Nitrogen-containing Reactant Patents (Class 528/288)
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Patent number: 6150494Abstract: The invention relates to a polymer prepared from the repeat units of residues of a monomer of at least one dicarboxylic acid or ester; a monomer comprising a diol, diamine or a mixture thereof; a monomer comprising at least one sulfonate group and at least one polyester reactive group, and a monomer comprising an optical brightener agent having at least one polyester reactive group. The invention further relates to a method for preparing a polymer. The invention further relates to method of marking an article or composition with the polymer. The invention further relates to a method for detecting and separating an article contacted with the polymer. The invention further relates to an article or composition contacted with the polymer. The invention further relates to a method for enhancing the optical brightness of an article or composition, by contacting the article or composition with the polymer.Type: GrantFiled: April 30, 1998Date of Patent: November 21, 2000Assignee: Eastman Chemical CompanyInventors: Richard Hsu-Shien Wang, James J. Krutak, Mahendra K. Sharma, Barbara C. Jackson
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Patent number: 6150490Abstract: The invention concerns biologically degradable polyesterS which are degraded under the action of micro-organisms in the natural environment. Said polyesters are high molecular weight satistical copolyesters which are made using an aliphatic polyalcohol, an aromatic polycarboxylic acid and also an aliphatic polycarboxylic acid as monomer components. They contain constitutional repeating or recurrent units comprising (i) a polyalcohol and an aromatic polycarboxylic acid and (ii) a polyalcohol and an aliphatic polycarboxylic acid, where over 90% of the units of type (i) are directly bonded with none or at most one other unit of type (i). The polyesters are produced by using a di-isocyanate as an additional monomer component, less isocyanate being used than any of the other monomer components. The present invention also concerns materials made from said biodegradable polyester and a process for producing said polyesters.Type: GrantFiled: August 14, 1998Date of Patent: November 21, 2000Assignee: Degussa-Huels AGInventors: Wolf-Dieter Deckwer, Rolf Joachim Muller, Uwe Witt, Hans-Jurgen Arning
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Patent number: 6139954Abstract: The invention relates to amorphous and crystalline fibers, particularly binder fibers, made from polyesters and the polyesters themselves. The polyesters of the invention are generally formed from a glycol component, such as a five carbon glycol, and a dicarboxylic acid component. The polyesters may be formed into a variety of products, for example fibers, composites and other molded articles. Preferably the polyesters are binder fibers for nonwovens, textile and industrial yarns and fabrics.Type: GrantFiled: August 6, 1999Date of Patent: October 31, 2000Assignee: Eastman Chemical CompanyInventors: Leron R. Dean, William A. Haile, Richard L. McConnell
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Patent number: 6132884Abstract: Process for producing highly stretchable, amorphous anisotropic melt-forming polymers having recurring units derived from p-hydroxybenzoic acid, 6-hydroxy-2-naphthoic acid, at least one aromatic diacid and an aromatic diol and/or hydroxyamine component, at least a portion of which is 4,4'-biphenol, which comprises incorporating into such polymers recurring units derived from resorcinol and at least one additional monomer that provides the resulting polymer with selected meta linkages, wherein each of said recurring units is present in the polymer in specified amounts.Type: GrantFiled: January 14, 2000Date of Patent: October 17, 2000Assignee: Ticona LLCInventors: H. Clay Linstid, III, Dominick L. Cangiano, Ronald N. DeMartino, James E. Kuder, Vincent J. Provino
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Patent number: 6129875Abstract: This invention relates to methods for controlling the oxidation of hydrocarbons to dibasic acids, in the presence of a catalyst and a monobasic acid, by removing the catalyst from the reaction mixture, outside the oxidation zone, after the oxidation has taken place at least partially. Initially, the catalyst is partially precipitated and removed by reducing the water level in the reaction mixture and/or subjecting the reaction mixture to a temperature, at which or over which catalyst precipitates. After the initial partial precipitation of the catalyst, the remaining catalyst is subjected to a thermal treatment, during which at least part of the monobasic acid is removed leaving behind molten dibasic acids, in which, at least a major part of the remaining catalyst is precipitated, and it is removed. A minor part of remaining catalyst is removed by methods, which include but are not limited to ion exchange, precipitation with a base or appropriate salt, and electrodialysis.Type: GrantFiled: February 4, 1999Date of Patent: October 10, 2000Assignee: RPC Inc.Inventors: Mark W. Dassel, Ader M. Rostami, Douglas J. Dudgeon, David C. DeCoster, Eustathios Vassiliou
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Patent number: 6121408Abstract: The powder coating for use in a coating method which includes the steps of mixing and applying two or more powder coatings to a substrate, the powder coating comprising a resin not having thermosetting properties at a temperature of 160.degree. C. or less by itself, and being heat-cured at a temperature of 160.degree. C. or less when used in combination with other powder coatings. The powder coating composition comprising two or more powder coatings, wherein each of the powder coatings comprises a resin not having thermosetting properties at a temperature of 160.degree. C. or less by itself, and being heat-cured at a temperature of 160.degree. C. or less to form a coating film when used in combination with other powder coatings.Type: GrantFiled: April 7, 1998Date of Patent: September 19, 2000Assignee: Kao CorporationInventors: Katsutoshi Aoki, Masayuki Maruta, Yukiya Sato, Hisakazu Tajima, Takehiko Tohjo, Yasunori Inagaki, Shingo Tanaka
