Solid Polymer Derived From Reactant Containing At Least Two Ethylenic Groups And Is Devoid Of Aryl Ring Patents (Class 525/232)
  • Publication number: 20130211010
    Abstract: Provided is a copolymer of a conjugated diene compound and a non-conjugated olefin, the copolymer being a block copolymer, the conjugated diene compound unit having 1,2 adduct (including 3,4 adduct) content of 5% or less or the conjugated diene compound unit having a cis-1,4 bond content of more than 92%, in which preferred examples of the conjugated diene compound include 1,3-butadiene and isopropylene, and preferred examples of the non-conjugated olefin include ethylene, propylene, and 1-butene.
    Type: Application
    Filed: July 26, 2011
    Publication date: August 15, 2013
    Applicant: BRIDGESTONE CORPORATION
    Inventors: Yasuo Horikawa, Shojiro Kaita, Olivier Tardif, Junko Matsushita
  • Publication number: 20130211008
    Abstract: The present invention relates to polyethylene compositions comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, in particular, this invention further relates to polyethylene blends comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, wherein the modifier has: 1) a g? value less than 0.75; 2) a Cayley tree topology with a layer number of 2 or more more; and 3) a average Mw between the branch points of 1,500 g/mol or more.
    Type: Application
    Filed: August 13, 2012
    Publication date: August 15, 2013
    Inventors: Pradeep P. SHIRODKAR, Jianya J. Cheng, Andy H. Tsou, Pamela J. Wright, Johannes M. Soulages
  • Publication number: 20130209774
    Abstract: The present invention relates to a cast film comprising a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g?vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g?vis of 0.90 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 3.0 or more; d) an Mz/Mn of 7.0 or more; e) a shear thinning ratio of 40 or more; and f) an I21 of 20 dg/min or less; where the film has at least a 10% reduction in neck-in as compared to the same composition formed into a film under the same conditions, except that the branched modifier is absent.
    Type: Application
    Filed: March 27, 2013
    Publication date: August 15, 2013
    Inventor: ExxonMobil Chemical Patents Inc.
  • Publication number: 20130202830
    Abstract: The invention provides a first composition comprising at least the following: i) a modified polymer comprising at least one branched modified polymer macromolecule (b1) and at least one linear modified polymer macromolecule (a1), and wherein the at least one branched modified polymer macromolecule and the at least one linear modified polymer macromolecule each, independently, comprises at least one amine group selected from the group consisting of formulas (1A-1F), each as described above: and combinations thereof; and wherein the at least one branched modified polymer macromolecule further comprises one of the structures (ib1-ib4) as described above, and the at least one linear modified polymer macromolecule further comprises one of the structures (iib1) as described above (see Formula 3A)
    Type: Application
    Filed: December 20, 2010
    Publication date: August 8, 2013
    Inventors: Sven Thiele, Sascha Rulhoff, Susanne Knoll
  • Patent number: 8487033
    Abstract: Provided are thermoplastic elastomer compositions composed of a thermoplastic component, an elastomeric component, and at least one particulate composition. Particulate compositions are composed of a particulate material and a carrier medium. Exemplary particulate materials include minerals, mineral compounds, including mineral oxides, clays, carbon, nanotubes, and combinations thereof. Typical carrier mediums are one or more polar polymers, apolar polymers, one or more oils, poly ?-olefins, or combinations thereof. The at least one particulate composition is dispersed within the thermoplastic component and/or the elastomeric component. Particulate compositions include clay grease compositions wherein a clay, e.g., an exfoliated clay, is utilized as a thickener.
    Type: Grant
    Filed: May 16, 2007
    Date of Patent: July 16, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventor: Danny Van Hoyweghen
  • Patent number: 8481646
    Abstract: This invention relates to the preparation of thermoplastic vulcanizates (TPVs) with unique morphological features, more specifically, this invention relates to a method for preparing TPV compositions wherein the mixing of plastomers and elastomers are carried out in solvent with curatives to induce cross-linking.
    Type: Grant
    Filed: February 23, 2011
    Date of Patent: July 9, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Weiqing Weng, Sunny Jacob, Peijun Jiang, Armenag H. Dekmezian, Aspy K. Mehta, James R. Ayers, David J. Lohse, Peter W. Manders, Palanisamy Arjunan
  • Patent number: 8476366
    Abstract: Embodiments of the invention provide block composites and their use in thermoplastic vulcanizate compounds.
    Type: Grant
    Filed: October 1, 2010
    Date of Patent: July 2, 2013
    Assignee: Dow Global Technologies, LLC
    Inventors: Kim L. Walton, Brian W. Walther, Robert T. Johnston, Jose M. Rego, Xiaosong Wu
  • Publication number: 20130150518
    Abstract: A floor covering including one of a sheet-shaped or plate-shaped matrix made of an elastomeric material. The matrix is provided with particles made of a thermoplastic material, where the elastomeric material of the matrix and the thermoplastic material of the particles each have at least one matching monomer.
