With Hydrocarbon Effluent Stream Splitting For Recycle To Different Syntheses Patents (Class 585/314)
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Patent number: 6096935Abstract: A process for producing alkyl aromatics using a transalkylation reaction zone and an alkylation reaction zone is disclosed. The transalkylation reaction zone effluent passes to the alkylation reaction zone where aromatics in the transalkylation reaction zone effluent are alkylated to the desired alkyl aromatics. This process decreases the capital and operating costs of recycling the aromatics in the transalkylation reaction zone effluent. This process is well suited for solid transalkylation and alkylation catalysts. Ethylbenzene and cumene may be produced by this process.Type: GrantFiled: July 28, 1998Date of Patent: August 1, 2000Assignee: UOP LLCInventors: Russell C. Schulz, Gregory J. Gajda
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Patent number: 6018086Abstract: The present invention relates to a process of preparing dialkylnaphthylenes and polyalkylenenaphthyleneates.Type: GrantFiled: October 10, 1997Date of Patent: January 25, 2000Assignees: Kabushiki Kaisha Kobe Seiko Sho, Mobil Oil CorporationInventors: Masahiro Motoyuki, Koji Yamamoto, Ajit Vishwanath Sapre, John Paul Mc Williams, Susan Patricia Donnelly
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Patent number: 6011189Abstract: A thermosetting plastic foam solid formed from the reaction product of: (a) either polyisocyanate or isocyanate-based foam; (b) a polyol-based foam; (c) a catalyst which is capable of promoting the thermosetting reaction between the polyisocyanate or isocyanate-based foam and the polyol-based foam; and (d) a blowing agent which comprises a high purity cyclopentane product, wherein the high purity cyclopentane product is about 95% or greater pure cyclopentane, and, optionally, (e) water and/or (f) liquid flame retardant.Type: GrantFiled: September 28, 1998Date of Patent: January 4, 2000Assignee: Exxon Chemical Patents Inc.Inventors: Robert H. Blanpied, James Darryl Thornsberry, Steven E. Silverberg, James R. Lattner, C. Harry McMullen, Leonel E. Sanchez, Tronze-I Dennis Wu
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Patent number: 5998684Abstract: A separation arrangement for a cumene process that operates with a relatively wet feed to an alkylation zone and relatively dry feed to a transalkylation zone reduces utilities and capital expenses for the separation and recycle of distinct wet and dry components by using an arrangement that first separates effluent from the trans alkylation and alkylation reaction zone in a benzene column before performing light ends and drying in a downstream depropanizer column. The arrangement uses a portion of the net overhead stream from the benzene column as a wet recycle stream for return to the alkylation reaction zone and sends another portion of the benzene net overhead to the depropanizer to supply a dry benzene recycle for the trans alkylation reaction zone.Type: GrantFiled: November 10, 1997Date of Patent: December 7, 1999Assignee: UOP LLCInventors: Perry K. Ho, Russell C. Schulz
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Patent number: 5990369Abstract: The present invention relates to a process for the production of light olefins comprising olefins having from 2 to 4 carbon atoms per molecule from an oxygenate feedstock. The process comprises passing the oxygenate feedstock to an oxygenate conversion zone containing a metal alumninophosphate catalyst to produce a light olefin stream. The light olefin stream is fractionated and a portion of the products are metathesized to enhance the yield of the ethylene, propylene, and/or butylene products. Propylene can be metathesized to produce more ethylene, or a combination of ethylene and butene can be metathesized to produce more propylene. This combination of light olefin production and metathesis, or disproportionation provides flexibility to overcome the equilibrium limitations of the metal aluminophosphate catalyst in the oxygenate conversion zone. In addition, the invention provides the advantage of extended catalyst life and greater catalyst stability in the oxygenate conversion zone.Type: GrantFiled: February 9, 1998Date of Patent: November 23, 1999Assignee: UOP LLCInventors: Paul T. Barger, R. Joe Lawson, Bipin V. Vora
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Patent number: 5955640Abstract: Integrated process for the production of butene-1 which comprises feeding a C.sub.4 hydrocarbon stream to a separation unit of butene-1 and recycling the remaining stream to the same unit after treatment in a bond isomerization section to convert the remaining butenes-2 into butene-1, a molecular sieve separation unit is inserted in the cycle operating with the hydrocarbons in a vapour phase, for the purge of the paraffins.Type: GrantFiled: May 24, 1996Date of Patent: September 21, 1999Assignees: Enichem S.p.A., Snamprogetti S.p.A.Inventors: Renato Paludetto, Alfredo Orsi, Roberto Trotta, Gianni Donati
