Two Aryl Rings Or Ring Systems Bonded Directly To The Same Carbon Patents (Class 564/315)
  • Patent number: 5977413
    Abstract: Disclosed is a method for producing bis(3-amino-4-hydroxyphenyl) compounds, which comprises reducing bis(3-nitro-4-hydroxyphenyl) compounds with hydrazines in the presence of a catalyst. The method produces bis(3-amino-4-hydroxyphenyl) compounds of high quality under mild conditions at high yields. The products can be isolated and purified in a simple manner to have a higher purity. The method is suitable to industrial-scale production of the products.
    Type: Grant
    Filed: July 28, 1998
    Date of Patent: November 2, 1999
    Assignee: Nippon Kayaku Kabushiki Kaisha
    Inventors: Jun-ichiro Tomaru, Kenji Kunikata, Masaki Fujimoto
  • Patent number: 5948941
    Abstract: A material for an organic EL device, having excellent capability of injecting holes from a metal electrode and having durability, and an organic EL device which is imparted with excellent stability in the repeated use for light emission by using the above material, the material having the formula (1), (6) or (7) as specified in claim 1.
    Type: Grant
    Filed: December 12, 1997
    Date of Patent: September 7, 1999
    Assignee: Toyo Ink Manufacturing Co., Ltd.
    Inventors: Michiko Tamano, Toshikazu Onikubo, Satoshi Okutsu, Toshio Enokida
  • Patent number: 5939554
    Abstract: A method for preparing a diarylalanine compound is provided. The method includes reacting a diarylaminopropanediol with a reducing agent to form a diarylaminopropanol compound and/or contacting a serine ester derivative with an aryl metal reagent to form diarylaminopropanediol. A diarylmethyloxazolidinone compound is also provided.
    Type: Grant
    Filed: April 17, 1997
    Date of Patent: August 17, 1999
    Assignee: NDSU Research Foundation
    Inventors: Mukund P. Sibi, Prasad K. Despande, Anthony J. LaLoggia
  • Patent number: 5910610
    Abstract: A triphenylamine derivative, represented by the following general formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, R.sup.5 and R.sup.6 each represents a hydrogen atom, a lower alkyl group, an alkoxy group, a halogen atom or an aryl group which may have a substituent group; and m and n each represents 0 or 1.
    Type: Grant
    Filed: September 2, 1997
    Date of Patent: June 8, 1999
    Assignee: Takasago International Corporation
    Inventors: Tohru Kobayashi, Yoshimasa Matsushima, Hiroshi Sugiyama, Toshimitsu Hagiwara
  • Patent number: 5863952
    Abstract: The single enantiomers of formula (I) and salts thereof ##STR1## are calcium channel antagonists useful in the treatment of ischaemic conditions e.g., stroke.
    Type: Grant
    Filed: July 11, 1997
    Date of Patent: January 26, 1999
    Assignee: SmithKline Beecham plc
    Inventors: Barry Sidney Orlek, John David Harling
  • Patent number: 5840984
    Abstract: Odor formation during storage of (hydrocarbylthio)aromatic amines due to formation and release of odoriferous sulfur-containing species such as dihydrocarbyldisulfides, is suppressed. To accomplish this, a small amount of N,N-dihydrocarbylhydroxylamine odor-inhibitor (e.g., N,N-diethylhydroxylamine) is blended with the (hydrocarbylthio)aromatic amine. This enables products such as a mixture of 3,5-di(methylthio)-2,4-diaminotoluene and 3,5-di(methylthio)-2,6-diaminotoluene) to be stored for long periods of time with significantly reduced formation and release of odoriferous sulfur-containing species.
    Type: Grant
    Filed: June 23, 1997
    Date of Patent: November 24, 1998
    Assignee: Albemarle Corporation
    Inventors: Gregory H. Lambeth, Paul L. Wiggins, William R. Brown
  • Patent number: 5773469
    Abstract: The invention relates to diaryl antimicrobial compounds of the general formula: ##STR1## where G, E L, J, q, m, X, Ar, W, p, n and A are as described herein, pharmaceutical compositions containing the compounds, methods for their production and their use in treating bacterial infections.