    Type: Application
    Filed: August 5, 2011
    Publication date: June 13, 2013
    Applicant: NORA SYSTEMS GMBH
    Inventors: Gregor Grun, Mario Kroger, Dieter Rischer
  • Patent number: 8461269
    Abstract: Rubber composition based on at least one diene elastomer, a polymer filler as reinforcing filler, a coupling agent providing the bond between the polymer filler and the elastomer. The polymer filler comprises nanoparticles of non-aromatic vinnyl polymer (“NAVP”) bearing a function Z of formula ?Si—X, X representing a hydroxyl or hydrolysable group. The NAVP is in particular a copolymer of methyl methacrylate, trimethoxysilylpropyl methacrylate and ethylene glycol dimethacrylate, in the form of nanobeads the diameter of which is between 10 and 100 nm.
    Type: Grant
    Filed: June 29, 2007
    Date of Patent: June 11, 2013
    Assignee: Micheln Recherche et Technique S.A.
    Inventors: Franck Varagniat, Sylvie Gandon-Pain, Arnaud Lapra
  • Patent number: 8455072
    Abstract: A polyolefin composition, and pipe systems and sheets made therefrom, the composition comprising (percent by weight), 1) 10-60% of a copolymer of propylene and hexene-1 comprising from 0.2 to 10% of recurring units derived from hexene-1; 2) 10-85% of a propylene polymer selected from propylene homopolymer and a polymer of propylene with 0.1-10% of an ?-olefin selected from ethylene, a C4-C10 a-olefin, hexene-1 excluded, and a mixture thereof, the propylene polymer being insoluble in xylene at ambient temperature in an amount over 85% and having a Polydispersity Index ranging from 4.5 to 12; and 3) 5-30% of a copolymer of ethylene with a C3-C10 ?-olefin and optionally a diene, having an ethylene content ranging from 15 to 60% and an intrinsic viscosity value of at least 1 dl/g.
    Type: Grant
    Filed: December 11, 2007
    Date of Patent: June 4, 2013
    Assignee: Basell Poliolefine Italia S.r.l.
    Inventors: Roberto De Palo, Roberta Marzolla
  • Patent number: 8450421
    Abstract: Cable layer comprising a propylene polymer composition comprising (a) a polypropylene (A) (b) an elastomeric copolymer (E) comprising units derived from propylene and ethylene and/or C4 to C20 ?-olefin and (c) a polar ethylene polymer (C) wherein the cable layer and/or the propylene polymer composition has a gel content of equal or more than 0.20 wt.-%.
    Type: Grant
    Filed: December 17, 2009
    Date of Patent: May 28, 2013
    Assignee: Borealis AG
    Inventors: Tung Pham, Doris Machl, Sybille Simon, Katja Klimke, Christer Svanberg, Thomas Steffl, David Friel
  • Publication number: 20130131273
    Abstract: Disclosed are copolymers which comprise: a) an isobutylene copolymer having grafted polymer groups, b) optionally a tackifier, and c) optionally a non-functionalized poly(isobutylene) polymer. The compositions are useful in adhesives and coatings.
    Type: Application
    Filed: January 21, 2013
    Publication date: May 23, 2013
    Applicant: 3M Innovative Properties Company
    Inventor: 3M Innovative Properties Company
  • Patent number: 8445580
    Abstract: Pneumatic rubber tire intended for heavy duty service having a cap/base configured tread with a silica-containing specialized cis 1,4-polybutadiene rubber-rich tread cap rubber layer.
    Type: Grant
    Filed: September 22, 2011
    Date of Patent: May 21, 2013
    Assignee: The Goodyear Tire & Rubber Company
    Inventor: Junling Zhao
  • Patent number: 8436100
    Abstract: A homogeneous polymer blend comprises a thermoplastic first polymer having a crystallinity of at least 30%; and a second polymer having a crystallinity of more than 5% and being at least partially cross-linked.
    Type: Grant
    Filed: February 25, 2011
    Date of Patent: May 7, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Peijun Jiang, Sunny Jacob, Aspy K. Mehta, Pradeep P. Shirodkar, Armenag H. Dekmezian, Palanisamy Arjunan
  • Patent number: 8436098
    Abstract: The invention relates to the use of polyorganosiloxanes having 3 or more siloxane units, which has (i) at least one organic component R1, where R1 has at least one carbon-carbon multiple bond, and (ii) at least one hydrocarbon component R2, where R2 has a chain length of 5 to 50 carbon atoms. The polyorganosiloxanes are used in the processing and vulcanization of rubber and are incorporated reactively into it. They give rise to a lowering in the viscosity of the rubber in the course of processing and in some cases to an improvement in the mechanical properties of the vulcanized rubber.