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Patent number: 6120895Abstract: Biodegradable polyesters based onA) 95-99.99 mol % of at least one polyester A containing as monomeric building blocks of an acid component comprisinga.sub.11) 20-95 mol % of at least one aliphatic or cycloaliphatic dicarboxylic acid or its ester-forming derivative anda.sub.12) 5-80 mol % of at least one aromatic dicarboxylic acid or its ester-forming derivative andat least one dihydroxy compound or at least one amino alcohol or their mixtures, andB) 0.01-5 mol % of a mixture comprising mono-, bi-, tri-, tetra- and higher-nuclear isocyanurates or corresponding compounds containing two, three or four functional groups capable of reacting with the end groups of polyester A, or mixtures of the isocyanurates and the corresponding compounds,as well as molding compositions comprising said polyesters, their manufacture and their use in the manufacture of moldings, filsm, fibers and coatings.Type: GrantFiled: March 17, 1999Date of Patent: September 19, 2000Assignee: BASF AktiengesellschaftInventors: Christoph Kowitz, Peter Bauer, Dieter Bernhard Beimborn, Bernd Bruchmann, Uwe Faller, Martin Laun, Udo Pagga, Gunter Pipper, Volker Warzelhan
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Patent number: 6111055Abstract: An ester-terminated dimer acid-based polyamide may be blended with a solvent to form a gel. The solvent may be flammable, and a wick may be added to the resulting gel so as to form a candle. Depending on the composition, the candle may be formed into a free standing pillar, or may be better suited to being placed in a container. The solvent may be mineral oil. A solid coating may be placed around the candle, for advantages including to enhance the mechanical stability of the gelled body, and to eliminate the tendency of a gel to have an oily feel and to accept noticeable fingerprints. The solvent which, in combination with the ester-terminated dimer acid-based polymer forms a gel, may be or include a fragrance material, an insecticide or an insect repellent. A wick may or may not be present in this gel, but in any event, the composition provides for the release of the fragrance, insecticide or insect-repellent.Type: GrantFiled: September 26, 1997Date of Patent: August 29, 2000Assignees: Union Camp Corporation, Bush Boake AllenInventors: Vivian Berger, Charles R. Frihart, Ronald L. Gordon, Jochen Heydel, Richard C. MacQueen, Mark S. Pavlin, Virgil Williams
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Patent number: 6107447Abstract: The invention relates to polymers which form cholesteric phases, to a process for their preparation and to their use.Novel polymers and oligomers which form cholesteric phases essentially consist, as molecular building blocks, ofA. at least one bifunctional chiral molecular building block which contains at least one cyclic structural element other than a monosubstituted p-phenylene group,B. at least one bifunctional achiral or racemic molecular building block which contains at least one cyclic structural element containing at least four ring members, andC. at least one bifunctional molecular building block which can be either chiral or achiral, cyclic or acyclic, and is different from the molecular building blocks A and B actually employed,with the proviso that the molecular building block A is not derived exclusively from camphoric acid.Type: GrantFiled: June 16, 1998Date of Patent: August 22, 2000Assignee: Hoechst Research Technology Deutchland GmbH & Co. KGInventors: Willi Kreuder, Axel Schonfeld, Gordon Calundann
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Patent number: 6107438Abstract: A method of producing a polyamide resin by reacting with at least one diamine compound, at least one linear polyester resin consisting of at least one dicarboxylic acid component and at least one diol component and having an intrinsic viscosity of not less than 0.2 dl/g, the at least one diamine compound being used in an amount of 0.5-1.5 mol per 1 mol of the at least one linear polyester resin as calculated in the repeating unit thereof, the linear polyester resin and the diamine compound being reacted in a reaction medium comprising at least one solvent selected from aprotic protophobic polar solvents, so that the at least one diol component of the linear polyester resin is substituted by the diamine compound, resulting in the polyamide resin as a reaction product.Type: GrantFiled: October 1, 1998Date of Patent: August 22, 2000Assignee: M & S Research and Development Co., Ltd.Inventor: Seiko Nakano
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Patent number: 6103864Abstract: The polyimides are derived from solutions of at least one low-boiling organic solvent, e.g. isopropanol containing a mixture of polyimide-forming monomers. The monomeric solutions have an extended shelf life at ambient (room) temperatures as high as 80.degree. C. and consist essentially of a mixture of monoalkyl ester-acids, alkyl diester-diacids and aromatic polyamines wherein the alkyl radicals of the ester-acids are derived from lower molecular weight aliphatic secondary alcohols having 3 to 5 carbon atoms per molecule such as isopropanol, secondary butanol, 2-methyl-3-butanol, 2 pentanol or 3-pentanol. The solutions of the polyimide-forming monomers have a substantially improved shelf-life and are particularly useful in the aerospace and aeronautical industry for the preparation of polyimide reinforced fiber composites such as the polyimide cured carbon composites used in jet engines, missiles, and for other high temperature applications.Type: GrantFiled: January 14, 1999Date of Patent: August 15, 2000Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space AdministrationInventors: William B. Alston, Gloria S. Gahn
