Abstract: A fluid storage and dispensing system, comprising: a fluid storage and dispensing vessel constructed and arranged for selective dispensing of fluid therefrom; a solid-phase support in the vessel; and an affinity medium on the solid-phase support, wherein the affinity medium reversibly takes up the fluid when contacted therewith, and from which the fluid is disengagable under dispensing conditions. The affinity medium may be a liquid, oil, gel, or solid (porous solid, thin film solid, or bulk solid). The system of the invention may be employed for the storage and dispensing of fluids such as hydride, halide and dopant gases for manufacturing of semiconductor products.

Abstract: A method of processing semiconductor manufacturing exhaust gases for recovering at least hexafluoroethane in which a feed stream composed of the exhaust gases is passed through an adsorbent bed selected to adsorb oxygen, and also nitrogen if present, but not to appreciably adsorb the hexafluoroethane. As a result, a product stream, discharged from the adsorbent bed, has a higher concentration of hexafluoroethane than in the feed stream. In one embodiment, only a single adsorbent such as carbon molecular sieve is provided to adsorb the oxygen or a modified 4A zeolite could be used to adsorb both oxygen and nitrogen. When nitrogen is a potential constituent, layers of carbon molecular sieve and zeolite are provided to adsorb the oxygen and then the nitrogen, respectively. A third adsorbent, preferably 5A zeolite may be provided in addition to the foregoing two adsorbents to also adsorb any carbon tetrafluoride produced as a by-product.

Abstract: A process for the separation and recovery of fluorochemicals from a gas stream containing a diluent gas and fluorochemicals by contact of the gas stream with a membrane system in combination with an adsorption system, the adsorption system used either before or after the membrane system.

Abstract: A device for removing at least laughing gas and anesthetic vapor from a gas sample based on a molecular sieve shall be improved such that it possesses good adsorption properties for both gas components. A molecular sieve arrangement is provided, which is flown through from a gas inlet to a gas outlet and comprises a first molecular sieve area with a first pore size between about 0.3 nm and 0.5 nm and a second molecular sieve area with a second pore size between about 0.8 nm and 1 nm.

Abstract: A compact organic solvent recovery system includes a backup treatment apparatus for environmentally safe treatment of an organic solvent leaking into a gas exiting an adsorption tower packed with an adsorbing material such as particulate active charcoal or active carbon fiber. Adsorption treatment of organic solvents includes introducing an organic solvent containing gas to be treated into an organic solvent recovery apparatus including an adsorption tower packed with adsorbing material. By subsequently introducing steam into the adsorption tower, the organic solvents are desorbed. By introducing the treated gas discharged from the organic solvent recovery apparatus into the backup treatment apparatus, the organic solvents leaking into the treated gas are adsorbed, and the gas treated in the backup treatment apparatus is simultaneously discharged as purified gas.

Abstract: A method for the removal and rapid decomposition of halogenated fumigation agents is described. A fumigation agent, such as methyl bromide, contained in the gas stream exiting a fumigation chamber or structure is captured on activated carbon or other retentive substrate and rapidly decomposed using thiosulfate and water. The method provides an inexpensive, safe, and on-site executable way to remove and detoxify methyl bromide from fumigation discharge gases, thereby reducing or eliminating methyl bromide emissions into the atmosphere.

Abstract: A condensable component present at low concentration in a feed gas mixture containing the condensable component and a noncondensable component is recovered by selective adsorption from the feed gas mixture in an adsorption step, the resulting adsorbed condensable component is desorbed by a heated purge gas in a regeneration step to yield a purge gas effluent enriched in desorbed condensable component, and the purge gas effluent is cooled to condense and recover the condensable component as a liquid.

Abstract: Processes and systems to recover at least one perfluorocompound gas from a gas mixture are provided. In one embodiment the inventive process comprises the steps of a) providing a gas mixture comprising at least one perfluorocompound gas and at least one carrier gas, the gas mixture being at a predetermined pressure; b) providing at least one glassy polymer membrane having a feed side and a permeate side; c) contacting the feed side of the at least one membrane with the gas mixture; d) withdrawing from the feed side of the membrane as a non-permeate stream at a pressure which is substantially equal to the predetermined pressure a concentrated gas mixture comprising essentially the at least one perfluorocompound gas; and e) withdrawing from the permeate side of the membrane as a permeate stream a depleted gas mixture comprising essentially the at least one carrier gas.

