Abstract: In production of cyclohexanone by hydrogenating phenol in the presence of a hydrogenation catalyst, improved catalyst life and improved hydrogenation rate are obtained if ketone impurities, particularly hydroxyacetone, are removed from the phenol prior to the hydrogenation. The present invention provides an improved method for reducing the ketone impurities in the phenol by contacting the phenol with a polyethylenimine and distilling the mixture formed to separate the phenol. The invention is particularly useful in production of cyclohexanone from phenol obtained by decomposition of cumene hydroperoxide.
Type:
Grant
Filed:
May 4, 1977
Date of Patent:
May 30, 1978
Assignee:
Allied Chemical Corporation
Inventors:
Jan F. Van Peppen, William Bernard Fisher