition of the invention stabilizes the enzyme with potassium borate.Type: GrantFiled: June 29, 2000Date of Patent: September 23, 2003Assignee: Ecolab Inc.Inventors: Victor Fuk-Pong Man, Steven Eugene Lentsch, Yvonne Marie Killeen
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Patent number: 6593287Abstract: Compositions including ether-capped poly(oxyalkylated) alcohol surfactants having superior grease cleaning abilities and improved spotting/filming benefits are provided.Type: GrantFiled: September 12, 2000Date of Patent: July 15, 2003Assignee: The Procter & Gamble CompanyInventors: Glenn Thomas Jordan, IV, William Michael Scheper, Mark Robert Sivik, Donna Jean Haeggberg, Bernard William Kluesener
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Patent number: 6583102Abstract: A method for preparing an antifoaming composition containing: a) at least one compound of formula (I): (Z)y-(G)x—O—RA (I); b) at least one compound of formula (II): Z—O—[CH2CH(R1)—O]n—Ra (II); c) optionally one or more compounds of formula (IV): (G)x—O—RA (III), and d) optionally one or more compounds of formula (IV): HO—[CH2—CH(R1)—O]n—RB (IV).Type: GrantFiled: May 30, 2001Date of Patent: June 24, 2003Assignee: Societe D'Exploitation de Produits Pour Les Industries Chimiques SeppicInventors: Alain Milius, Jean-Pierre Boiteux, Maryse Carrausse
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Patent number: 6566317Abstract: A process for inhibiting gel formation of a tablet-form detergent composition upon hydration, the process involving: (a) providing a detergent composition containing a surfactant component selected from the group consisting of an anionic surfactant, a nonionic surfactant, and mixtures thereof; (b) providing an anti-gelling agent selected from the group consisting of an alkyl polyglycoside, a polymeric surfactant, an alkyl sulfate, and mixtures thereof; and (c) mixing the surfactant with the anti-gelling prior to introducing the tablet-form detergent composition into water.Type: GrantFiled: April 10, 2001Date of Patent: May 20, 2003Assignee: Cognis CorporationInventors: Timothy C. Morris, Robert J. Valesky, Stephen F. Gross, Charles B. Allen
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Patent number: 6555515Abstract: The invention relates to new formulations for cleaning hard surfaces containing—based on the formulation—1 to 50% by weight of alkyl oligoglucosides corresponding to formula (I): R1O—[G]p (I) in which R1 is an at least partly branched alkyl radical containing 9 to 11 carbon atoms, G is a glucose unit and p is a number of 1.4 to 2.0. The products are distinguished by an improved cleaning performance in relation to formulations based on linear alkyl oligoglucosides.Type: GrantFiled: December 6, 1996Date of Patent: April 29, 2003Assignee: Henkel Kommanitgesellschaft auf AktienInventors: Udo Hees, Eva Kiewert, Rainer Eskuchen
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Patent number: 6492317Abstract: Hard surface cleaning formulations include an associative thickener and a blend of at least two nonionic surfactants selected from the group consisting of ethoxylated alcohols and ethoxylated fatty acids. The formulations exhibit an advantageously high foam volume of at least about 150 cc when a 100 ml aqueous solution containing about 0.1 wt. % of the formulation is agitated at 2,500 rpm for a cumulative agitation period of about 1200 seconds. The formulations also exhibit satisfactory foam stability sufficient to clean at least about 25 plates (ASTM D4009-92). Preferably, the associative thickener is the reaction product of a C6 or greater epoxide compound with a polyoxyalkylene polyol. The ethoxylated alcohols and ethoxylated fatty acids each most preferably contain C8 to C18 carbon chains which are ethoxylated with between about 3 to about 20 moles of ethylene oxide.Type: GrantFiled: May 19, 2000Date of Patent: December 10, 2002Assignee: BASF CorporationInventors: Charles O. Kerobo, Michael C. Welch, Richard J. Holland, Susanne M. Gessner, Sonia J. Patterson, Chacji Thankachan
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Patent number: 6472440Abstract: Defoamers are the products of the reaction of epichlorohydrin and compounds having the formula II R3(EO)n(PO)mOH (II) wherein R3 is an alkyl, alkenyl or arenyl group having from 4 to 22 carbon atoms; a substituted alkyl or alkenyl group having from 4 to 22 carbon atoms wherein; n is a number from 0 to 50 and m is a number from 0 to 10; wherein the mole ratio of epichlorohydrin to (II) is from about 0.60/1 to about 2/1 are extremely efficient defoamers for aqueous surfactant systems. The defoamers are added to a surfactant in an amount sufficient to reduce or eliminate foam and have the advantage of being totally dispersible in water, are readily biodegradable, contain no organic solvents and do not affect the detergency of surfactants with which they are used because they are nonionic surfactants in themselves.Type: GrantFiled: April 14, 1999Date of Patent: October 29, 2002Assignee: Cognis CorporationInventors: Stephen F. Gross, Michael S. Wiggins, Ronald W. Broadbent, David I. Devore
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Patent number: 6468957Abstract: The invention relates to a neutralization and granulation method wherein a neutralizing foam is used as granulation adjuvant. The neutralizing foam was previously obtained by mixing an anionic surfactant in its acid form, which was expanded using a gaseous medium, and a highly concentrated, aqueous alkaline component, which was expanded using a gaseous medium. The neutralizing foam has an average pore size of less than 10 mm, preferably less than 5 mm and especially less than 2 mm.Type: GrantFiled: March 28, 2001Date of Patent: October 22, 2002Assignee: Henkel Kommanditgesellschaft auf AktienInventors: Bernd Larson, Josef Markiefka, Wilfried Raehse, Wieland Schulze, Matthias Sunder
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Patent number: 6460548Abstract: Liquid hard-surface cleaning compositions are disclosed which comprise particular dicapped polyalkoxylene glycols. These compositions provide excellent next-time cleaning performance on hard-surfaces soiled by various soils, especially greasy type soils and/or burnt/sticky food residues typically found in a kitchen.Type: GrantFiled: August 16, 1999Date of Patent: October 8, 2002Assignee: The Procter & Gamble CompanyInventors: Neil James Gordon, Marc Francois Theophile Evers
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Patent number: 6451064Abstract: Liquid multipurpose cleaning compositions comprising a peroxygen bleach, a surfactant that exhibits a foaming property in the presence of a peroxygen bleach and a foam reducing system and processes for using same are provided.Type: GrantFiled: June 19, 2000Date of Patent: September 17, 2002Assignee: Procter & GambleInventors: Valerio Del Duca, Carlo Ricci, Carla Scorsini