Six-membered Nitrogen Ring Having At Least One Diverse Hetero Atom, E.g., Morpholine, Etc. Patents (Class 524/96)
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Patent number: 4826903Abstract: Composition useful for molding into articles such as food containers, beverage bottles, cured structural plastics and the like comprising molding grade linear or unsaturated polyester or polycarbonate (a) containing a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound or (b) having reacted therewith or copolymerized therein a styryl residue derived from a mono-4-acryloxystyryl or bis-4-acyloxystyryl compound, having the formula ##STR1## wherein R.sup.4 and R.sup.5 represent the acyl radical and the other radicals are as defined in the specification.Preferred compositions comprise a linear polyester containing a styryl residue as an integral part of the polymer chain. The styryl residues absorb ultraviolet radiation in the range of about 250 to about 390 nm. The residues are non-extractable from the polymer and stable at the conditions at which the polymers are manufactured and processed.Type: GrantFiled: February 22, 1988Date of Patent: May 2, 1989Assignee: Eastman Kodak CompanyInventors: Max A. Weaver, Samuel D. Hilbert, Wayne P. Pruett, Clarence A. Coates, Jr.
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Patent number: 4826902Abstract: A coating composition based on an acrylic resin which is useful for preparing lubricated steel products such as steel sheets or tubes is disclosed. The coating composition contains as additives a rust preventive which is a mixture of a sulfonamidecarboxylic acid and an cyclic amine and a water repellent. It exhibits improved rust-preventing properties when lubricated steel products having a coating film formed from the coating composition are stored for a prolonged period under coiled or stacked conditions.Type: GrantFiled: March 11, 1988Date of Patent: May 2, 1989Assignees: Nippon Oil & Fats Co., Ltd., Sumitomo Metal Industries, Ltd.Inventors: Hiroki Hanabata, Hideo Kawaguchi, Hiroshi Fukudome, Ryoichi Noumi, Hiromi Izaiku, Koichi Komai, Kisuke Yoshida
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Patent number: 4816506Abstract: Aqueous silicone dispersions containing (a) polydiorganosiloxanes having hydroxyl groups in the terminal units, (b) (organo)metallic compound(s), (c) a siliconate, and optionally, (d) a silicone resin.These aqueous silicone dispersions will cure to form elastomeric coatings or sealants when the water is removed by evaporation.Type: GrantFiled: October 30, 1987Date of Patent: March 28, 1989Assignee: Wacker-Chemie GmbHInventors: Norbert Gamon, Karl Braunsperger, Otto Schneider
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Patent number: 4812501Abstract: 1,3,2-oxazaphospholidine derivatives of the formula ##STR1## are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants.Type: GrantFiled: March 16, 1988Date of Patent: March 14, 1989Assignee: Ciba-Geigy CorporationInventors: Paul A. Odorisio, Stephen D. Pastor, James L. Hyun
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Patent number: 4812499Abstract: Compositions of thermoplastic polymers comprising, in mixture, a thermoplastic polymer and a mixture of self-extinguishability-conferring additives, formed by:ammonium phosphate or ammonium polyphosphate: ##STR1## (wherein p is preferably equal to or greater than 50); phosphorus-containing compound definable by means of the general formula: ##STR2## (wherein R.sub.1, R.sub.2 and R.sub.3 have the meaning as indicated in the disclosure).Type: GrantFiled: March 20, 1986Date of Patent: March 14, 1989Assignee: Enichem Sintesi S.p.A.Inventors: Gioacchino Cipriani, Gianluigi Landoni
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Patent number: 4774332Abstract: A compopund containing one or more units of formula I ##STR1## in which R.sub.1 is --CH.sub.2 C.sub.1-4 alkyl or --CH.sub.3 or both groups R.sub.1 form --(CH.sub.2).sub.5 --;R.sub.2 is --CH.sub.2 C.sub.1-4 alkyl or --CH.sub.3 or both groups R.sub.2 form --(CH.sub.2).sub.5 --;R.sub.3 is furylmethyl, unsubstituted C.sub.1-18 alkyl; C.sub.1-4 alkyl monosubstituted by phenyl, the phenyl group of which is unsubstituted or substituted by 1 to 3 groups selected from --OH and C.sub.1-8 alkyl; C.sub.2-8 alkyl monosubstituted by C.sub.1-4 alkoxy; phenyl, unsubstituted or substituted by 1 to 3 groups selected from C.sub.1-8 alkyl and --OH; or cyclohexy, unsubstituted or monosubstituted by C.sub.1-8 alkyl or --OH.These compounds are useful as light stabilizers for polymeric material.Type: GrantFiled: July 11, 1986Date of Patent: September 27, 1988Assignee: Sandoz, Ltd.Inventor: Lajos Avar
