Solid Polymer Derived From Reactant Containing At Least Two Ethylenic Groups And Is Devoid Of Aryl Ring Patents (Class 525/232)
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Publication number: 20130211010Abstract: Provided is a copolymer of a conjugated diene compound and a non-conjugated olefin, the copolymer being a block copolymer, the conjugated diene compound unit having 1,2 adduct (including 3,4 adduct) content of 5% or less or the conjugated diene compound unit having a cis-1,4 bond content of more than 92%, in which preferred examples of the conjugated diene compound include 1,3-butadiene and isopropylene, and preferred examples of the non-conjugated olefin include ethylene, propylene, and 1-butene.Type: ApplicationFiled: July 26, 2011Publication date: August 15, 2013Applicant: BRIDGESTONE CORPORATIONInventors: Yasuo Horikawa, Shojiro Kaita, Olivier Tardif, Junko Matsushita
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Publication number: 20130211008Abstract: The present invention relates to polyethylene compositions comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, in particular, this invention further relates to polyethylene blends comprising one or more ethylene polymers and one or more dendritic hydrocarbon polymer modifiers, wherein the modifier has: 1) a g? value less than 0.75; 2) a Cayley tree topology with a layer number of 2 or more more; and 3) a average Mw between the branch points of 1,500 g/mol or more.Type: ApplicationFiled: August 13, 2012Publication date: August 15, 2013Inventors: Pradeep P. SHIRODKAR, Jianya J. Cheng, Andy H. Tsou, Pamela J. Wright, Johannes M. Soulages
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Publication number: 20130209774Abstract: The present invention relates to a cast film comprising a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g?vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a) a g?vis of 0.90 or less; b) an Mw of 100,000 g/mol or more; c) an Mw/Mn of 3.0 or more; d) an Mz/Mn of 7.0 or more; e) a shear thinning ratio of 40 or more; and f) an I21 of 20 dg/min or less; where the film has at least a 10% reduction in neck-in as compared to the same composition formed into a film under the same conditions, except that the branched modifier is absent.Type: ApplicationFiled: March 27, 2013Publication date: August 15, 2013Inventor: ExxonMobil Chemical Patents Inc.
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Publication number: 20130202830Abstract: The invention provides a first composition comprising at least the following: i) a modified polymer comprising at least one branched modified polymer macromolecule (b1) and at least one linear modified polymer macromolecule (a1), and wherein the at least one branched modified polymer macromolecule and the at least one linear modified polymer macromolecule each, independently, comprises at least one amine group selected from the group consisting of formulas (1A-1F), each as described above: and combinations thereof; and wherein the at least one branched modified polymer macromolecule further comprises one of the structures (ib1-ib4) as described above, and the at least one linear modified polymer macromolecule further comprises one of the structures (iib1) as described above (see Formula 3A)Type: ApplicationFiled: December 20, 2010Publication date: August 8, 2013Inventors: Sven Thiele, Sascha Rulhoff, Susanne Knoll
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Patent number: 8487033Abstract: Provided are thermoplastic elastomer compositions composed of a thermoplastic component, an elastomeric component, and at least one particulate composition. Particulate compositions are composed of a particulate material and a carrier medium. Exemplary particulate materials include minerals, mineral compounds, including mineral oxides, clays, carbon, nanotubes, and combinations thereof. Typical carrier mediums are one or more polar polymers, apolar polymers, one or more oils, poly ?-olefins, or combinations thereof. The at least one particulate composition is dispersed within the thermoplastic component and/or the elastomeric component. Particulate compositions include clay grease compositions wherein a clay, e.g., an exfoliated clay, is utilized as a thickener.Type: GrantFiled: May 16, 2007Date of Patent: July 16, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventor: Danny Van Hoyweghen
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Patent number: 8481646Abstract: This invention relates to the preparation of thermoplastic vulcanizates (TPVs) with unique morphological features, more specifically, this invention relates to a method for preparing TPV compositions wherein the mixing of plastomers and elastomers are carried out in solvent with curatives to induce cross-linking.Type: GrantFiled: February 23, 2011Date of Patent: July 9, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Weiqing Weng, Sunny Jacob, Peijun Jiang, Armenag H. Dekmezian, Aspy K. Mehta, James R. Ayers, David J. Lohse, Peter W. Manders, Palanisamy Arjunan