    Type: Grant
    Filed: July 30, 2009
    Date of Patent: May 7, 2013
    Assignee: Schill + Seilacher “Struktol” GmbH
    Inventors: Uwe Dittrich, Volker Borger, Gisela Thummler, Theresia Klose
  • Publication number: 20130101927
    Abstract: A pellicle which has a mask adhesive layer that can be plastic-deformed readily particularly at a temperature at which exposure to light is carried out, rarely provides a residue of an adhesive agent upon the removal of the mask adhesive layer from a mask and has good handling properties, and which can prevent the position gap of a pattern. The pellicle comprises a pellicle frame, a pellicle membrane and a mask adhesive layer containing a mask adhesive agent. The mask adhesive agent comprises 100 parts by mass of a thermoplastic elastomer (A) having a tan ? peak temperature of ?20 to 30 DEG C and 20 to 150 parts by mass of an adhesiveness-imparting resin (B).
    Type: Application
    Filed: June 29, 2011
    Publication date: April 25, 2013
    Applicant: MITSUI CHEMICALS, INC.
    Inventors: Daiki Taneichi, Takashi Kozeki, Akihiro Koide
  • Patent number: 8426522
    Abstract: The copolymer rubber composition comprises 60 to 75% by weight of a copolymer rubber (1) and 40 to 25% by weight of a copolymer rubber (2), and [iodine value of the copolymer rubber (1)?iodine value of the copolymer rubber (2)] is 5 to 30. The copolymer rubber (1) is an ethylene-?-olefin-nonconjugated polyene copolymer rubber having an ethylene unit of 50 mol % to 70 mol %, an ?-olefin unit of 50 mol % to 30 mol %, and an iodine value of 15 to 45, and the copolymer rubber (2) is an ethylene-?-olefinic copolymer rubber having an ethylene unit of more than 70 mol % and 95 mol % or less, an ?-olefin unit of less than 30 mol % and 5 mol % or more, and an iodine value of 10 to 30.
    Type: Grant
    Filed: November 10, 2011
    Date of Patent: April 23, 2013
    Assignee: Sumitomo Chemical Company, Limited
    Inventor: Sadayuki Nakano
  • Patent number: 8426524
    Abstract: A reduced cost elastomeric blend suitable for use in vehicle timing belts and other applications constructed with elastomeric portions having a high HNBR concentration. The blends comprise from about 50 to less than 100 phr of HNBR and from about 0.1 to about 50 phr of lower cost diluent unsaturated nitrile rubber with from about 0.1 to about 30 phr of a heat resistant additive, which may be THERBAN HT. The elastomeric blends may be cured with a peroxide/co-agent cure system. The elastomeric blends may be mixed by a Y-mix method to improve ozone resistance. A timing belt constructed of the elastomeric blend is also taught.
    Type: Grant
    Filed: December 6, 2006
    Date of Patent: April 23, 2013
    Assignee: Veyance Technologies, Inc
    Inventors: Mauro Piccirilli, Thomas George Burrowes
  • Patent number: 8420738
    Abstract: A thermoplastic elastomer composition which has excellent cleanability and is suitable for use as a medical rubber supply. It is characterized by comprising a rubber ingredient dynamically crosslinked with a crosslinking agent and a matrix which comprises a thermoplastic resin and in which the crosslinked rubber ingredient has been dispersed, the crosslinking agent comprising a triazine derivative.
    Type: Grant
    Filed: October 2, 2008
    Date of Patent: April 16, 2013
    Assignee: Sumitomo Rubber Industries, Ltd.
    Inventors: Hiroaki Nakano, Hideyuki Okuyama
  • Publication number: 20130090433
    Abstract: The present invention relates to a branched modifier and a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g?vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a g?vis of less than 0.97, wherein the ethylene polymer has a g?vis of at least 0.01 units higher than the g?vis of the branched modifier.
    Type: Application
    Filed: September 20, 2012
    Publication date: April 11, 2013
    Applicant: ExxonMobile Chemical Patents Inc.
    Inventor: ExxonMobile Chemical Patents Inc.
  • Patent number: 8415432
    Abstract: The present invention is directed to a vulcanizable rubber composition comprising: a diene based elastomer; and a compound of formula I where Q is an n-valent organic group of 1 or more carbon atoms and optionally one or more of nitrogen, oxygen, sulfur, halogen, silicon, and phosphorus atoms; X is a divalent polymer group capable of exhibiting a lower critical solution temperature; R is independently a hydrogen atom or a monovalent group of formula (II) where Z is a monovalent organic group of 1 or more carbon atoms and optionally one or more of nitrogen, oxygen, sulfur, halogen, silicon, and phosphorus atoms; and n is an integer greater than or equal to 2. The invention is further directed to a rubber composition comprising the reaction product of a diene based elastomer and a compound of formula I, and a pneumatic tire with a tread comprising the rubber composition.