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Patent number: 4771091Abstract: Novel diazaspirodecanes of the general formula ##STR1## are prepared from known diazaspirodecane compounds and epoxy compounds or by reacting diazaspirodecane-substituted epoxy compounds with alcohols or amines and are excellent light stabilizers for synthetic polymers.Type: GrantFiled: November 24, 1986Date of Patent: September 13, 1988Assignee: Hoechst AktiengesellschaftInventor: Josef Ertl
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Patent number: 4759801Abstract: A method for preparing a pigment preparation comprising kneading a pigment presscake (comprising a pigment and water and/or one or more organic liquids) at a temperature in the range 80.degree. to 200.degree. C. under vacuum together with a thermoplastic material, thereby at the same time removing the water and/or any organic liquids present. These preparations are useful for coloring polymeric material.Type: GrantFiled: July 10, 1986Date of Patent: July 26, 1988Assignee: Sandoz Ltd.Inventors: Jurgen Goldmann, Bansi L. Kaul
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Patent number: 4757102Abstract: Various substituted aminoxy alkylamine derivatives are effective in stabilizing organic materials against oxidative, thermal and actinic degradation, said derivatives being particularly effective as color improvers and process stabilizers in organic materials containing phenolic antioxidants and/or metal salts of fatty acids and/or hindered amine light stabilizers and/or organic phosphorus compounds; and certain of said derivatives as new compounds.Type: GrantFiled: May 12, 1986Date of Patent: July 12, 1988Assignee: Ciba-Geigy CorporationInventors: Ramanathan Ravichandran, Stephen D. Pastor, Thomas E. Snead
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Patent number: 4730016Abstract: Disclosed herein is a resin composition obtained by mixing an olefin-base resin, which has in turn been obtained by partially neutralizing a free carboxyl group in a random copolymer of an .alpha.-olefin and an .alpha.,.beta.-ethylenically-unsaturated monocarboxylic or dicarboxylic acid, with a volatile rust preventive in a specific amount or more. The resin composition has excellent rust preventive properties and can hence be used advantageously as a wrapping material for metal products.Type: GrantFiled: April 14, 1986Date of Patent: March 8, 1988Assignee: Aicerro Chemical Company LimitedInventors: Akira Fujii, Yasuhisa Isobe, Kenichi Hashiudo
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Patent number: 4708979Abstract: Spherically polymerized polyolefins can be advantageously stabilized by being treated with at least one emulsion or dispersion containing a stabilizer or a mixture of stabilizers and an amine of formula I ##STR1## wherein R.sub.1 is C.sub.1 -C.sub.20 alkyl which may be substituted by --OH, or is C.sub.3 -C.sub.50 alkyl which is interrupted by one or more oxygen atoms, or is C.sub.1 -C.sub.8 alkoxy, and each of R.sub.2 and R.sub.3 independently of the other is hydrogen or has one of the meanings indicated for R.sub.1, or R.sub.2 and Rphd 3, together with the nitrogen atom to which they are attached, form a 5- to 7-membered heterocyclic ring.Type: GrantFiled: April 25, 1986Date of Patent: November 24, 1987Assignee: Ciba-Geigy CorporationInventors: Enea Pedrazzetti, Andre Schmitter, Walter W. Meyer
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Patent number: 4675353Abstract: Novel hindered 2-keto-1,4-diazacycloalkane-triazine oligomers having the general formula ##STR1## are useful antioxidants and UV stabilizers for various polymers.Type: GrantFiled: January 29, 1985Date of Patent: June 23, 1987Assignee: The BFGoodrich CompanyInventors: Pyong-Nae Son, John T. Lai