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Patent number: 6100370Abstract: The invention concerns a softener-free polyamide prepared by polycondensation and/or polymerization of polyamide-forming monomers, wherein it was obtained by adding 5-50 wt. % of a dimer diol with a molecular weight within the range of 400-1000 and/or corresponding OH-terminated polyesters.Type: GrantFiled: May 6, 1999Date of Patent: August 8, 2000Assignee: Ems-Chemie AGInventors: Heinz Hoff, Ulrich Wolf
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Patent number: 6074757Abstract: The invention relates to mixtures of preferably from 80 to 99.9% by weight, based on the mixture, of a solution S1 comprising one or more polyamidocarboxylic acids and preferably from 0.1 to 20% by weight, based on the mixture, of a solution S2 comprising one or more, preferably primary, diamines and one or more tetracarboxylic acid diesters, processes for producing polyimide coatings using such mixtures, the use of such mixtures for producing polyimide coatings, and also polyamide-coated articles obtainable using such mixtures.Type: GrantFiled: February 17, 1998Date of Patent: June 13, 2000Assignee: Schenectady Europe GmbHInventors: Klaus-Wilhelm Lienert, Gerold Schmidt, Rainer Blum
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Patent number: 6074758Abstract: A poly(hydroxy ester ether) is prepared by reacting a) a diacid containing a hetero moiety of the formula:HO.sub.2 CCH.sub.2 X(RX).sub.y CH.sub.2 CO.sub.2 Hwherein X is selected from the group consisting of --O--, --S--, and NH; y is the whole number 0 or 1; and R is selected from the group consisting of an aromatic moiety and a heterocyclic moiety having from 6 to 30 carbon atoms; andb) a diglycidyl ether generally represented by the formula: ##STR1## wherein R.sup.2 is an aromatic moiety or divalent aliphatic hydrocarbon having 2 to 20 carbon atoms. Films, articles and laminations made from the composition exhibit an oxygen permeability of less than about 8 cc-mil/100 in.sup.2 -24 hour-atmosphere. The present invention is further directed to a miscible blend having the poly(hydroxy ester ether) of the present invention and a second component selected from a saturated polyester of an aromatic diacid, such as PET and PEN.Type: GrantFiled: November 4, 1999Date of Patent: June 13, 2000Assignee: Eastman Chemical CompanyInventor: Robert Boyd Barbee
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Patent number: 6054552Abstract: In process for making a polyesteramide composition, an alkyl aryl terephthalate ester is formed from a dialkyl terephthalate by transesterification and then reacted with an alkyl diamine to form a bis-ester amide wherein the reaction product containing the bis-ester amide may be directly contacted with an alkyl diamine without the need for purification steps.Type: GrantFiled: August 14, 1998Date of Patent: April 25, 2000Assignee: General Electric CompanyInventors: Johannes Hubertus G. M. Lohmeijer, Timothy E. Banach, Daniel J. Brunelle, Gabrie Hoogland, Reimo Faber
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Patent number: 6051620Abstract: Polyester polyols which contain at least one dihydrazide linkage --C(.dbd.O)--NHNH--C(.dbd.O)-- reduce the incidence of scorching when used as a reactant in the manufacture of polyurethane foam. Also disclosed are compounds of structures (2) and (3):D--HN(--NH--C(.dbd.O)--R--C(.dbd.O)NH).sub.0-1 --NH--D (2)(A--C(.dbd.T)--NH)--.sub.Type: GrantFiled: June 11, 1997Date of Patent: April 18, 2000Assignee: CK Witco CorporationInventors: Ibrahim Bechara, Thomas R. Baranowski, James Stogis, Thomas H. Morong
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Patent number: 6048952Abstract: Novel mixtures of perfluoroalkyl halides and derivatives thereof are described. These mixtures contain some compounds with a straight perfluoroalkyl group and some with a branched perfluoroalkyl group. Methods of preparation and use are also described.Type: GrantFiled: February 4, 1997Date of Patent: April 11, 2000Assignee: 3M Innovative Properties CompanyInventors: Frederick E. Behr, Rudolf J. Dams, Johan E. DeWitte, Donald F. Hagen
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Patent number: 6048958Abstract: Diketo dinitriles are produced from the reaction of a diester and a nitrile in the presence of an alkali metal base. Polymers derived from the diketo dinitriles are useful as molding resins.Type: GrantFiled: December 1, 1998Date of Patent: April 11, 2000Assignee: Henkel CorporationInventor: Louis Rebrovic
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Patent number: 6046263Abstract: Products are described which are obtainable by reacting compounds of formula I with compounds of formula IIa or/and IIb and IIIa or/and IIIb and additionally, where appropriate, IV ##STR1## wherein the general symbols are as defined in claim 1, the compound of formula I being, for example, methyl 3-(3',5'-di-tert-butyl-4'-hydroxyphenyl)propionate, the compound of formula IIa being, for example, diethanolamine, the compound of formula IIIa being, for example, methyl oleate, and the compound of formula IV being, for example, sulfur. The cited products can be used as liquid antioxidants in organic materials.Type: GrantFiled: May 19, 1998Date of Patent: April 4, 2000Assignee: Ciba Specialty Chemicals CorporationInventors: Michael Rasberger, Samuel Evans, Paul Dubs, Stephan Allenbach