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Patent number: 5914433Abstract: The present invention relates to a process for the production of light olefins comprising olefins having from 2 to 4 carbon atoms per molecule from an oxygenate feedstock. The process comprises passing the oxygenate feedstock to an oxygenate conversion zone containing a metal aluminophosphate catalyst to produce a light olefin stream. A propylene stream and/or mixed butylene is fractionated from said light olefin stream and cracked to enhance the yield of ethylene and propylene products. This combination of light olefin product and propylene and butylene cracking in a riser cracking zone or a separate cracking zone provides flexibility to the process which overcomes the equilibrium limitations of the aluminophosphate catalyst. In addition, the invention provides the advantage of extended catalyst life and greater catalyst stability in the oxygenate conversion zone.Type: GrantFiled: July 22, 1997Date of Patent: June 22, 1999Assignee: UOP LLLInventor: Terry L. Marker
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Patent number: 5895831Abstract: A process for the production of motor fuel alkylate by reacting an alkene hydrocarbon, an alkane hydrocarbon and a hydrogen halide with a solid alkylation catalyst disposed in swing beds. The spent solid alkylation catalyst is regenerated in a highly integrated flow scheme associated with the alkylate recovery.Type: GrantFiled: December 4, 1996Date of Patent: April 20, 1999Assignee: UOP LLCInventors: Robert S. Brasier, Paul A. Sechrist, Dale J. Shields
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Patent number: 5856607Abstract: The present invention relates to a process for the production of ethylbenzene from dilute ethylene streams, especially from mixtures of ethane and ethylene where such mixture is the offgas from a refinery operation, such as a fluid catalytic cracking (FCC) operation and wherein the unreacted ethane from the alkylation reactor is dehydrogenated to produce ethylene which is recycled into the original dilute ethylene stream.Type: GrantFiled: May 2, 1997Date of Patent: January 5, 1999Assignee: Amoco CorporationInventor: Dae K. Kim
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Patent number: 5847253Abstract: A process for the production of alkylaromatic hydrocarbons that operates with a high water content in an alkylation zone and a low water content in a transalkylation zone is disclosed. An aromatic feed and an acyclic feed are first passed through the alkylation reaction zone that operates at a high water content. A stripping column receives the effluent of the alkylation reaction zone, removes water and unreacted aromatic feed and produces a bottom stream containing unreacted aromatic feed and alkylated aromatics. A recycle column receives the bottom stream and produces an overhead stream of unreacted aromatic feed having a low water content. The overhead stream and a stream of polyalkylated aromatics are contacted in the transalkylation zone.Type: GrantFiled: March 18, 1997Date of Patent: December 8, 1998Assignee: UOP LLCInventors: Perry K. Ho, Constante P. Tagamolila
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Patent number: 5811621Abstract: A polymerizable grade of ethylene is recovered from an olefin-containing composition, prepared by the conversion of a methoxy compound to olefins, by a process which significantly reduces the requirements of the demethanizer distillation column through which hydrogen and methane are eliminated as impurities from the ethylene product without suffering economically unacceptable losses of ethylene to the hydrogen-methane fraction that is separated. The invention also provides for a C-2 splitter column of simplified requirements.Type: GrantFiled: August 9, 1996Date of Patent: September 22, 1998Inventor: Christiaan P. van Dijk
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Patent number: 5789643Abstract: The i-butene present in a C.sub.4 raffinate I is subjected in a first step to a first hydroisomerization. The hydroisomerization product is subjected to fractional distillation, with essentially 2-butene and n-butane being obtained as bottom product and i-butene and i-butane being obtained as overhead product. The overhead product is condensed and the condensate is divided into two parts. One part is subjected to a second hydroisomerization and the second hydroisomerate is recycled to the upper third of the fractionation column. The other part of the condensed overhead product is fed to the oligomerization. The condensed overhead-product of the fractionation column is divided in such a manner that, based on 1 part by volume of condensate conducted to the oligomerization, 1-5 parts by volume are fed to the second hydroisomerization.Type: GrantFiled: October 30, 1997Date of Patent: August 4, 1998Assignee: EC Erdolchemie GmbHInventors: Jens Herwig, Hans-Jurgen Bister, Arnd Stuwe
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Patent number: 5770042Abstract: A process combination is disclosed to selectively upgrade naphtha to obtain an isoparaffin-rich product for blending into gasoline. A naphtha feedstock is subjected to ring cleavage to convert naphthenes to paraffins using a nonacidic catalyst followed by isomerization of paraffins to obtain an increased proportion of isoparaffins. Ring cleavage also may be effected on the product of isomerization and separation by fractionation or adsorption.Type: GrantFiled: October 31, 1995Date of Patent: June 23, 1998Assignee: UOPInventors: Leonid B. Galperin, Jeffery C. Bricker, Jennifer S. Holmgren
