Nitrogen-containing Reactant Patents (Class 528/288)
  • Patent number: 5880220
    Abstract: Biodegradable polyetheresteramides P1 which are obtained by reacting(a1) a mixture containing20-95 mol % of adipic acid or ester-forming derivatives thereof or mixtures thereof and5-80 mol % of terephthalic acid or ester-forming derivatives thereof or mixtures thereof, and(a2) a mixture of dihydroxy compounds(a21) from 15 to 99.3 mol % of a dihydroxy compound selected from the group consisting of C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,(a22) from 0.2 to 85 mol % of a dihydroxy compound containing ether functionalities of the formula IHO--((CH.sub.2).sub.n --O).sub.m --H Iwhere n is 2, 3 or 4 and m is an integer from 2 to 250, or mixtures thereof and(a23) from 0.5 to 80 mol % of an amino-C.sub.2 -C.sub.12 -alkanol or amino-C.sub.5 -C.sub.10 -cycloalkanol,where the molar ratio of (a1) to (a2) is from 0.4:1 to 1.5:1, with the proviso, inter alia, that the polyetheresteramides P1 have a molecular weight (M.sub.
    Type: Grant
    Filed: July 3, 1997
    Date of Patent: March 9, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Warzelhan, Gunnar Schornick, Frank Braun, Ursula Seeliger, Motonori Yamamoto, Peter Bauer
  • Patent number: 5880252
    Abstract: Pyrrolidonyl-containing polyesters and polyamides I to III ##STR1## where R, X, A and Z are defined herein, are suitable as film formers and conditioners in hair-cosmetic formulations, for stabilizing hydrogen-peroxide in aqueous solution, for complexing iodine, as tablet binders and as a constituent of film coatings in pharmaceutical preparations, for enzyme and bleach stabilization in detergent formulations, as an auxiliary in the production and finishing of textiles, as a solubilizer and protective colloid in the preparation and stabilization of polymer dispersions, and as an adhesive raw material.
    Type: Grant
    Filed: March 22, 1996
    Date of Patent: March 9, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Son Nguyen Kim, Jorg Breitenbach, Axel Sanner, Peter Hossel, Siegfried Lang
  • Patent number: 5877255
    Abstract: A binder producible by reaction of aromatic polyesters with polyols and fatty acid esters as well as a process for the production of such a binder are described.The inventive binder is particularly suitable for the production of polyurethanes and results in floor coverings with especially favorable properties.
    Type: Grant
    Filed: March 26, 1997
    Date of Patent: March 2, 1999
    Assignee: Sika AG vorm. kaspar Winkler & Co.
    Inventors: Ulrich Gerber, Paul Schelbert, Werner Meyer
  • Patent number: 5874522
    Abstract: Disclosed are novel crosslinked polymeric ammonium salts wherein in said polymeric salt: about 25% or more of the segments which link ammonium nitrogen atoms are group Y wherein Y is an n-alkylene group or alkyl substituted n-alkylene group, wherein said n-alkylene group has 7 to about 20 carbon atoms; zero to about 75% of segments which link ammonium nitrogen atoms are group Z wherein Z is a hydrocarbylene radical containing 2 or more carbon atoms, said hydrocarbylene radical optionally containing one or more hydroxyl, ether, amino, thioether, keto, or silyl groups or heterocyclic rings; and about 25% or more of the ammonium atoms are secondary ammonium atoms.
    Type: Grant
    Filed: November 3, 1997
    Date of Patent: February 23, 1999
    Assignee: DuPont Pharmaceuticals Company
    Inventors: Garret Daniel Figuly, Jose Ricardo Matos
  • Patent number: 5863991
    Abstract: Biodegradable polyetheresteramides Q1 with a molecular weight (M.sub.n) in the range from 6000 to 80,000 g/mol, a viscosity number in the range from 30 to 450 g/ml (measured in o-dichlorobenzene/phenol (50/50 ratio by weight) at a concentration of 0.5% by weight polyetheresteramide Q1 at 25.degree. C.), and a melting point in the range from 50.degree. to 200.degree. C., obtained by reacting a1) from 95 to 99.9% by weight polyetheresteramide P1, obtained by reacting a mixture ofb1) 20-95 mol % adipic acid or ester-forming derivatives thereof, and5-80 mol % terephthalic acid or ester-forming derivatives thereof, andb2) a mixture of a dihydroxy compound selected from C.sub.2 -C.sub.6 -alkanediols and C.sub.5 -C.sub.10 -cycloalkanediols,b22) a dihydroxy compound which contains ether functionalities and has the formula IHO--((CH.sub.2).sub.n --O)).sub.m --H Iwhere n is 2, 3 or 4 and m is an integer from 2 to 250, andb23) from 0.5 to 80 mol % of an amino-C.sub.2 -C.sub.12 -alkanol or an amino-C.sub.5 -C.sub.
    Type: Grant
    Filed: July 3, 1997
    Date of Patent: January 26, 1999
    Assignee: BASF Aktiengesellschaft
    Inventors: Volker Warzelhan, Gunnar Schornick, Matthias Kroner, Ursula Seeliger, Motonori Yamamoto, Gerhard Ramlow
  • Patent number: 5864002
    Abstract: A method of providing for manufacturing a colored polymer resin having the steps of:(a) blending a disazo colorant into a mixture of monomers, the colorant having a poly(oxyalkylene) substituent comprising from 2 to 200 alkylene oxide residues, bonded to each end of the disazo chromophore, the poly(oxyalkylene) substituent having a nucleophilic terminal group which is capable of reacting with at least a portion of the monomers;(b) providing conditions under which the monomers and disazo colorant polymerize to form a colored polymer resin.
