Sulfonic Acids Or Salts Thereof (i.e., Compounds Containing The Sulfonate Group, -s(=o)(=o)-o- Wherein The Single Bonded Oxygen Is Bonded Directly To Hydrogen, Or To A Group Ia Or Iia Light Metal Or To Substituted Or Unsubstituted Ammonium) Patents (Class 562/30)
  • Patent number: 8178648
    Abstract: A composition of matter comprising a diamine salt and sulfoisophthalic acid in a ratio other than one salt to one acid and a process for producing a diamine salt of sulfoisophthalic acid comprising generating a sulfoisophthalic acid and charging the sulfoisophthalic acid with diamine.
    Type: Grant
    Filed: November 6, 2008
    Date of Patent: May 15, 2012
    Assignee: Future Fuel Chemical Company
    Inventors: Tracy A. Torno, Candice Stalker, Maria Adriana Sousa-Ragle, Todd Coleman, Ronnie Hampton
  • Patent number: 8114570
    Abstract: Photoacid generators generate sulfonic acids of formula (1a) upon exposure to high-energy radiation. ROC(?O)R1—COOCH2CF2SO3?H+??(1a) RO is OH or C1-C20 organoxy, R1 is a divalent C1-C20 aliphatic group or forms a cyclic structure with RO. The photoacid generators are compatible with resins and can control acid diffusion and are thus suited for use in chemically amplified resist compositions.
    Type: Grant
    Filed: March 24, 2009
    Date of Patent: February 14, 2012
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Youichi Ohsawa, Takeshi Kinsho, Takeru Watanabe, Koji Hasegawa, Masaki Ohashi
  • Publication number: 20120034464
    Abstract: A substance includes diamond particles having a maximum linear dimension of less than about 1 ?m and an organic compound attached to surfaces of the diamond particles. The organic compound may include a surfactant or a polymer. A method of forming a substance includes exposing diamond particles to an organic compound, and exposing the diamond particles in the presence of the organic compound to ultrasonic energy. The diamond particles may have a maximum linear dimension of less than about 1 ?m. A composition includes a liquid, a plurality of diamond nanoparticles dispersed within the liquid, and an organic compound attached to surfaces of the diamond nanoparticles. A method includes mixing a plurality of diamond particles with a solution comprising a liquid solvent and an organic compound, and exposing the mixture including the plurality of diamond nanoparticles and the solution to ultrasonic energy.
    Type: Application
    Filed: October 18, 2011
    Publication date: February 9, 2012
    Applicant: BAKER HUGHES INCORPORATED
    Inventors: Soma Chakraborty, Gaurav Agrawal, Anthony A. DiGiovanni
  • Publication number: 20120020881
    Abstract: This invention relates to novel compounds suitable for labeling by positron emitting isotopes, such as 18F, 11C, 13N and 15O, through appropriate labeling reagents, such as 18F reagents and methods of preparing such a compound, compositions comprising such compounds, kits comprising such compounds or compositions and uses of such compounds, compositions or kits for diagnostic imaging by positron emission tomography (PET).
    Type: Application
    Filed: December 4, 2009
    Publication date: January 26, 2012
    Applicant: BAYER SCHERING PHARMA AKTIENGESELLSCHAFT
    Inventors: Lutz Lehmann, Timo Stellfeld, Keith Graham, Jessica Becaud, Linjing Mu
  • Publication number: 20120009521
    Abstract: A resist composition including: a base component (A) which exhibits changed solubility in an alkali developing solution under action of acid; and an acid-generator component (B) which generates acid upon exposure, wherein said acid-generator component (B) comprises an acid generator (B1) including a compound represented by general formula (b1-11) shown below: wherein R7? to R9? each independently represent an aryl group or an alkyl group, wherein two of R7? to R9? may be bonded to each other to form a ring with the sulfur atom, and at least one of R7? to R9? represents a substituted aryl group having a group represented by general formula (I) shown below as a substituent; X? represents an anion; and Rf represents a fluorinated alkyl group.
    Type: Application
    Filed: September 15, 2011
    Publication date: January 12, 2012
    Applicant: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Akiya Kawaue, Yoshiyuki Utsumi, Takehiro Seshimo, Tsuyoshi Nakamura, Naoto Motoike, Hiroaki Shimizu, Kensuke Matsuzawa, Hideo Hada
  • Publication number: 20120010423
    Abstract: A process for preparing a detergent alcohol mixture comprising the steps of providing one or more poly-branched poly-olefins, wherein the poly-branched poly-olefins must contain one non-branched terminal olefin and one or more additional branched olefins in the molecule; hydroformylating said poly-branched poly-olefins to produce a poly-branched olefin containing aldehyde product with one or more olefins or mixture thereof; reducing the aldehyde product of step (b) in the presence of hydrogen and a hydrogenation catalyst to form a poly-branched detergent alcohol mixture; and removing said poly-branched alcohol mixture from said catalyst and branched aldehydes, alcohols and surfactants produced from the products of this process.
