Abstract: This invention relates to water insoluble copolymer aqueous dispersions stabilized by multiple carboxylic acid functional comonomer residues against shear-induced coagulation. These copolymer dispersions are useful as pressure sensitive adhesives, and as binders for textiles, paper, non-woven materials, and coatings.
Abstract: Novel polymers having the structure--A).sub.x, --B).sub.y and --C).sub.z ;whereinA represents a polymerized acrylonitrile monomer;B represents a polymerized hydrophobic ethylenically unsaturated monomer;C represents a polymerized ionically charged vinyl monomer;x is from 10 to 90 weight percent;y is from 5 to 40 weight percent except that when B is a vinyl halide monomer, y is 10 to 89.9 weight percent; andz is from 0.1 to 10 weight percentThe polymers are useful in forming protective over-coats for photographic elements.
Type:
Grant
Filed:
November 29, 1984
Date of Patent:
September 9, 1986
Assignee:
Eastman Kodak Company
Inventors:
David J. Steklenski, Donald A. Upson, Howard M. Low
Abstract: The invention relates to stable water in oil dispersions, of hydrosoluble cationic polymers based on salified or quaternized dimethylaminoethyl acrylate copolymerized or not with acrylamide, and containing more than 5%(in moles) of cationic units uniformly and not statistically distributed along the chains, presenting a composition by weight of from 20 to 55% of polymers, from 20 to 45% of oil, from 1 to 5% of at least two emulsifying agents, and the balance to 100% being water, the oil phase being a mixture of normal C.sub.10 -C.sub.13 alkanes, one of the emulsifying agents having an HLB of 3 to 5, and good solubility in the oil phase, and a lipophilous group of a carbonated ramified chain of at least 16C and the other having an average HLB of 12 to 16, the percentages by weight of both agents being from 0.5 to 3% relative to the weight of the dispersion.
Type:
Grant
Filed:
February 3, 1983
Date of Patent:
April 8, 1986
Assignee:
Societe Francaise Hoechst
Inventors:
William Dunk, Jean Cabestany, Claude Trouve
Abstract: Compositions and articles containing polymeric vinyl aromatic aminimides are disclosed. The polymeric vinyl aromatic aminimides exhibit unusual rheological properties in an aqueous medium. The polymers provide thermoreversible gelling properties and exhibit negative thixotropy.
Abstract: Shelf-stable, one-package aqueous latices, which are curable with or without the application of heat, consist essentially of an alkaline-curable, self-crosslinking emulsion polymer, selected organic metal salts, and water. The alkali, alkaline earth, or heavy metal salts of C.sub.1 -C.sub.6 organic acids (e.g., sodium acetate) are post-added to th polymer emulsion or present during the polymerization. The polymer typically comprises about 90-99.9% by weight of one or more vinyl polymerizable monomers (e.g., acrylates, vinyl esters, and ethylene) and 0.1-10% by weight of a polymerizable non-ionic or cationic self-crosslinking monomer containing halohydrin groups (e.g., 3-chloro-2-hydroxypropyl (meth)acrylate or the reaction product of epichlorohydrin and N,N-dimethylaminopropyl methacrylamide or methacrylate).
Type:
Grant
Filed:
August 2, 1984
Date of Patent:
October 8, 1985
Assignee:
National Starch and Chemical Corporation
Abstract: Substantially linear, synthetic, water-soluble or water-dispersible cationic interpolymeric surfactants which are particularly useful for reducing the surface tension of an aqueous medium; such surfactants having a critical micelle concentration of from 0.01 to about 10 percent in water at 25.degree. C.
Abstract: High solids, low viscosity, alkaline-curable, thermosetting cationic vinyl ester based polymer latices, characterized by the high molecular weight of the polymer therein, are prepared by polymerizing at least 5% of selected vinyl esters (up to C.sub.6), 0.5-10% of a self-crosslinking cationic quaternary ammonium monomer, and optionally a vinyl polymerizable monomer such as butyl acrylate, ethylene, acrylamide, diallyl maleate, and/or 2-hydroxyethyl acrylate. The polymerization is carried out in the presence of water, a watersoluble cationic azo initiator, a water-soluble amino thiol salt chain transfer agent, and a cationic and/or nonionic surfactant. The latices are useful as formaldehyde-free binders for polyester nonwovens.
Type:
Grant
Filed:
October 5, 1983
Date of Patent:
December 18, 1984
Assignee:
National Starch and Chemical Corporation
Abstract: Substantially linear, synthetic, water-soluble or water-dispersible cationic interpolymeric surfactants which are particularly useful for reducing the surface tension of an aqueous medium; such surfactants having a critical micelle concentration of from 0.01 to about 10 percent in water at 25.degree. C.
Abstract: High molecular weight protonated latices stable typically up to pH of about 10 are cathodically electrodeposited onto electroconductive substrates, forming uniform, flexible coatings without the need of subsequent heat curing.
Abstract: A novel blend of two components: one a blend of algin and tamarind; and the other, a polycationic electroconductive polymer is disclosed, which is used as a paper coating composition. The paper coated above improvement in film-forming, reduction in air porosity, and an increase in oil and solvent holdout.
Abstract: Structured particle latexes are prepared by emulsion polymerizing monomeric materials in aqueous media in one or more stages wherein in at least one of the stages a reactive polymeric surfactant is used. The resulting latex contains nonionic particles to which are bound the reactive polymeric surfactant which forms a layer containing stabilizing "ionic" groups such as sulfonium groups, quaternary ammonium groups or sulfonate groups chemically bound at or near the surface of the polymer particles, which are dispersed in aqueous media. The cationic latexes are particularly suitable for beater additives and organic pigments.
Type:
Grant
Filed:
June 23, 1980
Date of Patent:
June 29, 1982
Assignee:
The Dow Chemical Company
Inventors:
Ritchie A. Wessling, Dale M. Pickelman, Sr.
Abstract: This invention is directed to a novel water soluble conductive material which is capable of being polymerized by actinic radiation. More specifically, this invention involves the use of a radiation curable quaternary ammonium salt obtained by mixing at least one tertiary amine having acryloyl or methacryloyl unsaturation and at least one halide. When the water-soluble conductive material is subjected to actinic radiation sufficient to cause polymerization, it maintains its conductive character, but becomes essentially impervious to attack by water or solvent, and remains tack-free even at high relative humidity. When the water-soluble conductive material is polymerized by actinic radiation, it is not necessary to drive water off during cure and then rehumidify to obtain proper conductivity as is often necessary with the prior art coatings.
Abstract: Cationic polyelectrolytes in water-soluble powder form, applicable to the flocculation of municipal sludge comprise copolymers of acrylamide and of quaternized or salified dimethylamino-ethyl acrylate, containing in molar proportions 10 to 50% of cationic units distributed regularly along the copolymer chains. They have an intrinsic viscosity higher than 6 and a measured cationicity higher than 90% of the theoretical cationicity.
Type:
Grant
Filed:
May 12, 1978
Date of Patent:
March 9, 1982
Assignee:
Societe Francaise Hoechst
Inventors:
Jean Cabestany, Claude Trouve, Dominique Depernet