    Type: Grant
    Filed: June 18, 1996
    Date of Patent: June 30, 1998
    Assignee: Ortho Pharmaceutical Corporation
    Inventors: Ramesh M. Kanojia, James P. Demers, Dennis J. Hlasta, Sigmond G. Johnson, Dieter H. Klaubert
  • Patent number: 5770675
    Abstract: Disclosed herein are cyclic oligomers comprising substituted or unsubstituted m-phenylene isophthalamide, complexes of these oligomers with selected metal salts, novel methods for their preparation, and polymerization of the cyclic oligomers to linear aramids. The aramids are useful, for example, as fibers for fire resistant clothing. Amino-finctional cyclic oligomers may be reacted with polyfunctional acyl halides to produce polyamides.
    Type: Grant
    Filed: June 18, 1996
    Date of Patent: June 23, 1998
    Assignee: E. I. du Pont de Nemours and Company
    Inventors: Young Hwan Kim, Wesley Memeger, Jr.
  • Patent number: 5750785
    Abstract: A 1,4-bis(2',2'-diphenylvinyl)benzene derivative represented by formula (I): ##STR1## wherein R.sup.1 and R.sup.2 each represents a different lower alkyl group and Me represents a methyl group, a charge transporting material containing the compound (I), and an electrophotographic photoreceptor comprising a charge transporting layer containing the charge transporting material are disclosed.
    Type: Grant
    Filed: February 7, 1996
    Date of Patent: May 12, 1998
    Assignee: Takasago International Corporation
    Inventors: Yoshimasa Matsushima, Hiroshi Sugiyama, Toshimitsu Hagiwara
  • Patent number: 5684180
    Abstract: The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and to the use thereof.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: November 4, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hartmut Knofel, Michael Brockelt
  • Patent number: 5679840
    Abstract: The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and their use.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: October 21, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hartmut Knofel, Michael Brockelt
  • Patent number: 5679841
    Abstract: The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and the use thereof.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: October 21, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hartmut Knofel, Michael Brockelt
  • Patent number: 5675035
    Abstract: The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and to their use.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: October 7, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hartmut Knofel, Michael Brockelt
  • Patent number: 5672737
    Abstract: The invention relates to a process for the fractionation and purification of mixtures of aromatic polyamines and to the use thereof.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: September 30, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hartmut Knofel, Michael Brockelt
  • Patent number: 5665756
    Abstract: Novel aminoalkyloximes of the formula ##STR1## wherein: a. X is hydrogen, loweralkyl, loweralkoxy, halogen, trifluoromethyl, or a group of the formula ##STR2## wherein Y is hydrogen or loweralkyl, and p is 1 or 2; b. A is a group of the formula ##STR3## c. R.sup.1 and R.sup.2 are independently hydrogen or lowerakyl; and d. m is 2 to 6 and n is 0, or 2 to 6, inclusive, serotonin reuptake inhibitors, useful for treating depression and obsessive compulsive disorders are described. Also described are precursors of and processes for the preparation of such aminoakyloximes.
    Type: Grant
    Filed: August 3, 1994
    Date of Patent: September 9, 1997
    Assignee: Hoechst Marion Roussel, Inc.
    Inventors: Gregory M. Shutske, Brian S. Freed, John D. Tomer, IV, R. Richard L. Hamer
  • Patent number: 5663424
    Abstract: The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and the use thereof.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: September 2, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hartmut Knofel, Michael Brockelt
  • Patent number: 5648519
    Abstract: The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and to the use thereof.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: July 15, 1997
    Assignee: Bayer Aktiengesesellschaft
    Inventors: Hartmut Knofel, Michael Brockelt
  • Patent number: 5648520
    Abstract: The invention relates to a process for the fractionation and purification of aromatic polyamine mixtures and the use thereof.