    Type: Application
    Filed: September 20, 2011
    Publication date: January 12, 2012
    Inventors: Jeffrey John Scheibel, Robert Edward Shumate
  • Publication number: 20110288055
    Abstract: This invention relates to pharmaceutically acceptable amphiphilic antioxidant compounds, compositions and dosage forms comprising said compounds, and methods and uses reliant on said compounds. The exemplified compounds are all mitoquinone derivatives, being methoxyphenyl alkyl triphenylphosphonium or methoxy dioxocyclohexadiene alkyl triphenylphosphonium derivatives. The compounds, compositions, dosage forms, uses and methods are useful in, for example, the treatment of diseases or conditions associated with oxidative stress.
    Type: Application
    Filed: January 5, 2011
    Publication date: November 24, 2011
    Inventors: Kenneth Martin Taylor, Robin A.J. Smith
  • Patent number: 8034533
    Abstract: Fluorine-free photoacid generators and photoresist compositions containing fluorine-free photoacid generators are enabled as alternatives to PFOS/PFAS photoacid generator-containing photoresists. The photoacid generators are characterized by the presence of a fluorine-free heteroaromatic sulfonate anionic component. The photoacid generators preferably contain an onium cationic component, more preferably a sulfonium cationic component. The photoresist compositions preferably contain an acid sensitive imaging polymer. The compositions are especially useful for forming material patterns using 193 nm (ArF) imaging radiation.
    Type: Grant
    Filed: January 16, 2008
    Date of Patent: October 11, 2011
    Assignee: International Business Machines Corporation
    Inventors: Sen Liu, Pushkara R. Varanasi
  • Publication number: 20110215274
    Abstract: Ferroelectric liquid crystal compositions including organic ion pair compounds wherein image sticking is reduced or eliminated. Use of the ferroelectric liquid crystal compositions in a ferroelectric liquid crystal display device allows for rapid image refresh rates without required a DC-balancing algorithm. The organic ion pair compounds provide electrical resistivity values for the compositions that result in reduced image sticking when the compositions are used in FLC display devices.
    Type: Application
    Filed: January 14, 2011
    Publication date: September 8, 2011
    Inventors: Cory Pecinovsky, William Thurmes, Brion C. Koprowski
  • Patent number: 8004078
    Abstract: Provided is an adhesive composition for a semiconductor device. For example, the adhesive composition comprises a binder resin and a silicon carbide filler. The silicon carbide filler has relatively high thermal conductivity and a relatively low coefficient of thermal expansion (CTE). Accordingly, the adhesive composition containing the silicon carbide filler exhibits improved heat dissipation performance and electrical performance due to high thermal conductivity and shows inhibition of delamination or cracking of semiconductor devices due to low CTE. The silicon carbide has high thermal conductivity, but is electrically non-conductive. Therefore, an electrically conductive adhesive can be obtained by additional incorporation of a silver (Ag) filler into the binder resin.
    Type: Grant
    Filed: March 17, 2009
    Date of Patent: August 23, 2011
    Assignee: Amkor Technology, Inc.
    Inventors: Jae Kyu Song, Bong Chan Kim, Min Yoo
  • Publication number: 20110172138
    Abstract: One subject of the invention is a dimethyl disulphide in which the content of biocarbon is at least 1%. Another subject of the invention is processes for preparing this dimethyl disulphide. Yet another subject of the invention is the use of such a dimethyl disulphide for the manufacture of methanesulphonic acid.
    Type: Application
    Filed: August 18, 2009
    Publication date: July 14, 2011
    Applicant: ARKEMA FRANCE
    Inventors: Christian Forquy, Georges Fremy
  • Publication number: 20110159433
    Abstract: Provided are a radiation-sensitive composition including a compound (P) having a partial structure (A) having an ionic structural site and capable of decomposing upon irradiation with an actinic ray or radiation to generate an acid and a partial structure (B) having at least one phenolic hydroxyl group, a part or all of hydrogen atoms of the hydroxyl group or groups each being protected by a group capable of leaving by the action of an acid, wherein the ionic structural site of the partial structure (A) contained in the compound (P) is a structure capable of generating an acid anion in the compound (P) upon irradiation with an actinic ray or radiation; a pattern-forming method using the same; and a resin which is used in the composition.