    Type: Grant
    Filed: October 18, 1996
    Date of Patent: January 26, 1999
    Assignee: Milliken Research Corporation
    Inventors: Eric B. Stephens, Mark E. Ragsdale, David J. Moody
  • Patent number: 5854376
    Abstract: A composition of an aliphatic ester-amide copolymer which is soluble in an organic solvent with an LD.sub.50 value (orally administered to a rat) of about 2,000 mg/kg or more.
    Type: Grant
    Filed: March 11, 1996
    Date of Patent: December 29, 1998
    Assignee: Sekisui Kaseihin Kogyo Kabushiki Kaisha
    Inventor: Takashi Higashi
  • Patent number: 5852155
    Abstract: Disclosed are polyesteramide resin compositions having amide units of formula (I): ##STR1## and the units of the formula (II): ##STR2## wherein the polyesteramide is substantially devoid of units derived from butane diol. The ratio of (I) to (II) in the polyesteramide is preferably less than 1:3. Preferred polyesteramides have at least 80% of units of formula (I) separated by at least one of the units of formula (II).
    Type: Grant
    Filed: March 1, 1995
    Date of Patent: December 22, 1998
    Assignee: General Electric Company
    Inventors: Jan Bussink, Reinoud Jaap Gaymans, Johannes Hubertus G. M. Lohmeijer, Ilias Nicholas Mamalis, Gary F. Smith, Antoinette Cornelia Maria van Bennekom
  • Patent number: 5840829
    Abstract: An adhesive is provided for bonding cyanate ester composite parts together which is also plateable with metal once chemically etched. The adhesive comprises a polymeric matrix and a filler of cyanate ester polymer. The polymeric matrix comprises at least one polyepoxide resin and a curing agent, while the cyanate ester polymer filler is present in the adhesive as a powder. In practice, the present adhesive is applied to the surface of cyanate ester composite articles to be bonded and is allowed to cure at room temperature. Thereafter, the surface of the assembly is chemically etched and then plated with metal. The present adhesive enable the complete coverage of the cyanate ester composite assembly with the plated metal, including the adhesive bondlines.
    Type: Grant
    Filed: November 25, 1997
    Date of Patent: November 24, 1998
    Assignee: Hughes Electronics Corporation
    Inventors: Ralph D. Hermansen, Brian M. Punsly, Wai-Cheng Seetoo
  • Patent number: 5840822
    Abstract: Mono(hydroxyalkyl)urea and 2-oxazolidone crosslinking agents and compositions which utilize such crosslinking agents are disclosed. The mono(hydroxyalkyl)urea crosslinking agents contain a single urea group, a single hydroxyl group, and have at least two carbon atoms disposed between the urea group and the hydroxyl group. The compositions contain a poly-functional molecule which contains at least two functional groups selected from the group consisting of carboxyl and anhydride.
    Type: Grant
    Filed: September 2, 1997
    Date of Patent: November 24, 1998
    Assignee: National Starch and Chemical Investment Holding Corporation
    Inventors: Sharon P. Lee, Steven P. Pauls, Sr.
  • Patent number: 5837803
    Abstract: A method of producing a polyamide resin by reacting 1 mol of linear polyester resin (as calculated in repeating unit of the linear polyester resin) consisting of at least one dicarboxylic acid component and at least one diol component and having an intrinsic viscosity of not less than 0.2 dl/g with 0.5-1.5 mol of at least one diamine compound in a reaction medium comprising at least one solvent which is selected from the group consisting of hydrocarbons, halogenated hydrocarbons, ethers and acetals, so that the diol component of the linear polyester resin is substituted by the diamine compound to provide the polyamide resin as a reaction product.
    Type: Grant
    Filed: March 31, 1997
    Date of Patent: November 17, 1998
    Assignee: M & S Research and Development Co., Ltd.
    Inventor: Seiko Nakano
  • Patent number: 5834412
    Abstract: Oligomeric or polymeric substituted or unsubstituted ethylene terephthalate esters comprising fluorescent whitening groups useful as soil release agents in laundry detergent compositions are described. The soil release agents of the present invention are especially suitable for use with polyester and polyester-blended fabric.
    Type: Grant
    Filed: June 4, 1997
    Date of Patent: November 10, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Robert Henry Rohrbaugh, Eugene Paul Gosselink
  • Patent number: 5811507
    Abstract: The present invention relates to a new polyesterimide of the type containing ester repeat functional groups E=--CO--O--, imide repeat functional groups I: ##STR1## and at least one chromophore, characterized in that it contains a quantity of recurrent amide functional groups capable of ring closure to imides which is smaller than or equal to 5 mol % relative to the sum of the imide functional groups and of the amide functional groups capable of ring closure to imides, which are present, and in that the polymerization functional groups consist essentially of E functional groups.This polyesterimide is preferably free from amide functional groups capable of ring closure to imides.One of the processes for obtaining this polyesterimide constitutes another subject-matter of the invention.Such a polymer is advantageously capable of behaving like a material that is transparent and/or active in nonlinear optics.
