Six-membered Nitrogen Ring Having At Least One Diverse Hetero Atom, E.g., Morpholine, Etc. Patents (Class 524/96)
  • Patent number: 5623005
    Abstract: A naphthopyran compound of general formula (I) ##STR1## wherein R.sub.1 represents a group of the formula --NR.sub.2 R.sub.3 wherein each of R.sub.2 and R.sub.3, which may be the same or different, independently represents an alkyl group, or a carbocyclic or heterocyclic group, or R.sub.2 and R.sub.3 taken together with the nitrogen atom to which they are attached represent a heterocyclic ring having one or more hetero atoms and which may optionally carry at least one substituent selected from alkyl, aryl, or heteroaryl groups; each of R.sub.4 and R.sub.5, which may be the same or different, independently represents an alkyl, alkenyl, carbocyclic or heterocyclic group, or R.sub.4 and R.sub.5 taken together with the carbon atom to which they are attached form a carboxylcyclic ring or a heterocyclic ring; and R.sub.6 represents a hydrogen atom or a substituent selected from alkyl, alkoxy, aryl, aryloxy, heteroaryl, halogen, a group of formula R.sub.
    Type: Grant
    Filed: November 2, 1995
    Date of Patent: April 22, 1997
    Assignee: Pilkington PLC
    Inventors: Martin Rickwood, Katharine E. Smith, Christopher D. Gabbutt, John D. Hepworth
  • Patent number: 5604275
    Abstract: This invention relates to an N-vinyl heterocyclic copolymer in substantially pure deionized water or in aqueous alcoholic solution which exhibits significantly reduced color and odor and which is obtained by contacting an alcohol-copolymer mixture with water and a nitrogen containing, trivalent boron complex compound selected from the group of borane-ammonia, borane-lower alkylamine, tetra-lower alkyl ammonium octahydrotriborate, morpholine-borane, lower alkyl morpholine-borane, silylamino borane and mixtures thereof and stripping alcohol from the resulting mixture under vacuum at between about 100 and about 740 mm Hg below absolute whereby an aqueous, 10-70 wt. % solids solution of the copolymer is obtained having a water white color stability of more than a year.
    Type: Grant
    Filed: September 27, 1995
    Date of Patent: February 18, 1997
    Assignee: ISP Investments Inc.
    Inventors: Yuanzhen Zhong, Philip F. Wolf
  • Patent number: 5585192
    Abstract: This invention is directed to a waterborne polyolefin composition which is useful as an adhesion promotor and is prepared by emulsifying non-oxidized, non-maleated, non-chlorinated, crystalline polyolefins and non-chlorinated, maleated, amorphous polyolefins in the presence of a surfactant, an amine and water.
    Type: Grant
    Filed: October 2, 1995
    Date of Patent: December 17, 1996
    Assignee: Eastman Chemical Company
    Inventors: Mahendra K. Sharma, Kevin A. Williams, Michael Bellas
  • Patent number: 5578667
    Abstract: The invention relates to novel water-soluble antioxidants of formula ##STR1## wherein the variables are as defined in the claims, to a process for their preparation and to the use thereof for the photochemical and thermal stabilisation of dyed and undyed polyamide fibre materials.
    Type: Grant
    Filed: September 15, 1995
    Date of Patent: November 26, 1996
    Assignee: Ciba-Geigy Corporation
    Inventors: Francesco Fuso, Gerhard Reinert
  • Patent number: 5502093
    Abstract: Polyacetal resin compositions have excellent weather resistance and environment resistance, which suppress resin deterioration/discoloration, crack and discoloration caused by additive bleeding during extended exposure to light while maintaining the initial molded product surface condition. The polyacetal compositions include a blend of (A) 100 parts by weight of a polyacetal resin, with the specific amounts of (B) an acrylic resin, (C) an oxyalkylene polymer having chains of 2 to 8 consecutive carbon atoms, (D) a UV absorber and (E) two kinds of the hindered amine compounds each having a different molecular weight.
    Type: Grant
    Filed: November 21, 1994
    Date of Patent: March 26, 1996
    Assignee: Polyplastics Co., Ltd.
    Inventors: Toru Katsumata, Nobuyuki Matsunaga
  • Patent number: 5424345
    Abstract: Triazinylphosphonic acids of general formula (I): ##STR1## obtained by subsequent condensation reaction of a cyanuric halide with a osphite and with amines, and then by hydrolysis reaction of the intermediate thus obtained. The compounds of general formula (I) are used in particular as flame retardant additives.