    Type: Application
    Filed: August 26, 2009
    Publication date: June 30, 2011
    Applicant: FUJIFILM CORPORATION
    Inventors: Hidenori Takahashi, Tomotaka Tsuchimura, Toru Tsuchihashi, Katsuhiro Yamashita, Naoyuki Nishikawa
  • Publication number: 20110152571
    Abstract: The present invention is directed to an isomerized alpha olefin sulfonate and a method of making the same wherein the isomerized alpha olefin sulfonate is derived from sulfonating an isomerized alpha olefin with sulfur trioxide in the presence of air thereby producing an isomerized alpha olefin sulfonic acid, wherein the isomerized alpha olefin is derived from the isomerization of C12-C20 normal alpha olefins; and neutralizing the isomerized alpha olefin sulfonic acid with a source of an alkali metal or ammonium or substituted ammonium ion.
    Type: Application
    Filed: December 8, 2010
    Publication date: June 23, 2011
    Inventors: Curtis Bay Campbell, Andrew J. Howes
  • Publication number: 20110144064
    Abstract: Provided herein are methods of decreasing a level of kynurenic acid in a cell and of treating a pathophysiological condition in a subject associated with an increase in kynurenic acid in a subject. In these methods the inhibitory action of dicarboxylic acids or derivatives or analogs thereof are effective to inhibit activity of kynurenine aminotransferase II. Also provided is a method of screening for potential inhibitory compounds for kynurenine aminotransferase II. The dicarboxylic acids or derivatives or analogs thereof may have the structural formula, where R1 is H, NH2 or NHCH3, R2 is H or CH3, n is 0 to 14, and X is —COOH, CH2OH, —PO3H2, —SO3H, or —SO3H; or a pharmacologically acceptable salt.
    Type: Application
    Filed: November 30, 2006
    Publication date: June 16, 2011
    Inventors: Robert Schwarcz, Roberto Pellicciari, Timothy Gately
  • Publication number: 20110136723
    Abstract: A compound of the general formula X-[Q-W—(CH?CH)n—(CH2)2-L]m (I) in which X represents a polymer; Q represents a linking group; W represents an electron-withdrawing group; n represents 0 or an integer of from 1 to 4; L represents a leaving group; and m represent an integer of from 1 to 8. The compounds find use in the conjugation of biological molecules.
    Type: Application
    Filed: July 17, 2009
    Publication date: June 9, 2011
    Applicant: POLYTHERICS LIMITED
    Inventor: Antony Godwin
  • Patent number: 7956214
    Abstract: Provided are processes for the synthesis of aniline derivatives, specifically certain aniline derivatives which have activity as thyroid receptor ligands.
    Type: Grant
    Filed: June 15, 2009
    Date of Patent: June 7, 2011
    Assignees: Karo Bio AB, Bristol-Myers Squibb Company
    Inventors: Ramakrishnan Chidambaram, Joydeep Kant, Raymond E. Weaver, Jurong Yu, Arun Ghosh
  • Publication number: 20110027716
    Abstract: According to one embodiment, an actinic-ray- or radiation-sensitive resin composition includes any of the compounds (A) of general formula (I) below that when exposed to actinic rays or radiation, generates an acid and a resin (B) whose rate of dissolution into an alkali developer is increased by the action of an acid. (The characters used in general formula (I) have the meanings mentioned in the description.
    Type: Application
    Filed: July 9, 2010
    Publication date: February 3, 2011
    Applicant: FUJIFILM CORPORATION
    Inventors: Shuhei YAMAGUCHI, Akinori Shibuya
  • Publication number: 20110021812
    Abstract: A process for preparing solid alkaline earth metal salts of secondary paraffinsulphonic acids is claimed. This process comprises converting an aqueous solution of a secondary paraffinsulphonic acid and an alkaline earth metal hydroxide into solid form by spray drying.
    Type: Application
    Filed: March 4, 2009
    Publication date: January 27, 2011
    Applicant: CLARIANT FINANCE (BVI) LIMITED
    Inventors: Gerd Reinhardt, Peter Naumann, Georg Borchers, Mathias Groeschen
  • Publication number: 20110017954
    Abstract: (1) A vinyl sulfonic acid, having a double bond content of 95 wt. % or more, and (i) a sodium (Na) content of 1 ppm or less, and (ii) a content of at least one metal selected from the group consisting of alkali earth metal and first row transition metal of 1 ppm or less. Alternatively, (2) a vinyl sulfonic acid, having a double bond content of 95 wt. % or more, and (i) a sodium (Na) content of 100 ppb or less, and (ii) a content of at least one metal selected from the group consisting of alkali earth metal and first row transition metal of 100 ppb or less. Further, a homopolymer or copolymer thereof, a production method thereof, or a thin-film distillation apparatus suited for the production thereof.