    Type: Grant
    Filed: November 14, 1996
    Date of Patent: September 22, 1998
    Assignee: Flamel Technologies
    Inventors: You-Ping Chan, Gilles Tapolsky, Remi Meyrueix, Jean-Pierre Lecomte, Michael Dickens
  • Patent number: 5807967
    Abstract: The present invention is a cyanate resin monomer having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n is an even integer from 6 to 10, inclusive.Another aspect of the invention is an essentially pure cyanate resin mono having the formula:NCO--CH.sub.2 --(CF.sub.2).sub.n --CH.sub.2 --OCNwhere n=3, 4, 6, 8, or 10. Another aspect of the invention is a prepolymer made by the process of heating a monomer of the invention to a conversion below the gel point. Another aspect of the invention is a method for depositing an interlevel dielectric resin on an integrated circuit, having the steps: (a) coating the integrated circuit with a thin film of a prepolymer made by the process of heating a monomer of the invention to below the gel point, and (b) curing the prepolymer to at least the gel point. Another aspect of the invention is a low dielectric thermoset polymer resin made from these monomers.
    Type: Grant
    Filed: March 21, 1996
    Date of Patent: September 15, 1998
    Assignee: The United States of America as represented by the Secretary of the Navy
    Inventors: Arthur W. Snow, Leonard J. Buckley
  • Patent number: 5789513
    Abstract: A coating composition comprising an alkyd or urethane resin and a polyfluorourethane of Formula II(R.sub.f --X--O--CO--NH).sub.m --A--(NH--CO--O--R).sub.(p-m) IIwhereinR.sub.f is a C.sub.2 -C.sub.20 linear or branched fluorocarbon,X is --(CH.sub.2).sub.n --, --(CH.sub.2).sub.g SO.sub.z (CH.sub.2).sub.t --, or --SO.sub.2 N(R.sub.1)CH.sub.2 CH.sub.2 --wherein n is 1 to about 20; g and t are each independently 1 to about 3; z is 0, 1 or 2; and R.sub.1 is an alkyl of 1 to about 4 carbon atoms;A is an aliphatic, cycloaliphatic, aromatic, or heterocyclic radical;R is a C.sub.3 -C.sub.20 linear, branched, or cyclic aliphatic group containing at least one ethylenically unsaturated double bond and optionally at least one phenyl or phenyl substituted with C.sub.1 -C.sub.6 alkyl or halogen;p is 2 to 3; andm is from about 0.8 to about 1.25 when p is 2, and m is from about 1 to about (p-1) when p is greater than 2 is disclosed.
    Type: Grant
    Filed: February 26, 1997
    Date of Patent: August 4, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventor: Jack Robert Kirchner
  • Patent number: 5783657
    Abstract: A low molecular weight, ester-terminated polyamide may be blended with a liquid hydrocarbon to form a transparent composition having gel consistency. The ester-terminated polyamide is prepared by reacting "x" equivalents of dicarboxylic acid wherein at least 50% of those equivalents are from polymerized fatty acid, "y" equivalents of diamine such as ethylene diamine, and "z" equivalents of monoalcohol having at least 4 carbon atoms. The stoichiometry of the reaction mixture is such that 0.9.ltoreq.{x/(y+z)}.ltoreq.1.1 and 0.1.ltoreq.{z/(y+z)}.ltoreq.0.7. The reactants are heated until they reach reaction equilibrium. The gel contains about 5-50% ester-terminated polyamide, with the remainder preferably being pure hydrocarbon. The gels are useful in formulating personal care products and other articles wherein some degree of gel-like or self-supporting consistency is desired.
    Type: Grant
    Filed: October 18, 1996
    Date of Patent: July 21, 1998
    Assignee: Union Camp Corporation
    Inventors: Mark S. Pavlin, Richard C. MacQueen
  • Patent number: 5780575
    Abstract: This invention relates to a thermally stable polyester, comprising:a polyester resin prepared by adding a dicarboxylic acid to a glycol compound, said dicarboxylic acid selected from the group consisting of aliphatic dicarboxylic acids having a total of from 3 to 16 carbon atoms, alicyclic dicarboxylic acids having 7 to 12 carbon atoms, aromatic dicarboxylic acids containing a total of from 8 to 16 carbon atoms, and combinations thereof, and wherein said glycol is selected from the group consisting of glycols having from 2 to 12 carbon atoms, glycol ethers having from 4 to 12 carbon atoms, and combinations thereof,said polyester resin having been prepared in the presence of a catalyst system consisting essentially of one or more antimony compounds which is not reacted with .alpha.-hydroxy carboxylic acids, .alpha.,.beta.-dicarboxylic acids or derivatives thereof.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: July 14, 1998
    Assignee: Eastman Chemical Company
    Inventors: Andrew Edwin Brink, Wayne Payton Pruett, Clinton Cherry, Kay Hunt Shackelford
  • Patent number: 5780581
    Abstract: An adhesive is provided for bonding cyanate ester composite parts together which is also plateable with metal once chemically etched. The adhesive comprises a polymeric matrix and a filler of cyanate ester polymer. The polymeric matrix comprises at least one polyepoxide resin and a curing agent, while the cyanate ester polymer filler is present in the adhesive as a powder. In practice, the present adhesive is applied to the surface of cyanate ester composite articles to be bonded and is allowed to cure at room temperature. Thereafter, the surface of the assembly is chemically etched and then plated with metal. The present adhesive enable the complete coverage of the cyanate ester composite assembly with the plated metal, including the adhesive bondlines.