    Type: Grant
    Filed: March 28, 1996
    Date of Patent: July 15, 1997
    Assignee: Bayer Aktiengesellschaft
    Inventors: Hartmut Knofel, Michael Brockelt
  • Patent number: 5648538
    Abstract: A process for preparing diarylamines in high yield, in which diarylamines are prepared from arylamines in the presence of a solid acid catalyst. The solid acid catalyst with good stability and regeneration ability consists of H-type beta zeolite and active alumina, the ratio of SiO.sub.2 /Al.sub.2 O.sub.3 in the zeolite is 20.about.100, and the content of active alumina is 10%.about.70% (wt).
    Type: Grant
    Filed: June 29, 1995
    Date of Patent: July 15, 1997
    Assignees: Fushun Research Institute of Petroleum and Petrochemicals, China Petrochemical Corp.
    Inventors: Xiusen Liu, Huarong Zhu, Fubin Ai, Lizhi Song, Zhihui Lu, Xuewei Hou
  • Patent number: 5599993
    Abstract: Four phenylethynyl amine compounds--3 and 4-aminophenoxy-4'-phenylethynylbenzophenone, and 3 and 4-amino-4'-phenylethynylbenzophenone--were readily prepared and were used to endcap imide oligomers. Phenylethynyl-terminated amide acid oligomers and phenylethynyl-terminated imide oligomers with various molecular weights and compositions were prepared and characterized. These oligomers were cured at 300.degree. C. to 400.degree. C. to provide crosslinked polyimides with excellent solvent resistance, high strength and modulus and good high temperature properties. Adhesive panels, composites, films and moldings from these phenylethynyl terminated imide oligomers gave excellent mechanical performance.
    Type: Grant
    Filed: January 20, 1995
    Date of Patent: February 4, 1997
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Paul M. Hergenrother, Robert G. Bryant, Brian J. Jensen, Stephen J. Havens
  • Patent number: 5573878
    Abstract: A triphenylamine derivative, a charge-transporting material comprising the triphenylamine derivative, and an electrophotographic photoreceptor containing a charge-transporting layer comprising the triphenylamine derivative are disclosed, wherein the triphenylamine derivative is represented by the following general formula (1): ##STR1## wherein R.sup.1, R.sup.2, R.sup.3, R.sup.4, and R.sup.5 may be the same or different and each represents a hydrogen atom, a lower alkyl group, an alkoxy group, a halogen atom, or an aryl group which may have a substituent, or R.sup.1 and R.sup.2 and/or R.sup.3 and R.sup.4 may be taken together to form a ring, and n represents 0 or 1.
    Type: Grant
    Filed: November 1, 1994
    Date of Patent: November 12, 1996
    Assignee: Takasago International Corporation
    Inventors: Toshimitsu Hagiwara, Hiroshi Sugiyama, Yoshimasa Matsushima, Tohru Kobayashi
  • Patent number: 5525704
    Abstract: Disclosed is an aromatic diamine compound represented by the formula (I) ##STR1## wherein R is H or CH.sub.3. Also disclosed is a bismaleimide compound represented by the formula (IV) ##STR2## wherein R is H or CH.sub.3, A resin forming composition comprising these compounds is also disclosed. The compounds are useful as raw materials for resins, and the resin forming composition and the resin can provide excellent heat resistance and impact resistance and low hygroscopicity.
    Type: Grant
    Filed: October 24, 1995
    Date of Patent: June 11, 1996
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Shoji Tamai, Norimasa Yamaya, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5488163
    Abstract: A process for the production of 4,4'-(phenylenediisopropyl)bis(2,6-dialkylanilines) of the general formula: ##STR1## wherein R.sub.1 and R.sub.2 are the same or different and each is a (C.sub.1 -C.sub.4)alkyl group, R.sub.3 is hydrogen or halogen, and the central phenylene function is substituted in the 1,3 or 1,4 position, by reaction of a corresponding diisopropyl benzene with a corresponding aniline in the presence of catalytic amounts of aluminum chloride. The 4,4'-(phenylenediisopropyl)-bis(2,6-dialkylanilines) are used as cross-linking agents for epoxy resins, as chain lengthening agents for polyurethanes, for the production of hydrolysis protective agents for polyurethanes, or for the production of UV stabilizers in varnishes.
    Type: Grant
    Filed: December 20, 1994
    Date of Patent: January 30, 1996
    Assignee: Lonza Ltd.