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Patent number: 6039902Abstract: This invention relates to methods of recycling catalyst in oxidations of hydrocarbons, such as cyclohexane for example, to respective intermediate oxidation products, such as adipic acid for example, by a direct process. The catalyst remains in solution despite removal of water from the composition, since the water removal is controlled at such temperatures and such remaining water levels that prevent catalyst from precipitating. The water removal is preferably conducted before removal of the intermediate oxidation product. Also, preferably, some, and more preferably all steps of the process are conducted in a single liquid phase region.Type: GrantFiled: September 18, 1997Date of Patent: March 21, 2000Assignee: RPC Inc.Inventors: Ader M. Rostami, David C. DeCoster, Eustathios Vassiliou, Mark W. Dassel
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Patent number: 6034204Abstract: Condensation products of basic amino acids with copolymerizable compounds which are obtainable by condensing(a) a basic amino acid selected from the group consisting of lysine, arginine, ornithine, tryptophane and mixtures thereof,(b) a copolymerizable compound selected from the group consisting of saturated monobasic carboxylic acids, unsaturated mono-basic carboxylic acids, polybasic carboxylic acids, carboxylic acid anhydrides, diketenes, monohydroxycarboxylic acids, polyhydroxycarboxylic acids and mixtures thereof, and optionally(c) at least one compound selected from the group consisting of amines, lactams, non-proteinogenic acids, alcohols, alkoxylated alcohols, alkoxylated amines, amino sugars, carbohydrates and sugar carboxylic acidsin a molar ratio of (a):(b) of from 100:1 to 1:1 at a temperature of at least 120.degree. C., and a process for the production of said condensation products by condensing compounds (a) and (b) and optionally (c) at a temperature of from 120.degree. to 300.degree. C.Type: GrantFiled: August 7, 1998Date of Patent: March 7, 2000Assignee: BASF AktiengesellschaftInventors: Bernhard Mohr, Dieter Boeckh, Ralf Norenberg, Sherri Randall, Rajan Panandiker, Eugene Paul Gosselink, LeeAnn Luipold
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Patent number: 6031061Abstract: A bis(trisubstitutedtrimellitic anhydride) derivative and a polyesterimide for optical communications, the polyesterimide being formed therefrom. The polyesterimide has a high refractive index, so that when using such polyesterimide as a material for a core of an optical fiber, the range of materials that can be selected for the cladding becomes wide. Also, a coating property and adhesion to a substrate are improved, thereby providing a good film forming property and thermal stability. Also, because the polyesterimide can minimize optical loss at a near infrared wavelength range, the polyesterimide is very useful as an optical material in the optical communications field adopting the light of near infrared wavelength.Type: GrantFiled: December 31, 1998Date of Patent: February 29, 2000Assignee: SamSung Electronics Co., Ltd.Inventors: Dong-hack Suh, Sun-young Chung, Tae-hyung Rhee
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Patent number: 6018004Abstract: Biodegradable polyesters P1 obtainable by reaction of a mixture consisting essentially of(a1) a mixture consisting essentially offrom 35 to 95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof,from 5 to 65 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, andfrom 0 to 5 mol % of a sulfonate compound, the sum of the individual mole percentages being 100 mol %, and(a2) a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,the molar ratio of (a1) to (a2) being chosen within the range from 0.4:1 to 1.5:1,with the proviso that the polyesters P1 have a molecular weight (M.sub.n) within the range from 5000 to 50,000 g/mol, a viscosity number within the range from 30 to 350 g/ml (measured in 50:50 w/w o-dichlorobenzene/phenol at a concentration of 0.5% by weight of polyester P1 at 25.degree. C.) and a melting point within the range from 50 to 170.degree. C.Type: GrantFiled: May 14, 1997Date of Patent: January 25, 2000Assignee: BASF AktiengesellschaftInventors: Volker Warzelhan, Gunnar Schornick, Bernd Bruchmann, Ursula Seeliger, Motonori Yamamoto, Peter Bauer
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Patent number: 6011133Abstract: Poly(alkylene dicarboxylate) polymers and copolymers having tetraalkyl- or trialkylammonium ion end groups and methods of synthesis, thereof. The methylene-containing copolymers, in general, adhere to glass and metals, including aluminum, iron, and copper. Poly(methylene-co-ethylene terephthalate) is a clear film useful in the protection of metals or glass from corrosion or scratching. Glass may be bound to glass or to metal using the polymers of the present invention or metal to metal seals may be made.Type: GrantFiled: November 16, 1998Date of Patent: January 4, 2000Assignee: Baylor UniversityInventors: A. G. Pinkus, Rajan Hariharan
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Patent number: 6011125Abstract: A thermoplastic resin composition comprises units represented by the amide formula (I): ##STR1## and the ester formula (II): ##STR2## wherein said amide units are present as a physical mixture in said resin or as a polymer with the repeating ester units to impart an enhanced crystallization rate as compared to said resin without said amide units of formula (I), said amide units being present in an effective amount to decrease the difference between the temperature of melting and the temperature of crystallization of said resin to an amount less than 5 mole percent of amide unites of formula (I) based on the moles of ester units of formula (II).Type: GrantFiled: September 25, 1998Date of Patent: January 4, 2000Assignee: General Electric CompanyInventors: Jan Lohmeijer, Reimo Faber, Gabrie Hoogland, Peter Serrano, Gert de Wit, Bret Ja Chisholm