    Type: Grant
    Filed: October 27, 1995
    Date of Patent: July 14, 1998
    Assignee: Hughes Aircraft Company
    Inventors: Ralph D. Hermansen, Brian M. Punsly, Wai-Cheng Seetoo
  • Patent number: 5780151
    Abstract: Disclosed is a radiation crosslinkable water-dispersible adhesive composition that is useful in forming paper and plastic articles and other products that can be recycled through a process which includes washing or repulping in aqueous media. The cross-linkable water-dispersible adhesive composition is preferably used as a hot melt adhesive. The cross-linkable water-dispersible adhesive composition is a low molecular weight, branched copolyester containing a sulfomonomer and unsaturated moieties. The radiation crosslinked adhesive composition has more cohesive strength and viscosity than its corresponding uncross-linked adhesive, yet is still water-dispersible during product recycling.
    Type: Grant
    Filed: December 8, 1995
    Date of Patent: July 14, 1998
    Assignee: Eastman Chemical Company
    Inventors: Richard Anthony Miller, Scott Ellery George
  • Patent number: 5766679
    Abstract: Chiral nematic polyesters comprise as alcohol component chiral diol structural units and as acid component dicarboxylic acid residues comprising mesogenic groups. The polyesters are particularly suitable for surface coating.
    Type: Grant
    Filed: August 15, 1997
    Date of Patent: June 16, 1998
    Assignee: BASF Aktiengesellschaft
    Inventors: Karl Siemensmeyer, Frank Meyer, Karl-Heinz Etzbach, Hans R. Kricheldorf, Nicolas Probst
  • Patent number: 5760162
    Abstract: In a process for the preparation of poly-o-hydroxyamides and poly-o-mercaptoamides, a bis-o-aminophenol or a bis-o-aminothiophenol is reacted at a temperature of .ltoreq.0.degree. C. with a mixed dianhydride of a dicarboxylic acid and a sulfonic acid with the following structure:E--SO.sub.2 --O--CO--R*--CO--O--SO.sub.2 --Ewhere E is an (optionally substituted) methyl, phenyl, or naphthyl group and R* is the parent body of the dicarboxylic acid.
    Type: Grant
    Filed: August 27, 1996
    Date of Patent: June 2, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventors: Recai Sezi, Hellmut Ahne, Roland Gestigkeit, Kurt Geibel
  • Patent number: 5760143
    Abstract: An ester-amide block copolymer of the formula (1): ##STR1## wherein R is an aromatic hydrocarbon group with 6-20 carbon atoms and G is a residue of an aliphatic polyester, an aliphatic polycarbonate, an aliphatic polyethercarbonate or a polyorganosiloxane, and having a weight average molecular weight of 30,000-1,000,000. This copolymer is advantageously prepared by polycondensing an activated acyl lactam-terminated aromatic amide of the formula (2) with a diol of the formula (3) by bulk polymerization in a molten state: ##STR2## wherein R and G are the same as defined above.
    Type: Grant
    Filed: November 15, 1995
    Date of Patent: June 2, 1998
    Assignee: Tosoh Corporation
    Inventors: Yuji Kubo, Hiroshi Yamakawa, Isamu Kirikihira, Shinji Shimosato
  • Patent number: 5750635
    Abstract: This invention relates to a thermally stable polyester, comprising:a polyester resin prepared by adding a dicarboxylic acid to a glycol compound, said dicarboxylic acid selected from the group consisting of aliphatic dicarboxylic acids having a total of from 3 to 16 carbon atoms, alicyclic dicarboxylic acids having 7 to 12 carbon atoms, aromatic dicarboxylic acids containing a total of from 8 to 16 carbon atoms, and combinations thereof, and wherein said glycol is selected from the group consisting of glycols having from 2 to 12 carbon atoms, glycol ethers having from 4 to 12 carbon atoms, and combinations thereof,said polyester resin having been prepared in the presence of a catalyst system consisting essentially of one or more antimony compounds which is not reacted with .alpha.-hydroxy carboxylic acids, .alpha.,.beta.-dicarboxylic acids or derivatives thereof.
    Type: Grant
    Filed: December 6, 1996
    Date of Patent: May 12, 1998
    Inventors: Andrew Edwin Brink, Wayne Payton Pruett, Clinton Cherry, Kay Hunt Shackelford
  • Patent number: 5750232
    Abstract: This invention relates to a plastic composite material which comprises:a thermoplastic plastic sheet and, bonded to one side thereof,a thermoplastic spun felt comprising a hot-melt adhesive, to a method of producing it and to its use.
    Type: Grant
    Filed: June 27, 1995
    Date of Patent: May 12, 1998
    Assignee: Elf Atochem Deutschland GmbH
    Inventors: Roland Eugen Steenblock, Joachim Buhrmann
  • Patent number: 5744570
    Abstract: Claimed is a copolyether amide having a melting point in the range of 180.degree. to 260.degree. C., incorporating at least 10 wt. % and not more than 30 wt. % of ethylene oxide groups, and composed of 30 to 60 wt. % of polyamide segments and 70 to 40 wt. % of segments derived from a (cyclo)aliphatic or aromatic dicarboxylic acid or a dimeric fatty acid and a polyoxyalkylene diamine derived from a polyoxyalkylene group having a molecular weight of 600 to 6000 and an atomic ratio of carbon to oxygen of 2.0 to 4.3. Also claimed is a non-porous, waterproof film having a water vapour permeability of at least 1000 g/m.sup.2 day determined at 30.degree. C. and 50% RH in accordance with ASTM E96-66 which is based on a the use of these films in rainwear, shoes, tents, chairs, as mattress covers and understating, for medical purpose garments, and for the manufacture of dressings.