    Type: Grant
    Filed: April 21, 1994
    Date of Patent: June 13, 1995
    Assignee: Ministero Dell 'Universita'E Della Ricerca Scientifica E Tecnologica
    Inventors: Roberto Cipolli, Cristina Rossi, Roberto Oriani, Enrico Masarati, Gilberto Nucida
  • Patent number: 5401797
    Abstract: A highly antioxidant resin composition containing a resin, a solution of a hypophosphite compound in an organic solvent, a heat stabilizer and a hindered amine base weathering stabilizer, which has improved heat stability and weather resistance. The hypophosphite compound is preferably dissolved in a polyvalent alcohol having a molecular weight of not more than 50,000.
    Type: Grant
    Filed: October 23, 1991
    Date of Patent: March 28, 1995
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Kozo Kotani, Taiichi Sakaya
  • Patent number: 5380815
    Abstract: Condensation compounds obtained by means of the polymerization of polyami compositions essentially constituted by derivatives of 2,4,6-triamino-1,3,5-triazine having the general formula (I): ##STR1## with aldehydes, preferably formaldehyde.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: January 10, 1995
    Assignee: Ministero Dell `Universita` E Della Ricerca Scientifica E Tecnologica
    Inventors: Roberto Cipolli, Roberto Oriani, Enrico Masarati, Gilberto Nucida
  • Patent number: 5354793
    Abstract: An accelerator composition and a rubber compounding composition in which a rubber is blended with a combination of three accelerators and sulfur for curing the rubber while minimizing the formation of iridescent sheen. The combination of accelerators included a thiolated morpholine, a dithiocarbamate and a benzothiazole.
    Type: Grant
    Filed: December 20, 1991
    Date of Patent: October 11, 1994
    Assignee: DSM Copolymer, Inc.
    Inventor: John C. Hudson
  • Patent number: 5352714
    Abstract: Improved silicone-containing hydrogels are disclosed with enhanced wettability comprising a silicone-containing monomer, hydrophilic monomers, and a relatively non-polar ring-containing monomer able to be converted to a highly polar amino acid upon hydration.
    Type: Grant
    Filed: July 30, 1992
    Date of Patent: October 4, 1994
    Assignee: Bausch & Lomb Incorporated
    Inventors: Yu-Chin Lai, Gary D. Friends, Paul L. Valint, Jr.
  • Patent number: 5350786
    Abstract: Stabilizers for organic polymers, consisting of one or more compounds of the classis of the sterically hindered amines (HALS) are directly added to the reaction mixture during the (co)polymerization of the .alpha.-olefins or of their mixtures with other unsaturated monomers.The so-obtained polymeric compositions result perfectly stabilized and show a thermo- and photo-oxidative resistance higher than that of the same polymeric compositions to which the same stabilizers are added by a traditional route.
    Type: Grant
    Filed: March 4, 1993
    Date of Patent: September 27, 1994
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Silvestro Costanzi, Damiano Gussoni, Luciano Pallini
  • Patent number: 5342862
    Abstract: Process for controlling the photodegradation of a film of polypropylene or propylene copolymers having a thickness of about 1.25 mils or less, by forming a composition comprising carbon black as the sole UV light absorbing staiblizer and comprising about 0.5% to about 2.4% by weight of the film, hindered amine light stabilizer for interrupting the free radical chain degradation mechanism and comprising about 0.02% to about 0.4% by weight of the film; and an impact modifier for enhancing the photodegradability of the film and comprising about 1% to 40% by weight of the film.
    Type: Grant
    Filed: December 13, 1993
    Date of Patent: August 30, 1994
    Assignee: Biolan Corporation
    Inventor: Murray H. Reich
  • Patent number: 5314938
    Abstract: Amelinic compounds of general formula (I) ##STR1## obtained by subsequent condensation reaction of 1 mol of a cyanuric acid lide with 1 mol of amine and of a polyamine and by hydrolysis reaction of the thus obtained intermediate. Compounds of general formula (I) are used, in particular, as antiflame additives.
    Type: Grant
    Filed: February 10, 1993
    Date of Patent: May 24, 1994
    Assignee: Ministereo Dell'Universita' E Della Ricerca Scientifica E Technologica
    Inventors: Roberto Cipolli, Gilberto Nucida, Enrico Masarati, Roberto Oriani, Mario Pirozzi
  • Patent number: 5310767
    Abstract: The present invention relates to novel tetramethylpiperidine compounds of the formula (I) ##STR1## in which R.sub.1 is e.g. hydrogen or methyl, R.sub.2 and R.sub.3 are e.g. --(CH.sub.2).sub.2 --, R.sub.4 is e.g. --CO--, --COCO-- or --COCH.sub.2 CO--, n is e.g. 1 and R.sub.5 is e.g. hydrogen or allyl.These compounds are suitable for use as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials.