    Inventors: Peter Hardt, Ulrich Daum, Theodor Volker
  • Patent number: 5453522
    Abstract: Bis-substituted methanes and undissociated methylene salts of the formula (Am).sub.2 Z wherein Am is bis-(1,4 dimethylaminophenyl) and Z is CH.sub.2 or CH.sup.+ X.sup.- wherein X.sup.- is a suitable anion, all useful in the production of deeply colored cations of the formula (Am).sub.2 CH.sup.+. These deeply colored cations are in turn useful in making and using carbonless copy papers, as well as thermal copying papers for use with fax machines.
    Type: Grant
    Filed: September 20, 1994
    Date of Patent: September 26, 1995
    Assignee: Indiana University Foundation
    Inventors: Chester Davis, Ford P. Wilgis, Vernon J. Shiner, Jr.
  • Patent number: 5410084
    Abstract: A polyimide comprising a requisite structural unit having one or more recurring structural units of the formula: ##STR1## such as the structural units of the formula ##STR2## Further, the present invention relates to a novel aromatic diamine which has a perfluoro radical and can be used as a raw material monomer of the polyimide, and a process for preparing the same.The polyimide can have an extremely low dielectric constant and is colorless, transparent and excellent in processability and heat resistance.
    Type: Grant
    Filed: June 2, 1994
    Date of Patent: April 25, 1995
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Mitsunori Matsuo, Tsutomu Ishida, Keizaburo Yamaguchi, Akihiro Yamaguchi
  • Patent number: 5395969
    Abstract: A compound suitable for use as a charge transport compound in organic photoconductors or as a charge control agent in electrophotographic toners. The compound, in the neutral form, is of the Formula (1): ##STR1## wherein: Ar is of formula (a), (b) or (c) ##STR2## each L independently is H, C.sub.1-4 -alkyl or halo; R.sup.1, R.sup.3 and R.sup.4 are each independently alkyl, substituted alkyl, aryl, substituted aryl, aralkyl, substituted aralkyl, cycloalkyl or allyl;R.sup.2 is an alkyl, aralkyl, cycloalkyl, allyl or aryl group which is unsubstituted or substituted by a group defined by X.sup.4 ; andX.sup.1, X.sup.2, X.sup.3, X.sup.4 & X.sup.5 are each independently H or a group capable of stabilising a positive charge on the adjacent carbon atom.
    Type: Grant
    Filed: July 23, 1993
    Date of Patent: March 7, 1995
    Assignee: Zeneca Limited
    Inventors: Raymond S. Gairns, Anthony A. Watson
  • Patent number: 5386058
    Abstract: A method for producing polymethine dyes comprising the steps of:(a) reacting a 1,1-diaryl-2-metallo-ethene with an .omega., .omega.,-diaryl-polyalkene-aldehyde in an anhydrous solvent under an inert atmosphere; and(b) neutralizing the reaction mixture from step (a) with an acid, thereby producing a polymethine dye.
    Type: Grant
    Filed: October 29, 1993
    Date of Patent: January 31, 1995
    Assignee: Minnesota Mining and Manufacturing Company
    Inventor: Roger A. Mader
  • Patent number: 5364967
    Abstract: Disclosed is an aromatic diamine compound represented by the formula (I) ##STR1## wherein R is H or CH.sub.3. Also disclosed is a bismaleimide compound represented by the formula (IV) ##STR2## wherein R is H or CH.sub.3, A resin forming composition comprising these compounds is also disclosed. The compounds are useful as raw materials for resins, and the resin forming composition and the resin can provide excellent heat resistance and impact resistance and low hygroscopicity.
    Type: Grant
    Filed: January 19, 1993
    Date of Patent: November 15, 1994
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Keizaburo Yamaguchi, Tatsuhiro Urakami, Yoshimitsu Tanabe, Midori Yamazaki, Shoji Tamai, Norimasa Yamaya, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5354511
    Abstract: Compounds having non-linear optical activity of the general formula ##STR1## wherein D and A are electron donor and acceptor groups, respectively, R.sup.1 and R.sup.2 are aromatic bridging groups, X and Y are preferably groups capable of partaking in polymerization reactions are suitable for use in polymer-based light modulator devices.
