Abstract: A total delivery oxygen concentration system is provided to supply concentrated oxygen to end users having a variety of oxygen capacity requirements. The system includes a first oxygen concentrating device that may be operated either singularly to produce a first flow of concentrated oxygen or in conjunction with a supplemental oxygen concentrating device. When operating in conjunction with the supplemental oxygen concentrating device, the first oxygen concentrating device serves as a source of compressed air for the supplemental oxygen concentrating device and receives a second flow of concentrated oxygen from the supplemental oxygen concentrating device to provide a combined concentrated oxygen flow to the end user.

Abstract: A VPSA apparatus includes a first adsorbent bed and a second adsorbent bed, a feed blower for providing a flow of a gas mixture at about atmospheric pressure to the beds, and a vacuum blower for removing a flow of gas therefrom and venting the gas to a space at atmospheric pressure. The VPSA process causes the first adsorbent bed to be poised for evacuation by the vacuum blower and concurrently, the second adsorbent bed is under vacuum conditions and is poised for pressurization by the feed blower. A single motor is coupled by a common shaft to both the feed blower and the vacuum blower and operates both. A conduit/valve arrangement is operative during at least a portion of a process time when the adsorbent beds are in pressurizing/evacuation states, respectively, to couple the feed blower to the second adsorbent bed when at vacuum and for concurrently coupling the vacuum blower to the first adsorbent bed which is to be evacuated.

Abstract: The present invention is directed to an apparatus for supplying gas at a first pressure and at a second pressure. The apparatus includes a gas generating system having a gas generating system outlet. A flow switch is in communication with the gas generating system outlet and has an outlet thereof forming a gas outlet at the first pressure. A pressure regulator is in communication with the gas generating system outlet for regulating gas flowing to the gas outlet at the first pressure. A solenoid valve is electrically controlled by the flow switch and is in communication with the gas generating system outlet and has a solenoid valve outlet. A pressure intensifier is in communication with the solenoid valve for raising the pressure of the gas generated by the gas generating system for output to an outlet at a second pressure.

Abstract: This invention provides a pressure swing adsorption process for purifying a synthesis gas stream containing from 60 to 90 mole % hydrogen and impurities such as CO2, CH4, N2, and CO. The PSA process of the invention further provides a method of adsorbing substantially all of the nitrogen and other contaminants from the feed gas stream; wherein the feed stream is passed at superatmospheric pressure through a plurality of adsorbent beds and each adsorbent bed contains at least a CaX, LiA, LiX or calcium containing mixed cation zeolite having a SiO2/Al2O3 mole ratio of 2.0-2.5. Such process involves sequentially pressurizing, depressurizing, purging and repressurizing the adsorbent beds with product hydrogen, and recovering product hydrogen in purities of 99.9% or greater from the beds.

Abstract: Process for separating nitrogen from a gas mixture containing nitrogen and at least one gas which is less polar than nitrogen, and employing a differential gas adsorption technique, called PSA process, using an adsorbent of zeolite type, according to which the PSA process is used at a temperature of at least 40° C. by employing as adsorbent a zeolite whose nitrogen adsorption isotherm at 20° C.

Abstract: A PSA, especially VSA, plant for separating a gas stream, operating in a production cycle and comprising at least one adsorber, preferably two or three adsorbers, and several valves having long and heterogeneous operating times. More specifically, the average operating time (&mgr;) of the valves is such that: 0.5 s<&mgr;<2 s and the operating time (&Dgr;t) of each of the valves is such that: &mgr;−x<&Dgr;t<&mgr;+x, with 0.1 s<x<0.5 s. The invention also relates to the use of such a PSA plant for producing a gas stream rich in oxygen, in nitrogen or in hydrogen, particularly a stream comprising more than 80% oxygen, which is then sent to an oxygen-consuming plant chosen from a combustion furnace, a paper-pulp manufacturing unit and a water treatment unit.