    Type: Grant
    Filed: December 10, 1992
    Date of Patent: May 10, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Valerio Borzatta, Graziano Vignali
  • Patent number: 5308899
    Abstract: Described are compositions protected against thermal and oxidative degradation that compriseA) a polyether polyol or mixtures of such polyols,B) at least one benzofuranone derivative of formula I, ##STR1## wherein L, G, m, R.sub.1 to R.sub.5 and R.sub.21 to R.sub.24 are as defined in claim 1,C) at least one compound from the group of the phenolic anti-oxidants, and/orD) at least one compound from the group of the amino anti-oxidants of the secondary amine type. Also polyurethane(s) (foam(s)) prepared therefrom are protected against thermal and oxidative degradation, especially against core scorching.
    Type: Grant
    Filed: November 16, 1992
    Date of Patent: May 3, 1994
    Assignee: Ciba-Geigy Corporation
    Inventor: Peter Michaelis
  • Patent number: 5306495
    Abstract: Compounds containing substituted piperidine groups, of the general formula (I) ##STR1## in which n is e.g. 1, 2 or 3, R.sub.1 is e.g. hydrogen or methyl, R.sub.2 is e.g. ethylene or trimethylene and if n is 1, A is e.g. hydrogen, --COOC.sub.18 H.sub.37 --n or --COC.sub.11 H.sub.23 --n, if n is 2, A is e.g. ##STR2## and if n is 3, A is e.g. ##STR3## are effective stabilizers for organic materials, especially synthetic polymers, which are subject to the action of light, heat and oxidation.
    Type: Grant
    Filed: March 2, 1992
    Date of Patent: April 26, 1994
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Graziano Vignali
  • Patent number: 5302642
    Abstract: Self-extinguishing polymeric compositions comprising an ammonium polyphoste having the general formula:(NH.sub.4).sub.n+2 P.sub.n O.sub.3n+1microencapsulated with condensation compounds obtained by polymerizing polyaminic compositions essentially constituted by derivatives of 2,4,6-triamino-1,3,5-triazine, having the general formula (II): ##STR1## with aldehydes, preferably formaldehyde.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: April 12, 1994
    Assignee: Ministero Dell `Universita` e Della Ricerca Scientifica e Technologica
    Inventors: Roberto Cipolli, Roberto Oriani, Enrico Masarati, Gilberto Nucida
  • Patent number: 5302640
    Abstract: Self-extinguishing, thermoplastic, polymeric compositions comprising a phhorus derivative and condensation compounds obtained by polymerizing polyaminic compositions essentially constituted by derivatives of 2,4,6-triamino-1,3,5-triazine, having the general formula (I): ##STR1## with aldehydes, preferably formaldehyde.
    Type: Grant
    Filed: November 13, 1992
    Date of Patent: April 12, 1994
    Assignee: Ministero Dell `Universita` e Della Ricerca Scientifica e Technologica
    Inventors: Roberto Cipolli, Roberto Oriani, Enrico Masarati, Gilberto Nucida
  • Patent number: 5252407
    Abstract: A rubber composite comprising polyester fibers as the reinforcing material, wherein a compound having at least one cyclic imino ether group of a specific structure in its molecule is incorporated in a rubber composite except for adhesive-treated polyester cords.
    Type: Grant
    Filed: November 18, 1991
    Date of Patent: October 12, 1993
    Assignees: Takeda Chemical Industries, Ltd., Toyo Boseki Kabushiki Kaisha
    Inventors: Kiyosuke Kamiyama, Shuzo Sawada, Kazuyuki Yabuki, Yasuo Sano
  • Patent number: 5225113
    Abstract: A photochromatic composition, endowed with a high light fatigue resistance contains a photochromatic compound belonging to the class of spirooxazines and an U.V.-stabilizer consisting of a sterically hindered amine to be defined by means of formula (I): ##STR1## wherein: R is either hydrogen or a methyl group,x is either oxygen or nitrogen,m is a number comprised within the range of from 2 to 10, andn is a number coprised within the range of from 1 to 100.A photochromatic article made from a thermoplastic material, endowed with a high light fatigue resistance, contains a thermoplastic material and the hereinabove disclosed photochromatic composition.