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Patent number: 5763716Abstract: A process of converting a feed of hydrocarbon-containing gases into liquid hydrocarbon products including a first reaction of converting the feed into one to 2.5 parts of hydrogen to one part carbon monoxide in the presence of carbon dioxide and then secondly reacting the hydrogen and carbon monoxide in a Fischer-Tropsch synthesis reactor using a promoted iron oxide catalyst slurry to form liquid hydrocarbon products, wherein the carbon dioxide from the first and second reactions is separated from the product streams and at least a portion of the separated carbon dioxide is recycled into the first reaction feed and the hydrocarbon products are separated by distillation and a normally gaseous portion of the separated products are further reacted in another Fischer-Tropsch synthesis reactor to produce additional liquid hydrocarbon product.Type: GrantFiled: April 10, 1997Date of Patent: June 9, 1998Assignee: Rentech, Inc.Inventors: Charles B. Benham, Mark S. Bohn, Dennis L. Yakobson
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Patent number: 5750798Abstract: A process for the production of ethers from a paraffin feedstock. The process includes a novel arrangement of dehydrogenation, isomerization, hydroisomerization, separation and etherification to provide a novel method for the production of ethers from a paraffin feedstock.Type: GrantFiled: December 13, 1995Date of Patent: May 12, 1998Assignee: Phillips Petroleum CompanyInventors: Mark D. Scharre, Warren M. Ewert, Harold R. Hunt
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Patent number: 5744670Abstract: A process for producing alkylnaphthalene from a feedstock comprising isomers of dialkylnaphthalene and naphthalene by contacting the feedstock with a catalyst composition, in which the process comprising transalkylation between isomers of dialkylnaphthalene and naphthalene to produce monoalkylnaphthalene, and isomerization of dialkylnaphthalene, wherein the catalyst composition comprising a synthetic zeolite characterized by an X-ray diffraction pattern including interplanar d-spacing as set forth in Table A of the specification.Type: GrantFiled: June 10, 1996Date of Patent: April 28, 1998Assignees: Kobe Steel, Ltd., Mobil Oil CorporationInventors: Masahiro Motoyuki, Koji Yamamoto, John Paul McWilliams, Robert Glenn Bundens
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Patent number: 5670703Abstract: The invention is directed to a process and an installation for the production of liquid fuels and raw chemicals from crude petroleum within the framework of a refinery process with process steps for distillation, thermal and/or catalytic cracking, and possibly reformation. The refinery process is directly supplemented by various process steps, i.e. a partial flow of the C.sub.4 components together with a flow of methanol or ethanol is subjected to a catalytic reaction, the unconverted n-butane-containing portion of the components is subjected to isomerization, a part of the isobutane is subjected to a thermal cracking process, and finally the product flow emerging therefrom is guided back, in its entirety or in part, into the fractionation stage for splitting.Type: GrantFiled: May 10, 1993Date of Patent: September 23, 1997Assignee: Mannesmann AktiengesellschaftInventors: Simon Barendregt, Jean Lucien Monfils
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Patent number: 5663466Abstract: A process for saturating benzene in a stream containing hydrocarbons and benzene maintains the benzene saturation reactor in a mixed phase at specific conditions to recover a saturation reactor effluent having a low benzene concentration and a reduced temperature. The benzene saturation reactor operates in a mixed phase without a hydrogen recycle and provides a saturated benzene effluent having less than 2 mol % benzene when operated at an effluent temperature of between 480.degree. F. and 600.degree. F. The discovered temperature range is relatively high and constant for feeds containing a substantial mount of benzene, despite changes in reaction zone pressure and reaction zone liquid LHSV.Type: GrantFiled: December 8, 1994Date of Patent: September 2, 1997Assignee: UOPInventors: Lynn H. Rice, Donald H. Bell
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Patent number: 5600046Abstract: This invention deals with a process for converting aliphatic C.sub.2 -C.sub.6 hydrocarbons into C.sub.6.sup.+ aromatics and C.sub.3.sup.= /C.sub.4.sup.= olefins. The process involves combining dehydrocyclodimerization (DHCD) with dehydrogenation. Thus, the feedstream is first sent to a DHCD zone which produces an effluent stream which contains C.sub.6.sup.+ aromatics along with C.sub.1 -C.sub.5 hydrocarbons. This effluent stream is separated into a stream containing C.sub.1 -C.sub.4 hydrocarbons and one containing C.sub.6.sup.+ aromatics. The C.sub.1 -C.sub.4 containing stream is flowed to a dehydrogenation zone to produce C.sub.3.sup.= /C.sub.4.sup.= olefins.Type: GrantFiled: December 2, 1994Date of Patent: February 4, 1997Assignee: UOPInventors: Christopher D. Gosling, Joseph H. Gregor, Charles P. Luebke