Abstract: A PSA, especially VSA, process for separating a stream of gas, such as air, containing at least one first compound, such as nitrogen, which is preferentially adsorbed on at least one adsorbent and at least one second compound, such as oxygen, which is adsorbed less preferentially on the adsorbent than the first compound. The adsorbent comprises at least particles of a zeolite having a Si/Al ratio of less than or equal to 5 and chosen from zeolites of X or A type, the zeolite having a kinetics coefficient (ak) and an intrinsic strength (&agr;), with: ak>0.5 s−1 and 0.10<&agr;<2. The invention also relates to an adsorbent for the non-cryogenic separation of gases, especially the gases from air and from syngas.

Abstract: A pressure swing adsorption process for the separation of hydrogen from a mixture of the same with methane, utilizing two separate PSA stages, one containing a nitrogen selective crystalline zeolite, and the second containing a methane selective adsorbent.

Abstract: A gas separation plant includes, downstream of the line for feeding the gas separation module with a compressed gas mixture, a liquid particle separation device which includes a liquid detector, for example, of the optronic type, delivering an output signal, connected to an alarm device and to a central control unit of the plant.

Abstract: The present invention relates to a rotary valve assembly for a pressure swing adsorption system. The rotary valve assembly includes a first valve member and a second valve member relatively rotatable about a common center of rotation to provide valving action for selectively transferring fluids therethrough. The second valve member has a first fluid section with at least one aperture adapted for transferring a first fluid of a first pressure and composition therethrough and a second fluid section with at least one aperture adapted for transferring a second fluid of a second pressure and composition therethrough. The first valve member has a first fluid section with at least one passage for transferring the first fluid in the valve assembly and a second fluid section with at least one passage for transferring the second fluid in the valve assembly.

Abstract: An improved adsorption process is provided for purifying hydrogen from a feed gas mixture including hydrogen and at least one impurity selected from the group consisting of carbon monoxide and nitrogen. The process includes providing an adsorption apparatus having a discharge end adsorption layer containing an adsorbent with a Henry's law constant (KH) at 70° F. for the impurity from about 0.5 to about 2.4 mmole/g/atm. The product gas collected from the adsorption apparatus is high purity (99.99+%) hydrogen.

Abstract: A method of separating a first gaseous component from a gas mixture comprising the first gaseous component and a second gaseous component comprising passing the gaseous mixture into an adsorption zone containing an adsorbent material capable of preferentially adsorbing at least one of the gaseous components in the gaseous mixture, to separate the first gaseous component from the second gaseous component wherein the adsorbent material is a monolithic having a plurality of channels throughout, said channels being aligned parallel to the direction of flow of the gaseous mixture and having a wall thickness of less than 1 mm and (b) recovering the non-preferentially adsorbed gaseous component from the adsorption zone. Preferably, the adsorption zone comprises multiple layers of monolithic structures in the shape of a wheel stacked one upon the other in a direction parallel to the direction of the flow of the gaseous mixture and form by spirally winding a sheet of corrugated adsorbable material about a hub.

Abstract: The plant for producing a product stream includes, mounted in series, several modules adapted to perform successive and distinct elementary treatments. At least two elementary treatment modules each include at least two treatment apparatuses mounted in parallel. The plant furthermore includes a device for controlling the various treatment apparatuses as a function of the product stream desired at the outlet of the plant. The control device includes sensors for measuring at least two variables representative of the product stream, and a fuzzy logic regulator adapted for controlling, in at least two distinct treatment modules, at least two treatment apparatuses of the same module, on the basis of the same measured representative variable.

Abstract: A method and plant to process a fluid comprising one or more compounds G2 having a kinetic diameter less than or equal to that of nitrogen and one or more compounds G1 having a kinetic diameter greater than or equal to that of methane. The method and plant use in combination, several adsorption and desorption stages during which a first stream F1 mainly comprising compounds G1, a second stream F2 enriched in compounds G2, a third stream F3 mainly comprising compounds G2 and a fourth stream F4 mainly comprising compounds G1 are produced. At least a fraction of stream F3 is used to flush adsorption section A1.