    Type: Grant
    Filed: March 19, 1992
    Date of Patent: July 6, 1993
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Busetto, Luciana Crisci
  • Patent number: 5214084
    Abstract: A polypropylene resin containing an .alpha.-olefinic copolymer rubber and an inorganic filler is stabilized by incorporating therein the following 6 components:(A) a hindered phenolic compound having a molecular weight of not less than 500,(B) a high-molecular hindered piperidine compound such as poly[{6-(1,1,3,3-tetramethylbutyl)amino-1,3,5-triazine-2,4-diyl}{(2,2,6,6- tetramethyl-4-piperidyl)-imino}hexamethylene{(2,2,6,6-tetramethyl-4-piperid yl)imino}],(C) a low-molecular hindered piperidine compound such as 2-methyl-2-(2,2,6,6-tetramethyl-4-piperidyl)amino-N-(2,2,6,6-tetramethyl-4 -piperidyl)propionamide,(D) a benzoate compound such as 2,4-di-t-butylphenyl 3,5-di-t-butyl-4-hydroxybenzoate,(E) a phosphorous compound such as bis(2,4-di-t-butylphenyl) pentaerythritol diphosphite, and(F) an amide compound such as ethylene-bisstearylamide. This composition may also contain a sulfur compound such as dialkyl thiodipropionate and pentaerythritol tetrakis(3-alkylthiopropionate).
    Type: Grant
    Filed: August 24, 1992
    Date of Patent: May 25, 1993
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Tamaki Ishii, Shinichi Yachigo
  • Patent number: 5210120
    Abstract: Polymeric compositions endowed with high self-extinguishing characteristics o flame, based on thermoplastic polymers or polymers having elastomeric properties, especially olefin polymers and copolymers, comprising:a) from 89 to 40 parts by weight of a thermoplastic polymer or of a polymer having elastomeric properties;b) from 8 to 33 parts by weight of one or more phosphates and/or phosphonates of ammonium or of amine;c) from 3 to 27 parts by weight of one or more oligomeric compounds derived from the 2,4-diamino-6-hydroxy-1,3,5-triazine, having the general formula (I): ##STR1##
    Type: Grant
    Filed: October 31, 1991
    Date of Patent: May 11, 1993
    Assignee: Ministero Dell'Universita' e Della Ricerca Scientifica e Technologica
    Inventors: Roberto Cipolli, Enrico Masarati, Gilberto Nucida, Roberto Oriani, Mario Pirozzi
  • Patent number: 5210118
    Abstract: The present invention relates to a novel method for stabilizing synthetic thermoplastic materials against thermal degradation, which comprises incorporating in said materials one or more compounds of the formula (I) ##STR1## in which R.sub.1 is unsubstituted or substituted phenyl, n is e.g. 1, 2 or 3, and, when n is 1, R.sub.2 is e.g. --COR.sub.3, --COOR.sub.4 or --CO-N(R.sub.5)R.sub.6 in which R.sub.3 is e.g. C.sub.4 -C.sub.17 alkyl, R.sub.4 is e.g. C.sub.4 -C.sub.18 alkyl, cyclohexyl or t-butylcyclohexyl, R.sub.5 and R.sub.6 which can be identical or different are e.g. C.sub.2 -C.sub.8 alkyl or cyclohexyl, and, when n is 2, R.sub.2 is e.g. --CO--R.sub.10 --OC, --COO-R.sub.11 --OOC-- or --CONH--R.sub.12 --NHCO- in which R.sub.10 is e.g. C.sub.2 -C.sub.8 alkylene, R.sub.11 is e.g. C.sub.4 -C.sub.6 alkylene and R.sub.12 is e.g. C.sub.4 -C.sub.6 alkylene, and, when n is 3, R.sub.2 is e.g. benzenetricarbonyl.Several compounds of the formula (I) are new.
    Type: Grant
    Filed: June 10, 1991
    Date of Patent: May 11, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Roberto Scrima
  • Patent number: 5200445
    Abstract: Polymeric compositions endowed with high characteristics of flame self-esguishing, based on thermoplastic polymers or showing elastomeric properties, especially olefin polymers and copolymers, comprising:a) from 89 to 40 parts by weight of a thermoplastic polymer or having elastomeric properties;b) from 8 to 33 parts b.w; of one or more phosphates and/or phosphonates of ammonium or of an amine;c) from 3 to 27 parts b.w.
    Type: Grant
    Filed: September 11, 1991
    Date of Patent: April 6, 1993
    Assignee: Ministero Dell'Universita' e Della Ricerca Scientifica e Tecnologica
    Inventors: Roberto Cipolli, Enrico Masarati, Gilberto Nucida, Mario Pirozzi, Roberto Oriani
  • Patent number: 5190999
    Abstract: Compositions comprising an organic material liable to oxidative, thermal and/or actinic degradation and at least one compound of the formula I ##STR1## are described in which n is 1-6, R, R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are preferably hydrogen and A is a monovalent radical or polyvalent linking moiety.Some of the compounds of the formula I are novel. They are particularly suitable for the stabilization of lubricating oils, metal processing fluids and hydraulic fluids, and of thermoplastics and elastomers.