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Patent number: 8476366Abstract: Embodiments of the invention provide block composites and their use in thermoplastic vulcanizate compounds.Type: GrantFiled: October 1, 2010Date of Patent: July 2, 2013Assignee: Dow Global Technologies, LLCInventors: Kim L. Walton, Brian W. Walther, Robert T. Johnston, Jose M. Rego, Xiaosong Wu
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Publication number: 20130150518Abstract: A floor covering including one of a sheet-shaped or plate-shaped matrix made of an elastomeric material. The matrix is provided with particles made of a thermoplastic material, where the elastomeric material of the matrix and the thermoplastic material of the particles each have at least one matching monomer.Type: ApplicationFiled: August 5, 2011Publication date: June 13, 2013Applicant: NORA SYSTEMS GMBHInventors: Gregor Grun, Mario Kroger, Dieter Rischer
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Patent number: 8461269Abstract: Rubber composition based on at least one diene elastomer, a polymer filler as reinforcing filler, a coupling agent providing the bond between the polymer filler and the elastomer. The polymer filler comprises nanoparticles of non-aromatic vinnyl polymer (“NAVP”) bearing a function Z of formula ?Si—X, X representing a hydroxyl or hydrolysable group. The NAVP is in particular a copolymer of methyl methacrylate, trimethoxysilylpropyl methacrylate and ethylene glycol dimethacrylate, in the form of nanobeads the diameter of which is between 10 and 100 nm.Type: GrantFiled: June 29, 2007Date of Patent: June 11, 2013Assignee: Micheln Recherche et Technique S.A.Inventors: Franck Varagniat, Sylvie Gandon-Pain, Arnaud Lapra
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Patent number: 8455072Abstract: A polyolefin composition, and pipe systems and sheets made therefrom, the composition comprising (percent by weight), 1) 10-60% of a copolymer of propylene and hexene-1 comprising from 0.2 to 10% of recurring units derived from hexene-1; 2) 10-85% of a propylene polymer selected from propylene homopolymer and a polymer of propylene with 0.1-10% of an ?-olefin selected from ethylene, a C4-C10 a-olefin, hexene-1 excluded, and a mixture thereof, the propylene polymer being insoluble in xylene at ambient temperature in an amount over 85% and having a Polydispersity Index ranging from 4.5 to 12; and 3) 5-30% of a copolymer of ethylene with a C3-C10 ?-olefin and optionally a diene, having an ethylene content ranging from 15 to 60% and an intrinsic viscosity value of at least 1 dl/g.Type: GrantFiled: December 11, 2007Date of Patent: June 4, 2013Assignee: Basell Poliolefine Italia S.r.l.Inventors: Roberto De Palo, Roberta Marzolla
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Patent number: 8450421Abstract: Cable layer comprising a propylene polymer composition comprising (a) a polypropylene (A) (b) an elastomeric copolymer (E) comprising units derived from propylene and ethylene and/or C4 to C20 ?-olefin and (c) a polar ethylene polymer (C) wherein the cable layer and/or the propylene polymer composition has a gel content of equal or more than 0.20 wt.-%.Type: GrantFiled: December 17, 2009Date of Patent: May 28, 2013Assignee: Borealis AGInventors: Tung Pham, Doris Machl, Sybille Simon, Katja Klimke, Christer Svanberg, Thomas Steffl, David Friel
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Publication number: 20130131273Abstract: Disclosed are copolymers which comprise: a) an isobutylene copolymer having grafted polymer groups, b) optionally a tackifier, and c) optionally a non-functionalized poly(isobutylene) polymer. The compositions are useful in adhesives and coatings.Type: ApplicationFiled: January 21, 2013Publication date: May 23, 2013Applicant: 3M Innovative Properties CompanyInventor: 3M Innovative Properties Company
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Patent number: 8445580Abstract: Pneumatic rubber tire intended for heavy duty service having a cap/base configured tread with a silica-containing specialized cis 1,4-polybutadiene rubber-rich tread cap rubber layer.Type: GrantFiled: September 22, 2011Date of Patent: May 21, 2013Assignee: The Goodyear Tire & Rubber CompanyInventor: Junling Zhao
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Patent number: 8436100Abstract: A homogeneous polymer blend comprises a thermoplastic first polymer having a crystallinity of at least 30%; and a second polymer having a crystallinity of more than 5% and being at least partially cross-linked.Type: GrantFiled: February 25, 2011Date of Patent: May 7, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Peijun Jiang, Sunny Jacob, Aspy K. Mehta, Pradeep P. Shirodkar, Armenag H. Dekmezian, Palanisamy Arjunan