Abstract: A repressurization phase of an adsorber comprises a step of first countercurrent repressurization with at least gas from a first co-current decompression of another adsorber, this phase ending in a step of co-current production. Immediately following the first countercurrent repressurization step, air is introduced co-current into the adsorber.

Abstract: An installation for the treatment of fluid having a receptacle (1) defining a non-vertical portion of a path for fluid through at least two adjacent masses (A; B; C) of particulate materials, typically different from each other, each mass being in direct contact with its neighbor or neighbors, without the interposition of a separating grid. The installation is particularly useful for the separation or drying of air.

Abstract: In this process, the apparatus for separating the feed gas is connected to the delivery side of at least one variable-rotation-speed compressor, whose speed is controlled on the basis of the measurement of a parameter representative of the flow of gas product. The process is useful in the production of nitrogen from atmospheric air.

Abstract: The invention relates to a process for controlling a PSA, especially VSA, plant for separating a gas stream, in particular a gas stream containing nitrogen and at least one less polar gaseous component, especially oxygen and/or hydrogen. The PSA plant operates in a production cycle and has one or more adsorbers, each production cycle comprising at least one feed step of feed duration (TA), which comprises introducing the gas stream to be separated into an adsorber; at least one production step, which comprises recovering a stream of gas produced at a prefixed production pressure (PP) and with a prefixed nominal production output (DN); and at least one pumping step of pumping duration (TP); which comprises extracting a gas stream from at least one adsorber.

Abstract: A PSA or VSA process for separating a gas flow, such as air, containing at least one first gas compound, such as nitrogen, which is preferentially adsorbed on at least one adsorbent, and at least one second gas compound, such as oxygen, which is adsorbed less preferentially on at least the one adsorbent than the first gas compound. The adsorbent used comprises particles of faujasite zeolite having a Si/Al ratio <1.5, such as a LSX zeolite, and containing 80 to 99% Li+ cations, 0.01 to 25% Na+ cations, 0.01% to 10% Mg2 cations, 0.01% to 10% Ca2+ cations and 0 to 3% K+ cations.

Abstract: The present invention provides a pressure swing adsorption process. The process includes providing a pressure swing adsorption apparatus having a discharge end adsorption layer of activated carbon, feeding through the apparatus a feed gas including hydrogen, carbon monoxide and at least one of argon and oxygen, and collecting a product gas from the apparatus, wherein the product gas is high purity hydrogen. Also provided is a method for decreasing an amount of impurities in a product gas from a pressure swing adsorption process for separating hydrogen from impurities including carbon monoxide, and at least one of argon and oxygen.

Abstract: A PSA process for separating a gas flow, such as air, containing a first gas compound, such as nitrogen, which is adsorbed preferentially on an adsorbent, and a second gas compound, such as oxygen, which is adsorbed less preferentially on the adsorbent than the first gas compound. The adsorbent is formed by an aggregate comprising a zeolite phase and a binder, and contains elements Si, Al, Li, Na, Mg, K and Ca, the total proportions of these elements in the adsorbent being such that the Si/Al ratio is between 1 and 2.4, the Na/Li ratio is between 0.012 and 0.300, the Mg/Li ratio is between 0.012 and 0.400, the Ca/Li ratio is between 0.012 and 0.200, and the K/Li ratio is between 0.001 and 0.060.

Abstract: Upon a reduction of the production flow rate, there is added to the cycle, at an extreme pressure PM and/or Pm of the cycle substantially different from atmospheric pressure, an idle time in the course of which the adsorber (1A, 1B) is isolated. The process is used in trans-atmospheric cycles for the production of oxygen from atmospheric air.