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Patent number: 4673700Abstract: Amide substituted benzylhydroxylamine derivatives are effective in stabilizing polyolefin compositions containing a stabilizer or mixture of stabilizers selected from the group consisting of the phenolic antioxidants, the hindered amine light stabilizers, the alkylated hydroxybenzoate light stabilizers, the ultraviolet light absorbers, the organic phosphorus compounds, the alkaline metal salts of fatty acids and the thiosynergists, against degradation upon high temperature extrusion, exposure to the combustion products of natural gas, gamma irradation or upon storage for extended periods. These amide substituted benzylhydroxylamine derivatives exhibit resistance to loss or extraction during processing and in end-use applications.Type: GrantFiled: November 21, 1985Date of Patent: June 16, 1987Assignee: Ciba-Geigy CorporationInventors: Ramanathan Ravichandran, Thomas E. Snead
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Patent number: 4670486Abstract: High molecular weight organic material is effectively colored by the incorporation therein of a copper or nickel complex of the ligand compound of formula I ##STR1## wherein A is an isocyclic or heterocyclic aromatic moiety, R is H, halogen, lower alkyl or alkoxy, R.sub.1 is H, lower alkyl, phenyl or substituted phenyl, and B is H, lower alkyl, ureido or substituted ureido, guanidino, anilino, benzamido or a heterocyclic aromatic moiety.Type: GrantFiled: June 13, 1985Date of Patent: June 2, 1987Assignee: Ciba-Geigy CorporationInventors: Georg Cseh, Paul Lienhard
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Patent number: 4639479Abstract: A polyalkylenepolyamine ("PAPA") main chain having pendant substituted 2-oxo-piperazinyl-triazines attached to the N atoms of the PAPA main chain are novel compounds which have highly desirable UV-light stabilizing (UV-S) activity coupled with unexpectedly good thermal stability. These compounds, referred to as "pendant piperazinyl triazines" or P[PIP-T] for brevity, are used in polymer recipes to formulate a stabilized polymeric composition comprising a light-degradable organic polymer containing an effective amount of a P[PIP-T] sufficient to stabilize the polymer. A P[PIP-T] is especially effective in a polyolefin in which there is from about 0.1 percent by weight (% by wt), to about 5% by wt, and is also effective in a wide variety of pastel colored and/or transparent commercially significant polymers.Type: GrantFiled: September 20, 1985Date of Patent: January 27, 1987Assignee: The BFGoodrich CompanyInventors: John T. Lai, Pyong N. Son
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Patent number: 4629752Abstract: A particular branched chain polyalkylenepolyamine ("PAPA") having plural amine groups including a secondary amine group intermediate terminal free primary amine groups (that is, neither one is hindered), and having at least two C atoms between each group, may be selectively cyclized with a ketoform reaction to form a polysubstituted piperazinone ("PSP"), with specific directivity. Such PSPs are linked to a triazine nucleus to yield piperazinone-triazine ("PIP-T") compounds which are excellent stabilizers for polyolefins and other light-degradable polymers. Certain acyclic polyalkylenepolyamines may have a PIP-T substituent at each N atom forming pendant PIP-Ts ("P[PIP-T]" for brevity) which are also excellent stabilizers, and like some of the PIP-Ts, some P[PIP-T]s provide photostabilization without noticeably interfering with the color of films and fibers provided by even pastel-colored pigments and dyes.Type: GrantFiled: July 22, 1985Date of Patent: December 16, 1986Assignee: The B. F. Goodrich CompanyInventors: Robert W. Layer, John T. Lai, Pyong N. Son
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Patent number: 4623684Abstract: A composition comprising:(A) a first component selected from the group consisting of:(i) an oil-soluble ethylene backbone polymer having a number average molecular weight in the range of about 500 to about 50,000;(ii) a hydrocarbyl-substituted phenol of the formula(R.sup.*).sub.a --Ar--(OH).sub.b Iwherein R.sup.Type: GrantFiled: October 16, 1985Date of Patent: November 18, 1986Assignee: The Lubrizol CorporationInventors: Casper J. Dorer, Jr., Katsumi Hayashi
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Patent number: 4617333Abstract: Stabilized polyolefinic compositions comprise a polyolefin, such as polyethylene and polypropylene and a stabilizing amount of an organic compound comprising at least one 3,3,5,5-tetramethylmorpholine or one 2,3,3,5,5-pentamethylene morpholine: ##STR1## wherein R is hydrogen or the methyl group; bearing a substituent on the carbon atom in the position 2 and/or on the nitrogen atom in the position 4 of the ring.Type: GrantFiled: March 8, 1985Date of Patent: October 14, 1986Assignee: Enichem Sintesi, S.p.A.Inventors: Silvestro Costanzi, Enrico Traverso, Roberto Podesta, Damiano Gussoni, Carlo Busetto