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Patent number: 6001910Abstract: A remoistenable hot melt adhesive composition comprising (i) 25 to 80% by weight of a sulfonated polyester;(ii) 3 to 40% by weight of an anionic or cationic plasticizer;(iii) 0 to 40% by weight of a polar tackifier;(iv) 0 to 3% by weight of an antioxidant; and(v) 10 to 35% by weight of a polar wax; and(vi) optionally 0 to 30% nonionic plasticizer, wherein the total of (i)-(vi) to equal 100% by weight.Type: GrantFiled: April 9, 1999Date of Patent: December 14, 1999Assignee: National Starch and Chemical Investment Holding CorporationInventors: Mitchell J. Blumenthal, Charles W. Paul, Matthew L. Sharak
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Patent number: 5998570Abstract: A low molecular weight, ester-terminated polyamide may be blended with a liquid hydrocarbon to form a transparent composition having gel consistency. The ester-terminated polyamide is prepared by reacting "x" equivalents of dicarboxylic acid wherein at least 50% of those equivalents are from polymerized fatty acid, "y" equivalents of diamine such as ethylene diamine, and "z" equivalents of monoalcohol having at least 4 carbon atoms. The stoichiometry of the reaction mixture is such that 0.9.ltoreq.{x/(y+z)}.ltoreq.1.1 and 0.1.ltoreq.{z/(y+z)}.ltoreq.0.7. The reactants are heated until they reach reaction equilibrium. The gel contains about 5-50% ester-terminated polyamide with the remainder preferably being pure hydrocarbon. The gels are useful in formulating personal care products and other articles wherein some degree of gel-like or self-supporting consistency is desired.Type: GrantFiled: May 6, 1998Date of Patent: December 7, 1999Assignee: Union Camp CorporationInventors: Mark S. Pavlin, Richard C. MacQueen
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Patent number: 5990266Abstract: Degradable polyesters useful in packaging, packing, agricultural, biomedical, and other applications are made by reacting amine-protected glutamic acid with diols or epoxy compounds. The polyesters include a thermoplastic main chain aliphatic polyester, a thermoset heterochain polyester and a thermoset heterochain aromatic polyester. Each of these polyesters can be hydrolyzed into monomers using a biological catalyst such as the enzyme lipase. The thermoplastic main chain aliphatic polyester and the thermoset heterochain polyester can be degraded to respiratory gases and biomass with a mixed culture of Rhizopus, chinesis, Rhizopus delemar, Penecillium pinophilum, Aspergillus niger and Pseudomonas aeruginosa microorganisms. This mixed culture of microorganisms can also be used to degrade other polyesters containing hydrolyzable backbone polyesters.Type: GrantFiled: December 2, 1998Date of Patent: November 23, 1999Assignee: University of NebraskaInventors: Raef M. Tadros, Delmar C. Timm
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Patent number: 5990318Abstract: Novel soluble polyester-supported chiral phosphines have been prepared and have been used in the preparation of rhodium and ruthenium catalysts. Such polymer-supported catalysts show high catalytic activities and enantioselectivities. In the case of Ru(BINAP) catalyst supported on soluble polyester, the resulting catalysts were found to be more active than those of the corresponding homogeneous Ru(BINAP) catalysts in the asymmetric hydrogenation of 2-arylpropenoic acids. These soluble polyester-supported catalysts can be easily separated from the reaction mixture and then be reused without loss of activity and selectivity.Type: GrantFiled: March 6, 1998Date of Patent: November 23, 1999Assignee: The Hong Kong Polytechnic UniversityInventors: Albert Sun-Chi Chan, Qing-Hua Fan
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Patent number: 5989697Abstract: Claimed is a copolyether amide having a melting point in the range of 180.degree. to 260.degree. C., incorporating at least 10 wt. % and not more than 30 wt. % of ethylene oxide groups, and composed of 30 to 60 wt. % of polyamide segments and 70 to 40 wt. % of segments derived from a (cyclo)aliphatic or aromatic dicarboxylic acid or a dimeric fatty acid and a polyoxyalkylene diamine derived from a polyoxyalkylene group having a molecular weight of 600 to 6000 and an atomic ratio of carbon to oxygen of 2.0 to 4.3. Also claimed is a non-porous, waterproof film having a water vapor permeability of at least 1000 g/m.sup.2 day determined at 30.degree. C. and 50% RH in accordance with ASTM E96-66 which is based on a the use of these films in rainwear, shoes, tents, chairs, as mattress covers and underslating, for medical purpose garments, and for the manufacture of dressings.Type: GrantFiled: November 24, 1997Date of Patent: November 23, 1999Assignee: Akzo Nobel, NVInventor: Bert Gebben
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Patent number: 5986041Abstract: A polyetheresteramide compound and the method of preparing it comprise: a polyether compound containing a diamino group at the end mixed with a diacid and a diol, and being polymerized and condensed to form a polyetheresteramide compound. This polyetheresteramide is a durable anti-static resin. In addition to the anti-static property, the polyetheresteramide compound has the physical properties of the original polyester. Thus, the polyetheresteramide compound can be added into an anti-static resin and applied in general resin industry, special chemical and spinning industries. The anti-static products, such as the anti-static thin plate, anti-static bag, IC cover tape, anti-static clothes, and dustless clothes, or even broadly applied in electronic communication, semiconductor, and optoelectronic manufactures.Type: GrantFiled: June 19, 1997Date of Patent: November 16, 1999Assignee: Industrial Technology Research InstituteInventors: Ling-Yu Cheng, Yuung-Ching Sheen, Tsai-Wie Tseng, Juh-Shyong Lee