Abstract: A method of separating a first gaseous component from a gas mixture comprising the first gaseous component and a second gaseous component comprising passing the gaseous mixture into an adsorption zone containing an adsorbent material capable of preferentially adsorbing at least one of the gaseous components in the gaseous mixture, to separate the first gaseous component from the second gaseous component wherein the adsorbent material is a monolith having a plurality of channels throughout, the channels being aligned parallel to the direction of flow of the gaseous mixture and having a wall thickness of less than 1 mm and (b) recovering the non-preferentially adsorbed gaseous component from the adsorption zone. Preferably, the adsorption zone comprises multiple layers of monolithic structures in the shape of a wheel stacked one upon the other in a direction parallel to the direction of the flow of the gaseous mixture and form by spirally winding a sheet of corrugated adsorbable material about a hub.

Abstract: A method and apparatus for operating a pressure swing adsorption process is disclosed that may utilize only a single adsorption stage yet still produce a continuous stream of a concentrated fluid. A portion of the enriched fluid produced during the adsorption cycle in an adsorption chamber is used to purge the adsorption chamber.

Abstract: According to the present invention, a process is provided which overcomes historical limitations to the capacity of PSA units for a wide variety of gas separations. Capacities in excess of about 110 thousand normal cubic meters per hour (100 million standard cubic feet per day) can now be achieved in a single integrated process train. The corresponding significant equipment reduction results from a departure from the accepted principle in the PSA arts that the length of the purge step must be equal to or less than the length of the adsorption step.

Abstract: A pressure swing adsorption process for the separation of hydrogen from a mixture of the same with methane, utilizing two separate PSA stages, one containing a nitrogen selective crystalline zeolite, and the second containing a methane selective adsorbent.

Abstract: The flow of gas between two vessels, each of which undergoes cyclic changes in gas pressure, is controlled by two check valves installed in parallel between the vessels. The first check valve allows gas to flow from the first vessel to the second vessel when the differential pressure between the vessels exceeds a first value, and the second check valve allows gas to flow from the second vessel to the first vessel when the differential pressure between the vessels exceeds a second value. The gas flow control method is particularly useful in pressure swing adsorption processes.

Abstract: The invention comprises a pressure swing adsorption process for the separation of a less adsorbable component from a mixture comprising the less adsorbable component and a more adsorbable component, the process comprising a cyclic adsorption/desorption process wherein the desorption step is at a selected pressure and occurs for a selected time such that a pressure reducing apparatus utilized to evacuate the gas does not require extraneous cooling.

Abstract: Pressure swing adsorption separation of a feed gas mixture, to obtain a purified product gas of the less strongly adsorbed fraction of the feed gas mixture, is performed in a plurality of preferably an even number of adsorbent beds, with each adsorbent bed communicating at its product end directly to a variable volume expansion chamber, and at its feed end by directional valves to a feed compressor and an exhaust vacuum pump. For high frequency operation of the pressure swing adsorption cycle, a high surface area layered support is used for the adsorbent. The compressor and vacuum pump pistons may be integrated with the cycle, reciprocating at twice the cycle frequency. Alternative configurations of the layered adsorbent beds are disclosed.

Abstract: The cycle employed is of the transatmospheric type with the use of a production buffer tank (C1), and with a purge/elution phase close to the low pressure in which gas output by another adsorber in the first cocurrent decompression phase is introduced in countercurrent into the adsorber (A, B) and, simultaneously, the countercurrent pumping is continued. During the production step, the oxygen produced is also sent into an auxiliary tank (C2), and the gas contained in this auxiliary tank is, with regard to the adsorber, used solely during a fraction of the pressurization phase of the adsorber.

Abstract: An adsorbent for separating gases, which comprises a binder and a crystalline low-silica faujasite type zeolite with a SiO2/Al2O3 molar ratio of from 1.9 to 2.1, wherein the average pore diameter of the macropores is equal to or larger than the mean free path of an adsorbable component when desorbing the adsorbable component from the adsorbent, and at least 70% of the total volume of the macropores is occupied by macropores having a diameter equal to or larger than the mean free path of the adsorbable component.

Abstract: A small system for efficiently producing low flow rates of a nitrogen or nitrogen/hydrogen stream from an initial feed which also contains oxygen, employing a defined catalytic reactor unit producing product at very high space velocities.