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Patent number: 4613342Abstract: A composition comprising:(A) a first component selected from the group consisting of:(i) an oil-soluble ethylene backbone polymer having a number average molecular weight in the range of about 500 to about 50,000;(ii) a hydrocarbyl-substituted phenol of the formula(R*).sub.a -Ar-(OH).sub.Type: GrantFiled: October 16, 1985Date of Patent: September 23, 1986Assignee: The Lubrizol CorporationInventors: Casper J. Dorer, Jr., Katsumi Hayashi
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Patent number: 4613636Abstract: A peroxide-curable fluoroelastomer composition which can be readily removed from a mold cavity without tearing which comprises a fluoroelastomer whose interpolymerized units consist essentially of units of tetrafluoroethylene, units of perfluoroalkyl perfluorovinyl ether, units of a bromine-containing olefin and, optionally, units of ethylene, and from about 0.05-2 parts per 100 parts fluoroelastomer of an N,N,N',N'-tetrasubstituted 1,8-diaminonaphthalene having the formula: ##STR1## wherein R.sub.1, R.sub.2, R.sub.3 and R.sub.4 are independently alkyl groups of 1-6 carbon atoms, phenyl or benzyl, R.sub.1 and R.sub.2 and/or R.sub.3 and R.sub.4 can be joined to form a 5- or 6-membered heterocyclic ring in which a carbon atom can be replaced by an oxygen or a sulfur atom, R.sub.1 and R.sub.3 and/or R.sub.2 and R.sub.Type: GrantFiled: July 12, 1985Date of Patent: September 23, 1986Assignee: E. I. Du Pont de Nemours and CompanyInventor: Leo Ojakaar
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Patent number: 4602052Abstract: A rubber composition containing carbon black as a reinforcing filler and a quaternary ammonium salt as a coupling agent and a method of making it are disclosed.Type: GrantFiled: September 17, 1984Date of Patent: July 22, 1986Assignee: Amoco CorporationInventors: Kenneth E. Weber, Dirk Oberlin
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Patent number: 4598105Abstract: A rubber composition containing carbon black and a second particulate filler of kaolin, metakaolin, talc, pyrophyllite coal, coke, graphite or metal carbonate filler and a method of making it are disclosed.Type: GrantFiled: September 17, 1984Date of Patent: July 1, 1986Assignee: Amoco CorporationInventors: Kenneth E. Weber, Dirk Oberlin
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Patent number: 4575526Abstract: A composition comprising:(A) a first component selected from the group consisting of:(i) an oil-soluble ethylene backbone polymer having a number average molecular weight in the range of about 500 to about 50,000;(ii) a hydrocarbyl-substituted phenol of the formula(R*).sub.a --Ar--(OH).sub.Type: GrantFiled: March 12, 1985Date of Patent: March 11, 1986Assignee: The Lubrizol CorporationInventors: Casper J. Dorer, Jr., Katsumi Hayashi
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Patent number: 4565843Abstract: This invention relates to new wire lacquers based on hydantoin group-containing polymers.Type: GrantFiled: December 18, 1984Date of Patent: January 21, 1986Assignee: Bayer AktiengesellschaftInventor: Willi Dunwald
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Patent number: 4525502Abstract: Water-based silicone resin emulsions are provided comprising an organopolysiloxane resin or mixture of resins which may include a solvent carrier, and a single emulsifying agent comprising the reaction product of an aliphatic carboxylic acid and an amine or ammonia as well as an amount of water sufficient for providing a water-based emulsion having a desired silicone resin solids content by weight.Type: GrantFiled: May 5, 1983Date of Patent: June 25, 1985Assignee: General Electric CompanyInventor: Frank J. Traver
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Patent number: 4522735Abstract: Amines are reacted with phosphorous trichloride to form N-dichlorophosphinoamines that are then reacted with a bisphenol in about equimolar amounts to provide polyphosphoramidite oligomers. The polyphosphoramidite oligomers are effective as stabilizers for polymers such as polyolefins, and form even more efficient stabilizer combinations with hydroxyphenylalkyleneyl isocyanurates.Type: GrantFiled: June 17, 1983Date of Patent: June 11, 1985Assignee: The B. F. Goodrich CompanyInventor: Dwight W. Chasar