    Type: Grant
    Filed: August 16, 1996
    Date of Patent: April 28, 1998
    Assignee: Akzo Nobel NV
    Inventor: Bert Gebben
  • Patent number: 5741602
    Abstract: A heat-curable, epoxy-free coating composition comprises a dry blend of at least two different binder resins, each binder resin comprising of (a) a carboxyl-terminated polyester resin having an acid value from 20 to 200 mg KOH/g and a glass transition temperature of at least 40.degree. C., and (b) a .beta.-hydroxylalkylamide with at least two .beta.-hydroxylalkylamide groups per molecule; the at least two different binder resins differing in functionality, or in other words in the number of carboxyl and/or .beta.-hydroxylalkylamide groups per binder resin molecule. Along with the binder resins, the coating composition optionally includes further additives that are typical for the processing and use of powder coatings.
    Type: Grant
    Filed: August 23, 1995
    Date of Patent: April 21, 1998
    Assignee: EMS-Inventa AG
    Inventors: Manfred Hoppe, Andreas Kaplan, Rene Gisler
  • Patent number: 5731389
    Abstract: Disclosed are blends of polyesteramides and polyester resins, optionally with polycarbonates, as well as methods for preparing said blends thereof. Preferred polyesteramides are those comprising amide units of formula (I): ##STR1## and ester units of formula (II): ##STR2## wherein the ratio of (I) to (II) is at least 1:1, and more preferably wherein at least 80% of the units of formula (I) are separated by at least one of the units of formula (II).
    Type: Grant
    Filed: April 24, 1996
    Date of Patent: March 24, 1998
    Assignee: General Electric Company
    Inventors: Christian Maria Emile Bailly, Bret Chisholm, Rene de Jongh, Gerrit de Wit
  • Patent number: 5731095
    Abstract: A water-soluble or water-dispersible fluorine-containing dendritic polymer surfactant having at least one terminal fluorocarbon moiety and at least one terminal anionic moiety, and which is suitable for use in preparing protective coating compositions is disclosed. The water-soluble or water-dispersible fluorine-containing dendritic polymer surfactants are represented by the general formula: ##STR1## where D represents a dendritic polymer, R.sub.F represents a fluorocarbon containing moiety, A.sup.- represents an anionic containing moiety, C.sup.+ represents a cation, T represents a terminal group of the dendritic polymer which has not been functionalized with a fluorocarbon or anionic moiety, n and m are at least each at least one, and the sum of n+m+q is the total number of terminal groups on the dendritic polymer. Also disclosed is a coating composition capable of forming a highly crosslinked, non-stick, protective coating.
    Type: Grant
    Filed: October 23, 1996
    Date of Patent: March 24, 1998
    Assignee: Oxazogen, Inc.
    Inventors: Larry A. Milco, Donald A. Tomalia
  • Patent number: 5728671
    Abstract: Oligomeric or polymeric substituted or unsubstituted ethylene terephthalate esters comprising fluorescent whitening groups useful as soil release agents in laundry detergent compositions are described. The soil release agents of the present invention are especially suitable for use with polyester and polyester-blended fabric.
    Type: Grant
    Filed: December 21, 1995
    Date of Patent: March 17, 1998
    Assignee: The Procter & Gamble Company
    Inventors: Robert Henry Rohrbaugh, Eugene Paul Gosselink
  • Patent number: 5726279
    Abstract: In a process for the preparation of poly-o-hydroxyamides and poly-o-mercaptoamides, a bis-o-aminophenol or a bis-o-aminothiophenol is reacted with a dicarboxylic acid derivative of the following structure: ##STR1## with D=O, S, or NH and where R* is the parent body of the dicarboxylic acid and the groups R.sup.1 through R.sup.4 are H, F, CH.sub.3, or CF.sub.3 (with a maximum of two CH.sub.3 or CF.sub.3 groups).
    Type: Grant
    Filed: August 29, 1996
    Date of Patent: March 10, 1998
    Assignee: Siemens Aktiengesellschaft
    Inventors: Recai Sezi, Hellmut Ahne
  • Patent number: 5723562
    Abstract: Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.
    Type: Grant
    Filed: December 5, 1996
    Date of Patent: March 3, 1998
    Assignee: Elf Atochem North America, Inc.
    Inventor: Daryl L. Stein
  • Patent number: 5720950
    Abstract: The present invention concerns a method for treating fibrotic conditions by administration of an effective amount of an antifibrotic agent. The antifibrotic agent is preferably a proline analog, such as cis-4-hydroxy-L-proline (cHyp). The antifibrotic agent is operatively linked to a monomer or a polymer, with or without a linking compound, e.g., lysine. Intravenous administration is preferred. The present method facilitates the delivery and release of the antifibrotic agent to inhibit collagen accumulation and thereby to treat fibrosis where collagen metabolism is implicated. A reduced quantity of the antifibrotic agent and a corresponding reduction in the potential for toxicity resulting from prolonged administration thereof may be realized.