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Patent number: 8436098Abstract: The invention relates to the use of polyorganosiloxanes having 3 or more siloxane units, which has (i) at least one organic component R1, where R1 has at least one carbon-carbon multiple bond, and (ii) at least one hydrocarbon component R2, where R2 has a chain length of 5 to 50 carbon atoms. The polyorganosiloxanes are used in the processing and vulcanization of rubber and are incorporated reactively into it. They give rise to a lowering in the viscosity of the rubber in the course of processing and in some cases to an improvement in the mechanical properties of the vulcanized rubber.Type: GrantFiled: July 30, 2009Date of Patent: May 7, 2013Assignee: Schill + Seilacher “Struktol” GmbHInventors: Uwe Dittrich, Volker Borger, Gisela Thummler, Theresia Klose
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Publication number: 20130101927Abstract: A pellicle which has a mask adhesive layer that can be plastic-deformed readily particularly at a temperature at which exposure to light is carried out, rarely provides a residue of an adhesive agent upon the removal of the mask adhesive layer from a mask and has good handling properties, and which can prevent the position gap of a pattern. The pellicle comprises a pellicle frame, a pellicle membrane and a mask adhesive layer containing a mask adhesive agent. The mask adhesive agent comprises 100 parts by mass of a thermoplastic elastomer (A) having a tan ? peak temperature of ?20 to 30 DEG C and 20 to 150 parts by mass of an adhesiveness-imparting resin (B).Type: ApplicationFiled: June 29, 2011Publication date: April 25, 2013Applicant: MITSUI CHEMICALS, INC.Inventors: Daiki Taneichi, Takashi Kozeki, Akihiro Koide
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Patent number: 8426522Abstract: The copolymer rubber composition comprises 60 to 75% by weight of a copolymer rubber (1) and 40 to 25% by weight of a copolymer rubber (2), and [iodine value of the copolymer rubber (1)?iodine value of the copolymer rubber (2)] is 5 to 30. The copolymer rubber (1) is an ethylene-?-olefin-nonconjugated polyene copolymer rubber having an ethylene unit of 50 mol % to 70 mol %, an ?-olefin unit of 50 mol % to 30 mol %, and an iodine value of 15 to 45, and the copolymer rubber (2) is an ethylene-?-olefinic copolymer rubber having an ethylene unit of more than 70 mol % and 95 mol % or less, an ?-olefin unit of less than 30 mol % and 5 mol % or more, and an iodine value of 10 to 30.Type: GrantFiled: November 10, 2011Date of Patent: April 23, 2013Assignee: Sumitomo Chemical Company, LimitedInventor: Sadayuki Nakano
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Patent number: 8426524Abstract: A reduced cost elastomeric blend suitable for use in vehicle timing belts and other applications constructed with elastomeric portions having a high HNBR concentration. The blends comprise from about 50 to less than 100 phr of HNBR and from about 0.1 to about 50 phr of lower cost diluent unsaturated nitrile rubber with from about 0.1 to about 30 phr of a heat resistant additive, which may be THERBAN HT. The elastomeric blends may be cured with a peroxide/co-agent cure system. The elastomeric blends may be mixed by a Y-mix method to improve ozone resistance. A timing belt constructed of the elastomeric blend is also taught.Type: GrantFiled: December 6, 2006Date of Patent: April 23, 2013Assignee: Veyance Technologies, IncInventors: Mauro Piccirilli, Thomas George Burrowes
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Patent number: 8420738Abstract: A thermoplastic elastomer composition which has excellent cleanability and is suitable for use as a medical rubber supply. It is characterized by comprising a rubber ingredient dynamically crosslinked with a crosslinking agent and a matrix which comprises a thermoplastic resin and in which the crosslinked rubber ingredient has been dispersed, the crosslinking agent comprising a triazine derivative.Type: GrantFiled: October 2, 2008Date of Patent: April 16, 2013Assignee: Sumitomo Rubber Industries, Ltd.Inventors: Hiroaki Nakano, Hideyuki Okuyama
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Publication number: 20130090433Abstract: The present invention relates to a branched modifier and a composition comprising more than 25 wt % (based on the weight of the composition) of one or more linear ethylene polymers having a g?vis of 0.97 or more and an Mw of 20,000 g/mol or more and at least 0.1 wt % of a branched modifier where the modifier has a g?vis of less than 0.97, wherein the ethylene polymer has a g?vis of at least 0.01 units higher than the g?vis of the branched modifier.Type: ApplicationFiled: September 20, 2012Publication date: April 11, 2013Applicant: ExxonMobile Chemical Patents Inc.Inventor: ExxonMobile Chemical Patents Inc.