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Patent number: 4515640Abstract: Fluoroaliphatic-thio,-sulfinyl and -sulfonyl substituted bicycloaliphatic amic acid amine salts of the formula: ##STR1## where R.sub.f is perfluoroalkyl, R' is alkylene optionally interrupted by --O--, --S-- or ##STR2## where R.sub.a is hydrogen or alkyl, Y is lower alkylene or --O--, n is 0-2, R.sub.1 and R.sub.2 are independently hydrogen, lower alkyl, hydroxy lower alkyl or together with the nitrogen to which they are attached, represented morpholino, R.sub.3, R.sub.4 and R.sub.5 are independently hydrogen, lower alkyl, or hydroxy lower alkyl, R.sub.6 is lower alkyl, carboxy lower alkyl, sulfo lower alkyl, hydroxy lower alkyl, benzyl or together with R.sub.5 and the nitrogen to which they are attached represent morpholino, and R is hydrogen or methyl are provided. These salts applied in the form of aqueous solutions, dispersions or emulsions are useful in rendering cellulosic and natural and synthetic polyamide materials oil and water repellent.Type: GrantFiled: June 13, 1983Date of Patent: May 7, 1985Assignee: Ciba Geigy CorporationInventors: Jurgen Kaschig, Eduard K. Kleiner, Karl F. Mueller, Thomas W. Cooke
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Patent number: 4508853Abstract: Polyurethane prepolymers containing terminal isocyanate groups in which oleochemical polyols are present as the polyol component. The oleochemical polyols are ring opened products or partial ring-opened products of epoxidized fatty acid triglycerides with alcohols. The use of oleochemical polyols having a residual epoxide number of from 1.0 to 4.0% by weight of epoxide oxygen is preferred. The polyurethane prepolymers are particularly suitable for use in one-component or two-component polyurethane foam formulations.Type: GrantFiled: May 8, 1984Date of Patent: April 2, 1985Assignee: Henkel KommanditgesellschaftInventors: Hermann Kluth, Alfred Meffert
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Patent number: 4504610Abstract: Self-extinguishing polymeric compositions based on thermoplastic polymers, comprising, for 100 parts by weight of total composition:(1) from 10 to 20 parts by weight of an ammonium phosphate or of an amine phosphate; and(2) from 5 to 8 parts by weight of an oligomer or polymer derived from 1,3,5-triazine, having general formula: ##STR1## wherein: ##STR2## or a heterocyclic radical containing in the ring at least a nitrogen atom, and linked to the triazine ring through one of such nitrogen atoms,R.sub.1 =alkyl or cycloalkyl,R.sub.2 =divalent radical of piperazine, of the type ##STR3## or a divalent radical of the type ##STR4## n=an integer from 20 to 50, extremes included, m=an integer from 2 to 6, extremes included.Type: GrantFiled: February 7, 1984Date of Patent: March 12, 1985Assignee: Montedison S.p.A.Inventors: Renzo Fontanelli, Gianluigi Landoni, Giovanni Legnani
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Patent number: 4495319Abstract: A concrete cure is provided which is totally water based and completely void of solvents. A moisture impermeable film is attained when the cure is applied to fresh concrete. The cure forms a barrier over the concrete allowing it to retain over 95% of the mixing water for a minimum of 72 hours when applied at the rate of 200 ft.sup.2 /gallon (5m.sup.2 /dm.sup.3). The concrete cure of the invention is a mixture of a hydrocarbon resin, emulsifying agents, paraffinic wax, and water. The cure may be provided in a clear or pigmented formulation. A method for making the concrete cure is also disclosed.Type: GrantFiled: December 29, 1983Date of Patent: January 22, 1985Assignee: W. R. Meadows, Inc.Inventors: John J. Sackis, Paul H. Anderson
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Patent number: 4495322Abstract: What are disclosed are coating formulations of improved storage stability comprising a silicone resin prepared by the condensation of partially hydrolyzed organo-silicon compounds in the presence of an acid, said coating formulations containing an amide of an alkanoic acid having up to 22 carbon atoms or an amide of benzoic acid, optionally substituted, or a carbamic acid ester having an alkyl group containing up to 18 carbon atoms or having a phenyl or naphthyl group, optionally substituted, in the ester part, or containing ureas or lactams, or mixtures thereof.Type: GrantFiled: March 5, 1984Date of Patent: January 22, 1985Assignee: Rohm GmbHInventor: Ralf Liebler