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Patent number: 5976615Abstract: A curable coating composition is described comprising a carbamate functional material and a crosslinking agent, reactive with the carbamate group. The composition further comprises a third component that is a mixture of catalysts including a phosphorus containing acid or acid derivative and other acid catalysts. Coatings prepared with this coating composition can be cured and coated with additional coating(s), providing good intercoat adhesion to the subsequent coating.Type: GrantFiled: July 9, 1997Date of Patent: November 2, 1999Assignee: BASF CorporationInventors: Gregory G. Menovcik, John G. Partyka, Aimee R. Barach, Sanjay Mehta
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Patent number: 5969079Abstract: Thermomechanical and thermo-oxidative stabilities in resin composites across the range of aerospace "engineering thermoplastic" resins are improved by forming four crosslinks at each addition polymerization site in the backbone of the resin using crosslinking functionalities of the general formula: ##STR1## wherein Z= ##STR2## .beta.=the residue an organic radical selected from the group consisting of: ##STR3## R.sub.R =a divalent organic radical; X=halogen;Me=methylT=allyl or methallyl.G=--CH.sub.2 --,--S--, --CO--, --SO--, --O--, --CHR.sub.3 --, or --C(R.sub.3).sub.2 --;i=1 or 2;R.sub.3 =hydrogen, lower alkyl, lower alkoxy, aryl, or aryloxy; and.theta.=--C.tbd.N, --O--C.tbd.N, --S--C.tbd.N, or --CR.sub.3 .dbd.C(R.sub.3).sub.Type: GrantFiled: October 21, 1994Date of Patent: October 19, 1999Assignee: The Boeing CompanyInventors: Hyman R. Lubowitz, Clyde H. Sheppard
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Patent number: 5962557Abstract: A colored polyester copolymer comprising the reaction product of at least one linear thermoplastic polyester precursor and at least ten parts per million by weight of a residue of at least one 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant. A composition may be formed comprising the copolymer in admixture with at least one thermoplastic polymer. The copolymer may be formed by reacting at least one thermoplastic polyester precursor with a 1,4-bis (2,6-dialkylanilino)-9,10-anthraquinone colorant which has a polyester reactive group.Type: GrantFiled: August 7, 1997Date of Patent: October 5, 1999Assignee: Eastman Chemical CorporationInventors: Max Allen Weaver, Brian Edison Maxwell, Gerry Foust Rhodes, James John Krutak, Sr.
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Patent number: 5962023Abstract: The present invention describes a crosslinked aliphatic polyoxaamide polymer and blends thereof that may be used to produce hydrogels, surgical devices such as catheters, molded devices, and the like. The crosslinked aliphatic polyoxaamide of the present invention are formed by crosslinking an aliphatic polyoxaamide having a first divalent repeating unit of formula I:?X--C(O)--C(R.sub.1) (R.sub.2)--O--(R.sub.3)--O--C(R.sub.1) (R.sub.2)--C(O)--! Iand a second repeating unit selected from the group of formulas consisting of:?--Y--R.sub.17 --!.sub.T, II?--O--R.sub.5 --C(O)--!.sub.B, and III(?--O--R.sub.9 --C(O)!.sub.P --O--).sub.L G XIand combinations thereof, wherein X and Y are selected from the group consisting of --O-- and --N(R)--, provided both X and Y are not both --0-- and may be blended with a second polymer that is preferably biocompatable.Type: GrantFiled: November 6, 1996Date of Patent: October 5, 1999Assignee: Ethicon, Inc.Inventors: Dennis D. Jamiolkowski, Rao S. Bezwada
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Patent number: 5958592Abstract: The present invention is a cyanate resin monomer having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n is an even integer from 6 to 10, inclusive.Another aspect of the invention is an essentially pure cyanate resin mono having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n=3, 4, 6, 8, or 10. Another aspect of the invention is a prepolymer made by the process of heating a monomer of the invention to a conversion below the gel point. Another aspect of the invention is a method for depositing an interlevel dielectric resin on an integrated circuit, having the steps: (a) coating the integrated circuit with a thin film of a prepolymer made by the process of heating a monomer of the invention to below the gel point, and (b) curing the prepolymer to at least the gel point. Another aspect of the invention is a low dielectric thermoset polymer resin made from these monomers.Type: GrantFiled: January 13, 1998Date of Patent: September 28, 1999Assignee: The United States of America as represented by the Secretary of the NavyInventors: Arthur W. Snow, Leonard J. Buckley
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Patent number: 5948878Abstract: A class of polycationic polymers comprising products obtained by the copolymerization of a diprimary amine and a suitable comonomer, wherein the diprimary amine contains at least two primary amines and at least two secondary amines, and their use for nucleic acid transfection, and the delivery of suitable anionically charged bioactive molecules.Type: GrantFiled: April 15, 1997Date of Patent: September 7, 1999Inventors: Stephen W. Burgess, Walter A. Shaw
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Patent number: 5939519Abstract: The crystallinity of poly(1,4-cyclohexanedimethyl 1,4-cyclohexanedicarboxylate) is enhanced by the incorporation of amide units, preferably derived from such compounds as 1,6-bis(4-carbomethoxycyclohexylcarboxamido)hexane. Crystallization temperatures increase, as do heats of crystallization.Type: GrantFiled: May 11, 1998Date of Patent: August 17, 1999Assignee: General Electric Co.Inventor: Daniel Joseph Brunelle