    Type: Grant
    Filed: June 15, 1994
    Date of Patent: February 24, 1998
    Assignee: University of Medicine & Dentistry of New Jersey
    Inventors: George J. Poiani, David J. Riley, Wei-Chi Liao, Joachim Kahn, Keria Fiorella Gean
  • Patent number: 5719256
    Abstract: The invention provides a novel preparation process of a polycondensation type polymer, an excellent polymer which is represented by lactic acid and the preparation process of the polymer, a polycondensation agent used for the preparation process, and an intermediate. Specifically, the invention provides a preparation process of the polycondensation type polymer, for example, polyamide, polyimide, polythioester and polyester, comprising bonding a carboxyl group comprising compound with an active hydrogen group comprising compound in the presence of haloiminium salt. The invention provides excellent polylactic acid having a controlled D/L-isomer ratio in the repeating structural units and preparation process of polylactic acid, and further provides a haloiminium salt compound used for the preparation process and an intermediate compound of acid chloride.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: February 17, 1998
    Assignee: Mitsu Toatsu Chemicals, Inc.
    Inventors: Shoji Tamai, Yukiko Mori, Kenichi Goto, Katsuji Watanabe, Osamu Kohgo, Kotaro Shimizu, Toshiyuki Kataoka, Takashi Kuroki, Wataru Yamashita, Hideki Mizuta, Teruyuki Nagata
  • Patent number: 5710235
    Abstract: An olefinic-terminated polyalkadiene that includes carboxy ester linking groups and at least one nascent secondary hydroxyl group that is capped with a monoisocyanate. This polyalkadiene can be made by reacting a hydroxyl-terminated polyalkadiene with a saturated cyclic acid anhydride to form a carboxylic acid-terminated polyalkadiene, reacting the carboxylic acid-terminated polyalkadiene with an olefinic monoepoxide to form an olefinic-terminated polyalkadiene, then reacting the olefinic-terminated polyalkadiene with a monoisocyanate.
    Type: Grant
    Filed: December 11, 1995
    Date of Patent: January 20, 1998
    Assignee: Lord Corporation
    Inventors: Kirk Joseph Abbey, Ian Christopher Quarmby
  • Patent number: 5709916
    Abstract: A loose tube for an optical fiber comprising a polybutylene terephthalate. The polybutylene terephthalate has a terminal carboxyl group concentration of 10 eq./10.sup.6 g.multidot.polymer or less and an intrinsic viscosity ?.eta.!, measured at 25.degree. C. in orthochlorophenol, of 0.9 to 1.4 dl/g.
    Type: Grant
    Filed: July 29, 1996
    Date of Patent: January 20, 1998
    Assignee: Teijin Limited
    Inventors: Noriyuki Akagi, Hiroki Nagano, Masami Umeda, Naonobu Tadokoro, Kazumoto Miyajima
  • Patent number: 5710210
    Abstract: Novel functionalized peroxides which may be used as crosslinking, grafting and curing agents, initiators for polymerization reactions and as monomers for condensation polymerizations to form peroxy-containing polymers, which in turn can be used to prepare block and graft copolymers, have the following Formula I: ##STR1## R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5, R.sup.6, R.sup.7, X, Y.sup.1, Y.sup.2, Y.sup.3, Z.sup.1, Z.sup.2, x, y and z are as defined in the Summary of the Invention. The compounds of Formula I may be prepared by reacting hydroxy-containing tertiary hydroperoxides with diacid halides, phosgene, dichloroformates, diisocyanates, anhydrides and lactones to form the functionalized peroxides. These reaction products may be further reacted, if desired, with dialcohols, diamines, aminoalcohols, epoxides, epoxy alcohols, epoxy amines, diacid halides, dichloroformates and diisocyanates to form additional functionalized peroxides.
    Type: Grant
    Filed: June 6, 1995
    Date of Patent: January 20, 1998
    Assignee: Elf Atochem North America, Inc.
    Inventor: Daryl L. Stein
  • Patent number: 5708122
    Abstract: Poly(ester-imides) containing t-butylhydroquinone and trimellitic anhydride as part of the repeat units, as well as other monomers, are useful as molding resins. The polymers have a high glass transition temperature and are particularly useful in applications requiring good wear resistance.
    Type: Grant
    Filed: April 19, 1996
    Date of Patent: January 13, 1998
    Assignee: E. I. Du Pont de Nemours and Company
    Inventor: Robert Ralph Luise
  • Patent number: 5705603
    Abstract: The invention relates to reaction products of polyetheramines with polymers containing dicarboxylic anhydride groups, which contain 20-80, preferably 40-60, mol % of bivalent structural units A and/or C and, if required, B ##STR1## in which R.sup.1 and R.sup.2, independently of one another, are hydrogen or methyl,a and b are equal to zero or one and a+b is equal to one,Y is X or NRR.sup.3,X is --OH, --O--C.sub.1-30 -alkyl, NR.sup.3 R.sup.4 or --O.sup..crclbar. N.sup..sym. R.sup.3 R.sup.4,R.sup.3 and R.sup.4, independently of one another, are hydrogen, C.sub.6 -C.sub.40 -alkyl or R,R is ##STR2## with the proviso that at least 1 mol % of the anhydride groups bonded to the polymer have reacted with a polyetheramine,Z is C.sub.2 -C.sub.4 -alkyl,n is a number from 1 to 1000,R.sup.5 is hydrogen, C.sub.1 -C.sub.30 -alkyl, C.sub.5 -C.sub.12 -cycloalkyl or C.sub.6 -C.sub.30 -aryl andR.sup.6 is hydrogen or C.sub.1 -C.sub.