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Patent number: 5569788Abstract: A process is directed to the removal of impurities such as sulfur compounds, oxygenates, and/or olefins from a light paraffin hydrocarbon feedstock such as a C.sub.4 -C.sub.6 fraction, which may be used subsequently in an isomerization process in an integrated complex for the production of ethers such as MTBE and TAME. The hydrocarbon feedstream is passed to a removal zone wherein the hydrocarbon feedstream is contacted with a selective solvent for the removal of the impurities comprising at least one of sulfur compounds, oxygenates and olefins to provide a rich solvent stream and a treated hydrocarbon stream. The rich solvent comprising the trace impurities is contacted with a stripping medium stream to regenerate the selective solvent in a stripping zone. The removal zone may be a liquid-liquid extraction zone or a gas absorption zone.Type: GrantFiled: March 20, 1995Date of Patent: October 29, 1996Assignee: UOPInventors: Paulino Forte, Stanley J. Frey
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Patent number: 5523502Abstract: A novel process having improved flexibility in olefins production is provided which integrates a deep catalytic cracking process with a steam cracking process, and optionally, also including steps of disproportionation and C.sub.4 hydrocarbon processing including methyl tertiary butyl ether synthesis.Type: GrantFiled: November 10, 1993Date of Patent: June 4, 1996Assignee: Stone & Webster Engineering Corp.Inventor: Jacob N. Rubin
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Patent number: 5481057Abstract: A process for catalytic cracking and C3/C4 olefin alkylation with phosphorus stabilized faujasite catalyst is disclosed. Catalytic cracking produces C3 and C4 olefins, which are alkylated using phosphorus stabilized and water activated cracking catalyst. Spent alkylation catalyst may be discharged into the FCC unit.Type: GrantFiled: March 25, 1994Date of Patent: January 2, 1996Assignee: Mobil Oil CorporationInventors: Weldon K. Bell, Tracy J. Huang, Rudolph M. Lago, Ying-Yen P. Tsao, D. Duayne Whitehurst
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Patent number: 5414179Abstract: A process for processing a cracked feed stream so as to provide a feed stream, having a requisite concentration of isobutylene and butene-1,to a polymerization unit for polymerization of isobutylene.Type: GrantFiled: April 29, 1994Date of Patent: May 9, 1995Assignee: Phillips Petroleum CompanyInventors: Harold R. Hunt, Stephen P. Thomas
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Patent number: 5414183Abstract: An improved process is disclosed for the removal of nitrogen compounds from light hydrocarbon streams. Such nitrogen removal enhances the performance of catalytic processes which upgrade light hydrocarbons, especially light olefins, such as isomerization and etherification. The nitrogen-removal process can usefully be combined with steps for removal of sulfur compounds and highly unsaturated compounds in a process combination for upgrading the light hydrocarbons.Type: GrantFiled: December 24, 1992Date of Patent: May 9, 1995Assignee: UOPInventors: Hayim Abrevaya, Suleyman M. Ozmen, Paul T. Barger, Christopher D. Gosling, Thomas A. Verachtert
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Patent number: 5401893Abstract: This invention deals with a process for converting aliphatic C.sub.2 -C.sub.6 hydrocarbons into C.sub.6.sup.+ aromatics and C.sub.3.sup.= /C.sub.4.sup.= olefins. The process involves combining dehydrocyclodimerization (DHCD) with dehydrogenation. Thus, the feedstream is first sent to a DHCD zone which produces an effluent stream which contains C.sub.6.sup.+ aromatics along with C.sub.1 -C.sub.5 hydrocarbons. This effluent stream is separated into a stream containing C.sub.1 -C.sub.4 hydrocarbons and one containing C.sub.6.sup.+ aromatics. The C.sub.1 -C.sub.4 containing stream is flowed to a dehydrogenation zone to produce C.sub.3.sup.= /C.sub.4.sup.= olefins.Type: GrantFiled: December 16, 1993Date of Patent: March 28, 1995Assignee: UOPInventors: Christopher D. Gosling, Joseph H. Gregor, Charles P. Luebke
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Patent number: 5334792Abstract: There is provided a process for ring opening of aromatics and cycloaliphatics, as well as isomerization of aliphatics. The feedstream to this process comprises hydrocarbons having 6 carbon atoms. The process involves the use of at least two reactors connected in series. The first reactor contains a zeolite catalyst and is operated under conditions which particularly promote ring opening. The catalyst in this first reactor may comprise zeolite Beta and platinum. A downstream reactor is operated under conditions to promote isomerization of aliphatics. The catalyst in the second reactor may comprise alumina, platinum and a chloride component.Type: GrantFiled: October 9, 1992Date of Patent: August 2, 1994Assignee: Mobil Oil CorporationInventors: Kenneth J. Del Rossi, David J. Dovedytis, David J. Esteves, Mohsen N. Harandi, Albin Huss, Jr.