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Patent number: 8415432Abstract: The present invention is directed to a vulcanizable rubber composition comprising: a diene based elastomer; and a compound of formula I where Q is an n-valent organic group of 1 or more carbon atoms and optionally one or more of nitrogen, oxygen, sulfur, halogen, silicon, and phosphorus atoms; X is a divalent polymer group capable of exhibiting a lower critical solution temperature; R is independently a hydrogen atom or a monovalent group of formula (II) where Z is a monovalent organic group of 1 or more carbon atoms and optionally one or more of nitrogen, oxygen, sulfur, halogen, silicon, and phosphorus atoms; and n is an integer greater than or equal to 2. The invention is further directed to a rubber composition comprising the reaction product of a diene based elastomer and a compound of formula I, and a pneumatic tire with a tread comprising the rubber composition.Type: GrantFiled: December 21, 2011Date of Patent: April 9, 2013Assignee: The Goodyear Tire & Rubber CompanyInventors: Ralf Mruk, Frank Schmitz, Robert Fokko Roskamp, Alexandra Hermann, Rudolf Wilhelm Zentel
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Patent number: 8404773Abstract: The instant invention is a coating composition, method of producing the same, articles made therefrom, and method of making such articles. The coating composition according to the instant invention comprises (a) 10 to 55 percent by weight of an ethylene based copolymer composition; (b) 5 to 25 percent by weight of a propylene polymer composition; (c) 15 to 60 percent by weight of a chlorinated olefin polymer composition; (d) optionally less than 40 percent by weight of a filler; and (e) optionally 1 to 20 weight percent by weight of an adhesion promoting agent.Type: GrantFiled: March 17, 2008Date of Patent: March 26, 2013Assignee: Dow Global Technologies LLCInventor: Daniel G. Moldovan
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Publication number: 20130072633Abstract: A flexible tubing material includes a radiation crosslinked blend of a first elastomeric polymer including a styrenic thermoplastic elastomer, an ethylene vinyl acetate elastomer, a polylefin elastomer with a second elastomeric polymer including a polyolefin elastomer, a diene elastomer, or combination thereof, with the proviso that the first elastomeric polymer and the second elastomeric polymer are different. In an embodiment, a method of making a material includes providing the first elastomeric polymer, providing the second elastomeric polymer, blending the first elastomeric polymer and the second elastomeric polymer, extruding or injection molding the blend, and crosslinking the blend with radiation.Type: ApplicationFiled: October 4, 2012Publication date: March 21, 2013Inventors: Yoshitaka Kawamoto, Sridhar Krishnamurthi Siddhamalli
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Patent number: 8389632Abstract: A process of extruding a blend of an irradiated extrudate of a first propylene polymer and a non-irradiated second propylene polymer, where the first propylene polymer comprises a non-phenolic stabilizer. The irradiation of the first propylene polymer extrudate is conducted in a reduced oxygen environment, and the irradiated extrudate of the first propylene polymer and the non-irradiated second propylene polymer are blended at a temperature below their respective melting points. The blend has an ARPSW of ?3.0 micron.Type: GrantFiled: February 9, 2011Date of Patent: March 5, 2013Assignee: Equistar Chemicals, LPInventors: Chun Lee, Charles S. Holland, James R. Beren, Anthony J. De Nicola, Jr.
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Patent number: 8383729Abstract: Including crosslinked rubber particles in an oriented polymer composition induces cavitation in the oriented polymer composition and can increases the scratch and mar resistance as well as fibrillation resistance.Type: GrantFiled: March 1, 2012Date of Patent: February 26, 2013Assignee: Eovations, LLCInventors: Kevin L. Nichols, Brett M. Birchmeier, Kim L. Walton
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Publication number: 20130035436Abstract: A composition for use in grips is disclosed. The composition may be used, for example, in making a golf club grip. The disclosed grip provides for improved shock absorption and other beneficial properties. In one embodiment the comprises a cross-linked composition of from about 40% by weight to about 80% by weight of one or a combination of a first material selected from the group consisting of butyl rubber, nitrile rubber, ethylene propylene rubber and chloroprene rubber, and from about 10% by weight to about 50% by weight of one or a combination of a second material selected from the group consisting of ethylene-propylene-diene copolymer (EPDM), polyurethane, ethylene-vinyl acetate copolymer, polypropylene and cork.Type: ApplicationFiled: August 9, 2012Publication date: February 7, 2013Applicant: LAMKIN CORPORATIONInventors: Robert J. Lamkin, David Claas, Christopher A. Lee, Miguel Angel Bravo, Maria Ramirez, Patricia Marquez, Roberto Rodriguez, Carlos Rodriguez, Moises Lucero, Feliciano Guillen, Iran Saenz, Andrew Kerr, Ernesto Castro