    Type: Grant
    Filed: November 27, 1992
    Date of Patent: October 11, 1994
    Assignee: AlliedSignal Inc.
    Inventors: Chengjiu Wu, Jianhui Shan, Ajay Nahata
  • Patent number: 5306821
    Abstract: This invention relates to a novel process for the preparation of tertiary carbinamines by double addition of organolanthanide reagents, especially organocerium reagents, to nitriles. It further relates to the preparation of such amines by the addition of organolanthanide reagents to imines.
    Type: Grant
    Filed: January 10, 1992
    Date of Patent: April 26, 1994
    Assignee: The Du Pont Merck Pharmaceutical Company
    Inventor: Engelbert Ciganek
  • Patent number: 5292896
    Abstract: Styrene derivatives of the formula ##STR1## and an electrophotographic photoconductor comprising an electroconductive support material and a photosensitive layer comprising at least one styrene derivatives of the same formula are disclosed, in which Ar represents an unsubstituted of substituted phenyl group or an unsubstituted or substituted styryl group, R represents hydrogen, a lower alkyl group or an unsubstituted or substituted phenyl group, and A is selected from the group consisting of ##STR2## wherein R.sup.1 represents a lower alkyl group or a lower alkoxy group, R.sup.2 and R.sup.3 each represent a lower alkyl group, an aralkyl group, or an unsubstituted or substituted phenyl group.
    Type: Grant
    Filed: September 4, 1991
    Date of Patent: March 8, 1994
    Assignee: Ricoh Company, Ltd.
    Inventors: Masayuki Shoshi, Masaomi Sasaki
  • Patent number: 5288908
    Abstract: Compounds of the formula ##STR1## in which X represents hydrogen, --NO.sub.2 or --NH.sub.2 and Y represents --CH.sub.3, --COOH, --CONH.sub.2, --NH.sub.2 or --N.dbd.N--Z, in which the group --Z is ##STR2## with the proviso that if Y represents the group --N.dbd.N--Z, X is only --NO.sub.2, and if Y represents the group --CH.sub.3, X is only hydrogen, are described. A compound of the formula ##STR3## the preparation of which in a multi-stage process, in which the compounds of the general formula (I) are also obtained, is described, is preferred.The resulting 3,4'-diamino compound is suitable for the preparation of polycondensates and shaped articles, films and fibers of high heat resistance.
    Type: Grant
    Filed: July 19, 1993
    Date of Patent: February 22, 1994
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jurgen Lau, Gunter Siegemund, Freimund Rohrscheid
  • Patent number: 5250735
    Abstract: Novel 2-(N-substituted-aminoalkyl)-5-(E)-alkylidene cyclopentanones, 2-(N-substituted-aminoalkyl)-5-(E)-arylalkylidene cyclopentanones, and derivatives thereof having the formula ##STR1## wherein x is methylene or ethylene; R.sub.1 is dimethylamino, diethylamino, 1-pyrrolidinyl, 1-piperidinyl, 4-morpholinyl, anilino or substituted anilino; R.sub.2 is hydrogen, straight or branched alkyl of 1 to 9 carbon atoms, aryl or arylalkyl; R.sub.3 is hydrogen, straight or branched alkyl of 1 to 9 carbon atoms, aryl or arylalkyl; and R.sub.4 is hydrogen, methyl, ethyl, allyl, benzyl, substituted benzyl, cyclopentyl, substituted cyclopentyl, cyclopenten-1-yl, or substituted cyclopenten-1-yl; and wherein aryl is phenyl or phenyl substituted with one or more methoxyl, hydroxyl, methylenedioxy, chloro, bromo, fluoro, ethoxycarbonylmethoxy, benzoxy, alkyl group, or their combination, possess anti-inflammatory, analgesic and anticancer properties.