    Type: Grant
    Filed: June 22, 1995
    Date of Patent: January 6, 1998
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Matthias Krull, Michael Feustel, Erdmann Mielcke
  • Patent number: 5705598
    Abstract: High performance polyester sulfone oligomers are prepared for aerospace applications by condensing mono- or difunctional crosslinkable end caps (i.e. unsaturated hydrocarbons having one or two crosslinking sites) with dicarboxylic acid halides and dialcobols (i.e. diols). Multidimensional oligomers have an aromatic hub from which the polyester chains radiate. Blends of the linear and multidimensional oligomers can be made using compatible, non-crosslinking polymers. Prepregs and composites are formed from the oligomers or blends.
    Type: Grant
    Filed: December 23, 1987
    Date of Patent: January 6, 1998
    Assignee: The Boeing Company
    Inventors: Hyman R. Lubowitz, Clyde H. Sheppard
  • Patent number: 5703177
    Abstract: This invention relates to biologically degradable, partially crystalline block copolyester-polyamides comprising at least two chemically differently structured segments of which at least one is a polyester (PES) block or a copolyester (coPES) block, preferably with a number average molecular mass of 340 to 10,000 g/mole, and at least one is a polyamide (PA) block or a copolyamide (coPA) block, preferably with a number average molecular mass of 400 to 3,000 g/mole. In addition, copolyester-amide (coPEA) blocks can be employed, preferably with a number average molecular mass of 500 to 5,000 g/mole. The invention also relates to a polycondensation process for the manufacture of these partially crystalline block copolyester-polyamides. The block copolymers described are useful for the manufacture of fibers, foils, molded articles and hot melt-type adhesives. Molded components manufactured from the copolymers in accordance with the invention are biologically degradable and are capable of being composted.
    Type: Grant
    Filed: December 15, 1995
    Date of Patent: December 30, 1997
    Assignee: Ems-Inventa AG
    Inventor: Heinz Hoff
  • Patent number: 5679761
    Abstract: The polymers according to the invention with repeating succinyl units additionally contain iminodisuccinate units.
    Type: Grant
    Filed: August 15, 1995
    Date of Patent: October 21, 1997
    Assignee: Bayer AG
    Inventors: Lutz Heuer, Winfried Joentgen, Torsten Groth, Hans-Joachim Traenckner, Nikolaus Muller, Hermann Uhr, Klaus-Peter Heise, Karl-Hermann Brucher, Joachim-Reinhard Wesener, Ute Wollborn, Hans-Georg Pirkl, Thomas Menzel, Ulrich Liesenfelder, Paul Wagner
  • Patent number: 5668236
    Abstract: The present invention relates to a hydrophilic highly swellable hydrogel based on (co)polymerized hydrophilic monomers or based on graft (co)polymers, characterized in that it is post-crosslinked with a polyamidoamine in an aqueous medium.
    Type: Grant
    Filed: April 29, 1996
    Date of Patent: September 16, 1997
    Assignee: Cassella Aktiengesellschaft
    Inventors: Fritz Engelhardt, Ulrich Riegel, Uwe Stuven, Helmut Klotzsche, Gustav Remmel
  • Patent number: 5668243
    Abstract: This invention relates to a polyester resin prepared by adding one or more dicarboxylic acid components to one or more glycol components containing 1,4-cyclohexanedimethanol equalling 100 mole %, the polyester resin having been prepared in the presence of a catalyst/stabilizer system consisting essentially of antimony compounds and phosphorous compounds and compounds selected from the group consisting essentially of zinc compounds, gallium compounds, and silicon compounds.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: September 16, 1997
    Assignee: Eastman Chemical Company
    Inventors: Cheuk Chung Yau, Leslie Shane Moody
  • Patent number: 5665151
    Abstract: The present invention provides inks which contain a near infrared fluorophoric compound incorporated into a water-dissipatible polyester backbone. The inks of the present invention are preferably colorless or "invisible" but could be made slightly colored if desirable. Specifically, the inks of the present invention comprise:A. between about 1 and 10 weight percent of at least one water-dissipatable polyester having from about 0.1 ppm by weight to about 10% by weight of a thermally stable near infrared fluorophoric compound copolymerized therein;B. between about 5 and 75 weight percent of at least aliphatic humectant;C. between about 0 and 15 weight percent of at least one lower aliphatic alcohol of no more than 3 carbon atoms;D. water and optionally up to about 2 weight percent of one or more additives;wherein the weight percentages of components A-D equal 100%.
    Type: Grant
    Filed: November 18, 1996
    Date of Patent: September 9, 1997
    Assignee: Eastman Chemical Company
    Inventors: Nelson Zamora Escano, James John Krutak, Sr.
  • Patent number: 5654367
    Abstract: An alternating copolymer comprising a repeating unit of the formula:--Z--(X--Y).sub.n -- (I)wherein n is at least 2, X is O, S, Se or Te, and Y and Z are independently an aromatic or substituted aromatic group, and at least one other repeating unit, which is useful as a photosensitive material used in a spatial light modulator.