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Patent number: 8357756Abstract: Compositions comprising the reaction product of: (a) a polyalkenamer; and (b) an organic modifier that includes at least one carbon to carbon unsaturated bond and at least one functional group selected from carboxyl, hydroxyl, amino, epoxy, (meth)acrylate, vinyl, ester, isocyanate, carbonyl, urethane, anhydride, or a metal salt thereof. Also disclosed are golf balls that include (i) a core, (ii) at least one intermediate layer, and (iii) at least one cover layer, wherein at least one of the core, intermediate layer or cover layer includes the polylalkenamer/functionalized organic modifier composition as a majority ingredient.Type: GrantFiled: November 4, 2009Date of Patent: January 22, 2013Assignee: Taylor Made Golf Company, Inc.Inventors: Hyun J. Kim, Hong G. Jeon
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Publication number: 20130012337Abstract: Compositions comprising the reaction product of: (a) a polyalkenamer; and (b) an organic modifier that includes at least one carbon to carbon unsaturated bond and at least one functional group selected from carboxyl, hydroxyl, amino, epoxy, (meth)acrylate, vinyl, ester, isocyanate, carbonyl, urethane, anhydride, or a metal salt thereof. Also disclosed are golf balls that include (i) a core, (ii) at least one intermediate layer, and (iii) at least one cover layer, wherein at least one of the core, intermediate layer or cover layer includes the polyalkenamer/functionalized organic modifier composition as a majority ingredient.Type: ApplicationFiled: September 14, 2012Publication date: January 10, 2013Inventors: Hyun J. Kim, Hong G. Jeon
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Patent number: 8349956Abstract: The present invention relates to a tire having a tread comprising a rubber composition that comprises at least: as a first diene elastomer, between 5 and 25 phr of a styrene-nitrile-butadiene terpolymer (SNBR) having a nitrile monomer content between 4 and 18% by weight; a second diene elastomer other than SNBR; a reinforcing filler; a liquid plasticizer, the glass transition temperature of which is below ?20° C. The invention makes it possible to improve the properties of rolling resistance and of grip on wet ground of tire treads.Type: GrantFiled: June 30, 2009Date of Patent: January 8, 2013Assignees: Compagnie Generale des Establissements Michelin, Michelin Recherche et Technique S.A.Inventors: Garance Lopitaux, Didier Vasseur
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Patent number: 8349963Abstract: An elastic material for use in an absorbent article is provided. The elastic material contains a crosslinked network formed from a linear block copolymer having a monoalkenyl aromatic midblock positioned between conjugated diene endblocks (e.g., butadiene-styrene-butadiene (“B-S-B”) triblock copolymer). Prior to crosslinking, such linear block copolymers have a relatively low viscosity and thus may be readily formed into a precursor elastic material (e.g., film, strands, web, etc.) that is subsequently crosslinked to achieve the desired elastic and mechanical properties. Crosslinking is typically achieved through the formation of free radicals (unpaired electrons) that link together to form a plurality of carbon-carbon covalent bonds at the conjugated diene endblocks.Type: GrantFiled: October 16, 2007Date of Patent: January 8, 2013Assignee: Kimberly-Clark Worldwide, Inc.Inventors: Oomman P. Thomas, John E. Flood
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Patent number: 8344070Abstract: A polymer composition comprises (a) least 40 wt % (based upon the weight of the composition) of a cyclic olefin polymer comprising at least one acyclic olefin and at least 20 wt % of one or more cyclic olefins (based upon the weight of the cyclic olefin polymer), wherein at least a portion of the cyclic olefin polymer has a glass transition temperature of greater than 100° C.; (b) an acyclic olefin polymer modifier in an amount up to 40 wt % (based upon the weight of the composition); and (c) at least 10 wt % (based upon the weight of the composition) of one of more fillers. The polymer composition has a notched Izod impact resistance measured at 23° C. of greater than 100 J/m and a flexural modulus (1% secant method) of greater than 1400 MPa.Type: GrantFiled: June 20, 2007Date of Patent: January 1, 2013Assignee: ExxonMobil Chemical Patents Inc.Inventors: Kevin R. Squire, Alan J. Oshinski, Kevin D. Robinson, Christian Peter Mehnert, Marsha M. Arvedson, Beverly J. Poole, Abhimanyu Onkar Patil, Lisa Saunders Baugh, Karla Schall Colle
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Publication number: 20120316283Abstract: Elastomer compositions comprising uncured elastomer and reclaimed elastomer are described. In one embodiment, the compositions comprise reclaimed elastomer material (micronized rubber powder) of broad particle size distribution, which is less expensive than traditional reclaimed elastomer material with narrow particle size distribution. Further, compositions comprising reclaimed elastomer materials with broad particle size distribution perform comparably to those comprising reclaimed elastomer materials with narrow particle size distribution. In other embodiments, the compositions comprise both vulcanized and devulcanized elastomer materials. Advantageously, by using a combination of vulcanized and devulcanized material, it is possible to incorporate a greater percentage by weight of reclaimed material in to an elastomer composition, thus providing additional cost savings while maintaining high levels of mechanical properties.Type: ApplicationFiled: June 8, 2012Publication date: December 13, 2012Inventors: Charles Rosenmayer, Frank Papp