Abstract: Method to remove organic halogenated molecules from gaseous currents arriving as a residue of industrial working processes or not, the gaseous current being delivered into a reactor (16) containing a fluid bed consisting of at least one solid adsorbent element after having undergone at least one filtration followed by a cooling, the gaseous current cooperating with the solid particles with exchange by adsorption between the gaseous current and the solid particles, the reactor (16) achieving a time of contact between the gaseous current and the solid particles at least longer than 3 seconds, the gaseous current which enters the reactor (16) having a temperature lower than 80.degree. C., but advantageously between 30.degree. and 70.degree. C., the cooling of the gaseous current upstream of the reactor (16) being followed by a gas/water or gas/air heat exchanger (13).

Abstract: The process of purifying oxygen-containing exhaust gases produced by combustion of waste materials including garbage, industrial waste and sewage sludge includes reacting an exhaust gas containing pollutants in a gas-solids suspension at a temperature of 120.degree. to 140.degree. C. and at a gas velocity from 3 to 20 m/s for a reaction time of 0.5 to 10 seconds with a mixture containing naturally occurring zeolites to remove mercury, mercury compounds and polyhalogenated hydrocarbons pollutants from the exhaust gas. The naturally occurring zeolites have a median particle size (d.sub.50) from 5 to 50 micrometers and the gas-solids suspension has a mean suspension density from 0.020 to 10 kg of solids per sm.sup.3 of exhaust gas. The mixture contains from 10 to 20% by weight mordenite, from 60 to 70% by weight clinoptilolite, from 0 to 5% by weight montmorillonite and a remaining balance of SiO.sub.2. The purified gas contains <50 micrograms of mercury per sm.sup.3, <0.1 ng TE per sm.sup.

Abstract: A process for recovery of halocarbons from a gas mixture containing the halocarbon and acid gas components comprises the steps of contacting the gas mixture with a dry scrubber to remove the acid gas components from the gas mixture and yield a first effluent gas mixture containing the halocarbon. The first effluent gas mixture is contacted with an adsorbent which is selective for the halocarbon component of the first effluent gas mixture to adsorb the halocarbon component and yield a second effluent gas. The adsorbed halocarbon is recovered by desorbing same from the adsorbent. The process of contacting with adsorbent can be carried out in at least two adsorbent beds joined at inlet and outlet ends thereof to gas feed and gas discharge manifolds, respectively.

Abstract: A process and apparatus for the recovery and purification of a contaminated refrigerant withdrawn from a refrigeration or refrigerant recovery system which employs a compressor and an adsorbent selective for the adsorption of halogenated hydrocarbons. The adsorbent is selected from the group consisting of silicalite, faujasites, steamed and rare earth exchanged zeolite Y, mordenite, ZSM-5 and mixtures thereof, and more particularly the group consisting of a low cerium rare earth exchanged zeolite Y-84, a low cerium rare earth exchanged zeolite LZ-210, Breck Structure Six, ECR-32, and mixtures thereof. A significant increase in the capacity of these adsorbents over conventional adsorbents combined with the use of novel process steps to recover, purify and return a purified refrigerant to the refrigeration system result in significant cost savings at reduced risk of release of halogenated hydrocarbons to the environment.

Abstract: Selected strongly adsorbed gaseous impurities are removed from a gas stream by pressure swing adsorption in an adsorption system which includes a single adsorption vessel, a gas storage vessel and a single gas pump. Feed gas is pumped at a selected adsorption pressure cocurrently through the adsorption vessel, which contains an adsorbent that selectively adsorbs the selected impurity or impurities. The less strongly adsorbed components of the gas mixture pass out the adsorption vessel through the nonadsorbed gas outlet end of the adsorption vessel. When the adsorbed gas front reaches a certain point in the adsorption vessel, the adsorption step is terminated and gas is countercurrently transferred from the adsorption vessel to a gas storage vessel, optionally with use of the gas pump. The adsorption vessel is then countercurrently evacuated by use of the pump and a selected gas-enriched product is recovered and sent to storage or further processed in downstream treatment operations.