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Patent number: 5932686Abstract: This invention relates to adhesion agents and compatibility agents, respectively, on the basis of partially crystalline, high-molecular block (co)polyester amides, produced by direct esterification of carboxyl-terminated or hydroxycarboxyl-terminated polyamide precondensates and hydroxyl-terminated or hydroxycarboxyl-terminated polyester segments, characterized in that the block (co)polyester amides form two crystalline phases and comprise as segments(A) at least one polyamide or copolyamide block having a uniform number average molar mass of at least 1000 g/mole,(B) at least one aromatic polyester and/or copolyester block having a uniform number average molar mass of at least 1000 g/mole, and(C) at least one further diol component of the general structureHO--R--OH,wherein R is selected from the group consisting of aliphatic or partially aromatic (co)polyesters, aliphatic polyethers, aliphatic (co)polyester amides, polycarbonates or aliphatic or aromatic hydrocarbons.Type: GrantFiled: October 17, 1997Date of Patent: August 3, 1999Assignee: EMS-Inventa AGInventor: Heinz Hoff
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Patent number: 5929198Abstract: New and improved polyamino acid polymers and derivatized polyamino acid polymers are provided. Relatively high molecular weight poly(succinimides) are prepared by solid phase polymerization of aspartic acid or glutamic acid in the presence of a super phosphoric acid catalyst. The poly(succinimides) may be hydrolyzed to provide biodegradable polyaspartic acid or polyglutamic acid homopolymer having weight average molecular weights.gtoreq.70,000. Higher molecular weight, water soluble, cross-linked polyamino acid polymers and gels are also provided. In a preferred embodiment, the poly(succinimides) are derivatized in aqueous media to provide storage stable, substantially linear, biodegradable polyamino acid polymers having pendant hydroxyl, ether, hydroxyalkylaminoalkyl, hydroxyalkoxyalkyl, carboxyl, sulfonoalkyl and/or phosphonoalkyl functionalities. The polymers are useful as chelants in various water treatment applications.Type: GrantFiled: September 30, 1996Date of Patent: July 27, 1999Assignee: Nalco Chemical CompanyInventor: Jiansheng Tang
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Patent number: 5929199Abstract: The present invention is a cyanate resin monomer having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n is an even integer from 6 to 10, inclusive.Another aspect of the invention is an essentially pure cyanate resin mono having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n=3, 4, 6, 8, or 10. Another aspect of the invention is a prepolymer made by the process of heating a monomer of the invention to a conversion below the gel point. Another aspect of the invention is a method for depositing an interlevel dielectric resin on an integrated circuit, having the steps: (a) coating the integrated circuit with a thin film of a prepolymer made by the process of heating a monomer of the invention to below the gel point, and (b) curing the prepolymer to at least the gel point. Another aspect of the invention is a low dielectric thermoset polymer resin made from these monomers.Type: GrantFiled: January 13, 1998Date of Patent: July 27, 1999Assignee: The United States of America as represented by the Secretary of the NavyInventors: Arthur W. Snow, Leonard J. Buckley
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Patent number: 5917000Abstract: A manufacturing process of continuously producing a polyether-ester amide elastomer, which is adapted for mass production and reducing manufacturing cost, includes the steps of melting a poly (tetra methylene ether) glycol reactant, a .epsilon.-caprolactam reactant and an adipic acid reactant, pre-polymerizing the melted reactants by esterification and ring-opening reaction to form a pre-polymer and highly polymerizing the pre-polymer to form the polyether-ester amide elastomer. The polyether-ester amide elastomer is specifically used as a raw ingredient for producing a polyether-ester amide elastic fiber by drying the polyether-ester amide elastomer in a drying device, extruding the dried polyether-ester amide elastomer by an extruder, and molten spinning the extruded polyether-ester amide elastomer to form the polyether-ester amide elastic fiber.Type: GrantFiled: April 29, 1998Date of Patent: June 29, 1999Inventors: J. H. Tsai, J. S. Chiou, Y. K Twu
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Patent number: 5916996Abstract: A process for the preparation of polyester-imide resin of the formula ##STR1## wherein n represents the number of segments present and is a number of from about 10 to about 10,000; R' is alkyl or alkylene; and R is independently an oxyalkylene or a polyoxyalkylene by the reaction of trimellitic acid, or a trimellitic anhydride, a glycol and a diamine of the formula ##STR2## wherein R represents a hydrogen or alkyl group; and n represents the number of monomer segments, and is a number of from about 1 to about 10, and which reaction is accomplished by heating the aforementioned components.Type: GrantFiled: June 23, 1994Date of Patent: June 29, 1999Assignee: Xerox CorporationInventors: Guerino G. Sacripante, Melvin D. Croucher, Stephan V. Drappel