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Patent number: 8329821Abstract: [Problem] To provide a thermoplastic elastomer composition for foaming, which has sufficient foamability and provides a molded article having good appearance. [Solution to Problem] A thermoplastic elastomer composition for foaming, which comprises 10 to 40% by weight of a partially or completely crosslinked ethylene/?-olefin/non-conjugated polyene copolymer rubber (A) comprising ethylene, an ?-olefin of 3 to 20 carbon atoms and a non-conjugated polyene, 3 to 33% by weight of an ethylene/?-olefin copolymer (B) comprising ethylene and an ?-olefin of 3 to 20 carbon atoms, 10 to 40% by weight of polypropylene (C) having a melting point, as determined by differential scanning calorimetry (DSC), of 40 to 170° C.Type: GrantFiled: July 14, 2009Date of Patent: December 11, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Hayato Kurita, Toru Takehara, Masakazu Jitsukata, Yuichi Ito
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Patent number: 8329824Abstract: The present invention provides a propylene polymer composition having excellent transparency, flexibility, heat resistance, scratch resistance and rubber elasticity with a good balance. The propylene polymer composition comprises 1 to 40 parts by weight of isotactic polypropylene (i) and 60 to 99 parts by weight of a propylene/ethylene/?-olefin copolymer (ii) which contains 45 to 89% by mol of a propylene component, 10 to 25% by mol of an ethylene component, and optionally, 0 to 30% by mol of constituent units (a) derived from an ?-olefin of 4 to 20 carbon atoms.Type: GrantFiled: May 12, 2004Date of Patent: December 11, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Ryoji Mori, Takashi Nakagawa, Akira Todo
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Patent number: 8329848Abstract: An object of the present invention is to provide a novel ethylene-?-olefin copolymer excellent in crosslinking properties; a foamed molded article having a low specific gravity and a low compression set (CS) and a composition capable of producing the foamed molded article, footwear parts composed of a foamed molded article; an ethylenic copolymer composition excellent in balance between weather resistance and mechanical strength, and an electric wire coating material and an electric wire sheath using the ethylenic copolymer composition; and a thermoplastic elastomer capable of producing a molded article excellent in balance between mechanical strength and toughness. The ethylenic copolymer (A) of the present invention is a copolymer composed of only ethylene and an ?-olefin having 3 to 20 carbon atoms, and is characterized in that vinyl-group content (a) per 1000 carbon atoms as measured by infrared absorption spectroscopy, MFR10/MFR2.16 (b), and the specific gravity (c) are within a specific range.Type: GrantFiled: June 2, 2008Date of Patent: December 11, 2012Assignee: Mitsui Chemicals, Inc.Inventors: Takayuki Kajihara, Hiroshi Uehara, Shigenobu Ikenaga, Kiminori Noda, Masayoshi Yamaguchi
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Publication number: 20120309902Abstract: Disclosed are a polybutadiene having a controlled microstructure, a narrow molecular weight distribution, minimal gel content, and a low APHA color, a modified polybutadiene, producing methods for both, and a rubber-reinforced styrene resin composition using the same. The polybutadiene of the present invention is characterised in that the ratio (Tcp/ML1+4) of a 5% toluene melting viscosity (Tcp) measured at 25° C. and the Mooney viscosity (ML1+4) at 100° C. is 2.0 or higher, the molecular weight distribution (Mw/Mn) is 2.80 or less, the gel content is 0.06 wt % or less, and the APHA color is 20 or less.Type: ApplicationFiled: February 21, 2011Publication date: December 6, 2012Applicant: UBE INDUSTRIES, LTD.Inventors: Yasuyoshi Okabe, Yuuji Matsudaira, Chaiyaket Vichuta, Toshiyuki Sakaguchi
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Patent number: 8318861Abstract: This invention relates to a rubber composition capable of using in a tread rubber of a tire to improve both an initial gripping performance and a running stability of the tire as compared with those of conventional tires, and more particularly to a rubber composition formed by compounding an indene-containing C9-based resin having a softening point of 130° C.-190° C. and an indene content of 30-80 mass % into a rubber component.Type: GrantFiled: January 11, 2008Date of Patent: November 27, 2012Assignee: Bridgestone CorporationInventors: Masahiro Houjo, Masayuki Hashimoto, Shigeki Kamo, Seiichi Kato, Masaki Toyoda
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Publication number: 20120289656Abstract: A high impact polystyrene (HIPS) is made from styrene monomer and 3 to 20 wt % of an elastomeric component phase including polybutadiene rubber and styrene butadiene copolymer. The HIPS has a 60 degree gloss of 90 or more, a Gardner drop of at least 10 in-lb, and an Izod impact strength of 1.8 ft-lb/in or more. The HIPS can have salami morphology with rubber particle size between 1 and 1.3 microns.Type: ApplicationFiled: April 13, 2012Publication date: November 15, 2012Applicant: FINA TECHNOLOGY, INC.Inventors: David W. Knoeppel, Likuo Sun, Jon Tippet