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Patent number: 5300696Abstract: A combination of an etherification process and a process for the isomerization of linear alkenes to isoalkenes uses an adsorptive separation zone that receives an effluent fraction from the etherification reaction zone and separates the fraction at low efficiency to produce an isomerization feed stream comprising normal butenes and butanes, and a butane stream that is rejected from the process. The rejection of butanes at low efficiency reduces or eliminates the loss of butenes with the rejection of butane. A low efficiency adsorptive separation to reject butanes also benefits the isomerization process by inhibiting coking.Type: GrantFiled: December 29, 1992Date of Patent: April 5, 1994Assignee: UOPInventors: Charles P. Luebke, Srikantiah Raghuram, Joseph E. Zimmermann
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Patent number: 5283373Abstract: A combination of an etherification process and a process for the isomerization of linear alkenes to isoalkenes uses a separation zone that receives an effluent stream from the etherification reaction zone and separates it into a high boiling stream, a low boiling stream and an intermediate boiling stream in order to reduce the mass flow of reactants through the isomerization and etherification reaction zones. The separation zone includes at least one distillation column. The distillation column can provide a distillation function only, or can also provide a reactive distillation zone. The intermediate boiling stream leaves a two column separation zone as a bottoms stream from a second column or in a single column separation zone as a sidecut which in the case of reactive distillation is taken from the point above a bed of catalyst within the column.Type: GrantFiled: December 28, 1992Date of Patent: February 1, 1994Assignee: UOPInventors: Charles P. Luebke, Bipin V. Vora, David A. Wegerer, Joseph E. Zimmermann
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Patent number: 5276212Abstract: A combination of an etherification process and a process for the isomerization of linear alkenes to isoalkenes uses a first etherification zone that passes an etherification effluent and an etherification recycle stream through a skeletal isomerization separation zone to prepare an etherification feed for an additional etherification reactor. Etherification of additional isoalkane reactants in a separate etherification zone permits the production of additional ether products through isomerization without requiring additional etherification capacity upstream of the isomerization zone. Therefore additional etherification capacity can be added without significant changes to existing etherification capacity. The additional etherification zone may be in the form of a reactive distillation reactor that provides a high boiling ether product stream, a low boiling isoalkane vent stream and an intermediate boiling normal butene sidecut stream.Type: GrantFiled: December 29, 1992Date of Patent: January 4, 1994Assignee: UOPInventors: Charles P. Luebke, Joseph E. Zimmermann
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Patent number: 5254748Abstract: A method for integrating several petroleum refining processes so as to efficiently produce tertiary alkyl ether compounds from a feed stream containing both saturated and unsaturated hydrocarbons is disclosed. An important step for forming isoolefins in the integrated process involves simultaneous catalytic conversion of an isoparaffin to an isoolefin and an n-olefin to an n-paraffin in a combination hydrogenation/dehydrogenation reactor. The thus produced isoolefin is reacted with a primary alcohol to form the desired tertiary alkyl ether compound in an ether forming process. Other conversion process included in the overall integration are an isomerization process to convert n-paraffins to isoparaffins and optionally an alkylation process to convert isoparaffins and olefins to an alkylate product.Type: GrantFiled: December 17, 1991Date of Patent: October 19, 1993Assignee: Phillips Petroleum CompanyInventors: Harvey D. Hensley, Richard L. Anderson, Michael E. Olbrich
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Patent number: 5237115Abstract: A novel integrated olefin processing scheme is provided where olefins and paraffins are processed to produce high octane gasoline blending components. The integrated process involves the dehydrogenation of paraffin compounds to olefin compounds and the processing of olefins by hydroisomerization to produce hydroisomerate streams which are subsequently etherified. Those olefin compounds which are not etherified pass to an alkylation process where they are alkylated with branched chain paraffin compounds to produce an alkylate product.Type: GrantFiled: June 16, 1992Date of Patent: August 17, 1993Assignee: Phillips Petroleum CompanyInventors: Donald J. Makovec, Robert O. Dunn, Martyn E. Pfile, Gary R. Patton, Larry E. Lew