Abstract: A method and apparatus for operating a pressure swing adsorption process having an adsorption zone is disclosed that may utilize only a single adsorption stage. The purge cycle is automatically commenced by a pressure build up in the enriched fluid vented from an adsorption zone.

Abstract: A PSA process and system utilizes a combination of cyclic feed, evacuation, purge, and repressurization steps to provide a final gas product enriched in one of the feed components. The process is carried out in a simple system which utilizes a single two-way four-port valve for controlling gas flow between an adsorber vessel and a blower, and the blower is used for the introduction of feed gas into the adsorber and the evacuation of gas from the adsorber. The control of gas flow in either direction between the adsorber vessel and a product gas storage tank is accomplished by two check valves installed in parallel between the vessel and the tank.

Abstract: A method and apparatus for operating a pressure swing adsorption process is disclosed that may utilize only a single adsorption stage yet still produce a continuous stream of a concentrated fluid.

Abstract: The invention comprises a PSA process and apparatus wherein the fixed adsorbent bed comprises an equilibrium zone and a mass transfer zone. Further, the equilibrium and mass transfer zones each comprise at least one adsorbent material, selective for the adsorption of a more selectively adsorbable component, that is selected on the basis of the performance of that adsorbent material under the process conditions applicable to either the equilibrium or mass transfer zones.

Abstract: Process and single-bed pressure swing adsorption system for separating gas mixtures, especially air. The process includes a simultaneous countercurrent product purge and partial product repressurization step which shortens cycle time and improves overall system operation.

Abstract: Adsorbent composites composed of microparticulate zeolites at least 90% of whose particles have a characteristic particle dimension not greater than about 0.6 micron and a macropore inert binder. The composites are useful for separating strongly adsorbed gas components from gas mixtures. Microparticulate type X zeolites composites are particularly useful for separating nitrogen or carbon dioxide from air.

Abstract: A dual-chambered, four-ported rotary valve with a rotatable drum having peripheral openings is used to selectively connect vacuum and/or air sources and a vent to absorption chambers in a two-bed VPSA (vacuum presssure swing absorption) system to replace separate valves and produce low cost enriched oxygen, via reduced power, increased reliability, and reduced complexity and cost.

Abstract: A method of separating a more strongly adsorbable component from one or more less strongly adsorbable components residing in a gaseous mixture comprising contacting the gaseous mixture at elevated pressure with a composition and adsorbing the more strongly adsorbed gas specie on the composition, wherein the composition is represented by the formulaM.sup.n+.sub.(2x+y)/n [Si.sub.(2-x-y) Al.sub.(y) Zn.sub.(x) ]O.sub.4 ;whereinM is cation selected from Groups 1, 2, 7, 10, 11, 12 and the f block elements as defined by thePeriodic Table of the elements as adopted by IUPAC;n is the valence of the selected cation; M;x is greater than or equal to 0.02 but less than or equal to 1;y is a value less than or equal to 0.98; and2x+y is greater than or equal to 0.80;wherein the composition of matter has a FAU structure and zinc resides in.sub.-- tetrahedral positions in the framework of the FAU structure.

Abstract: A process for reducing pollutants, particularly nitrogen oxides from combustion gases during a combustion process that takes place while oxygen is supplied, includes providing oxygen needed for the combustion process by separating oxygen from a gas mixture containing oxygen and nitrogen in a two-step process including (a) enriching the gas mixture with oxygen in a first step to provide an enriched gas mixture; and (b) separating oxygen out of the enriched gas mixture in a second step, wherein, during at least one step oxygen depleted gas mixture is removed via an outlet provided with permeability means that cause the outlet to have a higher permeability for nitrogen than oxygen.

Abstract: A process for controlling the atmosphere in a container including the steps of passing a pressurized portion of the atmosphere serially through a plurality of separate but inter-communicating adsorbent beds which selectively adsorb water vapor, ethylene, carbon dioxide and nitrogen from the compressed atmosphere, then isolating the ethylene-selective adsorbent and desorbing ethylene therefrom, then desorbing nitrogen from the nitrogen-selective adsorbent and purging the carbon dioxide-selective bed, the ethylene-selective bed and the water vapor-selective bed with the desorbed nitrogen, and returning the purge and purged gas mixture to the container.