Abstract: Acidic halogens, especially chlorides, are removed from a dry gas stream by contact with dry particles of solid caustic. The solid caustic particles are preferably non-porous, and disposed in a bed with at least a 10% bed interstitial volume. Limiting halogen content in gas, and operating with a bone dry gas, ensures that salts deposit on the surface of the solid caustic without plugging the bed of solid caustic. Efficient halogen removal can be achieved even when treating a bone dry gas, one having less than 10 ppmv water vapor, at ambient temperature, without plugging the bed.

Abstract: Acidic halides, especially chlorides, are removed from gas by contact with particles of solid caustic covered by aqueous and hydrocarbon phases, respectively. Effective neutralization is achieved without swelling or plugging the bed of solid caustic. Halides are removed as brine. Efficient caustic utilization is achieved by controlling water vapor levels in the gas based on pH of brine product.

Abstract: An quaternary phosphonium ion-exchanged clay and method of removing organic contaminants from air and/or water, by contacting the contaminants in the air or water with a quaternary phosphonium organo-clay. The clay is prepared by ion-exchange of an ion-exchangeable clay with (a) tetra-short chain alkyl (C.sub.1 -C.sub.4) quaternary phosphonium ion or (b) a di- or tri-short chain alkyl (C.sub.1 -C.sub.4) quaternary phosphonium ion having 1 or 2 mono-substituted or unsubstituted cycloakyl moieties, or one or two alkaryl moieties for removing air-laden and water-laden organic contaminants. The new organo-clays and methods are particularly adapted for removal of aromatic petroleum-based contaminants from water, such as benzene; alkyl-benzenes, such as toluene; xylenes (o-, m- and p-isomers); and chlorinated 1 and 2 carbon compounds, such as CCl.sub.4.

Abstract: The present invention is directed to a process for preventing the formation of dioxin and/or furan during combustion of composite combustible materials in a combustion chamber. The process includes passing the generated combustion gas in a flow from the combustion chamber to a dedusting device, cooled and purified while maintaining the SO.sub.3 content in the combustion gas flow from about 7 to about 500 mg/m.sup.3 and at a temperature of from about 300 .degree. to about 800.degree. C., The process allows at least surface regions of particles of meal dusts contained in the combustion gas to be converted to sulfates and thereby prevent formation of dioxins and furan. The invention also includes a steam generator for carrying out the process whose steel structures coming into contact with the combustion gases are either alloyed or coated with tungsten and/or vanadium on the combustion-gas side.

Abstract: A method for decomposing volatile organic halogenated compounds in water containing such compounds and metal ions by removing the metal ions from the water and then contacting the deionized water with a reducing agent in the presence of a catalyst. The volatile organic halogenated compounds are efficiently decomposed with a small energy requirement and low cost to eliminate, thus, making the water safe.

Abstract: Environmental release of carcinogenic polychlorinated dibenzo-dioxins and polychlorinated dibenzo-furan compounds that typically result from combustion of materials containing chlorine or hydrochloric acid-generating components is minimized by preferential sorption of the precursor reactants on sorbents added to exhaust gas at high temperatures containing such precursors prior to conversion of the precursors to carcinogenic compounds normally occurring as the exhaust gas is cooled.

Abstract: Unused methyl bromide from a fumigation cycle is captured by adsorption on a molecular sieve and recycled for reuse or recovery by desorption with hot gas without the need to purge the fumigation chamber with outside air. The loss of methyl bromide to the atmosphere is minimal.

Abstract: A method of treatment of a liquid or gaseous fluid to decompose volatile organic halogenated compounds therein comprises bringing the fluid containing volatile organic halogenated compounds in contact with a reducing agent in the presence of a metal catalyst and optionally thereafter treating the thus treated fluid with at least one of an adsorption treatment, a thermal decomposition and a biological decomposition treatment. The method efficiently decomposes the volatile organic halogenated compounds contained in a fluid, such as water or a gas, with a small expenditure of energy and at low cost and renders the fluid harmless to the environment.