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Patent number: 5210327Abstract: A combination of an etherification process and a process for the isomerization of linear alkenes to isoalkenes uses a separation zone that receives an effluent stream from the etherification reaction zone and separates it into a high boiling stream, a low boiling stream and an intermediate boiling stream in order to reduce the mass flow of reactants through the isomerization and etherification reaction zones. The separation zone normally has an arrangement of a distillation column. The distillation column can provide a distillation function only, or can also provide a reactive distillation zone. The intermediate boiling stream typically leaves the column as a sidecut which in the case of reactive distillation is taken from the point above a bed of catalyst within the column. Taking the sidecut stream substantially eliminates the circulation of isoalkane hydrocarbons through the etherification and isomerization zone and maintains normal alkanes at an acceptable equilibrium level.Type: GrantFiled: May 15, 1992Date of Patent: May 11, 1993Assignee: UOPInventors: Charles P. Luebke, Bipin V. Vora, David A. Wegerer, Joseph E. Zimmermann, Kevin C. Buck
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Patent number: 5177114Abstract: This invention comprises a method for converting natural gas to a normally liquid carbon containing compound, such as methanol and/or dimethyl ether and/or to gasoline grade liquid hydrocarbons and/or olefins. The method of this invention eliminates the need for steam reforming and/or adiabatic reforming with essentially pure oxygen of the natural gas to a synthesis gas. In accordance with the process of this invention, a synthesis gas may be produced at an operating pressure suitable for conversion thereof to methanol and/or dimethyl ether without the need for synthesis gas recompression. Further, the vent or bleed gas from the overheads after conversion to the crude product methanol/DME and/or its conversion to gasoline grade liquid hydrocarbons, generally has a BTU capacity required to serve as a fuel gas for supplying the energy needed for operation of a gas turbine which powers the gas compression equipment requirements by which the process of this invention may be practiced.Type: GrantFiled: March 30, 1992Date of Patent: January 5, 1993Assignee: Starchem Inc.Inventors: Christiaan P. Van Dijk, Lowell D. Fraley
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Patent number: 5166455Abstract: A process has been discovered for the conversion of C.sub.5 -C.sub.7 olefinic hydrocarbons, such as those contained in FCC light naphtha, to iso-butene-rich and isoamylene-rich streams in an integrated process for the production of MTBE and TAME. The process involves the initial separation of the isoamylene-rich C.sub.5 -fraction of the feedstream which is converted to TAME. The C.sub.6 -C.sub.7 fraction plus unreacted C.sub.5 's are converted by olefin interconversion with medium pore zeolite catalyst into an isobutylene and isoamylene-rich stream which is then used as feedstream for etherification to MTBE and TAME.Type: GrantFiled: January 16, 1992Date of Patent: November 24, 1992Assignee: Mobil Oil CorporationInventors: Arthur A. Chin, Frederick J. Krambeck, Stephen S. Wong, Sergei Yurchak
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Patent number: 5110446Abstract: The present invention provides a process for decreasing the energy consumption of a catalytic cracking process product recovery section while improving gasoline yield by integrating multistage vapor compression and product recovery with deacidification and conversion of C.sub.2 -C.sub.4 aliphatics to C.sub.5 + normally liquid hydrocarbons.Type: GrantFiled: September 7, 1990Date of Patent: May 5, 1992Assignee: Mobil Oil CorporationInventors: Mohsen N. Harandi, Hartley Owen
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Patent number: 5059744Abstract: An improved olefin upgrading technique and fixed-bed reactor system has been developed for increasing production of premium heavy hydrocarbons, such as distillate fuel, from lower olefinic feedstock. During recovery and recycle of intermediate range hydrocarbons products, a technique has been found for withdrawing a fraction rich in C.sub.5 -C.sub.9 gasoline range olefinic hydrocarbons from the oligomerization reactor effluent stream. By separating the reaction effluent in a multi-stage distillation system, fractionation feed can be separated into a heavier bottoms stream rich in C.sub.10 + hydrocarbons and a light hydrocarbon overhead, while withdrawing a liquid stream as an overflash fractionation stream rich in intermediate hydrocarbons. The overflash stream is combined to form a portion of the recycle stream to the reactor, thereby providing a more efficient and lower cost recovery process.Type: GrantFiled: September 29, 1989Date of Patent: October 22, 1991Assignee: Mobil Oil CorporationInventors: Moshen N. Harandi, Hartley Owen
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Patent number: 5041690Abstract: Methanol or other alcohol is converted to high octane gasoline components by an integrated process wherein crude aqueous alcohol feedstock is extracted with a liquid extractant stream containing C.sub.4 +iso-olefin and reacted to form tertiary-alkyl ethers, such as MTBE. The aqueous raffinate is converted to olefinic hydrocarbons in a MTO catalytic reactor. Propene from the MTO reaction is reacted with water to produce di-isopropyl ether, which may be blended with MTBE and C.sub.6 +MTO hydrocarbons to produce high octane gasoline. Isobutylene and isoamylenes from the MTO reaction can be recovered and recycled as a liquid extractant stream.Type: GrantFiled: August 3, 1990Date of Patent: August 20, 1991Assignee: Mobil Oil CorporationInventors: Mohsen N. Harandi, Hartley Owen