    Type: Grant
    Filed: December 21, 2011
    Date of Patent: April 9, 2013
    Assignee: The Goodyear Tire & Rubber Company
    Inventors: Ralf Mruk, Frank Schmitz, Robert Fokko Roskamp, Alexandra Hermann, Rudolf Wilhelm Zentel
  • Patent number: 8404773
    Abstract: The instant invention is a coating composition, method of producing the same, articles made therefrom, and method of making such articles. The coating composition according to the instant invention comprises (a) 10 to 55 percent by weight of an ethylene based copolymer composition; (b) 5 to 25 percent by weight of a propylene polymer composition; (c) 15 to 60 percent by weight of a chlorinated olefin polymer composition; (d) optionally less than 40 percent by weight of a filler; and (e) optionally 1 to 20 weight percent by weight of an adhesion promoting agent.
    Type: Grant
    Filed: March 17, 2008
    Date of Patent: March 26, 2013
    Assignee: Dow Global Technologies LLC
    Inventor: Daniel G. Moldovan
  • Publication number: 20130072633
    Abstract: A flexible tubing material includes a radiation crosslinked blend of a first elastomeric polymer including a styrenic thermoplastic elastomer, an ethylene vinyl acetate elastomer, a polylefin elastomer with a second elastomeric polymer including a polyolefin elastomer, a diene elastomer, or combination thereof, with the proviso that the first elastomeric polymer and the second elastomeric polymer are different. In an embodiment, a method of making a material includes providing the first elastomeric polymer, providing the second elastomeric polymer, blending the first elastomeric polymer and the second elastomeric polymer, extruding or injection molding the blend, and crosslinking the blend with radiation.
    Type: Application
    Filed: October 4, 2012
    Publication date: March 21, 2013
    Inventors: Yoshitaka Kawamoto, Sridhar Krishnamurthi Siddhamalli
  • Patent number: 8389632
    Abstract: A process of extruding a blend of an irradiated extrudate of a first propylene polymer and a non-irradiated second propylene polymer, where the first propylene polymer comprises a non-phenolic stabilizer. The irradiation of the first propylene polymer extrudate is conducted in a reduced oxygen environment, and the irradiated extrudate of the first propylene polymer and the non-irradiated second propylene polymer are blended at a temperature below their respective melting points. The blend has an ARPSW of ?3.0 micron.
    Type: Grant
    Filed: February 9, 2011
    Date of Patent: March 5, 2013
    Assignee: Equistar Chemicals, LP
    Inventors: Chun Lee, Charles S. Holland, James R. Beren, Anthony J. De Nicola, Jr.
  • Patent number: 8383729
    Abstract: Including crosslinked rubber particles in an oriented polymer composition induces cavitation in the oriented polymer composition and can increases the scratch and mar resistance as well as fibrillation resistance.
    Type: Grant
    Filed: March 1, 2012
    Date of Patent: February 26, 2013
    Assignee: Eovations, LLC
    Inventors: Kevin L. Nichols, Brett M. Birchmeier, Kim L. Walton
  • Publication number: 20130035436
    Abstract: A composition for use in grips is disclosed. The composition may be used, for example, in making a golf club grip. The disclosed grip provides for improved shock absorption and other beneficial properties. In one embodiment the comprises a cross-linked composition of from about 40% by weight to about 80% by weight of one or a combination of a first material selected from the group consisting of butyl rubber, nitrile rubber, ethylene propylene rubber and chloroprene rubber, and from about 10% by weight to about 50% by weight of one or a combination of a second material selected from the group consisting of ethylene-propylene-diene copolymer (EPDM), polyurethane, ethylene-vinyl acetate copolymer, polypropylene and cork.
    Type: Application
    Filed: August 9, 2012
    Publication date: February 7, 2013
    Applicant: LAMKIN CORPORATION
    Inventors: Robert J. Lamkin, David Claas, Christopher A. Lee, Miguel Angel Bravo, Maria Ramirez, Patricia Marquez, Roberto Rodriguez, Carlos Rodriguez, Moises Lucero, Feliciano Guillen, Iran Saenz, Andrew Kerr, Ernesto Castro
  • Patent number: 8357756
    Abstract: Compositions comprising the reaction product of: (a) a polyalkenamer; and (b) an organic modifier that includes at least one carbon to carbon unsaturated bond and at least one functional group selected from carboxyl, hydroxyl, amino, epoxy, (meth)acrylate, vinyl, ester, isocyanate, carbonyl, urethane, anhydride, or a metal salt thereof. Also disclosed are golf balls that include (i) a core, (ii) at least one intermediate layer, and (iii) at least one cover layer, wherein at least one of the core, intermediate layer or cover layer includes the polylalkenamer/functionalized organic modifier composition as a majority ingredient.