    Type: Grant
    Filed: May 26, 1995
    Date of Patent: August 5, 1997
    Assignee: Matsushita Electric Industrial Co., Ltd.
    Inventors: Akio Takimoto, Hirofumi Wakemoto, Eiichiro Tanaka, Masanori Watanabe, Junko Asayama, Hisahito Ogawa, Shigehiro Sato, Fumiko Yokotani
  • Patent number: 5652326
    Abstract: A polyetheresteramide having good heat resistance, permanent antistatic property and superior compatibility with thermoplastic resins and a resin composition containing of the polyetheresteramide are disclosed, wherein the polyetherester-amide consists essentially of a polyamide oligomer with carboxylic chain ends having a number average molecular weight between 200 and 5,000 and a bisphenol compound with oxyalkylene units having a number average molecular weight between 300 and 3,000. Antistatic resin compositions with good antistatic property and heat resistance are obtained from compositions comprising 3 to 40% by weight of the polyetheresteramide and 60 to 97% by weight of thermoplastic resins. The antistatic resin compositions can contain as compatibilizers vinyl polymers having functional groups such as carboxyl and epoxy groups or block polymers containing polyolefin blocks and aromatic vinyl polymer blocks.
    Type: Grant
    Filed: March 1, 1994
    Date of Patent: July 29, 1997
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Yasuhiro Ueda, Eiichi Senda, Yoshitsugu Takai, Tokiko Kokubu, Toshiaki Okamoto, Eiji Ichihara
  • Patent number: 5652320
    Abstract: The present invention provides an novel polymer having 1-2,000 equivalents of an N-sulfoamino group/10.sup.6 g of weight of the polymer.The polymer has excellent dispersibility of inorganic fine particles, hygroscopicity, and dye-affinity. The polymer provides a binder resin in which a magnetic or non-magnetic metal or metal oxide can highly be dispersed. The polymer also provides a magnetic recording medium which is excellent in electromagnetic conversion characteristic, surface smoothness, adhesion to non-magnetic substrates, and durability. The polymer provides a magnetic recording medium with improved travelling, travelling durability, signal-to-noise ratio, and drop-out. The polymer also provides a polyester fiber which has a high fiber strength and an excellent hygroscopicity and can be colored with cationic dyes.
    Type: Grant
    Filed: October 3, 1995
    Date of Patent: July 29, 1997
    Assignee: Sanyo Chemical Industries, Ltd.
    Inventors: Takashi Takemoto, Toshiro Shimada, Hiroshi Itayama
  • Patent number: 5650481
    Abstract: This invention relates to a polyester resin prepared by adding one or more dicarboxylic acid components to one or more glycol components containing 1,4-cyclohexanedimethanol equalling 100 mole %,the polyester resin having been prepared in the presence of a catalyst/stabilizer system consisting essentially of antimony compounds and phosphorous compounds and compounds selected from the group consisting essentially of zinc compounds, gallium compounds, and silicon compounds.
    Type: Grant
    Filed: October 15, 1996
    Date of Patent: July 22, 1997
    Assignee: Eastman Chemical Company
    Inventors: Cheuk Chung Yau, Leslie Shane Moody
  • Patent number: 5648088
    Abstract: The present invention describes aliphatic polyoxaesters containing amines and/or amido groups and blends thereof with other polymers that may be used to produce surgical devices such as sutures, sutures with attached needles, molded devices, and the like. The aliphatic polyoxaesters of the present invention have a first divalent repeating unit of formula I:[O--C(O)--C(R.sub.1)(R.sub.2)--O--(R.sub.3)--O--C(R.sub.1)(R.sub.2)--C(O)-- ]Iand a second repeating unit of the formula:[--O--R.sub.12 --].sub.u, XVIand optionally a third repeating unit with a formula selected from the group consisting of:[--O--R.sub.4 --].sub.A, II[--O--R.sub.5 --C(O)--].sub.B, III([--O--R.sub.5 --C(O)].sub.P --O--).sub.L G XIand combinations thereof wherein R.sub.12 contains an internal amine or internal amide group.
    Type: Grant
    Filed: March 5, 1996
    Date of Patent: July 15, 1997
    Assignee: Ethicon, Inc.
    Inventors: Rao S. Bezwada, Dennis D. Jamiolkowski
  • Patent number: 5646236
    Abstract: Polyesters obtained by reacting from 5 to 50 parts of at least one linear or branched, aliphatic or cycloaliphatic, at least dihydric alcohol, from 2 to 40 parts of at least one at least dibasic, aromatic carboxylic acid, from 0 to 40 parts of at least one 2-alkenyldicarboxylic anhydride, from 10 to 30 parts of at least one at least dibasic, linear or branched, aliphatic carboxylic acid, from 0 to 15 parts of an aliphatic, linear or branched hydroxy acid, from 0 to 15 parts of an aliphatic, linear or branched polyamine having at least one primary and at least one secondary or tertiary amino group, from 0 to 15 parts of a glycidyl ester of a branched, aliphatic monocarboxylic acid or of a glycidyl ether of a branched, aliphatic alcohol, and from 0 to 15 parts of polyhydroxyamine are useful, for example, as additives in coating compositions.
    Type: Grant
    Filed: January 30, 1995
    Date of Patent: July 8, 1997
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Markus A. Schafheutle, Achim Voelker, Susanne Wehner, Gerd Walz, Joachim Zoeller