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Patent number: 4491643Abstract: Bis(2,2,6,6-tetramethylpiperidyl-1,3,5-triazinyl)-spirodiamines and spiroglycol ethers are provided, having the formula: ##STR1##Type: GrantFiled: January 9, 1984Date of Patent: January 1, 1985Assignee: Adeka Argus Chemical Co., Ltd.Inventors: Motonobu Minagawa, Yutaka Nakahara, Toshihiro Shibata, Etsuo Tobita
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Patent number: 4439563Abstract: A concrete cure is provided which is totally water based and completely void of solvents. A moisture impermeable film is attained when the cure is applied to fresh concrete. The cure forms a barrier over the concrete allowing it to retain over 95% of the mixing water for a minimum of 72 hours when applied at the rate of 200 ft.sup.2 /gallon (5m.sup.2 /dm.sup.3). The concrete cure of the invention is a mixture of a hydrocarbon resin, emulsifying agents, paraffinic wax, and water. The cure may be provided in a clear or pigmented formulation. A method for making the concrete cure is also disclosed.Type: GrantFiled: September 23, 1982Date of Patent: March 27, 1984Assignee: W. R. Meadows, Inc.Inventors: John J. Sackis, Paul H. Anderson
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Patent number: 4433085Abstract: A triazolidine-3,5-dione/formaldehyde/amine condensate is disclosed of the formula ##STR1## in which wherein the terms R.sup.1, R.sup.2 and R.sup.5 are defined hereinafter in the specificationa process for the preparation of such condensate by reaction of a triazolidine-3,5-dione with formaldehyde and a suitable nitrogen compound and the use of the condensate as a flame-proofing agent for thermoplastics, especially polyamide and as an auxiliary for modifying polymeric substances.Type: GrantFiled: June 29, 1981Date of Patent: February 21, 1984Assignee: Bayer AktiengesellschaftInventors: Ludwig Rottmaier, Rudolf Merten
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Patent number: 4427817Abstract: The use of open-chain acetals or ketals corresponding to the following general formula ##STR1## as non-discoloring anti-ozonants for natural and/or synthetic rubber.Type: GrantFiled: April 6, 1982Date of Patent: January 24, 1984Assignee: Bayer AktiengesellschaftInventors: Dieter W. Bruck, Werner Jeblick, Heinrich Konigshofen, Ernst Roos, Lother Ruetz
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Patent number: 4427811Abstract: A silicone elastomeric emulsion having improved shelf life is produced by a method which mixes the ingredients of the emulsion with the exception of a filler other than colloidal silica, then ages the mixture for at least two weeks at room temperature then adds the filler other than colloidal silica. The improved emulsion yields a film upon drying that has better physical properties. The emulsion contains an anionically stabilized, hydroxyl endblocked polydiorganosiloxane, colloidal silica, and an alkyl tin salt, as well as the filler other than colloidal silica. The emulsion has a pH of greater than 9 and a solids content of greater than 40 percent by weight. The emulsion is useful in forming a protective elastomeric coating over a substrate and as a caulking material.Type: GrantFiled: September 24, 1982Date of Patent: January 24, 1984Assignee: Dow Corning CorporationInventors: Michael G. Elias, Alan L. Freiberg
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Patent number: 4417013Abstract: A solid pigment composition comprises an intimate mixture of a pigment and a copolymer of an alkyl or cycloalkyl methacrylate ester and a lesser amount of an aminoalkyl methacrylate ester. The compositions are compatible with a wide range of substrates such as paints, printing inks and bulk polymers.Type: GrantFiled: January 18, 1982Date of Patent: November 22, 1983Assignee: Sandoz Ltd.Inventor: Johann Schuster
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Patent number: 4407993Abstract: N-(.beta.-aminoethyl)-3-hydroxy-1,1,6,6-tetramethyl-piperidine and certain of its N- and O-substituted derivatives are useful as light stabilizers for polymeric materials, particularly for thermoplastic polymers and automotive finishes. Preferred compounds include the N-, O-diacyl derivatives.Type: GrantFiled: March 15, 1982Date of Patent: October 4, 1983Assignee: Sandoz Ltd.Inventors: Hans Hinsken, Wolfgang Mueller, Hermann Schneider