    Type: Grant
    Filed: April 3, 1992
    Date of Patent: October 5, 1993
    Assignee: University of Pittsburgh
    Inventors: Lan K. Wong, Hai-Tao Chen, Zhi-Zhong Ji
  • Patent number: 5247047
    Abstract: Aromatic polyamide oligomers containing polymerizable unsaturated groups are prepared by heating and reacting together an aromatic diisocyanate, an aromatic dicarboxylic acid and an unsaturated compound capable of reacting with the aromatic diisocyanate. The aromatic polyamide oligomers thus obtained have excellent molding processability and are useful as raw materials for thermosetting polyamides with enhanced mechanical strength and chemical stability at higher temperatures. The compositions comprising the aromatic polyamide oligomers and maleimide derivatives, further produce cured molded bodies with excellent heat resistance.
    Type: Grant
    Filed: January 7, 1992
    Date of Patent: September 21, 1993
    Assignee: Showa Highpolymer Co., Ltd.
    Inventors: Tadayuki Hosogane, Hiroshi Nakajima
  • Patent number: 5225595
    Abstract: Sulfonyl compounds of the formula ##STR1## where Ar is the radical of a benzene or naphthalene ring,R.sup.1 and R.sup.2 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl, substituted or unsubstituted phenyl, C.sub.1 -C.sub.4 -alkoxy, carboxyl, C.sub.1 -C.sub.4 -alkoxycarbonyl, cyano, halogen or hydroxysulfonyl,R.sup.3 is nitro, amino, C.sub.1 -C.sub.4 -alkanoylamino or benzoylamino, andR.sup.4 is a radical of the formula ##STR2## where X.sup.1, X.sup.2 and X.sup.3 are each hydrogen, substituted or unsubstituted C.sub.1 -C.sub.4 -alkyl or substituted or unsubstituted phenyl, andX.sup.4 is a group which is detachable under alkaline conditions,either in the free form or in the form of their salts, are useful for synthesizing reactive dyes.
    Type: Grant
    Filed: November 4, 1992
    Date of Patent: July 6, 1993
    Assignee: BASF Aktiengesellschaft
    Inventors: Bernd Siegel, Claus Marschner, Manfred Patsch
  • Patent number: 5206438
    Abstract: Disclosed is an aromatic diamine compound represented by the formula (I) ##STR1## wherein R is H or CH.sub.3. Also disclosed is a bismaleimide compound represented by the formula (IV) ##STR2## wherein R is H or CH.sub.3, A resin forming composition comprising these compounds is also disclosed. The compounds are useful as raw materials for resins, and the resin forming composition and the resin can provide excellent heat resistance and impact resistance and low hygroscopicity.
    Type: Grant
    Filed: October 23, 1990
    Date of Patent: April 27, 1993
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Keizaburo Yamaguchi, Tatsuhiro Urakami, Yoshimitsu Tanabe, Midori Yamazaki, Shoji Tamai, Norimasa Yamaya, Masahiro Ohta, Akihiro Yamaguchi
  • Patent number: 5196583
    Abstract: The invention provides a novel class of propargyl compounds represented by the formula: ##STR1## wherein R is an C.sub.1 -C.sub.20 alkyl group, C.sub.1 -C.sub.20 alkylene group, C.sub.1 -C.sub.20 alkylene group interrupted by --NH-- group(s), C.sub.6 -C.sub.7 alicyclic group and an aromatic group; R.sub.1 comprises 1-100% --CH.sub.2 --C.tbd.CH group and 99-0% hydrogen atom and n is an integer of 1 to 4, and preparation thereof.These compounds are useful as coating material or sealer or rim-injection molding material.
    Type: Grant
    Filed: December 4, 1990
    Date of Patent: March 23, 1993
    Assignee: Nippon Paint Co., Ltd.
    Inventors: Mitsuo Yamada, Kei Aoki
  • Patent number: 5166365
    Abstract: A novel fluorine-containing aromatic compound of the formula: ##STR1## wherein X is ##STR2## in which R.sub.f is a perfluoroalkyl group having 1 to 10 carbon atoms,R.sub.f ' is a perfluoroalkyl group having 1 to 12 carbon atoms,p is an integer of 1 to 3,q is an integer of 0 to 3,r is 0 or 1,s is an integer of 0 to 5and t is an integer of 0 to 5,Y is X, a hydrogen atom, an alkyl group having 1 to 8 carbon atoms or a fluoroalkyl group having 1 to 8 carbon atoms, andeach A is independently ##STR3## in which D is an amino, carboxyl, hydroxyl, methyl or haloformyl group, and n is an integer of 1 or 2, or ##STR4## can be used to derive various compounds, some of which are useful for preparing a fluorine-containing epoxy compound of polyimide with good properties.