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Patent number: 8309657Abstract: An object of the present invention is to provide a rubber composition which not only realizes sufficiently low heat generation properties but also exhibits more excellent crack growth resistance than the conventional rubber composition. The rubber composition contains in 100 mass % of rubber components thereof: 20-80 mass % of natural rubber in which the total nitrogen content in natural rubber latex is in the range of 0.1 mass % to 0.4 mass % (exclusive of 0.1 mass % and inclusive of 0.4 mass %); and butadiene-based polymer having cis content of 90% or higher.Type: GrantFiled: October 7, 2009Date of Patent: November 13, 2012Assignee: Bridgestone CorporationInventors: Junko Matsushita, Yoichi Ozawa
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Patent number: 8304496Abstract: The invention is directed to compositions comprising an elastomer component and a propylene component, and in which the elastomer component comprises at least one ethylene/?-olefin polymer, optionally containing a diene, and the polypropylene component comprises at least one branched polypropylene. Preferably, the elastomer component has a melt tan delta between about 0.7 and about 8, as measured by parallel plate rheometer at 0.1 rad/sec, 190° C., and 15 percent strain; and the ratio of the “melt tan delta of the elastomer component” to the “melt tan delta of the propylene component” is from 0.5 to 4. The invention also provides for method of making such compositions, and to low gloss articles prepared from the same. The inventive compositions are particularly suitable for fabricating thermoformed sheeting with reduced gloss.Type: GrantFiled: May 8, 2006Date of Patent: November 6, 2012Assignee: Dow Global Technologies LLCInventors: Laura B. Weaver, Douglas P. Waszeciak, Kim L. Walton
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Patent number: 8304462Abstract: The present invention provides methods of making composite materials comprising combining particles of crosslinked rubber with one or more aqueous polymer dispersion of a suspension polymer to form a mixture in aqueous dispersion, and, optionally, subjecting the aqueous dispersion mixture to solid state shear pulverization to form materials that can be processed as thermoplastics at crosslinked rubber concentrations of from 10 to as high as 95 wt. %, based on the total solids of the material. The method may further comprise kneading and/or compression molding the pulverized product to form useful articles, such as roofing membranes and shoe soles.Type: GrantFiled: December 28, 2009Date of Patent: November 6, 2012Assignee: Rohm and Haas CompanyInventors: Willie Lau, Rachel Z. Pytel, Joseph M. Rokowski
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Patent number: 8304460Abstract: The present invention provides methods of making shapeable composites in the form of finely divided materials or articles and the materials and articles produced by the methods, the methods comprising forming mixtures by (i) treating an aqueous thermoplastic acrylic or vinyl polymer to increase the particle size thereof to a weight average particle size of 1 ?m or more, and, optionally, dewatering to form a crumb mixture; and (ii) combining a thermoplastic acrylic or vinyl polymer with one or more waste rubber vulcanizate having a sieve particle size ranging from 10 to 600 ?m in the amount of from 15 to 95 wt. %, based on the total weight of polymer and rubber to form a crumb slurry, such that (ii) can take place before, during, after (i) but before any dewatering, or after any dewatering; and (iii) thermoplastic processing the mixture. Thermoplastic processing can directly form articles, like sheets or films. The shapeable composites have excellent adhesion to other materials.Type: GrantFiled: June 17, 2009Date of Patent: November 6, 2012Assignee: Rohm and Haas CompanyInventors: Willie Lau, Donald C. Schall, Harry R. Heulings, IV, Kimberly B. Kosto, Joseph M. Rokowski
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Patent number: 8304461Abstract: The present invention provides methods of making composite materials comprising combining particles of crosslinked rubber with coagulated aqueous polymer dispersions to form a mixture in aqueous dispersion, and subjecting the aqueous dispersion mixture to solid state shear pulverization to form materials that can be processed as thermoplastics at crosslinked rubber concentrations of from 10 to as high as 95 wt. %, based on the total solids of the material. The method may further comprise kneading the pulverized product to form useful articles, such as roofing membranes and shoe soles.Type: GrantFiled: July 10, 2009Date of Patent: November 6, 2012Assignee: Rohm and Haas CompanyInventors: Carlos A. Cruz, Willie Lau, Joseph M. Rokowski, Qi Wang
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Patent number: 8299191Abstract: Disclosed herein are tunable shape memory polymers (SMP's) and methods for manufacturing the disclosed SMP's.Type: GrantFiled: October 18, 2010Date of Patent: October 30, 2012Assignee: Georgia Tech Research Corp.Inventors: Walter E. Voit, Taylor Ware, Kenneth Gall