    Type: Application
    Filed: March 27, 2009
    Publication date: January 27, 2011
    Inventors: Hiroshi Akikaze, Takehiko Miyai, Kazuhiko Isshiki
  • Publication number: 20100331228
    Abstract: The present invention relates to the use of alkane sulfonic acid for descaling, and more generally for cleaning vats, casks, and other containers used for the storage, shipping, and handling of meat and early produce, particularly poultry, fruit, and vegetables. The present invention also relates to a composition in gel form including at least one alkane sulfonic acid.
    Type: Application
    Filed: April 28, 2009
    Publication date: December 30, 2010
    Inventors: Didier Juhue, Bernard Monguillon
  • Publication number: 20100313908
    Abstract: The present invention relates to the use of at least one alkanesulfonic acid of formula R—SO3H, in which R represents a saturated, linear or branched, hydrocarbon chain containing 1 to 4 carbon atoms, as agent for cleaning cement, mortar, concrete, lime, laitance and other derived products. The invention also relates to a method of cleaning cement, mortar, concrete, lime, laitance and other derived products using at least one alkanesulfonic acid.
    Type: Application
    Filed: November 30, 2009
    Publication date: December 16, 2010
    Inventors: Jean-Alex Laffitte, Bernard Monguillon
  • Publication number: 20100282467
    Abstract: A process for recovering oil from an oil-bearing formation comprises introducing into said formation an aqueous composition comprising at least one sulfonated derivative of one or more internal olefins, said internal olefins being characterized by having low amounts of tri-substitution on the olefin bond, said sulfonated derivative being obtained by sulfonating a composition comprising internal olefins of the formula: R1R2C?CR3R4 wherein R1, R2, R3 and R4 are the same or different and are hydrogen or straight- or branched-chain, saturated hydrocarbyl groups and the total number of carbon atoms of R1, R2, R3 and R4 is 6 to 44 with the proviso that at least about 96 mole percent of R1 and R3 are straight- or branched-chain, saturated hydrocarbyl groups and at least about 96 mole percent of R2 and R4 are hydrogen.
    Type: Application
    Filed: May 5, 2010
    Publication date: November 11, 2010
    Applicant: Stepan Company
    Inventors: John C. Hutchison, Patrick Shane Wolfe, Thomas Edward Waldman, Ramakrishna Ravikiran
  • Patent number: 7829521
    Abstract: The invention relates to surfactant compositions made from esters or amides of the betaine glycine, produced by reaction of the glycine betaine with a sulphonic acid and an alcohol or a fatty-chain amine derived from vegetable oils. The invention further relates to a cosmetic comprising said surfactant composition, in particular, liquid soap, bath foam, shower gel or shampoo.
    Type: Grant
    Filed: May 3, 2005
    Date of Patent: November 9, 2010
    Assignees: Eiffage Travaux Publics, Ecole Nationale Superieure de Chimie de Rennes
    Inventors: Jean-Pierre Antoine, Jerome Marcilloux, Martine Lefeuvre, Daniel Plusquellec, Thierry Benvegnu, Fabrice Goursaud, Bernard Parant
  • Patent number: 7824918
    Abstract: Novel fluorescent dyes are disclosed for use in analyte detection. In particular, mono- and bis-substituted HPTS dyes and methods of making them are provided.
    Type: Grant
    Filed: August 6, 2008
    Date of Patent: November 2, 2010
    Assignee: Glumetrics, Inc.
    Inventor: Jeff T. Suri
  • Publication number: 20100255419
    Abstract: A positive photosensitive composition comprises a compound capable of generating a specified sulfonic acid upon irradiation with one of an actinic ray and radiation and (B) a resin capable of decomposing under the action of an acid to increase the solubility in an alkali developer.
    Type: Application
    Filed: June 16, 2010
    Publication date: October 7, 2010
    Applicant: FUJIFILM Corporation
    Inventors: Kunihiko KODAMA, Toshiaki Aoai
  • Patent number: 7776111
    Abstract: The invention provides compositions comprising at least one alkylphenol-aldehyde resin (constituent I) and, based on the alkylphenol resin, from 0.005 to 10% by weight of at least one oil-soluble organic ammonium sulfonate (constituent II).