    Type: Grant
    Filed: November 4, 2009
    Date of Patent: January 22, 2013
    Assignee: Taylor Made Golf Company, Inc.
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Publication number: 20130012337
    Abstract: Compositions comprising the reaction product of: (a) a polyalkenamer; and (b) an organic modifier that includes at least one carbon to carbon unsaturated bond and at least one functional group selected from carboxyl, hydroxyl, amino, epoxy, (meth)acrylate, vinyl, ester, isocyanate, carbonyl, urethane, anhydride, or a metal salt thereof. Also disclosed are golf balls that include (i) a core, (ii) at least one intermediate layer, and (iii) at least one cover layer, wherein at least one of the core, intermediate layer or cover layer includes the polyalkenamer/functionalized organic modifier composition as a majority ingredient.
    Type: Application
    Filed: September 14, 2012
    Publication date: January 10, 2013
    Inventors: Hyun J. Kim, Hong G. Jeon
  • Patent number: 8349956
    Abstract: The present invention relates to a tire having a tread comprising a rubber composition that comprises at least: as a first diene elastomer, between 5 and 25 phr of a styrene-nitrile-butadiene terpolymer (SNBR) having a nitrile monomer content between 4 and 18% by weight; a second diene elastomer other than SNBR; a reinforcing filler; a liquid plasticizer, the glass transition temperature of which is below ?20° C. The invention makes it possible to improve the properties of rolling resistance and of grip on wet ground of tire treads.
    Type: Grant
    Filed: June 30, 2009
    Date of Patent: January 8, 2013
    Assignees: Compagnie Generale des Establissements Michelin, Michelin Recherche et Technique S.A.
    Inventors: Garance Lopitaux, Didier Vasseur
  • Patent number: 8349963
    Abstract: An elastic material for use in an absorbent article is provided. The elastic material contains a crosslinked network formed from a linear block copolymer having a monoalkenyl aromatic midblock positioned between conjugated diene endblocks (e.g., butadiene-styrene-butadiene (“B-S-B”) triblock copolymer). Prior to crosslinking, such linear block copolymers have a relatively low viscosity and thus may be readily formed into a precursor elastic material (e.g., film, strands, web, etc.) that is subsequently crosslinked to achieve the desired elastic and mechanical properties. Crosslinking is typically achieved through the formation of free radicals (unpaired electrons) that link together to form a plurality of carbon-carbon covalent bonds at the conjugated diene endblocks.
    Type: Grant
    Filed: October 16, 2007
    Date of Patent: January 8, 2013
    Assignee: Kimberly-Clark Worldwide, Inc.
    Inventors: Oomman P. Thomas, John E. Flood
  • Patent number: 8344070
    Abstract: A polymer composition comprises (a) least 40 wt % (based upon the weight of the composition) of a cyclic olefin polymer comprising at least one acyclic olefin and at least 20 wt % of one or more cyclic olefins (based upon the weight of the cyclic olefin polymer), wherein at least a portion of the cyclic olefin polymer has a glass transition temperature of greater than 100° C.; (b) an acyclic olefin polymer modifier in an amount up to 40 wt % (based upon the weight of the composition); and (c) at least 10 wt % (based upon the weight of the composition) of one of more fillers. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 100 J/m and a flexural modulus (1% secant method) of greater than 1400 MPa.
    Type: Grant
    Filed: June 20, 2007
    Date of Patent: January 1, 2013
    Assignee: ExxonMobil Chemical Patents Inc.
    Inventors: Kevin R. Squire, Alan J. Oshinski, Kevin D. Robinson, Christian Peter Mehnert, Marsha M. Arvedson, Beverly J. Poole, Abhimanyu Onkar Patil, Lisa Saunders Baugh, Karla Schall Colle
  • Publication number: 20120316283
    Abstract: Elastomer compositions comprising uncured elastomer and reclaimed elastomer are described. In one embodiment, the compositions comprise reclaimed elastomer material (micronized rubber powder) of broad particle size distribution, which is less expensive than traditional reclaimed elastomer material with narrow particle size distribution. Further, compositions comprising reclaimed elastomer materials with broad particle size distribution perform comparably to those comprising reclaimed elastomer materials with narrow particle size distribution. In other embodiments, the compositions comprise both vulcanized and devulcanized elastomer materials. Advantageously, by using a combination of vulcanized and devulcanized material, it is possible to incorporate a greater percentage by weight of reclaimed material in to an elastomer composition, thus providing additional cost savings while maintaining high levels of mechanical properties.