Abstract: An apparatus for containing and scrubbing toxic or corrosive gases from a leaking pipe or cylinder is provided. A gas passageway attaches at one end to a leakage location on a pipe or cylinder, and at the other end to an air operated exhauster. The air operated exhauster, through the input of a non-flammable purge gas, creates an exhaust flow from the leakage location to a drum which is attached to the air operated exhauster. The drum contains a scrubbing media which, when it contacts the leaked gas, cleans or removes the harmful component, thus allowing release to the atmosphere of the cleaned air.

Abstract: A novel organic amine-impregnated activated carbon composition is disclosed which may be used in breathing gas filters to enhance removal of various toxic perfluorocarbons. Three processes for impregnating activated carbon with organic amines are also disclosed. One of these processes comprises the steps of placing the amine in contact with substantially dry activated carbon, subjecting the carbon and amine to an environment devoid of oxidizing gases or vapors (such as oxygen gas), and then heating the carbon and amine for an extended period while maintaining this oxidizer-free environment. Pretreatment procedures to enhance both the shelf-life and service-life of the amine-impregnated activated carbon are also disclosed.

Abstract: A process is disclosed for separating HF from organics by passing a mixture of HF and organics through a column or bed containing a polymer which sorbs the HF leaving an essentially pure organic stream. The HF may be recovered from the polymer, or the organics may be recovered with reduced HF concentration. The HF and organics may form an azeotropic or azeotrope-like mixture.

Abstract: The present invention provides a process for the recovery of methyl chloride from a mixture thereof with isobutane. The process employs pressure swing adsorption with a size selective adsorbent having a pore opening of between about 3.7.times.3.7 Angstroms and about 4.9.times.5.7 Angstroms, such as zeolite A, clinoptilolite and mixtures thereof to selectively adsorb methyl chloride from vent streams comprising methyl chloride and isobutane and recovering a tail gas stream enriched in methyl chloride. The process may be used in applications such as treating the vent gas streams from the direct synthesis of methyl chlorosilanes. The process provides an economical route to recovering a valuable raw material in the process of making silicones and reduces the volume and methyl chloride content of the vent stream which is typically incinerated to avoid the release of halogenated hydrocarbons to the atmosphere.

Abstract: A process and apparatus for the recovery and purification of a contaminated refrigerant withdrawn from a refrigeration or refrigerant recovery system which employs a compressor and an adsorbent selective for the adsorption of halogenated hydrocarbons. The adsorbent is selected from the group consisting of silicalite, faujasites, steamed and rare earth exchanged zeolite Y, mordenite, ZSM-5 and mixtures thereof, and more particularly the group consisting of a low cerium rare earth exchanged zeolite Y-84, a low cerium rare earth exchanged zeolite LZ-210, Breck Structure Six, ECR-32, and mixtures thereof. A significant increase in the capacity of these adsorbents over conventional adsorbents combined with the use of novel process steps to recover, purify and return a purified refrigerant to the refrigeration system result in significant cost savings at reduced risk of release of halogenated hydrocarbons to the environment.

Abstract: A process produces fibers from polymers which give off troublesome gases and/or vapors during spinning, comprising the steps of:a) extruding the molten polymer through a spinneret into a closed spinning shaft,b) quenching the resulting filaments in the spinning shaft with a gas,c) taking off the resulting filaments from the spinning shaft,d) conducting the quench gas away from the spinning shaft and introducing it into a gas purification system ande) purifying the used quench gas by contact with an adsorbent for said troublesome gases and/or vapors.It is possible by the present invention to keep hazardous gases occurring during the spinning of polymers away from the surroundings and to dispose of them. Suitable polymers are in particular polyphenylene sulfides.

Abstract: Crystalline molecular sieves containing octahedral sites such as the sieves known as ETS-4, ETS-10 and ETAS-10 are used to remove volatile organic compounds from a mixture of the same with moist air at ambient temperature.

Abstract: A pressure swing and temperature swing adsorption system is disclosed which continuously purges contaminants such as nuclear, biological and chemical warfare agents from intake air and provides cool clean air to the crew compartment of a vehicle by progressively directing contaminated air through a first adsorption bed to clean the air, while simultaneously directing hot exhaust gases at about 600.degree. F. through a second adsorption bed for purging contaminants therefrom, while simultaneously cooling a third adsorption bed for enhancing adsorption of contaminants in the purging bed upon repeating the cycles of operation.