    Type: Grant
    Filed: July 20, 2005
    Date of Patent: August 17, 2010
    Assignee: Clariant Produkte (Deutschland) GmbH
    Inventors: Matthias Krull, Carsten Cohrs, Hildegard Freundl, Stefan Lorenz
  • Publication number: 20100196820
    Abstract: A resist composition including a base component (A) which exhibits changed solubility in an alkali developing solution under action of acid and an acid-generator component (B) which generates acid upon exposure, the acid-generator component (B) including an acid generator (B1) containing a compound having a cation moiety represented by general formula (I) (in the formula, R5 represents a hydrogen atom or an organic group of 1 to 30 carbon atoms which may have a substituent; and Q5 represents a single bond or a divalent linking group).
    Type: Application
    Filed: December 9, 2009
    Publication date: August 5, 2010
    Inventors: Akiya Kawaue, Yoshiyuki Utsumi, Shinichi Hidesaka, Natsuko Maruyama
  • Publication number: 20100197852
    Abstract: The invention provides a compound which is useful in production of a fluoropolymer and easy to be removed from the produced fluoropolymer, a method of producing the compound, and a method of producing a fluoropolymer using the compound. The invention provides a compound which is represented by Rf1—CH2O—CF2—CHF—Rf2—X, wherein Rf1 represents a fluoroalkyl group containing 1 to 5 carbon atoms, Rf2 represents a fluoroalkylene group containing 1 to 3 carbon atoms, X represents —COOM or —SO3M, and M represents one of H, K, Na, and NH4.
    Type: Application
    Filed: July 24, 2008
    Publication date: August 5, 2010
    Applicant: DAIKIN INDUSTRIES, LTD.
    Inventors: Nobuhiko Tsuda, Akinari Sugiyama
  • Patent number: 7695891
    Abstract: A photosensitive composition comprising a compound capable of generating a compound having a specific structure upon irradiation with actinic rays or radiation; a pattern forming method using the photosensitive composition; a compound having a specific structure; and a compound capable of generating a compound having a specific structure upon irradiation with actinic rays or radiation.
    Type: Grant
    Filed: June 21, 2006
    Date of Patent: April 13, 2010
    Assignee: FUJIFILM Corporation
    Inventor: Kenji Wada
  • Publication number: 20100069618
    Abstract: The invention concerns a process for preparing a hybrid organic-inorganic material (HOIM) with phosphorus-containing bridges between the surface of an inorganic substrate containing an element M and one or more organic groups of the covalent M-O-P-R type, said process using, as a precursor for said organic group or groups, at least one organophosphorus acid halide with formula RxP(O)Xy in which x=1 or 2, y=3?x, X being a halogen and R designating at least one organic alkyl, aryl or aryl-alkyl group. Non-exhaustive applications for the hybrid organic-inorganic material obtained by the process of the invention are in the fields of anti-corrosion, lubrication, microelectronics, nanotechnologies, composite materials, heterogeneous catalysis, supported catalysis, depollution and biomedical applications.
    Type: Application
    Filed: July 6, 2007
    Publication date: March 18, 2010
    Applicant: IFP
    Inventors: Renaud Revel, Florence Brodard-Severac, Gilles Guerrero, Hubert Mutin, Alain Forestiere, Alexandra Chaumonnot
  • Publication number: 20100035773
    Abstract: The aim of the present invention is to provide a lubricating oil composition for a hydrodynamic bearing device wherein oil film disruption is suppressed. It is solved by a lubricating oil composition for a hydrodynamic bearing device which comprises a base oil and an oil film disruption inhibitor such as metal sulfonate.
    Type: Application
    Filed: August 6, 2009
    Publication date: February 11, 2010
    Inventors: Katsushi HIRATA, Takanori Shiraishi
  • Patent number: 7659426
    Abstract: The present invention provides a pharmaceutical composition containing, as an active ingredient, a compound that specifically binds to KSRP or a functional fragment thereof, and a screening method for the compound. KSRP is a novel target protein for anticancer agents; a compound capable of regulating the expression and activity of such a protein and a pharmaceutical composition containing it are highly useful for proliferative diseases, particularly as anticancer agents. By providing the novel target protein, the mechanism behind the anticancer effect that has conventionally been unexplainable can be elucidated.
    Type: Grant
    Filed: November 30, 2004
    Date of Patent: February 9, 2010
    Assignee: Reverse Proteomics Research Institute Co., Ltd.
    Inventors: Akito Tanaka, Akira Yamazaki, Takeshi Tsutsumi, Tomohiro Terada, Masayuki Haramura
  • Patent number: 7569324
    Abstract: Sulfonate salts have the formula: R1COOCH2CH2CF2CF2SO3?M+ wherein R1 is alkyl, aryl or hetero-aryl, M+ is a Li, Na, K, ammonium or tetramethylammonium ion. Onium salts, oxime sulfonates and sulfonyloxyimides derived from these salts are effective photoacid generators in chemically amplified resist compositions.