    Type: Application
    Filed: June 8, 2012
    Publication date: December 13, 2012
    Inventors: Charles Rosenmayer, Frank Papp
  • Patent number: 8329821
    Abstract: [Problem] To provide a thermoplastic elastomer composition for foaming, which has sufficient foamability and provides a molded article having good appearance. [Solution to Problem] A thermoplastic elastomer composition for foaming, which comprises 10 to 40% by weight of a partially or completely crosslinked ethylene/?-olefin/non-conjugated polyene copolymer rubber (A) comprising ethylene, an ?-olefin of 3 to 20 carbon atoms and a non-conjugated polyene, 3 to 33% by weight of an ethylene/?-olefin copolymer (B) comprising ethylene and an ?-olefin of 3 to 20 carbon atoms, 10 to 40% by weight of polypropylene (C) having a melting point, as determined by differential scanning calorimetry (DSC), of 40 to 170° C.
    Type: Grant
    Filed: July 14, 2009
    Date of Patent: December 11, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Hayato Kurita, Toru Takehara, Masakazu Jitsukata, Yuichi Ito
  • Patent number: 8329824
    Abstract: The present invention provides a propylene polymer composition having excellent transparency, flexibility, heat resistance, scratch resistance and rubber elasticity with a good balance. The propylene polymer composition comprises 1 to 40 parts by weight of isotactic polypropylene (i) and 60 to 99 parts by weight of a propylene/ethylene/?-olefin copolymer (ii) which contains 45 to 89% by mol of a propylene component, 10 to 25% by mol of an ethylene component, and optionally, 0 to 30% by mol of constituent units (a) derived from an ?-olefin of 4 to 20 carbon atoms.
    Type: Grant
    Filed: May 12, 2004
    Date of Patent: December 11, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Ryoji Mori, Takashi Nakagawa, Akira Todo
  • Patent number: 8329848
    Abstract: An object of the present invention is to provide a novel ethylene-?-olefin copolymer excellent in crosslinking properties; a foamed molded article having a low specific gravity and a low compression set (CS) and a composition capable of producing the foamed molded article, footwear parts composed of a foamed molded article; an ethylenic copolymer composition excellent in balance between weather resistance and mechanical strength, and an electric wire coating material and an electric wire sheath using the ethylenic copolymer composition; and a thermoplastic elastomer capable of producing a molded article excellent in balance between mechanical strength and toughness. The ethylenic copolymer (A) of the present invention is a copolymer composed of only ethylene and an ?-olefin having 3 to 20 carbon atoms, and is characterized in that vinyl-group content (a) per 1000 carbon atoms as measured by infrared absorption spectroscopy, MFR10/MFR2.16 (b), and the specific gravity (c) are within a specific range.
    Type: Grant
    Filed: June 2, 2008
    Date of Patent: December 11, 2012
    Assignee: Mitsui Chemicals, Inc.
    Inventors: Takayuki Kajihara, Hiroshi Uehara, Shigenobu Ikenaga, Kiminori Noda, Masayoshi Yamaguchi
  • Publication number: 20120309902
    Abstract: Disclosed are a polybutadiene having a controlled microstructure, a narrow molecular weight distribution, minimal gel content, and a low APHA color, a modified polybutadiene, producing methods for both, and a rubber-reinforced styrene resin composition using the same. The polybutadiene of the present invention is characterised in that the ratio (Tcp/ML1+4) of a 5% toluene melting viscosity (Tcp) measured at 25° C. and the Mooney viscosity (ML1+4) at 100° C. is 2.0 or higher, the molecular weight distribution (Mw/Mn) is 2.80 or less, the gel content is 0.06 wt % or less, and the APHA color is 20 or less.
    Type: Application
    Filed: February 21, 2011
    Publication date: December 6, 2012
    Applicant: UBE INDUSTRIES, LTD.
    Inventors: Yasuyoshi Okabe, Yuuji Matsudaira, Chaiyaket Vichuta, Toshiyuki Sakaguchi
  • Patent number: 8318861
    Abstract: This invention relates to a rubber composition capable of using in a tread rubber of a tire to improve both an initial gripping performance and a running stability of the tire as compared with those of conventional tires, and more particularly to a rubber composition formed by compounding an indene-containing C9-based resin having a softening point of 130° C.-190° C. and an indene content of 30-80 mass % into a rubber component.
    Type: Grant
    Filed: January 11, 2008
    Date of Patent: November 27, 2012
    Assignee: Bridgestone Corporation
    Inventors: Masahiro Houjo, Masayuki Hashimoto, Shigeki Kamo, Seiichi Kato, Masaki Toyoda
  • Publication number: 20120289656
    Abstract: A high impact polystyrene (HIPS) is made from styrene monomer and 3 to 20 wt % of an elastomeric component phase including polybutadiene rubber and styrene butadiene copolymer. The HIPS has a 60 degree gloss of 90 or more, a Gardner drop of at least 10 in-lb, and an Izod impact strength of 1.8 ft-lb/in or more. The HIPS can have salami morphology with rubber particle size between 1 and 1.3 microns.