    Type: Grant
    Filed: May 10, 1990
    Date of Patent: November 24, 1992
    Assignee: Daikin Industries Ltd.
    Inventors: Yohnosuke Ohsaka, Tsutomu Kobayashhi, Motonobu Kubo
  • Patent number: 5145942
    Abstract: Novel polyimides have been prepared from the reaction of aromatic diahydrides with novel aromatic diamines having carbonyl and ether groups connecting aromatic rings containing pendant methyl groups. The methyl substituent polyimides exhibit good solubility and form tough, strong films. Upon exposure to ultraviolet irradiation and/or heat, the methyl substituted polyimides crosslink to become insoluble.
    Type: Grant
    Filed: September 28, 1990
    Date of Patent: September 8, 1992
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Paul M. Hergenrother, Stephen J. Havens
  • Patent number: 5145937
    Abstract: New polyimides have been prepared from the reaction of aromatic dianhydrides with novel aromatic diamines containing carbonyl and ether connecting groups between the aromatic rings. Several of these polyimides were shown to be semi-crystalline as evidenced by wide angle x-ray diffraction and differential scanning calorimetry. Most of the polyimides form tough solvent resistant films with high tensile properties. Several of these materials can be thermally processed to form solvent and base resistant moldings.
    Type: Grant
    Filed: November 9, 1989
    Date of Patent: September 8, 1992
    Assignee: The United States of America as represented by the Administrator of the National Aeronautics and Space Administration
    Inventors: Paul M. Hergenrother, Stephen J. Havens
  • Patent number: 5141937
    Abstract: Pharmaceutical products containing a 7-diphenylmethylenebicycloheptane or 7-diphenylmethylenebicycloheptene derivative of the formula I ##STR1## in which A, B, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the stated meanings, or a physiologically tolerated acid addition salt of these compounds, and the use thereof as hypolipidemics are described. In addition, new 7-diphenylmethylenebicycloheptane and -heptene derivatives of the formula Ia ##STR2## in which A, B, R.sup.1, R.sup.2, R.sup.3 and R.sup.4 have the stated meanings, and the physiologically tolerated acid addition salts thereof, as well as processes for the preparation thereof, are described.
    Type: Grant
    Filed: September 21, 1988
    Date of Patent: August 25, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Herbert Siegel, Ernold Granzer
  • Patent number: 5110983
    Abstract: Compounds of the formula I ##STR1## can be prepared by various process steps from 2-(4-methylphenyl)-2-hexafluoroisopropanol.Hexafluoroisopropyl-containing monomers are important starting compounds in the preparation of linear polycarboxamides and polycarboximides.
    Type: Grant
    Filed: March 22, 1990
    Date of Patent: May 5, 1992
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jurgen Lau, Gunter Siegemund, Freimund Rohrscheid
  • Patent number: 5077436
    Abstract: Bis(3-nitrophenoxy) derivatives of aromatic or bridged aromatic hydrocarbons are derived from m-dinitrobenzene and dihydroxy derivatives of said hydrocarbons and certain substituted derivatives thereof by a condensation reaction in dipolar aprotic solvents in the presence of bases. The bis(3-nitrophenoxy) derivatives and derivatives obtained are successively reduced to afford bis-(3-aminophenoxy)derivatives. This is a new method for reacting the dihydroxy-derivatives with m-dinitrobenzene, and hence can prepare novel bis(3-aminophenoxy) derivatives such as 4,4'-bis(3-amino-phenoxy)biphenyl, 1-[4-(3-aminophenoxy)phenyl]-1,3,3-trimethyl-6-(3-aminophenoxy)indan, 6,6'-bis(3-aminophenoxy)3,3,3',3'-tetramethyl-1,1'spirobiindan, and methyl substituted 2,2'-bis[4-(3-aminophenoxy)phenyl]propane.