Abstract: A mixed gas is contacted with a non-carbonaceous adsorbent while irradiating the adsorbent with an electromagnetic wave having a frequency of 1 MHz to 25 GHz, such as a microwave, so that a gas component having a smaller coefficient of dielectric loss is selectively adsorbed by the adsorbent. A gas adsorbed on an adsorbent may be desorbed therefrom by contact with a desorbing gas while irradiating the adsorbent with the above electromagnetic wave.

Abstract: A vapor phase adsorption system employing an adsorbent for removing a volatile organic compound from an air stream to produce a purified air effluent in which the adsorbent first adsorbs the compound and is then regenerated by raising the temperature of the adsorbent to a maximum desorption temperature, which employs an improvement which comprises an unloading compound pre-adsorbed on the adsorbent, wherein the unloading compound is an organic compound having a boiling point greater than that of the volatile organic compound and having an equilibrium loading capacity on the adsorbent at the maximum desorption temperature greater than the equilibrium loading capacity of the volatile organic compound.

Abstract: This invention relates to purification of a multicomponent gas while purifying and circulating a gas medium, such as a laser gas medium or the like. An object of the present invention is to provide a gas laser apparatus operating method and a gas laser apparatus in which it is easy to keep the laser output power constant for a long time. Disclosed is a method which performs laser oscillation while circulating a laser multicomponent gas medium containing a rare gas and in which the laser gas medium is circulated through an absorbent (10) which has been refrigerated to a temperature where all the components of the laser gas medium necessary for laser oscillation are not solidified.

Abstract: A method of removing hydrocarbon contaminants from air and a method of removing nonionic organic contaminants, particularly petroleum-derived aromatic contaminants that have a limited capacity to ionize in aqueous solution at substantially neutral pH, from water, by contacting the contaminants in the air or water with an organophilic clay that has been prepared by ion-exchange of an ion-exchangeable clay with a tetra short chain alkyl C.sub.1 -C.sub.4), quaternary ammonium ion for use in removing air-laden contaminants; or a di- or tri- short chain alkyl (C.sub.1 -C.sub.4), with one or two mono- substituted or unsubstituted cycloalkyl moieties, or one or two mono-substituted or unsubstituted aryl or one or two alkaryl moiety quaternary ammonium ion for removing air and water-laden contaminants.

Abstract: A method for the preparation of a carbon molecular sieve capable of separating acid gases and fluorocarbons of the formula C.sub.a H.sub.b X.sub.c F.sub.d, wherein a is from 1 to about 6, b is from 0 to about 13, c is from 0 to about 13, d is from 1 to about 14, and X is a halogen; on the basis of shape selectivity and size exclusion. A precursor resin is heated at about 0.2.degree. C. per minute to about 500.degree. C. Then the resin is soaked at about 500.degree. C. for about 6 hours in flowing inert gas.

Abstract: An integrated process for treating a vent gas stream containing halogenated organic compounds to produce a clean vent gas with vacuum swing adsorption of the halogenated organic compounds and the recycle of a gaseous stream from the halogenated organic compound recovery section. A liquid sponge oil containing halogenated organic compounds is contacted and admixed with the evacuated effluent from the adsorption zone to prevent the accumulation of normally gaseous hydrocarbonaceous compounds.

Abstract: A process for purifying waste gases containing polyhalogenated compounds, in particular dioxins and furans, which waste gases accumulate, for example, in a garbage incinerator 1, are directed through a filter 3, which contains an adsorption agent, e.g., activated coke. The adsorption agent, loaded with harmful substances, in particular dioxins and furans, is transported under an inert gas to another processing operation or to storage. During this transportation step, the dioxins and furans are decomposed in heating zones 11 and cooling zones 12, with the preferred decomposition temperature being about 250.degree.-450.degree. C.

Abstract: Ground water which contains heavy metal ions and toxic volatile organic compounds is purified by passing an air stream through it to purge out the organic compounds, adsorbing the displaced organic compounds on a molecular sieve and destroying them using a strong oxidizing agent such as hydrogen peroxide. This procedure avoids having the heavy metal ions from the water collect on the molecular sieve which causes the destruction of the oxidizing agent.