    Type: Grant
    Filed: June 25, 2007
    Date of Patent: August 4, 2009
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Katsuhiro Kobayashi, Youichi Ohsawa, Takeshi Kinsho, Takeru Watanabe
  • Publication number: 20090176963
    Abstract: Provided is a new organic-acid-based catalyst enabling production of a polyhydroxycarboxylic acid by direct dehydration polycondensation of a hydroxycarboxylic acid such as L-lactic acid, specifically, an organic-acid-based catalyst comprising an amine salt of a sulfonic acid or a phosphine salt of a sulfonic acid for production of polyhydroxycarboxylic acids such as poly-L-lactic acid.
    Type: Application
    Filed: June 12, 2007
    Publication date: July 9, 2009
    Inventors: Atsushi Abiko, Hisako Iwahashi
  • Patent number: 7556909
    Abstract: Sulfonate salts have the formula: CF3—CH(OH)—CF2SO3?M+ wherein M+ is a Li, Na, K, ammonium or tetramethylammonium ion. Because of inclusion within the molecule of a hydroxyl group which is a polar group, the sulfonic acids are effective for restraining the length of acid diffusion through hydrogen bond or the like. The photoacid generators that generate these sulfonic acids perform well during the device fabrication process including coating, pre-baking, exposure, post-exposure baking, and developing steps. The photoacid generators are little affected by water left on the wafer during the ArF immersion lithography.
    Type: Grant
    Filed: October 27, 2006
    Date of Patent: July 7, 2009
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Katsuhiro Kobayashi, Youichi Ohsawa, Takeshi Kinsho, Takeru Watanabe, Masaki Ohashi
  • Publication number: 20090137175
    Abstract: The present invention provides aqueous sizing compositions for application to glass fibers as well as polymeric resins reinforced with glass fibers at least partially coated with the aqueous sizing compositions. In some embodiments, sizing compositions of the present invention demonstrate advantageous properties resulting from the presence of an acid-amine component therein.
    Type: Application
    Filed: November 10, 2008
    Publication date: May 28, 2009
    Inventors: Jacobus Hendricus Antonius Van Der Woude, Jacob Cornelius Dijt, John Theo Penning, Ronald Boelman, Johannes Leonardus Tabak
  • Patent number: 7524609
    Abstract: A photosensitive composition, which comprises (A) a compound capable of generating an organic acid represented by formula (I) upon irradiation with actinic ray or radiation: Z—A—X—B—R—(Y)n??(I) wherein Z represents an organic acid group; A represents a divalent linking group; X represents a divalent linking group having a hetero atom; B represents an oxygen atom or —N(Rx)—; Rx represents a hydrogen atom or a monovalent organic group; R represents a monovalent organic group substituted with Y, and when B represents —N(Rx)—, R and Rx may be bonded to each other to form a cyclic structure; Y represents —COOH or —CHO, and when a plurality of Y's are present, the plurality of Y's may be the same or different; and n represents an integer of from 1 to 3.
    Type: Grant
    Filed: March 9, 2007
    Date of Patent: April 28, 2009
    Assignee: FUJIFILM Corporation
    Inventor: Kenji Wada
  • Publication number: 20090104322
    Abstract: By using protonic acids, diesters of dicarbonic acid may be stabilized against thermal and chemical decomposition over a relatively long period. Mixtures of diesters of dicarbonic acid and protonic acids are outstandingly suitable for preserving foods.
    Type: Application
    Filed: April 11, 2007
    Publication date: April 23, 2009
    Applicant: LANXESS DEUTSCHLAND GMBH
    Inventors: Steffen Kahlert, Johannes Kaulen, Erasmus Vogl
  • Patent number: 7514202
    Abstract: A thermal acid generator of generating an acid on heating above 100° C. has formula: CF3CH(OCOR)CF2SO3?(R1)4N+ wherein R is alkyl or aryl, R1 is hydrogen, alkyl, alkenyl, oxoalkyl, aryl, aralkyl or aryloxoalkyl, or R1 may bond together to form a ring with N. The sulfonic acid generated possesses an ester site within molecule so that less bulky acyl groups to bulky groups may be incorporated therein. The thermal acid generator provides a sufficient acid strength, is less volatile due to a high molecular weight, and ensures film formation. Upon disposal of used resist liquid, it may be converted into low accumulative compounds.