    Type: Grant
    Filed: June 24, 1991
    Date of Patent: March 2, 1993
    Assignee: Ciba-Geigy Corporation
    Inventor: Peter Nesvadba
  • Patent number: 5158998
    Abstract: Acrylic or alkyd resin and polyester based covering or coating compositions are stabilized against the action of light and moisture by adding, possibly in the presence of conventional stabilizers and antioxidants, at least one compound containing at least one N-substituted, sterically hindered piperidino, morpholino or pyrrolidino group, and at least one silyl function, or a polymer structure with a polyorganosiloxane structure containing sterically hindered piperidino groups in the molecule.
    Type: Grant
    Filed: March 18, 1991
    Date of Patent: October 27, 1992
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Carlo Neri, Francesco Gratani, Gianluigi Landoni, Silvestro Costanzi
  • Patent number: 5153245
    Abstract: Polymeric compositions endowed with high characterics of self-extinguishing o flame based on thermoplastic polymers or having elastomeric properties, especially olefin polymers and copolymers, comprising:a) from 91 to 40 parts by weight of a thermoplastic polymer or having elastomeric properties;b) from 6 to 33 parts by weight of one or more phosphates and/or phosphonates of ammonium or of an amine;c) from 3 to 27 parts by weight of one or more compounds derived from 2,4-diamino-6-hydroxy-1,3,5-triazine, having the general formula (I): ##STR1##
    Type: Grant
    Filed: September 9, 1991
    Date of Patent: October 6, 1992
    Assignee: Ministero Dell'Universita' E Della Ricerca Scientifica E Technologic
    Inventors: Roberto Cipolli, Gilberto Nucida, Enrico Masarati, Roberto Oriani, Mario Pirozzi
  • Patent number: 5139885
    Abstract: A resin composition, being useful for coating on electric wire, comprises an aromatic polyester, a halogenated compound such as diol, diglycidyl and dicarboxylic acid and a di-heterocyclic compound.
    Type: Grant
    Filed: March 20, 1990
    Date of Patent: August 18, 1992
    Assignee: Polyplastics Co., Ltd.
    Inventors: Toshio Nakane, Yukihiko Kageyama, Hiroaki Konuma, Kenji Hijikata
  • Patent number: 5130356
    Abstract: A novel, optically transparent, isotropic molding for optical purposes which is free of orientation birefringence consists of a mixture of polyphenylene ethers, vinylaromatic polymers and additives. The novel molding contains traces of novel diphenoquinone and/or diphenohydroquinone derivatives as additives and may also contain novel ammonium salts of sulfuric acid half esters of diphenohydroquinones as further additives. The novel molding has a yellowness index (YI) of from 40 to 90. It can be produced in a simple manner by injection molding processes. The novel molding in the form of a circular disk having a central hole is very useful as a dimensionally stable substrate of audio compact disks (CD), audiovisual compact disks (CDV), laser-optical computer disks and magneto-optical computer disks, and data media of this type which contain these novel dimensionally stable substrates have particularly advantageous performance characteristics.
    Type: Grant
    Filed: February 1, 1990
    Date of Patent: July 14, 1992
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl-Heinz Feuerherd, Carola Hedtmann-Rein, Ludger Leber
  • Patent number: 5116919
    Abstract: A process for increasing the relative viscosity of a polyamide includes heating the polyamide in the presence of a base and a catalyst with the catalyst being at least one compound of the formula:X--(CH.sub.2).sub.n PO.sub.3 R.sub.2wherein X is 2-pyridyl, 4-morpholino, 1-pyrrolidino, 1-piperidino or R'.sub.2 --N-- wherein R' is an alkyl group having between 1 and 12 carbon atoms;n is an integer from 2 to 5; andR, being the same or different, is H or an alkyl group having between 1 and 12 carbon atoms.
    Type: Grant
    Filed: December 5, 1990
    Date of Patent: May 26, 1992
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: John F. Buzinkai, Marion R. DeWitt, Jr., Robert C. Wheland
  • Patent number: 5085905
    Abstract: An elastomeric composition having improved adhesion to metal reinforcement is disclosed, said elastomeric composition comprising an elastomer containing, an adhesion promoting amount of a polysulfide having the formulaR--S.sub.(m) --R'where m is an integer of from about 2 to 6; R and R' are the same or different and are ##STR1## R" is an alkyl group of from about 1 to 4 carbon atoms; and R'" is an alkyl group of from about 1 to 4 carbon atoms or an aryl group.
    Type: Grant
    Filed: June 6, 1990
    Date of Patent: February 4, 1992
    Assignee: Dayco Products, Inc.