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Patent number: 8293843Abstract: Disclosed are processes for producing polypropylene resin compositions including two or three sorts of propylene-based polymeric materials, the processes including a first step of melt-kneading at least a propylene-?-olefin block copolymer containing a polymer portion composed mainly of propylene and a propylene-?-olefin copolymer portion having a relatively high intrinsic viscosity and a second step of melt-kneading the product of the first step with a propylene-ethylene block copolymer containing a polymer portion composed mainly of propylene and a propylene-ethylene copolymer portion having a relatively low intrinsic viscosity or a polymer portion composed mainly of propylene having a relatively low intrinsic viscosity. In the composition produced by these processes, no or substantially no fish eyes develop.Type: GrantFiled: April 7, 2005Date of Patent: October 23, 2012Assignee: Sumitomo Chemical Company, LimitedInventors: Satoru Moritomi, Takashi Sanada, Mitsuyoshi Shimano
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Publication number: 20120255661Abstract: A process for preparing a copolymer of an acyclic conjugated diene and a cyclic conjugated diene using a polymerization catalyst system comprising a transition metal compound or a lanthanide metal compound, an alkylating agent, and an inorganic halide alcoholate, and rubber compositions and tires comprising the same. The copolymer contains at least 90% acyclic conjugated diene monomer, has a number average molecular weight of between 40,000 and 300,000, and has a cis-bond content of at least 92%.Type: ApplicationFiled: October 13, 2010Publication date: October 11, 2012Inventors: Zengquan Qin, Eiju Suzuki
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Publication number: 20120248002Abstract: A polymer composition of polypropylene copolymer and 1 to 50% by weight of hard resin. The polypropylene copolymer is either an impact copolymer or a random copolymer. The polymer composition can be used to make injection stretch blow molded articles having improved top load strength.Type: ApplicationFiled: March 30, 2011Publication date: October 4, 2012Applicant: Fina Technology, Inc.Inventors: Luyi Sun, Tim Coffy, Leland Daniels
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Patent number: 8278392Abstract: Disclosed are processes for producing polypropylene resin compositions including two or three sorts of propylene-based polymeric materials, the processes including a first step of melt-kneading at least a propylene-?-olefin block copolymer containing a polymer portion composed mainly of propylene and a propylene-?-olefin copolymer portion having a relatively high intrinsic viscosity and a second step of melt-kneading the product of the first step with a propylene-ethylene block copolymer containing a polymer portion composed mainly of propylene and a propylene-ethylene copolymer portion having a relatively low intrinsic viscosity or a polymer portion composed mainly of propylene having a relatively low intrinsic viscosity. In the composition produced by these processes, no or substantially no fish eyes develop.Type: GrantFiled: February 17, 2010Date of Patent: October 2, 2012Assignee: Sumitomo Chemical Company, LimitedInventors: Satoru Moritomi, Takashi Sanada, Mitsuyoshi Shimano
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Publication number: 20120244304Abstract: Farnesene interpolymer comprises units derived from a farnesene (e.g., ?-farnesene or ?-farnesene) and units derived from at least one vinyl monomer. The farnesene interpolymer can be prepared by copolymerizing the farnesene and at least one vinyl monomer in the presence of a catalyst. In some embodiments, the farnesene is prepared from a sugar by using a microorganism. In other embodiments, the at least one vinyl monomer is ethylene, an ?-olefin, or a substituted or unsubstituted vinyl halide, vinyl ether, acrylonitrile, acrylic ester, methacrylic ester, acrylamide or methacrylamide, or a combination thereof.Type: ApplicationFiled: May 25, 2012Publication date: September 27, 2012Applicant: Amyris, Inc.Inventor: Derek James MCPHEE
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Patent number: 8268927Abstract: A water redispersible polymer powder is produced by drying an aqueous mixture of a high Tg carboxylated styrene butadiene polymer and a low Tg carboxylated styrene butadiene polymer, where the ratio of the mean or average particle size of the high Tg polymer to the particle size of the low Tg polymer is from 1:1 to 5:1, preferably from 1:1 to 3:1, and the amount of the high Tg polymer is from 20 wt. % to 35 wt. %, preferably from 25 wt. % to 30 wt. %, based upon the total weight of the high Tg polymer and the low Tg polymer. Cement compositions such as mortars, which contain the redispersible polymer powder exhibit unexpectedly superior high bond strength and high impact resistance.Type: GrantFiled: June 23, 2011Date of Patent: September 18, 2012Assignee: Dow Global Technologies LLCInventors: Robert Baumann, Juergen Dombrowski, Hartmut Kuehn, Etienne Lazarus, Gerold A Lohmuller, Margarita Perello, Yafei Zhu