Abstract: This invention is directed to the synthesis of high bulk density high gas absorption capacity adsorbents for gas storage applications. Specifically, this invention is concerned with novel gas absorbents with high gravimetric and volumetric gas adsorption capacities which are made from fullerene-based materials. By pressing fullerene powder into pellet form using a conventional press, then polymerizing it by subjecting the fullerene to high temperature and high inert gas pressure, the resulting fullerene-based materials have high bulk densities and high gas adsorption capacities. By pre-chemical modification or post-polymerization activation processes, the gas adsorption capacities of the fullerene-based adsorbents can be further enhanced. These materials are suitable for low pressure gas storage applications, such as oxygen storage for home oxygen therapy uses or on-board vehicle natural gas storage.

Abstract: Pressure swing adsorption process and system for separating gas mixtures comprising at least one more strongly adsorbable component and at least one less strongly adsorbable component. The process includes storing gas enriched in one of the components in a first storage tank and a second storage tank. Final product gas is provided from the second storage tank while gas for purge, rinse, and/or repressurization is provided from the first storage tank.

Abstract: This process uses a pressure variation cycle, in which, at at least one instant in the cycle, a terminal of a compression machine (1, 3) is switched from a first space (A1) which is at a first pressure P1 to a second space (A2) which is at a pressure P2 significantly different from P1. The switching comprises an intermediate operation in which the terminal is brought simultaneously into communication with the first space and with the second space. The process is useful in the production of oxygen from atmospheric air by adsorption.

Abstract: Pressure swing adsorption process and system for separating gas mixtures comprising at least one more strongly adsorbable component and at least one less strongly adsorbable component. The process includes storing gas enriched in one of the components in a first storage tank and a second storage tank which are arranged in series. Final product gas is provided from the second storage tank while gas for purge, rinse, and/or repressurization is provided from the first storage tank.

Abstract: According to this process, in the case of a reduction in the production rate, the maximum pressure PM of the cycle is lowered and the ratio of this maximum pressure to the minimum pressure Pm of the cycle is reduced, in particular by altering the durations of compression and decompression stages. The process is applicable to the production of oxygen at variable rate.

Abstract: Process for purifying an inert fluid, in particular argon or helium, with respect to at least one of its impurities nitrogen (N.sub.2), oxygen (O.sub.2), carbon dioxide (CO.sub.2), carbon monoxide (CO) and hydrocarbons, in which at least some of the impurities are removed using a first adsorbent of the X zeolite type having a silica to aluminum ratio less than or equal to 1.15, and a purified inert fluid containing at most 10 ppb, preferably at most 1 ppb of impurities is recovered.

Abstract: A molecular sieve type gas separation apparatus (10) for separating product gas from a gas supply (14) includes at least one sieve bed (11-13) which during an adsorption charge phase of a cycle, adsorbs non product gas in the gas supply (14), and in a desorption regeneration phase of the cycle desorbs the previously adsorbed non product gas. The apparatus further includes an outlet (18) to which product gas is delivered during the adsorption charge phase, and an outlet (31) for non product gas during the desorption regeneration phase. A sensor (36) responsive to the concentration of a constituent in the product gas, and a control (20) to switch the apparatus (10) between the adsorption charge and desorption regeneration phases are further provided. The control (20) is adapted to adjust the duration of adsorption charge phase relative to the duration of the desorption regeneration phase in each cycle.

Abstract: The device comprises an adsorber (1) and three outlet capacities (2-4), first (8, 9) and second (10, 11) structure to establish bidirectional communication between the adsorber and the elution capacity (2) and the repressurization capacity (3), respectively, and third structure (14A, 15; 16) to establish unidirectional communication from the adsorber to the production capacity (4).