    Inventor: Harold D. Beck
  • Patent number: 5079284
    Abstract: A polymer such as polyester is modified with reaction with a modifier of a compound having the formula: ##STR1## in which X is halogen, Y.sub.1 and Y.sub.2 are a three- to eight-membered ring, Z is a divalent organic group and n is 1 or more.
    Type: Grant
    Filed: February 8, 1990
    Date of Patent: January 7, 1992
    Assignee: Polyplastics Co., Ltd.
    Inventors: Toshio Nakane, Yukihiko Kageyama, Kenji Hijikata
  • Patent number: 5047531
    Abstract: Piperidine-triazine compounds of the general formula (I) ##STR1## in which R.sub.1 is e.g. hydrogen or methyl, R.sub.2 is e.g. C.sub.2 -C.sub.6 alkylene, R.sub.3 is e.g. a group ##STR2## ##STR3## can be used as light stabilizers, heat stabilizers and oxidation stabilizers for organic materials, in particular synthetic polymers.
    Type: Grant
    Filed: August 2, 1989
    Date of Patent: September 10, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Giuseppe Cantatore, Graziano Vignali
  • Patent number: 5041478
    Abstract: A resin composition for printed circuit board and the printed circuit board in which said resin composition is used as substrate, said resin composition comprising one or more cyclic phosphonitrile compounds represented by the general formula [I] and/or [II] and an aromatic maleimide compound and/or an aromatic amine: ##STR1## wherein at least two of R's (R.sub.1 to R.sub.
    Type: Grant
    Filed: June 6, 1990
    Date of Patent: August 20, 1991
    Assignee: Hitachi, Ltd.
    Inventors: Katuo Sugawara, Akio Takahashi, Masahiro Ono, Toshikazu Narahara
  • Patent number: 5037877
    Abstract: A process for producing an acrylic and/or methacrylic polymer based preparation for the surface treatment of zinc consists in polymerizing at least one (meth)acrylic acid and at least one (meth)acrylate in a mixture of organic cosolvents. The preparation is then formed from the resultant copolymer in the cosolvents by dilution in a quantity of water and preferably an excess of water with respect to the cosolvents in the polymerization stage.
    Type: Grant
    Filed: August 6, 1990
    Date of Patent: August 6, 1991
    Assignee: Produits Chimiques Auxiliaires et de Synthese (P.C.A.S.)
    Inventor: Jean P. Kerherve
  • Patent number: 5021479
    Abstract: Substituted hydroxylamine ester stabilizers corresponding to the formula ##STR1## wherein n is 0-2, X is a direct bond, --S-- or --CH.sub.2 S--, R.sub.1 and R.sub.2 are independently hydrogen, alkyl, cycloalkyl, aralkyl, R.sub.3 and R.sub.4 are independently alkyl, cycloalkyl or aralkyl, and R.sub.5 is hydrogen or the group ##STR2## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation.
    Type: Grant
    Filed: October 12, 1989
    Date of Patent: June 4, 1991
    Assignee: Ciba-Geigy Corporation
    Inventors: Ramanathan Ravichandran, Stephen D. Pastor
  • Patent number: 5019611
    Abstract: There is disclosed compounds having, within their structural formulae, a trivalent moiety: ##STR1## which exhibit antiozonant activity when added to rubber compositions at antiozonant effective levels and which exhibit synergistic antiozonant activity when used with conventional antiozonants in rubber compositions. There is also disclosed novel compounds which can be used as antiozonants.
    Type: Grant
    Filed: January 15, 1987
    Date of Patent: May 28, 1991
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Kevin L. Rollick, James G. Gillick, Joseph A. Kuczkowski
  • Patent number: 5004789
    Abstract: Compositions of phenolic resins, for example, phenol formaldehyde resins, containing an additive of triethanolamine borate or an amine/oxygen-containing boron derivative mixture, e.g., triethanolamine and boric anhydride, are particularly useful for the manufacture of prepeg mats.
    Type: Grant
    Filed: June 4, 1987
    Date of Patent: April 2, 1991
    Assignee: Societe Chimiques des Charbonnages S.A.
    Inventors: Francois Boinot, Michel Cousin, Pierre-Michel Francois, Francois Michel-Dansac
  • Patent number: 4985479
    Abstract: A stabilized polyolefin composition having improved weathering resistance is provided, whereby the following four components are incorporated into a polyolefin:(A) a hindered piperidine compound having a molecular weight of more than 750, such as poly-{[6-morpholino-1,3,5-triazine-2,4-diyl][2,2,6,6-tetramethyl-4-piperid yl)imino]hexamethylene[2,2,6,6-tetramethyl-4-piperidyl)imino]},(B) a hindered piperidine compound having a molecular weight of less than 500, such as bis(2,2,6,6-tetramethyl-4-piperidyl) sebacate,(C) a benzoate compound such as 2,4-di-t-butylphenyl 3,5-di-t-butyl-4-hydroxybenzoate, and(D) a phosphorus-containing compound such as bis(2,4-di-t-butylphenyl) pentaerythritol diphosphite.