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Patent number: 5908589Abstract: This invention relates to methods and reactor devices for controlling the oxidation of hydrocarbons to dibasic acids, in the presence of a catalyst and a monobasic acid, by removing the catalyst from the reaction mixture, outside the oxidation zone, after the oxidation has taken place at least partially. Initially, the catalyst is partially precipitated and removed by reducing the water level in the reaction mixture and/or subjecting the reaction mixture to a temperature, at which or over which catalyst precipitates. After the initial partial precipitation of the catalyst, the mother liquor remaining is subjected to a thermal treatment during which at least the major part of the monobasic acid is removed leaving behind molten dibasic acids, in which the remaining catalyst precipitates substantially in its totality, and it is removed. The precipitated catalyst in the two precipitation stages may be recycled in miscellaneous ways.Type: GrantFiled: December 8, 1997Date of Patent: June 1, 1999Assignee: Twenty-First Century Research CorporationInventors: David C. DeCoster, Eustathios Vassiliou, Mark W. Dassel, Ader M. Rostami, Douglas J. Dudgeon
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Patent number: 5902897Abstract: The present invention relates to polyamines which are prepared by reactinga) unsaturated oligoesters having an average of 2 to 4 double bonds per molecule andb) optionally other unsaturated compounds suitable as Michael addition acceptors and having an average of 1 to 4 double bonds per molecule withc) (cyclo)aliphatic diamines having two primary amino groups andd) optionally other amino-functional compounds suitable as Michael addition donors.The present invention also relates to the use of these polyamines as a binder component in lacquers and coating compositions, particularly as reactants for blocked polyisocyanates in one-component stoving lacquers.Type: GrantFiled: July 19, 1996Date of Patent: May 11, 1999Assignee: Bayer AktiengesellschaftInventors: Christian Wamprecht, Theodor Engbert, Holger Casselmann, Josef Pedain, Jurgen Meixner
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Patent number: 5900475Abstract: The present invention relates to a poly(allylamine) polymer and, more generally, a hydrocarbon amine polymer. Preferably, these polymers are crosslinked. The present invention also relates to methods of forming these polymers and methods for their use. Further, the present invention relates to alkylating agents that can be employed to form the polymers and to methods for forming the alkylating agents Generally, the polymer sequestrant includes a substituent bound to an amine of the polymer. The substituent includes a quaternary amine-containing moiety having one, two or three terminal hydrophobic substituents. A method of preparing quaternary amine-containing alkylating agents includes reacting an unsymmetrical dihalide with a tertiary amine having at least one hydrophobic substituent. A method for binding bile salts of bile acids in a mammal includes orally administering to the mammal a therapeutically-effective amount of the polymer sequestrant.Type: GrantFiled: June 6, 1996Date of Patent: May 4, 1999Assignee: GelTex Pharmaceuticals, Inc.Inventors: W. Harry Mandeville, III, Stephen Randall Holmes-Farley, John S. Petersen
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Patent number: 5895809Abstract: The invention relates to a method of producing partially aromatic copolyamides from polymeric esters of aromatic dicarboxylic acids by amidation of the ester groups with diamines, removal of the split-off alcohols or diols and after-condensation of the low-molecular precondensates as well as by the following compounding to polyamide molding materials.Type: GrantFiled: February 13, 1997Date of Patent: April 20, 1999Assignee: EMS-Polyloy GmbHInventors: Harald Wagner, Joachim Ensinger, Erich Krumpschmid
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Patent number: 5888597Abstract: The invention relates to a packaging comprising a thermoplastic film based on a polymer containing polyamide blocks and polyether blocks, said polymer being permeable to water vapor, to ethylene, to CO.sub.2 and to oxygen, such that the permeability to CO.sub.2 is very much greater than the permeability to oxygen. The invention is particularly useful for making sachets in order to conserve fresh fruit, vegetables or meat.Type: GrantFiled: April 10, 1996Date of Patent: March 30, 1999Assignee: Elf Atochem S.A.Inventors: Alain Frey, Roland Leroux, Laurent Fischer
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Patent number: 5889126Abstract: The invention relates to Amorphous and/or semicrystalline copolyesters containing .beta.-hydroxyalkylamide groups according to formula (I) ##STR1## whereinP=polymer chain of the polyesterR1=alkyl residues with 1-5 atoms or hydrogen or ##STR2## R2=alkyl residues with 1-5 C-atoms or hydrogen, R3=alkyl residues and 1-5 C-atoms or hydrogen, andn.gtoreq.2,with a molecular weight (Mn) of 300 to 15,000 and a hydroxyl value of 10 to 400 ?mg KOH/g!.Type: GrantFiled: July 11, 1997Date of Patent: March 30, 1999Assignee: EMS-Inventa AGInventors: Andreas Kaplan, Rene Gisler, Eberhard Kinkelin
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Patent number: 5886137Abstract: A process for preparing salts of polyaspartic acid by treating polycondensates in aqueous medium with bases, employing at least 0.7 equivalent of an alkali metal and/or alkaline earth metal base per mole of the aspartimide, aspartic acid and/or aspartamide units present in the polycondensates, and the bases being added within from 30 min to 20 hours to an aqueous suspension of polycondensates of aspartic acid which has been heated to 40.degree.-140.degree. C., and the reaction mixture being allowed to react further where appropriate, and the use of alkali metal and/or alkaline earth metal salts of polyaspartic acids obtainable by treating polycondensates of aspartic acid in aqueous medium with more than 1 equivalent of an alkali metal and/or alkaline earth metal base, with the molecular weight of the polycondensates being reduced, as additive to detergents and cleaners.Type: GrantFiled: February 27, 1997Date of Patent: March 23, 1999Assignee: BASF AktiengesellschaftInventors: Matthias Kroner, Gunnar Schornick, Uwe Strotmann, Volker Schwendemann, Thomas Meyer, Alfons Ludwig