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Patent number: 5026934Abstract: The invention provides a method of converting light hydrocarbons to olefins, gasoline and methanol. In the first stage, a gas containing one or more light hydrocarbons is synthesized to higher hydrocarbons including raw gasoline. However, at commercially acceptable selectivities using currently available catalyst, a majority of the light hydrocarbons remain unsynthesized. In addition, the synthesis produces significant quantities of carbon dioxide and some carbon monoxide. In this method the unsynthesized light hydrocarbons and the oxides of carbon are used to produce methanol, which can be used for several purposes including gasoline or ethylene synthesis.Type: GrantFiled: February 12, 1990Date of Patent: June 25, 1991Assignee: Lyondell Petrochemical CompanyInventors: Charanjit S. Bains, Martin P. Grosboll
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Patent number: 5023389Abstract: The invention relates to a process for preparing normally liquid hydrocarbon products such as middle distillates and methyl-t-butylether from a hydrocarbon feed containing linear and branched olefins (e.g. propane and butenes in light ends) comprising at least the following steps:i) selectively converting branched olefins in the feed in the presence of a catalyst into a normally liquid hydrocarbonaceous product (e.g. MTBE);ii) separating linear olefins from product obtained in step (i), andiii) catalytically oligomerizing linear olefins obtained from step (ii) into liquid hydrocarbons such as middle distillates.Type: GrantFiled: February 10, 1989Date of Patent: June 11, 1991Assignee: Shell Oil CompanyInventors: Pierre Grandvallet, Andras G. T. G. Kortbeek, Johannes P. Van Den Berg, Karl-Heinz Robschlager
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Patent number: 5015795Abstract: The thermal stability of synthetic lubricants composed of alpha-olefin oligomers is improved by reaction with an olefin such as decene or the lower molecular weight, non-lubricant range olefins produced in the course of the oligomerization of 1-alkenes. The alkylation of the lube range oligomer is carried out using acidic alkylation catalyst such as solid, open-pore catalyst, e.g., fluorided alumina.The improved lubricant compositions of the present invention comprise a high viscosity index liquid lubricant oligomer composition containing C.sub.30 -C.sub.1300 hydrocarbons with at least one higher alkyl branch per oligomer molecule, said alkyl branch containing between 12 and 40 carbon atoms. In a preferred embodiment the novel alkylated lubricant composition has a methyl to methylene branch ratio of less than 0.19 and pour point below -15.degree. C.Type: GrantFiled: August 3, 1990Date of Patent: May 14, 1991Assignee: Mobil Oil CorporationInventor: Bruce P. Pelrine
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Patent number: 5001292Abstract: An integrated process is disclosed that substantially reduces the cost of producing MTBE and other alkyl tert-alkyl ethers by eliminating a major portion of the equipment and operating costs associated with the downstream processing of the etherification reactor effluent. The integrated process combines the process for the etherification of isoolefins and methanol, or other alkanols, to produce methyl tertiary alkyl ethers such as MTBE and/or TAME with the catalytic process for converting feedstock such as oxygenates, light olefins and paraffins to higher molecular weight hydrocarbons. Unconverted reactants from the etherification reaction, which may comprise unreacted alkanol and unreacted hydrocarbons or just unreacted hydrocarbons, are separated from the product ethers and passed to the catalytic conversion process reactor for conversion to gasoline boiling range hydrocarbons.Type: GrantFiled: October 16, 1989Date of Patent: March 19, 1991Assignee: Mobil Oil CorporationInventors: Mohsen N. Harandi, Hartley Owen
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Patent number: 4990712Abstract: Gasoline octane number and yield are improved while excess fuel gas production is decreased in a catalytic cracking process by integrating etherification and oxygenate/aliphatic upgrading processes into the catalytic cracking unit product fractionation section.Type: GrantFiled: May 18, 1990Date of Patent: February 5, 1991Assignee: Mobil Oil CorporationInventors: Mohsen N. Harandi, Hartley Owen
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Patent number: 4962249Abstract: Near linear higher olefinic hydrocarbons produced by the oligomerization of lower olefins using surface deactivated zeolite catalyst can be converted to a mixture comprising slightly branched and linear higher alpha olefins. These alpha olefins are oligomerized to lubricant grade hydrocarbons in contact with cationic, Ziegler or coordination catalyst. Oligomerization of the aforementioned alpha olefins using reduced valence state Group VIB metal oxide catalyst on porous support provides a hydrocarbon lubricant with a viscosity index of greater than 130 at 100.degree. C.Type: GrantFiled: February 15, 1990Date of Patent: October 9, 1990Assignee: Mobil Oil CorporationInventors: Catherine S. H. Chen, Margaret M. S. Wu