    Type: Application
    Filed: April 13, 2012
    Publication date: November 15, 2012
    Applicant: FINA TECHNOLOGY, INC.
    Inventors: David W. Knoeppel, Likuo Sun, Jon Tippet
  • Patent number: 8309657
    Abstract: An object of the present invention is to provide a rubber composition which not only realizes sufficiently low heat generation properties but also exhibits more excellent crack growth resistance than the conventional rubber composition. The rubber composition contains in 100 mass % of rubber components thereof: 20-80 mass % of natural rubber in which the total nitrogen content in natural rubber latex is in the range of 0.1 mass % to 0.4 mass % (exclusive of 0.1 mass % and inclusive of 0.4 mass %); and butadiene-based polymer having cis content of 90% or higher.
    Type: Grant
    Filed: October 7, 2009
    Date of Patent: November 13, 2012
    Assignee: Bridgestone Corporation
    Inventors: Junko Matsushita, Yoichi Ozawa
  • Patent number: 8304496
    Abstract: The invention is directed to compositions comprising an elastomer component and a propylene component, and in which the elastomer component comprises at least one ethylene/?-olefin polymer, optionally containing a diene, and the polypropylene component comprises at least one branched polypropylene. Preferably, the elastomer component has a melt tan delta between about 0.7 and about 8, as measured by parallel plate rheometer at 0.1 rad/sec, 190° C., and 15 percent strain; and the ratio of the “melt tan delta of the elastomer component” to the “melt tan delta of the propylene component” is from 0.5 to 4. The invention also provides for method of making such compositions, and to low gloss articles prepared from the same. The inventive compositions are particularly suitable for fabricating thermoformed sheeting with reduced gloss.
    Type: Grant
    Filed: May 8, 2006
    Date of Patent: November 6, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Laura B. Weaver, Douglas P. Waszeciak, Kim L. Walton
  • Patent number: 8304462
    Abstract: The present invention provides methods of making composite materials comprising combining particles of crosslinked rubber with one or more aqueous polymer dispersion of a suspension polymer to form a mixture in aqueous dispersion, and, optionally, subjecting the aqueous dispersion mixture to solid state shear pulverization to form materials that can be processed as thermoplastics at crosslinked rubber concentrations of from 10 to as high as 95 wt. %, based on the total solids of the material. The method may further comprise kneading and/or compression molding the pulverized product to form useful articles, such as roofing membranes and shoe soles.
    Type: Grant
    Filed: December 28, 2009
    Date of Patent: November 6, 2012
    Assignee: Rohm and Haas Company
    Inventors: Willie Lau, Rachel Z. Pytel, Joseph M. Rokowski
  • Patent number: 8304460
    Abstract: The present invention provides methods of making shapeable composites in the form of finely divided materials or articles and the materials and articles produced by the methods, the methods comprising forming mixtures by (i) treating an aqueous thermoplastic acrylic or vinyl polymer to increase the particle size thereof to a weight average particle size of 1 ?m or more, and, optionally, dewatering to form a crumb mixture; and (ii) combining a thermoplastic acrylic or vinyl polymer with one or more waste rubber vulcanizate having a sieve particle size ranging from 10 to 600 ?m in the amount of from 15 to 95 wt. %, based on the total weight of polymer and rubber to form a crumb slurry, such that (ii) can take place before, during, after (i) but before any dewatering, or after any dewatering; and (iii) thermoplastic processing the mixture. Thermoplastic processing can directly form articles, like sheets or films. The shapeable composites have excellent adhesion to other materials.
    Type: Grant
    Filed: June 17, 2009
    Date of Patent: November 6, 2012
    Assignee: Rohm and Haas Company
    Inventors: Willie Lau, Donald C. Schall, Harry R. Heulings, IV, Kimberly B. Kosto, Joseph M. Rokowski
  • Patent number: 8304461
    Abstract: The present invention provides methods of making composite materials comprising combining particles of crosslinked rubber with coagulated aqueous polymer dispersions to form a mixture in aqueous dispersion, and subjecting the aqueous dispersion mixture to solid state shear pulverization to form materials that can be processed as thermoplastics at crosslinked rubber concentrations of from 10 to as high as 95 wt. %, based on the total solids of the material. The method may further comprise kneading the pulverized product to form useful articles, such as roofing membranes and shoe soles.
    Type: Grant
    Filed: July 10, 2009
    Date of Patent: November 6, 2012
    Assignee: Rohm and Haas Company
    Inventors: Carlos A. Cruz, Willie Lau, Joseph M. Rokowski, Qi Wang
  • Patent number: 8299191
    Abstract: Disclosed herein are tunable shape memory polymers (SMP's) and methods for manufacturing the disclosed SMP's.