    Type: Grant
    Filed: March 28, 1989
    Date of Patent: January 15, 1991
    Assignee: Sumitomo Chemical Company, Ltd.
    Inventors: Hideo Nagasaki, Shinichi Yachigo, Takeshi Takata, Hiroki Yamamoto, Yukoh Takahashi
  • Patent number: 4977197
    Abstract: A photopolymerizable dental composition, which comprises:(A) an organic composite filler obtained by polymerizing at least one carboxylic acid monomer of the formula: ##STR1## wherein R.sub.1 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a --COOY group, a halogen atom, or a phenyl group or a derivative thereof; R.sub.2 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a --COOZ group, a halogen atom, or a phenyl group or a derivative thereof; R.sub.3 is a hydrogen atom, a C.sub.1 -C.sub.15 alkyl group, a halogen atom, or a phenyl group or a derivative thereof; and each of X, Y and Z is a hydrogen atom, NH.sub.4 or an alkali metal atom; or the formula: ##STR2## wherein each of R.sub.4 and R.sub.5 is a hydrogen atom, a C.sub.1 -C.sub.
    Type: Grant
    Filed: May 12, 1988
    Date of Patent: December 11, 1990
    Assignee: Mitsubishi Rayon Company Limited
    Inventors: Isao Sasaki, Nobuhiro Mukai, Hitoshi Ige
  • Patent number: 4954541
    Abstract: A resin composition, being useful for coating on electric wire, comprises an aromatic polyester, a halogenated compound such as diol, diglycidyl and dicarboxylic acid and a di-heterocyclic compound.
    Type: Grant
    Filed: November 15, 1988
    Date of Patent: September 4, 1990
    Assignee: Polyplastics Co., Ltd.
    Inventors: Toshio Nakane, Yukihiko Kageyama, Hiroaki Konuma, Kenji Hijikata
  • Patent number: 4952619
    Abstract: Reactive stabilizing compounds, able to stabilize organic polymers, contain in their molecule a sterically hindered amino group and a hydrolyzable silyl function.In stabilizing organic polymers, said reactive stabilizing compounds can be hydrolyzed at the silyl function with the formation of silanol groups, which are made to interact in order to form complex resinous stabilizing structures. These latter are added in stabilizing quantities to the polymer to the stabilized.According to one particular embodiment, the hydrolysis at the silyl function and the formation of the resinous structure take place spontaneously within the polymer to be stabilized.According to a further embodiment, the reactive stabilizing compound is added to the polymer after being stably supported on a solid support by reaction with an inorganic solid having surface hydroxyl groups.
    Type: Grant
    Filed: May 14, 1987
    Date of Patent: August 28, 1990
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Alberto Greco, Carlo Busetto, Luigi Cassar, Carlo Neri
  • Patent number: 4948546
    Abstract: AB dispersants made by group transfer polymerization aid in controlling color shift during casting of MMA polymer sheet containing color pigments and additives, particularly chain transfer agent and sheet release agent.
    Type: Grant
    Filed: December 2, 1988
    Date of Patent: August 14, 1990
    Assignee: E. I. Du Pont de Nemours and Company
    Inventors: Walter H. Delphin, Clyde S. Hutchins, Robert J. Buchacek
  • Patent number: 4946880
    Abstract: Reactive stabilizer compounds, to be used in the stabilization of organic polymers, contain a sterically hindered, N-substituted piperidinic, morpholinic or pyrrolidinic group, and at least a hydrolysable silicic function.Such compounds give rise, by hydrolysis of the silicic function, to complex resinous structures endowed with stabilizing properties.The reactive stabilizer compounds can spontaneously hydrolyse inside the polymer, or they can be stably supported on a solid support, or they can be chemically linked to the polymeric chain to be stabilized.
    Type: Grant
    Filed: October 5, 1987
    Date of Patent: August 7, 1990
    Assignee: Enichem Synthesis S.p.A.
    Inventors: Silvestro Costanzi, Damiano Gussoni, Omero Zavattini, deceased, by Clara Pungiluppi, heir, by Renato Zavattini, heir, Luciano Pallini
  • Patent number: 4946734
    Abstract: A resin composition for printed circuit board and the printed circuit board in which said resin composition is used as substrate, said resin composition comprising one or more cyclic phosphonitrile compounds represented by the general formula [I] and/or [II] and an aromatic maleimide compound and/or an aromatic amine: ##STR1## wherein at least two of R's (R.sub.1 to R.sub.