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Patent number: 4950821Abstract: An improved process is disclosed for the conversion of natural gas into middle distillates. In the process, natural gas is converted into synthesis gas or syngas consisting essentially of carbonmonoxide and hydrogen. The syngas is contacted with a series of three catalyst beds comprising of an admixture of oxides of copper, zinc and aluminium in the first bed, an oxide of aluminium in the second bed and silicate salt of a rare earth metal in the third bed. From the aqueous phase, the olefinic hydrocarbons are separated and then converted into oligomers boiling in the middle distillates range by contacting with solid oligomerization catalyst. The oligiomers in admixture with hydrogen are then converted into middle distillates by contacting the admixture with a hydrogenation catalyst. The middle distillates are well known for their varied applications as fuel and illuminators.Type: GrantFiled: August 11, 1989Date of Patent: August 21, 1990Assignee: Council of Scientific & Industrial ResearchInventors: Paul Ratnasamy, Subramanian Sivasanker
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Patent number: 4891457Abstract: A staged reactor technique for converting ethene-rich olefinic feedstock to heavier hydrocarbons, particularly gasoline and distillate range products. By employing low temperature and high temperature separators, an economic recycle is provided for each stage.Type: GrantFiled: September 13, 1985Date of Patent: January 2, 1990Inventors: Hartley Owen, Bernard S. Wright
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Patent number: 4886925Abstract: An integrated process is disclosed for the conversion of C.sub.2 + normal olefins into methyl tertiaryalkyl ethers and high octane gasoline. The process combines olefins interconversion with etherification and conversion of unreacted methanol and olefins in contact with acidic, shape selective metallosilicate zeolite catalyst.Type: GrantFiled: May 2, 1988Date of Patent: December 12, 1989Inventor: Mohsen N. Harandi
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Patent number: 4879428Abstract: An improved olefin upgrading technique has been developed for increasing production of premium heavy hydrocarbons, such as distillate fuel, from lower olefinic feedstock. During recovery and recycle of intermediate range hydrocarbons products, a process has been found for withdrawing a fraction rich in C.sub.5 -C.sub.9 gasoline range olefinic hydrocarbons from the oligomerization reactor effluent stream. By separating the reaction effluent in a multistage distillation system, fractionation feed can be separated into a heavier bottoms stream rich in C.sub.10+ hydrocarbons and a light hydrocarbon overhead, while withdrawing a liquid stream as an overflash fractionation stream rich in intermediate hydrocarbons. The overflash stream is combined to form a portion of the recycle stream to the reactor, thereby providing a more efficient and lower cost recovery process.Type: GrantFiled: March 3, 1988Date of Patent: November 7, 1989Inventors: Mohsen N. Harandi, Hartley Owen
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Patent number: 4806699Abstract: Aromatic hydrocarbons are produced from a feedstock comprising ethane and/or propane and/or butane by the steps of:(A) reacting the feedstock in the presence of a dehydrocyclodimerization catalyst to produce a product comprising aromatic hydrocarbons, hydrogen and methane,(B) separating the product of step (A) into an aromatic hydrocarbon fraction, a methane-rich gaseous fraction and a hydrogen-rich gaseous fraction,(C) feeding all or part of the methane-rich gaseous fraction separated in step (B) to a synthesis gas production unit, thereby to produce synthesis gas, and(D) contacting the synthesis gas from step (C) together with all or part of the hydrogen-rich gaseous fraction separated in step (B), thereby increasing the hydrogen to carbon monoxide ratio of the synthesis gas, with a Fischer-Tropsch conversion catalyst to produce a hydrocarbon product.Type: GrantFiled: November 5, 1987Date of Patent: February 21, 1989Assignee: The British Petroleum Company p.l.c.Inventors: David J. H. Smith, William T. Woodfin
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Patent number: 4788365Abstract: An integrated process for the conversion of methanol to high octane gasoline and distillate. Methanol is converted to olefins in the presence of zeolite type catalyst. C.sub.4 and C.sub.5 olefin fraction is converted to MTBE and TAME in the presence of excess methanol and acid etherification catalyst. Unreacted methanol and hydrocarbons are passed to an olefins to gasoline and distillate oligomerization unit in conjunction with C.sub.3, C.sub.6 and C.sub.7 olefins from the methanol to olefins unit whereby distillate and LPG products are produced. Gasoline products from the oligomerization unit are passed to the etherification unit whereby an ether-rich gasoline fraction is separated.Type: GrantFiled: December 8, 1987Date of Patent: November 29, 1988Assignee: Mobil Oil CorporationInventors: Mohsen N. Harandi, Hartley Owen
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Patent number: 4788366Abstract: A multi-stage catalytic olefin upgrading technique for converting lower olefinic feedstock to heavier liquid hydrocarbon product.Type: GrantFiled: December 28, 1987Date of Patent: November 29, 1988Assignee: Mobil Oil CorporationInventors: Mohsen N. Harandi, Hartley Owen, Samuel A. Tabak