    Type: Grant
    Filed: October 18, 2010
    Date of Patent: October 30, 2012
    Assignee: Georgia Tech Research Corp.
    Inventors: Walter E. Voit, Taylor Ware, Kenneth Gall
  • Patent number: 8293843
    Abstract: Disclosed are processes for producing polypropylene resin compositions including two or three sorts of propylene-based polymeric materials, the processes including a first step of melt-kneading at least a propylene-?-olefin block copolymer containing a polymer portion composed mainly of propylene and a propylene-?-olefin copolymer portion having a relatively high intrinsic viscosity and a second step of melt-kneading the product of the first step with a propylene-ethylene block copolymer containing a polymer portion composed mainly of propylene and a propylene-ethylene copolymer portion having a relatively low intrinsic viscosity or a polymer portion composed mainly of propylene having a relatively low intrinsic viscosity. In the composition produced by these processes, no or substantially no fish eyes develop.
    Type: Grant
    Filed: April 7, 2005
    Date of Patent: October 23, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoru Moritomi, Takashi Sanada, Mitsuyoshi Shimano
  • Publication number: 20120255661
    Abstract: A process for preparing a copolymer of an acyclic conjugated diene and a cyclic conjugated diene using a polymerization catalyst system comprising a transition metal compound or a lanthanide metal compound, an alkylating agent, and an inorganic halide alcoholate, and rubber compositions and tires comprising the same. The copolymer contains at least 90% acyclic conjugated diene monomer, has a number average molecular weight of between 40,000 and 300,000, and has a cis-bond content of at least 92%.
    Type: Application
    Filed: October 13, 2010
    Publication date: October 11, 2012
    Inventors: Zengquan Qin, Eiju Suzuki
  • Publication number: 20120248002
    Abstract: A polymer composition of polypropylene copolymer and 1 to 50% by weight of hard resin. The polypropylene copolymer is either an impact copolymer or a random copolymer. The polymer composition can be used to make injection stretch blow molded articles having improved top load strength.
    Type: Application
    Filed: March 30, 2011
    Publication date: October 4, 2012
    Applicant: Fina Technology, Inc.
    Inventors: Luyi Sun, Tim Coffy, Leland Daniels
  • Patent number: 8278392
    Abstract: Disclosed are processes for producing polypropylene resin compositions including two or three sorts of propylene-based polymeric materials, the processes including a first step of melt-kneading at least a propylene-?-olefin block copolymer containing a polymer portion composed mainly of propylene and a propylene-?-olefin copolymer portion having a relatively high intrinsic viscosity and a second step of melt-kneading the product of the first step with a propylene-ethylene block copolymer containing a polymer portion composed mainly of propylene and a propylene-ethylene copolymer portion having a relatively low intrinsic viscosity or a polymer portion composed mainly of propylene having a relatively low intrinsic viscosity. In the composition produced by these processes, no or substantially no fish eyes develop.
    Type: Grant
    Filed: February 17, 2010
    Date of Patent: October 2, 2012
    Assignee: Sumitomo Chemical Company, Limited
    Inventors: Satoru Moritomi, Takashi Sanada, Mitsuyoshi Shimano
  • Publication number: 20120244304
    Abstract: Farnesene interpolymer comprises units derived from a farnesene (e.g., ?-farnesene or ?-farnesene) and units derived from at least one vinyl monomer. The farnesene interpolymer can be prepared by copolymerizing the farnesene and at least one vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. In other embodiments, the at least one vinyl monomer is ethylene, an ?-olefin, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.
    Type: Application
    Filed: May 25, 2012
    Publication date: September 27, 2012
    Applicant: Amyris, Inc.
    Inventor: Derek James MCPHEE
  • Patent number: 8268927
    Abstract: A water redispersible polymer powder is produced by drying an aqueous mixture of a high Tg carboxylated styrene butadiene polymer and a low Tg carboxylated styrene butadiene polymer, where the ratio of the mean or average particle size of the high Tg polymer to the particle size of the low Tg polymer is from 1:1 to 5:1, preferably from 1:1 to 3:1, and the amount of the high Tg polymer is from 20 wt. % to 35 wt. %, preferably from 25 wt. % to 30 wt. %, based upon the total weight of the high Tg polymer and the low Tg polymer. Cement compositions such as mortars, which contain the redispersible polymer powder exhibit unexpectedly superior high bond strength and high impact resistance.
    Type: Grant
    Filed: June 23, 2011
    Date of Patent: September 18, 2012
    Assignee: Dow Global Technologies LLC
    Inventors: Robert Baumann, Juergen Dombrowski, Hartmut Kuehn, Etienne Lazarus, Gerold A Lohmuller, Margarita Perello, Yafei Zhu