    Type: Grant
    Filed: February 21, 1986
    Date of Patent: December 31, 1991
    Assignee: Mitsui Toatsu Chemicals, Inc.
    Inventors: Yukihiro Yoshikawa, Keizaburo Yamaguchi, Kenichi Sugimoto, Yoshimitsu Tanabe, Akihiro Yamaguchi
  • Patent number: 5072045
    Abstract: The invention relates to an improved process for producing alkenylated aromatic amines which involves the catalytic reaction of an aromatic amine with a diene. The improvement resides in using a solvent in which the aromatic amine and diene are soluble in the proportions present in the reaction but inert to the reaction.
    Type: Grant
    Filed: December 21, 1987
    Date of Patent: December 10, 1991
    Assignee: Air Products and Chemicals, Inc.
    Inventors: William F. Burgoyne, Jr., Dale D. Dixon
  • Patent number: 5043478
    Abstract: An improved process for the preparation of certain fluorinated aromatic diamines is disclosed. The step-wise addition of an alkali metal hydroxide to the starting material produces increased yields of higher purity diamine product.
    Type: Grant
    Filed: April 18, 1989
    Date of Patent: August 27, 1991
    Assignee: Ethyl Corporation
    Inventor: William E. Wright
  • Patent number: 5015770
    Abstract: (Hydrocarbylthio)aromatic amines are prepared by reacting an aromatic amine, such as an aminobenzene, with a hydrocarbyl disulfide, such as an alkyl disulfide, in the presence of iodine, iodine monochloride, or iodine monobromide as a catalyst.
    Type: Grant
    Filed: July 16, 1990
    Date of Patent: May 14, 1991
    Assignee: Ethyl Corporation
    Inventor: Gordon G. Knapp
  • Patent number: 4996235
    Abstract: The present invention provides 3,4-diphenylbutanamines capable of selectively inhibiting the uptake of serotonin and norepinephrine.
    Type: Grant
    Filed: November 25, 1987
    Date of Patent: February 26, 1991
    Assignee: Eli Lilly and Company
    Inventors: David W. Robertson, David T. Wong
  • Patent number: 4996362
    Abstract: 5-[(4-N,N-ditolylamino)benzyl]-5H-dibenzo[a,d]-cycloheptane derivatives having formula (I), which are useful as organic photoconductive materials in electrophotography.
    Type: Grant
    Filed: May 3, 1990
    Date of Patent: February 26, 1991
    Assignee: Ricoh Company, Ltd.
    Inventors: Masaomi Sasaki, Tomotsu Aruga
  • Patent number: 4978790
    Abstract: Compounds of the formula ##STR1## in which A represents the radicals ##STR2## in which R.sup.1 and R.sup.2 are different from one another and denote hydrogen, --NO.sub.2 or --NH.sub.2, R.sup.3 is hydrogen or halogen, X represents --NO.sub.2 or --NH.sub.2, with the proviso that R.sup.1 is hydrogen, if R.sup.2 is --NO.sub.2 or --NH.sub.2 and R.sup.2 is hydrogen, if R.sup.1 is --NO.sub.2 or --NH.sub.2.The compounds are prepared from 4,4'-bis[2-(4-hydroxyphenyl)hexafluoroisopropyl]diphenyl ether by nitration or reaction with nitrobenzenes followed by reduction of the nitro groups. They are used for the preparation of high-temperature-resistant polycondensates.
    Type: Grant
    Filed: November 23, 1988
    Date of Patent: December 18, 1990
    Assignee: Hoechst Aktiengesellschaft
    Inventors: Jurgen Lau, Gunter Siegemund
  • Patent number: 4973754
    Abstract: Bis(p-aminocumyl)benzenes are prepared by treating diisopropylbenzene derivatives with a primary or secondary aniline in the presence of a catalytic amount of an acidic perfluorinated polymer.
    Type: Grant
    Filed: May 15, 1989
    Date of Patent: November 27, 1990
    Assignee: Shell Oil Company
    Inventor: Simon M. Li