    Type: Grant
    Filed: May 9, 2007
    Date of Patent: April 7, 2009
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Youichi Ohsawa, Takeru Watanabe, Jun Hatakeyama
  • Patent number: 7511169
    Abstract: Sulfonate salts have the formula: CF3—CH(OCOR)—CF2SO3?M+ wherein R is C1-C20 alkyl or C6-C14 aryl, and M+ is a lithium, sodium, potassium, ammonium or tetramethylammonium ion. Onium salts, oximesulfonates and sulfonyloxyimides and other compounds derived from these sulfonate salts are effective photoacid generators in chemically amplified resist compositions.
    Type: Grant
    Filed: April 5, 2006
    Date of Patent: March 31, 2009
    Assignee: Shin-Etsu Chemical Co., Ltd.
    Inventors: Youichi Ohsawa, Takeru Watanabe, Takeshi Kinsho, Katsuhiro Kobayashi
  • Patent number: 7491482
    Abstract: The present application relates to a compound of formula AiXi where Ai is an organic onium cation; and Xi is an anion of the formula X—CF2CF2OCF2CF2—SO3?. The compounds are useful as photoactive materials.
    Type: Grant
    Filed: December 4, 2006
    Date of Patent: February 17, 2009
    Assignee: AZ Electronic Materials USA Corp.
    Inventors: Munirathna Padmanaban, Srinivasan Chakrapani, M. Dalil Rahman
  • Patent number: 7473409
    Abstract: A recycling process is presented to treat spent waste acid solutions whereby useful products are produced. Spent waste acid containing inorganic and organic contaminants is mixed with a magnesium compound containing aluminum and iron compounds that form oxyhydroxide flocs that complex, react, sequester and/or co-precipate the contaminates from the admixture. The magnesium reacts with sulfate ions to form a high quality magnesium sulfate solution.
    Type: Grant
    Filed: August 30, 2006
    Date of Patent: January 6, 2009
    Assignee: Veolia ES Technical Solutions L.L.C.
    Inventor: Danny Mislenkov
  • Publication number: 20080311522
    Abstract: A compound represented by general formula (b-14); and acid generator consisting of the compound; and a resist composition including a base component (A) which exhibits changed solubility in an alkali developing solution under action of acid and an acid-generator component (B) which generates acid upon exposure, the acid-generator component (B) including an acid generator (B1) consisting of a compound represented by general formula (b1-14): wherein R7? to R9? each independently represents an aryl group or an alkyl group, wherein two of R7? to R9? may be bonded to each other to form a ring with the sulfur atom, and at least one of R7? to R9? represents a substituted aryl group in which a portion or all of the hydrogen atoms are substituted with an alkoxyalkyloxy group or an alkoxycarbonylalkyloxy group; and X? represents an anion.
    Type: Application
    Filed: June 9, 2008
    Publication date: December 18, 2008
    Applicant: Tokyo Ohka Kogyo Co., Ltd.
    Inventors: Takeshi Iwai, Hideo Hada, Keita Ishiduka, Akiya Kawaue, Hiroaki Shimizu, Kyoko Ohshita, Tsuyoshi Nakamura, Komei Hirahara, Yuichi Suzuki, Takehiro Seshimo
  • Patent number: 7429628
    Abstract: A method for preparing a thermoplastic composition containing an antistatic agent is described. The antistatic agent is a phosphonium sulfonate salt that is prepared by a method that includes combining in an aqueous medium sodium hydroxide and/or lithium hydroxide, a sulfonyl fluoride compound, and a phosphonium halide compound; and separating the phosphonium sulfonate from the aqueous medium. The phosphonium sulfonate salt is then combined with a thermoplastic resin.
    Type: Grant
    Filed: October 9, 2007
    Date of Patent: September 30, 2008
    Assignee: SABIC Innovative Plastics IP B.V.
    Inventors: Theodorus Lambertus Hoeks, Chiel Albertus Leenders, Robert Dirk van de Grampel
  • Publication number: 20080171672
    Abstract: A method of treating a hydrocarbon containing formation is described. The method includes providing a hydrocarbon recovery composition to the hydrocarbon containing formation. The hydrocarbon recovery composition includes a branched internal olefin sulfonate having an average carbon number of at least 15 and an average number of branches per molecule of at least about 0.8.
    Type: Application
    Filed: December 19, 2007
    Publication date: July 17, 2008
    Inventors: Manuel Luis CANO, Kirk Herbert Raney
  • Patent number: 7371892
    Abstract: A process for working up ?-sulfatoethylsulfonylaniline-2-sulfonic acid from a solution in aqueous sulfuric acid, comprises a first step of the ?-sulfatoethylsulfonylaniline-2-sulfonic acid being precipitated by addition of alkali or alkaline earth metal and/or ammonium salts, separated off and dissolved or the sulfuric acid being precipitated by addition of calcium salts and the resulting calcium sulfate being separated off if appropriate, and a second step of the resultant solution being adjusted to a pH between 1 and 5 by addition of alkali or alkaline earth metal or ammonium hydroxide, carbonate, bicarbonate and/or acetate, any calcium sulfate still present being separated off and the ?-sulfatoethylsulfonylaniline-2-sulfonic acid being isolated from the solution.