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Patent number: 4399240Abstract: Acrylonitrile is a monomer that is widely used in the synthesis of a vast variety of polymers. Undesirable quantities of unpolymerized residual acrylonitrile are often present in these acrylonitrile polymers. This residual or free acrylonitrile dissolved in an acrylonitrile polymer and/or its emulsifier system and the water phase used in its polymerization can be reduced significantly in concentration by treatment with saturated 6 to 7 membered ring heterocyclic amines. These amines react with acrylonitrile by a nitrogen-cyanoethylation reaction which results in the formation of a tertiary amino linkage.Type: GrantFiled: December 30, 1981Date of Patent: August 16, 1983Assignee: The Goodyear Tire & Rubber CompanyInventor: Michael L. Senyek
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Patent number: 4382798Abstract: An anti-soiling treating agent comprising(a) a perfluoroalkyl-containing hybrid urethane compound (I) resulting from the addition reaction of two perfluoroalkyl-containing alcohols which have a difference in melting point of at least 20.degree. C. and are selected from compounds of the following formulaRf--A--B--OHwherein Rf represents a linear or branched perfluoroalkyl group, A is the group --CH.sub.2 --.sub.Type: GrantFiled: August 10, 1981Date of Patent: May 10, 1983Assignee: Dainippon Inc. & Chemicals Inc.Inventors: Yasuyuki Suzuki, Tadashi Ito
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Patent number: 4370430Abstract: Oligomers of the formula ##STR1## which contain at least one piperidyl radical per repeating unit are useful as light stabilizers for polymers.Type: GrantFiled: August 31, 1981Date of Patent: January 25, 1983Assignee: American Cyanamid CompanyInventor: Joseph A. Hoffman
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Patent number: 4367304Abstract: Compounds of the formula I, II, III or IV ##STR1## wherein X is halogen, OH, --OR.sup.1, --OOCR.sup.2, --OOC--R.sup.4 --COOR.sup.3 or --N(R.sup.5)(R.sup.6), or the two X groups together form a group --O--R.sup.9 --O-- or --OOC--R.sup.9 --COO--, Y has one of the meanings given for X, or it is --NHR.sup.5, --NHNH.sub.2 or --NHNH-phenyl, Z has one of the meanings given for X, or is --SR, and R, R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.9 and R' are organic radicals having the meanings defined hereinbelow, are thermal stabilizers for chlorine-containing thermoplastics particularly for PVC. Their effect can be further intensified by the addition of co-stabilizers.Type: GrantFiled: November 4, 1980Date of Patent: January 4, 1983Assignee: Ciba-Geigy CorporationInventors: Klaus-Peter Michaelis, Wolfgang Wehner, Holger Andreas, Horst Muller
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Patent number: 4325862Abstract: A solid pigment composition comprises an intimate mixture of a pigment and a copolymer of an alkyl or cycloalkyl methacrylate ester and a lesser amount of an aminoalkyl methacrylate ester. The compositions are compatible with a wide range of substrates such as paints, printing inks and bulk polymers.Type: GrantFiled: June 2, 1980Date of Patent: April 20, 1982Assignee: Sandoz Ltd.Inventor: Johann Schuster
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Patent number: 4325859Abstract: A stable organic polymer-polyol-alkali metal silicate emulsion is produced by mixing an aqueous solution of an alkali metal silicate or alkali metal metasilicate pentahydrate, a liquid polyol, an organic polymer in a fluid state, and a small amount of an acid while heating the mixture to 40.degree. C. to 100.degree. C. and agitating until the mixture emulsifies. The emulsion may be used to produce organic polymer-polyurethane silicate foams and resinous product.Type: GrantFiled: July 20, 1981Date of Patent: April 20, 1982Inventor: David H. Blount
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Patent number: 4324717Abstract: Mannich bases of hindered aromatic alcohols are incorporated in polymeric norbornene materials to improve their resistance to oxidation.Type: GrantFiled: June 23, 1980Date of Patent: April 13, 1982Assignee: The B. F. Goodrich CompanyInventor: Robert W. Layer