    Type: Grant
    Filed: November 18, 1987
    Date of Patent: August 7, 1990
    Assignee: Hitachi, Ltd.
    Inventors: Katuo Sugawara, Akio Takahashi, Masahiro Ono, Toshikazu Narahara
  • Patent number: 4929653
    Abstract: Excellent stabilization of pigmented polypropylene (PP) fiber against gas fade upon exposure to atmospheric pollutants is obtained with a hindered amine containing a polysubstituted piperazin-2-one (PSP) moiety, for example, a C.sub.2 -C.sub.12 alkylene connecting two PSP moieties, or a trisubstituted triazine ring with three PSP substituents, or a polyalkylene polyamine having pendant substituted oxo-piperazinyl-traizine moieties (PIP-T), that is, having pendant triazine rings substituted with PSP substituents. The stabilizers are unexpectedly effected when used without an antioxidant which produces yellowing, if used. Either pigmented or unpigmented PSP-stabilized PP fibers, and particularly fibers pigmented with white or pastel dyes, and having a non-alkaline "finish" are especially benefitted.
    Type: Grant
    Filed: July 13, 1987
    Date of Patent: May 29, 1990
    Assignee: The BF Goodrich Company
    Inventors: George Kletecka, John T. Lai, Pyong N. Son
  • Patent number: 4927667
    Abstract: An aqueous process is described for preparing water-resistant coatings of hydrophobic copolymers of a predetermined composition. The hydrophobic copolymers are made from hydrophilic comonomers such as a vinyl lactam and a polymerizable carboxylic acid. The hydrophobic copolymers are rendered water soluble with a volatile neutralizing agent, such as ammonium hydroxide, then coated onto a substrate and heated to provide the water-resistant coating, and, if desired, redissolved in an aqueous alkaline solution.
    Type: Grant
    Filed: June 22, 1989
    Date of Patent: May 22, 1990
    Assignee: GAF Chemicals Corporation
    Inventors: Jenn S. Shih, Terry E. Smith, Robert B. Login
  • Patent number: 4918122
    Abstract: The invention provides a composition comprising a resin processable at temperatures upto 160.degree. C. having incorporated therein a flame retardant amount of a salt formed by reaction between dimethyl methyl phosphonate, monomethyl methyl phosphonate or methyl phosphonic acid, and a compound of the general formula (I) ##STR1## in which X is 0 or S; R.sup.1 is H, alkyl with 1 to 4 carbon atoms, alkenyl of up to 4 carbon atoms, CN, CONH.sub.2 or NH.sub.2, R.sup.2 is H, alkyl with 1 to 4 carbon atoms or alkenyl of up to 4 carbon atoms or R.sup.1 and R.sup.2 together with the nitrogen atom to which they are attached form a heterocyclic ring of up to 6 carbon atoms which may optionally contain another hetero atom and R is H, an alkyl group with 1 to 8 carbon atoms, an aryl group with 6 to 10 carbon atoms, a cycloalkyl group with 5 to 12 carbon atoms or a heterocyclic group with up to 9 ring carbon atoms, or, together with R.sup.1 forms an alkylene chain of 3 to 10 carbon atoms, or R is a group NHR.sup.
    Type: Grant
    Filed: July 15, 1987
    Date of Patent: April 17, 1990
    Assignee: Ciba-Geigy Corporation
    Inventors: Richard J. Dellar, Norman Richardson, deceased, Brian G. Clubley
  • Patent number: 4889881
    Abstract: An ethylene-.alpha.-olefin vulcanized rubber composition with excellent weather resistance and high transparency which is formed by vulcanizing with an organic peroxide an unvulcanized rubber composition comprising an ethylene-.alpha.-olefin rubber containing no metal oxide nor metal carbonate.
    Type: Grant
    Filed: August 9, 1988
    Date of Patent: December 26, 1989
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Hiroyoshi Takao, Yoshio Tanimoto, Kiyosi Ikeda
  • Patent number: H889
    Abstract: Improved processabiity and thermal stability is demonstrated by stabilized compositions comprising a linear alternating polymer of carbon monoxide and at least one ethylenically unsaturated hydrocarbon having incorporated therein a stabilizing quantity of a stable organic free radical.
    Type: Grant
    Filed: August 7, 1989
    Date of Patent: February 5, 1991
    Assignee: Shell Oil Company
    Inventor: Robert Q. Kluttz