    Type: Grant
    Filed: February 26, 2005
    Date of Patent: May 13, 2008
    Assignee: BASF Aktiengesellschaft
    Inventor: Laszlo Somogyi
  • Publication number: 20080045415
    Abstract: Alkyl ether sulfates having 1 to 9 carbon atoms in the alkyl chain and 1 to 20 alkyleneoxy units in the ether moiety are suitable for use as low-foam additives for enhancing the activity of water-soluble or partially water-soluble agrochemicals. They can be used to produce low-foam preparations for crop protection.
    Type: Application
    Filed: June 19, 2007
    Publication date: February 21, 2008
    Applicant: Bayer CropScience AG
    Inventors: Peter Baur, Thomas Auler, Roland Deckwer, Stephanie Giessler
  • Patent number: 7256306
    Abstract: This invention relates new and improved processes for the preparation of arylalkylsulfonic acids derived from aromatic or substituted aromatic molecules and AOS acid (generally a mixture of alkenesulfonic acid and sultones, produced from the sulfonation of alpha olefins) and to cleaning compositions comprising said arylalkylsulfonic acids. The invention involves the use of a superacid catalyst to effectuate the conversion of AOS acid and aromatic reactants to arylalkylsulfonic acid under substantially anhydrous conditions, whereby a substantial improvement in the rate of conversion of the reactants to arylalkylsulfonic acid and/or improvement in mono-alkylation selectivity is realized, as compared to methods of preparation previously disclosed. Also useful as an alkylation promoter is the arylalkylsulfonic acid reaction product itself, produced in situ or from a previous reaction (i.e., a self-catalyst heel).
    Type: Grant
    Filed: August 2, 2002
    Date of Patent: August 14, 2007
    Assignee: Stepan Company
    Inventors: Gregory P. Dado, Randal H. Bernhardt
  • Patent number: 7211690
    Abstract: A method for making the phosphonium sulfonate salt of generic formula (1): wherein each X is independently a halogen or hydrogen, provided that the molar ratio of halogen to hydrogen is greater than about 0.90; p is 0 or 1 and q and r are integers of 0 to about 7 provided that q+r is less than 8 and that if p is not zero then r is greater than zero; and each R is the same or different hydrocarbon radical containing 1 to about 18 carbon atoms, the method comprising combining in an aqueous medium a compound of generic formula (2): wherein M is Li or Na, and X, q, p, and r are as defined above, with a stoichiometric excess of a compound of the generic formula (3): (R)4P-Z??(3) wherein Z is a halogen and R is as defined above; and separating the product of formula (1) from the medium.
    Type: Grant
    Filed: October 15, 2004
    Date of Patent: May 1, 2007
    Assignee: General Electric Company
    Inventors: Theodorus Lambertus Hoeks, Chiel Albertus Leenders, Robert Dirk van de Grampel
  • Patent number: 7189489
    Abstract: Compounds of the formulae I, II and III wherein R1 is for example hydrogen, C3–C8cycloalkyl, C1–C12alkyl, phenyl unsubstituted or substituted; R2 and R2? for example are hydrogen, C1–C20alkyl, C3–C8cycloalkyl or phenyl, unsubstituted or substituted, or are Ar1 is for example phenyl, optionally substituted by e.g. Ar2 is for example phenylene, optionally substituted e.g. by —(CO)R7, (D), (E) or (F); Ar3 is for example phenyl; M1, M2 and M3 are, for example, C1–C20alkylene; M4 is for example direct bond, —O—, —S—, —Y—(C1–C10alkylene)-Y?—, optionally substituted; Y and Y? are for example a direct bond or —O—; R7 is for example hydrogen, C1–C20alkyl or phenyl, optionally substituted; R8, R9, R8? and R9? are for example hydrogen or C1–C12alkyl, exhibit an unexpectedly good performance in photopolymerization reactions.
    Type: Grant
    Filed: June 4, 2002
    Date of Patent: March 13, 2007
    Assignee: Ciba Specialty Chemicals Corporation
    Inventors: Kazuhiko Kunimoto, Junichi Tanabe, Hisatoshi Kura, Hidetaka Oka, Masaki Ohwa